Articles | Volume 26, issue 20
https://doi.org/10.5194/acp-26-15257-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-26-15257-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Impacts of the heterogeneous ammonia uptake on air quality in the North China Plain
Yuxuan Lu
State Key Laboratory of Loess Science, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
University of Chinese Academy of Sciences, Beijing 100049, China
Ruonan Wang
State Key Laboratory of Loess Science, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
Ningning Zhang
CORRESPONDING AUTHOR
State Key Laboratory of Loess Science, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
Qiyuan Wang
State Key Laboratory of Loess Science, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
Yuepeng Pan
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
Qian Jiang
State Key Laboratory of Loess Science, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
Xuexi Tie
State Key Laboratory of Loess Science, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, China
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Looking at characteristics and δ13C compositions of dicarboxylic acids and related compounds in BB aerosols, we used a combined combustion and aging system to generate fresh and aged aerosols from burning straw. The results showed the emission factors (EFaged) of total diacids of aging experiments were around an order of magnitude higher than EFfresh. This meant that dicarboxylic acids are involved with secondary photochemical processes in the atmosphere rather than primary emissions from BB.
Cited articles
Behera, S., Sharma, M., Aneja, V., and Balasubramanian, R.: Ammonia in the atmosphere: A review on emission sources, atmospheric chemistry and deposition on terrestrial bodies, Environ. Sci. Pollut. Res. Int., 20, 8092–8131, https://doi.org/10.1007/s11356-013-2051-9, 2013.
Bei, N., Wu, J., Elser, M., Feng, T., Cao, J., El-Haddad, I., Li, X., Huang, R., Li, Z., Long, X., Xing, L., Zhao, S., Tie, X., Prévôt, A. S. H., and Li, G.: Impacts of meteorological uncertainties on the haze formation in Beijing–Tianjin–Hebei (BTH) during wintertime: a case study, Atmos. Chem. Phys., 17, 14579–14591, https://doi.org/10.5194/acp-17-14579-2017, 2017.
Cheng, Y., Li, S.-M., and Leithead, A.: Chemical Characteristics and Origins of Nitrogen-Containing Organic Compounds in PM2.5 Aerosols in the Lower Fraser Valley, Environ. Sci. Technol., 40, 5846–5852, https://doi.org/10.1021/es0603857, 2006.
Cheng, Y., Zheng, G., Wei, C., Mu, Q., Zheng, B., Wang, Z., Gao, M., Zhang, Q., He, K., Carmichael, G., Pöschl, U., and Su, H.: Reactive nitrogen chemistry in aerosol water as a source of sulfate during haze events in China, Sci. Adv., 2, e1601530, https://doi.org/10.1126/sciadv.1601530, 2016.
Clarisse, L., Clerbaux, C., Dentener, F., Hurtmans, D., and Coheur, P.-F.: Global ammonia distribution derived from infrared satellite observations, Nat. Geosci., 2, 479–483, https://doi.org/10.1038/ngeo551, 2009.
Crowley, J. N., Ammann, M., Cox, R. A., Hynes, R. G., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V – heterogeneous reactions on solid substrates, Atmos. Chem. Phys., 10, 9059–9223, https://doi.org/10.5194/acp-10-9059-2010, 2010.
Feng, T., Bei, N., Zhao, S., Wu, J., Liu, S., Li, X., Liu, L., Wang, R., Zhang, X., Tie, X., and Li, G.: Nitrate debuts as a dominant contributor to particulate pollution in Beijing: Roles of enhanced atmospheric oxidizing capacity and decreased sulfur dioxide emission, Atmos. Environ., 244, 117995, https://doi.org/10.1016/j.atmosenv.2020.117995, 2021.
Fu, H., Luo, Z., and Hu, S.: A temporal-spatial analysis and future trends of ammonia emissions in China, Sci. Total Environ., 731, 138897, https://doi.org/10.1016/j.scitotenv.2020.138897, 2020.
Fu, X., Wang, S., Xing, J., Zhang, X., Wang, T., and Hao, J.: Increasing Ammonia Concentrations Reduce the Effectiveness of Particle Pollution Control Achieved via SO2 and NOx Emissions Reduction in East China, Environ. Sci. Tech. Let., 4, 221–227, https://doi.org/10.1021/acs.estlett.7b00143, 2017.
Harrison, M. A. J., Barra, S., Borghesi, D., Vione, D., Arsene, C., and Iulian Olariu, R.: Nitrated phenols in the atmosphere: a review, Atmos. Environ., 39, 231–248, https://doi.org/10.1016/j.atmosenv.2004.09.044, 2005.
Ianniello, A., Spataro, F., Esposito, G., Allegrini, I., Rantica, E., Ancora, M. P., Hu, M., and Zhu, T.: Occurrence of gas phase ammonia in the area of Beijing (China), Atmos. Chem. Phys., 10, 9487–9503, https://doi.org/10.5194/acp-10-9487-2010, 2010.
Lachatre, M., Fortems-Cheiney, A., Foret, G., Siour, G., Dufour, G., Clarisse, L., Clerbaux, C., Coheur, P.-F., Van Damme, M., and Beekmann, M.: The unintended consequence of SO2 and NO2 regulations over China: increase of ammonia levels and impact on PM2.5 concentrations, Atmos. Chem. Phys., 19, 6701–6716, https://doi.org/10.5194/acp-19-6701-2019, 2019.
Laskin, A., Smith, J. S., and Laskin, J.: Molecular characterization of nitrogen-containing organic compounds in biomass burning aerosols using high-resolution mass spectrometry, Environ. Sci. Technol., 43, 3764–3771, https://doi.org/10.1021/es803456n, 2009.
Laskin, A., Laskin, J., and Nizkorodov, S. A.: Chemistry of Atmospheric Brown Carbon, Chem. Rev., 115, 4335–4382, https://doi.org/10.1021/cr5006167, 2015.
Laskin, J., Laskin, A., Nizkorodov, S. A., Roach, P., Eckert, P., Gilles, M. K., Wang, B., Lee, H. J., and Hu, Q.: Molecular Selectivity of Brown Carbon Chromophores, Environ. Sci. Technol., 48, 12047–12055, https://doi.org/10.1021/es503432r, 2014.
Li, G., Lei, W., Zavala, M., Volkamer, R., Dusanter, S., Stevens, P., and Molina, L. T.: Impacts of HONO sources on the photochemistry in Mexico City during the MCMA-2006/MILAGO Campaign, Atmos. Chem. Phys., 10, 6551–6567, https://doi.org/10.5194/acp-10-6551-2010, 2010.
Li, G., Bei, N., Tie, X., and Molina, L. T.: Aerosol effects on the photochemistry in Mexico City during MCMA-2006/MILAGRO campaign, Atmos. Chem. Phys., 11, 5169–5182, https://doi.org/10.5194/acp-11-5169-2011, 2011a.
Li, G., Zavala, M., Lei, W., Tsimpidi, A. P., Karydis, V. A., Pandis, S. N., Canagaratna, M. R., and Molina, L. T.: Simulations of organic aerosol concentrations in Mexico City using the WRF-CHEM model during the MCMA-2006/MILAGRO campaign, Atmos. Chem. Phys., 11, 3789–3809, https://doi.org/10.5194/acp-11-3789-2011, 2011b.
Liu, L., Xu, W., Lu, X., Zhong, B., Guo, Y., Lu, X., Zhao, Y., He, W., Wang, S., Zhang, X., Liu, X., and Vitousek, P.: Exploring global changes in agricultural ammonia emissions and their contribution to nitrogen deposition since 1980, P. Natl. Acad. Sci. USA, 119, e2121998119, https://doi.org/10.1073/pnas.2121998119, 2022a.
Liu, P., Ding, J., Ji, Y., Xu, H., Liu, S., Xiao, B., Jin, H., Zhong, X., Guo, Z., Wang, H., and Liu, L.: Satellite Support to Estimate Livestock Ammonia Emissions: A Case Study in Hebei, China, Atmosphere, 13, 1552, https://doi.org/10.3390/atmos13101552, 2022b.
Liu, Y., Liggio, J., Staebler, R., and Li, S.-M.: Reactive uptake of ammonia to secondary organic aerosols: kinetics of organonitrogen formation, Atmos. Chem. Phys., 15, 13569–13584, https://doi.org/10.5194/acp-15-13569-2015, 2015.
Lu, C., Wang, X., Li, R., Gu, R., Zhang, Y., Li, W., Gao, R., Chen, B., Xue, L., and Wang, W.: Emissions of fine particulate nitrated phenols from residential coal combustion in China, Atmos. Environ., 203, 10–17, https://doi.org/10.1016/j.atmosenv.2019.01.047, 2019.
Luo, C., Zender, C. S., Bian, H., and Metzger, S.: Role of ammonia chemistry and coarse mode aerosols in global climatological inorganic aerosol distributions, Atmos. Environ., 41, 2510–2533, https://doi.org/10.1016/j.atmosenv.2006.11.030, 2007.
Ma, J., Shi, H., Zhu, Y., Li, R., Wang, S., Lu, N., Yao, Y., Bian, Z., and Huang, K.: The Evolution of Global Surface Ammonia Concentrations during 2001–2019: Magnitudes, Patterns, and Drivers, Environ. Sci. Technol., 59, 5066–5079, https://doi.org/10.1021/acs.est.4c14020, 2025.
Makar, P. A., Moran, M. D., Zheng, Q., Cousineau, S., Sassi, M., Duhamel, A., Besner, M., Davignon, D., Crevier, L.-P., and Bouchet, V. S.: Modelling the impacts of ammonia emissions reductions on North American air quality, Atmos. Chem. Phys., 9, 7183–7212, https://doi.org/10.5194/acp-9-7183-2009, 2009.
Mang, S. A., Henricksen, D. K., Bateman, A. P., and Nizkorodov, S. A.: Contribution of Carbonyl Photochemistry to Aging of Atmospheric Secondary Organic Aerosol, J. Phys. Chem. A, 112, 8337–8344, https://doi.org/10.1021/jp804376c, 2008.
Moise, T., Flores, J. M., and Rudich, Y.: Optical Properties of Secondary Organic Aerosols and Their Changes by Chemical Processes, Chem. Rev., 115, 4400–4439, https://doi.org/10.1021/cr5005259, 2015.
Na, K., Song, C., Switzer, C., and Cocker, D. R.: Effect of ammonia on secondary organic aerosol formation from alpha-pinene ozonolysis in dry and humid conditions, Environ. Sci. Technol., 41, 6096–6102, https://doi.org/10.1021/es061956y, 2007.
Nenes, A., Pandis, S. N., and Pilinis, C.: ISORROPIA: A new thermodynamic equilibrium model for multiphase multicomponent inorganic aerosols, Aquat. Geochem., 4, 123–152, https://doi.org/10.1023/A:1009604003981, 1998.
Nenes, A., Pandis, S. N., Weber, R. J., and Russell, A.: Aerosol pH and liquid water content determine when particulate matter is sensitive to ammonia and nitrate availability, Atmos. Chem. Phys., 20, 3249–3258, https://doi.org/10.5194/acp-20-3249-2020, 2020.
Nguyen, T. B., Lee, P. B., Updyke, K. M., Bones, D. L., Laskin, J., Laskin, A., and Nizkorodov, S. A.: Formation of nitrogen- and sulfur-containing light-absorbing compounds accelerated by evaporation of water from secondary organic aerosols, J. Geophys. Res.-Atmos., 117, D01207, https://doi.org/10.1029/2011JD016944, 2012.
Pan, Y., Tian, S., Zhao, Y., Zhang, L., Zhu, X., Gao, J., Huang, W., Zhou, Y., Song, Y., Zhang, Q., and Wang, Y.: Identifying Ammonia Hotspots in China Using a National Observation Network, Environ. Sci. Technol., 52, 3926–3934, https://doi.org/10.1021/acs.est.7b05235, 2018.
Pye, H. O. T., Nenes, A., Alexander, B., Ault, A. P., Barth, M. C., Clegg, S. L., Collett Jr., J. L., Fahey, K. M., Hennigan, C. J., Herrmann, H., Kanakidou, M., Kelly, J. T., Ku, I.-T., McNeill, V. F., Riemer, N., Schaefer, T., Shi, G., Tilgner, A., Walker, J. T., Wang, T., Weber, R., Xing, J., Zaveri, R. A., and Zuend, A.: The acidity of atmospheric particles and clouds, Atmos. Chem. Phys., 20, 4809–4888, https://doi.org/10.5194/acp-20-4809-2020, 2020.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics: from air pollution to climate change, John Wiley & Sons, New York, 1326 pp., ISBN 9780471178156, 1998.
Van Damme, M., Clarisse, L., Whitburn, S., Hadji-Lazaro, J., Hurtmans, D., Clerbaux, C., and Coheur, P.-F.: Industrial and agricultural ammonia point sources exposed, Nature, 564, 99–103, https://doi.org/10.1038/s41586-018-0747-1, 2018.
Van Damme, M., Clarisse, L., Franco, B., Sutton, M., Erisman, J. W., Wichink Kruit, R., van Zanten, M., Whitburn, S., Hadji-Lazaro, J., Hurtmans, D., Clerbaux, C., and Coheur, P.-F.: Global, regional and national trends of atmospheric ammonia derived from a decadal (2008–2018) satellite record, Environ. Res. Lett., 16, 055017, https://doi.org/10.1088/1748-9326/abd5e0, 2021.
Wang, C., Li, X., Zhang, T., Tang, A., Cui, M., Liu, X., Ma, X., Zhang, Y., Liu, X., and Zheng, M.: Developing Nitrogen Isotopic Source Profiles of Atmospheric Ammonia for Source Apportionment of Ammonia in Urban Beijing, Front. Environ. Sci., 10, 903013, https://doi.org/10.3389/fenvs.2022.903013, 2022a.
Wang, M., Wang, Q., Ho, S. S. H., Li, H., Zhang, R., Ran, W., Qu, L., Lee, S. C., and Cao, J.: Chemical characteristics and sources of nitrogen-containing organic compounds at a regional site in the North China Plain during the transition period of autumn and winter, Sci. Total Environ., 812, 151451, https://doi.org/10.1016/j.scitotenv.2021.151451, 2022b.
Wang, M., Wang, Q., Ho, S. S. H., Tian, J., Zhang, Y., Lee, S., and Cao, J.: Dominant influence of biomass combustion and cross-border transport on nitrogen-containing organic compound levels in the southeastern Tibetan Plateau, Atmos. Chem. Phys., 24, 11175–11189, https://doi.org/10.5194/acp-24-11175-2024, 2024.
Wang, X. F., Wang, H. L., Jing, H., Wang, W. N., Cui, W. D., Williams, B. J., and Biswas, P.: Formation of nitrogen-containing organic aerosol during combustion of high-sulfur-content coal, Energ. Fuel., 31, 14161–14168, https://doi.org/10.1021/acs.energyfuels.7b02273, 2017.
Wen, L., Chen, J., Yang, L., Wang, X., Xu, C., Sui, X., Yao, L., Zhu, Y., Zhang, J., Zhu, T., and Wang, W.: Enhanced formation of fine particulate nitrate at a rural site on the North China Plain in summer: The important roles of ammonia and ozone, Atmos. Environ., 101, 294–302, https://doi.org/10.1016/j.atmosenv.2014.11.037, 2015.
Wu, J., Li, G., Cao, J., Bei, N., Wang, Y., Feng, T., Huang, R., Liu, S., Zhang, Q., and Tie, X.: Contributions of trans-boundary transport to summertime air quality in Beijing, China, Atmos. Chem. Phys., 17, 2035–2051, https://doi.org/10.5194/acp-17-2035-2017, 2017.
Wu, J., Bei, N., Hu, B., Liu, S., Zhou, M., Wang, Q., Li, X., Liu, L., Feng, T., Liu, Z., Wang, Y., Cao, J., Tie, X., Wang, J., Molina, L. T., and Li, G.: Aerosol–radiation feedback deteriorates the wintertime haze in the North China Plain, Atmos. Chem. Phys., 19, 8703–8719, https://doi.org/10.5194/acp-19-8703-2019, 2019.
Wu, K., Zhu, S., Liu, Y., Wang, H., Yang, X., Liu, L., Dabdub, D., and Cappa, C. D.: Modeling Ammonia and Its Uptake by Secondary Organic Aerosol Over China, J. Geophys. Res.-Atmos., 126, e2020JD034109, https://doi.org/10.1029/2020JD034109, 2021.
Xu, R., Tian, H., Pan, S., Prior, S. A., Feng, Y., Batchelor, W. D., Chen, J., and Yang, J.: Global ammonia emissions from synthetic nitrogen fertilizer applications in agricultural systems: Empirical and process-based estimates and uncertainty, Glob. Change Biol., 25, 314–326, https://doi.org/10.1111/gcb.14499, 2019.
Yang, S. L., Wang, M. Y., Wang, M. J., Zhang, X., Han, Q., Wang, H., Xiong, Q., Zhang, C., and Wang, M.: Establishing an emission inventory for ammonia, a key driver of haze formation in the southern North China plain during the COVID-19 pandemic, Sci. Total Environ., 904, 166857, https://doi.org/10.1016/j.scitotenv.2023.166857, 2023.
Zhang, G., Lian, X., Fu, Y., Lin, Q., Li, L., Song, W., Wang, Z., Tang, M., Chen, D., Bi, X., Wang, X., and Sheng, G.: High secondary formation of nitrogen-containing organics (NOCs) and its possible link to oxidized organics and ammonium, Atmos. Chem. Phys., 20, 1469–1481, https://doi.org/10.5194/acp-20-1469-2020, 2020.
Zhang, G., Wang, T., Lin, Q., Liu, K., Sun, W., Chen, D., Li, L., Wang, X., and Bi, X.: A comparative study on the formation of nitrogen-containing organic compounds in cloud droplets and aerosol particles, J. Environ. Sci., 146, 456–464, https://doi.org/10.1016/j.jes.2024.01.026, 2025.
Zhang, G., Li, T., Sun, W., Huang, X., Wang, T., Wang, X., Ma, N., Hu, W., Tang, M., Shi, Z., Wang, X., Peng, P., and Bi, X.: Molecular Evidence of Aqueous-Processed NOCs: From Mechanistic Insights to Environmental Impacts, J. Geophys. Res.-Atmos., 131, e2025JD045757, https://doi.org/10.1029/2025JD045757, 2026.
Zhang, R., Han, Y., Shi, A., Sun, X., Yan, X., Huang, Y., and Wang, Y.: Characteristics of ambient ammonia and its effects on particulate ammonium in winter of urban Beijing, China, Environ. Sci. Pollut. R., 28, 62828–62838, https://doi.org/10.1007/s11356-021-14108-w, 2021.
Zheng, G., Su, H., and Cheng, Y.: Role of Carbon Dioxide, Ammonia, and Organic Acids in Buffering Atmospheric Acidity: The Distinct Contribution in Clouds and Aerosols, Environ. Sci. Technol., 57, 12571–12582, https://doi.org/10.1021/acs.est.2c09851, 2023.
Zhu, S., Horne, J. R., Montoya-Aguilera, J., Hinks, M. L., Nizkorodov, S. A., and Dabdub, D.: Modeling reactive ammonia uptake by secondary organic aerosol in CMAQ: application to the continental US, Atmos. Chem. Phys., 18, 3641–3657, https://doi.org/10.5194/acp-18-3641-2018, 2018.
Zhu, S., Wu, K., Nizkorodov, S. A., and Dabdub, D.: Modeling reactive ammonia uptake by secondary organic aerosol in a changing climate: a WRF-CMAQ evaluation, Front. Environ. Sci., 10, 867908, https://doi.org/10.3389/fenvs.2022.867908, 2022.
Short summary
This study explored how ammonia reacts with secondary organic aerosols over northern China using model simulations constrained by observational data. The reaction had little effect on overall fine particle pollution but may provide an additional source of nitrogen-containing organic particles, improving understanding of atmospheric pollution formation and chemical processes in air quality models.
This study explored how ammonia reacts with secondary organic aerosols over northern China using...
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