Articles | Volume 13, issue 6
https://doi.org/10.5194/acp-13-3045-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-13-3045-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
15 Mar 2013
Research article |
| 15 Mar 2013
The diurnal variability of atmospheric nitrogen oxides (NO and NO2) above the Antarctic Plateau driven by atmospheric stability and snow emissions
M. M. Frey
British Antarctic Survey, Natural Environment Research Council, Cambridge, UK
N. Brough
British Antarctic Survey, Natural Environment Research Council, Cambridge, UK
J. L. France
Department of Earth Sciences, Royal Holloway, University of London, Egham, UK
P. S. Anderson
British Antarctic Survey, Natural Environment Research Council, Cambridge, UK
Scottish Association for Marine Science, Oban, Argyll, Scotland, PA37 1QA, UK
O. Traulle
CNRM-GAME, URA 1357, Météo France CNRS, Toulouse, France
M. D. King
Department of Earth Sciences, Royal Holloway, University of London, Egham, UK
A. E. Jones
British Antarctic Survey, Natural Environment Research Council, Cambridge, UK
E. W. Wolff
British Antarctic Survey, Natural Environment Research Council, Cambridge, UK
J. Savarino
Université Joseph Fourier – Grenoble 1/CNRS-INSU, Laboratoire de Glaciologie et Géophysique de l'Environnement, St. Martin d'Hères, France
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J. Erbland, W. C. Vicars, J. Savarino, S. Morin, M. M. Frey, D. Frosini, E. Vince, and J. M. F. Martins
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This preprint is open for discussion and under review for Climate of the Past (CP).
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We show how measurements of nitrogen isotopes in Antarctic ice core records can be used to show dramatic thinning of an ice sheet during ice mass changes in the Holocene. Combining such measurements with proxies for ice sheet elevation could be a powerful tool for constraining the history of ice dynamics at sites which are sensitive to rapid changes, and could contribute to constraining ice sheet models.
Felix S. L. Ng, Rachael H. Rhodes, Tyler J. Fudge, and Eric W. Wolff
EGUsphere, https://doi.org/10.5194/egusphere-2025-1566, https://doi.org/10.5194/egusphere-2025-1566, 2025
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Impurity diffusion in ice causes loss of climate history. We give a new method of finding the diffusion rate from ice-core records. Its use on sulphate data from the EPICA Dome C core reveals rapid diffusion in snow that suggests H2SO4 vapour diffusion in air pores, and much slower diffusion in the ice below that indicates signal relocation between crystal interfaces. We estimate a maximum sulphate diffusion length of 2 cm for ice 1–2 Myr old sought by the ice-coring projects on Little Dome C.
Niklas Kappelt, Eric Wolff, Marcus Christl, Christof Vockenhuber, Philip Gautschi, and Raimund Muscheler
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Rosalie H. Shepherd, Martin D. King, Andrew D. Ward, Edward J. Stuckey, Rebecca J. L. Welbourn, Neil Brough, Adam Milsom, Christian Pfrang, and Thomas Arnold
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Rachael H. Rhodes, Yvan Bollet-Quivogne, Piers Barnes, Mirko Severi, and Eric W. Wolff
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Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
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Applying factor analysis techniques to H-NMR spectra, we present the organic aerosol (OA) source apportionment of PM1 samples collected in parallel at two Antarctic stations, namely Signy and Halley, allowing investigation of aerosol–climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open-ocean) and sympagic (sea-ice-influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
V. Holly L. Winton, Robert Mulvaney, Joel Savarino, Kyle R. Clem, and Markus M. Frey
Clim. Past, 20, 1213–1232, https://doi.org/10.5194/cp-20-1213-2024, https://doi.org/10.5194/cp-20-1213-2024, 2024
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In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We present the first results including a 1300-year record of snow accumulation and aerosol chemistry. We investigate the aerosol and moisture source regions and atmospheric processes related to the ice core record and discuss what this means for developing a record of past ultraviolet radiation and ozone depletion using the stable isotopic composition of nitrate measured in the same ice core.
Magdalena Pühl, Anke Roiger, Alina Fiehn, Alan M. Gorchov Negron, Eric A. Kort, Stefan Schwietzke, Ignacio Pisso, Amy Foulds, James Lee, James L. France, Anna E. Jones, Dave Lowry, Rebecca E. Fisher, Langwen Huang, Jacob Shaw, Prudence Bateson, Stephen Andrews, Stuart Young, Pamela Dominutti, Tom Lachlan-Cope, Alexandra Weiss, and Grant Allen
Atmos. Chem. Phys., 24, 1005–1024, https://doi.org/10.5194/acp-24-1005-2024, https://doi.org/10.5194/acp-24-1005-2024, 2024
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In April–May 2019 we carried out an airborne field campaign in the southern North Sea with the aim of studying methane emissions of offshore gas installations. We determined methane emissions from elevated methane measured downstream of the sampled installations. We compare our measured methane emissions with estimated methane emissions from national and global annual inventories. As a result, we find inconsistencies of inventories and large discrepancies between measurements and inventories.
Isobel Rowell, Carlos Martin, Robert Mulvaney, Helena Pryer, Dieter Tetzner, Emily Doyle, Hara Madhav Talasila, Jilu Li, and Eric Wolff
Clim. Past, 19, 1699–1714, https://doi.org/10.5194/cp-19-1699-2023, https://doi.org/10.5194/cp-19-1699-2023, 2023
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We present an age scale for a new type of ice core from a vulnerable region in West Antarctic, which is lacking in longer-term (greater than a few centuries) ice core records. The Sherman Island core extends to greater than 1 kyr. We provide modelling evidence for the potential of a 10 kyr long core. We show that this new type of ice core can be robustly dated and that climate records from this core will be a significant addition to existing regional climate records.
Amelia M. H. Bond, Markus M. Frey, Jan Kaiser, Jörg Kleffmann, Anna E. Jones, and Freya A. Squires
Atmos. Chem. Phys., 23, 5533–5550, https://doi.org/10.5194/acp-23-5533-2023, https://doi.org/10.5194/acp-23-5533-2023, 2023
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Atmospheric nitrous acid (HONO) amount fractions measured at Halley Research Station, Antarctica, were found to be low. Vertical fluxes of HONO from the snow were also measured and agree with the estimated HONO production rate from photolysis of snow nitrate. In a simple box model of HONO sources and sinks, there was good agreement between the measured flux and amount fraction. HONO was found to be an important OH radical source at Halley.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
David A. Hodell, Simon J. Crowhurst, Lucas Lourens, Vasiliki Margari, John Nicolson, James E. Rolfe, Luke C. Skinner, Nicola C. Thomas, Polychronis C. Tzedakis, Maryline J. Mleneck-Vautravers, and Eric W. Wolff
Clim. Past, 19, 607–636, https://doi.org/10.5194/cp-19-607-2023, https://doi.org/10.5194/cp-19-607-2023, 2023
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We produced a 1.5-million-year-long history of climate change at International Ocean Discovery Program Site U1385 of the Iberian margin, a well-known location for rapidly accumulating sediments on the seafloor. Our record demonstrates that longer-term orbital changes in Earth's climate were persistently overprinted by abrupt millennial-to-centennial climate variability. The occurrence of abrupt climate change is modulated by the slower variations in Earth's orbit and climate background state.
Maxim L. Lamare, John D. Hedley, and Martin D. King
The Cryosphere, 17, 737–751, https://doi.org/10.5194/tc-17-737-2023, https://doi.org/10.5194/tc-17-737-2023, 2023
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The reflectivity of sea ice is crucial for modern climate change and for monitoring sea ice from satellites. The reflectivity depends on the angle at which the ice is viewed and the angle illuminated. The directional reflectivity is calculated as a function of viewing angle, illuminating angle, thickness, wavelength and surface roughness. Roughness cannot be considered independent of thickness, illumination angle and the wavelength. Remote sensors will use the data to image sea ice from space.
Eric W. Wolff, Andrea Burke, Laura Crick, Emily A. Doyle, Helen M. Innes, Sue H. Mahony, James W. B. Rae, Mirko Severi, and R. Stephen J. Sparks
Clim. Past, 19, 23–33, https://doi.org/10.5194/cp-19-23-2023, https://doi.org/10.5194/cp-19-23-2023, 2023
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Large volcanic eruptions leave an imprint of a spike of sulfate deposition that can be measured in ice cores. Here we use a method that logs the number and size of large eruptions recorded in an Antarctic core in a consistent way through the last 200 000 years. The rate of recorded eruptions is variable but shows no trends. In particular, there is no increase in recorded eruptions during deglaciation periods. This is consistent with most recorded eruptions being from lower latitudes.
Benjamin Heikki Redmond Roche and Martin D. King
The Cryosphere, 16, 3949–3970, https://doi.org/10.5194/tc-16-3949-2022, https://doi.org/10.5194/tc-16-3949-2022, 2022
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Sea ice is bright, playing an important role in reflecting incoming solar radiation. The reflectivity of sea ice is affected by the presence of pollutants, such as crude oil, even at low concentrations. Modelling how the brightness of three types of sea ice is affected by increasing concentrations of crude oils shows that the type of oil, the type of ice, the thickness of the ice, and the size of the oil droplets are important factors. This shows that sea ice is vulnerable to oil pollution.
Albane Barbero, Roberto Grilli, Markus M. Frey, Camille Blouzon, Detlev Helmig, Nicolas Caillon, and Joël Savarino
Atmos. Chem. Phys., 22, 12025–12054, https://doi.org/10.5194/acp-22-12025-2022, https://doi.org/10.5194/acp-22-12025-2022, 2022
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The high reactivity of the summer Antarctic boundary layer results in part from the emissions of nitrogen oxides produced during photo-denitrification of the snowpack, but its underlying mechanisms are not yet fully understood. The results of this study suggest that more NO2 is produced from the snowpack early in the photolytic season, possibly due to stronger UV irradiance caused by a smaller solar zenith angle near the solstice.
Takahito Mitsui, Polychronis C. Tzedakis, and Eric W. Wolff
Clim. Past, 18, 1983–1996, https://doi.org/10.5194/cp-18-1983-2022, https://doi.org/10.5194/cp-18-1983-2022, 2022
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We provide simple quantitative models for the interglacial and glacial intensities over the last 800 000 years. Our results suggest that the memory of previous climate states and the time course of the insolation in both hemispheres are crucial for understanding interglacial and glacial intensities. In our model, the shift in interglacial intensities at the Mid-Brunhes Event (~430 ka) is ultimately attributed to the amplitude modulation of obliquity.
Helene M. Hoffmann, Mackenzie M. Grieman, Amy C. F. King, Jenna A. Epifanio, Kaden Martin, Diana Vladimirova, Helena V. Pryer, Emily Doyle, Axel Schmidt, Jack D. Humby, Isobel F. Rowell, Christoph Nehrbass-Ahles, Elizabeth R. Thomas, Robert Mulvaney, and Eric W. Wolff
Clim. Past, 18, 1831–1847, https://doi.org/10.5194/cp-18-1831-2022, https://doi.org/10.5194/cp-18-1831-2022, 2022
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The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
Eric W. Wolff, Hubertus Fischer, Tas van Ommen, and David A. Hodell
Clim. Past, 18, 1563–1577, https://doi.org/10.5194/cp-18-1563-2022, https://doi.org/10.5194/cp-18-1563-2022, 2022
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Projects are underway to drill ice cores in Antarctica reaching 1.5 Myr back in time. Dating such cores will be challenging. One method is to match records from the new core against datasets from existing marine sediment cores. Here we explore the options for doing this and assess how well the ice and marine records match over the existing 800 000-year time period. We are able to recommend a strategy for using marine data to place an age scale on the new ice cores.
David N. Wagner, Matthew D. Shupe, Christopher Cox, Ola G. Persson, Taneil Uttal, Markus M. Frey, Amélie Kirchgaessner, Martin Schneebeli, Matthias Jaggi, Amy R. Macfarlane, Polona Itkin, Stefanie Arndt, Stefan Hendricks, Daniela Krampe, Marcel Nicolaus, Robert Ricker, Julia Regnery, Nikolai Kolabutin, Egor Shimanshuck, Marc Oggier, Ian Raphael, Julienne Stroeve, and Michael Lehning
The Cryosphere, 16, 2373–2402, https://doi.org/10.5194/tc-16-2373-2022, https://doi.org/10.5194/tc-16-2373-2022, 2022
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Based on measurements of the snow cover over sea ice and atmospheric measurements, we estimate snowfall and snow accumulation for the MOSAiC ice floe, between November 2019 and May 2020. For this period, we estimate 98–114 mm of precipitation. We suggest that about 34 mm of snow water equivalent accumulated until the end of April 2020 and that at least about 50 % of the precipitated snow was eroded or sublimated. Further, we suggest explanations for potential snowfall overestimation.
Patrick Le Moigne, Eric Bazile, Anning Cheng, Emanuel Dutra, John M. Edwards, William Maurel, Irina Sandu, Olivier Traullé, Etienne Vignon, Ayrton Zadra, and Weizhong Zheng
The Cryosphere, 16, 2183–2202, https://doi.org/10.5194/tc-16-2183-2022, https://doi.org/10.5194/tc-16-2183-2022, 2022
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This paper describes an intercomparison of snow models, of varying complexity, used for numerical weather prediction or academic research. The results show that the simplest models are, under certain conditions, able to reproduce the surface temperature just as well as the most complex models. Moreover, the diversity of surface parameters of the models has a strong impact on the temporal variability of the components of the simulated surface energy balance.
Linh N. T. Nguyen, Harro A. J. Meijer, Charlotte van Leeuwen, Bert A. M. Kers, Hubertus A. Scheeren, Anna E. Jones, Neil Brough, Thomas Barningham, Penelope A. Pickers, Andrew C. Manning, and Ingrid T. Luijkx
Earth Syst. Sci. Data, 14, 991–1014, https://doi.org/10.5194/essd-14-991-2022, https://doi.org/10.5194/essd-14-991-2022, 2022
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We present 20-year flask sample records of atmospheric CO2, O2, and APO from the stations Lutjewad (the Netherlands), Mace Head (Ireland), and Halley (Antarctica). Data from Lutjewad and Mace Head show similar long-term trends and seasonal cycles, agreeing with measurements from another station (Weybourne, UK). Measurements from Halley agree partly with those conducted by other institutes. From our 2002–2018 Lutjewad and Mace Head records, we find good agreement for global ocean carbon uptake.
Charel Wohl, Anna E. Jones, William T. Sturges, Philip D. Nightingale, Brent Else, Brian J. Butterworth, and Mingxi Yang
Biogeosciences, 19, 1021–1045, https://doi.org/10.5194/bg-19-1021-2022, https://doi.org/10.5194/bg-19-1021-2022, 2022
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We measured concentrations of five different organic gases in seawater in the high Arctic during summer. We found higher concentrations near the surface of the water column (top 5–10 m) and in areas of partial ice cover. This suggests that sea ice influences the concentrations of these gases. These gases indirectly exert a slight cooling effect on the climate, and it is therefore important to measure the levels accurately for future climate predictions.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
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The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Shona E. Wilde, Pamela A. Dominutti, Grant Allen, Stephen J. Andrews, Prudence Bateson, Stephane J.-B. Bauguitte, Ralph R. Burton, Ioana Colfescu, James France, James R. Hopkins, Langwen Huang, Anna E. Jones, Tom Lachlan-Cope, James D. Lee, Alastair C. Lewis, Stephen D. Mobbs, Alexandra Weiss, Stuart Young, and Ruth M. Purvis
Atmos. Chem. Phys., 21, 3741–3762, https://doi.org/10.5194/acp-21-3741-2021, https://doi.org/10.5194/acp-21-3741-2021, 2021
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We use airborne measurements to evaluate the speciation of volatile organic compound (VOC) emissions from offshore oil and gas (O&G) installations in the North Sea. The composition of emissions varied across regions associated with either gas, condensate or oil extraction, demonstrating that VOC emissions are not uniform across the whole O&G sector. We compare our results to VOC source profiles in the UK emissions inventory, showing these emissions are not currently fully characterized.
Bette L. Otto-Bliesner, Esther C. Brady, Anni Zhao, Chris M. Brierley, Yarrow Axford, Emilie Capron, Aline Govin, Jeremy S. Hoffman, Elizabeth Isaacs, Masa Kageyama, Paolo Scussolini, Polychronis C. Tzedakis, Charles J. R. Williams, Eric Wolff, Ayako Abe-Ouchi, Pascale Braconnot, Silvana Ramos Buarque, Jian Cao, Anne de Vernal, Maria Vittoria Guarino, Chuncheng Guo, Allegra N. LeGrande, Gerrit Lohmann, Katrin J. Meissner, Laurie Menviel, Polina A. Morozova, Kerim H. Nisancioglu, Ryouta O'ishi, David Salas y Mélia, Xiaoxu Shi, Marie Sicard, Louise Sime, Christian Stepanek, Robert Tomas, Evgeny Volodin, Nicholas K. H. Yeung, Qiong Zhang, Zhongshi Zhang, and Weipeng Zheng
Clim. Past, 17, 63–94, https://doi.org/10.5194/cp-17-63-2021, https://doi.org/10.5194/cp-17-63-2021, 2021
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The CMIP6–PMIP4 Tier 1 lig127k experiment was designed to address the climate responses to strong orbital forcing. We present a multi-model ensemble of 17 climate models, most of which have also completed the CMIP6 DECK experiments and are thus important for assessing future projections. The lig127ksimulations show strong summer warming over the NH continents. More than half of the models simulate a retreat of the Arctic minimum summer ice edge similar to the average for 2000–2018.
James L. France, Prudence Bateson, Pamela Dominutti, Grant Allen, Stephen Andrews, Stephane Bauguitte, Max Coleman, Tom Lachlan-Cope, Rebecca E. Fisher, Langwen Huang, Anna E. Jones, James Lee, David Lowry, Joseph Pitt, Ruth Purvis, John Pyle, Jacob Shaw, Nicola Warwick, Alexandra Weiss, Shona Wilde, Jonathan Witherstone, and Stuart Young
Atmos. Meas. Tech., 14, 71–88, https://doi.org/10.5194/amt-14-71-2021, https://doi.org/10.5194/amt-14-71-2021, 2021
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Measuring emission rates of methane from installations is tricky, and it is even more so when those installations are located offshore. Here, we show the aircraft set-up and demonstrate an effective methodology for surveying emissions from UK and Dutch offshore oil and gas installations. We present example data collected from two campaigns to demonstrate the challenges and solutions encountered during these surveys.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
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The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Charel Wohl, Ian Brown, Vassilis Kitidis, Anna E. Jones, William T. Sturges, Philip D. Nightingale, and Mingxi Yang
Biogeosciences, 17, 2593–2619, https://doi.org/10.5194/bg-17-2593-2020, https://doi.org/10.5194/bg-17-2593-2020, 2020
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The oceans represent a poorly understood source of organic carbon to the atmosphere. In this paper, we present ship-based measurements of specific compounds in ambient air and seawater of the Southern Ocean. We present fluxes of these gases between air and sea at very high resolution. The data also contain evidence for day and night variations in some of these compounds. These measurements can be used to better understand the role of the Southern Ocean in the cycling of these compounds.
Thomas Lachlan-Cope, David C. S. Beddows, Neil Brough, Anna E. Jones, Roy M. Harrison, Angelo Lupi, Young Jun Yoon, Aki Virkkula, and Manuel Dall'Osto
Atmos. Chem. Phys., 20, 4461–4476, https://doi.org/10.5194/acp-20-4461-2020, https://doi.org/10.5194/acp-20-4461-2020, 2020
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We present a statistical cluster analysis of the physical characteristics of particle size distributions collected at Halley (Antarctica) for the year 2015. Complex interactions between multiple ecosystems, coupled with different atmospheric circulation, result in very different aerosol size distributions populating the Southern Hemisphere.
Markus M. Frey, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Xin Yang, Anna E. Jones, Michelle G. Nerentorp Mastromonaco, David H. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 20, 2549–2578, https://doi.org/10.5194/acp-20-2549-2020, https://doi.org/10.5194/acp-20-2549-2020, 2020
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A winter sea ice expedition to Antarctica provided the first direct observations of sea salt aerosol (SSA) production during snow storms above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in Antarctica not explained otherwise. Defining SSA sources is important given the critical roles that aerosol plays for climate, for air quality and as a potential ice core proxy for sea ice conditions in the past.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell N. Drysdale, Philip L. Gibbard, Lauren Gregoire, Feng He, Ruza F. Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis C. Tzedakis, Eric Wolff, and Xu Zhang
Geosci. Model Dev., 12, 3649–3685, https://doi.org/10.5194/gmd-12-3649-2019, https://doi.org/10.5194/gmd-12-3649-2019, 2019
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As part of the Past Global Changes (PAGES) working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation for the Paleoclimate Modelling Intercomparison Project (PMIP4). This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. Key paleo-records for model-data comparison are also included.
Charel Wohl, David Capelle, Anna Jones, William T. Sturges, Philip D. Nightingale, Brent G. T. Else, and Mingxi Yang
Ocean Sci., 15, 925–940, https://doi.org/10.5194/os-15-925-2019, https://doi.org/10.5194/os-15-925-2019, 2019
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In this paper we present a gas equilibrator that can be used to equilibrate gases continuously or in discrete samples from seawater into a carrier gas. The headspace is analysed by a commercially available proton-transfer-reaction mass spectrometer. This allows for the measurement of a broad range of dissolved gases up to a very high solubility in seawater. The main advantage of this equilibrator is its unique design and ease of reproducibility.
Xin Yang, Markus M. Frey, Rachael H. Rhodes, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Anna E. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 19, 8407–8424, https://doi.org/10.5194/acp-19-8407-2019, https://doi.org/10.5194/acp-19-8407-2019, 2019
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This is a comprehensive model–data comparison aiming to evaluate the proposed mechanism of sea salt aerosol (SSA) production from blowing snow on sea ice. Some key parameters such as snow salinity and blowing-snow size distribution were constrained by data collected in the Weddell Sea. The good agreement between modelled SSA and the cruise data strongly indicates that sea ice surface is a large SSA source in polar regions, a process which has not been considered in current climate models.
Étienne Vignon, Olivier Traullé, and Alexis Berne
Atmos. Chem. Phys., 19, 4659–4683, https://doi.org/10.5194/acp-19-4659-2019, https://doi.org/10.5194/acp-19-4659-2019, 2019
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The future sea-level rise will depend on how much the Antarctic ice sheet gain – via precipitation – or loose mass. The simulation of precipitation by numerical models used for projections depends on the representation of the atmospheric circulation over and around Antarctica. Using daily measurements from balloon soundings at nine Antarctic stations, this study characterizes the structure of the atmosphere over the Antarctic coast and its representation in atmospheric simulations.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell Drysdale, Philip Gibbard, Lauren Gregoire, Feng He, Ruza Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis Tzedakis, Eric Wolff, and Xu Zhang
Clim. Past Discuss., https://doi.org/10.5194/cp-2018-106, https://doi.org/10.5194/cp-2018-106, 2018
Preprint withdrawn
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The penultimate deglaciation (~ 138–128 ka), which represents the transition into the Last Interglacial period, provides a framework to investigate the climate and environmental response to large changes in boundary conditions. Here, as part of the PAGES-PMIP working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation as well as a selection of paleo records for upcoming model-data comparisons.
Rosalie H. Shepherd, Martin D. King, Amelia A. Marks, Neil Brough, and Andrew D. Ward
Atmos. Chem. Phys., 18, 5235–5252, https://doi.org/10.5194/acp-18-5235-2018, https://doi.org/10.5194/acp-18-5235-2018, 2018
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The refractive index of atmospheric extracts sourced from urban (London), remote (Antarctica), and woodsmoke aerosol was determined by applying optical trapping simultaneously with Mie spectroscopy. In addition, owing to the absorbing nature of woodsmoke and an aqueous humic acid aerosol extract, the absorption Ångström exponent could be determined.The refractive index and absorption Ångström exponent were then applied in a top-of-the-atmosphere albedo radiation transfer model.
Hoi Ga Chan, Markus M. Frey, and Martin D. King
Atmos. Chem. Phys., 18, 1507–1534, https://doi.org/10.5194/acp-18-1507-2018, https://doi.org/10.5194/acp-18-1507-2018, 2018
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Emissions of reactive nitrogen from snowpacks influence remote air quality. Two physical air–snow models for nitrate were developed. One assumes that below a threshold temperature the air–snow grain interface is pure ice and above it a disordered interface emerges. The other assumes an air–ice interface below melting and that any liquid present is concentrated in micropockets. Only the latter matches observations at two Antarctic lcoations covering a wide range of environmental conditions.
Amelia A. Marks, Maxim L. Lamare, and Martin D. King
The Cryosphere, 11, 2867–2881, https://doi.org/10.5194/tc-11-2867-2017, https://doi.org/10.5194/tc-11-2867-2017, 2017
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Arctic sea ice extent is declining rapidly. Prediction of sea ice trends relies on sea ice models that need to be evaluated with real data. A realistic sea ice environment is created in a laboratory by the Royal Holloway sea ice simulator and is used to show a sea ice model can replicate measured properties of sea ice, e.g. reflectance. Black carbon, a component of soot found in atmospheric pollution, is also experimentally shown to reduce the sea ice reflectance, which could exacerbate melting.
Ian Crawford, Martin W. Gallagher, Keith N. Bower, Thomas W. Choularton, Michael J. Flynn, Simon Ruske, Constantino Listowski, Neil Brough, Thomas Lachlan-Cope, Zoë L. Fleming, Virginia E. Foot, and Warren R. Stanley
Atmos. Chem. Phys., 17, 14291–14307, https://doi.org/10.5194/acp-17-14291-2017, https://doi.org/10.5194/acp-17-14291-2017, 2017
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We present the first real-time detection of bioparticles on the Antarctic continent using a novel UV-LIF technique. The high time resolution of the technique allowed us to examine the relationships between bioparticle concentrations and airmass history and local winds, which would not have been possible with conventional high-volume filter sampling techniques. We also show evidence of episodic long-range transport of pollen from coastal South America to the continent.
Michel Legrand, Susanne Preunkert, Eric Wolff, Rolf Weller, Bruno Jourdain, and Dietmar Wagenbach
Atmos. Chem. Phys., 17, 14039–14054, https://doi.org/10.5194/acp-17-14039-2017, https://doi.org/10.5194/acp-17-14039-2017, 2017
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Multiple year-round records of bulk and size-segregated composition of sea-salt aerosol and acidic gases (HCl and HNO3) were obtained at inland Antarctica. Both acidic sulfur particles and nitric acid are involved in the observed sea-salt dechlorination in spring/summer. The observed sulfate to sodium mass ratio of sea-salt aerosol in winter (0.16 ± 0.05) suggests on average a similar contribution of sea-ice and open-ocean emissions to the sea-salt load over inland Antarctica at that season.
Rachael H. Rhodes, Xin Yang, Eric W. Wolff, Joseph R. McConnell, and Markus M. Frey
Atmos. Chem. Phys., 17, 9417–9433, https://doi.org/10.5194/acp-17-9417-2017, https://doi.org/10.5194/acp-17-9417-2017, 2017
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Sea salt aerosol comes from the open ocean or the sea ice surface. In the polar regions, this opens up the possibility of reconstructing sea ice history using sea salt recorded in ice cores. We use a chemical transport model to demonstrate that the sea ice source of aerosol is important in the Arctic. For the first time, we simulate realistic Greenland ice core sea salt in a process-based model. The importance of the sea ice source increases from south to north across the Greenland ice sheet.
Emma C. Turner, Stafford Withington, David A. Newnham, Peter Wadhams, Anna E. Jones, and Robin Clancy
Atmos. Meas. Tech., 9, 5461–5485, https://doi.org/10.5194/amt-9-5461-2016, https://doi.org/10.5194/amt-9-5461-2016, 2016
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Observations of the submillimetre part of the electromagnetic spectrum have previously been the domain of the astronomical community. However, new technological
advances in the superconducting detectors field are offering the atmospheric sciences unexplored opportunities to perform useful spectroscopy in this region,
exploiting existing radio telescope sites. Example simulations at six sites are presented for HBr, HOBr, HO2 and N2O showing the need for broad
high-resolution measurements.
Michel Legrand, Joseph McConnell, Hubertus Fischer, Eric W. Wolff, Susanne Preunkert, Monica Arienzo, Nathan Chellman, Daiana Leuenberger, Olivia Maselli, Philip Place, Michael Sigl, Simon Schüpbach, and Mike Flannigan
Clim. Past, 12, 2033–2059, https://doi.org/10.5194/cp-12-2033-2016, https://doi.org/10.5194/cp-12-2033-2016, 2016
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Here, we review previous attempts made to reconstruct past forest fire using chemical signals recorded in Greenland ice. We showed that the Greenland ice records of ammonium, found to be a good fire proxy, consistently indicate changing fire activity in Canada in response to past climatic conditions that occurred since the last 15 000 years, including the Little Ice Age and the last large climatic transition.
Emma J. Stone, Emilie Capron, Daniel J. Lunt, Antony J. Payne, Joy S. Singarayer, Paul J. Valdes, and Eric W. Wolff
Clim. Past, 12, 1919–1932, https://doi.org/10.5194/cp-12-1919-2016, https://doi.org/10.5194/cp-12-1919-2016, 2016
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Climate models forced only with greenhouse gas concentrations and orbital parameters representative of the early Last Interglacial are unable to reproduce the observed colder-than-present temperatures in the North Atlantic and the warmer-than-present temperatures in the Southern Hemisphere. Using a climate model forced also with a freshwater amount derived from data representing melting from the remnant Northern Hemisphere ice sheets accounts for this response via the bipolar seesaw mechanism.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
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Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Ikumi Oyabu, Yoshinori Iizuka, Eric Wolff, and Margareta Hansson
Clim. Past Discuss., https://doi.org/10.5194/cp-2016-42, https://doi.org/10.5194/cp-2016-42, 2016
Manuscript not accepted for further review
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This study presented the chemical compositions of non-volatile particles around the last termination in the Dome C ice core by using the sublimation-EDS method. The major soluble salt particles are CaSO4, Na2SO4, and NaCl, and time-series changes in the composition of these salts are similar to those for the Dome Fuji ice core. However, some differences occurred. The sulfatization rate of NaCl at Dome C is higher than that at Dome Fuji.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
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Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
M. L. Lamare, J. Lee-Taylor, and M. D. King
Atmos. Chem. Phys., 16, 843–860, https://doi.org/10.5194/acp-16-843-2016, https://doi.org/10.5194/acp-16-843-2016, 2016
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The decrease in reflectivity (albedo) of sea ice and snow containing mineral dusts and volcanic ashes is calculated. The type of snow and sea ice, the thickness and the layering of mineral aerosol deposits are varied. The results show that the response of the albedo of snow and sea ice to mineral aerosol deposits is more sensitive to the type of snow or sea ice than to the properties of the mineral aerosol deposits themselves.
J. Erbland, J. Savarino, S. Morin, J. L. France, M. M. Frey, and M. D. King
Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, https://doi.org/10.5194/acp-15-12079-2015, 2015
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In this paper, we describe the development of a numerical model which aims at representing nitrate recycling at the air-snow interface on the East Antarctic Plateau. Stable isotopes are used as diagnostic and evaluation tools by comparing the model's results to recent field measurements of nitrate and key atmospheric species at Dome C, Antarctica. From sensitivity tests conducted with the model, we propose a framework for the interpretation of the nitrate isotope record in deep ice cores.
S. Fujita, F. Parrenin, M. Severi, H. Motoyama, and E. W. Wolff
Clim. Past, 11, 1395–1416, https://doi.org/10.5194/cp-11-1395-2015, https://doi.org/10.5194/cp-11-1395-2015, 2015
M. M. Frey, H. K. Roscoe, A. Kukui, J. Savarino, J. L. France, M. D. King, M. Legrand, and S. Preunkert
Atmos. Chem. Phys., 15, 7859–7875, https://doi.org/10.5194/acp-15-7859-2015, https://doi.org/10.5194/acp-15-7859-2015, 2015
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Surprisingly large concentrations and flux of atmospheric nitrogen oxides were measured at Dome C, East Antarctica. It was found that the surface snow holds a significant reservoir of photochemically produced NOx and is a sink of gas-phase ozone. Main drivers of NOx snow emissions were large snow nitrate concentrations, with contributions of increased UV from decreases in stratospheric ozone. Observed halogen and hydroxyl radical concentrations were too low to explain large NO2:NO ratios.
H. G. Chan, M. D. King, and M. M. Frey
Atmos. Chem. Phys., 15, 7913–7927, https://doi.org/10.5194/acp-15-7913-2015, https://doi.org/10.5194/acp-15-7913-2015, 2015
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
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During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
H. Gallée, S. Preunkert, S. Argentini, M. M. Frey, C. Genthon, B. Jourdain, I. Pietroni, G. Casasanta, H. Barral, E. Vignon, C. Amory, and M. Legrand
Atmos. Chem. Phys., 15, 6225–6236, https://doi.org/10.5194/acp-15-6225-2015, https://doi.org/10.5194/acp-15-6225-2015, 2015
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Regional climate model MAR was run for the region of Dome C located on the East Antarctic plateau, during summer 2011–2012, with a high vertical resolution in the lower troposphere. MAR is generally in very good agreement with the observations and provides sufficiently reliable information about surface turbulent fluxes and vertical profiles of vertical diffusion coefficients when discussing the representativeness of chemical measurements made nearby the ground surface at Dome C.
F. Parrenin, S. Fujita, A. Abe-Ouchi, K. Kawamura, V. Masson-Delmotte, H. Motoyama, F. Saito, M. Severi, B. Stenni, R. Uemura, and E. Wolff
Clim. Past Discuss., https://doi.org/10.5194/cpd-11-377-2015, https://doi.org/10.5194/cpd-11-377-2015, 2015
Revised manuscript has not been submitted
A. Kukui, M. Legrand, S. Preunkert, M. M. Frey, R. Loisil, J. Gil Roca, B. Jourdain, M. D. King, J. L. France, and G. Ancellet
Atmos. Chem. Phys., 14, 12373–12392, https://doi.org/10.5194/acp-14-12373-2014, https://doi.org/10.5194/acp-14-12373-2014, 2014
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Concentrations of OH radicals and the sum of peroxy radicals, RO2, were measured in the boundary layer for the first time on the East Antarctic Plateau at the Concordia Station during the austral summer 2011/2012. The concentrations of radicals were comparable to those observed at the South Pole, confirming that the elevated oxidative capacity of the Antarctic atmospheric boundary layer found at the South Pole is not restricted to the South Pole but common over the high Antarctic plateau.
A. E. Jones, N. Brough, P. S. Anderson, and E. W. Wolff
Atmos. Chem. Phys., 14, 11843–11851, https://doi.org/10.5194/acp-14-11843-2014, https://doi.org/10.5194/acp-14-11843-2014, 2014
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We report observations of nitric acid and peroxynitric acid, in coastal Antarctica during winter. During winter, it is dark 24h per day, so there is no influence of sunlight on atmospheric composition. We show that observed variability in concentrations is highly correlated with changes in temperature. We derive enthalpies of adsorption and show they are consistent with those derived in laboratory studies. The Antarctic, during winter, is an ideal natural laboratory to study air-snow exchange.
M. Lothon, F. Lohou, D. Pino, F. Couvreux, E. R. Pardyjak, J. Reuder, J. Vilà-Guerau de Arellano, P Durand, O. Hartogensis, D. Legain, P. Augustin, B. Gioli, D. H. Lenschow, I. Faloona, C. Yagüe, D. C. Alexander, W. M. Angevine, E Bargain, J. Barrié, E. Bazile, Y. Bezombes, E. Blay-Carreras, A. van de Boer, J. L. Boichard, A. Bourdon, A. Butet, B. Campistron, O. de Coster, J. Cuxart, A. Dabas, C. Darbieu, K. Deboudt, H. Delbarre, S. Derrien, P. Flament, M. Fourmentin, A. Garai, F. Gibert, A. Graf, J. Groebner, F. Guichard, M. A. Jiménez, M. Jonassen, A. van den Kroonenberg, V. Magliulo, S. Martin, D. Martinez, L. Mastrorillo, A. F. Moene, F. Molinos, E. Moulin, H. P. Pietersen, B. Piguet, E. Pique, C. Román-Cascón, C. Rufin-Soler, F. Saïd, M. Sastre-Marugán, Y. Seity, G. J. Steeneveld, P. Toscano, O. Traullé, D. Tzanos, S. Wacker, N. Wildmann, and A. Zaldei
Atmos. Chem. Phys., 14, 10931–10960, https://doi.org/10.5194/acp-14-10931-2014, https://doi.org/10.5194/acp-14-10931-2014, 2014
M. Legrand, S. Preunkert, M. Frey, Th. Bartels-Rausch, A. Kukui, M. D. King, J. Savarino, M. Kerbrat, and B. Jourdain
Atmos. Chem. Phys., 14, 9963–9976, https://doi.org/10.5194/acp-14-9963-2014, https://doi.org/10.5194/acp-14-9963-2014, 2014
A. A. Marks and M. D. King
The Cryosphere, 8, 1625–1638, https://doi.org/10.5194/tc-8-1625-2014, https://doi.org/10.5194/tc-8-1625-2014, 2014
A. M. Foley, D. Dalmonech, A. D. Friend, F. Aires, A. T. Archibald, P. Bartlein, L. Bopp, J. Chappellaz, P. Cox, N. R. Edwards, G. Feulner, P. Friedlingstein, S. P. Harrison, P. O. Hopcroft, C. D. Jones, J. Kolassa, J. G. Levine, I. C. Prentice, J. Pyle, N. Vázquez Riveiros, E. W. Wolff, and S. Zaehle
Biogeosciences, 10, 8305–8328, https://doi.org/10.5194/bg-10-8305-2013, https://doi.org/10.5194/bg-10-8305-2013, 2013
Q. Libois, G. Picard, J. L. France, L. Arnaud, M. Dumont, C. M. Carmagnola, and M. D. King
The Cryosphere, 7, 1803–1818, https://doi.org/10.5194/tc-7-1803-2013, https://doi.org/10.5194/tc-7-1803-2013, 2013
H. Fischer, J. Severinghaus, E. Brook, E. Wolff, M. Albert, O. Alemany, R. Arthern, C. Bentley, D. Blankenship, J. Chappellaz, T. Creyts, D. Dahl-Jensen, M. Dinn, M. Frezzotti, S. Fujita, H. Gallee, R. Hindmarsh, D. Hudspeth, G. Jugie, K. Kawamura, V. Lipenkov, H. Miller, R. Mulvaney, F. Parrenin, F. Pattyn, C. Ritz, J. Schwander, D. Steinhage, T. van Ommen, and F. Wilhelms
Clim. Past, 9, 2489–2505, https://doi.org/10.5194/cp-9-2489-2013, https://doi.org/10.5194/cp-9-2489-2013, 2013
S. Masclin, M. M. Frey, W. F. Rogge, and R. C. Bales
Atmos. Chem. Phys., 13, 8857–8877, https://doi.org/10.5194/acp-13-8857-2013, https://doi.org/10.5194/acp-13-8857-2013, 2013
L. Bazin, A. Landais, B. Lemieux-Dudon, H. Toyé Mahamadou Kele, D. Veres, F. Parrenin, P. Martinerie, C. Ritz, E. Capron, V. Lipenkov, M.-F. Loutre, D. Raynaud, B. Vinther, A. Svensson, S. O. Rasmussen, M. Severi, T. Blunier, M. Leuenberger, H. Fischer, V. Masson-Delmotte, J. Chappellaz, and E. Wolff
Clim. Past, 9, 1715–1731, https://doi.org/10.5194/cp-9-1715-2013, https://doi.org/10.5194/cp-9-1715-2013, 2013
D. Veres, L. Bazin, A. Landais, H. Toyé Mahamadou Kele, B. Lemieux-Dudon, F. Parrenin, P. Martinerie, E. Blayo, T. Blunier, E. Capron, J. Chappellaz, S. O. Rasmussen, M. Severi, A. Svensson, B. Vinther, and E. W. Wolff
Clim. Past, 9, 1733–1748, https://doi.org/10.5194/cp-9-1733-2013, https://doi.org/10.5194/cp-9-1733-2013, 2013
A. A. Marks and M. D. King
The Cryosphere, 7, 1193–1204, https://doi.org/10.5194/tc-7-1193-2013, https://doi.org/10.5194/tc-7-1193-2013, 2013
J. Erbland, W. C. Vicars, J. Savarino, S. Morin, M. M. Frey, D. Frosini, E. Vince, and J. M. F. Martins
Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, https://doi.org/10.5194/acp-13-6403-2013, 2013
A. E. Jones, E. W. Wolff, N. Brough, S. J.-B. Bauguitte, R. Weller, M. Yela, M. Navarro-Comas, H. A. Ochoa, and N. Theys
Atmos. Chem. Phys., 13, 1457–1467, https://doi.org/10.5194/acp-13-1457-2013, https://doi.org/10.5194/acp-13-1457-2013, 2013
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Hemispheric differences in ozone across the stratosphere–troposphere exchange region
Observation and modeling of atmospheric OH and HO2∗ radicals at a subtropical rural site and implications for secondary pollutants
Tracing elevated abundance of CH2Cl2 in the subarctic upper troposphere to the Asian Summer Monsoon
Carbonyl compounds from typical combustion sources: emission characteristics, influencing factors, and their contribution to ozone formation
Formation drivers and photochemical effects of ClNO2 in a coastal city of Southeast China
Significant influence of oxygenated volatile organic compounds on atmospheric chemistry: a case study in a typical industrial city in China
Global ground-based tropospheric ozone measurements: reference data and individual site trends (2000–2022) from the TOAR-II/HEGIFTOM project
Understanding summertime H2O2 chemistry in the North China Plain through observations and modeling studies
Volatile organic compound sources and impacts in an urban Mediterranean area (Marseille, France)
Short-lived organic nitrates in a suburban temperate forest: an indication of efficient assimilation of reactive nitrogen by the biosphere?
Spatiotemporal variations in atmospheric CH4 concentrations and enhancements in northern China based on a comprehensive dataset: ground-based observations, TROPOMI data, inventory data, and inversions
Marine emissions and trade winds control the atmospheric nitrous oxide in the Galapagos Islands
Measurement report: A complex street-level air quality observation campaign in a heavy-traffic area utilizing the multivariate adaptive regression splines method for field calibration of low-cost sensors
The impact of organic nitrates on summer ozone formation in Shanghai, China
Differences in the key volatile organic compound species between their emitted and ambient concentrations in ozone formation
Tracing Ammonia Emission Sources in California's Salton Sea Region: Insights from Airborne Longwave-Infrared Hyperspectral Imaging and Ground Monitoring
Mechanistic insights into chloroacetic acid production from atmospheric multiphase volatile organic compound–chlorine chemistry
Accurate elucidation of oxidation under heavy ozone pollution: a full suite of radical measurements in the chemically complex atmosphere
Isotopic signatures of methane emission from oil and natural gas plants in southwestern China
Emissions of intermediate-volatility and semi-volatile organic compounds (I/SVOCs) from different cumulative-mileage diesel vehicles at various ambient temperatures
Characterization of nitrous acid and its potential effects on secondary pollution in the warm season in Beijing urban areas
Vertical changes in volatile organic compounds (VOCs) and impacts on photochemical ozone formation
Airborne quantification of Angolan offshore oil and gas methane emissions
Diurnal, seasonal, and interannual variations in δ(18O) of atmospheric O2 and its application to evaluate natural and anthropogenic changes in oxygen, carbon, and water cycles
Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer
Atmospheric carbonyl compounds are crucial in regional ozone heavy pollution: insights from the Chengdu Plain Urban Agglomeration, China
Evaluating urban methane emissions and their attributes in a megacity, Osaka, Japan, via mobile and eddy covariance measurements
Tropical Ozone Trends (1998 to 2023): A Synthesis from SHADOZ, IAGOS and OMI/MLS Observations
Ozone (O3) observations in Saxony, Germany for 1997–2020: Trends, modelling and implications for O3 control
Understanding summertime peroxyacetyl nitrate (PAN) formation and its relation to aerosol pollution: insights from high-resolution measurements and modeling
Measurement report: Exploring the variations in ambient BTEX in urban Europe and their environmental health implications
Seasonal air concentration variability, gas–particle partitioning, precipitation scavenging, and air–water equilibrium of organophosphate esters in southern Canada
Measurement report: Surface exchange fluxes of HONO during the growth process of paddy fields in the Huaihe River Basin, China
Molecular and seasonal characteristics of organic vapors in urban Beijing: insights from Vocus-PTR measurements
BVOC and speciated monoterpene concentrations and fluxes at a Scandinavian boreal forest
The variations in volatile organic compounds based on the policy change for Omicron in the traffic hub of Zhengzhou
On the dynamics of ozone depletion events at Villum Research Station in the High Arctic
Measurement report: Long-term measurements of surface ozone and trends in semi-natural sub-Saharan African ecosystems
Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant
Reactive chlorine-, sulfur-, and nitrogen-containing volatile organic compounds impact atmospheric chemistry in the megacity of Delhi during both clean and extremely polluted seasons
Analysis of the day-to-day variability of ozone vertical profiles in the lower troposphere during the 2022 Paris ACROSS campaign
Ozone deposition measurements over wheat fields in the North China Plain: variability and related factors of deposition flux and velocity
Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station–airport distance
CO2 and CO temporal variability over Mexico City from ground-based total column and surface measurements
Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization
Measurement report: In-flight and ground-based measurements of nitrogen oxide emissions from latest-generation jet engines and 100 % sustainable aviation fuel
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Measurement report: Urban ammonia and amines in Houston, Texas
Biomass-burning sources control ambient particulate matter, but traffic and industrial sources control volatile organic compound (VOC) emissions and secondary-pollutant formation during extreme pollution events in Delhi
Multi-year observations of variable incomplete combustion in the New York megacity
Rodrigo J. Seguel, Charlie Opazo, Yann Cohen, Owen R. Cooper, Laura Gallardo, Björn-Martin Sinnhuber, Florian Obersteiner, Andreas Zahn, Peter Hoor, Susanne Rohs, and Andreas Marsing
Atmos. Chem. Phys., 25, 8553–8573, https://doi.org/10.5194/acp-25-8553-2025, https://doi.org/10.5194/acp-25-8553-2025, 2025
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We explored ozone differences between the Northern Hemisphere and Southern Hemispheres in the upper troposphere–lower stratosphere. We found lower ozone (with stratospheric origin) in the Southern Hemisphere, especially during years of severe ozone depletion. Sudden stratospheric warming events increased the ozone in each hemisphere, highlighting the relationship between stratospheric processes and ozone in the upper troposphere, where ozone is an important greenhouse gas.
Zhouxing Zou, Tianshu Chen, Qianjie Chen, Weihang Sun, Shichun Han, Zhuoyue Ren, Xinyi Li, Wei Song, Aoqi Ge, Qi Wang, Xiao Tian, Chenglei Pei, Xinming Wang, Yanli Zhang, and Tao Wang
Atmos. Chem. Phys., 25, 8147–8161, https://doi.org/10.5194/acp-25-8147-2025, https://doi.org/10.5194/acp-25-8147-2025, 2025
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We measured ambient OH and HO2* (HO2 and contribution from RO2, organic peroxyl radicals) concentrations at a subtropical rural site and compared our observations with model results. During warm periods, the model overestimated concentrations of OH and HO2, leading to overestimation of ozone and nitric acid production. Our findings highlight the need to better understand how OH and HO2 are formed and removed, which is important for accurate air quality and climate predictions.
Markus Jesswein, Valentin Lauther, Nicolas Emig, Peter Hoor, Timo Keber, Hans-Christoph Lachnitt, Linda Ort, Tanja Schuck, Johannes Strobel, Ronja Van Luijt, C. Michael Volk, Franziska Weyland, and Andreas Engel
Atmos. Chem. Phys., 25, 8107–8126, https://doi.org/10.5194/acp-25-8107-2025, https://doi.org/10.5194/acp-25-8107-2025, 2025
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The study investigates transport within the Asian Summer Monsoon, focusing on how CH2Cl2 reaches the subarctic tropopause region. Using data from the PHILEAS campaign in 2023, events with increased mixing ratios were detected. Their origin, the transport paths to the tropopause region, and the potential entry into the stratosphere were analyzed. The East Asian Summer Monsoon was identified as the main transport pathway, with only a small contribution to the stratosphere in the following days.
Yanjie Lu, Xinxin Feng, Yanli Feng, Minjun Jiang, Yu Peng, Tian Chen, and Yingjun Chen
Atmos. Chem. Phys., 25, 8043–8059, https://doi.org/10.5194/acp-25-8043-2025, https://doi.org/10.5194/acp-25-8043-2025, 2025
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Through lab tests and field measurements from typical sources, we found that carbonyl compounds from biomass burning are an order of magnitude higher than those from vehicles. The formation of carbonyl compounds in solid and liquid fuel is governed by combustion temperature and emission standards, respectively. Fuel type determines the chemical composition. Biomass burning and farm machinery are key drivers of atmospheric oxidation capacity. This study provides actionable solutions to safeguard public health.
Gaojie Chen, Xiaolong Fan, Haichao Wang, Yee Jun Tham, Ziyi Lin, Xiaoting Ji, Lingling Xu, Baoye Hu, and Jinsheng Chen
Atmos. Chem. Phys., 25, 7815–7828, https://doi.org/10.5194/acp-25-7815-2025, https://doi.org/10.5194/acp-25-7815-2025, 2025
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Our study revealed that the nighttime heterogeneous dinitrogen pentoxide (N2O5) uptake process was the major contributor of nitryl chloride (ClNO2) sources, while nitrate photolysis may promote the elevation of daytime ClNO2 concentrations. The rates of alkane oxidation by chlorine (Cl) radical in the early morning exceeded those by OH radical, significantly promoted the formation of ROx and ozone (O3), and further enhanced the atmospheric oxidation capacity levels.
Jingwen Dai, Kun Zhang, Yanli Feng, Xin Yi, Rui Li, Jin Xue, Qing Li, Lishu Shi, Jiaqiang Liao, Yanan Yi, Fangting Wang, Liumei Yang, Hui Chen, Ling Huang, Jiani Tan, Yangjun Wang, and Li Li
Atmos. Chem. Phys., 25, 7467–7484, https://doi.org/10.5194/acp-25-7467-2025, https://doi.org/10.5194/acp-25-7467-2025, 2025
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Oxygenated volatile organic compounds (OVOCs) are important ozone (O3) precursors. However, most O3 formation analysis based on the box model (OBM) does not include any OVOC constraint. To access the interference of OVOCs with O3 simulation, this study presents results from a field campaign and OBM analysis. Our results indicate that no OVOC constraint in the OBM can lead to overestimation of OVOCs, free radicals, and O3.
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 7187–7225, https://doi.org/10.5194/acp-25-7187-2025, https://doi.org/10.5194/acp-25-7187-2025, 2025
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Tropospheric ozone is an important greenhouse gas and is an air pollutant. The time variability of tropospheric ozone is mainly driven by anthropogenic emissions. In this paper, we study the distribution and time variability of ozone from harmonized ground-based observations from five different measurement techniques. Our findings provide clear standard references for atmospheric models and evolving tropospheric ozone satellite data for the 2000–2022 period.
Can Ye, Pengfei Liu, Chaoyang Xue, Chenglong Zhang, Zhuobiao Ma, Chengtang Liu, Junfeng Liu, Keding Lu, Yujing Mu, and Yuanhang Zhang
Atmos. Chem. Phys., 25, 6991–7005, https://doi.org/10.5194/acp-25-6991-2025, https://doi.org/10.5194/acp-25-6991-2025, 2025
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This study investigates H2O2 chemistry in rural North China. The observed H2O2 showed distinct diurnal variations influenced by photochemical reactions. A box model revealed that H2O2 is primarily produced by HO2 recombination and removed mainly via particle uptake. Reductions in NOx, PM2.5, and alkanes raised H2O2 levels, while cutting alkenes, aromatics, CO, and HONO lowered them. A dual strategy focusing on VOC and NOx control is essential to reduce both H2O2 and ozone pollution.
Marvin Dufresne, Thérèse Salameh, Thierry Leonardis, Grégory Gille, Alexandre Armengaud, and Stéphane Sauvage
Atmos. Chem. Phys., 25, 5977–5999, https://doi.org/10.5194/acp-25-5977-2025, https://doi.org/10.5194/acp-25-5977-2025, 2025
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This paper discusses the 18-month-long measurement of non-methane hydrocarbons (NMHCs) in Marseille, where there was no measurement since early 2000, despite the impact of NMHCs on air quality and climate. Traffic-related sources are the largest contributor to NMHC concentrations in Marseille, and shipping strongly contributes to the formation of aerosols. Finally, the Covid-19 lockdown had an impact on NMHC concentrations, reaching a 50 % decrease for traffic-related sources.
Simone T. Andersen, Rolf Sander, Patrick Dewald, Laura Wüst, Tobias Seubert, Gunther N. T. E. Türk, Jan Schuladen, Max R. McGillen, Chaoyang Xue, Abdelwahid Mellouki, Alexandre Kukui, Vincent Michoud, Manuela Cirtog, Mathieu Cazaunau, Astrid Bauville, Hichem Bouzidi, Paola Formenti, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Christopher Cantrell, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 25, 5893–5909, https://doi.org/10.5194/acp-25-5893-2025, https://doi.org/10.5194/acp-25-5893-2025, 2025
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Measurements and modelling of reactive nitrogen gases observed in a suburban temperate forest in Rambouillet, France, circa 50 km southwest of Paris in 2022 indicate that the biosphere rapidly scavenges organic nitrates of mixed biogenic and anthropogenic origin, resulting in short lifetimes for, for example, alkyl nitrates and peroxy nitrates.
Pengfei Han, Ning Zeng, Bo Yao, Wen Zhang, Weijun Quan, Pucai Wang, Ting Wang, Minqiang Zhou, Qixiang Cai, Yuzhong Zhang, Ruosi Liang, Wanqi Sun, and Shengxiang Liu
Atmos. Chem. Phys., 25, 4965–4988, https://doi.org/10.5194/acp-25-4965-2025, https://doi.org/10.5194/acp-25-4965-2025, 2025
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Methane (CH4) is a potent greenhouse gas. Northern China contributes a large proportion of CH4 emissions, yet large observation gaps exist. Here we compiled a comprehensive dataset, which is publicly available, that includes ground-based, satellite-based, inventory, and modeling results to show the CH4 concentrations, enhancements, and spatial–temporal variations. The data can benefit the research community and policy-makers for future observations, atmospheric inversions, and policy-making.
Timur Cinay, Dickon Young, Nazaret Narváez Jimenez, Cristina Vintimilla-Palacios, Ariel Pila Alonso, Paul B. Krummel, William Vizuete, and Andrew R. Babbin
Atmos. Chem. Phys., 25, 4703–4718, https://doi.org/10.5194/acp-25-4703-2025, https://doi.org/10.5194/acp-25-4703-2025, 2025
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We present the initial 15 months of nitrous oxide measurements from the Galapagos Emissions Monitoring Station. The observed variability in atmospheric mole fractions during this period can be linked to several factors: seasonal variations in trade wind speed and direction across the eastern Pacific, differences in the transport history of air masses sampled, and spatiotemporal heterogeneity in regional marine nitrous oxide emissions from the coastal upwelling systems of Peru and Chile.
Petra Bauerová, Josef Keder, Adriana Šindelářová, Ondřej Vlček, William Patiño, Pavel Krč, Jan Geletič, Hynek Řezníček, Martin Bureš, Kryštof Eben, Michal Belda, Jelena Radović, Vladimír Fuka, Radek Jareš, Igor Esau, and Jaroslav Resler
Atmos. Chem. Phys., 25, 4477–4504, https://doi.org/10.5194/acp-25-4477-2025, https://doi.org/10.5194/acp-25-4477-2025, 2025
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The study explored urban air quality in Prague using low-cost sensors and highlighted the multivariate adaptive regression splines (MARS) correction method's effectiveness in enhancing accuracy. Results showed traffic's impact on nitrogen dioxide levels and atmospheric dynamics on particulate matter. The research confirmed MARS-corrected sensors as cost-effective for monitoring, despite challenges like sensor ageing and data quality control.
Chunmeng Li, Xiaorui Chen, Haichao Wang, Tianyu Zhai, Xuefei Ma, Xinping Yang, Shiyi Chen, Min Zhou, Shengrong Lou, Xin Li, Limin Zeng, and Keding Lu
Atmos. Chem. Phys., 25, 3905–3918, https://doi.org/10.5194/acp-25-3905-2025, https://doi.org/10.5194/acp-25-3905-2025, 2025
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This study reports an observation of organic nitrate (including total peroxy nitrates and total alkyl nitrates) in Shanghai, China, during the summer of 2021, by homemade thermal dissociation cavity-enhanced absorption spectroscopy (TD-CEAS; Atmos. Meas. Tech., 14, 4033–4051, 2021). The distribution of organic nitrates and their effects on local ozone production are analyzed based on field observations in conjunction with model simulations.
Xudong Zheng and Shaodong Xie
Atmos. Chem. Phys., 25, 3807–3820, https://doi.org/10.5194/acp-25-3807-2025, https://doi.org/10.5194/acp-25-3807-2025, 2025
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To reduce uncertainties in identifying the key volatile organic compounds (VOCs) in ozone (O3) formation from ambient concentrations, this study comprehensively calculates the emitted VOC concentrations during both nighttime and daytime using the nitrate radical, O3, and hydroxyl radical reaction rates and ambient VOC concentrations. Based on the emitted concentrations, isoprene is one of the top three species contributing to O3 formation, which may be overlooked in observed concentrations.
Sina Hasheminassab, David M. Tratt, Olga V. Kalashnikova, Clement S. Chang, Morad Alvarez, Kerry N. Buckland, Michael J. Garay, Francesca M. Hopkins, Eric R. Keim, Le Kuai, Yaning Miao, Payam Pakbin, William C. Porter, and Mohammad H. Sowlat
EGUsphere, https://doi.org/10.5194/egusphere-2025-1378, https://doi.org/10.5194/egusphere-2025-1378, 2025
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Ammonia (NH3) is a key air pollutant linked to fine particle pollution, yet its sources remain poorly understood. Using airborne infrared imaging and ground sensors, we mapped NH3 emissions in California’s Salton Sea region with unprecedented detail. We found high emissions from farms, geothermal plants, and waste sites, including sources missing from inventories. These findings highlight the need for better NH3 monitoring to improve air quality models and guide pollution reduction strategies.
Mingxue Li, Men Xia, Chunshui Lin, Yifan Jiang, Weihang Sun, Yurun Wang, Yingnan Zhang, Maoxia He, and Tao Wang
Atmos. Chem. Phys., 25, 3753–3764, https://doi.org/10.5194/acp-25-3753-2025, https://doi.org/10.5194/acp-25-3753-2025, 2025
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Our field campaigns observed a strong diel pattern of chloroacetic acid as well as a strong correlation between its level and that of reactive chlorine species at a coastal site. Using quantum chemical calculations and box model simulation with an updated Master Chemical Mechanism, we found that the formation pathway of chloroacetic acid involved multiphase processes. Our study enhances understanding of atmospheric organic chlorine chemistry and emphasizes the importance of multiphase reactions.
Renzhi Hu, Guoxian Zhang, Haotian Cai, Jingyi Guo, Keding Lu, Xin Li, Shengrong Lou, Zhaofeng Tan, Changjin Hu, Pinhua Xie, and Wenqing Liu
Atmos. Chem. Phys., 25, 3011–3028, https://doi.org/10.5194/acp-25-3011-2025, https://doi.org/10.5194/acp-25-3011-2025, 2025
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A full suite of radical measurements (OH, HO2, RO2, and kOH) was established to accurately elucidate the limitations of oxidation in a chemically complex atmosphere. Sensitivity tests revealed that the incorporation of complex processes enabled a balance in both radical concentrations and coordinate ratios, effectively addressing the deficiency in the ozone generation mechanism. The full-chain radical detection bridged the gap between the photochemistry and the intensive oxidation level.
Dingxi Chen, Yi Liu, Zetong Niu, Ao Wang, Pius Otwil, Yuanyuan Huang, Zhongcong Sun, Xiaobing Pang, Liyang Zhan, and Longfei Yu
EGUsphere, https://doi.org/10.5194/egusphere-2025-377, https://doi.org/10.5194/egusphere-2025-377, 2025
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We carried out studies at 11 oil and gas sites in Southwest China (an important natural gas production area), investigating the methane concentration distribution pattern and emission inventory of oil and gas industrial sites through a combination of ground monitoring and drone airborne monitoring techniques, and at the same time, utilizing stable isotope techniques to trace back the methane from the oil and gas sites.
Shuwen Guo, Xuan Zheng, Xiao He, Lewei Zeng, Liqiang He, Xian Wu, Yifei Dai, Zihao Huang, Ting Chen, Shupei Xiao, Yan You, Sheng Xiang, Shaojun Zhang, Jingkun Jiang, and Ye Wu
Atmos. Chem. Phys., 25, 2695–2705, https://doi.org/10.5194/acp-25-2695-2025, https://doi.org/10.5194/acp-25-2695-2025, 2025
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We considered two potential influencing factors of heavy-duty diesel vehicle emissions that are rarely mentioned in the literature: cumulative mileage and ambient temperatures. The results suggest that prolonged use of heavy-duty diesel vehicles and low ambient temperatures leads to reduced engine combustion efficiency, which in turn increases tailpipe emissions significantly.
Junling Li, Chaofan Lian, Mingyuan Liu, Hao Zhang, Yongxin Yan, Yufei Song, Chun Chen, Jiaqi Wang, Haijie Zhang, Yanqin Ren, Yucong Guo, Weigang Wang, Yisheng Xu, Hong Li, Jian Gao, and Maofa Ge
Atmos. Chem. Phys., 25, 2551–2568, https://doi.org/10.5194/acp-25-2551-2025, https://doi.org/10.5194/acp-25-2551-2025, 2025
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As a key source of hydroxyl (OH) radical, nitrous acid (HONO) has attracted much attention for its important role in the atmospheric oxidant capacity (AOC) increase. In this study, we made a comparison of the ambient levels, variation patterns, sources, and formation pathway in the warm season on the basis of continuous intensive observations at an urban site of Beijing. This work highlights the importance of HONO for the AOC in the warm season.
Xiao-Bing Li, Bin Yuan, Yibo Huangfu, Suxia Yang, Xin Song, Jipeng Qi, Xianjun He, Sihang Wang, Yubin Chen, Qing Yang, Yongxin Song, Yuwen Peng, Guiqian Tang, Jian Gao, Dasa Gu, and Min Shao
Atmos. Chem. Phys., 25, 2459–2472, https://doi.org/10.5194/acp-25-2459-2025, https://doi.org/10.5194/acp-25-2459-2025, 2025
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Online vertical gradient measurements of volatile organic compounds (VOCs), ozone, and NOx were conducted based on a 325 m tall tower in urban Beijing. Vertical changes in the concentrations, compositions, key drivers, and environmental impacts of VOCs were analyzed in this study. We find that VOC species display differentiated vertical variation patterns and distinct roles in contributing to photochemical ozone formation with increasing height in the urban planetary boundary layer.
Alina Fiehn, Maximilian Eckl, Magdalena Pühl, Tiziana Bräuer, Klaus-Dirk Gottschaldt, Heinfried Aufmhoff, Lisa Eirenschmalz, Gregor Neumann, Felicitas Sakellariou, Daniel Sauer, Robert Baumann, Guilherme De Aguiar Ventura, Winne Nayole Cadete, Dário Luciano Zua, Manuel Xavier, Paulo Correia, and Anke Roiger
EGUsphere, https://doi.org/10.5194/egusphere-2025-635, https://doi.org/10.5194/egusphere-2025-635, 2025
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In September 2022, the METHANE-To-Go Africa (MTGA) campaign, part of UNEP’s IMEO Methane Science Studies, conducted the first CH₄ emissions measurements from West Africa’s offshore oil and gas sector. Using an aircraft-based mass balance method, emissions from Angolan offshore facilities were quantified. Older, low-producing facilities showed higher emissions than newer ones. High-emission events were observed, highlighting the need for targeted monitoring and mitigation efforts.
Shigeyuki Ishidoya, Satoshi Sugawara, and Atsushi Okazaki
Atmos. Chem. Phys., 25, 1965–1987, https://doi.org/10.5194/acp-25-1965-2025, https://doi.org/10.5194/acp-25-1965-2025, 2025
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The 18O/16O ratio of atmospheric oxygen, δatm(18O), is higher than that of ocean water due to isotopic effects during biospheric activities. This is known as the Dole–Morita effect, and its millennial-scale variations are recorded in ice cores. However, small variations of δatm(18O) in the present day have never been detected so far. This paper presents the first observations of diurnal, seasonal, and secular variations in δatm(18O) and applies them to evaluate oxygen, carbon, and water cycles.
Delaney B. Kilgour, Christopher M. Jernigan, Olga Garmash, Sneha Aggarwal, Shengqian Zhou, Claudia Mohr, Matt E. Salter, Joel A. Thornton, Jian Wang, Paul Zieger, and Timothy H. Bertram
Atmos. Chem. Phys., 25, 1931–1947, https://doi.org/10.5194/acp-25-1931-2025, https://doi.org/10.5194/acp-25-1931-2025, 2025
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We report simultaneous measurements of dimethyl sulfide (DMS) and hydroperoxymethyl thioformate (HPMTF) in the eastern North Atlantic. We use an observationally constrained box model to show that cloud loss is the dominant sink of HPMTF in this region over 6 weeks, resulting in large reductions in DMS-derived products that contribute to aerosol formation and growth. Our findings indicate that fast cloud processing of HPMTF must be included in global models to accurately capture the sulfur cycle.
Jiemeng Bao, Xin Zhang, Zhenhai Wu, Li Zhou, Jun Qian, Qinwen Tan, Fumo Yang, Junhui Chen, Yunfeng Li, Hefan Liu, Liqun Deng, and Hong Li
Atmos. Chem. Phys., 25, 1899–1916, https://doi.org/10.5194/acp-25-1899-2025, https://doi.org/10.5194/acp-25-1899-2025, 2025
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We studied carbonyl compounds' role in ozone pollution in the Chengdu Plain Urban Agglomeration, China. During heavy pollution in August 2019, we measured carbonyls at nine sites and analyzed their impact. Areas with higher carbonyl levels, like Chengdu, had worse ozone pollution. While their abundance matters, chemical reactions with other pollutants are the main drivers. Our findings show regional cooperation is vital to reducing ozone pollution effectively.
Masahito Ueyama, Taku Umezawa, Yukio Terao, Mark Lunt, and James Lawrence France
EGUsphere, https://doi.org/10.5194/egusphere-2024-3926, https://doi.org/10.5194/egusphere-2024-3926, 2025
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Methane (CH4) emissions were measured in Megacity Osaka, Japan, using mobile and eddy covariance methods. The CH4 emissions were much higher than those reported in local inventories, with natural gas contributing up to 74 % of the emissions. Several CH4 sources not accounted for in current inventories were identified. These results emphasize the need for more comprehensive emissions tracking in urban areas to enhance climate change mitigation efforts.
Anne M. Thompson, Ryan M. Stauffer, Debra E. Kollonige, Jerald R. Ziemke, Maria Cazorla, Pawel Wolff, and Bastien Sauvage
EGUsphere, https://doi.org/10.5194/egusphere-2024-3761, https://doi.org/10.5194/egusphere-2024-3761, 2025
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This paper uses tropical ozone profiles from balloon borne instruments and aircraft to show that ozone in the free troposphere is not growing fast except over equatorial SE Asia.
Yaru Wang, Dominik van Pinxteren, Andreas Tilgner, Erik Hans Hoffmann, Max Hell, Susanne Bastian, and Hartmut Herrmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-4202, https://doi.org/10.5194/egusphere-2024-4202, 2025
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Tropospheric ground-level ozone (O3) is a global air-quality pollutant and greenhouse gas. Long-term O3 trends from 16 stations in Saxony, Germany, were compared over three periods, revealing worsened O3 pollution over the last decade. O3 formation has been volatile organic compound (VOC)-limited at traffic and urban sites for the past 20 years. To mitigate O3 pollution, moderate nitrogen oxides and additional VOC controls, particularly in solvent use, should be prioritized in the coming years.
Baoye Hu, Naihua Chen, Rui Li, Mingqiang Huang, Jinsheng Chen, Youwei Hong, Lingling Xu, Xiaolong Fan, Mengren Li, Lei Tong, Qiuping Zheng, and Yuxiang Yang
Atmos. Chem. Phys., 25, 905–921, https://doi.org/10.5194/acp-25-905-2025, https://doi.org/10.5194/acp-25-905-2025, 2025
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Box modeling with the Master Chemical Mechanism (MCM) was used to explore summertime peroxyacetyl nitrate (PAN) formation and its link to aerosol pollution under high-ozone conditions. The MCM model is effective in the study of PAN photochemical formation and performed better during the clean period than the haze period. Machine learning analysis identified ammonia, nitrate, and fine particulate matter as the top three factors contributing to simulation bias.
Xiansheng Liu, Xun Zhang, Marvin Dufresne, Tao Wang, Lijie Wu, Rosa Lara, Roger Seco, Marta Monge, Ana Maria Yáñez-Serrano, Marie Gohy, Paul Petit, Audrey Chevalier, Marie-Pierre Vagnot, Yann Fortier, Alexia Baudic, Véronique Ghersi, Grégory Gille, Ludovic Lanzi, Valérie Gros, Leïla Simon, Heidi Héllen, Stefan Reimann, Zoé Le Bras, Michelle Jessy Müller, David Beddows, Siqi Hou, Zongbo Shi, Roy M. Harrison, William Bloss, James Dernie, Stéphane Sauvage, Philip K. Hopke, Xiaoli Duan, Taicheng An, Alastair C. Lewis, James R. Hopkins, Eleni Liakakou, Nikolaos Mihalopoulos, Xiaohu Zhang, Andrés Alastuey, Xavier Querol, and Thérèse Salameh
Atmos. Chem. Phys., 25, 625–638, https://doi.org/10.5194/acp-25-625-2025, https://doi.org/10.5194/acp-25-625-2025, 2025
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This study examines BTEX (benzene, toluene, ethylbenzene, xylenes) pollution in urban areas across seven European countries. Analyzing data from 22 monitoring sites, we found traffic and industrial activities significantly impact BTEX levels, with peaks during rush hours. The risk from BTEX exposure remains moderate, especially in high-traffic and industrial zones, highlighting the need for targeted air quality management to protect public health and improve urban air quality.
Yuening Li, Faqiang Zhan, Chubashini Shunthirasingham, Ying Duan Lei, Jenny Oh, Amina Ben Chaaben, Zhe Lu, Kelsey Lee, Frank A. P. C. Gobas, Hayley Hung, and Frank Wania
Atmos. Chem. Phys., 25, 459–472, https://doi.org/10.5194/acp-25-459-2025, https://doi.org/10.5194/acp-25-459-2025, 2025
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Organophosphate esters are important humanmade trace contaminants. Measuring them in the atmospheric gas phase, particles, precipitation, and surface water in Canada, we explore seasonal concentration variability, gas–particle partitioning, precipitation scavenging, and the air–water equilibrium. Whereas higher summer concentrations and efficient precipitation scavenging conform with expectations, the lack of a relationship between compound volatility and gas–particle partitioning is puzzling.
Fanhao Meng, Baobin Han, Min Qin, Wu Fang, Ke Tang, Dou Shao, Zhitang Liao, Jun Duan, Yan Feng, Yong Huang, Ting Ni, and Pinhua Xie
Atmos. Chem. Phys., 24, 14191–14208, https://doi.org/10.5194/acp-24-14191-2024, https://doi.org/10.5194/acp-24-14191-2024, 2024
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Comprehensive observations of HONO and NOx fluxes were conducted over paddy fields in the Huaihe River Basin. Consecutive peaks in HONO and NO fluxes suggest a potentially enhanced release of HONO and NO due to soil tillage, whereas waterlogged soil may inhibit microbial nitrification processes following irrigation. Notably, biological processes and light-driven NO2 reactions at the surface may serve as sources of HONO and influence the local HONO budget during rotary tillage.
Zhaojin An, Rujing Yin, Xinyan Zhao, Xiaoxiao Li, Yuyang Li, Yi Yuan, Junchen Guo, Yiqi Zhao, Xue Li, Dandan Li, Yaowei Li, Dongbin Wang, Chao Yan, Kebin He, Douglas R. Worsnop, Frank N. Keutsch, and Jingkun Jiang
Atmos. Chem. Phys., 24, 13793–13810, https://doi.org/10.5194/acp-24-13793-2024, https://doi.org/10.5194/acp-24-13793-2024, 2024
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Online Vocus-PTR measurements show the compositions and seasonal variations in organic vapors in urban Beijing. With enhanced sensitivity and mass resolution, various species at a level of sub-parts per trillion (ppt) and organics with multiple oxygens (≥ 3) were observed. The fast photooxidation process in summer leads to an increase in both concentration and proportion of organics with multiple oxygens, while, in other seasons, the variations in them could be influenced by mixed sources.
Ross Charles Petersen, Thomas Holst, Cheng Wu, Radovan Krejci, Jeremy Chan, Claudia Mohr, and Janne Rinne
EGUsphere, https://doi.org/10.5194/egusphere-2024-3410, https://doi.org/10.5194/egusphere-2024-3410, 2024
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Ecosystem-scale emissions of biogenic volatile organic compounds (BVOCs) are important for atmospheric chemistry. Here we investigate boreal BVOC fluxes from a forest in central Sweden. BVOC fluxes were measured above-canopy using proton-transfer-reaction mass spectrometry, while compound-specific monoterpene (MT) fluxes were assessed using a concentration gradient method. We also evaluate the impact of chemical degradation on observed sesquiterpene (SQT) and nighttime MT fluxes.
Bowen Zhang, Dong Zhang, Zhe Dong, Xinshuai Song, Ruiqin Zhang, and Xiao Li
Atmos. Chem. Phys., 24, 13587–13601, https://doi.org/10.5194/acp-24-13587-2024, https://doi.org/10.5194/acp-24-13587-2024, 2024
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To gain insight into the impact of changes due to epidemic control policies, we undertook continuous online monitoring of volatile organic compounds (VOCs) at an urban site in Zhengzhou over a 2-month period. This study examines the characteristics of VOCs, their sources, and their temporal evolution. It also assesses the impact of the policy change on VOC pollution during the monitoring period, thus providing a basis for further research on VOC pollution and source control.
Jakob Boyd Pernov, Jens Liengaard Hjorth, Lise Lotte Sørensen, and Henrik Skov
Atmos. Chem. Phys., 24, 13603–13631, https://doi.org/10.5194/acp-24-13603-2024, https://doi.org/10.5194/acp-24-13603-2024, 2024
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Arctic ozone depletion events (ODEs) occur every spring and have vast implications for the oxidizing capacity, radiative balance, and mercury oxidation. In this study, we analyze ozone, ODEs, and their connection to meteorological and air mass history variables through statistical analyses, back trajectories, and machine learning (ML) at Villum Research Station. ODEs are favorable under sunny, calm conditions with air masses arriving from northerly wind directions with sea ice contact.
Hagninou Elagnon Venance Donnou, Aristide Barthélémy Akpo, Money Ossohou, Claire Delon, Véronique Yoboué, Dungall Laouali, Marie Ouafo-Leumbe, Pieter Gideon Van Zyl, Ousmane Ndiaye, Eric Gardrat, Maria Dias-Alves, and Corinne Galy-Lacaux
Atmos. Chem. Phys., 24, 13151–13182, https://doi.org/10.5194/acp-24-13151-2024, https://doi.org/10.5194/acp-24-13151-2024, 2024
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Ozone is a secondary air pollutant that is detrimental to human and plant health. A better understanding of its chemical evolution is a challenge for Africa, where it is still undersampled. Out of 14 sites examined (1995–2020), high levels of O3 are reported in southern Africa. The dominant chemical processes leading to O3 formation are identified. A decrease in O3 is observed at Katibougou (Mali) and Banizoumbou (Niger), and an increase is found at Zoétélé (Cameroon) and Skukuza (South Africa).
Junwei Song, Georgios I. Gkatzelis, Ralf Tillmann, Nicolas Brüggemann, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 24, 13199–13217, https://doi.org/10.5194/acp-24-13199-2024, https://doi.org/10.5194/acp-24-13199-2024, 2024
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Biogenic volatile organic compounds (BVOCs) and organic aerosol (OA) particles were measured online in a stressed spruce-dominated forest. OA was mainly attributed to the monoterpene oxidation products. The mixing ratios of BVOCs were higher than the values previously measured in other temperate forests. The results demonstrate that BVOCs are influenced not only by meteorology and biogenic emissions but also by local anthropogenic emissions and subsequent chemical transformation processes.
Sachin Mishra, Vinayak Sinha, Haseeb Hakkim, Arpit Awasthi, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Baerbel Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 13129–13150, https://doi.org/10.5194/acp-24-13129-2024, https://doi.org/10.5194/acp-24-13129-2024, 2024
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We quantified 111 gases using mass spectrometry to understand how seasonal and emission changes lead from clean air in the monsoon season to extremely polluted air in the post-monsoon season in Delhi. Averaged total mass concentrations (260 µg m-3) were > 4 times in polluted periods, driven by biomass burning emissions and reduced atmospheric ventilation. Reactive gaseous nitrogen, chlorine, and sulfur compounds hitherto unreported from such a polluted environment were discovered.
Gérard Ancellet, Camille Viatte, Anne Boynard, François Ravetta, Jacques Pelon, Cristelle Cailteau-Fischbach, Pascal Genau, Julie Capo, Axel Roy, and Philippe Nédélec
Atmos. Chem. Phys., 24, 12963–12983, https://doi.org/10.5194/acp-24-12963-2024, https://doi.org/10.5194/acp-24-12963-2024, 2024
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Characterization of ozone pollution in urban areas benefited from a measurement campaign in summer 2022 in the Paris region. The analysis is based on 21 d of lidar and aircraft observations. The main objective is an analysis of the sensitivity of ozone pollution to the micrometeorological processes in the urban atmospheric boundary layer and the transport of regional pollution. The paper also discusses to what extent satellite observations can track observed ozone plumes.
Xiaoyi Zhang, Wanyun Xu, Weili Lin, Gen Zhang, Jinjian Geng, Li Zhou, Huarong Zhao, Sanxue Ren, Guangsheng Zhou, Jianmin Chen, and Xiaobin Xu
Atmos. Chem. Phys., 24, 12323–12340, https://doi.org/10.5194/acp-24-12323-2024, https://doi.org/10.5194/acp-24-12323-2024, 2024
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Ozone (O3) deposition is a key process that removes surface O3, affecting air quality, ecosystems and climate change. We conducted O3 deposition measurement over a wheat canopy using a newly relaxed eddy accumulation flux system. Large variabilities in O3 deposition were detected, mainly determined by crop growth and modulated by various environmental factors. More O3 deposition observations over different surfaces are needed for exploring deposition mechanisms and model optimization.
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024, https://doi.org/10.5194/acp-24-11927-2024, 2024
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In this study, we identify 23 suitable pairs of sites from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) and In-service Aircraft for a Global Observing System (IAGOS) datasets (1995 to 2021), compare the average vertical distributions of tropospheric O3 from ozonesonde and aircraft measurements, and analyze the differences based on ozonesonde type and station–airport distance.
Noémie Taquet, Wolfgang Stremme, María Eugenia González del Castillo, Victor Almanza, Alejandro Bezanilla, Olivier Laurent, Carlos Alberti, Frank Hase, Michel Ramonet, Thomas Lauvaux, Ke Che, and Michel Grutter
Atmos. Chem. Phys., 24, 11823–11848, https://doi.org/10.5194/acp-24-11823-2024, https://doi.org/10.5194/acp-24-11823-2024, 2024
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We characterize the variability in CO and CO2 emissions over Mexico City from long-term time-resolved Fourier transform infrared spectroscopy solar absorption and surface measurements from 2013 to 2021. Using the average intraday CO growth rate from total columns, the average CO / CO2 ratio and TROPOMI data, we estimate the interannual variability in the CO and CO2 anthropogenic emissions of Mexico City, highlighting the effect of an unprecedented drop in activity due to the COVID-19 lockdown.
Akima Ringsdorf, Achim Edtbauer, Bruna Holanda, Christopher Poehlker, Marta O. Sá, Alessandro Araújo, Jürgen Kesselmeier, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 24, 11883–11910, https://doi.org/10.5194/acp-24-11883-2024, https://doi.org/10.5194/acp-24-11883-2024, 2024
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We show the average height distribution of separately observed aldehydes and ketones over a day and discuss their rainforest-specific sources and sinks as well as their seasonal changes above the Amazon. Ketones have much longer atmospheric lifetimes than aldehydes and thus different implications for atmospheric chemistry. However, they are commonly observed together, which we overcome by measuring with a NO+ chemical ionization mass spectrometer for the first time in the Amazon rainforest.
Theresa Harlass, Rebecca Dischl, Stefan Kaufmann, Raphael Märkl, Daniel Sauer, Monika Scheibe, Paul Stock, Tiziana Bräuer, Andreas Dörnbrack, Anke Roiger, Hans Schlager, Ulrich Schumann, Magdalena Pühl, Tobias Schripp, Tobias Grein, Linda Bondorf, Charles Renard, Maxime Gauthier, Mark Johnson, Darren Luff, Paul Madden, Peter Swann, Denise Ahrens, Reetu Sallinen, and Christiane Voigt
Atmos. Chem. Phys., 24, 11807–11822, https://doi.org/10.5194/acp-24-11807-2024, https://doi.org/10.5194/acp-24-11807-2024, 2024
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Emissions from aircraft have a direct impact on our climate. Here, we present airborne and ground-based measurement data of nitrogen oxides that were collected in the exhaust of an Airbus aircraft. We study the impact of burning fossil and sustainable aviation fuel on nitrogen oxide emissions at different engine settings related to combustor temperature, pressure and fuel flow. Further, we compare observations with engine emission models.
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024, https://doi.org/10.5194/acp-24-11603-2024, 2024
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Using measurements of various trace gases in a suburban forest near Paris in the summer of 2022, we were able to gain insight into the sources and sinks of NOx (NO+NO2) with a special focus on their nighttime chemical and physical loss processes. NO was observed as a result of nighttime soil emissions when O3 levels were strongly depleted by deposition. NO oxidation products were not observed at night, indicating that soil and/or foliar surfaces are an efficient sink of reactive N.
Lee Tiszenkel, James H. Flynn, and Shan-Hu Lee
Atmos. Chem. Phys., 24, 11351–11363, https://doi.org/10.5194/acp-24-11351-2024, https://doi.org/10.5194/acp-24-11351-2024, 2024
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Ammonia and amines are important ingredients for aerosol formation in urban environments, but the measurements of these compounds are extremely challenging. Our observations show that urban ammonia and amines in Houston are emitted from urban sources, and diurnal variations in their concentrations are likely governed by gas-to-particle conversion and emissions.
Arpit Awasthi, Baerbel Sinha, Haseeb Hakkim, Sachin Mishra, Varkrishna Mummidivarapu, Gurmanjot Singh, Sachin D. Ghude, Vijay Kumar Soni, Narendra Nigam, Vinayak Sinha, and Madhavan N. Rajeevan
Atmos. Chem. Phys., 24, 10279–10304, https://doi.org/10.5194/acp-24-10279-2024, https://doi.org/10.5194/acp-24-10279-2024, 2024
Short summary
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We use 111 volatile organic compounds (VOCs), PM10, and PM2.5 in a positive matrix factorization (PMF) model to resolve 11 pollution sources validated with chemical fingerprints. Crop residue burning and heating account for ~ 50 % of the PM, while traffic and industrial emissions dominate the gas-phase VOC burden and formation potential of secondary organic aerosols (> 60 %). Non-tailpipe emissions from compressed-natural-gas-fuelled commercial vehicles dominate the transport sector's PM burden.
Luke D. Schiferl, Cong Cao, Bronte Dalton, Andrew Hallward-Driemeier, Ricardo Toledo-Crow, and Róisín Commane
Atmos. Chem. Phys., 24, 10129–10142, https://doi.org/10.5194/acp-24-10129-2024, https://doi.org/10.5194/acp-24-10129-2024, 2024
Short summary
Short summary
Carbon monoxide (CO) is an air pollutant and an important indicator of the incomplete combustion of fossil fuels in cities. Using 4 years of winter and spring observations in New York City, we found that both the magnitude and variability of CO from the metropolitan area are greater than expected. Transportation emissions cannot explain the missing and variable CO, which points to energy from buildings as a likely underappreciated source of urban air pollution and greenhouse gas emissions.
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