Articles | Volume 25, issue 15
https://doi.org/10.5194/acp-25-8719-2025
https://doi.org/10.5194/acp-25-8719-2025
Research article
 | 
11 Aug 2025
Research article |  | 11 Aug 2025

Enhanced atmospheric oxidation and particle reductions driving changes to nitrate formation mechanisms across coastal and inland regions of north China

Zhenze Liu, Jianhua Qi, Yuanzhe Ni, Likun Xue, and Xiaohuan Liu

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Regional Heterogeneity in Wintertime Atmospheric Nitrate Formation over China’s Marginal Seas: Roles of Halogen Chemistry and Dimethyl Sulfide-Related Processes
Zhenze Liu, Jianhua Qi, Yuanzhe Ni, Xiaohuan Liu, Gang Yuan, and Mingxu Liu
EGUsphere, https://doi.org/10.5194/egusphere-2026-5674,https://doi.org/10.5194/egusphere-2026-5674, 2026
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Cited articles

Albertin, S., Savarino, J., Bekki, S., Barbero, A., and Caillon, N.: Measurement report: Nitrogen isotopes (δ15N) and first quantification of oxygen isotope anomalies (Δ17O, δ18O) in atmospheric nitrogen dioxide, Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, 2021. 
Albertin, S., Savarino, J., Bekki, S., Barbero, A., Grilli, R., Fournier, Q., Ventrillard, I., Caillon, N., and Law, K.: Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources, Atmos. Chem. Phys., 24, 1361–1388, https://doi.org/10.5194/acp-24-1361-2024, 2024. 
Alexander, B., Sherwen, T., Holmes, C. D., Fisher, J. A., Chen, Q., Evans, M. J., and Kasibhatla, P.: Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations, Atmos. Chem. Phys., 20, 3859–3877, https://doi.org/10.5194/acp-20-3859-2020, 2020. 
Ansari, A. S. and Pandis, S. N.: Response of Inorganic PM to Precursor Concentrations, Environ. Sci. Technol., 32, 2706–2714, https://doi.org/10.1021/es971130j, 1998. 
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Our research investigated nitrate formation in air pollution across inland and coastal cities in northern China during the winters of 2013 and 2018. Using air quality models and isotopic analysis, we identified regional differences, with coastal cities showing more contribution from the dinitrogen pentoxide (N2O5) heterogeneous reaction. Reducing nitrogen oxides (NOx), volatile organic compounds (VOCs), and ammonia (NH3) was crucial for lowering nitrate levels and improving air quality.
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