Articles | Volume 20, issue 22
Atmos. Chem. Phys., 20, 14077–14090, 2020
https://doi.org/10.5194/acp-20-14077-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 20, 14077–14090, 2020
https://doi.org/10.5194/acp-20-14077-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
20 Nov 2020
Research article
| 20 Nov 2020
Chemical composition, structures, and light absorption of N-containing aromatic compounds emitted from burning wood and charcoal in household cookstoves
Mingjie Xie et al.
Related authors
Zhenqi Xu, Wei Feng, Yicheng Wang, Haoran Ye, Yuhang Wang, Hong Liao, and Mingjie Xie
Atmos. Chem. Phys., 22, 13739–13752, https://doi.org/10.5194/acp-22-13739-2022, https://doi.org/10.5194/acp-22-13739-2022, 2022
Short summary
Short summary
This work uses a solvent (DMF) that can efficiently dissolve low-volatility OC to examine BrC absorption and sources, which will benefit future investigations on the physicochemical properties of large organic molecules. The study results also shed light on potential sources for methanol-insoluble OC. These results highlight the importance of testing different solvents to investigate the structures and light absorption of low-volatility BrC.
Chao Qin, Yafeng Gou, Yuhang Wang, Yuhao Mao, Hong Liao, Qin'geng Wang, and Mingjie Xie
Atmos. Chem. Phys., 21, 12141–12153, https://doi.org/10.5194/acp-21-12141-2021, https://doi.org/10.5194/acp-21-12141-2021, 2021
Short summary
Short summary
In this study, we found that the aqueous solution in aerosols is an important absorbing phase for gaseous polyols in the atmosphere, indicating that the dissolution in aerosol liquid water should not be ignored when investigating gas–particle partitioning of water-soluble organics. The exponential increase in effective partitioning coefficients of polyol tracers with sulfate ion concentrations could be attributed to organic–inorganic interactions in the particle phase.
Huan Yu, Lili Ren, Xiangpeng Huang, Mingjie Xie, Jun He, and Hang Xiao
Atmos. Chem. Phys., 19, 4025–4039, https://doi.org/10.5194/acp-19-4025-2019, https://doi.org/10.5194/acp-19-4025-2019, 2019
Short summary
Short summary
Iodine is an essential trace element for mammals and aquatic plants. Increasing alga populations due to serious eutrophication in the coastal waters of China promote iodine emission. China contributes about 60 % of the global cultivated seaweed production. Iodine is likely emitted to the atmosphere and transformed into nanoparticles during the farming, harvesting, and processing of seaweed. Wild and farmed algae make the coastal area of China a potential hotspot of new particle formation.
Mingjie Xie, Xi Chen, Michael D. Hays, and Amara L. Holder
Atmos. Chem. Phys., 19, 2899–2915, https://doi.org/10.5194/acp-19-2899-2019, https://doi.org/10.5194/acp-19-2899-2019, 2019
Short summary
Short summary
We did a comprehensive work on understanding the composition and structural information of N-containing aromatic compounds (NACs) and their contributions to organic matter and bulk extract absorption of biomass burning (BB) aerosols. Some NACs with methoxy and cyanate groups specific to the BB were identified. The general implication is that the formation of NACs during BB might depend largely on burn conditions and is less impacted by fuel types and/or ambient conditions.
Yunhua Chang, Kan Huang, Mingjie Xie, Congrui Deng, Zhong Zou, Shoudong Liu, and Yanlin Zhang
Atmos. Chem. Phys., 18, 11793–11812, https://doi.org/10.5194/acp-18-11793-2018, https://doi.org/10.5194/acp-18-11793-2018, 2018
Short summary
Short summary
We continuously performed a one-year and hourly-resolved measurement of 18 atmospheric elements in PM2.5 in Shanghai megacity. Here our high time-resolution observations over a long-term period provide baseline data with high detail, which are of great use for examining acute exposure of morbidity and mortality risk in association with PM2.5 metal species in China's megacities.
Xi Chen, Mingjie Xie, Michael D. Hays, Eric Edgerton, Donna Schwede, and John T. Walker
Atmos. Chem. Phys., 18, 6829–6846, https://doi.org/10.5194/acp-18-6829-2018, https://doi.org/10.5194/acp-18-6829-2018, 2018
M. Xie, K. C. Barsanti, M. P. Hannigan, S. J. Dutton, and S. Vedal
Atmos. Chem. Phys., 13, 7381–7393, https://doi.org/10.5194/acp-13-7381-2013, https://doi.org/10.5194/acp-13-7381-2013, 2013
Yaqin Gao, Hongli Wang, Lingling Yuan, Shengao Jing, Bin Yuan, Guofeng Shen, Liang Zhu, Abigail Koss, Yingjie Li, Qian Wang, Dan Dan Huang, Shuhui Zhu, Shikang Tao, Shengrong Lou, and Cheng Huang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-711, https://doi.org/10.5194/acp-2022-711, 2022
Preprint under review for ACP
Short summary
Short summary
A near-complete speciation of Reactive organic gases (ROGs) emitted from residential combustion was developed to get more insights into their atmospheric effects. Oxygenated species, higher hydrocarbons and nitrogen-containing ones played larger roles in the emissions of residential combustion comparing with the common hydrocarbons. Based on the near-complete speciation, ROG emissions from residential combustion were largely underestimated, leading to more underestimation of their OHR and SOAP.
Yi Cheng, Shaofei Kong, Liquan Yao, Huang Zheng, Jian Wu, Qin Yan, Shurui Zheng, Yao Hu, Zhenzhen Niu, Yingying Yan, Zhenxing Shen, Guofeng Shen, Dantong Liu, Shuxiao Wang, and Shihua Qi
Earth Syst. Sci. Data, 14, 4757–4775, https://doi.org/10.5194/essd-14-4757-2022, https://doi.org/10.5194/essd-14-4757-2022, 2022
Short summary
Short summary
This work establishes the first emission inventory of carbonaceous aerosols from cooking, fireworks, sacrificial incense, joss paper burning, and barbecue, using multi-source datasets and tested emission factors. These emissions were concentrated in specific periods and areas. Positive and negative correlations between income and emissions were revealed in urban and rural regions. The dataset will be helpful for improving modeling studies and modifying corresponding emission control policies.
Zhenqi Xu, Wei Feng, Yicheng Wang, Haoran Ye, Yuhang Wang, Hong Liao, and Mingjie Xie
Atmos. Chem. Phys., 22, 13739–13752, https://doi.org/10.5194/acp-22-13739-2022, https://doi.org/10.5194/acp-22-13739-2022, 2022
Short summary
Short summary
This work uses a solvent (DMF) that can efficiently dissolve low-volatility OC to examine BrC absorption and sources, which will benefit future investigations on the physicochemical properties of large organic molecules. The study results also shed light on potential sources for methanol-insoluble OC. These results highlight the importance of testing different solvents to investigate the structures and light absorption of low-volatility BrC.
Ruosi Liang, Yuzhong Zhang, Jingran Liu, Wei Chen, Peixuan Zhang, Cuihong Chen, Huiqin Mao, Guofeng Shen, Zhen Qu, Zichong Chen, Minqiang Zhou, Pucai Wang, Robert J. Parker, Hartmut Boesch, Alba Lorente, Joannes D. Maasakkers, and Ilse Aben
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-508, https://doi.org/10.5194/acp-2022-508, 2022
Revised manuscript under review for ACP
Short summary
Short summary
We quantify East Asian methane emissions with regional inversions of satellite observations from two different instruments (GOSAT and TROPOMI). The two inversions show discrepancies in methane emissions from northern India and East China. Evaluation against independent observations supports TROPOMI-derived emissions in norther India and GOSAT-derived emissions in East China.
John Thomas Walker, Xi Chen, Zhiyong Wu, Donna Schwede, Ryan Daly, Aleksandra Djurkovic, A. Christopher Oishi, Eric Edgerton, Jesse Bash, Jennifer Knoepp, Melissa Puchalski, John Iiames, and Chelcy Ford Miniat
Biogeosciences Discuss., https://doi.org/10.5194/bg-2022-133, https://doi.org/10.5194/bg-2022-133, 2022
Revised manuscript accepted for BG
Short summary
Short summary
Better estimates of atmospheric nitrogen (N) deposition are needed to accurately assess ecosystem risk and impacts from deposition of nutrients and acidity. Using measurements and modeling, we estimate total N deposition is 6.6 kg N ha-1 yr-1 at a forest site in the southern Appalachian Mountains, a region sensitive to atmospheric deposition. Reductions in deposition of reduced forms of N (ammonia and ammonium) will be needed to meet the lowest estimates of N critical loads for the region.
Chao Qin, Yafeng Gou, Yuhang Wang, Yuhao Mao, Hong Liao, Qin'geng Wang, and Mingjie Xie
Atmos. Chem. Phys., 21, 12141–12153, https://doi.org/10.5194/acp-21-12141-2021, https://doi.org/10.5194/acp-21-12141-2021, 2021
Short summary
Short summary
In this study, we found that the aqueous solution in aerosols is an important absorbing phase for gaseous polyols in the atmosphere, indicating that the dissolution in aerosol liquid water should not be ignored when investigating gas–particle partitioning of water-soluble organics. The exponential increase in effective partitioning coefficients of polyol tracers with sulfate ion concentrations could be attributed to organic–inorganic interactions in the particle phase.
Han Han, Yue Wu, Jane Liu, Tianliang Zhao, Bingliang Zhuang, Honglei Wang, Yichen Li, Huimin Chen, Ye Zhu, Hongnian Liu, Qin'geng Wang, Shu Li, Tijian Wang, Min Xie, and Mengmeng Li
Atmos. Chem. Phys., 20, 13591–13610, https://doi.org/10.5194/acp-20-13591-2020, https://doi.org/10.5194/acp-20-13591-2020, 2020
Short summary
Short summary
Combining simulations from a global chemical transport model and a trajectory model, we find that black carbon aerosols from South Asia and East Asia contribute 77 % of the surface black carbon in the Tibetan Plateau. The Asian monsoon largely modulates inter-annual transport of black carbon from non-local regions to the Tibetan Plateau surface in most seasons, while inter-annual fire activities in South Asia influence black carbon concentration over the Tibetan Plateau surface mainly in spring.
Qiuyue Zhao, Jun Bi, Qian Liu, Zhenghao Ling, Guofeng Shen, Feng Chen, Yuezhen Qiao, Chunyan Li, and Zongwei Ma
Atmos. Chem. Phys., 20, 3905–3919, https://doi.org/10.5194/acp-20-3905-2020, https://doi.org/10.5194/acp-20-3905-2020, 2020
Short summary
Short summary
Understanding the composition, temporal variability and source apportionment of volatile organic compounds (VOCs) is necessary for determining effective control measures to minimize VOCs and their related photochemical pollution. This study conducted source apportionments of VOCs and evaluated their contributions to ozone formation at an urban site in Nanjing with data from 1-year of field measurements.
Huan Yu, Lili Ren, Xiangpeng Huang, Mingjie Xie, Jun He, and Hang Xiao
Atmos. Chem. Phys., 19, 4025–4039, https://doi.org/10.5194/acp-19-4025-2019, https://doi.org/10.5194/acp-19-4025-2019, 2019
Short summary
Short summary
Iodine is an essential trace element for mammals and aquatic plants. Increasing alga populations due to serious eutrophication in the coastal waters of China promote iodine emission. China contributes about 60 % of the global cultivated seaweed production. Iodine is likely emitted to the atmosphere and transformed into nanoparticles during the farming, harvesting, and processing of seaweed. Wild and farmed algae make the coastal area of China a potential hotspot of new particle formation.
Mingjie Xie, Xi Chen, Michael D. Hays, and Amara L. Holder
Atmos. Chem. Phys., 19, 2899–2915, https://doi.org/10.5194/acp-19-2899-2019, https://doi.org/10.5194/acp-19-2899-2019, 2019
Short summary
Short summary
We did a comprehensive work on understanding the composition and structural information of N-containing aromatic compounds (NACs) and their contributions to organic matter and bulk extract absorption of biomass burning (BB) aerosols. Some NACs with methoxy and cyanate groups specific to the BB were identified. The general implication is that the formation of NACs during BB might depend largely on burn conditions and is less impacted by fuel types and/or ambient conditions.
Yunhua Chang, Kan Huang, Mingjie Xie, Congrui Deng, Zhong Zou, Shoudong Liu, and Yanlin Zhang
Atmos. Chem. Phys., 18, 11793–11812, https://doi.org/10.5194/acp-18-11793-2018, https://doi.org/10.5194/acp-18-11793-2018, 2018
Short summary
Short summary
We continuously performed a one-year and hourly-resolved measurement of 18 atmospheric elements in PM2.5 in Shanghai megacity. Here our high time-resolution observations over a long-term period provide baseline data with high detail, which are of great use for examining acute exposure of morbidity and mortality risk in association with PM2.5 metal species in China's megacities.
Xi Chen, Mingjie Xie, Michael D. Hays, Eric Edgerton, Donna Schwede, and John T. Walker
Atmos. Chem. Phys., 18, 6829–6846, https://doi.org/10.5194/acp-18-6829-2018, https://doi.org/10.5194/acp-18-6829-2018, 2018
Xiaohui Zhang, Yan Lu, Qin'geng Wang, and Xin Qian
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2017-1113, https://doi.org/10.5194/acp-2017-1113, 2018
Preprint withdrawn
Short summary
Short summary
Activity data at prefectural-city level combined with high-resolution land use data were adopted to improve spatial resolution and detailed crop rotations and harvest times in different regions were considered in determining temporal distribution. Also, MODIS fire products were applied to verify the spatial and temporal variations of the emissions. Results showed that high emissions were generally located in Eastern, Central and Northeastern China, and temporally peaking in June and October.
Xi Chen, John T. Walker, and Chris Geron
Atmos. Meas. Tech., 10, 3893–3908, https://doi.org/10.5194/amt-10-3893-2017, https://doi.org/10.5194/amt-10-3893-2017, 2017
Short summary
Short summary
The MARGA instrument is a powerful research tool for investigating atmospheric chemistry and the exchange of gases and particles between the atmosphere and biosphere. Our study examines the operating characteristics of the instrument with a focus on the software used to calculate air concentrations. We show that more accurate measurements may be obtained by calibrating the instrument with a range of standards in addition to the single internal standard used in online concentration calculations.
Yi Li, Tammy M. Thompson, Martin Van Damme, Xi Chen, Katherine B. Benedict, Yixing Shao, Derek Day, Alexandra Boris, Amy P. Sullivan, Jay Ham, Simon Whitburn, Lieven Clarisse, Pierre-François Coheur, and Jeffrey L. Collett Jr.
Atmos. Chem. Phys., 17, 6197–6213, https://doi.org/10.5194/acp-17-6197-2017, https://doi.org/10.5194/acp-17-6197-2017, 2017
J. Pavlovic, J. S. Kinsey, and M. D. Hays
Atmos. Meas. Tech., 7, 2829–2838, https://doi.org/10.5194/amt-7-2829-2014, https://doi.org/10.5194/amt-7-2829-2014, 2014
M. Xie, K. C. Barsanti, M. P. Hannigan, S. J. Dutton, and S. Vedal
Atmos. Chem. Phys., 13, 7381–7393, https://doi.org/10.5194/acp-13-7381-2013, https://doi.org/10.5194/acp-13-7381-2013, 2013
R. Wang, S. Tao, P. Ciais, H. Z. Shen, Y. Huang, H. Chen, G. F. Shen, B. Wang, W. Li, Y. Y. Zhang, Y. Lu, D. Zhu, Y. C. Chen, X. P. Liu, W. T. Wang, X. L. Wang, W. X. Liu, B. G. Li, and S. L. Piao
Atmos. Chem. Phys., 13, 5189–5203, https://doi.org/10.5194/acp-13-5189-2013, https://doi.org/10.5194/acp-13-5189-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Chemical characterization of organic compounds involved in iodine-initiated new particle formation from coastal macroalgal emission
The Urmia playa as a source of airborne dust and ice-nucleating particles – Part 2: Unraveling the relationship between soil dust composition and ice nucleation activity
Winter brown carbon over six of China's megacities: light absorption, molecular characterization, and improved source apportionment revealed by multilayer perceptron neural network
Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds
Not all types of secondary organic aerosol mix: two phases observed when mixing different secondary organic aerosol types
Comprehensive characterization of particulate intermediate-volatility and semi-volatile organic compounds (I/SVOCs) from heavy-duty diesel vehicles using two-dimensional gas chromatography time-of-flight mass spectrometry
Measurement report: Investigation of pH- and particle-size-dependent chemical and optical properties of water-soluble organic carbon: implications for its sources and aging processes
SO2 enhances aerosol formation from anthropogenic volatile organic compound ozonolysis by producing sulfur-containing compounds
The influence of the addition of isoprene on the volatility of particles formed from the photo-oxidation of anthropogenic–biogenic mixtures
Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface
Particle-phase processing of α-pinene NO3 secondary organic aerosol in the dark
Chemical characteristics and sources of PM2.5 in Hohhot, a semi-arid city in northern China: insight from the COVID-19 lockdown
The positive effect of formaldehyde on the photocatalytic renoxification of nitrate on TiO2 particles
Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical
A comprehensive study on hygroscopic behaviour and nitrate depletion of NaNO3 and dicarboxylic acid mixtures: implications for nitrate depletion in tropospheric aerosols
Secondary organic aerosols from OH oxidation of cyclic volatile methyl siloxanes as an important Si source in the atmosphere
Effects of OH radical and SO2 concentrations on photochemical reactions of mixed anthropogenic organic gases
Effects of the sample matrix on the photobleaching and photodegradation of toluene-derived secondary organic aerosol compounds
Functionality-based formation of secondary organic aerosol from m-xylene photooxidation
Chemical composition of secondary organic aerosol particles formed from mixtures of anthropogenic and biogenic precursors
A novel pathway of atmospheric sulfate formation through carbonate radicals
Magnetic fraction of the atmospheric dust in Kraków – physicochemical characteristics and possible environmental impact
A sulfuric acid nucleation potential model for the atmosphere
Optical and chemical properties and oxidative potential of aqueous-phase products from OH and 3C∗-initiated photooxidation of eugenol
The relationship between PM2.5 and anticyclonic wave activity during summer over the United States
Modeling Diurnal Variation of SOA Formation via Multiphase Reactions of Biogenic Hydrocarbons
Iron from coal combustion particles dissolves much faster than mineral dust under simulated atmospheric acidic conditions
Cellulose in atmospheric particulate matter at rural and urban sites across France and Switzerland
Kinetics, SOA yields, and chemical composition of secondary organic aerosol from β-caryophyllene ozonolysis with and without nitrogen oxides between 213 and 313 K
Chemical transformation of α-pinene-derived organosulfate via heterogeneous OH oxidation: implications for sources and environmental fates of atmospheric organosulfates
Aqueous chemical bleaching of 4-nitrophenol brown carbon by hydroxyl radicals; products, mechanism, and light absorption
Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low-NOx and high-NOx conditions
Secondary organic aerosol formation from camphene oxidation: measurements and modeling
Technical note: Real-time diagnosis of the hygroscopic growth micro-dynamics of nanoparticles with Fourier transform infrared spectroscopy
Single-particle Raman spectroscopy for studying physical and chemical processes of atmospheric particles
Are reactive oxygen species (ROS) a suitable metric to predict toxicity of carbonaceous aerosol particles?
Secondary organic aerosol and organic nitrogen yields from the nitrate radical (NO3) oxidation of alpha-pinene from various RO2 fates
Secondary organic aerosol formation from the oxidation of decamethylcyclopentasiloxane at atmospherically relevant OH concentrations
Aqueous secondary organic aerosol formation from the direct photosensitized oxidation of vanillin in the absence and presence of ammonium nitrate
Evolution of volatility and composition in sesquiterpene-mixed and α-pinene secondary organic aerosol particles during isothermal evaporation
Potential new tracers and their mass fraction in the emitted PM10 from the burning of household waste in stoves
Synergetic effects of NH3 and NOx on the production and optical absorption of secondary organic aerosol formation from toluene photooxidation
Chemical composition of nanoparticles from α-pinene nucleation and the influence of isoprene and relative humidity at low temperature
Technical note: Adsorption and desorption equilibria from statistical thermodynamics and rates from transition state theory
Nighttime chemistry of biomass burning emissions in urban areas: A dual mobile chamber study
Formation and evolution of secondary organic aerosols derived from urban-lifestyle sources: vehicle exhaust and cooking emissions
Mass spectral characterization of secondary organic aerosol from urban cooking and vehicular sources
An organic crystalline state in ageing atmospheric aerosol proxies: spatially resolved structural changes in levitated fatty acid particles
Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition
The driving factors of new particle formation and growth in the polluted boundary layer
Yibei Wan, Xiangpeng Huang, Chong Xing, Qiongqiong Wang, Xinlei Ge, and Huan Yu
Atmos. Chem. Phys., 22, 15413–15423, https://doi.org/10.5194/acp-22-15413-2022, https://doi.org/10.5194/acp-22-15413-2022, 2022
Short summary
Short summary
The organic compounds involved in continental new particle formation have been investigated in depth in the last 2 decades. In contrast, no prior work has studied the exact chemical composition of organic compounds and their role in coastal new particle formation. We present a complementary study to the ongoing laboratory and field research on iodine nucleation in the coastal atmosphere. This study provided a more complete story of coastal I-NPF from low-tide macroalgal emission.
Nikou Hamzehpour, Claudia Marcolli, Kristian Klumpp, Debora Thöny, and Thomas Peter
Atmos. Chem. Phys., 22, 14931–14956, https://doi.org/10.5194/acp-22-14931-2022, https://doi.org/10.5194/acp-22-14931-2022, 2022
Short summary
Short summary
Dust aerosols from dried lakebeds contain mineral particles, as well as soluble salts and (bio-)organic compounds. Here, we investigate ice nucleation (IN) activity of dust samples from Lake Urmia playa, Iran. We find high IN activity of the untreated samples that decreases after organic matter removal but increases after removing soluble salts and carbonates, evidencing inhibiting effects of soluble salts and carbonates on the IN activity of organic matter and minerals, especially microcline.
Diwei Wang, Zhenxing Shen, Qian Zhang, Yali Lei, Tian Zhang, Shasha Huang, Jian Sun, Hongmei Xu, and Junji Cao
Atmos. Chem. Phys., 22, 14893–14904, https://doi.org/10.5194/acp-22-14893-2022, https://doi.org/10.5194/acp-22-14893-2022, 2022
Short summary
Short summary
The optical properties and molecular structure of atmospheric brown carbon (BrC) in winter of several megacities in China were analyzed, and the source contribution of brown carbon was improved by using positive matrix factorization coupled with a multilayer perceptron neural network. These results can provide a basis for the more effective control of BrC to reduce its impacts on regional climates and human health.
Aristeidis Voliotis, Mao Du, Yu Wang, Yunqi Shao, M. Rami Alfarra, Thomas J. Bannan, Dawei Hu, Kelly L. Pereira, Jaqueline F. Hamilton, Mattias Hallquist, Thomas F. Mentel, and Gordon McFiggans
Atmos. Chem. Phys., 22, 14147–14175, https://doi.org/10.5194/acp-22-14147-2022, https://doi.org/10.5194/acp-22-14147-2022, 2022
Short summary
Short summary
Mixing experiments are crucial and highly beneficial for our understanding of atmospheric chemical interactions. However, interpretation quickly becomes complex, and both the experimental design and evaluation need to be scrutinised carefully. Advanced online and offline compositional measurements can reveal substantial additional information to aid in the interpretation of yield data, including components uniquely found in mixtures and property changes in SOA formed from mixtures of VOCs.
Fabian Mahrt, Long Peng, Julia Zaks, Yuanzhou Huang, Paul E. Ohno, Natalie R. Smith, Florence K. A. Gregson, Yiming Qin, Celia L. Faiola, Scot T. Martin, Sergey A. Nizkorodov, Markus Ammann, and Allan K. Bertram
Atmos. Chem. Phys., 22, 13783–13796, https://doi.org/10.5194/acp-22-13783-2022, https://doi.org/10.5194/acp-22-13783-2022, 2022
Short summary
Short summary
The number of condensed phases in mixtures of different secondary organic aerosol (SOA) types determines their impact on air quality and climate. Here we observe the number of phases in individual particles that contain mixtures of two different types of SOA. We find that SOA mixtures can form one- or two-phase particles, depending on the difference in the average oxygen-to-carbon (O / C) ratios of the two SOA types that are internally mixed within individual particles.
Xiao He, Xuan Zheng, Shaojun Zhang, Xuan Wang, Ting Chen, Xiao Zhang, Guanghan Huang, Yihuan Cao, Liqiang He, Xubing Cao, Yuan Cheng, Shuxiao Wang, and Ye Wu
Atmos. Chem. Phys., 22, 13935–13947, https://doi.org/10.5194/acp-22-13935-2022, https://doi.org/10.5194/acp-22-13935-2022, 2022
Short summary
Short summary
With the use of two-dimensional gas chromatography time-of-flight mass spectrometry (GC × GC ToF-MS), we successfully give a comprehensive characterization of particulate intermediate-volatility and semi-volatile organic compounds (I/SVOCs) emitted from heavy-duty diesel vehicles. I/SVOCs are speciated, identified, and quantified based on the patterns of the mass spectrum, and the gas–particle partitioning is fully addressed.
Yuanyuan Qin, Juanjuan Qin, Xiaobo Wang, Kang Xiao, Ting Qi, Yuwei Gao, Xueming Zhou, Shaoxuan Shi, Jingnan Li, Jingsi Gao, Ziyin Zhang, Jihua Tan, Yang Zhang, and Rongzhi Chen
Atmos. Chem. Phys., 22, 13845–13859, https://doi.org/10.5194/acp-22-13845-2022, https://doi.org/10.5194/acp-22-13845-2022, 2022
Short summary
Short summary
Deep interrogation of water-soluble organic carbon (WSOC) in aerosols is critical and challenging considering its involvement in many key aerosol-associated chemical reactions. This work examined how the chemical structures (functional groups) and optical properties (UV/fluorescence properties) of WSOC were affected by pH and particle size. We found that the pH- and particle-size-dependent behaviors could be used to reveal the structures, sources, and aging of aerosol WSOC.
Zhaomin Yang, Kun Li, Narcisse T. Tsona, Xin Luo, and Lin Du
EGUsphere, https://doi.org/10.5194/egusphere-2022-1068, https://doi.org/10.5194/egusphere-2022-1068, 2022
Short summary
Short summary
SO2 significantly promotes particle formation during cyclooctene ozonolysis. Carboxylic acids and their dimers were major products in particles formed in the absence of SO2. SO2 can induce the production of organosulfates with stronger particle formation ability than their precursors, leading to the enhancement in particle formation. Formation mechanisms and structures of organosulfates were proposed, which is helpful for better understanding how SO2 perturbs the formation and fate of particles.
Aristeidis Voliotis, Mao Du, Yu Wang, Yunqi Shao, Thomas J. Bannan, Michael Flynn, Spyros N. Pandis, Carl J. Percival, M. Rami Alfarra, and Gordon McFiggans
Atmos. Chem. Phys., 22, 13677–13693, https://doi.org/10.5194/acp-22-13677-2022, https://doi.org/10.5194/acp-22-13677-2022, 2022
Short summary
Short summary
The addition of a low-yield precursor to the reactive mixture of aVOC and bVOC can increase or decrease the SOA volatility that is system-dependent. Therefore, the SOA volatility of the mixtures cannot always be predicted based on the additivity. In complex mixtures the formation of lower-volatility products likely outweighs the formation of products with higher volatility. The unique products of each mixture contribute significantly to the signal, suggesting interactions can be important.
Tao Wang, Yangyang Liu, Hanyun Cheng, Zhenzhen Wang, Hongbo Fu, Jianmin Chen, and Liwu Zhang
Atmos. Chem. Phys., 22, 13467–13493, https://doi.org/10.5194/acp-22-13467-2022, https://doi.org/10.5194/acp-22-13467-2022, 2022
Short summary
Short summary
This study compared the gas-phase, aqueous-phase, and heterogeneous SO2 oxidation pathways by combining laboratory work with a modelling study. The heterogeneous oxidation, particularly that induced by the dust surface drivers, presents positive implications for the removal of airborne SO2 and formation of sulfate aerosols. This work highlighted the atmospheric significance of heterogeneous oxidation and suggested a comparison model to evaluate the following heterogeneous laboratory research.
David M. Bell, Cheng Wu, Amelie Bertrand, Emelie Graham, Janne Schoonbaert, Stamatios Giannoukos, Urs Baltensperger, Andre S. H. Prevot, Ilona Riipinen, Imad El Haddad, and Claudia Mohr
Atmos. Chem. Phys., 22, 13167–13182, https://doi.org/10.5194/acp-22-13167-2022, https://doi.org/10.5194/acp-22-13167-2022, 2022
Short summary
Short summary
A series of studies designed to investigate the evolution of organic aerosol were performed in an atmospheric simulation chamber, using a common oxidant found at night (NO3). The chemical composition steadily changed from its initial composition via different chemical reactions that were taking place inside of the aerosol particle. These results show that the composition of organic aerosol steadily changes during its lifetime in the atmosphere.
Haijun Zhou, Tao Liu, Bing Sun, Yongli Tian, Xingjun Zhou, Feng Hao, Xi Chun, Zhiqiang Wan, Peng Liu, Jingwen Wang, and Dagula Du
Atmos. Chem. Phys., 22, 12153–12166, https://doi.org/10.5194/acp-22-12153-2022, https://doi.org/10.5194/acp-22-12153-2022, 2022
Short summary
Short summary
A single year’s offline measurement was conducted in Hohhot to reveal the chemical characteristics and sources of PM2.5 in a semi-arid region. We believe that our study makes a significant contribution to the literature because relatively few studies have focused on the chemical composition and sources of PM2.5 with offline measurements. A knowledge gap exists concerning how chemical composition and sources respond to implemented control measures for aerosols, particularly in a semi-arid region.
Yuhan Liu, Xuejiao Wang, Jing Shang, Weiwei Xu, Mengshuang Sheng, and Chunxiang Ye
Atmos. Chem. Phys., 22, 11347–11358, https://doi.org/10.5194/acp-22-11347-2022, https://doi.org/10.5194/acp-22-11347-2022, 2022
Short summary
Short summary
In this study, the influence of HCHO on renoxification on nitrate-doped TiO2 particles is investigated by using an experimental chamber. Mass NOx release is suggested to follow the NO−3-NO3·-HNO3-NOx pathway, with HCHO involved in the transformation of NO3· to HNO3 through hydrogen abstraction. Our proposed reaction mechanism by which HCHO promotes photocatalytic renoxification is helpful for deeply understanding the atmospheric photochemical processes and nitrogen cycling.
Yindong Guo, Hongru Shen, Iida Pullinen, Hao Luo, Sungah Kang, Luc Vereecken, Hendrik Fuchs, Mattias Hallquist, Ismail-Hakki Acir, Ralf Tillmann, Franz Rohrer, Jürgen Wildt, Astrid Kiendler-Scharr, Andreas Wahner, Defeng Zhao, and Thomas F. Mentel
Atmos. Chem. Phys., 22, 11323–11346, https://doi.org/10.5194/acp-22-11323-2022, https://doi.org/10.5194/acp-22-11323-2022, 2022
Short summary
Short summary
The oxidation of limonene, a common volatile emitted by trees and chemical products, by NO3, a nighttime oxidant, forms many highly oxygenated organic molecules (HOM), including C10-30 compounds. Most of the HOM are second-generation organic nitrates, in which carbonyl-substituted C10 nitrates accounted for a major fraction. Their formation can be explained by chemistry of peroxy radicals. HOM, especially low-volatile ones, play an important role in nighttime new particle formation and growth.
Shuaishuai Ma, Qiong Li, and Yunhong Zhang
Atmos. Chem. Phys., 22, 10955–10970, https://doi.org/10.5194/acp-22-10955-2022, https://doi.org/10.5194/acp-22-10955-2022, 2022
Short summary
Short summary
The nitrate phase state can play a critical role in determining the occurrence and extent of nitrate depletion in internally mixed NaNO3–DCA particles, which may be instructive for relevant aerosol reaction systems. Besides, organic acids have a potential to deplete nitrate based on the comprehensive consideration of acidity, particle-phase state, droplet water activity, and HNO3 gas-phase diffusion.
Chong Han, Hongxing Yang, Kun Li, Patrick Lee, John Liggio, Amy Leithead, and Shao-Meng Li
Atmos. Chem. Phys., 22, 10827–10839, https://doi.org/10.5194/acp-22-10827-2022, https://doi.org/10.5194/acp-22-10827-2022, 2022
Short summary
Short summary
We presented yields and compositions of Si-containing SOAs generated from the reaction of cVMSs (D3–D6) with OH radicals. NOx played a negative role in cVMS SOA formation, while ammonium sulfate seeds enhanced D3–D5 SOA yields at short photochemical ages under high-NOx conditions. The aerosol mass spectra confirmed that the components of cVMS SOAs significantly relied on OH exposure. A global cVMS-derived SOA source strength was estimated in order to understand SOA formation potentials of cVMSs.
Junling Li, Kun Li, Hao Zhang, Xin Zhang, Yuanyuan Ji, Wanghui Chu, Yuxue Kong, Yangxi Chu, Yanqin Ren, Yujie Zhang, Haijie Zhang, Rui Gao, Zhenhai Wu, Fang Bi, Xuan Chen, Xuezhong Wang, Weigang Wang, Hong Li, and Maofa Ge
Atmos. Chem. Phys., 22, 10489–10504, https://doi.org/10.5194/acp-22-10489-2022, https://doi.org/10.5194/acp-22-10489-2022, 2022
Short summary
Short summary
Ozone formation is enhanced by higher OH concentration and higher temperature but is influenced little by SO2. SO2 can largely enhance the particle formation. Organo-sulfates and organo-nitrates are detected in the formed particles, and the presence of SO2 can promote the formation of organo-sulfates. The results provide a scientific basis for systematically evaluating the effects of SO2, OH concentration, and temperature on the oxidation of mixed organic gases in the atmosphere.
Alexandra L. Klodt, Marley Adamek, Monica Dibley, Sergey A. Nizkorodov, and Rachel E. O'Brien
Atmos. Chem. Phys., 22, 10155–10171, https://doi.org/10.5194/acp-22-10155-2022, https://doi.org/10.5194/acp-22-10155-2022, 2022
Short summary
Short summary
We investigated photochemistry of a secondary organic aerosol under three different conditions: in a dilute aqueous solution mimicking cloud droplets, in a solution of concentrated ammonium sulfate mimicking deliquesced aerosol, and in an organic matrix mimicking dry organic aerosol. We find that rate and mechanisms of photochemistry depend sensitively on these conditions, suggesting that the same organic aerosol compounds will degrade at different rates depending on their local environment.
Yixin Li, Jiayun Zhao, Mario Gomez-Hernandez, Michael Lavallee, Natalie M. Johnson, and Renyi Zhang
Atmos. Chem. Phys., 22, 9843–9857, https://doi.org/10.5194/acp-22-9843-2022, https://doi.org/10.5194/acp-22-9843-2022, 2022
Short summary
Short summary
Here we elucidate the production of COOs and their roles in SOA and brown carbon formation from m-xylene oxidation by simultaneously monitoring the evolution of gas-phase products and aerosol properties in an environmental chamber. A kinetic framework is developed to predict SOA production from the concentrations and uptake coefficients for COOs. This functionality-based approach reproduces SOA formation from m-xylene oxidation well and is applicable to VOC oxidation for other species.
Yunqi Shao, Aristeidis Voliotis, Mao Du, Yu Wang, Kelly Pereira, Jacqueline Hamilton, M. Rami Alfarra, and Gordon McFiggans
Atmos. Chem. Phys., 22, 9799–9826, https://doi.org/10.5194/acp-22-9799-2022, https://doi.org/10.5194/acp-22-9799-2022, 2022
Short summary
Short summary
This study explored the chemical properties of secondary organic aerosol (SOA) that formed from photo-oxidation of single and mixed biogenic and anthropogenic precursors. We showed that SOA chemical properties in a mixed vapour system are mainly affected by the
higher-yield precursor's oxidation products and products from
cross-product formation. This study also identifies potential tracer compounds in a mixed vapour system that might be used in SOA source attribution in future ambient studies.
Yangyang Liu, Yue Deng, Jiarong Liu, Xiaozhong Fang, Tao Wang, Kejian Li, Kedong Gong, Aziz U. Bacha, Iqra Nabi, Qiuyue Ge, Xiuhui Zhang, Christian George, and Liwu Zhang
Atmos. Chem. Phys., 22, 9175–9197, https://doi.org/10.5194/acp-22-9175-2022, https://doi.org/10.5194/acp-22-9175-2022, 2022
Short summary
Short summary
Both CO2 and carbonate salt work as the precursor of carbonate radicals, which largely promotes sulfate formation during the daytime. This study provides the first indication that the carbonate radical not only plays a role as an intermediate in tropospheric anion chemistry but also as a strong oxidant for the surface processing of trace gas in the atmosphere. CO2, carbponate radicals, and sulfate receive attention from those looking at the environment, atmosphere, aerosol, and photochemistry.
Jan Marek Michalik, Wanda Wilczyńska-Michalik, Łukasz Gondek, Waldemar Tokarz, Jan Żukrowski, Marta Gajewska, and Marek Michalik
EGUsphere, https://doi.org/10.5194/egusphere-2022-462, https://doi.org/10.5194/egusphere-2022-462, 2022
Short summary
Short summary
Magnetic fraction of the aerosols in Kraków was collected and analysed using scanning and transmission electron microscopy with energy dispersive spectrometry, X-ray diffraction, Mössbauer spectrometry, and magnetometry. It contains metallic Fe or Fe-rich alloy and Fe oxides. Occurrence of nanometre scale Fe3O4 particles (predominantly of anthropogenic origin) is shown. Our results can be useful in a determination of the sources and transport of pollutants, potential harmful effects, etc.
Jack S. Johnson and Coty N. Jen
Atmos. Chem. Phys., 22, 8287–8297, https://doi.org/10.5194/acp-22-8287-2022, https://doi.org/10.5194/acp-22-8287-2022, 2022
Short summary
Short summary
Sulfuric acid nucleation forms particles in Earth's atmosphere that influence cloud formation and climate. This study introduces the Nucleation Potential Model, which simplifies the diverse reactions between sulfuric acid and numerous precursor gases to predict nucleation rates. Results show that the model is capable of estimating the potency and concentration of mixtures of precursor gases from laboratory and field observations and can be used to model nucleation across diverse environments.
Xudong Li, Ye Tao, Longwei Zhu, Shuaishuai Ma, Shipeng Luo, Zhuzi Zhao, Ning Sun, Xinlei Ge, and Zhaolian Ye
Atmos. Chem. Phys., 22, 7793–7814, https://doi.org/10.5194/acp-22-7793-2022, https://doi.org/10.5194/acp-22-7793-2022, 2022
Short summary
Short summary
This work has, for the first time, investigated the optical and chemical properties and oxidative potential of aqueous-phase photooxidation products of eugenol (a biomass-burning-emitted compound) and elucidated the interplay among these properties. Large mass yields exceeding 100 % were found, and the aqueous processing is a source of BrC (likely relevant with humic-like substances). We also show that aqueous processing can produce species that are more toxic than that of its precursor.
Ye Wang, Natalie Mahowald, Peter Hess, Wenxiu Sun, and Gang Chen
Atmos. Chem. Phys., 22, 7575–7592, https://doi.org/10.5194/acp-22-7575-2022, https://doi.org/10.5194/acp-22-7575-2022, 2022
Short summary
Short summary
PM2.5 is positively related to anticyclonic wave activity (AWA) changes close to the observing sites. Changes between current and future climates in AWA can explain up to 75 % of PM2.5 variability at some stations using a linear regression model. Our analysis indicates that higher PM2.5 concentrations occur when a positive AWA anomaly is prominent, which could be critical for understanding how pollutants respond to changing atmospheric circulation and for developing robust pollution projections.
Sanghee Han and Myoseon Jang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-327, https://doi.org/10.5194/acp-2022-327, 2022
Revised manuscript accepted for ACP
Short summary
Short summary
The diurnal pattern in biogenic SOA formation is simulated by using the UNIPAR model, which predicts SOA growth via multiphase reactions of hydrocarbons under varying NOx levels, aerosol acidity, humidity, and temperature. The simulation suggests that nighttime SOA formation, even in the urban environments where anthropogenic emission is high, is dominated by products from ozonolysis and NO3-initiated oxidation of biogenic hydrocarbons.
Clarissa Baldo, Akinori Ito, Michael D. Krom, Weijun Li, Tim Jones, Nick Drake, Konstantin Ignatyev, Nicholas Davidson, and Zongbo Shi
Atmos. Chem. Phys., 22, 6045–6066, https://doi.org/10.5194/acp-22-6045-2022, https://doi.org/10.5194/acp-22-6045-2022, 2022
Short summary
Short summary
High ionic strength relevant to the aerosol-water enhanced proton-promoted dissolution of iron in coal fly ash (up to 7 times) but suppressed oxalate-promoted dissolution at low pH (< 3). Fe in coal fly ash dissolved up to 7 times faster than in Saharan dust at low pH. A global model with the updated dissolution rates of iron in coal fly ash suggested a larger contribution of pyrogenic dissolved Fe over regions with a strong impact from fossil fuel combustions.
Adam Brighty, Véronique Jacob, Gaëlle Uzu, Lucille Borlaza, Sébastien Conil, Christoph Hueglin, Stuart K. Grange, Olivier Favez, Cécile Trébuchon, and Jean-Luc Jaffrezo
Atmos. Chem. Phys., 22, 6021–6043, https://doi.org/10.5194/acp-22-6021-2022, https://doi.org/10.5194/acp-22-6021-2022, 2022
Short summary
Short summary
With an revised analytical method and long-term sampling strategy, we have been able to elucidate much more information about atmospheric plant debris, a poorly understood class of particulate matter. We found weaker seasonal patterns at urban locations compared to rural locations and significant interannual variability in concentrations between previous years and 2020, during the COVID-19 pandemic. This suggests a possible man-made influence on plant debris concentration and source strength.
Linyu Gao, Junwei Song, Claudia Mohr, Wei Huang, Magdalena Vallon, Feng Jiang, Thomas Leisner, and Harald Saathoff
Atmos. Chem. Phys., 22, 6001–6020, https://doi.org/10.5194/acp-22-6001-2022, https://doi.org/10.5194/acp-22-6001-2022, 2022
Short summary
Short summary
We study secondary organic aerosol (SOA) from β-caryophyllene (BCP) ozonolysis with and without nitrogen oxides over 213–313 K in the simulation chamber. The yields and the rate constants were determined at 243–313 K. Chemical compositions varied at different temperatures, indicating a strong impact on the BCP ozonolysis pathways. This work helps to better understand the SOA from BCP ozonolysis for conditions representative of the real atmosphere from the boundary layer to the upper troposphere.
Rongshuang Xu, Sze In Madeleine Ng, Wing Sze Chow, Yee Ka Wong, Yuchen Wang, Donger Lai, Zhongping Yao, Pui-Kin So, Jian Zhen Yu, and Man Nin Chan
Atmos. Chem. Phys., 22, 5685–5700, https://doi.org/10.5194/acp-22-5685-2022, https://doi.org/10.5194/acp-22-5685-2022, 2022
Short summary
Short summary
To date, while over a hundred organosulfates (OSs) have been detected in atmospheric aerosols, many of them are still unidentified, with unknown precursors and formation processes. We found the heterogeneous OH oxidation of an α-pinene-derived organosulfate (C10H17O5SNa, αpOS-249, αpOS-249) can proceed at an efficient rate and transform into more oxygenated OSs, which have been commonly detected in atmospheric aerosols and α-pinene-derived SOA in chamber studies.
Bartłomiej Witkowski, Priyanka Jain, and Tomasz Gierczak
Atmos. Chem. Phys., 22, 5651–5663, https://doi.org/10.5194/acp-22-5651-2022, https://doi.org/10.5194/acp-22-5651-2022, 2022
Short summary
Short summary
This article describes a comprehensive investigation of the aqueous oxidation of 4-nitrophenol (4NP) by hydroxyl radicals (OH). The reaction was carried out in a laboratory photoreactor. We report the formation of key intermediates under different pH conditions and the evolution of the light absorption of the reaction solution. The results provide new insights into the formation and removal (chemical bleaching) of light-absorbing organic aerosols (atmospheric brown carbon).
Zijun Li, Angela Buchholz, Luis M. F. Barreira, Arttu Ylisirniö, Liqing Hao, Iida Pullinen, Siegfried Schobesberger, and Annele Virtanen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2022-285, https://doi.org/10.5194/acp-2022-285, 2022
Revised manuscript accepted for ACP
Short summary
Short summary
Interaction between NOx and biogenic emissions can be important in suburban areas. Our study showed that the addition of NOx during α-pinene SOA formation produced considerable amounts of organic nitrates and affected the composition of non-nitrated organic compounds. The compositional difference consequently altered the primary type of aqueous-phase processes during the isothermal particle evaporation.
Qi Li, Jia Jiang, Isaac K. Afreh, Kelley C. Barsanti, and David R. Cocker III
Atmos. Chem. Phys., 22, 3131–3147, https://doi.org/10.5194/acp-22-3131-2022, https://doi.org/10.5194/acp-22-3131-2022, 2022
Short summary
Short summary
Chamber-derived secondary organic aerosol (SOA) yields from camphene are reported for the first time. The role of peroxy radicals (RO2) was investigated using chemically detailed box models. We observed higher SOA yields (up to 64 %) in the experiments with added NOx than without due to the formation of highly oxygenated organic molecules (HOMs) when
NOx is present. This work can improve the representation of camphene in air quality models and provide insights into other monoterpene studies.
Xiuli Wei, Haosheng Dai, Huaqiao Gui, Jiaoshi Zhang, Yin Cheng, Jie Wang, Yixin Yang, Youwen Sun, and Jianguo Liu
Atmos. Chem. Phys., 22, 3097–3109, https://doi.org/10.5194/acp-22-3097-2022, https://doi.org/10.5194/acp-22-3097-2022, 2022
Short summary
Short summary
We demonstrated the usage of the Fourier transform infrared (FTIR) spectroscopic technique to characterize in real time the hygroscopic growth properties of nanoparticles and their phase transition micro-dynamics at the molecular level. We first realize real-time measurements of water content and dry nanoparticle mass to characterize hygroscopic growth factors. We then identify in real time the hydration interactions and the dynamic hygroscopic growth process of the functional groups.
Zhancong Liang, Yangxi Chu, Masao Gen, and Chak K. Chan
Atmos. Chem. Phys., 22, 3017–3044, https://doi.org/10.5194/acp-22-3017-2022, https://doi.org/10.5194/acp-22-3017-2022, 2022
Short summary
Short summary
The properties and fate of individual airborne particles can be significantly different, leading to distinct environmental impacts (e.g., climate and human health). While many instruments only analyze an ensemble of these particles, single-particle Raman spectroscopy enables unambiguous characterization of individual particles. This paper comprehensively reviews the applications of such a technique in studying atmospheric particles, especially for their physicochemical processing.
Zhi-Hui Zhang, Elena Hartner, Battist Utinger, Benjamin Gfeller, Andreas Paul, Martin Sklorz, Hendryk Czech, Bin Xia Yang, Xin Yi Su, Gert Jakobi, Jürgen Orasche, Jürgen Schnelle-Kreis, Seongho Jeong, Thomas Gröger, Michal Pardo, Thorsten Hohaus, Thomas Adam, Astrid Kiendler-Scharr, Yinon Rudich, Ralf Zimmermann, and Markus Kalberer
Atmos. Chem. Phys., 22, 1793–1809, https://doi.org/10.5194/acp-22-1793-2022, https://doi.org/10.5194/acp-22-1793-2022, 2022
Short summary
Short summary
Using a novel setup, we comprehensively characterized the formation of particle-bound reactive oxygen species (ROS) in anthropogenic and biogenic secondary organic aerosols (SOAs). We found that more than 90 % of all ROS components in both SOA types have a short lifetime. Our results also show that photochemical aging promotes particle-bound ROS production and enhances the oxidative potential of the aerosols. We found consistent results between chemical-based and biological-based ROS analyses.
Kelvin H. Bates, Guy J. P. Burke, James D. Cope, and Tran B. Nguyen
Atmos. Chem. Phys., 22, 1467–1482, https://doi.org/10.5194/acp-22-1467-2022, https://doi.org/10.5194/acp-22-1467-2022, 2022
Short summary
Short summary
The main nighttime sink of α-pinene, a hydrocarbon abundantly emitted by plants, is reaction with NO3 to form nitrooxy peroxy radicals (nRO2). Using uniquely designed chamber experiments, we show that this reaction is a major source of organic aerosol when nRO2 reacts with other nRO2 and forms a nitrooxy hydroperoxide when nRO2 reacts with HO2. Under ambient conditions these pathways are key loss processes of atmospheric reactive nitrogen in areas with mixed biogenic and anthropogenic influence.
Sophia M. Charan, Yuanlong Huang, Reina S. Buenconsejo, Qi Li, David R. Cocker III, and John H. Seinfeld
Atmos. Chem. Phys., 22, 917–928, https://doi.org/10.5194/acp-22-917-2022, https://doi.org/10.5194/acp-22-917-2022, 2022
Short summary
Short summary
In this study, we investigate the secondary organic aerosol formation potential of decamethylcyclopentasiloxane (D5), which is used as a tracer for volatile chemical products and measured in high concentrations both outdoors and indoors. By performing experiments in different types of reactors, we find that D5’s aerosol formation is highly dependent on OH, and, at low OH concentrations or exposures, D5 forms little aerosol. We also reconcile results from other studies.
Beatrix Rosette Go Mabato, Yan Lyu, Yan Ji, Yong Jie Li, Dan Dan Huang, Xue Li, Theodora Nah, Chun Ho Lam, and Chak K. Chan
Atmos. Chem. Phys., 22, 273–293, https://doi.org/10.5194/acp-22-273-2022, https://doi.org/10.5194/acp-22-273-2022, 2022
Short summary
Short summary
Biomass burning (BB) is a global phenomenon that releases large quantities of pollutants such as phenols and aromatic carbonyls into the atmosphere. These compounds can form secondary organic aerosols (SOAs) which play an important role in the Earth’s energy budget. In this work, we demonstrated that the direct irradiation of vanillin (VL) could generate aqueous SOA (aqSOA) such as oligomers. In the presence of nitrate, VL photo-oxidation can also form nitrated compounds.
Zijun Li, Angela Buchholz, Arttu Ylisirniö, Luis Barreira, Liqing Hao, Siegfried Schobesberger, Taina Yli-Juuti, and Annele Virtanen
Atmos. Chem. Phys., 21, 18283–18302, https://doi.org/10.5194/acp-21-18283-2021, https://doi.org/10.5194/acp-21-18283-2021, 2021
Short summary
Short summary
We compared the evolution of two types of secondary organic aerosol (SOA) particles during isothermal evaporation. The sesquiterpene SOA particles demonstrated higher resilience to evaporation than α-pinene SOA particles generated under comparable conditions. In-depth analysis showed that under high-relative-humidity conditions, particulate water drove the evolution of particulate constituents by reducing the particle viscosity and initiating chemical aqueous-phase processes.
András Hoffer, Ádám Tóth, Beatrix Jancsek-Turóczi, Attila Machon, Aida Meiramova, Attila Nagy, Luminita Marmureanu, and András Gelencsér
Atmos. Chem. Phys., 21, 17855–17864, https://doi.org/10.5194/acp-21-17855-2021, https://doi.org/10.5194/acp-21-17855-2021, 2021
Short summary
Short summary
Due to the widespread use of plastics high amounts of waste are burned in households worldwide, emitting vast amounts of PM10 and PAHs into the atmosphere. In this work different types of common plastics were burned in the laboratory with a view to identifying potentially specific tracer compounds and determining their emission factors. The compounds found were also successfully identified in atmospheric PM10 samples, indicating their potential use as ambient tracers for illegal waste burning.
Shijie Liu, Dandan Huang, Yiqian Wang, Si Zhang, Xiaodi Liu, Can Wu, Wei Du, and Gehui Wang
Atmos. Chem. Phys., 21, 17759–17773, https://doi.org/10.5194/acp-21-17759-2021, https://doi.org/10.5194/acp-21-17759-2021, 2021
Short summary
Short summary
A series of chamber experiments was performed to probe the individual and common effects of NH3 and NOx on toluene secondary organic aerosol (SOA) formation through OH photooxidation. The synergetic effects of NH3 and NOx on the toluene SOA concentration and optical absorption were observed. The higher-volatility products formed in the presence of NOx could precipitate into the particle phase when NH3 was added. The formation pathways of N-containing OAs through NOx or NH3 are also discussed.
Lucía Caudillo, Birte Rörup, Martin Heinritzi, Guillaume Marie, Mario Simon, Andrea C. Wagner, Tatjana Müller, Manuel Granzin, Antonio Amorim, Farnoush Ataei, Rima Baalbaki, Barbara Bertozzi, Zoé Brasseur, Randall Chiu, Biwu Chu, Lubna Dada, Jonathan Duplissy, Henning Finkenzeller, Loïc Gonzalez Carracedo, Xu-Cheng He, Victoria Hofbauer, Weimeng Kong, Houssni Lamkaddam, Chuan P. Lee, Brandon Lopez, Naser G. A. Mahfouz, Vladimir Makhmutov, Hanna E. Manninen, Ruby Marten, Dario Massabò, Roy L. Mauldin, Bernhard Mentler, Ugo Molteni, Antti Onnela, Joschka Pfeifer, Maxim Philippov, Ana A. Piedehierro, Meredith Schervish, Wiebke Scholz, Benjamin Schulze, Jiali Shen, Dominik Stolzenburg, Yuri Stozhkov, Mihnea Surdu, Christian Tauber, Yee Jun Tham, Ping Tian, António Tomé, Steffen Vogt, Mingyi Wang, Dongyu S. Wang, Stefan K. Weber, André Welti, Wang Yonghong, Wu Yusheng, Marcel Zauner-Wieczorek, Urs Baltensperger, Imad El Haddad, Richard C. Flagan, Armin Hansel, Kristina Höhler, Jasper Kirkby, Markku Kulmala, Katrianne Lehtipalo, Ottmar Möhler, Harald Saathoff, Rainer Volkamer, Paul M. Winkler, Neil M. Donahue, Andreas Kürten, and Joachim Curtius
Atmos. Chem. Phys., 21, 17099–17114, https://doi.org/10.5194/acp-21-17099-2021, https://doi.org/10.5194/acp-21-17099-2021, 2021
Short summary
Short summary
We performed experiments in the CLOUD chamber at CERN at low temperatures to simulate new particle formation in the upper free troposphere (at −30 ºC and −50 ºC). We measured the particle and gas phase and found that most of the compounds present in the gas phase are detected as well in the particle phase. The major compounds in the particles are C8–10 and C18–20. Specifically, we showed that C5 and C15 compounds are detected in a mixed system with isoprene and α-pinene at −30 ºC, 20 % RH.
Daniel A. Knopf and Markus Ammann
Atmos. Chem. Phys., 21, 15725–15753, https://doi.org/10.5194/acp-21-15725-2021, https://doi.org/10.5194/acp-21-15725-2021, 2021
Short summary
Short summary
Adsorption on and desorption of gas molecules from solid or liquid surfaces or interfaces represent the initial interaction of gas-to-condensed-phase processes that can define the physicochemical evolution of the condensed phase. We apply a thermodynamic and microscopic treatment of these multiphase processes to evaluate how adsorption and desorption rates and surface accommodation depend on the choice of adsorption model and standard states with implications for desorption energy and lifetimes.
Spiro D. Jorga, Kalliopi Florou, Christos Kaltsonoudis, John K. Kodros, Christina Vasilakopoulou, Manuela Cirtog, Axel Fouqueau, Bénédicte Picquet-Varrault, Athanasios Nenes, and Spyros N. Pandis
Atmos. Chem. Phys., 21, 15337–15349, https://doi.org/10.5194/acp-21-15337-2021, https://doi.org/10.5194/acp-21-15337-2021, 2021
Short summary
Short summary
We test the hypothesis that significant secondary organic aerosol production can take place even during winter nights through the oxidation of the emitted organic vapors by the nitrate radicals produced during the reaction of ozone and nitrogen oxides. Our experiments, using as a starting point the ambient air of an urban area with high biomass burning activity, demonstrate that, even with sunlight, there is 20 %–70 % additional organic aerosol formed in a few hours.
Zirui Zhang, Wenfei Zhu, Min Hu, Kefan Liu, Hui Wang, Rongzhi Tang, Ruizhe Shen, Ying Yu, Rui Tan, Kai Song, Yuanju Li, Wenbin Zhang, Zhou Zhang, Hongming Xu, Shijin Shuai, Shuangde Li, Yunfa Chen, Jiayun Li, Yuesi Wang, and Song Guo
Atmos. Chem. Phys., 21, 15221–15237, https://doi.org/10.5194/acp-21-15221-2021, https://doi.org/10.5194/acp-21-15221-2021, 2021
Short summary
Short summary
We comprehensively investigated the mass growth potential, oxidation degree, formation pathway, and mass spectra features of typical urban-lifestyle secondary organic aerosols (SOAs) including vehicle SOAs and cooking SOAs. The mass spectra we acquired could provide necessary references to estimate the mass fractions of vehicle and cooking SOAs in the atmosphere, which would greatly decrease the uncertainty in air quality evaluation and health risk assessment in urban areas.
Wenfei Zhu, Song Guo, Zirui Zhang, Hui Wang, Ying Yu, Zheng Chen, Ruizhe Shen, Rui Tan, Kai Song, Kefan Liu, Rongzhi Tang, Yi Liu, Shengrong Lou, Yuanju Li, Wenbin Zhang, Zhou Zhang, Shijin Shuai, Hongming Xu, Shuangde Li, Yunfa Chen, Min Hu, Francesco Canonaco, and Andre S. H. Prévôt
Atmos. Chem. Phys., 21, 15065–15079, https://doi.org/10.5194/acp-21-15065-2021, https://doi.org/10.5194/acp-21-15065-2021, 2021
Short summary
Short summary
The experiments of primary emissions and secondary organic aerosol (SOA) formation from urban lifestyle sources (cooking and vehicles) were conducted. The mass spectral features of primary organic aerosol (POA) and SOA were characterized by using a high-resolution time-of-flight aerosol mass spectrometer. This work, for the first time, establishes the vehicle and cooking SOA source profiles and can be further used as source constraints in the OA source apportionment in the ambient atmosphere.
Adam Milsom, Adam M. Squires, Jacob A. Boswell, Nicholas J. Terrill, Andrew D. Ward, and Christian Pfrang
Atmos. Chem. Phys., 21, 15003–15021, https://doi.org/10.5194/acp-21-15003-2021, https://doi.org/10.5194/acp-21-15003-2021, 2021
Short summary
Short summary
Atmospheric aerosols can be solid, semi-solid or liquid. This phase state may impact key aerosol processes such as oxidation and water uptake, affecting cloud droplet formation and urban air pollution. We have observed a solid crystalline organic phase in a levitated proxy for cooking emissions, oleic acid. Spatially resolved structural changes were followed during ageing by X-ray scattering, revealing phase gradients, aggregate products and a markedly reduced ozonolysis reaction rate.
Cheng Wu, David M. Bell, Emelie L. Graham, Sophie Haslett, Ilona Riipinen, Urs Baltensperger, Amelie Bertrand, Stamatios Giannoukos, Janne Schoonbaert, Imad El Haddad, Andre S. H. Prevot, Wei Huang, and Claudia Mohr
Atmos. Chem. Phys., 21, 14907–14925, https://doi.org/10.5194/acp-21-14907-2021, https://doi.org/10.5194/acp-21-14907-2021, 2021
Short summary
Short summary
Night-time reactions of biogenic volatile organic compounds and nitrate radicals can lead to the formation of secondary organic aerosol (BSOANO3). Here, we study the impacts of light exposure on the BSOANO3 from three biogenic precursors. Our results suggest that photolysis causes photodegradation of a substantial fraction of BSOANO3, changes the chemical composition and bulk volatility, and might be a potentially important loss pathway of BSOANO3 during the night-to-day transition.
Mao Xiao, Christopher R. Hoyle, Lubna Dada, Dominik Stolzenburg, Andreas Kürten, Mingyi Wang, Houssni Lamkaddam, Olga Garmash, Bernhard Mentler, Ugo Molteni, Andrea Baccarini, Mario Simon, Xu-Cheng He, Katrianne Lehtipalo, Lauri R. Ahonen, Rima Baalbaki, Paulus S. Bauer, Lisa Beck, David Bell, Federico Bianchi, Sophia Brilke, Dexian Chen, Randall Chiu, António Dias, Jonathan Duplissy, Henning Finkenzeller, Hamish Gordon, Victoria Hofbauer, Changhyuk Kim, Theodore K. Koenig, Janne Lampilahti, Chuan Ping Lee, Zijun Li, Huajun Mai, Vladimir Makhmutov, Hanna E. Manninen, Ruby Marten, Serge Mathot, Roy L. Mauldin, Wei Nie, Antti Onnela, Eva Partoll, Tuukka Petäjä, Joschka Pfeifer, Veronika Pospisilova, Lauriane L. J. Quéléver, Matti Rissanen, Siegfried Schobesberger, Simone Schuchmann, Yuri Stozhkov, Christian Tauber, Yee Jun Tham, António Tomé, Miguel Vazquez-Pufleau, Andrea C. Wagner, Robert Wagner, Yonghong Wang, Lena Weitz, Daniela Wimmer, Yusheng Wu, Chao Yan, Penglin Ye, Qing Ye, Qiaozhi Zha, Xueqin Zhou, Antonio Amorim, Ken Carslaw, Joachim Curtius, Armin Hansel, Rainer Volkamer, Paul M. Winkler, Richard C. Flagan, Markku Kulmala, Douglas R. Worsnop, Jasper Kirkby, Neil M. Donahue, Urs Baltensperger, Imad El Haddad, and Josef Dommen
Atmos. Chem. Phys., 21, 14275–14291, https://doi.org/10.5194/acp-21-14275-2021, https://doi.org/10.5194/acp-21-14275-2021, 2021
Short summary
Short summary
Experiments at CLOUD show that in polluted environments new particle formation (NPF) is largely driven by the formation of sulfuric acid–base clusters, stabilized by amines, high ammonia concentrations or lower temperatures. While oxidation products of aromatics can nucleate, they play a minor role in urban NPF. Our experiments span 4 orders of magnitude variation of observed NPF rates in ambient conditions. We provide a framework based on NPF and growth rates to interpret ambient observations.
Cited articles
Ahrens, L., Harner, T., Shoeib, M., Lane, D. A., and Murphy, J. G.: Improved
characterization of gas–particle partitioning for per- and polyfluoroalkyl
substances in the atmosphere using annular diffusion denuder samplers,
Environ. Sci. Technol., 46, 7199–7206, https://doi.org/10.1021/es300898s,
2012.
Anenberg, S. C., Balakrishnan, K., Jetter, J., Masera, O., Mehta, S., Moss,
J., and Ramanathan, V.: Cleaner cooking solutions to achieve health,
climate, and economic cobenefits, Environ. Sci. Technol., 47,
3944–3952, https://doi.org/10.1021/es304942e, 2013.
Aunan, K., Berntsen, T. K., Myhre, G., Rypdal, K., Streets, D. G., Woo,
J.-H., and Smith, K. R.: Radiative forcing from household fuel burning in
Asia, Atmos. Environ., 43, 5674–5681,
https://doi.org/10.1016/j.atmosenv.2009.07.053, 2009.
Bond, T. C., Streets, D. G., Yarber, K. F., Nelson, S. M., Woo, J.-H., and
Klimont, Z.: A technology-based global inventory of black and organic carbon
emissions from combustion, J. Geophys. Res.-Atmos.,
109, D14203, https://doi.org/10.1029/2003jd003697, 2004.
Bonjour, S., Adair-Rohani, H., Wolf, J., Bruce Nigel, G., Mehta, S.,
Prüss-Ustün, A., Lahiff, M., Rehfuess Eva, A., Mishra, V., and Smith
Kirk, R.: Solid fuel use for household cooking: Country and regional
estimates for 1980–2010, Environ. Health Persp., 121, 784–790,
https://doi.org/10.1289/ehp.1205987, 2013.
Cao, G., Zhang, X., and Zheng, F.: Inventory of black carbon and organic
carbon emissions from China, Atmos. Environ., 40, 6516–6527,
https://doi.org/10.1016/j.atmosenv.2006.05.070, 2006.
Chen, Y. and Bond, T. C.: Light absorption by organic carbon from wood combustion, Atmos. Chem. Phys., 10, 1773–1787, https://doi.org/10.5194/acp-10-1773-2010, 2010.
Chen, Y., Sheng, G., Bi, X., Feng, Y., Mai, B., and Fu, J.: Emission factors
for carbonaceous particles and polycyclic aromatic hydrocarbons from
residential coal combustion in China, Environ. Sci. Technol.,
39, 1861–1867, https://doi.org/10.1021/es0493650, 2005.
Claeys, M., Vermeylen, R., Yasmeen, F., Gómez-González, Y., Chi, X.,
Maenhaut, W., Mészáros, T., and Salma, I.: Chemical characterisation
of humic-like substances from urban, rural and tropical biomass burning
environments using liquid chromatography with UV/vis photodiode array
detection and electrospray ionisation mass spectrometry, Environ.
Chem., 9, 273–284, https://doi.org/10.1071/EN11163, 2012.
De Haan, D. O., Hawkins, L. N., Welsh, H. G., Pednekar, R., Casar, J. R.,
Pennington, E. A., de Loera, A., Jimenez, N. G., Symons, M. A., Zauscher,
M., Pajunoja, A., Caponi, L., Cazaunau, M., Formenti, P., Gratien, A.,
Pangui, E., and Doussin, J.-F.: Brown carbon production in ammonium- or
amine-containing aerosol particles by reactive uptake of methylglyoxal and
photolytic cloud cycling, Environ. Sci. Technol., 51,
7458–7466, https://doi.org/10.1021/acs.est.7b00159, 2017.
Desyaterik, Y., Sun, Y., Shen, X., Lee, T., Wang, X., Wang, T., and Collett,
J. L.: Speciation of “brown” carbon in cloud water impacted by
agricultural biomass burning in eastern China, J. Geophys. Res.-Atmos., 118, 7389–7399, https://doi.org/10.1002/jgrd.50561, 2013.
Di Lorenzo, R. A. and Young, C. J.: Size separation method for absorption
characterization in brown carbon: Application to an aged biomass burning
sample, Geophys. Res. Lett., 43, 458–465, https://doi.org/10.1002/2015gl066954,
2016.
Di Lorenzo, R. A., Washenfelder, R. A., Attwood, A. R., Guo, H., Xu, L., Ng,
N. L., Weber, R. J., Baumann, K., Edgerton, E., and Young, C. J.:
Molecular-size-separated brown carbon absorption for biomass-burning aerosol
at multiple field sites, Environ. Sci. Technol., 51,
3128–3137, https://doi.org/10.1021/acs.est.6b06160, 2017.
Ding, Y., Pang, Y., and Eatough, D. J.: High-volume diffusion denuder
sampler for the routine monitoring of fine particulate matter: I. Design and
optimization of the PC-BOSS, Aerosol Sci. Technol., 36, 369–382,
https://doi.org/10.1080/027868202753571205, 2002.
Donahue, N. M., Epstein, S. A., Pandis, S. N., and Robinson, A. L.: A two-dimensional volatility basis set: 1. organic-aerosol mixing thermodynamics, Atmos. Chem. Phys., 11, 3303–3318, https://doi.org/10.5194/acp-11-3303-2011, 2011.
Feng, Y., Ramanathan, V., and Kotamarthi, V. R.: Brown carbon: a significant atmospheric absorber of solar radiation?, Atmos. Chem. Phys., 13, 8607–8621, https://doi.org/10.5194/acp-13-8607-2013, 2013.
Fleming, L. T., Lin, P., Laskin, A., Laskin, J., Weltman, R., Edwards, R. D., Arora, N. K., Yadav, A., Meinardi, S., Blake, D. R., Pillarisetti, A., Smith, K. R., and Nizkorodov, S. A.: Molecular composition of particulate matter emissions from dung and brushwood burning household cookstoves in Haryana, India, Atmos. Chem. Phys., 18, 2461–2480, https://doi.org/10.5194/acp-18-2461-2018, 2018.
Forrister, H., Liu, J., Scheuer, E., Dibb, J., Ziemba, L., Thornhill, K. L.,
Anderson, B., Diskin, G., Perring, A. E., Schwarz, J. P., Campuzano-Jost,
P., Day, D. A., Palm, B. B., Jimenez, J. L., Nenes, A., and Weber, R. J.:
Evolution of brown carbon in wildfire plumes, Geophys. Res. Lett.,
42, 4623–4630, https://doi.org/10.1002/2015gl063897, 2015.
Gilman, J. B., Lerner, B. M., Kuster, W. C., Goldan, P. D., Warneke, C., Veres, P. R., Roberts, J. M., de Gouw, J. A., Burling, I. R., and Yokelson, R. J.: Biomass burning emissions and potential air quality impacts of volatile organic compounds and other trace gases from fuels common in the US, Atmos. Chem. Phys., 15, 13915–13938, https://doi.org/10.5194/acp-15-13915-2015, 2015.
Glarborg, P., Jensen, A., and Johnsson, J. E.: Fuel nitrogen conversion in
solid fuel fired systems, Prog. Energ. Combust., 29,
89–113, 2003.
Global Alliance for Clean Cookstoves: Water Boiling Test (WBT) 4.2.3,
Released 19 March 2014, available at:
http://cleancookstoves.org/technology-and-fuels/testing/protocols.html
(last access: July 2017), 2014.
Harrison, M. A., Barra, S., Borghesi, D., Vione, D., Arsene, C., and Olariu,
R. I.: Nitrated phenols in the atmosphere: a review, Atmos. Environ., 39, 231–248, 2005.
Hecobian, A., Zhang, X., Zheng, M., Frank, N., Edgerton, E. S., and Weber, R. J.: Water-Soluble Organic Aerosol material and the light-absorption characteristics of aqueous extracts measured over the Southeastern United States, Atmos. Chem. Phys., 10, 5965–5977, https://doi.org/10.5194/acp-10-5965-2010, 2010.
Iinuma, Y., Böge, O., Gräfe, R., and Herrmann, H.:
Methyl-nitrocatechols: Atmospheric tracer compounds for biomass burning
secondary organic aerosols, Environ. Sci. Technol., 44,
8453–8459, https://doi.org/10.1021/es102938a, 2010.
International Agency for Research on Cancer: Some non-heterocyclic
polycyclic aromatic hydrocarbons and some related exposures (Vol. 92), IARC
Press, International Agency for Research on Cancer, Lyon, France, 2010.
Jaeckels, J. M., Bae, M. S., and Schauer, J. J.: Positive matrix
factorization (PMF) analysis of molecular marker measurements to quantify
the sources of organic aerosols, Environ. Sci. Technol., 41,
5763–5769, https://doi.org/10.1021/es062536b, 2007.
Jetter, J. J. and Kariher, P.: Solid-fuel household cook stoves:
Characterization of performance and emissions, Biomass and Bioenergy, 33,
294–305, https://doi.org/10.1016/j.biombioe.2008.05.014, 2009.
Jetter, J., Zhao, Y., Smith, K. R., Khan, B., Yelverton, T., DeCarlo, P.,
and Hays, M. D.: Pollutant emissions and energy efficiency under controlled
conditions for household biomass cookstoves and implications for metrics
useful in setting international test standards, Environ. Sci. Technol., 46, 10827–10834, https://doi.org/10.1021/es301693f, 2012.
Kaal, J., Martínez Cortizas, A., and Nierop, K. G. J.: Characterisation
of aged charcoal using a coil probe pyrolysis-GC/MS method optimised for
black carbon, J. Anal. Appl. Pyrol., 85, 408–416,
https://doi.org/10.1016/j.jaap.2008.11.007, 2009.
Kim, K.-H., Jahan, S. A., Kabir, E., and Brown, R. J. C.: A review of
airborne polycyclic aromatic hydrocarbons (PAHs) and their human health
effects, Environ. Int., 60, 71–80,
https://doi.org/10.1016/j.envint.2013.07.019, 2013.
Kim Oanh, N. T., Bætz Reutergårdh, L., and Dung, N. T.: Emission of
polycyclic aromatic hydrocarbons and particulate matter from domestic
combustion of selected fuels, Environ. Sci. Technol., 33,
2703–2709, https://doi.org/10.1021/es980853f, 1999.
Kirchstetter, T. W., Corrigan, C. E., and Novakov, T.: Laboratory and field
investigation of the adsorption of gaseous organic compounds onto quartz
filters, Atmos. Environ., 35, 1663–1671,
https://doi.org/10.1016/S1352-2310(00)00448-9, 2001.
Klimont, Z., Cofala, J., Xing, J., Wei, W., Zhang, C., Wang, S., Kejun, J.,
Bhandari, P., Mathur, R., Purohit, P., Rafaj, P., Chambers, A., Amann, M.,
and Hao, J.: Projections of SO2, NOx and carbonaceous aerosols emissions in
Asia, Tellus B, 61, 602–617, https://doi.org/10.1111/j.1600-0889.2009.00428.x, 2009.
Kwamena, N.-O. and Abbatt, J.: Heterogeneous nitration reactions of
polycyclic aromatic hydrocarbons and n-hexane soot by exposure to
NO3/NO2/N2O5, Atmos. Environ., 42, 8309–8314, 2008.
Lacey, F. and Henze, D.: Global climate impacts of country-level primary
carbonaceous aerosol from solid-fuel cookstove emissions, Environ.
Res. Lett., 10, 114003, https://doi.org/10.1088/1748-9326/10/11/114003, 2015.
Lei, Y., Zhang, Q., He, K. B., and Streets, D. G.: Primary anthropogenic aerosol emission trends for China, 1990–2005, Atmos. Chem. Phys., 11, 931–954, https://doi.org/10.5194/acp-11-931-2011, 2011.
Li, Q., Jacob, D. J., Bey, I., Yantosca, R. M., Zhao, Y., Kondo, Y., and
Notholt, J.: Atmospheric hydrogen cyanide (HCN): Biomass burning source,
ocean sink?, Geophys. Res. Lett., 27, 357–360,
https://doi.org/10.1029/1999gl010935, 2000.
Lin, P., Liu, J. M., Shilling, J. E., Kathmann, S. M., Laskin, J., and
Laskin, A.: Molecular characterization of brown carbon (BrC) chromophores in
secondary organic aerosol generated from photo-oxidation of toluene,
Phys. Chem. Chem. Phys., 17, 23312–23325, https://doi.org/10.1039/c5cp02563j,
2015.
Lin, P., Aiona, P. K., Li, Y., Shiraiwa, M., Laskin, J., Nizkorodov, S. A.,
and Laskin, A.: Molecular characterization of brown carbon in biomass
burning aerosol particles, Environ. Sci. Technol., 50,
11815–11824, https://doi.org/10.1021/acs.est.6b03024, 2016.
Lin, P., Bluvshtein, N., Rudich, Y., Nizkorodov, S. A., Laskin, J., and
Laskin, A.: Molecular chemistry of atmospheric brown carbon inferred from a
nationwide biomass burning event, Environ. Sci. Technol., 51,
11561–11570, https://doi.org/10.1021/acs.est.7b02276, 2017.
Liu, J., Bergin, M., Guo, H., King, L., Kotra, N., Edgerton, E., and Weber, R. J.: Size-resolved measurements of brown carbon in water and methanol extracts and estimates of their contribution to ambient fine-particle light absorption, Atmos. Chem. Phys., 13, 12389–12404, https://doi.org/10.5194/acp-13-12389-2013, 2013.
Lu, C., Wang, X., Li, R., Gu, R., Zhang, Y., Li, W., Gao, R., Chen, B., Xue,
L., and Wang, W.: Emissions of fine particulate nitrated phenols from
residential coal combustion in China, Atmos. Environ., 203, 10–17,
https://doi.org/10.1016/j.atmosenv.2019.01.047, 2019.
Lu, J. W., Flores, J. M., Lavi, A., Abo-Riziq, A., and Rudich, Y.: Changes
in the optical properties of benzo[a]pyrene-coated aerosols upon
heterogeneous reactions with NO2 and NO3, Phys. Chem. Chem.
Phys., 13, 6484–6492, https://doi.org/10.1039/C0CP02114H, 2011.
Lu, Z., Streets, D. G., Winijkul, E., Yan, F., Chen, Y., Bond, T. C., Feng,
Y., Dubey, M. K., Liu, S., Pinto, J. P., and Carmichael, G. R.: Light
absorption properties and radiative effects of primary organic aerosol
emissions, Environ. Sci. Technol., 49, 4868–4877,
https://doi.org/10.1021/acs.est.5b00211, 2015.
McMeeking, G., Fortner, E., Onasch, T., Taylor, J., Flynn, M., Coe, H., and
Kreidenweis, S.: Impacts of nonrefractory material on light absorption by
aerosols emitted from biomass burning, J. Geophys. Res.-Atmos., 119, 12272–12286, 2014.
Mohr, C., Lopez-Hilfiker, F. D., Zotter, P., Prévôt, A. S. H., Xu,
L., Ng, N. L., Herndon, S. C., Williams, L. R., Franklin, J. P., Zahniser,
M. S., Worsnop, D. R., Knighton, W. B., Aiken, A. C., Gorkowski, K. J.,
Dubey, M. K., Allan, J. D., and Thornton, J. A.: Contribution of nitrated
phenols to wood burning brown carbon light absorption in Detling, United
Kingdom during winter time, Environ. Sci. Technol., 47,
6316–6324, https://doi.org/10.1021/es400683v, 2013.
Nakayama, T., Matsumi, Y., Sato, K., Imamura, T., Yamazaki, A., and
Uchiyama, A.: Laboratory studies on optical properties of secondary organic
aerosols generated during the photooxidation of toluene and the ozonolysis
of α-pinene, J. Geophys. Res.-Atmos., 115, D24204, https://doi.org/10.1029/2010jd014387, 2010.
Park, R. J., Kim, M. J., Jeong, J. I., Youn, D., and Kim, S.: A contribution
of brown carbon aerosol to the aerosol light absorption and its radiative
forcing in East Asia, Atmos. Environ., 44, 1414–1421,
https://doi.org/10.1016/j.atmosenv.2010.01.042, 2010.
Peters, A. J., Lane, D. A., Gundel, L. A., Northcott, G. L., and Jones, K.
C.: A comparison of high volume and diffusion denuder samplers for measuring
semivolatile organic compounds in the atmosphere, Environ. Sci. Technol., 34, 5001–5006, https://doi.org/10.1021/es000056t, 2000.
Pokhrel, R. P., Wagner, N. L., Langridge, J. M., Lack, D. A., Jayarathne, T., Stone, E. A., Stockwell, C. E., Yokelson, R. J., and Murphy, S. M.: Parameterization of single-scattering albedo (SSA) and absorption Ångström exponent (AAE) with EC∕OC for aerosol emissions from biomass burning, Atmos. Chem. Phys., 16, 9549–9561, https://doi.org/10.5194/acp-16-9549-2016, 2016.
Ravindra, K., Sokhi, R., and Van Grieken, R.: Atmospheric polycyclic
aromatic hydrocarbons: Source attribution, emission factors and regulation,
Atmos. Environ., 42, 2895–2921,
https://doi.org/10.1016/j.atmosenv.2007.12.010, 2008.
Reff, A., Bhave, P. V., Simon, H., Pace, T. G., Pouliot, G. A., Mobley, J.
D., and Houyoux, M.: Emissions inventory of PM2.5 trace elements across the
United States, Environ. Sci. Technol., 43, 5790–5796,
https://doi.org/10.1021/es802930x, 2009.
Riddle, S. G., Jakober, C. A., Robert, M. A., Cahill, T. M., Charles, M. J.,
and Kleeman, M. J.: Large PAHs detected in fine particulate matter emitted
from light-duty gasoline vehicles, Atmos. Environ., 41, 8658–8668,
https://doi.org/10.1016/j.atmosenv.2007.07.023, 2007.
Saleh, R., Robinson, E. S., Tkacik, D. S., Ahern, A. T., Liu, S., Aiken, A.
C., Sullivan, R. C., Presto, A. A., Dubey, M. K., Yokelson, R. J., Donahue,
N. M., and Robinson, A. L.: Brownness of organics in aerosols from biomass
burning linked to their black carbon content, Nat. Geosci., 7, 647–650,
https://doi.org/10.1038/ngeo2220, 2014.
Samburova, V., Connolly, J., Gyawali, M., Yatavelli, R. L. N., Watts, A. C.,
Chakrabarty, R. K., Zielinska, B., Moosmüller, H., and Khlystov, A.:
Polycyclic aromatic hydrocarbons in biomass-burning emissions and their
contribution to light absorption and aerosol toxicity, Sci. Total
Environ., 568, 391–401, https://doi.org/10.1016/j.scitotenv.2016.06.026,
2016.
Schneider, J., Bürger, V., and Arnold, F.: Methyl cyanide and hydrogen
cyanide measurements in the lower stratosphere: Implications for methyl
cyanide sources and sinks, J. Geophys. Res.-Atmos.,
102, 25501–25506, https://doi.org/10.1029/97jd02364, 1997.
Shen, G., Tao, S., Wei, S., Zhang, Y., Wang, R., Wang, B., Li, W., Shen, H.,
Huang, Y., Chen, Y., Chen, H., Yang, Y., Wang, W., Wei, W., Wang, X., Liu,
W., Wang, X., and Simonich, S. L. M.: Reductions in Emissions of
Carbonaceous particulate matter and polycyclic aromatic hydrocarbons from
combustion of biomass pellets in comparison with raw fuel burning,
Environ. Sci. Technol., 46, 6409–6416, https://doi.org/10.1021/es300369d,
2012.
Shrivastava, M. K., Subramanian, R., Rogge, W. F., and Robinson, A. L.:
Sources of organic aerosol: Positive matrix factorization of molecular
marker data and comparison of results from different source apportionment
models, Atmos. Environ., 41, 9353–9369,
https://doi.org/10.1016/j.atmosenv.2007.09.016, 2007.
Simoneit, B. R.: Biomass burning – a review of organic tracers for smoke
from incomplete combustion, Appl. Geochem., 17, 129–162, 2002.
Simoneit, B. R., Rogge, W., Mazurek, M., Standley, L., Hildemann, L., and
Cass, G.: Lignin pyrolysis products, lignans, and resin acids as specific
tracers of plant classes in emissions from biomass combustion, Environ. Sci. Technol., 27, 2533–2541, 1993.
Smith, K. R., Bruce, N., Balakrishnan, K., Adair-Rohani, H., Balmes, J.,
Chafe, Z., Dherani, M., Hosgood, H. D., Mehta, S., Pope, D., and Rehfuess,
E.: Millions dead: How do we know and what does it mean? Methods used in the
comparative risk assessment of household air pollution, Annu. Rev.
Publ. Health, 35, 185–206, https://doi.org/10.1146/annurev-publhealth-032013-182356, 2014.
Subramanian, R., Khlystov, A. Y., Cabada, J. C., and Robinson, A. L.:
Positive and negative artifacts in particulate organic carbon measurements
with denuded and undenuded sampler configurations special issue of Aerosol
Science and Technology on findings from the fine particulate matter
supersites program, Aerosol Sci. Technol., 38, 27–48,
https://doi.org/10.1080/02786820390229354, 2004.
Sun, J., Zhi, G., Hitzenberger, R., Chen, Y., Tian, C., Zhang, Y., Feng, Y., Cheng, M., Zhang, Y., Cai, J., Chen, F., Qiu, Y., Jiang, Z., Li, J., Zhang, G., and Mo, Y.: Emission factors and light absorption properties of brown carbon from household coal combustion in China, Atmos. Chem. Phys., 17, 4769–4780, https://doi.org/10.5194/acp-17-4769-2017, 2017.
Teich, M., van Pinxteren, D., Wang, M., Kecorius, S., Wang, Z., Müller, T., Močnik, G., and Herrmann, H.: Contributions of nitrated aromatic compounds to the light absorption of water-soluble and particulate brown carbon in different atmospheric environments in Germany and China, Atmos. Chem. Phys., 17, 1653–1672, https://doi.org/10.5194/acp-17-1653-2017, 2017.
Tuccella, P., Curci, G., Pitari, G., Lee, S., and Jo, D. S.: Direct
radiative effect of absorbing aerosols: sensitivity to mixing state, brown
carbon and soil dust refractive index and shape, J. Geophys. Res.-Atmos., 125, e2019JD030967, https://doi.org/10.1029/2019JD030967, 2020.
Turpin, B. J. and Lim, H.-J.: Species contributions to PM2.5 mass
concentrations: Revisiting common assumptions for estimating organic mass,
Aerosol Sci. Technol., 35, 602–610, https://doi.org/10.1080/02786820119445, 2001.
Wang, X., Heald, C. L., Ridley, D. A., Schwarz, J. P., Spackman, J. R., Perring, A. E., Coe, H., Liu, D., and Clarke, A. D.: Exploiting simultaneous observational constraints on mass and absorption to estimate the global direct radiative forcing of black carbon and brown carbon, Atmos. Chem. Phys., 14, 10989–11010, https://doi.org/10.5194/acp-14-10989-2014, 2014.
Wathore, R., Mortimer, K., and Grieshop, A. P.: In-use emissions and
estimated impacts of traditional, natural- and forced-draft cookstoves in
rural Malawi, Environ. Sci. Technol., 51, 1929–1938,
https://doi.org/10.1021/acs.est.6b05557, 2017.
Watson, J. G., Chow, J. C., Chen, L. W. A., and Frank, N. H.: Methods to
assess carbonaceous aerosol sampling artifacts for IMPROVE and other
long-term networks, J. Air Waste Manag. Assoc.,
59, 898–911, https://doi.org/10.3155/1047-3289.59.8.898, 2009.
Xie, M., Hannigan, M. P., Dutton, S. J., Milford, J. B., Hemann, J. G.,
Miller, S. L., Schauer, J. J., Peel, J. L., and Vedal, S.: Positive matrix
factorization of PM2.5: Comparison and implications of using different
speciation data sets, Environ. Sci. Technol., 46,
11962–11970, https://doi.org/10.1021/es302358g, 2012.
Xie, M., Piedrahita, R., Dutton, S. J., Milford, J. B., Hemann, J. G., Peel,
J. L., Miller, S. L., Kim, S.-Y., Vedal, S., Sheppard, L., and Hannigan, M.
P.: Positive matrix factorization of a 32-month series of daily PM2.5
speciation data with incorporation of temperature stratification,
Atmos. Environ., 65, 11–20,
https://doi.org/10.1016/j.atmosenv.2012.09.034, 2013.
Xie, M., Hannigan, M. P., and Barsanti, K. C.: Gas/particle partitioning of
n-alkanes, PAHs and oxygenated PAHs in urban Denver, Atmos. Environ., 95, 355–362, https://doi.org/10.1016/j.atmosenv.2014.06.056,
2014.
Xie, M., Chen, X., Hays, M. D., Lewandowski, M., Offenberg, J., Kleindienst,
T. E., and Holder, A. L.: Light absorption of secondary organic aerosol:
Composition and contribution of nitroaromatic compounds, Environ. Sci. Technol., 51, 11607–11616, https://doi.org/10.1021/acs.est.7b03263, 2017a.
Xie, M., Hays, M. D., and Holder, A. L.: Light-absorbing organic carbon from
prescribed and laboratory biomass burning and gasoline vehicle emissions,
Sci. Rep.-UK, 7, 7318, https://doi.org/10.1038/s41598-017-06981-8, 2017b.
Xie, M., Shen, G., Holder, A. L., Hays, M. D., and Jetter, J. J.: Light
absorption of organic carbon emitted from burning wood, charcoal, and
kerosene in household cookstoves, Environ. Pollut., 240, 60–67,
https://doi.org/10.1016/j.envpol.2018.04.085, 2018.
Xie, M., Chen, X., Hays, M. D., and Holder, A. L.: Composition and light absorption of N-containing aromatic compounds in organic aerosols from laboratory biomass burning, Atmos. Chem. Phys., 19, 2899–2915, https://doi.org/10.5194/acp-19-2899-2019, 2019.
Xie, M., Zhao, Z., Holder, A., Hays, M., Chen, X., Shen, G., Jetter, J., Champion, W., and Wang, Q. G.: Replication Data for: Chemical composition, structures, and light absorption of N-containing aromatic compounds emitted from burning wood and charcoal in household cookstoves, V1 ed., Harvard Dataverse, https://doi.org/10.7910/DVN/VERFPS, 2020.
Yang, M., Howell, S. G., Zhuang, J., and Huebert, B. J.: Attribution of aerosol light absorption to black carbon, brown carbon, and dust in China – interpretations of atmospheric measurements during EAST-AIRE, Atmos. Chem. Phys., 9, 2035–2050, https://doi.org/10.5194/acp-9-2035-2009, 2009.
Zhang, X., Lin, Y.-H., Surratt, J. D., and Weber, R. J.: Sources,
composition and absorption Ångström exponent of light-absorbing
organic components in aerosol extracts from the Los Angeles basin,
Environ. Sci. Technol., 47, 3685–3693, https://doi.org/10.1021/es305047b,
2013.
Short summary
This study investigated the composition, structures, and light absorption of N-containing aromatic compounds (NACs) in PM2.5 emitted from burning red oak and charcoal in a variety of cookstoves. The results suggest that the identified NACs might have substantial fractions remaining in the gas phase. In comparison to other sources, cookstove emissions from red oak or charcoal fuels did not exhibit unique NAC structural features but had distinct NAC composition.
This study investigated the composition, structures, and light absorption of N-containing...
Altmetrics
Final-revised paper
Preprint