Articles | Volume 20, issue 22
https://doi.org/10.5194/acp-20-14077-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-14077-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Nov 2020
Research article |
| 20 Nov 2020
| 20 Nov 2020
Chemical composition, structures, and light absorption of N-containing aromatic compounds emitted from burning wood and charcoal in household cookstoves
Mingjie Xie
CORRESPONDING AUTHOR
Collaborative Innovation Center of Atmospheric Environment and
Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment
Monitoring and Pollution Control, School of Environmental Science and
Engineering, Nanjing University of Information Science & Technology, 219
Ningliu Road, Nanjing 210044, China
Zhenzhen Zhao
Collaborative Innovation Center of Atmospheric Environment and
Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment
Monitoring and Pollution Control, School of Environmental Science and
Engineering, Nanjing University of Information Science & Technology, 219
Ningliu Road, Nanjing 210044, China
Amara L. Holder
Office of Research and Development, US Environmental Protection
Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Michael D. Hays
Office of Research and Development, US Environmental Protection
Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Xi Chen
Office of Research and Development, US Environmental Protection
Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Guofeng Shen
Laboratory for Earth Surface Processes, College of Urban and
Environmental Sciences, Peking University, Beijing 100871, China
James J. Jetter
Office of Research and Development, US Environmental Protection
Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Wyatt M. Champion
Oak Ridge Institute for Science and Education (ORISE), Center for Environmental Measurement and Modeling, Office of Research and Development, US Environmental Protection Agency, 109 T.W. Alexander Drive, Research Triangle Park, NC 27711, USA
Qin'geng Wang
State Key Laboratory of Pollution Control and Resource Reuse, Nanjing
University, Nanjing 210023, China
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We measured changes in light absorption during the aqueous oxidation of six phenols with hydroxyl radical (●OH) or an organic triplet excited state (3C*). All the phenols formed light-absorbing secondary brown carbon (BrC), which then decayed with continued oxidation. Extrapolation to ambient conditions suggest ●OH is the dominant sink of secondary phenolic BrC in fog/cloud drops, while 3C* controls the lifetime of this light absorption in particle water.
Aaron Lieberman, Julietta Picco, Murat Onder, and Cort Anastasio
Atmos. Chem. Phys., 24, 4411–4419, https://doi.org/10.5194/acp-24-4411-2024, https://doi.org/10.5194/acp-24-4411-2024, 2024
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We developed a method that uses aqueous S(IV) to quantitatively convert NO2 to NO2−, which allows both species to be quantified using the Griess method. As an example of the utility of the method, we quantified both photolysis channels of nitrate, with and without a scavenger for hydroxyl radical (·OH). The results show that without a scavenger, ·OH reacts with nitrite to form nitrogen dioxide, suppressing the apparent quantum yield of NO2− and enhancing that of NO2.
Xingjun Fan, Ao Cheng, Xufang Yu, Tao Cao, Dan Chen, Wenchao Ji, Yongbing Cai, Fande Meng, Jianzhong Song, and Ping'an Peng
Atmos. Chem. Phys., 24, 3769–3783, https://doi.org/10.5194/acp-24-3769-2024, https://doi.org/10.5194/acp-24-3769-2024, 2024
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Molecular-level characteristics of high molecular weight (HMW) and low MW (LMW) humic-like substances (HULIS) were comprehensively investigated, where HMW HULIS had larger chromophores and larger molecular size than LMW HULIS and exhibited higher aromaticity and humification. Electrospray ionization high-resolution mass spectrometry revealed more aromatic molecules in HMW HULIS. HMW HULIS had more CHON compounds, while LMW HULIS had more CHO compounds.
Daniel A. Knopf, Markus Ammann, Thomas Berkemeier, Ulrich Pöschl, and Manabu Shiraiwa
Atmos. Chem. Phys., 24, 3445–3528, https://doi.org/10.5194/acp-24-3445-2024, https://doi.org/10.5194/acp-24-3445-2024, 2024
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The initial step of interfacial and multiphase chemical processes involves adsorption and desorption of gas species. This study demonstrates the role of desorption energy governing the residence time of the gas species at the environmental interface. A parameterization is formulated that enables the prediction of desorption energy based on the molecular weight, polarizability, and oxygen-to-carbon ratio of the desorbing chemical species. Its application to gas–particle interactions is discussed.
Feng Jiang, Kyla Siemens, Claudia Linke, Yanxia Li, Yiwei Gong, Thomas Leisner, Alexander Laskin, and Harald Saathoff
Atmos. Chem. Phys., 24, 2639–2649, https://doi.org/10.5194/acp-24-2639-2024, https://doi.org/10.5194/acp-24-2639-2024, 2024
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We investigated the optical properties, chemical composition, and formation mechanisms of secondary organic aerosol (SOA) and brown carbon (BrC) from the oxidation of indole with and without NO2 in the Aerosol Interaction and Dynamics in the Atmosphere (AIDA) simulation chamber. This work is one of the very few to link the optical properties and chemical composition of indole SOA with and without NO2 by simulation chamber experiments.
Evangelia Kostenidou, Baptiste Marques, Brice Temime-Roussel, Yao Liu, Boris Vansevenant, Karine Sartelet, and Barbara D'Anna
Atmos. Chem. Phys., 24, 2705–2729, https://doi.org/10.5194/acp-24-2705-2024, https://doi.org/10.5194/acp-24-2705-2024, 2024
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Secondary organic aerosol (SOA) from gasoline vehicles can be a significant source of particulate matter in urban areas. Here the chemical composition of secondary volatile organic compounds and SOA produced by photo-oxidation of Euro 5 gasoline vehicle emissions was studied. The volatility of the SOA formed was calculated. Except for the temperature and the concentration of the aerosol, additional parameters may play a role in the gas-to-particle partitioning.
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Patricia Córdoba, Andres Alastuey, Natalia Moreno, Melani Hernández-Chiriboga, Konrad Kandler, Martina Klose, Roger N. Clark, Bethany L. Ehlmann, Rebecca N. Greenberger, Abigail M. Keebler, Phil Brodrick, Robert Green, Paul Ginoux, Xavier Querol, and Carlos Pérez García-Pando
EGUsphere, https://doi.org/10.5194/egusphere-2024-434, https://doi.org/10.5194/egusphere-2024-434, 2024
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In this research, we studied the dust-emitting properties of crusts and aeolian ripples from the Mojave Desert. These properties are key to understand the effect of dust upon climate. We found two different playa lakes according to the groundwater regime which implies differences on crusts cohesion state and its mineralogy, which can affect the dust emission potential and properties. We also compare them with Moroccan Sahara crusts and Icelandic top sediments.
András Hoffer, Aida Meiramova, Ádám Tóth, Beatrix Jancsek-Turóczi, Gyula Kiss, Ágnes Rostási, Erika Andrea Levei, Luminita Marmureanu, Attila Machon, and András Gelencsér
Atmos. Chem. Phys., 24, 1659–1671, https://doi.org/10.5194/acp-24-1659-2024, https://doi.org/10.5194/acp-24-1659-2024, 2024
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Specific tracer compounds identified previously in controlled test burnings of different waste types in the laboratory were detected and quantified in ambient PM10 samples collected in five Hungarian and four Romanian settlements. Back-of-the-envelope calculations based on the relative emission factors of individual tracers suggested that the contribution of solid waste burning particulate emissions to ambient PM10 mass concentrations may be as high as a few percent.
Xiao-San Luo, Weijie Huang, Guofeng Shen, Yuting Pang, Mingwei Tang, Weijun Li, Zhen Zhao, Hanhan Li, Yaqian Wei, Longjiao Xie, and Tariq Mehmood
Atmos. Chem. Phys., 24, 1345–1360, https://doi.org/10.5194/acp-24-1345-2024, https://doi.org/10.5194/acp-24-1345-2024, 2024
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PM2.5 are air pollutants threatening health globally, but they are a mixture of chemical compositions from many sources and result in unequal toxicity. Which composition from which source of PM2.5 as the most hazardous object is a question hindering effective pollution control policy-making. With chemical and toxicity experiments, we found automobile exhaust and coal combustion to be priority emissions with higher toxic compositions for precise air pollution control, ensuring public health.
Matthew B. Goss and Jesse H. Kroll
Atmos. Chem. Phys., 24, 1299–1314, https://doi.org/10.5194/acp-24-1299-2024, https://doi.org/10.5194/acp-24-1299-2024, 2024
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The chemistry driving dimethyl sulfide (DMS) oxidation and subsequent sulfate particle formation in the atmosphere is poorly constrained. We oxidized two related compounds (dimethyl sulfoxide and dimethyl disulfide) in the laboratory under varied NOx conditions and measured the gas- and particle-phase products. These results demonstrate that both the OH addition and OH abstraction pathways for DMS oxidation contribute to particle formation via mechanisms that do not involve the SO2 intermediate.
Ryan J. Patnaude, Kathryn A. Moore, Russell J. Perkins, Thomas C. J. Hill, Paul J. DeMott, and Sonia M. Kreidenweis
Atmos. Chem. Phys., 24, 911–928, https://doi.org/10.5194/acp-24-911-2024, https://doi.org/10.5194/acp-24-911-2024, 2024
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In this study we examined the effect of atmospheric aging on sea spray aerosols (SSAs) to form ice and how newly formed secondary marine aerosols (SMAs) may freeze at cirrus temperatures (< −38 °C). Results show that SSAs freeze at different relative humidities (RHs) depending on the temperature and that the ice-nucleating ability of SSA was not hindered by atmospheric aging. SMAs are shown to freeze at high RHs and are likely inefficient at forming ice at cirrus temperatures.
Bartłomiej Witkowski, Priyanka Jain, Beata Wileńska, and Tomasz Gierczak
Atmos. Chem. Phys., 24, 663–688, https://doi.org/10.5194/acp-24-663-2024, https://doi.org/10.5194/acp-24-663-2024, 2024
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This article reports the results of the kinetic measurements for the aqueous oxidation of the 29 aliphatic alcohols by hydroxyl radical (OH) at different temperatures. The data acquired and the literature data were used to optimize a model for predicting the aqueous OH reactivity of alcohols and carboxylic acids and to estimate the atmospheric lifetimes of five terpenoic alcohols. The kinetic data provided new insights into the mechanism of aqueous oxidation of aliphatic molecules by the OH.
Junting Qiu, Xinlin Shen, Jiangyao Chen, Guiying Li, and Taicheng An
Atmos. Chem. Phys., 24, 155–166, https://doi.org/10.5194/acp-24-155-2024, https://doi.org/10.5194/acp-24-155-2024, 2024
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We studied reactions of secondary ozonides (SOZs) with amines. SOZs formed from ozonolysis of β-caryophyllene and α-humulene are found to be reactive to ethylamine and methylamine. Products from SOZs with various conformations reacting with the same amine had different functional groups. Our findings indicate that interaction of SOZs with amines in the atmosphere is very complicated, which is potentially a hitherto unrecognized source of N-containing compound formation.
Juanjuan Qin, Leiming Zhang, Yuanyuan Qin, Shaoxuan Shi, Jingnan Li, Zhao Shu, Yuwei Gao, Ting Qi, Jihua Tan, and Xinming Wang
EGUsphere, https://doi.org/10.5194/egusphere-2023-2632, https://doi.org/10.5194/egusphere-2023-2632, 2024
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The present research unveiled that acidity dominants, while transition metal ions harmonize, the light absorption properties of HULIS. Cu2+ has obvious quenching effects on HULIS by complexation, hydrogen substitution, or electrostatic adsorption with aromatic structures of HULIS. Such effects are less pronounced from Mn2+, Ni2+, and Zn2+; Cu2+. Oxidized HULIS might contain electron-donating groups, whereas N-containing compounds might contain electron-withdrawing groups.
Lan Ma, Reed Worland, Laura Heinlein, Chrystal Guzman, Wenqing Jiang, Christopher Niedek, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 24, 1–21, https://doi.org/10.5194/acp-24-1-2024, https://doi.org/10.5194/acp-24-1-2024, 2024
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We measured concentrations of three photooxidants – the hydroxyl radical, triplet excited states of organic carbon, and singlet molecular oxygen – in fine particles collected over a year. Concentrations are highest in extracts of fresh biomass burning particles, largely because they have the highest particle concentrations and highest light absorption. When normalized by light absorption, rates of formation for each oxidant are generally similar for the four particle types we observed.
Adolfo González-Romero, Cristina González-Flórez, Agnesh Panta, Jesús Yus-Díez, Cristina Reche, Patricia Córdoba, Natalia Moreno, Andres Alastuey, Konrad Kandler, Martina Klose, Clarissa Baldo, Roger N. Clark, Zongbo Shi, Xavier Querol, and Carlos Pérez García-Pando
Atmos. Chem. Phys., 23, 15815–15834, https://doi.org/10.5194/acp-23-15815-2023, https://doi.org/10.5194/acp-23-15815-2023, 2023
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The effect of dust emitted from desertic surfaces upon climate and ecosystems depends on size and mineralogy, but data from soil mineral atlases of desert soils are scarce. We performed particle-size distribution, mineralogy, and Fe speciation in southern Morocco. Results show coarser particles with high quartz proportion are near the elevated areas, while in depressed areas, sizes are finer, and proportions of clays and nano-Fe oxides are higher. This difference is important for dust modelling.
Victor Lannuque, Barbara D'Anna, Evangelia Kostenidou, Florian Couvidat, Alvaro Martinez-Valiente, Philipp Eichler, Armin Wisthaler, Markus Müller, Brice Temime-Roussel, Richard Valorso, and Karine Sartelet
Atmos. Chem. Phys., 23, 15537–15560, https://doi.org/10.5194/acp-23-15537-2023, https://doi.org/10.5194/acp-23-15537-2023, 2023
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Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from toluene oxidation. In this study, speciation measurements in gaseous and particulate phases were carried out, providing partitioning and volatility data on individual toluene SOA components at different temperatures. A new detailed oxidation mechanism was developed to improve modeled speciation, and effects of different processes involved in gas–particle partitioning at the molecular scale are explored.
Xiaoliang Wang, Hatef Firouzkouhi, Judith C. Chow, John G. Watson, Steven Sai Hang Ho, Warren Carter, and Alexandra S. M. De Vos
Atmos. Chem. Phys., 23, 15375–15393, https://doi.org/10.5194/acp-23-15375-2023, https://doi.org/10.5194/acp-23-15375-2023, 2023
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Open burning of municipal solid waste emits chemicals that are harmful to the environment. This paper reports source profiles and emission factors for PM2.5 species and acidic/alkali gases from laboratory combustion of 10 waste categories (including plastics and biomass) that represent open burning in South Africa. Results will be useful for health and climate impact assessments, speciated emission inventories, source-oriented dispersion models, and receptor-based source apportionment.
Jun Zhang, Kun Li, Tiantian Wang, Erlend Gammelsæter, Rico K. Y. Cheung, Mihnea Surdu, Sophie Bogler, Deepika Bhattu, Dongyu S. Wang, Tianqu Cui, Lu Qi, Houssni Lamkaddam, Imad El Haddad, Jay G. Slowik, Andre S. H. Prevot, and David M. Bell
Atmos. Chem. Phys., 23, 14561–14576, https://doi.org/10.5194/acp-23-14561-2023, https://doi.org/10.5194/acp-23-14561-2023, 2023
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We conducted burning experiments to simulate various types of solid fuel combustion, including residential burning, wildfires, agricultural burning, cow dung, and plastic bag burning. The chemical composition of the particles was characterized using mass spectrometers, and new potential markers for different fuels were identified using statistical analysis. This work improves our understanding of emissions from solid fuel burning and offers support for refined source apportionment.
Hyun Gu Kang, Yanfang Chen, Yoojin Park, Thomas Berkemeier, and Hwajin Kim
Atmos. Chem. Phys., 23, 14307–14323, https://doi.org/10.5194/acp-23-14307-2023, https://doi.org/10.5194/acp-23-14307-2023, 2023
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D5 is an emerging anthropogenic pollutant that is ubiquitous in indoor and urban environments, and the OH oxidation of D5 forms secondary organosiloxane aerosol (SOSiA). Application of a kinetic box model that uses a volatility basis set (VBS) showed that consideration of oxidative aging (aging-VBS) predicts SOSiA formation much better than using a standard-VBS model. Ageing-dependent parameterization is needed to accurately model SOSiA to assess the implications of siloxanes for air quality.
Kai Song, Rongzhi Tang, Jingshun Zhang, Zichao Wan, Yuan Zhang, Kun Hu, Yuanzheng Gong, Daqi Lv, Sihua Lu, Yu Tan, Ruifeng Zhang, Ang Li, Shuyuan Yan, Shichao Yan, Baoming Fan, Wenfei Zhu, Chak K. Chan, Maosheng Yao, and Song Guo
Atmos. Chem. Phys., 23, 13585–13595, https://doi.org/10.5194/acp-23-13585-2023, https://doi.org/10.5194/acp-23-13585-2023, 2023
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Incense burning is common in Asia, posing threats to human health and air quality. However, less is known about its emissions and health risks. Full-volatility organic species from incense-burning smoke are detected and quantified. Intermediate-volatility volatile organic compounds (IVOCs) are crucial organics accounting for 19.2 % of the total emission factors (EFs) and 40.0 % of the secondary organic aerosol (SOA) estimation, highlighting the importance of incorporating IVOCs into SOA models.
Qianqian Gao, Shengqiang Zhu, Kaili Zhou, Jinghao Zhai, Shaodong Chen, Qihuang Wang, Shurong Wang, Jin Han, Xiaohui Lu, Hong Chen, Liwu Zhang, Lin Wang, Zimeng Wang, Xin Yang, Qi Ying, Hongliang Zhang, Jianmin Chen, and Xiaofei Wang
Atmos. Chem. Phys., 23, 13049–13060, https://doi.org/10.5194/acp-23-13049-2023, https://doi.org/10.5194/acp-23-13049-2023, 2023
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Dust is a major source of atmospheric aerosols. Its chemical composition is often assumed to be similar to the parent soil. However, this assumption has not been rigorously verified. Dust aerosols are mainly generated by wind erosion, which may have some chemical selectivity. Mn, Cd and Pb were found to be highly enriched in fine-dust (PM2.5) aerosols. In addition, estimation of heavy metal emissions from dust generation by air quality models may have errors without using proper dust profiles.
Daniel C. O. Thornton, Sarah D. Brooks, Elise K. Wilbourn, Jessica Mirrielees, Alyssa N. Alsante, Gerardo Gold-Bouchot, Andrew Whitesell, and Kiana McFadden
Atmos. Chem. Phys., 23, 12707–12729, https://doi.org/10.5194/acp-23-12707-2023, https://doi.org/10.5194/acp-23-12707-2023, 2023
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A major uncertainty in our understanding of clouds and climate is the sources and properties of the aerosol on which clouds grow. We found that aerosol containing organic matter from fast-growing marine phytoplankton was a source of ice-nucleating particles (INPs). INPs facilitate freezing of ice crystals at warmer temperatures than otherwise possible and therefore change cloud formation and properties. Our results show that ecosystem processes and the properties of sea spray aerosol are linked.
Adam Milsom, Shaojun Qi, Ashmi Mishra, Thomas Berkemeier, Zhenyu Zhang, and Christian Pfrang
Atmos. Chem. Phys., 23, 10835–10843, https://doi.org/10.5194/acp-23-10835-2023, https://doi.org/10.5194/acp-23-10835-2023, 2023
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Aerosols and films are found indoors and outdoors. Our study measures and models reactions of a cooking aerosol proxy with the atmospheric oxidant ozone relying on a low-cost but sensitive technique based on mass changes and film rigidity. We found that film morphology changed and film rigidity increased with evidence of surface crust formation during ozone exposure. Our modelling results demonstrate clear potential to take this robust method to the field for reaction monitoring.
Shan Zhang, Lin Du, Zhaomin Yang, Narcisse Tsona Tchinda, Jianlong Li, and Kun Li
Atmos. Chem. Phys., 23, 10809–10822, https://doi.org/10.5194/acp-23-10809-2023, https://doi.org/10.5194/acp-23-10809-2023, 2023
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In this study, we have investigated the distinct impacts of humidity on the ozonolysis of two structurally different monoterpenes (limonene and Δ3-carene). We found that the molecular structure of precursors can largely influence the SOA formation under high RH by impacting the multi-generation reactions. Our results could advance knowledge on the roles of water content in aerosol formation and inform ongoing research on particle environmental effects and applications in models.
Yangzhihao Zhan, Min Xie, Wei Zhao, Tijian Wang, Da Gao, Pulong Chen, Jun Tian, Kuanguang Zhu, Shu Li, Bingliang Zhuang, Mengmeng Li, Yi Luo, and Runqi Zhao
Atmos. Chem. Phys., 23, 9837–9852, https://doi.org/10.5194/acp-23-9837-2023, https://doi.org/10.5194/acp-23-9837-2023, 2023
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Although the main source contribution of pollution is secondary inorganic aerosols in Nanjing, health risks mainly come from industry sources and vehicle emissions. Therefore, the development of megacities should pay more attention to the health burden of vehicle emissions, coal combustion, and industrial processes. This study provides new insight into assessing the relationship between source apportionment and health risks and can provide valuable insight into air pollution strategies.
Jonathan P. D. Abbatt and A. R. Ravishankara
Atmos. Chem. Phys., 23, 9765–9785, https://doi.org/10.5194/acp-23-9765-2023, https://doi.org/10.5194/acp-23-9765-2023, 2023
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With important climate and air quality impacts, atmospheric multiphase chemistry involves gas interactions with aerosol particles and cloud droplets. We summarize the status of the field and discuss potential directions for future growth. We highlight the importance of a molecular-level understanding of the chemistry, along with atmospheric field studies and modeling, and emphasize the necessity for atmospheric multiphase chemists to interact widely with scientists from neighboring disciplines.
Zhancong Liang, Zhihao Cheng, Ruifeng Zhang, Yiming Qin, and Chak K. Chan
Atmos. Chem. Phys., 23, 9585–9595, https://doi.org/10.5194/acp-23-9585-2023, https://doi.org/10.5194/acp-23-9585-2023, 2023
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In this study, we found that the photolysis of sodium nitrate leads to a much quicker decay of free amino acids (FAAs, with glycine as an example) in the particle phase than ammonium nitrate photolysis, which is likely due to the molecular interactions between FAAs and different nitrate salts. Since sodium nitrate likely co-exists with FAAs in the coarse-mode particles, particulate nitrate photolysis can possibly contribute to a rapid decay of FAAs and affect atmospheric nitrogen cycling.
Julian Resch, Kate Wolfer, Alexandre Barth, and Markus Kalberer
Atmos. Chem. Phys., 23, 9161–9171, https://doi.org/10.5194/acp-23-9161-2023, https://doi.org/10.5194/acp-23-9161-2023, 2023
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Detailed chemical analysis of organic aerosols is necessary to better understand their effects on climate and health. Aerosol samples are often stored for days to months before analysis. We examined the effects of storage conditions (i.e., time, temperature, and aerosol storage on filters or as solvent extracts) on composition and found significant changes in the concentration of individual compounds, indicating that sample storage can strongly affect the detailed chemical particle composition.
Xiaoliang Wang, Hatef Firouzkouhi, Judith C. Chow, John G. Watson, Warren Carter, and Alexandra S. M. De Vos
Atmos. Chem. Phys., 23, 8921–8937, https://doi.org/10.5194/acp-23-8921-2023, https://doi.org/10.5194/acp-23-8921-2023, 2023
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Open burning of household and municipal solid waste is a common practice in developing countries and is a significant source of air pollution. However, few studies have measured emissions from open burning of waste. This study determined gas and particulate emissions from open burning of 10 types of household solid-waste materials. These results can improve emission inventories, air quality management, and assessment of the health and climate effects of open burning of household waste.
Anita M. Avery, Mariam Fawaz, Leah R. Williams, Tami Bond, and Timothy B. Onasch
Atmos. Chem. Phys., 23, 8837–8854, https://doi.org/10.5194/acp-23-8837-2023, https://doi.org/10.5194/acp-23-8837-2023, 2023
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Pyrolysis is the thermal decomposition of fuels like wood which occurs during combustion or as an isolated process. During combustion, some pyrolysis products are emitted directly, while others are oxidized in the combustion process. This work describes the chemical composition of particle-phase pyrolysis products in order to investigate both the uncombusted emissions from wildfires and the fuel that participates in combustion.
Lan Ma, Reed Worland, Wenqing Jiang, Christopher Niedek, Chrystal Guzman, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 23, 8805–8821, https://doi.org/10.5194/acp-23-8805-2023, https://doi.org/10.5194/acp-23-8805-2023, 2023
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Although photooxidants are important in airborne particles, little is known of their concentrations. By measuring oxidants in a series of particle dilutions, we predict their concentrations in aerosol liquid water (ALW). We find •OH concentrations in ALW are on the order of 10−15 M, similar to their cloud/fog values, while oxidizing triplet excited states and singlet molecular oxygen have ALW values of ca. 10−13 M and 10−12 M, respectively, roughly 10–100 times higher than in cloud/fog drops.
Daniel A. Knopf, Peiwen Wang, Benny Wong, Jay M. Tomlin, Daniel P. Veghte, Nurun N. Lata, Swarup China, Alexander Laskin, Ryan C. Moffet, Josephine Y. Aller, Matthew A. Marcus, and Jian Wang
Atmos. Chem. Phys., 23, 8659–8681, https://doi.org/10.5194/acp-23-8659-2023, https://doi.org/10.5194/acp-23-8659-2023, 2023
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Ambient particle populations and associated ice-nucleating particles (INPs)
were examined from particle samples collected on board aircraft in the marine
boundary layer and free troposphere in the eastern North Atlantic during
summer and winter. Chemical imaging shows distinct differences in the
particle populations seasonally and with sampling altitudes, which are
reflected in the INP types. Freezing parameterizations are derived for
implementation in cloud-resolving and climate models.
Dandan Liu, Yun Zhang, Shujun Zhong, Shuang Chen, Qiaorong Xie, Donghuan Zhang, Qiang Zhang, Wei Hu, Junjun Deng, Libin Wu, Chao Ma, Haijie Tong, and Pingqing Fu
Atmos. Chem. Phys., 23, 8383–8402, https://doi.org/10.5194/acp-23-8383-2023, https://doi.org/10.5194/acp-23-8383-2023, 2023
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Based on ultra-high-resolution mass spectrometry analysis, we found that β-pinene oxidation-derived highly oxygenated organic molecules (HOMs) exhibit higher yield at high ozone concentration, while limonene oxidation-derived HOMs exhibit higher yield at moderate ozone concentration. The distinct molecular response of HOMs and low-volatile species in different biogenic secondary organic aerosols to ozone concentrations provides a new clue for more accurate air quality prediction and management.
Mengying Bao, Yan-Lin Zhang, Fang Cao, Yihang Hong, Yu-Chi Lin, Mingyuan Yu, Hongxing Jiang, Zhineng Cheng, Rongshuang Xu, and Xiaoying Yang
Atmos. Chem. Phys., 23, 8305–8324, https://doi.org/10.5194/acp-23-8305-2023, https://doi.org/10.5194/acp-23-8305-2023, 2023
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The interaction between the sources and molecular compositions of humic-like substances (HULIS) at Nanjing, China, was explored. Significant fossil fuel source contributions to HULIS were found in the 14C results from biomass burnng and traffic emissions. Increasing biogenic secondary organic aerosol (SOA) products and anthropogenic aromatic compounds were detected in summer and winter, respectively.
Molly Frauenheim, Jason D. Surratt, Zhenfa Zhang, and Avram Gold
Atmos. Chem. Phys., 23, 7859–7866, https://doi.org/10.5194/acp-23-7859-2023, https://doi.org/10.5194/acp-23-7859-2023, 2023
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We report synthesis of the isoprene-derived photochemical oxidation products trans- and cis-β-epoxydiols in high overall yields from inexpensive, readily available starting compounds. Protection/deprotection steps or time-consuming purification is not required, and the reactions can be scaled up to gram quantities. The procedures provide accessibility of these important compounds to atmospheric chemistry laboratories with only basic capabilities in organic synthesis.
Xiangyun Zhang, Jun Li, Sanyuan Zhu, Junwen Liu, Ping Ding, Shutao Gao, Chongguo Tian, Yingjun Chen, Ping'an Peng, and Gan Zhang
Atmos. Chem. Phys., 23, 7495–7502, https://doi.org/10.5194/acp-23-7495-2023, https://doi.org/10.5194/acp-23-7495-2023, 2023
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The results show that 14C elemental carbon (EC) was not only related to the isolation method but also to the types and proportions of the biomass sources in the sample. The hydropyrolysis (Hypy) method, which can be used to isolate a highly stable portion of ECHypy and avoid charring, is a more effective and stable approach for the matrix-independent 14C quantification of EC in aerosols, and the 13C–ECHypy and non-fossil ECHypy values of SRM1649b were –24.9 ‰ and 11 %, respectively.
Amir Yazdani, Satoshi Takahama, John K. Kodros, Marco Paglione, Mauro Masiol, Stefania Squizzato, Kalliopi Florou, Christos Kaltsonoudis, Spiro D. Jorga, Spyros N. Pandis, and Athanasios Nenes
Atmos. Chem. Phys., 23, 7461–7477, https://doi.org/10.5194/acp-23-7461-2023, https://doi.org/10.5194/acp-23-7461-2023, 2023
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Organic aerosols directly emitted from wood and pellet stove combustion are found to chemically transform (approximately 15 %–35 % by mass) under daytime aging conditions simulated in an environmental chamber. A new marker for lignin-like compounds is found to degrade at a different rate than previously identified biomass burning markers and can potentially provide indication of aging time in ambient samples.
Hao Luo, Luc Vereecken, Hongru Shen, Sungah Kang, Iida Pullinen, Mattias Hallquist, Hendrik Fuchs, Andreas Wahner, Astrid Kiendler-Scharr, Thomas F. Mentel, and Defeng Zhao
Atmos. Chem. Phys., 23, 7297–7319, https://doi.org/10.5194/acp-23-7297-2023, https://doi.org/10.5194/acp-23-7297-2023, 2023
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Oxidation of limonene, an element emitted by trees and chemical products, by OH, a daytime oxidant, forms many highly oxygenated organic molecules (HOMs), including C10-20 compounds. HOMs play an important role in new particle formation and growth. HOM formation can be explained by the chemistry of peroxy radicals. We found that a minor branching ratio initial pathway plays an unexpected, significant role. Considering this pathway enables accurate simulations of HOMs and other concentrations.
Heather L. Runberg and Brian J. Majestic
Atmos. Chem. Phys., 23, 7213–7223, https://doi.org/10.5194/acp-23-7213-2023, https://doi.org/10.5194/acp-23-7213-2023, 2023
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Environmentally persistent free radicals (EPFRs) are an emerging pollutant found in soot particles. Understanding how these change as they move through the atmosphere is important to human health. Here, soot was generated in the laboratory and exposed to simulated sunlight. The concentrations and characteristics of EPFRs in the soot were measured and found to be unchanged. However, it was also found that the ability of soot to form hydroxyl radicals was stronger for fresh soot.
Wenqing Jiang, Christopher Niedek, Cort Anastasio, and Qi Zhang
Atmos. Chem. Phys., 23, 7103–7120, https://doi.org/10.5194/acp-23-7103-2023, https://doi.org/10.5194/acp-23-7103-2023, 2023
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We studied how aqueous-phase secondary organic aerosol (aqSOA) form and evolve from a phenolic carbonyl commonly present in biomass burning smoke. The composition and optical properties of the aqSOA are significantly affected by photochemical reactions and are dependent on the oxidants' concentration and identity in water. During photoaging, the aqSOA initially becomes darker, but prolonged aging leads to the formation of volatile products, resulting in significant mass loss and photobleaching.
Lucía Caudillo, Mihnea Surdu, Brandon Lopez, Mingyi Wang, Markus Thoma, Steffen Bräkling, Angela Buchholz, Mario Simon, Andrea C. Wagner, Tatjana Müller, Manuel Granzin, Martin Heinritzi, Antonio Amorim, David M. Bell, Zoé Brasseur, Lubna Dada, Jonathan Duplissy, Henning Finkenzeller, Xu-Cheng He, Houssni Lamkaddam, Naser G. A. Mahfouz, Vladimir Makhmutov, Hanna E. Manninen, Guillaume Marie, Ruby Marten, Roy L. Mauldin, Bernhard Mentler, Antti Onnela, Tuukka Petäjä, Joschka Pfeifer, Maxim Philippov, Ana A. Piedehierro, Birte Rörup, Wiebke Scholz, Jiali Shen, Dominik Stolzenburg, Christian Tauber, Ping Tian, António Tomé, Nsikanabasi Silas Umo, Dongyu S. Wang, Yonghong Wang, Stefan K. Weber, André Welti, Marcel Zauner-Wieczorek, Urs Baltensperger, Richard C. Flagan, Armin Hansel, Jasper Kirkby, Markku Kulmala, Katrianne Lehtipalo, Douglas R. Worsnop, Imad El Haddad, Neil M. Donahue, Alexander L. Vogel, Andreas Kürten, and Joachim Curtius
Atmos. Chem. Phys., 23, 6613–6631, https://doi.org/10.5194/acp-23-6613-2023, https://doi.org/10.5194/acp-23-6613-2023, 2023
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In this study, we present an intercomparison of four different techniques for measuring the chemical composition of nanoparticles. The intercomparison was performed based on the observed chemical composition, calculated volatility, and analysis of the thermograms. We found that the methods generally agree on the most important compounds that are found in the nanoparticles. However, they do see different parts of the organic spectrum. We suggest potential explanations for these differences.
Ruifeng Zhang and Chak Keung Chan
Atmos. Chem. Phys., 23, 6113–6126, https://doi.org/10.5194/acp-23-6113-2023, https://doi.org/10.5194/acp-23-6113-2023, 2023
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Research into sulfate and nitrate formation from co-uptake of NO2 and SO2, especially under irradiation, is rare. We studied the co-uptake of NO2 and SO2 by NaCl droplets under various conditions, including irradiation and dark, and RHs, using Raman spectroscopy flow cell and kinetic model simulation. Significant nitrate formation from NO2 hydrolysis can be photolyzed to generate OH radicals that can further react with chloride to produce reactive chlorine species and promote sulfate formation.
Shinnosuke Ishizuka, Oliver Reich, Grégory David, and Ruth Signorell
Atmos. Chem. Phys., 23, 5393–5402, https://doi.org/10.5194/acp-23-5393-2023, https://doi.org/10.5194/acp-23-5393-2023, 2023
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Photosensitizers play an important role in the photochemistry of atmospheric aerosols. Our study provides evidence that mesoscopic glycine clusters forming in aqueous droplets act as unconventional photosensitizers in the visible light spectrum. We observed the influence of these photoactive molecular aggregates in single optically trapped aqueous droplets. Such mesoscopic photosensitizers might be more important for aerosol photochemistry than previously anticipated.
Liyuan Zhou, Zhancong Liang, Beatrix Rosette Go Mabato, Rosemarie Ann Infante Cuevas, Rongzhi Tang, Mei Li, Chunlei Cheng, and Chak K. Chan
Atmos. Chem. Phys., 23, 5251–5261, https://doi.org/10.5194/acp-23-5251-2023, https://doi.org/10.5194/acp-23-5251-2023, 2023
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This study reveals the sulfate formation in photosensitized particles from biomass burning under UV and SO2, of which the relative atmospheric importance in sulfate production was qualitatively compared to nitrate photolysis. On the basis of single-particle aerosol mass spectrometry measurements, the number percentage of sulfate-containing particles and relative peak area of sulfate in single-particle spectra exhibited a descending order of 3,4-dimethoxybenzaldehyde > vanillin > syringaldehyde.
Mohammed Jaoui, Kenneth S. Docherty, Michael Lewandowski, and Tadeusz E. Kleindienst
Atmos. Chem. Phys., 23, 4637–4661, https://doi.org/10.5194/acp-23-4637-2023, https://doi.org/10.5194/acp-23-4637-2023, 2023
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VCPs are a class of chemicals widely used in industrial and consumer products (e.g., coatings, adhesives, inks, personal care products) and are an important component of total VOCs in urban atmospheres. This study provides SOA yields and detailed chemical analysis of the gas- and aerosol-phase products of the photooxidation of one of these VCPs, benzyl alcohol. These results will allow better links between characterized sources and their resulting criteria for pollutant formation.
Cited articles
Ahrens, L., Harner, T., Shoeib, M., Lane, D. A., and Murphy, J. G.: Improved
characterization of gas–particle partitioning for per- and polyfluoroalkyl
substances in the atmosphere using annular diffusion denuder samplers,
Environ. Sci. Technol., 46, 7199–7206, https://doi.org/10.1021/es300898s,
2012.
Anenberg, S. C., Balakrishnan, K., Jetter, J., Masera, O., Mehta, S., Moss,
J., and Ramanathan, V.: Cleaner cooking solutions to achieve health,
climate, and economic cobenefits, Environ. Sci. Technol., 47,
3944–3952, https://doi.org/10.1021/es304942e, 2013.
Aunan, K., Berntsen, T. K., Myhre, G., Rypdal, K., Streets, D. G., Woo,
J.-H., and Smith, K. R.: Radiative forcing from household fuel burning in
Asia, Atmos. Environ., 43, 5674–5681,
https://doi.org/10.1016/j.atmosenv.2009.07.053, 2009.
Bond, T. C., Streets, D. G., Yarber, K. F., Nelson, S. M., Woo, J.-H., and
Klimont, Z.: A technology-based global inventory of black and organic carbon
emissions from combustion, J. Geophys. Res.-Atmos.,
109, D14203, https://doi.org/10.1029/2003jd003697, 2004.
Bonjour, S., Adair-Rohani, H., Wolf, J., Bruce Nigel, G., Mehta, S.,
Prüss-Ustün, A., Lahiff, M., Rehfuess Eva, A., Mishra, V., and Smith
Kirk, R.: Solid fuel use for household cooking: Country and regional
estimates for 1980–2010, Environ. Health Persp., 121, 784–790,
https://doi.org/10.1289/ehp.1205987, 2013.
Cao, G., Zhang, X., and Zheng, F.: Inventory of black carbon and organic
carbon emissions from China, Atmos. Environ., 40, 6516–6527,
https://doi.org/10.1016/j.atmosenv.2006.05.070, 2006.
Chen, Y. and Bond, T. C.: Light absorption by organic carbon from wood combustion, Atmos. Chem. Phys., 10, 1773–1787, https://doi.org/10.5194/acp-10-1773-2010, 2010.
Chen, Y., Sheng, G., Bi, X., Feng, Y., Mai, B., and Fu, J.: Emission factors
for carbonaceous particles and polycyclic aromatic hydrocarbons from
residential coal combustion in China, Environ. Sci. Technol.,
39, 1861–1867, https://doi.org/10.1021/es0493650, 2005.
Claeys, M., Vermeylen, R., Yasmeen, F., Gómez-González, Y., Chi, X.,
Maenhaut, W., Mészáros, T., and Salma, I.: Chemical characterisation
of humic-like substances from urban, rural and tropical biomass burning
environments using liquid chromatography with UV/vis photodiode array
detection and electrospray ionisation mass spectrometry, Environ.
Chem., 9, 273–284, https://doi.org/10.1071/EN11163, 2012.
De Haan, D. O., Hawkins, L. N., Welsh, H. G., Pednekar, R., Casar, J. R.,
Pennington, E. A., de Loera, A., Jimenez, N. G., Symons, M. A., Zauscher,
M., Pajunoja, A., Caponi, L., Cazaunau, M., Formenti, P., Gratien, A.,
Pangui, E., and Doussin, J.-F.: Brown carbon production in ammonium- or
amine-containing aerosol particles by reactive uptake of methylglyoxal and
photolytic cloud cycling, Environ. Sci. Technol., 51,
7458–7466, https://doi.org/10.1021/acs.est.7b00159, 2017.
Desyaterik, Y., Sun, Y., Shen, X., Lee, T., Wang, X., Wang, T., and Collett,
J. L.: Speciation of “brown” carbon in cloud water impacted by
agricultural biomass burning in eastern China, J. Geophys. Res.-Atmos., 118, 7389–7399, https://doi.org/10.1002/jgrd.50561, 2013.
Di Lorenzo, R. A. and Young, C. J.: Size separation method for absorption
characterization in brown carbon: Application to an aged biomass burning
sample, Geophys. Res. Lett., 43, 458–465, https://doi.org/10.1002/2015gl066954,
2016.
Di Lorenzo, R. A., Washenfelder, R. A., Attwood, A. R., Guo, H., Xu, L., Ng,
N. L., Weber, R. J., Baumann, K., Edgerton, E., and Young, C. J.:
Molecular-size-separated brown carbon absorption for biomass-burning aerosol
at multiple field sites, Environ. Sci. Technol., 51,
3128–3137, https://doi.org/10.1021/acs.est.6b06160, 2017.
Ding, Y., Pang, Y., and Eatough, D. J.: High-volume diffusion denuder
sampler for the routine monitoring of fine particulate matter: I. Design and
optimization of the PC-BOSS, Aerosol Sci. Technol., 36, 369–382,
https://doi.org/10.1080/027868202753571205, 2002.
Donahue, N. M., Epstein, S. A., Pandis, S. N., and Robinson, A. L.: A two-dimensional volatility basis set: 1. organic-aerosol mixing thermodynamics, Atmos. Chem. Phys., 11, 3303–3318, https://doi.org/10.5194/acp-11-3303-2011, 2011.
Feng, Y., Ramanathan, V., and Kotamarthi, V. R.: Brown carbon: a significant atmospheric absorber of solar radiation?, Atmos. Chem. Phys., 13, 8607–8621, https://doi.org/10.5194/acp-13-8607-2013, 2013.
Fleming, L. T., Lin, P., Laskin, A., Laskin, J., Weltman, R., Edwards, R. D., Arora, N. K., Yadav, A., Meinardi, S., Blake, D. R., Pillarisetti, A., Smith, K. R., and Nizkorodov, S. A.: Molecular composition of particulate matter emissions from dung and brushwood burning household cookstoves in Haryana, India, Atmos. Chem. Phys., 18, 2461–2480, https://doi.org/10.5194/acp-18-2461-2018, 2018.
Forrister, H., Liu, J., Scheuer, E., Dibb, J., Ziemba, L., Thornhill, K. L.,
Anderson, B., Diskin, G., Perring, A. E., Schwarz, J. P., Campuzano-Jost,
P., Day, D. A., Palm, B. B., Jimenez, J. L., Nenes, A., and Weber, R. J.:
Evolution of brown carbon in wildfire plumes, Geophys. Res. Lett.,
42, 4623–4630, https://doi.org/10.1002/2015gl063897, 2015.
Gilman, J. B., Lerner, B. M., Kuster, W. C., Goldan, P. D., Warneke, C., Veres, P. R., Roberts, J. M., de Gouw, J. A., Burling, I. R., and Yokelson, R. J.: Biomass burning emissions and potential air quality impacts of volatile organic compounds and other trace gases from fuels common in the US, Atmos. Chem. Phys., 15, 13915–13938, https://doi.org/10.5194/acp-15-13915-2015, 2015.
Glarborg, P., Jensen, A., and Johnsson, J. E.: Fuel nitrogen conversion in
solid fuel fired systems, Prog. Energ. Combust., 29,
89–113, 2003.
Global Alliance for Clean Cookstoves: Water Boiling Test (WBT) 4.2.3,
Released 19 March 2014, available at:
http://cleancookstoves.org/technology-and-fuels/testing/protocols.html
(last access: July 2017), 2014.
Harrison, M. A., Barra, S., Borghesi, D., Vione, D., Arsene, C., and Olariu,
R. I.: Nitrated phenols in the atmosphere: a review, Atmos. Environ., 39, 231–248, 2005.
Hecobian, A., Zhang, X., Zheng, M., Frank, N., Edgerton, E. S., and Weber, R. J.: Water-Soluble Organic Aerosol material and the light-absorption characteristics of aqueous extracts measured over the Southeastern United States, Atmos. Chem. Phys., 10, 5965–5977, https://doi.org/10.5194/acp-10-5965-2010, 2010.
Iinuma, Y., Böge, O., Gräfe, R., and Herrmann, H.:
Methyl-nitrocatechols: Atmospheric tracer compounds for biomass burning
secondary organic aerosols, Environ. Sci. Technol., 44,
8453–8459, https://doi.org/10.1021/es102938a, 2010.
International Agency for Research on Cancer: Some non-heterocyclic
polycyclic aromatic hydrocarbons and some related exposures (Vol. 92), IARC
Press, International Agency for Research on Cancer, Lyon, France, 2010.
Jaeckels, J. M., Bae, M. S., and Schauer, J. J.: Positive matrix
factorization (PMF) analysis of molecular marker measurements to quantify
the sources of organic aerosols, Environ. Sci. Technol., 41,
5763–5769, https://doi.org/10.1021/es062536b, 2007.
Jetter, J. J. and Kariher, P.: Solid-fuel household cook stoves:
Characterization of performance and emissions, Biomass and Bioenergy, 33,
294–305, https://doi.org/10.1016/j.biombioe.2008.05.014, 2009.
Jetter, J., Zhao, Y., Smith, K. R., Khan, B., Yelverton, T., DeCarlo, P.,
and Hays, M. D.: Pollutant emissions and energy efficiency under controlled
conditions for household biomass cookstoves and implications for metrics
useful in setting international test standards, Environ. Sci. Technol., 46, 10827–10834, https://doi.org/10.1021/es301693f, 2012.
Kaal, J., Martínez Cortizas, A., and Nierop, K. G. J.: Characterisation
of aged charcoal using a coil probe pyrolysis-GC/MS method optimised for
black carbon, J. Anal. Appl. Pyrol., 85, 408–416,
https://doi.org/10.1016/j.jaap.2008.11.007, 2009.
Kim, K.-H., Jahan, S. A., Kabir, E., and Brown, R. J. C.: A review of
airborne polycyclic aromatic hydrocarbons (PAHs) and their human health
effects, Environ. Int., 60, 71–80,
https://doi.org/10.1016/j.envint.2013.07.019, 2013.
Kim Oanh, N. T., Bætz Reutergårdh, L., and Dung, N. T.: Emission of
polycyclic aromatic hydrocarbons and particulate matter from domestic
combustion of selected fuels, Environ. Sci. Technol., 33,
2703–2709, https://doi.org/10.1021/es980853f, 1999.
Kirchstetter, T. W., Corrigan, C. E., and Novakov, T.: Laboratory and field
investigation of the adsorption of gaseous organic compounds onto quartz
filters, Atmos. Environ., 35, 1663–1671,
https://doi.org/10.1016/S1352-2310(00)00448-9, 2001.
Klimont, Z., Cofala, J., Xing, J., Wei, W., Zhang, C., Wang, S., Kejun, J.,
Bhandari, P., Mathur, R., Purohit, P., Rafaj, P., Chambers, A., Amann, M.,
and Hao, J.: Projections of SO2, NOx and carbonaceous aerosols emissions in
Asia, Tellus B, 61, 602–617, https://doi.org/10.1111/j.1600-0889.2009.00428.x, 2009.
Kwamena, N.-O. and Abbatt, J.: Heterogeneous nitration reactions of
polycyclic aromatic hydrocarbons and n-hexane soot by exposure to
NO3/NO2/N2O5, Atmos. Environ., 42, 8309–8314, 2008.
Lacey, F. and Henze, D.: Global climate impacts of country-level primary
carbonaceous aerosol from solid-fuel cookstove emissions, Environ.
Res. Lett., 10, 114003, https://doi.org/10.1088/1748-9326/10/11/114003, 2015.
Lei, Y., Zhang, Q., He, K. B., and Streets, D. G.: Primary anthropogenic aerosol emission trends for China, 1990–2005, Atmos. Chem. Phys., 11, 931–954, https://doi.org/10.5194/acp-11-931-2011, 2011.
Li, Q., Jacob, D. J., Bey, I., Yantosca, R. M., Zhao, Y., Kondo, Y., and
Notholt, J.: Atmospheric hydrogen cyanide (HCN): Biomass burning source,
ocean sink?, Geophys. Res. Lett., 27, 357–360,
https://doi.org/10.1029/1999gl010935, 2000.
Lin, P., Liu, J. M., Shilling, J. E., Kathmann, S. M., Laskin, J., and
Laskin, A.: Molecular characterization of brown carbon (BrC) chromophores in
secondary organic aerosol generated from photo-oxidation of toluene,
Phys. Chem. Chem. Phys., 17, 23312–23325, https://doi.org/10.1039/c5cp02563j,
2015.
Lin, P., Aiona, P. K., Li, Y., Shiraiwa, M., Laskin, J., Nizkorodov, S. A.,
and Laskin, A.: Molecular characterization of brown carbon in biomass
burning aerosol particles, Environ. Sci. Technol., 50,
11815–11824, https://doi.org/10.1021/acs.est.6b03024, 2016.
Lin, P., Bluvshtein, N., Rudich, Y., Nizkorodov, S. A., Laskin, J., and
Laskin, A.: Molecular chemistry of atmospheric brown carbon inferred from a
nationwide biomass burning event, Environ. Sci. Technol., 51,
11561–11570, https://doi.org/10.1021/acs.est.7b02276, 2017.
Liu, J., Bergin, M., Guo, H., King, L., Kotra, N., Edgerton, E., and Weber, R. J.: Size-resolved measurements of brown carbon in water and methanol extracts and estimates of their contribution to ambient fine-particle light absorption, Atmos. Chem. Phys., 13, 12389–12404, https://doi.org/10.5194/acp-13-12389-2013, 2013.
Lu, C., Wang, X., Li, R., Gu, R., Zhang, Y., Li, W., Gao, R., Chen, B., Xue,
L., and Wang, W.: Emissions of fine particulate nitrated phenols from
residential coal combustion in China, Atmos. Environ., 203, 10–17,
https://doi.org/10.1016/j.atmosenv.2019.01.047, 2019.
Lu, J. W., Flores, J. M., Lavi, A., Abo-Riziq, A., and Rudich, Y.: Changes
in the optical properties of benzo[a]pyrene-coated aerosols upon
heterogeneous reactions with NO2 and NO3, Phys. Chem. Chem.
Phys., 13, 6484–6492, https://doi.org/10.1039/C0CP02114H, 2011.
Lu, Z., Streets, D. G., Winijkul, E., Yan, F., Chen, Y., Bond, T. C., Feng,
Y., Dubey, M. K., Liu, S., Pinto, J. P., and Carmichael, G. R.: Light
absorption properties and radiative effects of primary organic aerosol
emissions, Environ. Sci. Technol., 49, 4868–4877,
https://doi.org/10.1021/acs.est.5b00211, 2015.
McMeeking, G., Fortner, E., Onasch, T., Taylor, J., Flynn, M., Coe, H., and
Kreidenweis, S.: Impacts of nonrefractory material on light absorption by
aerosols emitted from biomass burning, J. Geophys. Res.-Atmos., 119, 12272–12286, 2014.
Mohr, C., Lopez-Hilfiker, F. D., Zotter, P., Prévôt, A. S. H., Xu,
L., Ng, N. L., Herndon, S. C., Williams, L. R., Franklin, J. P., Zahniser,
M. S., Worsnop, D. R., Knighton, W. B., Aiken, A. C., Gorkowski, K. J.,
Dubey, M. K., Allan, J. D., and Thornton, J. A.: Contribution of nitrated
phenols to wood burning brown carbon light absorption in Detling, United
Kingdom during winter time, Environ. Sci. Technol., 47,
6316–6324, https://doi.org/10.1021/es400683v, 2013.
Nakayama, T., Matsumi, Y., Sato, K., Imamura, T., Yamazaki, A., and
Uchiyama, A.: Laboratory studies on optical properties of secondary organic
aerosols generated during the photooxidation of toluene and the ozonolysis
of α-pinene, J. Geophys. Res.-Atmos., 115, D24204, https://doi.org/10.1029/2010jd014387, 2010.
Park, R. J., Kim, M. J., Jeong, J. I., Youn, D., and Kim, S.: A contribution
of brown carbon aerosol to the aerosol light absorption and its radiative
forcing in East Asia, Atmos. Environ., 44, 1414–1421,
https://doi.org/10.1016/j.atmosenv.2010.01.042, 2010.
Peters, A. J., Lane, D. A., Gundel, L. A., Northcott, G. L., and Jones, K.
C.: A comparison of high volume and diffusion denuder samplers for measuring
semivolatile organic compounds in the atmosphere, Environ. Sci. Technol., 34, 5001–5006, https://doi.org/10.1021/es000056t, 2000.
Pokhrel, R. P., Wagner, N. L., Langridge, J. M., Lack, D. A., Jayarathne, T., Stone, E. A., Stockwell, C. E., Yokelson, R. J., and Murphy, S. M.: Parameterization of single-scattering albedo (SSA) and absorption Ångström exponent (AAE) with EC∕OC for aerosol emissions from biomass burning, Atmos. Chem. Phys., 16, 9549–9561, https://doi.org/10.5194/acp-16-9549-2016, 2016.
Ravindra, K., Sokhi, R., and Van Grieken, R.: Atmospheric polycyclic
aromatic hydrocarbons: Source attribution, emission factors and regulation,
Atmos. Environ., 42, 2895–2921,
https://doi.org/10.1016/j.atmosenv.2007.12.010, 2008.
Reff, A., Bhave, P. V., Simon, H., Pace, T. G., Pouliot, G. A., Mobley, J.
D., and Houyoux, M.: Emissions inventory of PM2.5 trace elements across the
United States, Environ. Sci. Technol., 43, 5790–5796,
https://doi.org/10.1021/es802930x, 2009.
Riddle, S. G., Jakober, C. A., Robert, M. A., Cahill, T. M., Charles, M. J.,
and Kleeman, M. J.: Large PAHs detected in fine particulate matter emitted
from light-duty gasoline vehicles, Atmos. Environ., 41, 8658–8668,
https://doi.org/10.1016/j.atmosenv.2007.07.023, 2007.
Saleh, R., Robinson, E. S., Tkacik, D. S., Ahern, A. T., Liu, S., Aiken, A.
C., Sullivan, R. C., Presto, A. A., Dubey, M. K., Yokelson, R. J., Donahue,
N. M., and Robinson, A. L.: Brownness of organics in aerosols from biomass
burning linked to their black carbon content, Nat. Geosci., 7, 647–650,
https://doi.org/10.1038/ngeo2220, 2014.
Samburova, V., Connolly, J., Gyawali, M., Yatavelli, R. L. N., Watts, A. C.,
Chakrabarty, R. K., Zielinska, B., Moosmüller, H., and Khlystov, A.:
Polycyclic aromatic hydrocarbons in biomass-burning emissions and their
contribution to light absorption and aerosol toxicity, Sci. Total
Environ., 568, 391–401, https://doi.org/10.1016/j.scitotenv.2016.06.026,
2016.
Schneider, J., Bürger, V., and Arnold, F.: Methyl cyanide and hydrogen
cyanide measurements in the lower stratosphere: Implications for methyl
cyanide sources and sinks, J. Geophys. Res.-Atmos.,
102, 25501–25506, https://doi.org/10.1029/97jd02364, 1997.
Shen, G., Tao, S., Wei, S., Zhang, Y., Wang, R., Wang, B., Li, W., Shen, H.,
Huang, Y., Chen, Y., Chen, H., Yang, Y., Wang, W., Wei, W., Wang, X., Liu,
W., Wang, X., and Simonich, S. L. M.: Reductions in Emissions of
Carbonaceous particulate matter and polycyclic aromatic hydrocarbons from
combustion of biomass pellets in comparison with raw fuel burning,
Environ. Sci. Technol., 46, 6409–6416, https://doi.org/10.1021/es300369d,
2012.
Shrivastava, M. K., Subramanian, R., Rogge, W. F., and Robinson, A. L.:
Sources of organic aerosol: Positive matrix factorization of molecular
marker data and comparison of results from different source apportionment
models, Atmos. Environ., 41, 9353–9369,
https://doi.org/10.1016/j.atmosenv.2007.09.016, 2007.
Simoneit, B. R.: Biomass burning – a review of organic tracers for smoke
from incomplete combustion, Appl. Geochem., 17, 129–162, 2002.
Simoneit, B. R., Rogge, W., Mazurek, M., Standley, L., Hildemann, L., and
Cass, G.: Lignin pyrolysis products, lignans, and resin acids as specific
tracers of plant classes in emissions from biomass combustion, Environ. Sci. Technol., 27, 2533–2541, 1993.
Smith, K. R., Bruce, N., Balakrishnan, K., Adair-Rohani, H., Balmes, J.,
Chafe, Z., Dherani, M., Hosgood, H. D., Mehta, S., Pope, D., and Rehfuess,
E.: Millions dead: How do we know and what does it mean? Methods used in the
comparative risk assessment of household air pollution, Annu. Rev.
Publ. Health, 35, 185–206, https://doi.org/10.1146/annurev-publhealth-032013-182356, 2014.
Subramanian, R., Khlystov, A. Y., Cabada, J. C., and Robinson, A. L.:
Positive and negative artifacts in particulate organic carbon measurements
with denuded and undenuded sampler configurations special issue of Aerosol
Science and Technology on findings from the fine particulate matter
supersites program, Aerosol Sci. Technol., 38, 27–48,
https://doi.org/10.1080/02786820390229354, 2004.
Sun, J., Zhi, G., Hitzenberger, R., Chen, Y., Tian, C., Zhang, Y., Feng, Y., Cheng, M., Zhang, Y., Cai, J., Chen, F., Qiu, Y., Jiang, Z., Li, J., Zhang, G., and Mo, Y.: Emission factors and light absorption properties of brown carbon from household coal combustion in China, Atmos. Chem. Phys., 17, 4769–4780, https://doi.org/10.5194/acp-17-4769-2017, 2017.
Teich, M., van Pinxteren, D., Wang, M., Kecorius, S., Wang, Z., Müller, T., Močnik, G., and Herrmann, H.: Contributions of nitrated aromatic compounds to the light absorption of water-soluble and particulate brown carbon in different atmospheric environments in Germany and China, Atmos. Chem. Phys., 17, 1653–1672, https://doi.org/10.5194/acp-17-1653-2017, 2017.
Tuccella, P., Curci, G., Pitari, G., Lee, S., and Jo, D. S.: Direct
radiative effect of absorbing aerosols: sensitivity to mixing state, brown
carbon and soil dust refractive index and shape, J. Geophys. Res.-Atmos., 125, e2019JD030967, https://doi.org/10.1029/2019JD030967, 2020.
Turpin, B. J. and Lim, H.-J.: Species contributions to PM2.5 mass
concentrations: Revisiting common assumptions for estimating organic mass,
Aerosol Sci. Technol., 35, 602–610, https://doi.org/10.1080/02786820119445, 2001.
Wang, X., Heald, C. L., Ridley, D. A., Schwarz, J. P., Spackman, J. R., Perring, A. E., Coe, H., Liu, D., and Clarke, A. D.: Exploiting simultaneous observational constraints on mass and absorption to estimate the global direct radiative forcing of black carbon and brown carbon, Atmos. Chem. Phys., 14, 10989–11010, https://doi.org/10.5194/acp-14-10989-2014, 2014.
Wathore, R., Mortimer, K., and Grieshop, A. P.: In-use emissions and
estimated impacts of traditional, natural- and forced-draft cookstoves in
rural Malawi, Environ. Sci. Technol., 51, 1929–1938,
https://doi.org/10.1021/acs.est.6b05557, 2017.
Watson, J. G., Chow, J. C., Chen, L. W. A., and Frank, N. H.: Methods to
assess carbonaceous aerosol sampling artifacts for IMPROVE and other
long-term networks, J. Air Waste Manag. Assoc.,
59, 898–911, https://doi.org/10.3155/1047-3289.59.8.898, 2009.
Xie, M., Hannigan, M. P., Dutton, S. J., Milford, J. B., Hemann, J. G.,
Miller, S. L., Schauer, J. J., Peel, J. L., and Vedal, S.: Positive matrix
factorization of PM2.5: Comparison and implications of using different
speciation data sets, Environ. Sci. Technol., 46,
11962–11970, https://doi.org/10.1021/es302358g, 2012.
Xie, M., Piedrahita, R., Dutton, S. J., Milford, J. B., Hemann, J. G., Peel,
J. L., Miller, S. L., Kim, S.-Y., Vedal, S., Sheppard, L., and Hannigan, M.
P.: Positive matrix factorization of a 32-month series of daily PM2.5
speciation data with incorporation of temperature stratification,
Atmos. Environ., 65, 11–20,
https://doi.org/10.1016/j.atmosenv.2012.09.034, 2013.
Xie, M., Hannigan, M. P., and Barsanti, K. C.: Gas/particle partitioning of
n-alkanes, PAHs and oxygenated PAHs in urban Denver, Atmos. Environ., 95, 355–362, https://doi.org/10.1016/j.atmosenv.2014.06.056,
2014.
Xie, M., Chen, X., Hays, M. D., Lewandowski, M., Offenberg, J., Kleindienst,
T. E., and Holder, A. L.: Light absorption of secondary organic aerosol:
Composition and contribution of nitroaromatic compounds, Environ. Sci. Technol., 51, 11607–11616, https://doi.org/10.1021/acs.est.7b03263, 2017a.
Xie, M., Hays, M. D., and Holder, A. L.: Light-absorbing organic carbon from
prescribed and laboratory biomass burning and gasoline vehicle emissions,
Sci. Rep.-UK, 7, 7318, https://doi.org/10.1038/s41598-017-06981-8, 2017b.
Xie, M., Shen, G., Holder, A. L., Hays, M. D., and Jetter, J. J.: Light
absorption of organic carbon emitted from burning wood, charcoal, and
kerosene in household cookstoves, Environ. Pollut., 240, 60–67,
https://doi.org/10.1016/j.envpol.2018.04.085, 2018.
Xie, M., Chen, X., Hays, M. D., and Holder, A. L.: Composition and light absorption of N-containing aromatic compounds in organic aerosols from laboratory biomass burning, Atmos. Chem. Phys., 19, 2899–2915, https://doi.org/10.5194/acp-19-2899-2019, 2019.
Xie, M., Zhao, Z., Holder, A., Hays, M., Chen, X., Shen, G., Jetter, J., Champion, W., and Wang, Q. G.: Replication Data for: Chemical composition, structures, and light absorption of N-containing aromatic compounds emitted from burning wood and charcoal in household cookstoves, V1 ed., Harvard Dataverse, https://doi.org/10.7910/DVN/VERFPS, 2020.
Yang, M., Howell, S. G., Zhuang, J., and Huebert, B. J.: Attribution of aerosol light absorption to black carbon, brown carbon, and dust in China – interpretations of atmospheric measurements during EAST-AIRE, Atmos. Chem. Phys., 9, 2035–2050, https://doi.org/10.5194/acp-9-2035-2009, 2009.
Zhang, X., Lin, Y.-H., Surratt, J. D., and Weber, R. J.: Sources,
composition and absorption Ångström exponent of light-absorbing
organic components in aerosol extracts from the Los Angeles basin,
Environ. Sci. Technol., 47, 3685–3693, https://doi.org/10.1021/es305047b,
2013.
Short summary
This study investigated the composition, structures, and light absorption of N-containing aromatic compounds (NACs) in PM2.5 emitted from burning red oak and charcoal in a variety of cookstoves. The results suggest that the identified NACs might have substantial fractions remaining in the gas phase. In comparison to other sources, cookstove emissions from red oak or charcoal fuels did not exhibit unique NAC structural features but had distinct NAC composition.
This study investigated the composition, structures, and light absorption of N-containing...
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