Articles | Volume 20, issue 22
https://doi.org/10.5194/acp-20-14077-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-14077-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Chemical composition, structures, and light absorption of N-containing aromatic compounds emitted from burning wood and charcoal in household cookstoves
Mingjie Xie
CORRESPONDING AUTHOR
Collaborative Innovation Center of Atmospheric Environment and
Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment
Monitoring and Pollution Control, School of Environmental Science and
Engineering, Nanjing University of Information Science & Technology, 219
Ningliu Road, Nanjing 210044, China
Zhenzhen Zhao
Collaborative Innovation Center of Atmospheric Environment and
Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment
Monitoring and Pollution Control, School of Environmental Science and
Engineering, Nanjing University of Information Science & Technology, 219
Ningliu Road, Nanjing 210044, China
Amara L. Holder
Office of Research and Development, US Environmental Protection
Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Michael D. Hays
Office of Research and Development, US Environmental Protection
Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Xi Chen
Office of Research and Development, US Environmental Protection
Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Guofeng Shen
Laboratory for Earth Surface Processes, College of Urban and
Environmental Sciences, Peking University, Beijing 100871, China
James J. Jetter
Office of Research and Development, US Environmental Protection
Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Wyatt M. Champion
Oak Ridge Institute for Science and Education (ORISE), Center for Environmental Measurement and Modeling, Office of Research and Development, US Environmental Protection Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Qin'geng Wang
State Key Laboratory of Pollution Control and Resource Reuse, Nanjing
University, Nanjing 210023, China
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Cited articles
Ahrens, L., Harner, T., Shoeib, M., Lane, D. A., and Murphy, J. G.: Improved
characterization of gas–particle partitioning for per- and polyfluoroalkyl
substances in the atmosphere using annular diffusion denuder samplers,
Environ. Sci. Technol., 46, 7199–7206, https://doi.org/10.1021/es300898s,
2012.
Anenberg, S. C., Balakrishnan, K., Jetter, J., Masera, O., Mehta, S., Moss,
J., and Ramanathan, V.: Cleaner cooking solutions to achieve health,
climate, and economic cobenefits, Environ. Sci. Technol., 47,
3944–3952, https://doi.org/10.1021/es304942e, 2013.
Aunan, K., Berntsen, T. K., Myhre, G., Rypdal, K., Streets, D. G., Woo,
J.-H., and Smith, K. R.: Radiative forcing from household fuel burning in
Asia, Atmos. Environ., 43, 5674–5681,
https://doi.org/10.1016/j.atmosenv.2009.07.053, 2009.
Bond, T. C., Streets, D. G., Yarber, K. F., Nelson, S. M., Woo, J.-H., and
Klimont, Z.: A technology-based global inventory of black and organic carbon
emissions from combustion, J. Geophys. Res.-Atmos.,
109, D14203, https://doi.org/10.1029/2003jd003697, 2004.
Bonjour, S., Adair-Rohani, H., Wolf, J., Bruce Nigel, G., Mehta, S.,
Prüss-Ustün, A., Lahiff, M., Rehfuess Eva, A., Mishra, V., and Smith
Kirk, R.: Solid fuel use for household cooking: Country and regional
estimates for 1980–2010, Environ. Health Persp., 121, 784–790,
https://doi.org/10.1289/ehp.1205987, 2013.
Cao, G., Zhang, X., and Zheng, F.: Inventory of black carbon and organic
carbon emissions from China, Atmos. Environ., 40, 6516–6527,
https://doi.org/10.1016/j.atmosenv.2006.05.070, 2006.
Chen, Y. and Bond, T. C.: Light absorption by organic carbon from wood combustion, Atmos. Chem. Phys., 10, 1773–1787, https://doi.org/10.5194/acp-10-1773-2010, 2010.
Chen, Y., Sheng, G., Bi, X., Feng, Y., Mai, B., and Fu, J.: Emission factors
for carbonaceous particles and polycyclic aromatic hydrocarbons from
residential coal combustion in China, Environ. Sci. Technol.,
39, 1861–1867, https://doi.org/10.1021/es0493650, 2005.
Claeys, M., Vermeylen, R., Yasmeen, F., Gómez-González, Y., Chi, X.,
Maenhaut, W., Mészáros, T., and Salma, I.: Chemical characterisation
of humic-like substances from urban, rural and tropical biomass burning
environments using liquid chromatography with UV/vis photodiode array
detection and electrospray ionisation mass spectrometry, Environ.
Chem., 9, 273–284, https://doi.org/10.1071/EN11163, 2012.
De Haan, D. O., Hawkins, L. N., Welsh, H. G., Pednekar, R., Casar, J. R.,
Pennington, E. A., de Loera, A., Jimenez, N. G., Symons, M. A., Zauscher,
M., Pajunoja, A., Caponi, L., Cazaunau, M., Formenti, P., Gratien, A.,
Pangui, E., and Doussin, J.-F.: Brown carbon production in ammonium- or
amine-containing aerosol particles by reactive uptake of methylglyoxal and
photolytic cloud cycling, Environ. Sci. Technol., 51,
7458–7466, https://doi.org/10.1021/acs.est.7b00159, 2017.
Desyaterik, Y., Sun, Y., Shen, X., Lee, T., Wang, X., Wang, T., and Collett,
J. L.: Speciation of “brown” carbon in cloud water impacted by
agricultural biomass burning in eastern China, J. Geophys. Res.-Atmos., 118, 7389–7399, https://doi.org/10.1002/jgrd.50561, 2013.
Di Lorenzo, R. A. and Young, C. J.: Size separation method for absorption
characterization in brown carbon: Application to an aged biomass burning
sample, Geophys. Res. Lett., 43, 458–465, https://doi.org/10.1002/2015gl066954,
2016.
Di Lorenzo, R. A., Washenfelder, R. A., Attwood, A. R., Guo, H., Xu, L., Ng,
N. L., Weber, R. J., Baumann, K., Edgerton, E., and Young, C. J.:
Molecular-size-separated brown carbon absorption for biomass-burning aerosol
at multiple field sites, Environ. Sci. Technol., 51,
3128–3137, https://doi.org/10.1021/acs.est.6b06160, 2017.
Ding, Y., Pang, Y., and Eatough, D. J.: High-volume diffusion denuder
sampler for the routine monitoring of fine particulate matter: I. Design and
optimization of the PC-BOSS, Aerosol Sci. Technol., 36, 369–382,
https://doi.org/10.1080/027868202753571205, 2002.
Donahue, N. M., Epstein, S. A., Pandis, S. N., and Robinson, A. L.: A two-dimensional volatility basis set: 1. organic-aerosol mixing thermodynamics, Atmos. Chem. Phys., 11, 3303–3318, https://doi.org/10.5194/acp-11-3303-2011, 2011.
Feng, Y., Ramanathan, V., and Kotamarthi, V. R.: Brown carbon: a significant atmospheric absorber of solar radiation?, Atmos. Chem. Phys., 13, 8607–8621, https://doi.org/10.5194/acp-13-8607-2013, 2013.
Fleming, L. T., Lin, P., Laskin, A., Laskin, J., Weltman, R., Edwards, R. D., Arora, N. K., Yadav, A., Meinardi, S., Blake, D. R., Pillarisetti, A., Smith, K. R., and Nizkorodov, S. A.: Molecular composition of particulate matter emissions from dung and brushwood burning household cookstoves in Haryana, India, Atmos. Chem. Phys., 18, 2461–2480, https://doi.org/10.5194/acp-18-2461-2018, 2018.
Forrister, H., Liu, J., Scheuer, E., Dibb, J., Ziemba, L., Thornhill, K. L.,
Anderson, B., Diskin, G., Perring, A. E., Schwarz, J. P., Campuzano-Jost,
P., Day, D. A., Palm, B. B., Jimenez, J. L., Nenes, A., and Weber, R. J.:
Evolution of brown carbon in wildfire plumes, Geophys. Res. Lett.,
42, 4623–4630, https://doi.org/10.1002/2015gl063897, 2015.
Gilman, J. B., Lerner, B. M., Kuster, W. C., Goldan, P. D., Warneke, C., Veres, P. R., Roberts, J. M., de Gouw, J. A., Burling, I. R., and Yokelson, R. J.: Biomass burning emissions and potential air quality impacts of volatile organic compounds and other trace gases from fuels common in the US, Atmos. Chem. Phys., 15, 13915–13938, https://doi.org/10.5194/acp-15-13915-2015, 2015.
Glarborg, P., Jensen, A., and Johnsson, J. E.: Fuel nitrogen conversion in
solid fuel fired systems, Prog. Energ. Combust., 29,
89–113, 2003.
Global Alliance for Clean Cookstoves: Water Boiling Test (WBT) 4.2.3,
Released 19 March 2014, available at:
http://cleancookstoves.org/technology-and-fuels/testing/protocols.html
(last access: July 2017), 2014.
Harrison, M. A., Barra, S., Borghesi, D., Vione, D., Arsene, C., and Olariu,
R. I.: Nitrated phenols in the atmosphere: a review, Atmos. Environ., 39, 231–248, 2005.
Hecobian, A., Zhang, X., Zheng, M., Frank, N., Edgerton, E. S., and Weber, R. J.: Water-Soluble Organic Aerosol material and the light-absorption characteristics of aqueous extracts measured over the Southeastern United States, Atmos. Chem. Phys., 10, 5965–5977, https://doi.org/10.5194/acp-10-5965-2010, 2010.
Iinuma, Y., Böge, O., Gräfe, R., and Herrmann, H.:
Methyl-nitrocatechols: Atmospheric tracer compounds for biomass burning
secondary organic aerosols, Environ. Sci. Technol., 44,
8453–8459, https://doi.org/10.1021/es102938a, 2010.
International Agency for Research on Cancer: Some non-heterocyclic
polycyclic aromatic hydrocarbons and some related exposures (Vol. 92), IARC
Press, International Agency for Research on Cancer, Lyon, France, 2010.
Jaeckels, J. M., Bae, M. S., and Schauer, J. J.: Positive matrix
factorization (PMF) analysis of molecular marker measurements to quantify
the sources of organic aerosols, Environ. Sci. Technol., 41,
5763–5769, https://doi.org/10.1021/es062536b, 2007.
Jetter, J. J. and Kariher, P.: Solid-fuel household cook stoves:
Characterization of performance and emissions, Biomass and Bioenergy, 33,
294–305, https://doi.org/10.1016/j.biombioe.2008.05.014, 2009.
Jetter, J., Zhao, Y., Smith, K. R., Khan, B., Yelverton, T., DeCarlo, P.,
and Hays, M. D.: Pollutant emissions and energy efficiency under controlled
conditions for household biomass cookstoves and implications for metrics
useful in setting international test standards, Environ. Sci. Technol., 46, 10827–10834, https://doi.org/10.1021/es301693f, 2012.
Kaal, J., Martínez Cortizas, A., and Nierop, K. G. J.: Characterisation
of aged charcoal using a coil probe pyrolysis-GC/MS method optimised for
black carbon, J. Anal. Appl. Pyrol., 85, 408–416,
https://doi.org/10.1016/j.jaap.2008.11.007, 2009.
Kim, K.-H., Jahan, S. A., Kabir, E., and Brown, R. J. C.: A review of
airborne polycyclic aromatic hydrocarbons (PAHs) and their human health
effects, Environ. Int., 60, 71–80,
https://doi.org/10.1016/j.envint.2013.07.019, 2013.
Kim Oanh, N. T., Bætz Reutergårdh, L., and Dung, N. T.: Emission of
polycyclic aromatic hydrocarbons and particulate matter from domestic
combustion of selected fuels, Environ. Sci. Technol., 33,
2703–2709, https://doi.org/10.1021/es980853f, 1999.
Kirchstetter, T. W., Corrigan, C. E., and Novakov, T.: Laboratory and field
investigation of the adsorption of gaseous organic compounds onto quartz
filters, Atmos. Environ., 35, 1663–1671,
https://doi.org/10.1016/S1352-2310(00)00448-9, 2001.
Klimont, Z., Cofala, J., Xing, J., Wei, W., Zhang, C., Wang, S., Kejun, J.,
Bhandari, P., Mathur, R., Purohit, P., Rafaj, P., Chambers, A., Amann, M.,
and Hao, J.: Projections of SO2, NOx and carbonaceous aerosols emissions in
Asia, Tellus B, 61, 602–617, https://doi.org/10.1111/j.1600-0889.2009.00428.x, 2009.
Kwamena, N.-O. and Abbatt, J.: Heterogeneous nitration reactions of
polycyclic aromatic hydrocarbons and n-hexane soot by exposure to
NO3/NO2/N2O5, Atmos. Environ., 42, 8309–8314, 2008.
Lacey, F. and Henze, D.: Global climate impacts of country-level primary
carbonaceous aerosol from solid-fuel cookstove emissions, Environ.
Res. Lett., 10, 114003, https://doi.org/10.1088/1748-9326/10/11/114003, 2015.
Lei, Y., Zhang, Q., He, K. B., and Streets, D. G.: Primary anthropogenic aerosol emission trends for China, 1990–2005, Atmos. Chem. Phys., 11, 931–954, https://doi.org/10.5194/acp-11-931-2011, 2011.
Li, Q., Jacob, D. J., Bey, I., Yantosca, R. M., Zhao, Y., Kondo, Y., and
Notholt, J.: Atmospheric hydrogen cyanide (HCN): Biomass burning source,
ocean sink?, Geophys. Res. Lett., 27, 357–360,
https://doi.org/10.1029/1999gl010935, 2000.
Lin, P., Liu, J. M., Shilling, J. E., Kathmann, S. M., Laskin, J., and
Laskin, A.: Molecular characterization of brown carbon (BrC) chromophores in
secondary organic aerosol generated from photo-oxidation of toluene,
Phys. Chem. Chem. Phys., 17, 23312–23325, https://doi.org/10.1039/c5cp02563j,
2015.
Lin, P., Aiona, P. K., Li, Y., Shiraiwa, M., Laskin, J., Nizkorodov, S. A.,
and Laskin, A.: Molecular characterization of brown carbon in biomass
burning aerosol particles, Environ. Sci. Technol., 50,
11815–11824, https://doi.org/10.1021/acs.est.6b03024, 2016.
Lin, P., Bluvshtein, N., Rudich, Y., Nizkorodov, S. A., Laskin, J., and
Laskin, A.: Molecular chemistry of atmospheric brown carbon inferred from a
nationwide biomass burning event, Environ. Sci. Technol., 51,
11561–11570, https://doi.org/10.1021/acs.est.7b02276, 2017.
Liu, J., Bergin, M., Guo, H., King, L., Kotra, N., Edgerton, E., and Weber, R. J.: Size-resolved measurements of brown carbon in water and methanol extracts and estimates of their contribution to ambient fine-particle light absorption, Atmos. Chem. Phys., 13, 12389–12404, https://doi.org/10.5194/acp-13-12389-2013, 2013.
Lu, C., Wang, X., Li, R., Gu, R., Zhang, Y., Li, W., Gao, R., Chen, B., Xue,
L., and Wang, W.: Emissions of fine particulate nitrated phenols from
residential coal combustion in China, Atmos. Environ., 203, 10–17,
https://doi.org/10.1016/j.atmosenv.2019.01.047, 2019.
Lu, J. W., Flores, J. M., Lavi, A., Abo-Riziq, A., and Rudich, Y.: Changes
in the optical properties of benzo[a]pyrene-coated aerosols upon
heterogeneous reactions with NO2 and NO3, Phys. Chem. Chem.
Phys., 13, 6484–6492, https://doi.org/10.1039/C0CP02114H, 2011.
Lu, Z., Streets, D. G., Winijkul, E., Yan, F., Chen, Y., Bond, T. C., Feng,
Y., Dubey, M. K., Liu, S., Pinto, J. P., and Carmichael, G. R.: Light
absorption properties and radiative effects of primary organic aerosol
emissions, Environ. Sci. Technol., 49, 4868–4877,
https://doi.org/10.1021/acs.est.5b00211, 2015.
McMeeking, G., Fortner, E., Onasch, T., Taylor, J., Flynn, M., Coe, H., and
Kreidenweis, S.: Impacts of nonrefractory material on light absorption by
aerosols emitted from biomass burning, J. Geophys. Res.-Atmos., 119, 12272–12286, 2014.
Mohr, C., Lopez-Hilfiker, F. D., Zotter, P., Prévôt, A. S. H., Xu,
L., Ng, N. L., Herndon, S. C., Williams, L. R., Franklin, J. P., Zahniser,
M. S., Worsnop, D. R., Knighton, W. B., Aiken, A. C., Gorkowski, K. J.,
Dubey, M. K., Allan, J. D., and Thornton, J. A.: Contribution of nitrated
phenols to wood burning brown carbon light absorption in Detling, United
Kingdom during winter time, Environ. Sci. Technol., 47,
6316–6324, https://doi.org/10.1021/es400683v, 2013.
Nakayama, T., Matsumi, Y., Sato, K., Imamura, T., Yamazaki, A., and
Uchiyama, A.: Laboratory studies on optical properties of secondary organic
aerosols generated during the photooxidation of toluene and the ozonolysis
of α-pinene, J. Geophys. Res.-Atmos., 115, D24204, https://doi.org/10.1029/2010jd014387, 2010.
Park, R. J., Kim, M. J., Jeong, J. I., Youn, D., and Kim, S.: A contribution
of brown carbon aerosol to the aerosol light absorption and its radiative
forcing in East Asia, Atmos. Environ., 44, 1414–1421,
https://doi.org/10.1016/j.atmosenv.2010.01.042, 2010.
Peters, A. J., Lane, D. A., Gundel, L. A., Northcott, G. L., and Jones, K.
C.: A comparison of high volume and diffusion denuder samplers for measuring
semivolatile organic compounds in the atmosphere, Environ. Sci. Technol., 34, 5001–5006, https://doi.org/10.1021/es000056t, 2000.
Pokhrel, R. P., Wagner, N. L., Langridge, J. M., Lack, D. A., Jayarathne, T., Stone, E. A., Stockwell, C. E., Yokelson, R. J., and Murphy, S. M.: Parameterization of single-scattering albedo (SSA) and absorption Ångström exponent (AAE) with EC∕OC for aerosol emissions from biomass burning, Atmos. Chem. Phys., 16, 9549–9561, https://doi.org/10.5194/acp-16-9549-2016, 2016.
Ravindra, K., Sokhi, R., and Van Grieken, R.: Atmospheric polycyclic
aromatic hydrocarbons: Source attribution, emission factors and regulation,
Atmos. Environ., 42, 2895–2921,
https://doi.org/10.1016/j.atmosenv.2007.12.010, 2008.
Reff, A., Bhave, P. V., Simon, H., Pace, T. G., Pouliot, G. A., Mobley, J.
D., and Houyoux, M.: Emissions inventory of PM2.5 trace elements across the
United States, Environ. Sci. Technol., 43, 5790–5796,
https://doi.org/10.1021/es802930x, 2009.
Riddle, S. G., Jakober, C. A., Robert, M. A., Cahill, T. M., Charles, M. J.,
and Kleeman, M. J.: Large PAHs detected in fine particulate matter emitted
from light-duty gasoline vehicles, Atmos. Environ., 41, 8658–8668,
https://doi.org/10.1016/j.atmosenv.2007.07.023, 2007.
Saleh, R., Robinson, E. S., Tkacik, D. S., Ahern, A. T., Liu, S., Aiken, A.
C., Sullivan, R. C., Presto, A. A., Dubey, M. K., Yokelson, R. J., Donahue,
N. M., and Robinson, A. L.: Brownness of organics in aerosols from biomass
burning linked to their black carbon content, Nat. Geosci., 7, 647–650,
https://doi.org/10.1038/ngeo2220, 2014.
Samburova, V., Connolly, J., Gyawali, M., Yatavelli, R. L. N., Watts, A. C.,
Chakrabarty, R. K., Zielinska, B., Moosmüller, H., and Khlystov, A.:
Polycyclic aromatic hydrocarbons in biomass-burning emissions and their
contribution to light absorption and aerosol toxicity, Sci. Total
Environ., 568, 391–401, https://doi.org/10.1016/j.scitotenv.2016.06.026,
2016.
Schneider, J., Bürger, V., and Arnold, F.: Methyl cyanide and hydrogen
cyanide measurements in the lower stratosphere: Implications for methyl
cyanide sources and sinks, J. Geophys. Res.-Atmos.,
102, 25501–25506, https://doi.org/10.1029/97jd02364, 1997.
Shen, G., Tao, S., Wei, S., Zhang, Y., Wang, R., Wang, B., Li, W., Shen, H.,
Huang, Y., Chen, Y., Chen, H., Yang, Y., Wang, W., Wei, W., Wang, X., Liu,
W., Wang, X., and Simonich, S. L. M.: Reductions in Emissions of
Carbonaceous particulate matter and polycyclic aromatic hydrocarbons from
combustion of biomass pellets in comparison with raw fuel burning,
Environ. Sci. Technol., 46, 6409–6416, https://doi.org/10.1021/es300369d,
2012.
Shrivastava, M. K., Subramanian, R., Rogge, W. F., and Robinson, A. L.:
Sources of organic aerosol: Positive matrix factorization of molecular
marker data and comparison of results from different source apportionment
models, Atmos. Environ., 41, 9353–9369,
https://doi.org/10.1016/j.atmosenv.2007.09.016, 2007.
Simoneit, B. R.: Biomass burning – a review of organic tracers for smoke
from incomplete combustion, Appl. Geochem., 17, 129–162, 2002.
Simoneit, B. R., Rogge, W., Mazurek, M., Standley, L., Hildemann, L., and
Cass, G.: Lignin pyrolysis products, lignans, and resin acids as specific
tracers of plant classes in emissions from biomass combustion, Environ. Sci. Technol., 27, 2533–2541, 1993.
Smith, K. R., Bruce, N., Balakrishnan, K., Adair-Rohani, H., Balmes, J.,
Chafe, Z., Dherani, M., Hosgood, H. D., Mehta, S., Pope, D., and Rehfuess,
E.: Millions dead: How do we know and what does it mean? Methods used in the
comparative risk assessment of household air pollution, Annu. Rev.
Publ. Health, 35, 185–206, https://doi.org/10.1146/annurev-publhealth-032013-182356, 2014.
Subramanian, R., Khlystov, A. Y., Cabada, J. C., and Robinson, A. L.:
Positive and negative artifacts in particulate organic carbon measurements
with denuded and undenuded sampler configurations special issue of Aerosol
Science and Technology on findings from the fine particulate matter
supersites program, Aerosol Sci. Technol., 38, 27–48,
https://doi.org/10.1080/02786820390229354, 2004.
Sun, J., Zhi, G., Hitzenberger, R., Chen, Y., Tian, C., Zhang, Y., Feng, Y., Cheng, M., Zhang, Y., Cai, J., Chen, F., Qiu, Y., Jiang, Z., Li, J., Zhang, G., and Mo, Y.: Emission factors and light absorption properties of brown carbon from household coal combustion in China, Atmos. Chem. Phys., 17, 4769–4780, https://doi.org/10.5194/acp-17-4769-2017, 2017.
Teich, M., van Pinxteren, D., Wang, M., Kecorius, S., Wang, Z., Müller, T., Močnik, G., and Herrmann, H.: Contributions of nitrated aromatic compounds to the light absorption of water-soluble and particulate brown carbon in different atmospheric environments in Germany and China, Atmos. Chem. Phys., 17, 1653–1672, https://doi.org/10.5194/acp-17-1653-2017, 2017.
Tuccella, P., Curci, G., Pitari, G., Lee, S., and Jo, D. S.: Direct
radiative effect of absorbing aerosols: sensitivity to mixing state, brown
carbon and soil dust refractive index and shape, J. Geophys. Res.-Atmos., 125, e2019JD030967, https://doi.org/10.1029/2019JD030967, 2020.
Turpin, B. J. and Lim, H.-J.: Species contributions to PM2.5 mass
concentrations: Revisiting common assumptions for estimating organic mass,
Aerosol Sci. Technol., 35, 602–610, https://doi.org/10.1080/02786820119445, 2001.
Wang, X., Heald, C. L., Ridley, D. A., Schwarz, J. P., Spackman, J. R., Perring, A. E., Coe, H., Liu, D., and Clarke, A. D.: Exploiting simultaneous observational constraints on mass and absorption to estimate the global direct radiative forcing of black carbon and brown carbon, Atmos. Chem. Phys., 14, 10989–11010, https://doi.org/10.5194/acp-14-10989-2014, 2014.
Wathore, R., Mortimer, K., and Grieshop, A. P.: In-use emissions and
estimated impacts of traditional, natural- and forced-draft cookstoves in
rural Malawi, Environ. Sci. Technol., 51, 1929–1938,
https://doi.org/10.1021/acs.est.6b05557, 2017.
Watson, J. G., Chow, J. C., Chen, L. W. A., and Frank, N. H.: Methods to
assess carbonaceous aerosol sampling artifacts for IMPROVE and other
long-term networks, J. Air Waste Manag. Assoc.,
59, 898–911, https://doi.org/10.3155/1047-3289.59.8.898, 2009.
Xie, M., Hannigan, M. P., Dutton, S. J., Milford, J. B., Hemann, J. G.,
Miller, S. L., Schauer, J. J., Peel, J. L., and Vedal, S.: Positive matrix
factorization of PM2.5: Comparison and implications of using different
speciation data sets, Environ. Sci. Technol., 46,
11962–11970, https://doi.org/10.1021/es302358g, 2012.
Xie, M., Piedrahita, R., Dutton, S. J., Milford, J. B., Hemann, J. G., Peel,
J. L., Miller, S. L., Kim, S.-Y., Vedal, S., Sheppard, L., and Hannigan, M.
P.: Positive matrix factorization of a 32-month series of daily PM2.5
speciation data with incorporation of temperature stratification,
Atmos. Environ., 65, 11–20,
https://doi.org/10.1016/j.atmosenv.2012.09.034, 2013.
Xie, M., Hannigan, M. P., and Barsanti, K. C.: Gas/particle partitioning of
n-alkanes, PAHs and oxygenated PAHs in urban Denver, Atmos. Environ., 95, 355–362, https://doi.org/10.1016/j.atmosenv.2014.06.056,
2014.
Xie, M., Chen, X., Hays, M. D., Lewandowski, M., Offenberg, J., Kleindienst,
T. E., and Holder, A. L.: Light absorption of secondary organic aerosol:
Composition and contribution of nitroaromatic compounds, Environ. Sci. Technol., 51, 11607–11616, https://doi.org/10.1021/acs.est.7b03263, 2017a.
Xie, M., Hays, M. D., and Holder, A. L.: Light-absorbing organic carbon from
prescribed and laboratory biomass burning and gasoline vehicle emissions,
Sci. Rep.-UK, 7, 7318, https://doi.org/10.1038/s41598-017-06981-8, 2017b.
Xie, M., Shen, G., Holder, A. L., Hays, M. D., and Jetter, J. J.: Light
absorption of organic carbon emitted from burning wood, charcoal, and
kerosene in household cookstoves, Environ. Pollut., 240, 60–67,
https://doi.org/10.1016/j.envpol.2018.04.085, 2018.
Xie, M., Chen, X., Hays, M. D., and Holder, A. L.: Composition and light absorption of N-containing aromatic compounds in organic aerosols from laboratory biomass burning, Atmos. Chem. Phys., 19, 2899–2915, https://doi.org/10.5194/acp-19-2899-2019, 2019.
Xie, M., Zhao, Z., Holder, A., Hays, M., Chen, X., Shen, G., Jetter, J., Champion, W., and Wang, Q. G.: Replication Data for: Chemical composition, structures, and light absorption of N-containing aromatic compounds emitted from burning wood and charcoal in household cookstoves, V1 ed., Harvard Dataverse, https://doi.org/10.7910/DVN/VERFPS, 2020.
Yang, M., Howell, S. G., Zhuang, J., and Huebert, B. J.: Attribution of aerosol light absorption to black carbon, brown carbon, and dust in China – interpretations of atmospheric measurements during EAST-AIRE, Atmos. Chem. Phys., 9, 2035–2050, https://doi.org/10.5194/acp-9-2035-2009, 2009.
Zhang, X., Lin, Y.-H., Surratt, J. D., and Weber, R. J.: Sources,
composition and absorption Ångström exponent of light-absorbing
organic components in aerosol extracts from the Los Angeles basin,
Environ. Sci. Technol., 47, 3685–3693, https://doi.org/10.1021/es305047b,
2013.
Short summary
This study investigated the composition, structures, and light absorption of N-containing aromatic compounds (NACs) in PM2.5 emitted from burning red oak and charcoal in a variety of cookstoves. The results suggest that the identified NACs might have substantial fractions remaining in the gas phase. In comparison to other sources, cookstove emissions from red oak or charcoal fuels did not exhibit unique NAC structural features but had distinct NAC composition.
This study investigated the composition, structures, and light absorption of N-containing...
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