Articles | Volume 19, issue 10
https://doi.org/10.5194/acp-19-7055-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-7055-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
24 May 2019
Research article |
| 24 May 2019
| 24 May 2019
Simultaneous shipborne measurements of CO2, CH4 and CO and their application to improving greenhouse-gas flux estimates in Australia
School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia
Nicholas M. Deutscher
School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia
Jenny A. Fisher
School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia
Dagmar Kubistin
School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia
German Meteorological Service, Meteorological Observatory Hohenpeißenberg, Hohenpeißenberg, Germany
Clare Paton-Walsh
School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia
David W. T. Griffith
School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia
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Mei Bai, Zoe Loh, David W. T. Griffith, Debra Turner, Richard Eckard, Robert Edis, Owen T. Denmead, Glenn W. Bryant, Clare Paton-Walsh, Matthew Tonini, Sean M. McGinn, and Deli Chen
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Atmos. Meas. Tech., 15, 2433–2463, https://doi.org/10.5194/amt-15-2433-2022, https://doi.org/10.5194/amt-15-2433-2022, 2022
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Edward Malina, Ben Veihelmann, Matthias Buschmann, Nicholas M. Deutscher, Dietrich G. Feist, and Isamu Morino
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Peter Sperlich, Gordon W. Brailsford, Rowena C. Moss, John McGregor, Ross J. Martin, Sylvia Nichol, Sara Mikaloff-Fletcher, Beata Bukosa, Magda Mandic, C. Ian Schipper, Paul Krummel, and Alan D. Griffiths
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Thomas E. Taylor, Christopher W. O'Dell, David Crisp, Akhiko Kuze, Hannakaisa Lindqvist, Paul O. Wennberg, Abhishek Chatterjee, Michael Gunson, Annmarie Eldering, Brendan Fisher, Matthäus Kiel, Robert R. Nelson, Aronne Merrelli, Greg Osterman, Frédéric Chevallier, Paul I. Palmer, Liang Feng, Nicholas M. Deutscher, Manvendra K. Dubey, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Cheng Liu, Martine De Mazière, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, David F. Pollard, Markus Rettinger, Matthias Schneider, Coleen M. Roehl, Mahesh Kumar Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Mihalis Vrekoussis, Thorsten Warneke, and Debra Wunch
Earth Syst. Sci. Data, 14, 325–360, https://doi.org/10.5194/essd-14-325-2022, https://doi.org/10.5194/essd-14-325-2022, 2022
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We provide an analysis of an 11-year record of atmospheric carbon dioxide (CO2) concentrations derived using an optimal estimation retrieval algorithm on measurements made by the GOSAT satellite. The new product (version 9) shows improvement over the previous version (v7.3) as evaluated against independent estimates of CO2 from ground-based sensors and atmospheric inversion systems. We also compare the new GOSAT CO2 values to collocated estimates from NASA's Orbiting Carbon Observatory-2.
Andrew Zammit-Mangion, Michael Bertolacci, Jenny Fisher, Ann Stavert, Matthew Rigby, Yi Cao, and Noel Cressie
Geosci. Model Dev., 15, 45–73, https://doi.org/10.5194/gmd-15-45-2022, https://doi.org/10.5194/gmd-15-45-2022, 2022
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We present a framework for estimating the sources and sinks (flux) of carbon dioxide from satellite data. The framework is statistical and yields measures of uncertainty alongside all estimates of flux and other parameters in the underlying model. It also allows us to generate other insights, such as the size of errors and biases in the data. The primary aim of this research was to develop a fully statistical flux inversion framework for use by atmospheric scientists.
Yohanna Villalobos, Peter J. Rayner, Jeremy D. Silver, Steven Thomas, Vanessa Haverd, Jürgen Knauer, Zoë M. Loh, Nicholas M. Deutscher, David W. T. Griffith, and David F. Pollard
Atmos. Chem. Phys., 21, 17453–17494, https://doi.org/10.5194/acp-21-17453-2021, https://doi.org/10.5194/acp-21-17453-2021, 2021
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Semi-arid ecosystems such as those in Australia are evolving and might play an essential role in the future of climate change. We use carbon dioxide concentrations derived from the OCO-2 satellite instrument and a regional transport model to understand if Australia was a carbon sink or source of CO2 in 2015. Our research's main findings suggest that Australia acted as a carbon sink of about −0.41 ± 0.08 petagrams of carbon in 2015, driven primarily by savanna and sparsely vegetated ecosystems.
Mahesh Kumar Sha, Bavo Langerock, Jean-François L. Blavier, Thomas Blumenstock, Tobias Borsdorff, Matthias Buschmann, Angelika Dehn, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. García, David W. T. Griffith, Michel Grutter, James W. Hannigan, Frank Hase, Pauli Heikkinen, Christian Hermans, Laura T. Iraci, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Nicolas Kumps, Jochen Landgraf, Alba Lorente, Emmanuel Mahieu, Maria V. Makarova, Johan Mellqvist, Jean-Marc Metzger, Isamu Morino, Tomoo Nagahama, Justus Notholt, Hirofumi Ohyama, Ivan Ortega, Mathias Palm, Christof Petri, David F. Pollard, Markus Rettinger, John Robinson, Sébastien Roche, Coleen M. Roehl, Amelie N. Röhling, Constantina Rousogenous, Matthias Schneider, Kei Shiomi, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, Osamu Uchino, Voltaire A. Velazco, Corinne Vigouroux, Mihalis Vrekoussis, Pucai Wang, Thorsten Warneke, Tyler Wizenberg, Debra Wunch, Shoma Yamanouchi, Yang Yang, and Minqiang Zhou
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Revised manuscript not accepted
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Human activities led to rising levels of greenhouse gases (carbon dioxide (CO2), methane (CH4), carbon monoxide (CO)) in the atmosphere, threatening our future. We use models and measurements to predict and understand the climatological impact of these gases. Here, we describe a new simulation in the GEOS-Chem model that uses a more accurate method to simulate CO2, CH4 and CO, through their chemical dependence. Relative to the original simulations our results agree better with measurements.
Ilya Stanevich, Dylan B. A. Jones, Kimberly Strong, Martin Keller, Daven K. Henze, Robert J. Parker, Hartmut Boesch, Debra Wunch, Justus Notholt, Christof Petri, Thorsten Warneke, Ralf Sussmann, Matthias Schneider, Frank Hase, Rigel Kivi, Nicholas M. Deutscher, Voltaire A. Velazco, Kaley A. Walker, and Feng Deng
Atmos. Chem. Phys., 21, 9545–9572, https://doi.org/10.5194/acp-21-9545-2021, https://doi.org/10.5194/acp-21-9545-2021, 2021
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We explore the utility of a weak-constraint (WC) four-dimensional variational (4D-Var) data assimilation scheme for mitigating systematic errors in methane simulation in the GEOS-Chem model. We use data from the Greenhouse Gases Observing Satellite (GOSAT) and show that, compared to the traditional 4D-Var approach, the WC scheme improves the agreement between the model and independent observations. We find that the WC corrections to the model provide insight into the source of the errors.
Matthieu Dogniaux, Cyril Crevoisier, Raymond Armante, Virginie Capelle, Thibault Delahaye, Vincent Cassé, Martine De Mazière, Nicholas M. Deutscher, Dietrich G. Feist, Omaira E. Garcia, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Isamu Morino, Justus Notholt, David F. Pollard, Coleen M. Roehl, Kei Shiomi, Kimberly Strong, Yao Té, Voltaire A. Velazco, and Thorsten Warneke
Atmos. Meas. Tech., 14, 4689–4706, https://doi.org/10.5194/amt-14-4689-2021, https://doi.org/10.5194/amt-14-4689-2021, 2021
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We present the Adaptable 4A Inversion (5AI), an implementation of the optimal estimation (OE) algorithm, relying on the Automatized Atmospheric Absorption Atlas (4A/OP) radiative transfer model, that enables the retrieval of greenhouse gas atmospheric weighted columns from infrared measurements. It is tested on a sample of Orbiting Carbon Observatory-2 observations, and its results satisfactorily compare to several reference products, thus showing the reliability of 5AI OE implementation.
Stefan Noël, Maximilian Reuter, Michael Buchwitz, Jakob Borchardt, Michael Hilker, Heinrich Bovensmann, John P. Burrows, Antonio Di Noia, Hiroshi Suto, Yukio Yoshida, Matthias Buschmann, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Isamu Morino, Justus Notholt, Hirofumi Ohyama, Christof Petri, James R. Podolske, David F. Pollard, Mahesh Kumar Sha, Kei Shiomi, Ralf Sussmann, Yao Té, Voltaire A. Velazco, and Thorsten Warneke
Atmos. Meas. Tech., 14, 3837–3869, https://doi.org/10.5194/amt-14-3837-2021, https://doi.org/10.5194/amt-14-3837-2021, 2021
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We present the first GOSAT and GOSAT-2 XCO2 data derived with the FOCAL retrieval algorithm. Comparisons of the GOSAT-FOCAL product with other data reveal long-term agreement within about 1 ppm over 1 decade, differences in seasonal variations of about 0.5 ppm, and a mean regional bias to ground-based TCCON data of 0.56 ppm with a mean scatter of 1.89 ppm. GOSAT-2-FOCAL data are preliminary only, but first comparisons show that they compare well with the GOSAT-FOCAL results and TCCON.
Nicholas M. Deutscher, Travis A. Naylor, Christopher G. R. Caldow, Hamish L. McDougall, Alex G. Carter, and David W. T. Griffith
Atmos. Meas. Tech., 14, 3119–3130, https://doi.org/10.5194/amt-14-3119-2021, https://doi.org/10.5194/amt-14-3119-2021, 2021
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This work describes the performance of an open-path measurement system for greenhouse gases in an extended field trial. The instrument obtained measurement repeatability of 0.1 % or better for CO2 and CH4 measurements over a 1.55 km one-way pathway. Comparison to co-located in situ measurements allows characterisation of biases relative to global reference scales. The research was done to show the applicability of the technique and its ability to detect atmospheric-relevant sources and sinks.
Thomas Blumenstock, Frank Hase, Axel Keens, Denis Czurlok, Orfeo Colebatch, Omaira Garcia, David W. T. Griffith, Michel Grutter, James W. Hannigan, Pauli Heikkinen, Pascal Jeseck, Nicholas Jones, Rigel Kivi, Erik Lutsch, Maria Makarova, Hamud K. Imhasin, Johan Mellqvist, Isamu Morino, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Uwe Raffalski, Markus Rettinger, John Robinson, Matthias Schneider, Christian Servais, Dan Smale, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, and Voltaire A. Velazco
Atmos. Meas. Tech., 14, 1239–1252, https://doi.org/10.5194/amt-14-1239-2021, https://doi.org/10.5194/amt-14-1239-2021, 2021
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This study investigates the level of channeling (optical resonances) of each FTIR spectrometer within the Network for the Detection of Atmospheric Composition Change (NDACC). Since the air gap of the beam splitter is a significant source of channeling, we propose new beam splitters with an increased wedge of the air gap. This study shows the potential for reducing channeling in the FTIR spectrometers operated by the NDACC, thereby increasing the quality of recorded spectra across the network.
Alba Lorente, Tobias Borsdorff, Andre Butz, Otto Hasekamp, Joost aan de Brugh, Andreas Schneider, Lianghai Wu, Frank Hase, Rigel Kivi, Debra Wunch, David F. Pollard, Kei Shiomi, Nicholas M. Deutscher, Voltaire A. Velazco, Coleen M. Roehl, Paul O. Wennberg, Thorsten Warneke, and Jochen Landgraf
Atmos. Meas. Tech., 14, 665–684, https://doi.org/10.5194/amt-14-665-2021, https://doi.org/10.5194/amt-14-665-2021, 2021
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TROPOMI aboard Sentinel-5P satellite provides methane (CH4) measurements with exceptional temporal and spatial resolution. The study describes a series of improvements developed to retrieve CH4 from TROPOMI. The updated CH4 product features (among others) a more accurate a posteriori correction derived independently of any reference data. The validation of the improved data product shows good agreement with ground-based and satellite measurements, which highlights the quality of the TROPOMI CH4.
Robert J. Parker, Alex Webb, Hartmut Boesch, Peter Somkuti, Rocio Barrio Guillo, Antonio Di Noia, Nikoleta Kalaitzi, Jasdeep S. Anand, Peter Bergamaschi, Frederic Chevallier, Paul I. Palmer, Liang Feng, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Rigel Kivi, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, Christof Petri, David F. Pollard, Coleen Roehl, Mahesh K. Sha, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Yao Té, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, and Debra Wunch
Earth Syst. Sci. Data, 12, 3383–3412, https://doi.org/10.5194/essd-12-3383-2020, https://doi.org/10.5194/essd-12-3383-2020, 2020
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This work presents the latest release of the University of Leicester GOSAT methane data and acts as the definitive description of this dataset. We detail the processing, validation and evaluation involved in producing these data and highlight its many applications. With now over a decade of global atmospheric methane observations, this dataset has helped, and will continue to help, us better understand the global methane budget and investigate how it may respond to a future changing climate.
Erik Lutsch, Kimberly Strong, Dylan B. A. Jones, Thomas Blumenstock, Stephanie Conway, Jenny A. Fisher, James W. Hannigan, Frank Hase, Yasuko Kasai, Emmanuel Mahieu, Maria Makarova, Isamu Morino, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Anatoly V. Poberovskii, Ralf Sussmann, and Thorsten Warneke
Atmos. Chem. Phys., 20, 12813–12851, https://doi.org/10.5194/acp-20-12813-2020, https://doi.org/10.5194/acp-20-12813-2020, 2020
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This paper describes the use of a network of 10 Arctic and midlatitude ground-based FTIR measurement sites to detect enhancements of the wildfire tracers carbon monoxide, hydrogen cyanide, and ethane from 2003 to 2018. A tagged CO GEOS-Chem simulation is used for source attribution and to evaluate the relative contribution of CO sources to the FTIR measurements. The use of FTIR measurements allowed for the emission ratios of hydrogen cyanide and ethane to be quantified.
Hirofumi Ohyama, Isamu Morino, Voltaire A. Velazco, Theresa Klausner, Gerry Bagtasa, Matthäus Kiel, Matthias Frey, Akihiro Hori, Osamu Uchino, Tsuneo Matsunaga, Nicholas M. Deutscher, Joshua P. DiGangi, Yonghoon Choi, Glenn S. Diskin, Sally E. Pusede, Alina Fiehn, Anke Roiger, Michael Lichtenstern, Hans Schlager, Pao K. Wang, Charles C.-K. Chou, Maria Dolores Andrés-Hernández, and John P. Burrows
Atmos. Meas. Tech., 13, 5149–5163, https://doi.org/10.5194/amt-13-5149-2020, https://doi.org/10.5194/amt-13-5149-2020, 2020
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Column-averaged dry-air mole fractions of CO2 and CH4 measured by a solar viewing portable Fourier transform spectrometer (EM27/SUN) were validated with in situ profile data obtained during the transfer flights of two aircraft campaigns. Atmospheric dynamical properties based on ERA5 and WRF-Chem were used as criteria for selecting the best aircraft profiles for the validation. The resulting air-mass-independent correction factors for the EM27/SUN data were 0.9878 for CO2 and 0.9829 for CH4.
Mahesh Kumar Sha, Martine De Mazière, Justus Notholt, Thomas Blumenstock, Huilin Chen, Angelika Dehn, David W. T. Griffith, Frank Hase, Pauli Heikkinen, Christian Hermans, Alex Hoffmann, Marko Huebner, Nicholas Jones, Rigel Kivi, Bavo Langerock, Christof Petri, Francis Scolas, Qiansi Tu, and Damien Weidmann
Atmos. Meas. Tech., 13, 4791–4839, https://doi.org/10.5194/amt-13-4791-2020, https://doi.org/10.5194/amt-13-4791-2020, 2020
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We present the results of the 2017 FRM4GHG campaign at the Sodankylä TCCON site aimed at characterising the assessment of several low-cost portable instruments for precise solar absorption measurements of column-averaged dry-air mole fractions of CO2, CH4, and CO. The test instruments provided stable and precise measurements of these gases with quantified small biases. This qualifies the instruments to complement TCCON and expand the global coverage of ground-based measurements of these gases.
Ilya Stanevich, Dylan B. A. Jones, Kimberly Strong, Robert J. Parker, Hartmut Boesch, Debra Wunch, Justus Notholt, Christof Petri, Thorsten Warneke, Ralf Sussmann, Matthias Schneider, Frank Hase, Rigel Kivi, Nicholas M. Deutscher, Voltaire A. Velazco, Kaley A. Walker, and Feng Deng
Geosci. Model Dev., 13, 3839–3862, https://doi.org/10.5194/gmd-13-3839-2020, https://doi.org/10.5194/gmd-13-3839-2020, 2020
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Systematic errors in atmospheric models pose a challenge for inverse modeling studies of methane (CH4) emissions. We evaluated the CH4 simulation in the GEOS-Chem model at the horizontal resolutions of 4° × 5° and 2° × 2.5°. Our analysis identified resolution-dependent biases in the model, which we attributed to discrepancies between the two model resolutions in vertical transport in the troposphere and in stratosphere–troposphere exchange.
Becky Alexander, Tomás Sherwen, Christopher D. Holmes, Jenny A. Fisher, Qianjie Chen, Mat J. Evans, and Prasad Kasibhatla
Atmos. Chem. Phys., 20, 3859–3877, https://doi.org/10.5194/acp-20-3859-2020, https://doi.org/10.5194/acp-20-3859-2020, 2020
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Nitrogen oxides are important for the formation of tropospheric oxidants and are removed from the atmosphere mainly through the formation of nitrate. We compare observations of the oxygen isotopes of nitrate with a global model to test our understanding of the chemistry nitrate formation. We use the model to quantify nitrate formation pathways in the atmosphere and identify key uncertainties and their relevance for the oxidation capacity of the atmosphere.
Maximilian Reuter, Michael Buchwitz, Oliver Schneising, Stefan Noël, Heinrich Bovensmann, John P. Burrows, Hartmut Boesch, Antonio Di Noia, Jasdeep Anand, Robert J. Parker, Peter Somkuti, Lianghai Wu, Otto P. Hasekamp, Ilse Aben, Akihiko Kuze, Hiroshi Suto, Kei Shiomi, Yukio Yoshida, Isamu Morino, David Crisp, Christopher W. O'Dell, Justus Notholt, Christof Petri, Thorsten Warneke, Voltaire A. Velazco, Nicholas M. Deutscher, David W. T. Griffith, Rigel Kivi, David F. Pollard, Frank Hase, Ralf Sussmann, Yao V. Té, Kimberly Strong, Sébastien Roche, Mahesh K. Sha, Martine De Mazière, Dietrich G. Feist, Laura T. Iraci, Coleen M. Roehl, Christian Retscher, and Dinand Schepers
Atmos. Meas. Tech., 13, 789–819, https://doi.org/10.5194/amt-13-789-2020, https://doi.org/10.5194/amt-13-789-2020, 2020
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We present new satellite-derived data sets of atmospheric carbon dioxide (CO2) and methane (CH4). The data products are column-averaged dry-air mole fractions of CO2 and CH4, denoted XCO2 and XCH4. The products cover the years 2003–2018 and are merged Level 2 (satellite footprints) and merged Level 3 (gridded at monthly time and 5° x 5° spatial resolution) products obtained from combining several individual sensor products. We present the merging algorithms and product validation results.
Jonas Simon Wilzewski, Anke Roiger, Johan Strandgren, Jochen Landgraf, Dietrich G. Feist, Voltaire A. Velazco, Nicholas M. Deutscher, Isamu Morino, Hirofumi Ohyama, Yao Té, Rigel Kivi, Thorsten Warneke, Justus Notholt, Manvendra Dubey, Ralf Sussmann, Markus Rettinger, Frank Hase, Kei Shiomi, and André Butz
Atmos. Meas. Tech., 13, 731–745, https://doi.org/10.5194/amt-13-731-2020, https://doi.org/10.5194/amt-13-731-2020, 2020
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Through spectral degradation of GOSAT measurements in the 1.6 and 2.0 μm spectral bands, we mimic a single-band, passive satellite sensor for monitoring of CO2 emissions at fine spatial scales. We compare retrievals of XCO2 from these bands to TCCON and native GOSAT retrievals. At spectral resolutions near 1.3 nm, XCO2 retrievals from both bands show promising performance, but the 2.0 μm band is favorable due to better noise performance and the potential to retrieve some aerosol information.
Oliver Schneising, Michael Buchwitz, Maximilian Reuter, Heinrich Bovensmann, John P. Burrows, Tobias Borsdorff, Nicholas M. Deutscher, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Christian Hermans, Laura T. Iraci, Rigel Kivi, Jochen Landgraf, Isamu Morino, Justus Notholt, Christof Petri, David F. Pollard, Sébastien Roche, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Voltaire A. Velazco, Thorsten Warneke, and Debra Wunch
Atmos. Meas. Tech., 12, 6771–6802, https://doi.org/10.5194/amt-12-6771-2019, https://doi.org/10.5194/amt-12-6771-2019, 2019
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We introduce an algorithm that is used to simultaneously derive the abundances of the important atmospheric constituents carbon monoxide and methane from the TROPOMI instrument onboard the Sentinel-5 Precursor satellite, which enables the determination of both gases with an unprecedented level of detail on a global scale. The quality of the resulting data sets is assessed and the first results are presented.
Susan S. Kulawik, Sean Crowell, David Baker, Junjie Liu, Kathryn McKain, Colm Sweeney, Sebastien C. Biraud, Steve Wofsy, Christopher W. O'Dell, Paul O. Wennberg, Debra Wunch, Coleen M. Roehl, Nicholas M. Deutscher, Matthäus Kiel, David W. T. Griffith, Voltaire A. Velazco, Justus Notholt, Thorsten Warneke, Christof Petri, Martine De Mazière, Mahesh K. Sha, Ralf Sussmann, Markus Rettinger, Dave F. Pollard, Isamu Morino, Osamu Uchino, Frank Hase, Dietrich G. Feist, Sébastien Roche, Kimberly Strong, Rigel Kivi, Laura Iraci, Kei Shiomi, Manvendra K. Dubey, Eliezer Sepulveda, Omaira Elena Garcia Rodriguez, Yao Té, Pascal Jeseck, Pauli Heikkinen, Edward J. Dlugokencky, Michael R. Gunson, Annmarie Eldering, David Crisp, Brendan Fisher, and Gregory B. Osterman
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2019-257, https://doi.org/10.5194/amt-2019-257, 2019
Publication in AMT not foreseen
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This paper provides a benchmark of OCO-2 v8 and ACOS-GOSAT v7.3 XCO2 and lowermost tropospheric (LMT) errors. The paper focuses on the systematic errors and subtracts out validation, co-location, and random errors, looks at the correlation scale-length (spatially and temporally) of systematic errors, finding that the scale lengths are similar to bias correction scale-lengths. The assimilates of the bias correction term is used to place an error on fluxes estimates.
Jacob K. Hedelius, Tai-Long He, Dylan B. A. Jones, Bianca C. Baier, Rebecca R. Buchholz, Martine De Mazière, Nicholas M. Deutscher, Manvendra K. Dubey, Dietrich G. Feist, David W. T. Griffith, Frank Hase, Laura T. Iraci, Pascal Jeseck, Matthäus Kiel, Rigel Kivi, Cheng Liu, Isamu Morino, Justus Notholt, Young-Suk Oh, Hirofumi Ohyama, David F. Pollard, Markus Rettinger, Sébastien Roche, Coleen M. Roehl, Matthias Schneider, Kei Shiomi, Kimberly Strong, Ralf Sussmann, Colm Sweeney, Yao Té, Osamu Uchino, Voltaire A. Velazco, Wei Wang, Thorsten Warneke, Paul O. Wennberg, Helen M. Worden, and Debra Wunch
Atmos. Meas. Tech., 12, 5547–5572, https://doi.org/10.5194/amt-12-5547-2019, https://doi.org/10.5194/amt-12-5547-2019, 2019
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We seek ways to improve the accuracy of column measurements of carbon monoxide (CO) – an important tracer of pollution – made from the MOPITT satellite instrument. We devise a filtering scheme which reduces the scatter and also eliminates bias among the MOPITT detectors. Compared to ground-based observations, MOPITT measurements are about 6 %–8 % higher. When MOPITT data are implemented in a global assimilation model, they tend to reduce the model mismatch with aircraft measurements.
Laura Cartwright, Andrew Zammit-Mangion, Sangeeta Bhatia, Ivan Schroder, Frances Phillips, Trevor Coates, Karita Negandhi, Travis Naylor, Martin Kennedy, Steve Zegelin, Nick Wokker, Nicholas M. Deutscher, and Andrew Feitz
Atmos. Meas. Tech., 12, 4659–4676, https://doi.org/10.5194/amt-12-4659-2019, https://doi.org/10.5194/amt-12-4659-2019, 2019
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Despite extensive research, emission detection and quantification of greenhouse gases (GHGs) remain an open problem. This article presents a novel statistical framework for detecting and quantifying methane emissions and showcases its efficacy on data collected from different instruments in the 2015 Ginninderra controlled-release experiment. The developed techniques can be used to aid GHG emission reduction schemes by, for example, detecting and quantifying leaks from carbon storage facilities.
Voltaire A. Velazco, Nicholas M. Deutscher, Isamu Morino, Osamu Uchino, Beata Bukosa, Masataka Ajiro, Akihide Kamei, Nicholas B. Jones, Clare Paton-Walsh, and David W. T. Griffith
Earth Syst. Sci. Data, 11, 935–946, https://doi.org/10.5194/essd-11-935-2019, https://doi.org/10.5194/essd-11-935-2019, 2019
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We present ground-based measurements of atmospheric carbon dioxide columns from a portable spectrometer taken in a semiarid region of Australia. We compared these measurements to space-based retrievals from the Greenhouse Gases Observing Satellite (GOSAT) and calibrated them against a Total Carbon Column Observing Network (TCCON) instrument to ascertain a retrieval bias. We also present the unique opportunities that Central Australia could offer in the context of satellite product validation.
Debra Wunch, Dylan B. A. Jones, Geoffrey C. Toon, Nicholas M. Deutscher, Frank Hase, Justus Notholt, Ralf Sussmann, Thorsten Warneke, Jeroen Kuenen, Hugo Denier van der Gon, Jenny A. Fisher, and Joannes D. Maasakkers
Atmos. Chem. Phys., 19, 3963–3980, https://doi.org/10.5194/acp-19-3963-2019, https://doi.org/10.5194/acp-19-3963-2019, 2019
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We used five atmospheric observatories in Europe measuring total column dry-air mole fractions of methane and carbon monoxide to infer methane emissions in the area between the observatories. We find that the methane emissions are overestimated by the state-of-the-art inventories, and that this is likely due, at least in part, to the inventory disaggregation. We find that there is significant uncertainty in the carbon monoxide inventories that requires further investigation.
Matthias Frey, Mahesh K. Sha, Frank Hase, Matthäus Kiel, Thomas Blumenstock, Roland Harig, Gregor Surawicz, Nicholas M. Deutscher, Kei Shiomi, Jonathan E. Franklin, Hartmut Bösch, Jia Chen, Michel Grutter, Hirofumi Ohyama, Youwen Sun, André Butz, Gizaw Mengistu Tsidu, Dragos Ene, Debra Wunch, Zhensong Cao, Omaira Garcia, Michel Ramonet, Felix Vogel, and Johannes Orphal
Atmos. Meas. Tech., 12, 1513–1530, https://doi.org/10.5194/amt-12-1513-2019, https://doi.org/10.5194/amt-12-1513-2019, 2019
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In a 3.5-year long study, the long-term performance of a mobile EM27/SUN spectrometer, used for greenhouse gas observations, is checked with respect to a co-located reference spectrometer. We find that the EM27/SUN is stable on timescales of several years, qualifying it for permanent carbon cycle studies.
The performance of an ensemble of 30 EM27/SUN spectrometers was also tested in the framework of the COllaborative Carbon Column Observing Network (COCCON) and found to be very uniform.
Minqiang Zhou, Bavo Langerock, Kelley C. Wells, Dylan B. Millet, Corinne Vigouroux, Mahesh Kumar Sha, Christian Hermans, Jean-Marc Metzger, Rigel Kivi, Pauli Heikkinen, Dan Smale, David F. Pollard, Nicholas Jones, Nicholas M. Deutscher, Thomas Blumenstock, Matthias Schneider, Mathias Palm, Justus Notholt, James W. Hannigan, and Martine De Mazière
Atmos. Meas. Tech., 12, 1393–1408, https://doi.org/10.5194/amt-12-1393-2019, https://doi.org/10.5194/amt-12-1393-2019, 2019
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N2O is an important atmospheric gas which is observed by two ground-based FTIR networks (TCCON and NDACC). The difference between NDACC and TCCON XN2O measurements is discussed. It is found that the bias between the two networks is within their combined uncertainties. However, TCCON measurements are affected by a priori profiles. In addition, the TCCON and NDACC N2O measurements are compared with the GEOS-Chem model simulations.
Nicole K. Scharko, Ashley M. Oeck, Russell G. Tonkyn, Stephen P. Baker, Emily N. Lincoln, Joey Chong, Bonni M. Corcoran, Gloria M. Burke, David R. Weise, Tanya L. Myers, Catherine A. Banach, David W. T. Griffith, and Timothy J. Johnson
Atmos. Meas. Tech., 12, 763–776, https://doi.org/10.5194/amt-12-763-2019, https://doi.org/10.5194/amt-12-763-2019, 2019
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We report five species (naphthalene, methyl nitrite, allene, acrolein and acetaldehyde) that were detected in biomass burning fires that had been seen before in burn studies, but are reported for the first time when using infrared spectroscopy for detection.
Dan Smale, Vanessa Sherlock, David W. T. Griffith, Rowena Moss, Gordon Brailsford, Sylvia Nichol, and Michael Kotkamp
Atmos. Meas. Tech., 12, 637–673, https://doi.org/10.5194/amt-12-637-2019, https://doi.org/10.5194/amt-12-637-2019, 2019
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We present a 10-year (Jan 2007–Dec 2016) time series of continuous in situ measurements of methane, carbon monoxide and nitrous oxide made by an in situ Fourier transform infrared trace gas and isotope analyser operated at Lauder, New Zealand. We perform a practical evaluation of multi-year performance of the analyser and report on operational methodology, measurement precision, reproducibility, accuracy and instrument reliability.
Christopher W. O'Dell, Annmarie Eldering, Paul O. Wennberg, David Crisp, Michael R. Gunson, Brendan Fisher, Christian Frankenberg, Matthäus Kiel, Hannakaisa Lindqvist, Lukas Mandrake, Aronne Merrelli, Vijay Natraj, Robert R. Nelson, Gregory B. Osterman, Vivienne H. Payne, Thomas E. Taylor, Debra Wunch, Brian J. Drouin, Fabiano Oyafuso, Albert Chang, James McDuffie, Michael Smyth, David F. Baker, Sourish Basu, Frédéric Chevallier, Sean M. R. Crowell, Liang Feng, Paul I. Palmer, Mavendra Dubey, Omaira E. García, David W. T. Griffith, Frank Hase, Laura T. Iraci, Rigel Kivi, Isamu Morino, Justus Notholt, Hirofumi Ohyama, Christof Petri, Coleen M. Roehl, Mahesh K. Sha, Kimberly Strong, Ralf Sussmann, Yao Te, Osamu Uchino, and Voltaire A. Velazco
Atmos. Meas. Tech., 11, 6539–6576, https://doi.org/10.5194/amt-11-6539-2018, https://doi.org/10.5194/amt-11-6539-2018, 2018
David W. T. Griffith
Atmos. Meas. Tech., 11, 6189–6201, https://doi.org/10.5194/amt-11-6189-2018, https://doi.org/10.5194/amt-11-6189-2018, 2018
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In recent years optical spectroscopic techniques have become commonly used in the determination of mole fractions of trace gases in air. These techniques in many cases determine the mole fractions of only individual isotopic variants (
isotopologues) of the trace gas, while for many applications the total mole fraction of all isotopologues is required. This paper sets out the measurements and calculations required to convert between individual isotopologue and total trace gas amounts.
Corinne Vigouroux, Carlos Augusto Bauer Aquino, Maite Bauwens, Cornelis Becker, Thomas Blumenstock, Martine De Mazière, Omaira García, Michel Grutter, César Guarin, James Hannigan, Frank Hase, Nicholas Jones, Rigel Kivi, Dmitry Koshelev, Bavo Langerock, Erik Lutsch, Maria Makarova, Jean-Marc Metzger, Jean-François Müller, Justus Notholt, Ivan Ortega, Mathias Palm, Clare Paton-Walsh, Anatoly Poberovskii, Markus Rettinger, John Robinson, Dan Smale, Trissevgeni Stavrakou, Wolfgang Stremme, Kim Strong, Ralf Sussmann, Yao Té, and Geoffrey Toon
Atmos. Meas. Tech., 11, 5049–5073, https://doi.org/10.5194/amt-11-5049-2018, https://doi.org/10.5194/amt-11-5049-2018, 2018
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A few ground-based stations have provided time series of HCHO columns until now, which was not optimal for providing good diagnostics for satellite or model validation. In this work, HCHO time series have been determined in a harmonized way at 21 stations ensuring, in addition to a better spatial and level of abundances coverage, that internal biases within the network have been minimized. This data set shows consistent good agreement with model data and is ready for future satellite validation.
Lianghai Wu, Otto Hasekamp, Haili Hu, Jochen Landgraf, Andre Butz, Joost aan de Brugh, Ilse Aben, Dave F. Pollard, David W. T. Griffith, Dietrich G. Feist, Dmitry Koshelev, Frank Hase, Geoffrey C. Toon, Hirofumi Ohyama, Isamu Morino, Justus Notholt, Kei Shiomi, Laura Iraci, Matthias Schneider, Martine de Mazière, Ralf Sussmann, Rigel Kivi, Thorsten Warneke, Tae-Young Goo, and Yao Té
Atmos. Meas. Tech., 11, 3111–3130, https://doi.org/10.5194/amt-11-3111-2018, https://doi.org/10.5194/amt-11-3111-2018, 2018
Youwen Sun, Mathias Palm, Cheng Liu, Frank Hase, David Griffith, Christine Weinzierl, Christof Petri, Wei Wang, and Justus Notholt
Atmos. Meas. Tech., 11, 2879–2896, https://doi.org/10.5194/amt-11-2879-2018, https://doi.org/10.5194/amt-11-2879-2018, 2018
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We simulated instrumental line shape (ILS) degradations with respect to typical types of misalignment, and compared their influence on each NDACC gas. The requirements to suppress the ILS-degradation-related biases within a specified accuracy for all NDACC gases were deduced.
Young-Suk Oh, S. Takele Kenea, Tae-Young Goo, Kyu-Sun Chung, Jae-Sang Rhee, Mi-Lim Ou, Young-Hwa Byun, Paul O. Wennberg, Matthäus Kiel, Joshua P. DiGangi, Glenn S. Diskin, Voltaire A. Velazco, and David W. T. Griffith
Atmos. Meas. Tech., 11, 2361–2374, https://doi.org/10.5194/amt-11-2361-2018, https://doi.org/10.5194/amt-11-2361-2018, 2018
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We focused on the measurements taken during the period of February 2014 to November 2017. The FTS instrument was stable during the whole measurement period. The g-b FTS retrieval of XCO2 and XCH4 were compared with aircraft measurements that were conducted over Anmyeondo station on 22 May 2016, 29 October, and 12 November 2017. The preliminary comparison results of XCO2 between FTS and OCO-2 were also presented over the Anmyeondo station.
Jennifer Kaiser, Daniel J. Jacob, Lei Zhu, Katherine R. Travis, Jenny A. Fisher, Gonzalo González Abad, Lin Zhang, Xuesong Zhang, Alan Fried, John D. Crounse, Jason M. St. Clair, and Armin Wisthaler
Atmos. Chem. Phys., 18, 5483–5497, https://doi.org/10.5194/acp-18-5483-2018, https://doi.org/10.5194/acp-18-5483-2018, 2018
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Isoprene emissions from vegetation have a large effect on atmospheric chemistry and air quality. Here we use the adjoint of GEOS-Chem in an inversion of OMI formaldehyde observations to produce top-down estimates of isoprene emissions in the southeast US during the summer of 2013. We find that MEGAN v2.1 is biased high on average by 40 %. Our downward correction of isoprene emissions leads to a small reduction in modeled surface O3 and decreases the contribution of isoprene to organic aerosol.
David W. T. Griffith, Denis Pöhler, Stefan Schmitt, Samuel Hammer, Sanam N. Vardag, and Ulrich Platt
Atmos. Meas. Tech., 11, 1549–1563, https://doi.org/10.5194/amt-11-1549-2018, https://doi.org/10.5194/amt-11-1549-2018, 2018
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Measurements of atmospheric trace gases over an open path complement in situ measurements by spatial averaging. This paper describes the first open-path measurements of CO2, CH4 and other trace gases by near-infrared Fourier transform spectroscopy. The measurements were made in Heidelberg, Germany, for 4 months in 2014 over a 1.5 km path and compared to in situ measurements made at one end of the path. The experiment setup and methods (and the comparisons of open path to in situ) are described.
Elise-Andrée Guérette, Clare Paton-Walsh, Maximilien Desservettaz, Thomas E. L. Smith, Liubov Volkova, Christopher J. Weston, and Carl P. Meyer
Atmos. Chem. Phys., 18, 3717–3735, https://doi.org/10.5194/acp-18-3717-2018, https://doi.org/10.5194/acp-18-3717-2018, 2018
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We characterised trace gas emissions from Australian temperate forest fires through measurements at nine prescribed fires. We find that smoke from Australian forest fires is different from that of American forest fires, and different from Australian savanna fires. This will impact plume chemistry and influence air quality outcomes downwind of the fires. We therefore recommend the use of data specific to Australian forest fires when studying the impacts of these fires on air quality and health.
Vanessa Selimovic, Robert J. Yokelson, Carsten Warneke, James M. Roberts, Joost de Gouw, James Reardon, and David W. T. Griffith
Atmos. Chem. Phys., 18, 2929–2948, https://doi.org/10.5194/acp-18-2929-2018, https://doi.org/10.5194/acp-18-2929-2018, 2018
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We burned fuels representing western US wildfires in large-scale laboratory simulations to generate relevant emissions as confirmed by lab–field comparison. We report emission factors (EFs) for light scattering and absorption and BC along with SSA at 870 and 401 nm and AAE. We report EF for 22 trace gases that are major inorganic and organic emissions from flaming and smoldering. We report trace gas EF for species rarely (NH3) or not yet measured (e.g., HONO, acetic acid) for real US wildfires.
David F. Pollard, Vanessa Sherlock, John Robinson, Nicholas M. Deutscher, Brian Connor, and Hisako Shiona
Earth Syst. Sci. Data, 9, 977–992, https://doi.org/10.5194/essd-9-977-2017, https://doi.org/10.5194/essd-9-977-2017, 2017
Marc D. Mallet, Maximilien J. Desservettaz, Branka Miljevic, Andelija Milic, Zoran D. Ristovski, Joel Alroe, Luke T. Cravigan, E. Rohan Jayaratne, Clare Paton-Walsh, David W. T. Griffith, Stephen R. Wilson, Graham Kettlewell, Marcel V. van der Schoot, Paul Selleck, Fabienne Reisen, Sarah J. Lawson, Jason Ward, James Harnwell, Min Cheng, Rob W. Gillett, Suzie B. Molloy, Dean Howard, Peter F. Nelson, Anthony L. Morrison, Grant C. Edwards, Alastair G. Williams, Scott D. Chambers, Sylvester Werczynski, Leah R. Williams, V. Holly L. Winton, Brad Atkinson, Xianyu Wang, and Melita D. Keywood
Atmos. Chem. Phys., 17, 13681–13697, https://doi.org/10.5194/acp-17-13681-2017, https://doi.org/10.5194/acp-17-13681-2017, 2017
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Fires play an important role within atmosphere. Gaseous and aerosol emissions influence Earth's temperature but these emissions can vary drastically across region and season. The SAFIRED (Savannah Fires in the Early Dry Season) campaign was undertaken at the Australian Tropical Research Station in north Australia during the 2014 early dry season. This paper presents an overview of the fires in this region, the measurements of their emissions and the implications of these fires on the atmosphere.
Jenny A. Fisher, Lee T. Murray, Dylan B. A. Jones, and Nicholas M. Deutscher
Geosci. Model Dev., 10, 4129–4144, https://doi.org/10.5194/gmd-10-4129-2017, https://doi.org/10.5194/gmd-10-4129-2017, 2017
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Carbon monoxide (CO) simulation in atmospheric chemistry models is used for source–receptor analysis, emission inversion, and interpretation of observations. We introduce a major update to CO simulation in the GEOS-Chem chemical transport model that removes fundamental inconsistencies relative to the standard model, resolving biases of more than 100 ppb and errors in vertical structure. We also add source tagging of secondary CO and demonstrate it provides added value in low-emission regions.
Zhiting Wang, Thorsten Warneke, Nicholas M. Deutscher, Justus Notholt, Ute Karstens, Marielle Saunois, Matthias Schneider, Ralf Sussmann, Harjinder Sembhi, David W. T. Griffith, Dave F. Pollard, Rigel Kivi, Christof Petri, Voltaire A. Velazco, Michel Ramonet, and Huilin Chen
Atmos. Chem. Phys., 17, 13283–13295, https://doi.org/10.5194/acp-17-13283-2017, https://doi.org/10.5194/acp-17-13283-2017, 2017
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In this paper we separate the biases of atmospheric methane models into stratospheric and tropospheric parts. It is observed in other studies that simulated total columns of atmospheric methane present a latitudinal bias compared to measurements. The latitudinal gradients are considered to be from the stratosphere. However, our results show that the latitudinal biases could come from the troposphere in two of three models evaluated in this study.
Dean Howard, Peter F. Nelson, Grant C. Edwards, Anthony L. Morrison, Jenny A. Fisher, Jason Ward, James Harnwell, Marcel van der Schoot, Brad Atkinson, Scott D. Chambers, Alan D. Griffiths, Sylvester Werczynski, and Alastair G. Williams
Atmos. Chem. Phys., 17, 11623–11636, https://doi.org/10.5194/acp-17-11623-2017, https://doi.org/10.5194/acp-17-11623-2017, 2017
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Mercury, a toxic metal, can be transported globally through the atmosphere, with deposition to ecosystems an important pathway to human exposure. 2 years of atmospheric mercury monitoring in tropical Australia supports recent evidence that Southern Hemisphere concentrations are lower than previously thought. Exchange between the atmosphere and ecosystems can take place on daily scales, with night deposition offset by morning re-emission. This could be an important transport pathway for mercury.
Jesse W. Greenslade, Simon P. Alexander, Robyn Schofield, Jenny A. Fisher, and Andrew K. Klekociuk
Atmos. Chem. Phys., 17, 10269–10290, https://doi.org/10.5194/acp-17-10269-2017, https://doi.org/10.5194/acp-17-10269-2017, 2017
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An analysis of data from ozonesondes released at three southern oceanic sites shows the impact of stratospheric ozone in this region. Using a novel method of transport classification, this work estimates the seasonality and quantity of stratospherically sourced ozone. We find that ozone is transported most frequently in summer due to regional-scale low-pressure weather systems. We also estimate a stratospheric ozone source of 2.0–3.3 Tg/year over three Southern Ocean regions.
Wei Wang, Yuan Tian, Cheng Liu, Youwen Sun, Wenqing Liu, Pinhua Xie, Jianguo Liu, Jin Xu, Isamu Morino, Voltaire A. Velazco, David W. T. Griffith, Justus Notholt, and Thorsten Warneke
Atmos. Meas. Tech., 10, 2627–2643, https://doi.org/10.5194/amt-10-2627-2017, https://doi.org/10.5194/amt-10-2627-2017, 2017
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A ground-based high-resolution Fourier transform spectrometer (FTS) station has been established in Hefei, China to remotely measure CO2, CO and other greenhouse gases. Our research aim is to provide information for constraining regional sources and sinks, and validate satellite data, such as GOSAT, OCO-2 and TANSAT. We investigate the potential of FTS to determine the temporal variability of atmospheric CO2 and CO, and assess the ability of our observations to validate satellite data.
Christopher Chan Miller, Daniel J. Jacob, Eloise A. Marais, Karen Yu, Katherine R. Travis, Patrick S. Kim, Jenny A. Fisher, Lei Zhu, Glenn M. Wolfe, Thomas F. Hanisco, Frank N. Keutsch, Jennifer Kaiser, Kyung-Eun Min, Steven S. Brown, Rebecca A. Washenfelder, Gonzalo González Abad, and Kelly Chance
Atmos. Chem. Phys., 17, 8725–8738, https://doi.org/10.5194/acp-17-8725-2017, https://doi.org/10.5194/acp-17-8725-2017, 2017
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The use of satellite glyoxal observations for estimating isoprene emissions has been limited by knowledge of the glyoxal yield from isoprene. We use SENEX aircraft observations over the southeast US to evaluate glyoxal yields from isoprene in a 3-D atmospheric model. The SENEX observations support a pathway for glyoxal formation in pristine regions that we propose here, which may have implications for improving isoprene emissions estimates from upcoming high-resolution geostationary satellites.
Matthias Buschmann, Nicholas M. Deutscher, Mathias Palm, Thorsten Warneke, Christine Weinzierl, and Justus Notholt
Atmos. Meas. Tech., 10, 2397–2411, https://doi.org/10.5194/amt-10-2397-2017, https://doi.org/10.5194/amt-10-2397-2017, 2017
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The column averaged dry-air mole fractions of CO2 and CH4 (xCO2 and xCH4) of the Total Carbon Column Observing Network (TCCON) are retrieved from solar absorption Fourier transform infrared (FTIR) spectrometry. At the Ny-Ålesund site in the high arctic, however, during the polar night no solar measurements are possible. Here, we present a new method to measure xCO2 and xCH4 using the moon as a light source in the near-infrared and present the complete seasonal cycles of xCO2 and xCH4.
Debra Wunch, Paul O. Wennberg, Gregory Osterman, Brendan Fisher, Bret Naylor, Coleen M. Roehl, Christopher O'Dell, Lukas Mandrake, Camille Viatte, Matthäus Kiel, David W. T. Griffith, Nicholas M. Deutscher, Voltaire A. Velazco, Justus Notholt, Thorsten Warneke, Christof Petri, Martine De Maziere, Mahesh K. Sha, Ralf Sussmann, Markus Rettinger, David Pollard, John Robinson, Isamu Morino, Osamu Uchino, Frank Hase, Thomas Blumenstock, Dietrich G. Feist, Sabrina G. Arnold, Kimberly Strong, Joseph Mendonca, Rigel Kivi, Pauli Heikkinen, Laura Iraci, James Podolske, Patrick W. Hillyard, Shuji Kawakami, Manvendra K. Dubey, Harrison A. Parker, Eliezer Sepulveda, Omaira E. García, Yao Te, Pascal Jeseck, Michael R. Gunson, David Crisp, and Annmarie Eldering
Atmos. Meas. Tech., 10, 2209–2238, https://doi.org/10.5194/amt-10-2209-2017, https://doi.org/10.5194/amt-10-2209-2017, 2017
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This paper describes the comparisons between NASA's Orbiting Carbon Observatory (OCO-2) column-averaged dry-air mole fractions of CO2 with its primary ground-based validation network, the Total Carbon Column Observing Network (TCCON). The paper shows that while the standard bias correction reduces much of the spurious variability in the satellite measurements, residual biases remain.
Clare Paton-Walsh, Élise-Andrée Guérette, Dagmar Kubistin, Ruhi Humphries, Stephen R. Wilson, Doreena Dominick, Ian Galbally, Rebecca Buchholz, Mahendra Bhujel, Scott Chambers, Min Cheng, Martin Cope, Perry Davy, Kathryn Emmerson, David W. T. Griffith, Alan Griffiths, Melita Keywood, Sarah Lawson, Suzie Molloy, Géraldine Rea, Paul Selleck, Xue Shi, Jack Simmons, and Voltaire Velazco
Earth Syst. Sci. Data, 9, 349–362, https://doi.org/10.5194/essd-9-349-2017, https://doi.org/10.5194/essd-9-349-2017, 2017
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The MUMBA campaign provides a detailed snapshot of the atmospheric composition in an urban coastal environment with strong biogenic sources nearby. This campaign involved collaboration between several institutes and was undertaken to provide a case study for atmospheric models in a poorly sampled region of the globe.
Rebecca R. Buchholz, Merritt N. Deeter, Helen M. Worden, John Gille, David P. Edwards, James W. Hannigan, Nicholas B. Jones, Clare Paton-Walsh, David W. T. Griffith, Dan Smale, John Robinson, Kimberly Strong, Stephanie Conway, Ralf Sussmann, Frank Hase, Thomas Blumenstock, Emmanuel Mahieu, and Bavo Langerock
Atmos. Meas. Tech., 10, 1927–1956, https://doi.org/10.5194/amt-10-1927-2017, https://doi.org/10.5194/amt-10-1927-2017, 2017
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The study presents the first systematic use of ground-based remote-sensing data from the Network for the Detection of Atmospheric Composition Change (NDACC) to validate satellite-based Measurements of Pollution in the Troposphere (MOPITT) total column carbon monoxide (CO). MOPITT generally shows low bias with respect to the ground-based instruments. The geographic and temporal dependence of validation results are determined. Our findings inform some recommendations for using MOPITT measurements.
Liang Feng, Paul I. Palmer, Hartmut Bösch, Robert J. Parker, Alex J. Webb, Caio S. C. Correia, Nicholas M. Deutscher, Lucas G. Domingues, Dietrich G. Feist, Luciana V. Gatti, Emanuel Gloor, Frank Hase, Rigel Kivi, Yi Liu, John B. Miller, Isamu Morino, Ralf Sussmann, Kimberly Strong, Osamu Uchino, Jing Wang, and Andreas Zahn
Atmos. Chem. Phys., 17, 4781–4797, https://doi.org/10.5194/acp-17-4781-2017, https://doi.org/10.5194/acp-17-4781-2017, 2017
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We use the GEOS-Chem global 3-D model of atmospheric chemistry and transport and an ensemble Kalman filter to simultaneously infer regional fluxes of methane (CH4) and carbon dioxide (CO2) directly from GOSAT retrievals of XCH4:XCO2, using sparse ground-based CH4 and CO2 mole fraction data to anchor the ratio. Our results show that assimilation of GOSAT data significantly reduced the posterior uncertainty and changed the a priori spatial distribution of CH4 emissions.
Andelija Milic, Marc D. Mallet, Luke T. Cravigan, Joel Alroe, Zoran D. Ristovski, Paul Selleck, Sarah J. Lawson, Jason Ward, Maximilien J. Desservettaz, Clare Paton-Walsh, Leah R. Williams, Melita D. Keywood, and Branka Miljevic
Atmos. Chem. Phys., 17, 3945–3961, https://doi.org/10.5194/acp-17-3945-2017, https://doi.org/10.5194/acp-17-3945-2017, 2017
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This study reports chemical characterization of fresh and processed aerosols sampled over a month-long field campaign, during the intense fire period in Australian tropical savannah region. The study illustrates diversity in fire emissions and importance of processed fire emissions and formation of secondary species, including biogenic secondary species, in northern Australia.
Whitney Bader, Benoît Bovy, Stephanie Conway, Kimberly Strong, Dan Smale, Alexander J. Turner, Thomas Blumenstock, Chris Boone, Martine Collaud Coen, Ancelin Coulon, Omaira Garcia, David W. T. Griffith, Frank Hase, Petra Hausmann, Nicholas Jones, Paul Krummel, Isao Murata, Isamu Morino, Hideaki Nakajima, Simon O'Doherty, Clare Paton-Walsh, John Robinson, Rodrigue Sandrin, Matthias Schneider, Christian Servais, Ralf Sussmann, and Emmanuel Mahieu
Atmos. Chem. Phys., 17, 2255–2277, https://doi.org/10.5194/acp-17-2255-2017, https://doi.org/10.5194/acp-17-2255-2017, 2017
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An increase of 0.31 ± 0.03 % year−1 of atmospheric methane is reported using 10 years of solar observations performed at 10 ground-based stations since 2005. These trend agree with a GEOS-Chem-tagged simulation that accounts for the contribution of each emission source and one sink in the total methane. The GEOS-Chem simulation shows that anthropogenic emissions from coal mining and gas and oil transport and exploration have played a major role in the increase methane since 2005.
Benedikt J. Fest, Nina Hinko-Najera, Tim Wardlaw, David W. T. Griffith, Stephen J. Livesley, and Stefan K. Arndt
Biogeosciences, 14, 467–479, https://doi.org/10.5194/bg-14-467-2017, https://doi.org/10.5194/bg-14-467-2017, 2017
Sabine Barthlott, Matthias Schneider, Frank Hase, Thomas Blumenstock, Matthäus Kiel, Darko Dubravica, Omaira E. García, Eliezer Sepúlveda, Gizaw Mengistu Tsidu, Samuel Takele Kenea, Michel Grutter, Eddy F. Plaza-Medina, Wolfgang Stremme, Kim Strong, Dan Weaver, Mathias Palm, Thorsten Warneke, Justus Notholt, Emmanuel Mahieu, Christian Servais, Nicholas Jones, David W. T. Griffith, Dan Smale, and John Robinson
Earth Syst. Sci. Data, 9, 15–29, https://doi.org/10.5194/essd-9-15-2017, https://doi.org/10.5194/essd-9-15-2017, 2017
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Tropospheric water vapour isotopologue distributions have been consistently generated and quality-filtered for 12 globally distributed ground-based FTIR sites. The products are provided as two data types. The first type is best-suited for tropospheric water vapour distribution studies. The second type is needed for analysing moisture pathways by means of {H2O,δD}-pair distributions. This paper describes the data types and gives recommendations for their correct usage.
Dmitry A. Belikov, Shamil Maksyutov, Alexander Ganshin, Ruslan Zhuravlev, Nicholas M. Deutscher, Debra Wunch, Dietrich G. Feist, Isamu Morino, Robert J. Parker, Kimberly Strong, Yukio Yoshida, Andrey Bril, Sergey Oshchepkov, Hartmut Boesch, Manvendra K. Dubey, David Griffith, Will Hewson, Rigel Kivi, Joseph Mendonca, Justus Notholt, Matthias Schneider, Ralf Sussmann, Voltaire A. Velazco, and Shuji Aoki
Atmos. Chem. Phys., 17, 143–157, https://doi.org/10.5194/acp-17-143-2017, https://doi.org/10.5194/acp-17-143-2017, 2017
Katherine M. Saad, Debra Wunch, Nicholas M. Deutscher, David W. T. Griffith, Frank Hase, Martine De Mazière, Justus Notholt, David F. Pollard, Coleen M. Roehl, Matthias Schneider, Ralf Sussmann, Thorsten Warneke, and Paul O. Wennberg
Atmos. Chem. Phys., 16, 14003–14024, https://doi.org/10.5194/acp-16-14003-2016, https://doi.org/10.5194/acp-16-14003-2016, 2016
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Current approaches to constrain the global methane budget assimilate total column measurements into models, but model biases can impact results. We use tropospheric methane columns to evaluate model transport errors and identify a seasonal time lag in the Northern Hemisphere troposphere masked by stratospheric compensating effects. We find systematic biases in the stratosphere will alias into model-derived emissions estimates, especially those in the high Northern latitudes that vary seasonally.
Katherine R. Travis, Daniel J. Jacob, Jenny A. Fisher, Patrick S. Kim, Eloise A. Marais, Lei Zhu, Karen Yu, Christopher C. Miller, Robert M. Yantosca, Melissa P. Sulprizio, Anne M. Thompson, Paul O. Wennberg, John D. Crounse, Jason M. St. Clair, Ronald C. Cohen, Joshua L. Laughner, Jack E. Dibb, Samuel R. Hall, Kirk Ullmann, Glenn M. Wolfe, Illana B. Pollack, Jeff Peischl, Jonathan A. Neuman, and Xianliang Zhou
Atmos. Chem. Phys., 16, 13561–13577, https://doi.org/10.5194/acp-16-13561-2016, https://doi.org/10.5194/acp-16-13561-2016, 2016
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Ground-level ozone pollution in the Southeast US involves complex chemistry driven by anthropogenic emissions of nitrogen oxides (NOx) and biogenic emissions of isoprene. We find that US NOx emissions are overestimated nationally by as much as 50 % and that reducing model emissions by this amount results in good agreement with SEAC4RS aircraft measurements in August and September 2013. Observations of nitrate wet deposition fluxes and satellite NO2 columns further support this result.
Lei Zhu, Daniel J. Jacob, Patrick S. Kim, Jenny A. Fisher, Karen Yu, Katherine R. Travis, Loretta J. Mickley, Robert M. Yantosca, Melissa P. Sulprizio, Isabelle De Smedt, Gonzalo González Abad, Kelly Chance, Can Li, Richard Ferrare, Alan Fried, Johnathan W. Hair, Thomas F. Hanisco, Dirk Richter, Amy Jo Scarino, James Walega, Petter Weibring, and Glenn M. Wolfe
Atmos. Chem. Phys., 16, 13477–13490, https://doi.org/10.5194/acp-16-13477-2016, https://doi.org/10.5194/acp-16-13477-2016, 2016
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HCHO column data are widely used as a proxy for VOCs emissions, but validation of the data has been extremely limited. We use accurate aircraft observations to validate and intercompare 6 HCHO retrievals with GEOS-Chem as the intercomparison platform. Retrievals are interconsistent in spatial variability over the SE US and in daily variability, but are biased low by 20–51 %. Our work supports the use of HCHO column as a quantitative proxy for isoprene emission after correction of the low bias.
V. Holly L. Winton, Ross Edwards, Andrew R. Bowie, Melita Keywood, Alistair G. Williams, Scott D. Chambers, Paul W. Selleck, Maximilien Desservettaz, Marc D. Mallet, and Clare Paton-Walsh
Atmos. Chem. Phys., 16, 12829–12848, https://doi.org/10.5194/acp-16-12829-2016, https://doi.org/10.5194/acp-16-12829-2016, 2016
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The deposition of soluble aerosol iron (Fe) can initiate nitrogen fixation and trigger toxic algal blooms in nitrate-poor tropical waters. We present dry season soluble Fe data from northern Australia that reflect coincident dust and biomass burning sources of soluble Fe. Our results show that while biomass burning species are not a direct source of soluble Fe, biomass burning may substantially enhance the solubility of mineral dust with fractional Fe solubility up to 12 % in mixed aerosols.
Andreas Ostler, Ralf Sussmann, Prabir K. Patra, Sander Houweling, Marko De Bruine, Gabriele P. Stiller, Florian J. Haenel, Johannes Plieninger, Philippe Bousquet, Yi Yin, Marielle Saunois, Kaley A. Walker, Nicholas M. Deutscher, David W. T. Griffith, Thomas Blumenstock, Frank Hase, Thorsten Warneke, Zhiting Wang, Rigel Kivi, and John Robinson
Atmos. Meas. Tech., 9, 4843–4859, https://doi.org/10.5194/amt-9-4843-2016, https://doi.org/10.5194/amt-9-4843-2016, 2016
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Our evaluation of column-averaged methane (XCH4) in models and TCCON reveals latitudinal biases between 0.4 % and 2.1 % originating from an inter-model spread in stratospheric CH4. Substituting model stratospheric CH4 fields by satellite data significantly reduces the large XCH4 bias observed for one model. For other models, showing only minor biases, the impact is ambiguous; i.e., the satellite uncertainty range hinders a more accurate model evaluation needed to improve inverse modeling.
Yao Té, Pascal Jeseck, Bruno Franco, Emmanuel Mahieu, Nicholas Jones, Clare Paton-Walsh, David W. T. Griffith, Rebecca R. Buchholz, Juliette Hadji-Lazaro, Daniel Hurtmans, and Christof Janssen
Atmos. Chem. Phys., 16, 10911–10925, https://doi.org/10.5194/acp-16-10911-2016, https://doi.org/10.5194/acp-16-10911-2016, 2016
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This paper studies the seasonal variation of surface and column CO at three different sites (Paris, Jungfraujoch and Wollongong), with an emphasis on establishing a link between the CO vertical distribution and the nature of CO emission sources. We find the first evidence of a time lag between surface and free tropospheric CO seasonal variations in the Northern Hemisphere.
Makoto Inoue, Isamu Morino, Osamu Uchino, Takahiro Nakatsuru, Yukio Yoshida, Tatsuya Yokota, Debra Wunch, Paul O. Wennberg, Coleen M. Roehl, David W. T. Griffith, Voltaire A. Velazco, Nicholas M. Deutscher, Thorsten Warneke, Justus Notholt, John Robinson, Vanessa Sherlock, Frank Hase, Thomas Blumenstock, Markus Rettinger, Ralf Sussmann, Esko Kyrö, Rigel Kivi, Kei Shiomi, Shuji Kawakami, Martine De Mazière, Sabrina G. Arnold, Dietrich G. Feist, Erica A. Barrow, James Barney, Manvendra Dubey, Matthias Schneider, Laura T. Iraci, James R. Podolske, Patrick W. Hillyard, Toshinobu Machida, Yousuke Sawa, Kazuhiro Tsuboi, Hidekazu Matsueda, Colm Sweeney, Pieter P. Tans, Arlyn E. Andrews, Sebastien C. Biraud, Yukio Fukuyama, Jasna V. Pittman, Eric A. Kort, and Tomoaki Tanaka
Atmos. Meas. Tech., 9, 3491–3512, https://doi.org/10.5194/amt-9-3491-2016, https://doi.org/10.5194/amt-9-3491-2016, 2016
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In this study, we correct the biases of GOSAT XCO2 and XCH4 using TCCON data. To evaluate the effectiveness of our correction method, uncorrected/corrected GOSAT data are compared to independent XCO2 and XCH4 data derived from aircraft measurements. Consequently, we suggest that this method is effective for reducing the biases of the GOSAT data. We consider that our work provides GOSAT data users with valuable information and contributes to the further development of studies on greenhouse gases.
Matthieu Pommier, Cathy Clerbaux, Pierre-François Coheur, Emmanuel Mahieu, Jean-François Müller, Clare Paton-Walsh, Trissevgeni Stavrakou, and Corinne Vigouroux
Atmos. Chem. Phys., 16, 8963–8981, https://doi.org/10.5194/acp-16-8963-2016, https://doi.org/10.5194/acp-16-8963-2016, 2016
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This work presents for the first time 7 years of formic acid (HCOOH) measurements recorded by the satellite instrument, IASI. The comparison of the data set with ground-based FTIR measurements and a CTM shows the interannual and the seasonal variation are well captured. Global distributions are provided, highlighting the long-range transport of tropospheric HCOOH over the oceans and the detection of source regions e.g. over India, USA, and Africa.
Kathryn M. Emmerson, Ian E. Galbally, Alex B. Guenther, Clare Paton-Walsh, Elise-Andree Guerette, Martin E. Cope, Melita D. Keywood, Sarah J. Lawson, Suzie B. Molloy, Erin Dunne, Marcus Thatcher, Thomas Karl, and Simin D. Maleknia
Atmos. Chem. Phys., 16, 6997–7011, https://doi.org/10.5194/acp-16-6997-2016, https://doi.org/10.5194/acp-16-6997-2016, 2016
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We have tested how a model using a global inventory of plant-based emissions compares with four sets of measurements made in southeast Australia. This region is known for its eucalypt species, which dominate the summertime global inventory. The Australian part of the inventory has been produced using measurements made on eucalypt saplings. The model could not match the measurements, and the inventory needs to be improved by taking measurements of a wider range of Australian plant types and ages.
Jenny A. Fisher, Daniel J. Jacob, Katherine R. Travis, Patrick S. Kim, Eloise A. Marais, Christopher Chan Miller, Karen Yu, Lei Zhu, Robert M. Yantosca, Melissa P. Sulprizio, Jingqiu Mao, Paul O. Wennberg, John D. Crounse, Alex P. Teng, Tran B. Nguyen, Jason M. St. Clair, Ronald C. Cohen, Paul Romer, Benjamin A. Nault, Paul J. Wooldridge, Jose L. Jimenez, Pedro Campuzano-Jost, Douglas A. Day, Weiwei Hu, Paul B. Shepson, Fulizi Xiong, Donald R. Blake, Allen H. Goldstein, Pawel K. Misztal, Thomas F. Hanisco, Glenn M. Wolfe, Thomas B. Ryerson, Armin Wisthaler, and Tomas Mikoviny
Atmos. Chem. Phys., 16, 5969–5991, https://doi.org/10.5194/acp-16-5969-2016, https://doi.org/10.5194/acp-16-5969-2016, 2016
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We use new airborne and ground-based observations from two summer 2013 campaigns in the southeastern US, interpreted with a chemical transport model, to understand the impact of isoprene and monoterpene chemistry on the atmospheric NOx budget via production of organic nitrates (RONO2). We find that a diversity of species contribute to observed RONO2. Our work implies that the NOx sink to RONO2 production is only sensitive to NOx emissions in regions where they are already low.
L. M. T. Joelsson, J. A. Schmidt, E. J. K. Nilsson, T. Blunier, D. W. T. Griffith, S. Ono, and M. S. Johnson
Atmos. Chem. Phys., 16, 4439–4449, https://doi.org/10.5194/acp-16-4439-2016, https://doi.org/10.5194/acp-16-4439-2016, 2016
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We present experimental kinetic isotope effects (KIE) for the OH oxidation of CH3D and 13CH3D and their temperature dependence. Our determination of the 13CH3D + OH KIE is novel and we find no "clumped" isotope effect within the experimental uncertainty.
Karen Yu, Daniel J. Jacob, Jenny A. Fisher, Patrick S. Kim, Eloise A. Marais, Christopher C. Miller, Katherine R. Travis, Lei Zhu, Robert M. Yantosca, Melissa P. Sulprizio, Ron C. Cohen, Jack E. Dibb, Alan Fried, Tomas Mikoviny, Thomas B. Ryerson, Paul O. Wennberg, and Armin Wisthaler
Atmos. Chem. Phys., 16, 4369–4378, https://doi.org/10.5194/acp-16-4369-2016, https://doi.org/10.5194/acp-16-4369-2016, 2016
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Increasing the spatial resolution of a chemical transport model may improve simulations but can be computationally expensive. Using observations from the SEAC4RS aircraft campaign, we find that at higher spatial resolutions, models are better able to simulate the chemical pathways of ozone precursors, but the overall effect on regional mean concentrations is small. This implies that for continental boundary layer applications, coarse resolution models are adequate.
Johannes Laubach, Matti Barthel, Anitra Fraser, John E. Hunt, and David W. T. Griffith
Biogeosciences, 13, 1309–1327, https://doi.org/10.5194/bg-13-1309-2016, https://doi.org/10.5194/bg-13-1309-2016, 2016
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We continuously measured CH4 and N2O fluxes on two pastures that differed with respect to management. Two micrometeorological ratio methods were used; one was more suitable for daytime and the other for night-time. Over a year, both methods indicated both sites as net sources of CH4 and N2O, similar to other managed grasslands. At the irrigated, fertilised and rotationally grazed site, the N2O emissions were 1.21 (±0.15) % of the nitrogen inputs from animal excreta and fertiliser application.
Susan Kulawik, Debra Wunch, Christopher O'Dell, Christian Frankenberg, Maximilian Reuter, Tomohiro Oda, Frederic Chevallier, Vanessa Sherlock, Michael Buchwitz, Greg Osterman, Charles E. Miller, Paul O. Wennberg, David Griffith, Isamu Morino, Manvendra K. Dubey, Nicholas M. Deutscher, Justus Notholt, Frank Hase, Thorsten Warneke, Ralf Sussmann, John Robinson, Kimberly Strong, Matthias Schneider, Martine De Mazière, Kei Shiomi, Dietrich G. Feist, Laura T. Iraci, and Joyce Wolf
Atmos. Meas. Tech., 9, 683–709, https://doi.org/10.5194/amt-9-683-2016, https://doi.org/10.5194/amt-9-683-2016, 2016
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To accurately estimate source and sink locations of carbon dioxide, systematic errors in satellite measurements and models must be characterized. This paper examines two satellite data sets (GOSAT, launched 2009, and SCIAMACHY, launched 2002), and two models (CarbonTracker and MACC) vs. the TCCON CO2 validation data set. We assess biases and errors by season and latitude, satellite performance under averaging, and diurnal variability. Our findings are useful for assimilation of satellite data.
Yuting Wang, Nicholas M. Deutscher, Mathias Palm, Thorsten Warneke, Justus Notholt, Ian Baker, Joe Berry, Parvadha Suntharalingam, Nicholas Jones, Emmanuel Mahieu, Bernard Lejeune, James Hannigan, Stephanie Conway, Joseph Mendonca, Kimberly Strong, J. Elliott Campbell, Adam Wolf, and Stefanie Kremser
Atmos. Chem. Phys., 16, 2123–2138, https://doi.org/10.5194/acp-16-2123-2016, https://doi.org/10.5194/acp-16-2123-2016, 2016
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OCS could provide an additional constraint on the carbon cycle. The FTIR networks have existed for more than 20 years. For the first time, we used FTIR measurements of OCS and CO2 to study their relationship. We put the coupled CO2 and OCS land fluxes from the Simple Biosphere Model (SiB) into a transport model, and compared the simulations to the measurements. Looking at OCS and CO2 together inspires some new thoughts in how the biospheric models reproduce the carbon cycle in the real world.
Matthias Buschmann, Nicholas M. Deutscher, Vanessa Sherlock, Mathias Palm, Thorsten Warneke, and Justus Notholt
Atmos. Meas. Tech., 9, 577–585, https://doi.org/10.5194/amt-9-577-2016, https://doi.org/10.5194/amt-9-577-2016, 2016
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The column-averaged dry-air mole fraction of CO2 has been retrieved from high-resolution solar absorption spectra from two different measurement networks. We investigate the differences between these retrievals and find that their sensitivity differs greatly. As a result the direct comparison of the two retrievals remains challenging.
Sébastien Massart, Anna Agustí-Panareda, Jens Heymann, Michael Buchwitz, Frédéric Chevallier, Maximilian Reuter, Michael Hilker, John P. Burrows, Nicholas M. Deutscher, Dietrich G. Feist, Frank Hase, Ralf Sussmann, Filip Desmet, Manvendra K. Dubey, David W. T. Griffith, Rigel Kivi, Christof Petri, Matthias Schneider, and Voltaire A. Velazco
Atmos. Chem. Phys., 16, 1653–1671, https://doi.org/10.5194/acp-16-1653-2016, https://doi.org/10.5194/acp-16-1653-2016, 2016
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This study presents the European Centre for Medium-Range Weather Forecasts (ECMWF) monitoring of atmospheric CO2 using measurements from the Greenhouse gases Observing Satellite (GOSAT). We show that the modelled CO2 has a better precision than standard CO2 satellite products compared to ground-based measurements. We also present the CO2 forecast based on our best knowledge of the atmospheric CO2 distribution. We show that it has skill to forecast the largest scale CO2 patterns up to day 5.
E. A. Marais, D. J. Jacob, J. L. Jimenez, P. Campuzano-Jost, D. A. Day, W. Hu, J. Krechmer, L. Zhu, P. S. Kim, C. C. Miller, J. A. Fisher, K. Travis, K. Yu, T. F. Hanisco, G. M. Wolfe, H. L. Arkinson, H. O. T. Pye, K. D. Froyd, J. Liao, and V. F. McNeill
Atmos. Chem. Phys., 16, 1603–1618, https://doi.org/10.5194/acp-16-1603-2016, https://doi.org/10.5194/acp-16-1603-2016, 2016
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Isoprene secondary organic aerosol (SOA) is a dominant aerosol component in the southeast US, but models routinely underestimate isoprene SOA with traditional schemes based on chamber studies operated under conditions not representative of isoprene-emitting forests. We develop a new irreversible uptake mechanism to reproduce isoprene SOA yields (3.3 %) and composition, and find a factor of 2 co-benefit of SO2 emission controls on reducing sulfate and organic aerosol in the southeast US.
L. Feng, P. I. Palmer, R. J. Parker, N. M. Deutscher, D. G. Feist, R. Kivi, I. Morino, and R. Sussmann
Atmos. Chem. Phys., 16, 1289–1302, https://doi.org/10.5194/acp-16-1289-2016, https://doi.org/10.5194/acp-16-1289-2016, 2016
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There is an on-going debate on the larger European biospheric uptake inferred from GOSAT XCO2 retrievals than those inferred from in situ data. Using a set of 15 experiments, we found that the elevated uptake over Europe could largely be explained by mis-fitting data due to regional XCO2 biases: 50–80 % of the elevated European uptake is due to retrievals outside the immediate European; and a varying monthly bias of up to 0.5 ppm for XCO2 retrievals over Europe could explain most of the remainder.
H. Lindqvist, C. W. O'Dell, S. Basu, H. Boesch, F. Chevallier, N. Deutscher, L. Feng, B. Fisher, F. Hase, M. Inoue, R. Kivi, I. Morino, P. I. Palmer, R. Parker, M. Schneider, R. Sussmann, and Y. Yoshida
Atmos. Chem. Phys., 15, 13023–13040, https://doi.org/10.5194/acp-15-13023-2015, https://doi.org/10.5194/acp-15-13023-2015, 2015
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Atmospheric carbon dioxide concentration varies seasonally mainly due to plant photosynthesis in the Northern Hemisphere. We found that the satellite GOSAT can capture this variability from space to within 1ppm. We also found that models can differ by more than 1ppm. This implies that the satellite measurements could be useful in evaluating models and their prior estimates of carbon dioxide sources and sinks.
R. J. Parker, H. Boesch, K. Byckling, A. J. Webb, P. I. Palmer, L. Feng, P. Bergamaschi, F. Chevallier, J. Notholt, N. Deutscher, T. Warneke, F. Hase, R. Sussmann, S. Kawakami, R. Kivi, D. W. T. Griffith, and V. Velazco
Atmos. Meas. Tech., 8, 4785–4801, https://doi.org/10.5194/amt-8-4785-2015, https://doi.org/10.5194/amt-8-4785-2015, 2015
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Atmospheric CH4 is an important greenhouse gas. Long-term global observations are necessary to understand its behaviour, with satellite observations playing a key role. The "proxy" retrieval method is one of the most successful but relies on the contribution from atmospheric CO2 models. This work assesses the significance of the uncertainty from the model CO2 within the retrieval and determines that despite this uncertainty the data are still valuable for determining sources and sinks of CH4.
V. Duflot, C. Wespes, L. Clarisse, D. Hurtmans, Y. Ngadi, N. Jones, C. Paton-Walsh, J. Hadji-Lazaro, C. Vigouroux, M. De Mazière, J.-M. Metzger, E. Mahieu, C. Servais, F. Hase, M. Schneider, C. Clerbaux, and P.-F. Coheur
Atmos. Chem. Phys., 15, 10509–10527, https://doi.org/10.5194/acp-15-10509-2015, https://doi.org/10.5194/acp-15-10509-2015, 2015
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We present global distributions of acetylene (C2H2) and hydrogen cyanide (HCN) total
columns derived from the Infrared Atmospheric Sounding Interferometer (IASI). C2H2 and HCN are ubiquitous atmospheric trace gases with medium tropospheric lifetime, which are frequently used as indicators of combustion sources and as tracers for atmospheric transport and chemistry. We show that there is an overall agreement between ground-based and space measurements, as well as model simulations.
P. S. Kim, D. J. Jacob, J. A. Fisher, K. Travis, K. Yu, L. Zhu, R. M. Yantosca, M. P. Sulprizio, J. L. Jimenez, P. Campuzano-Jost, K. D. Froyd, J. Liao, J. W. Hair, M. A. Fenn, C. F. Butler, N. L. Wagner, T. D. Gordon, A. Welti, P. O. Wennberg, J. D. Crounse, J. M. St. Clair, A. P. Teng, D. B. Millet, J. P. Schwarz, M. Z. Markovic, and A. E. Perring
Atmos. Chem. Phys., 15, 10411–10433, https://doi.org/10.5194/acp-15-10411-2015, https://doi.org/10.5194/acp-15-10411-2015, 2015
A. Ostler, R. Sussmann, P. K. Patra, P. O. Wennberg, N. M. Deutscher, D. W. T. Griffith, T. Blumenstock, F. Hase, R. Kivi, T. Warneke, Z. Wang, M. De Mazière, J. Robinson, and H. Ohyama
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-20395-2015, https://doi.org/10.5194/acpd-15-20395-2015, 2015
Preprint withdrawn
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We find that stratospheric model-transport errors are common for chemical transport models that are used for inverse estimates of CH4 emissions. These model-transport errors cause latitudinal as well as seasonal biases in simulated stratospheric and, hence, column-averaged CH4 mixing ratios (XCH4). Such a model bias corresponds to an overestimation of arctic and mid-latitude CH4 emissions if inversion studies do not apply an ad hoc bias correction before inverting fluxes from XCH4 observations.
J. Heymann, M. Reuter, M. Hilker, M. Buchwitz, O. Schneising, H. Bovensmann, J. P. Burrows, A. Kuze, H. Suto, N. M. Deutscher, M. K. Dubey, D. W. T. Griffith, F. Hase, S. Kawakami, R. Kivi, I. Morino, C. Petri, C. Roehl, M. Schneider, V. Sherlock, R. Sussmann, V. A. Velazco, T. Warneke, and D. Wunch
Atmos. Meas. Tech., 8, 2961–2980, https://doi.org/10.5194/amt-8-2961-2015, https://doi.org/10.5194/amt-8-2961-2015, 2015
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Long-term data sets of global atmospheric carbon dioxide concentrations based on observations from different satellite instruments may suffer from inconsistencies originating from the use of different retrieval algorithms. This issue has been addressed by applying the Bremen Optimal Estimation DOAS retrieval algorithm to SCIAMACHY and TANSO-FTS observations. Detailed comparisons with TCCON and CarbonTracker show good consistency between the SCIAMACHY and TANSO-FTS data sets.
G. Zeng, J. E. Williams, J. A. Fisher, L. K. Emmons, N. B. Jones, O. Morgenstern, J. Robinson, D. Smale, C. Paton-Walsh, and D. W. T. Griffith
Atmos. Chem. Phys., 15, 7217–7245, https://doi.org/10.5194/acp-15-7217-2015, https://doi.org/10.5194/acp-15-7217-2015, 2015
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We assess the impact of biogenic emissions on CO and HCHO in the Southern Hemisphere (SH), with simulations using different emission inventories. Differences in biogenic emissions result in large differences on modelled CO in the source and the remote regions. Substantial inter-model differences exist. Models significantly underestimate observed HCHO columns in the SH, suggesting missing sources in the models. Differences in the CO/OH/CH4 chemistry lead to differences in HCHO in remote regions.
A. J. Turner, D. J. Jacob, K. J. Wecht, J. D. Maasakkers, E. Lundgren, A. E. Andrews, S. C. Biraud, H. Boesch, K. W. Bowman, N. M. Deutscher, M. K. Dubey, D. W. T. Griffith, F. Hase, A. Kuze, J. Notholt, H. Ohyama, R. Parker, V. H. Payne, R. Sussmann, C. Sweeney, V. A. Velazco, T. Warneke, P. O. Wennberg, and D. Wunch
Atmos. Chem. Phys., 15, 7049–7069, https://doi.org/10.5194/acp-15-7049-2015, https://doi.org/10.5194/acp-15-7049-2015, 2015
R. A. Scheepmaker, C. Frankenberg, N. M. Deutscher, M. Schneider, S. Barthlott, T. Blumenstock, O. E. Garcia, F. Hase, N. Jones, E. Mahieu, J. Notholt, V. Velazco, J. Landgraf, and I. Aben
Atmos. Meas. Tech., 8, 1799–1818, https://doi.org/10.5194/amt-8-1799-2015, https://doi.org/10.5194/amt-8-1799-2015, 2015
S. Barthlott, M. Schneider, F. Hase, A. Wiegele, E. Christner, Y. González, T. Blumenstock, S. Dohe, O. E. García, E. Sepúlveda, K. Strong, J. Mendonca, D. Weaver, M. Palm, N. M. Deutscher, T. Warneke, J. Notholt, B. Lejeune, E. Mahieu, N. Jones, D. W. T. Griffith, V. A. Velazco, D. Smale, J. Robinson, R. Kivi, P. Heikkinen, and U. Raffalski
Atmos. Meas. Tech., 8, 1555–1573, https://doi.org/10.5194/amt-8-1555-2015, https://doi.org/10.5194/amt-8-1555-2015, 2015
J. A. Fisher, S. R. Wilson, G. Zeng, J. E. Williams, L. K. Emmons, R. L. Langenfelds, P. B. Krummel, and L. P. Steele
Atmos. Chem. Phys., 15, 3217–3239, https://doi.org/10.5194/acp-15-3217-2015, https://doi.org/10.5194/acp-15-3217-2015, 2015
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The Southern Hemisphere (SH) serves as an important test bed for evaluating our understanding of the processes that drive the composition of the clean background atmosphere. Using data from two aircraft campaigns, combined with four atmospheric chemistry models, we find a large sensitivity in the remote SH to biogenic emissions and their subsequent chemistry and transport. Future model evaluation and measurement campaigns should prioritize reducing uncertainties in these processes.
C. Viatte, K. Strong, J. Hannigan, E. Nussbaumer, L. K. Emmons, S. Conway, C. Paton-Walsh, J. Hartley, J. Benmergui, and J. Lin
Atmos. Chem. Phys., 15, 2227–2246, https://doi.org/10.5194/acp-15-2227-2015, https://doi.org/10.5194/acp-15-2227-2015, 2015
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Seven tropospheric species (CO, HCN, C2H6, C2H2, CH3OH, HCOOH, and H2CO) released by biomass burning events transported to the high Arctic were monitored with two sets of FTIR measurements, located at Eureka (Nunavut, Canada) and Thule (Greenland), from 2008 to 2012. We compared these data sets with the MOZART-4 chemical transport model to help improve its simulations in the Arctic. Emission factors of these biomass burning products were derived and compared to the literature.
S. N. Vardag, S. Hammer, M. Sabasch, D. W. T. Griffith, and I. Levin
Atmos. Meas. Tech., 8, 579–592, https://doi.org/10.5194/amt-8-579-2015, https://doi.org/10.5194/amt-8-579-2015, 2015
M. Reuter, M. Buchwitz, M. Hilker, J. Heymann, O. Schneising, D. Pillai, H. Bovensmann, J. P. Burrows, H. Bösch, R. Parker, A. Butz, O. Hasekamp, C. W. O'Dell, Y. Yoshida, C. Gerbig, T. Nehrkorn, N. M. Deutscher, T. Warneke, J. Notholt, F. Hase, R. Kivi, R. Sussmann, T. Machida, H. Matsueda, and Y. Sawa
Atmos. Chem. Phys., 14, 13739–13753, https://doi.org/10.5194/acp-14-13739-2014, https://doi.org/10.5194/acp-14-13739-2014, 2014
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Current knowledge about the European terrestrial biospheric carbon sink relies upon bottom-up and global surface flux inverse model estimates using in situ measurements. Our analysis of five satellite data sets comprises a regional inversion designed to be insensitive to potential retrieval biases and transport errors. We show that the satellite-derived sink is larger (1.0±0.3GtC/a) than previous estimates (0.4±0.4GtC/a).
S. R. Utembe, N. Jones, P. J. Rayner, I. Genkova, D. W. T. Griffith, D. M. O'Brien, C. Lunney, and A. J. Clark
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-31551-2014, https://doi.org/10.5194/acpd-14-31551-2014, 2014
Revised manuscript not accepted
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A methodology to estimate CO2 emissions from an isolated power plant
is presented and illustrated for a power station in South Australia. It involves measurement of in-situ and column-averaged CO2 near the power plant, forward modelling of the observed signals (using WRF-Chem) and inverse modelling to obtain an estimate of the power plant fluxes. Better simulation is obtained for column data giving better estimates of fluxes. Our estimated emissions are within 6% of the reported values.
A. Ostler, R. Sussmann, M. Rettinger, N. M. Deutscher, S. Dohe, F. Hase, N. Jones, M. Palm, and B.-M. Sinnhuber
Atmos. Meas. Tech., 7, 4081–4101, https://doi.org/10.5194/amt-7-4081-2014, https://doi.org/10.5194/amt-7-4081-2014, 2014
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Ground-based FTIR soundings of column-average methane from NDACC and TCCON can be combined without the need to apply an overall calibration factor. NDACC and TCCON measurements complement one another and provide valuable information for satellite validation, evaluation of chemical-transport models, and source-sink inversions. The impact of dynamical variability on NDACC and TCCON retrievals of column-average methane is reflected in different smoothing effects.
A. Agustí-Panareda, S. Massart, F. Chevallier, S. Boussetta, G. Balsamo, A. Beljaars, P. Ciais, N. M. Deutscher, R. Engelen, L. Jones, R. Kivi, J.-D. Paris, V.-H. Peuch, V. Sherlock, A. T. Vermeulen, P. O. Wennberg, and D. Wunch
Atmos. Chem. Phys., 14, 11959–11983, https://doi.org/10.5194/acp-14-11959-2014, https://doi.org/10.5194/acp-14-11959-2014, 2014
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This paper presents a new operational CO2 forecast product as part of the Copernicus Atmospheric Services suite of atmospheric composition products, using the state-of-the-art numerical weather prediction model from the European Centre of Medium-Range Weather Forecasts.
The evaluation with independent observations shows that the forecast has skill in predicting the synoptic variability of CO2. The online simulation of CO2 fluxes from vegetation contributes to this skill.
C. Paton-Walsh, T. E. L. Smith, E. L. Young, D. W. T. Griffith, and É.-A. Guérette
Atmos. Chem. Phys., 14, 11313–11333, https://doi.org/10.5194/acp-14-11313-2014, https://doi.org/10.5194/acp-14-11313-2014, 2014
T. E. L. Smith, C. Paton-Walsh, C. P. Meyer, G. D. Cook, S. W. Maier, J. Russell-Smith, M. J. Wooster, and C. P. Yates
Atmos. Chem. Phys., 14, 11335–11352, https://doi.org/10.5194/acp-14-11335-2014, https://doi.org/10.5194/acp-14-11335-2014, 2014
Z. Wang, N. M. Deutscher, T. Warneke, J. Notholt, B. Dils, D. W. T. Griffith, M. Schmidt, M. Ramonet, and C. Gerbig
Atmos. Meas. Tech., 7, 3295–3305, https://doi.org/10.5194/amt-7-3295-2014, https://doi.org/10.5194/amt-7-3295-2014, 2014
N. M. Deutscher, V. Sherlock, S. E. Mikaloff Fletcher, D. W. T. Griffith, J. Notholt, R. Macatangay, B. J. Connor, J. Robinson, H. Shiona, V. A. Velazco, Y. Wang, P. O. Wennberg, and D. Wunch
Atmos. Chem. Phys., 14, 9883–9901, https://doi.org/10.5194/acp-14-9883-2014, https://doi.org/10.5194/acp-14-9883-2014, 2014
C. E. Stockwell, R. J. Yokelson, S. M. Kreidenweis, A. L. Robinson, P. J. DeMott, R. C. Sullivan, J. Reardon, K. C. Ryan, D. W. T. Griffith, and L. Stevens
Atmos. Chem. Phys., 14, 9727–9754, https://doi.org/10.5194/acp-14-9727-2014, https://doi.org/10.5194/acp-14-9727-2014, 2014
K. M. Saad, D. Wunch, G. C. Toon, P. Bernath, C. Boone, B. Connor, N. M. Deutscher, D. W. T. Griffith, R. Kivi, J. Notholt, C. Roehl, M. Schneider, V. Sherlock, and P. O. Wennberg
Atmos. Meas. Tech., 7, 2907–2918, https://doi.org/10.5194/amt-7-2907-2014, https://doi.org/10.5194/amt-7-2907-2014, 2014
E. Sepúlveda, M. Schneider, F. Hase, S. Barthlott, D. Dubravica, O. E. García, A. Gomez-Pelaez, Y. González, J. C. Guerra, M. Gisi, R. Kohlhepp, S. Dohe, T. Blumenstock, K. Strong, D. Weaver, M. Palm, A. Sadeghi, N. M. Deutscher, T. Warneke, J. Notholt, N. Jones, D. W. T. Griffith, D. Smale, G. W. Brailsford, J. Robinson, F. Meinhardt, M. Steinbacher, T. Aalto, and D. Worthy
Atmos. Meas. Tech., 7, 2337–2360, https://doi.org/10.5194/amt-7-2337-2014, https://doi.org/10.5194/amt-7-2337-2014, 2014
B. Dils, M. Buchwitz, M. Reuter, O. Schneising, H. Boesch, R. Parker, S. Guerlet, I. Aben, T. Blumenstock, J. P. Burrows, A. Butz, N. M. Deutscher, C. Frankenberg, F. Hase, O. P. Hasekamp, J. Heymann, M. De Mazière, J. Notholt, R. Sussmann, T. Warneke, D. Griffith, V. Sherlock, and D. Wunch
Atmos. Meas. Tech., 7, 1723–1744, https://doi.org/10.5194/amt-7-1723-2014, https://doi.org/10.5194/amt-7-1723-2014, 2014
A. Galli, S. Guerlet, A. Butz, I. Aben, H. Suto, A. Kuze, N. M. Deutscher, J. Notholt, D. Wunch, P. O. Wennberg, D. W. T. Griffith, O. Hasekamp, and J. Landgraf
Atmos. Meas. Tech., 7, 1105–1119, https://doi.org/10.5194/amt-7-1105-2014, https://doi.org/10.5194/amt-7-1105-2014, 2014
F. Deng, D. B. A. Jones, D. K. Henze, N. Bousserez, K. W. Bowman, J. B. Fisher, R. Nassar, C. O'Dell, D. Wunch, P. O. Wennberg, E. A. Kort, S. C. Wofsy, T. Blumenstock, N. M. Deutscher, D. W. T. Griffith, F. Hase, P. Heikkinen, V. Sherlock, K. Strong, R. Sussmann, and T. Warneke
Atmos. Chem. Phys., 14, 3703–3727, https://doi.org/10.5194/acp-14-3703-2014, https://doi.org/10.5194/acp-14-3703-2014, 2014
S. K. Akagi, I. R. Burling, A. Mendoza, T. J. Johnson, M. Cameron, D. W. T. Griffith, C. Paton-Walsh, D. R. Weise, J. Reardon, and R. J. Yokelson
Atmos. Chem. Phys., 14, 199–215, https://doi.org/10.5194/acp-14-199-2014, https://doi.org/10.5194/acp-14-199-2014, 2014
D. Wunch, P. O. Wennberg, J. Messerschmidt, N. C. Parazoo, G. C. Toon, N. M. Deutscher, G. Keppel-Aleks, C. M. Roehl, J. T. Randerson, T. Warneke, and J. Notholt
Atmos. Chem. Phys., 13, 9447–9459, https://doi.org/10.5194/acp-13-9447-2013, https://doi.org/10.5194/acp-13-9447-2013, 2013
Y. Yoshida, N. Kikuchi, I. Morino, O. Uchino, S. Oshchepkov, A. Bril, T. Saeki, N. Schutgens, G. C. Toon, D. Wunch, C. M. Roehl, P. O. Wennberg, D. W. T. Griffith, N. M. Deutscher, T. Warneke, J. Notholt, J. Robinson, V. Sherlock, B. Connor, M. Rettinger, R. Sussmann, P. Ahonen, P. Heikkinen, E. Kyrö, J. Mendonca, K. Strong, F. Hase, S. Dohe, and T. Yokota
Atmos. Meas. Tech., 6, 1533–1547, https://doi.org/10.5194/amt-6-1533-2013, https://doi.org/10.5194/amt-6-1533-2013, 2013
J. Messerschmidt, N. Parazoo, D. Wunch, N. M. Deutscher, C. Roehl, T. Warneke, and P. O. Wennberg
Atmos. Chem. Phys., 13, 5103–5115, https://doi.org/10.5194/acp-13-5103-2013, https://doi.org/10.5194/acp-13-5103-2013, 2013
R. A. Scheepmaker, C. Frankenberg, A. Galli, A. Butz, H. Schrijver, N. M. Deutscher, D. Wunch, T. Warneke, S. Fally, and I. Aben
Atmos. Meas. Tech., 6, 879–894, https://doi.org/10.5194/amt-6-879-2013, https://doi.org/10.5194/amt-6-879-2013, 2013
H. Boesch, N. M. Deutscher, T. Warneke, K. Byckling, A. J. Cogan, D. W. T. Griffith, J. Notholt, R. J. Parker, and Z. Wang
Atmos. Meas. Tech., 6, 599–612, https://doi.org/10.5194/amt-6-599-2013, https://doi.org/10.5194/amt-6-599-2013, 2013
S. K. Akagi, R. J. Yokelson, I. R. Burling, S. Meinardi, I. Simpson, D. R. Blake, G. R. McMeeking, A. Sullivan, T. Lee, S. Kreidenweis, S. Urbanski, J. Reardon, D. W. T. Griffith, T. J. Johnson, and D. R. Weise
Atmos. Chem. Phys., 13, 1141–1165, https://doi.org/10.5194/acp-13-1141-2013, https://doi.org/10.5194/acp-13-1141-2013, 2013
R. J. Yokelson, I. R. Burling, J. B. Gilman, C. Warneke, C. E. Stockwell, J. de Gouw, S. K. Akagi, S. P. Urbanski, P. Veres, J. M. Roberts, W. C. Kuster, J. Reardon, D. W. T. Griffith, T. J. Johnson, S. Hosseini, J. W. Miller, D. R. Cocker III, H. Jung, and D. R. Weise
Atmos. Chem. Phys., 13, 89–116, https://doi.org/10.5194/acp-13-89-2013, https://doi.org/10.5194/acp-13-89-2013, 2013
M. Schneider, S. Barthlott, F. Hase, Y. González, K. Yoshimura, O. E. García, E. Sepúlveda, A. Gomez-Pelaez, M. Gisi, R. Kohlhepp, S. Dohe, T. Blumenstock, A. Wiegele, E. Christner, K. Strong, D. Weaver, M. Palm, N. M. Deutscher, T. Warneke, J. Notholt, B. Lejeune, P. Demoulin, N. Jones, D. W. T. Griffith, D. Smale, and J. Robinson
Atmos. Meas. Tech., 5, 3007–3027, https://doi.org/10.5194/amt-5-3007-2012, https://doi.org/10.5194/amt-5-3007-2012, 2012
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Seasonal, regional, and vertical characteristics of high-carbon-monoxide plumes along with their associated ozone anomalies, as seen by IAGOS between 2002 and 2019
The potential of drone observations to improve air quality predictions by 4D-Var
Process analysis of elevated concentrations of organic acids at Whiteface Mountain, New York
Ozone source attribution in polluted European areas during summer 2017 as simulated with MECO(n)
Opinion: Challenges and needs of tropospheric chemical mechanism development
The atmospheric oxidizing capacity in China – Part 2: Sensitivity to emissions of primary pollutants
Role of chemical production and depositional losses on formaldehyde in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM)
Review of source analyses of ambient volatile organic compounds considering reactive losses: methods of reducing loss effects, impacts of losses, and sources
Interpreting summertime hourly variation of NO2 columns with implications for geostationary satellite applications
An investigation into atmospheric nitrous acid (HONO) processes in South Korea
Performance evaluation of UKESM1 for surface ozone across the pan-tropics
Constraining light dependency in modeled emissions through comparison to observed biogenic volatile organic compound (BVOC) concentrations in a southeastern US forest
A global re-analysis of regionally resolved emissions and atmospheric mole fractions of SF6 for the period 2005–2021
Tropospheric ozone precursors: global and regional distributions, trends, and variability
The contribution of transport emissions to ozone mixing ratios and methane lifetime in 2015 and 2050 in the Shared Socioeconomic Pathways (SSPs)
Ether and ester formation from peroxy radical recombination: a qualitative reaction channel analysis
ACEIC: a comprehensive anthropogenic chlorine emission inventory for China
Impact of methane and other precursor emission reductions on surface ozone in Europe: scenario analysis using the European Monitoring and Evaluation Programme (EMEP) Meteorological Synthesizing Centre – West (MSC-W) model
Verifying national inventory-based combustion emissions of CO2 across the UK and mainland Europe using satellite observations of atmospheric CO and CO2
An improved estimate of inorganic iodine emissions from the ocean using a coupled surface microlayer box model
Impact of improved representation of volatile organic compound emissions and production of NOx reservoirs on modeled urban ozone production
The effect of different climate and air quality policies in China on in situ ozone production in Beijing
Assessing the relative impacts of satellite ozone and its precursor observations to improve global tropospheric ozone analysis using multiple chemical reanalysis systems
Evaluating present-day and future impacts of agricultural ammonia emissions on atmospheric chemistry and climate
Enhancing long-term trend simulation of the global tropospheric hydroxyl (TOH) and its drivers from 2005 to 2019: a synergistic integration of model simulations and satellite observations
Intercomparison of GEOS-Chem and CAM-chem tropospheric oxidant chemistry within the Community Earth System Model version 2 (CESM2)
Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation
Air pollution satellite-based CO2 emission inversion: system evaluation, sensitivity analysis, and future perspective
Anthropogenic emission controls reduce summertime ozone-temperature sensitivity in the United States
Large contributions of soil emissions to the atmospheric nitrogen budget and their impacts on air quality and temperature rise in North China
Why did ozone concentrations remain high during Shanghai's static management? A statistical and radical-chemistry perspective
Impact of introducing electric vehicles on ground-level O3 and PM2.5 in the Greater Tokyo Area: Yearly trends and the importance of changes in the Urban Heat Island effect
Revising VOC emissions speciation improves the simulation of global background ethane and propane
Changes in South American surface ozone trends: exploring the influences of precursors and extreme events
Evaluating NOx stack plume emissions using a high-resolution atmospheric chemistry model and satellite-derived NO2 columns
NOx emissions in France in 2019–2021 as estimated by the high-spatial-resolution assimilation of TROPOMI NO2 observations
Urban ozone formation and sensitivities to volatile chemical products, cooking emissions, and NOx across the Los Angeles Basin
Aggravated surface O3 pollution primarily driven by meteorological variations in China during the 2020 COVID-19 pandemic lockdown period
Identifying decadal trends in deweathered concentrations of criteria air pollutants in Canadian urban atmospheres with machine learning approaches
Evaluation of modelled versus observed non-methane volatile organic compounds at European Monitoring and Evaluation Programme sites in Europe
Constraining non-methane VOC emissions with TROPOMI HCHO observations: impact on summertime ozone simulation in August 2022 in China
Insights on ozone pollution control in urban areas by decoupling meteorological factors based on machine learning
Revealing the significant acceleration of hydrofluorocarbon (HFC) emissions in eastern Asia through long-term atmospheric observations
Interpreting Geostationary Environment Monitoring Spectrometer (GEMS) geostationary satellite observations of the diurnal variation in nitrogen dioxide (NO2) over East Asia
An intercomparison of satellite, airborne, and ground-level observations with WRF–CAMx simulations of NO2 columns over Houston, Texas, during the September 2021 TRACER-AQ campaign
Investigating processes influencing simulation of local Arctic wintertime anthropogenic pollution in Fairbanks, Alaska during ALPACA-2022
Interannual variability of summertime formaldehyde (HCHO) vertical column density and its main drivers at northern high latitudes
The impact of multi-decadal changes in VOC speciation on urban ozone chemistry: a case study in Birmingham, United Kingdom
Technical note: Challenges in detecting free tropospheric ozone trends in a sparsely sampled environment
Combined assimilation of NOAA surface and MIPAS satellite observations to constrain the global budget of carbonyl sulfide
Thibaut Lebourgeois, Bastien Sauvage, Pawel Wolff, Béatrice Josse, Virginie Marécal, Yasmine Bennouna, Romain Blot, Damien Boulanger, Hannah Clark, Jean-Marc Cousin, Philippe Nedelec, and Valérie Thouret
Atmos. Chem. Phys., 24, 13975–14004, https://doi.org/10.5194/acp-24-13975-2024, https://doi.org/10.5194/acp-24-13975-2024, 2024
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Our study examines intense-carbon-monoxide (CO) pollution events measured by commercial aircraft from the In-service Aircraft for a Global Observing System (IAGOS) research infrastructure. We combine these measurements with the SOFT-IO model to trace the origin of the observed CO. A comprehensive analysis of the geographical origin, source type, seasonal variation, and ozone levels of these pollution events is provided.
Hassnae Erraji, Philipp Franke, Astrid Lampert, Tobias Schuldt, Ralf Tillmann, Andreas Wahner, and Anne Caroline Lange
Atmos. Chem. Phys., 24, 13913–13934, https://doi.org/10.5194/acp-24-13913-2024, https://doi.org/10.5194/acp-24-13913-2024, 2024
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Four-dimensional variational data assimilation allows for the simultaneous optimisation of initial values and emission rates by using trace-gas profiles from drone observations in a regional air quality model. Assimilated profiles positively impact the representation of air pollutants in the model by improving their vertical distribution and ground-level concentrations. This case study highlights the potential of drone data to enhance air quality analyses including local emission evaluation.
Christopher Lawrence, Mary Barth, John Orlando, Paul Casson, Richard Brandt, Daniel Kelting, Elizabeth Yerger, and Sara Lance
Atmos. Chem. Phys., 24, 13693–13713, https://doi.org/10.5194/acp-24-13693-2024, https://doi.org/10.5194/acp-24-13693-2024, 2024
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This work uses chemical transport and box modeling to study the gas- and aqueous-phase production of organic acid concentrations measured in cloud water at the summit of Whiteface Mountain on 1 July 2018. Isoprene was the major source of formic, acetic, and oxalic acid. Gas-phase chemistry greatly underestimated formic and acetic acid, indicating missing sources, while cloud chemistry was a key source of oxalic acid. More studies of organic acids are required to better constrain their sources.
Markus Kilian, Volker Grewe, Patrick Jöckel, Astrid Kerkweg, Mariano Mertens, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 24, 13503–13523, https://doi.org/10.5194/acp-24-13503-2024, https://doi.org/10.5194/acp-24-13503-2024, 2024
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Anthropogenic emissions are a major source of precursors of tropospheric ozone. As ozone formation is highly non-linear, we apply a global–regional chemistry–climate model with a source attribution method (tagging) to quantify the contribution of anthropogenic emissions to ozone. Our analysis shows that the contribution of European anthropogenic emissions largely increases during large ozone periods, indicating that emissions from these sectors drive ozone values.
Barbara Ervens, Andrew Rickard, Bernard Aumont, William P. L. Carter, Max McGillen, Abdelwahid Mellouki, John Orlando, Bénédicte Picquet-Varrault, Paul Seakins, William R. Stockwell, Luc Vereecken, and Timothy J. Wallington
Atmos. Chem. Phys., 24, 13317–13339, https://doi.org/10.5194/acp-24-13317-2024, https://doi.org/10.5194/acp-24-13317-2024, 2024
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Chemical mechanisms describe the chemical processes in atmospheric models that are used to describe the changes in the atmospheric composition. Therefore, accurate chemical mechanisms are necessary to predict the evolution of air pollution and climate change. The article describes all steps that are needed to build chemical mechanisms and discusses the advances and needs of experimental and theoretical research activities needed to build reliable chemical mechanisms.
Jianing Dai, Guy P. Brasseur, Mihalis Vrekoussis, Maria Kanakidou, Kun Qu, Yijuan Zhang, Hongliang Zhang, and Tao Wang
Atmos. Chem. Phys., 24, 12943–12962, https://doi.org/10.5194/acp-24-12943-2024, https://doi.org/10.5194/acp-24-12943-2024, 2024
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This paper employs a regional chemical transport model to quantify the sensitivity of air pollutants and photochemical parameters to specified emission reductions in China for representative winter and summer conditions. The study provides insights into further air quality control in China with reduced primary emissions.
T. Nash Skipper, Emma L. D'Ambro, Forwood C. Wiser, V. Faye McNeill, Rebecca H. Schwantes, Barron H. Henderson, Ivan R. Piletic, Colleen B. Baublitz, Jesse O. Bash, Andrew R. Whitehill, Lukas C. Valin, Asher P. Mouat, Jennifer Kaiser, Glenn M. Wolfe, Jason M. St. Clair, Thomas F. Hanisco, Alan Fried, Bryan K. Place, and Havala O.T. Pye
Atmos. Chem. Phys., 24, 12903–12924, https://doi.org/10.5194/acp-24-12903-2024, https://doi.org/10.5194/acp-24-12903-2024, 2024
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We develop the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) version 2 to improve predictions of formaldehyde in ambient air compared to satellite-, aircraft-, and ground-based observations. With the updated chemistry, we estimate the cancer risk from inhalation exposure to ambient formaldehyde across the contiguous USA and predict that 40 % of this risk is controllable through reductions in anthropogenic emissions of nitrogen oxides and reactive organic carbon.
Baoshuang Liu, Yao Gu, Yutong Wu, Qili Dai, Shaojie Song, Yinchang Feng, and Philip K. Hopke
Atmos. Chem. Phys., 24, 12861–12879, https://doi.org/10.5194/acp-24-12861-2024, https://doi.org/10.5194/acp-24-12861-2024, 2024
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Reactive loss of volatile organic compounds (VOCs) is a long-term issue yet to be resolved in VOC source analyses. We assess common methods of, and existing issues in, reducing losses, impacts of losses, and sources in current source analyses. We offer a potential supporting role for solving issues of VOC conversion. Source analyses of consumed VOCs that reacted to produce ozone and secondary organic aerosols can play an important role in the effective control of secondary pollution in air.
Deepangsu Chatterjee, Randall V. Martin, Chi Li, Dandan Zhang, Haihui Zhu, Daven K. Henze, James H. Crawford, Ronald C. Cohen, Lok N. Lamsal, and Alexander M. Cede
Atmos. Chem. Phys., 24, 12687–12706, https://doi.org/10.5194/acp-24-12687-2024, https://doi.org/10.5194/acp-24-12687-2024, 2024
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We investigate the hourly variation of NO2 columns and surface concentrations by applying the GEOS-Chem model to interpret aircraft and ground-based measurements over the US and Pandora sun photometer measurements over the US, Europe, and Asia. Corrections to the Pandora columns and finer model resolution improve the modeled representation of the summertime hourly variation of total NO2 columns to explain the weaker hourly variation in NO2 columns than at the surface.
Kiyeon Kim, Kyung Man Han, Chul Han Song, Hyojun Lee, Ross Beardsley, Jinhyeok Yu, Greg Yarwood, Bonyoung Koo, Jasper Madalipay, Jung-Hun Woo, and Seogju Cho
Atmos. Chem. Phys., 24, 12575–12593, https://doi.org/10.5194/acp-24-12575-2024, https://doi.org/10.5194/acp-24-12575-2024, 2024
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We incorporated each HONO process into the current CMAQ modeling framework to enhance the accuracy of HONO mixing ratio predictions. These results expand our understanding of HONO photochemistry and identify crucial sources of HONO that impact the total HONO budget in Seoul, South Korea. Through this investigation, we contribute to resolving discrepancies in understanding chemical transport models, with implications for better air quality management and environmental protection in the region.
Flossie Brown, Gerd Folberth, Stephen Sitch, Paulo Artaxo, Marijn Bauters, Pascal Boeckx, Alexander W. Cheesman, Matteo Detto, Ninong Komala, Luciana Rizzo, Nestor Rojas, Ines dos Santos Vieira, Steven Turnock, Hans Verbeeck, and Alfonso Zambrano
Atmos. Chem. Phys., 24, 12537–12555, https://doi.org/10.5194/acp-24-12537-2024, https://doi.org/10.5194/acp-24-12537-2024, 2024
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Ozone is a pollutant that is detrimental to human and plant health. Ozone monitoring sites in the tropics are limited, so models are often used to understand ozone exposure. We use measurements from the tropics to evaluate ozone from the UK Earth system model, UKESM1. UKESM1 is able to capture the pattern of ozone in the tropics, except in southeast Asia, although it systematically overestimates it at all sites. This work highlights that UKESM1 can capture seasonal and hourly variability.
Namrata Shanmukh Panji, Deborah F. McGlynn, Laura E. R. Barry, Todd M. Scanlon, Manuel T. Lerdau, Sally E. Pusede, and Gabriel Isaacman-VanWertz
Atmos. Chem. Phys., 24, 12495–12507, https://doi.org/10.5194/acp-24-12495-2024, https://doi.org/10.5194/acp-24-12495-2024, 2024
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Climate change will bring about changes in parameters that are currently used in global-scale models to calculate biogenic emissions. This study seeks to understand the factors driving these models by comparing long-term datasets of biogenic compounds to modeled emissions. We note that the light-dependent fractions currently used in models do not accurately represent regional observations. We provide evidence for the time-dependent variation in this parameter for future modifications to models.
Martin Vojta, Andreas Plach, Saurabh Annadate, Sunyoung Park, Gawon Lee, Pallav Purohit, Florian Lindl, Xin Lan, Jens Mühle, Rona L. Thompson, and Andreas Stohl
Atmos. Chem. Phys., 24, 12465–12493, https://doi.org/10.5194/acp-24-12465-2024, https://doi.org/10.5194/acp-24-12465-2024, 2024
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We constrain the global emissions of the very potent greenhouse gas sulfur hexafluoride (SF6) between 2005 and 2021. We show that SF6 emissions are decreasing in the USA and in the EU, while they are substantially growing in China, leading overall to an increasing global emission trend. The national reports for the USA, EU, and China all underestimated their SF6 emissions. However, stringent mitigation measures can successfully reduce SF6 emissions, as can be seen in the EU emission trend.
Yasin Elshorbany, Jerald R. Ziemke, Sarah Strode, Hervé Petetin, Kazuyuki Miyazaki, Isabelle De Smedt, Kenneth Pickering, Rodrigo J. Seguel, Helen Worden, Tamara Emmerichs, Domenico Taraborrelli, Maria Cazorla, Suvarna Fadnavis, Rebecca R. Buchholz, Benjamin Gaubert, Néstor Y. Rojas, Thiago Nogueira, Thérèse Salameh, and Min Huang
Atmos. Chem. Phys., 24, 12225–12257, https://doi.org/10.5194/acp-24-12225-2024, https://doi.org/10.5194/acp-24-12225-2024, 2024
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We investigated tropospheric ozone spatial variability and trends from 2005 to 2019 and related those to ozone precursors on global and regional scales. We also investigate the spatiotemporal characteristics of the ozone formation regime in relation to ozone chemical sources and sinks. Our analysis is based on remote sensing products of the tropospheric column of ozone and its precursors, nitrogen dioxide, formaldehyde, and total column CO, as well as ozonesonde data and model simulations.
Mariano Mertens, Sabine Brinkop, Phoebe Graf, Volker Grewe, Johannes Hendricks, Patrick Jöckel, Anna Lanteri, Sigrun Matthes, Vanessa S. Rieger, Mattia Righi, and Robin N. Thor
Atmos. Chem. Phys., 24, 12079–12106, https://doi.org/10.5194/acp-24-12079-2024, https://doi.org/10.5194/acp-24-12079-2024, 2024
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We quantified the contributions of land transport, shipping, and aviation emissions to tropospheric ozone; its radiative forcing; and the reductions of the methane lifetime using chemistry-climate model simulations. The contributions were analysed for the conditions of 2015 and for three projections for the year 2050. The results highlight the challenges of mitigating ozone formed by emissions of the transport sector, caused by the non-linearitiy of the ozone chemistry and the long lifetime.
Lauri Franzon, Marie Camredon, Richard Valorso, Bernard Aumont, and Theo Kurtén
Atmos. Chem. Phys., 24, 11679–11699, https://doi.org/10.5194/acp-24-11679-2024, https://doi.org/10.5194/acp-24-11679-2024, 2024
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In this article we investigate the formation of large, sticky molecules from various organic compounds entering the atmosphere as primary emissions and the degree to which these processes may contribute to organic aerosol particle mass. More specifically, we qualitatively investigate a recently discovered chemical reaction channel for one of the most important short-lived radical compounds, peroxy radicals, and discover which of these reactions are most atmospherically important.
Siting Li, Yiming Liu, Yuqi Zhu, Yinbao Jin, Yingying Hong, Ao Shen, Yifei Xu, Haofan Wang, Haichao Wang, Xiao Lu, Shaojia Fan, and Qi Fan
Atmos. Chem. Phys., 24, 11521–11544, https://doi.org/10.5194/acp-24-11521-2024, https://doi.org/10.5194/acp-24-11521-2024, 2024
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This study establishes an inventory of anthropogenic chlorine emissions in China in 2019 with expanded species (HCl, Cl-, Cl2, HOCl) and sources (41 specific sources). The inventory is validated by a modeling study against the observations. This study enhances the understanding of anthropogenic chlorine emissions in the atmosphere, identifies key sources, and provides scientific support for pollution control and climate change.
Willem E. van Caspel, Zbigniew Klimont, Chris Heyes, and Hilde Fagerli
Atmos. Chem. Phys., 24, 11545–11563, https://doi.org/10.5194/acp-24-11545-2024, https://doi.org/10.5194/acp-24-11545-2024, 2024
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Methane in the atmosphere contributes to the production of ozone gas – an air pollutant and greenhouse gas. Our results highlight that simultaneous reductions in methane emissions help avoid offsetting the air pollution benefits already achieved by the already-approved precursor emission reductions by 2050 in the European Monitoring and Evaluation Programme region, while also playing an important role in bringing air pollution further down towards World Health Organization guideline limits.
Tia R. Scarpelli, Paul I. Palmer, Mark Lunt, Ingrid Super, and Arjan Droste
Atmos. Chem. Phys., 24, 10773–10791, https://doi.org/10.5194/acp-24-10773-2024, https://doi.org/10.5194/acp-24-10773-2024, 2024
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Under the Paris Agreement, countries must track their anthropogenic greenhouse gas emissions. This study describes a method to determine self-consistent estimates for combustion emissions and natural fluxes of CO2 from atmospheric data. We report consistent estimates inferred using this approach from satellite data and ground-based data over Europe, suggesting that satellite data can be used to determine national anthropogenic CO2 emissions for countries where ground-based CO2 data are absent.
Ryan J. Pound, Lucy V. Brown, Mat J. Evans, and Lucy J. Carpenter
Atmos. Chem. Phys., 24, 9899–9921, https://doi.org/10.5194/acp-24-9899-2024, https://doi.org/10.5194/acp-24-9899-2024, 2024
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Iodine-mediated loss of ozone to the ocean surface and the subsequent emission of iodine species has a large effect on the troposphere. Here we combine recent experimental insights to develop a box model of the process, which we then parameterize and incorporate into the GEOS-Chem transport model. We find that these new insights have a small impact on the total emission of iodine but significantly change its distribution.
Katherine R. Travis, Benjamin A. Nault, James H. Crawford, Kelvin H. Bates, Donald R. Blake, Ronald C. Cohen, Alan Fried, Samuel R. Hall, L. Gregory Huey, Young Ro Lee, Simone Meinardi, Kyung-Eun Min, Isobel J. Simpson, and Kirk Ullman
Atmos. Chem. Phys., 24, 9555–9572, https://doi.org/10.5194/acp-24-9555-2024, https://doi.org/10.5194/acp-24-9555-2024, 2024
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Human activities result in the emission of volatile organic compounds (VOCs) that contribute to air pollution. Detailed VOC measurements were taken during a field study in South Korea. When compared to VOC inventories, large discrepancies showed underestimates from chemical products, liquefied petroleum gas, and long-range transport. Improved emissions and chemistry of these VOCs better described urban pollution. The new chemical scheme is relevant to urban areas and other VOC sources.
Beth S. Nelson, Zhenze Liu, Freya A. Squires, Marvin Shaw, James R. Hopkins, Jacqueline F. Hamilton, Andrew R. Rickard, Alastair C. Lewis, Zongbo Shi, and James D. Lee
Atmos. Chem. Phys., 24, 9031–9044, https://doi.org/10.5194/acp-24-9031-2024, https://doi.org/10.5194/acp-24-9031-2024, 2024
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The impact of combined air quality and carbon neutrality policies on O3 formation in Beijing was investigated. Emissions inventory data were used to estimate future pollutant mixing ratios relative to ground-level observations. O3 production was found to be most sensitive to changes in alkenes, but large reductions in less reactive compounds led to larger reductions in future O3 production. This study highlights the importance of understanding the emissions of organic pollutants.
Takashi Sekiya, Emanuele Emili, Kazuyuki Miyazaki, Antje Inness, Zhen Qu, R. Bradley Pierce, Dylan Jones, Helen Worden, William Y. Y. Cheng, Vincent Huijnen, and Gerbrand Koren
EGUsphere, https://doi.org/10.5194/egusphere-2024-2426, https://doi.org/10.5194/egusphere-2024-2426, 2024
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Five global chemical reanalysis datasets were used to assess the relative impacts of assimilating satellite ozone and its precursors measurements on tropospheric ozone analyses for 2010. The multiple reanalysis system comparison allows for evaluating dependency of the impacts on different reanalysis systems. The results suggested the importance of satellite ozone and its precursor measurements for improving ozone analysis in the whole troposphere, with varying the magnitudes among the systems.
Maureen Beaudor, Didier Hauglustaine, Juliette Lathière, Martin Van Damme, Lieven Clarisse, and Nicolas Vuichard
EGUsphere, https://doi.org/10.5194/egusphere-2024-2022, https://doi.org/10.5194/egusphere-2024-2022, 2024
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Agriculture is the biggest ammonia (NH3) source, impacting air quality, climate, and ecosystems. Because of food demand, NH3 emissions are projected to rise by 2100. Using a global model, we analyzed the impact of present and future NH3 emissions generated from a land model. Our results show improved ammonia patterns compared to a reference inventory. Future scenarios predict up to 70 % increase in global NH3 burden, significant changes in radiative forcing, and could significantly elevate N2O.
Amir H. Souri, Bryan N. Duncan, Sarah A. Strode, Daniel C. Anderson, Michael E. Manyin, Junhua Liu, Luke D. Oman, Zhen Zhang, and Brad Weir
Atmos. Chem. Phys., 24, 8677–8701, https://doi.org/10.5194/acp-24-8677-2024, https://doi.org/10.5194/acp-24-8677-2024, 2024
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We explore a new method of using the wealth of information obtained from satellite observations of Aura OMI NO2, HCHO, and MERRA-2 reanalysis in NASA’s GEOS model equipped with an efficient tropospheric OH (TOH) estimator to enhance the representation of TOH spatial distribution and its long-term trends. This new framework helps us pinpoint regional inaccuracies in TOH and differentiate between established prior knowledge and newly acquired information from satellites on TOH trends.
Haipeng Lin, Louisa K. Emmons, Elizabeth W. Lundgren, Laura Hyesung Yang, Xu Feng, Ruijun Dang, Shixian Zhai, Yunxiao Tang, Makoto M. Kelp, Nadia K. Colombi, Sebastian D. Eastham, Thibaud M. Fritz, and Daniel J. Jacob
Atmos. Chem. Phys., 24, 8607–8624, https://doi.org/10.5194/acp-24-8607-2024, https://doi.org/10.5194/acp-24-8607-2024, 2024
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Tropospheric ozone is a major air pollutant, a greenhouse gas, and a major indicator of model skill. Global atmospheric chemistry models show large differences in simulations of tropospheric ozone, but isolating sources of differences is complicated by different model environments. By implementing the GEOS-Chem model side by side to CAM-chem within a common Earth system model, we identify and evaluate specific differences between the two models and their impacts on key chemical species.
Victor Lannuque and Karine Sartelet
Atmos. Chem. Phys., 24, 8589–8606, https://doi.org/10.5194/acp-24-8589-2024, https://doi.org/10.5194/acp-24-8589-2024, 2024
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Large uncertainties remain in understanding secondary organic aerosol (SOA) formation and speciation from naphthalene oxidation. This study details the development of the first near-explicit chemical scheme for naphthalene oxidation by OH, which includes kinetic and mechanistic data, and is able to reproduce most of the experimentally identified products in both gas and particle phases.
Hui Li, Jiaxin Qiu, and Bo Zheng
EGUsphere, https://doi.org/10.5194/egusphere-2024-1986, https://doi.org/10.5194/egusphere-2024-1986, 2024
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We conduct a sensitivity analysis on various factors including prior, model resolution, satellite constraint, and inversion system configuration to assess the vulnerability of emission estimates across temporal, sectoral, and regional dimensions. Our analysis first reveals the robustness of emissions estimated by this air pollution satellite sensor-based CO2 emission inversion system, with relative change between tests and Base inversion below 4.0 % for national annual NOx and CO2 emissions.
Shuai Li, Xiao Lu, and Haolin Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1889, https://doi.org/10.5194/egusphere-2024-1889, 2024
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We report that the summertime ozone-temperature sensitivity decreased by 50 % from 3.0 ppbv/K in 1990 to 1.5 ppb/K in 2021 in the US. GEOS-Chem simulations show that anthropogenic NOx emission reduction is the dominant driver of the ozone-temperature sensitivity decline, through influencing both the temperature-direct and temperature-indirect processes. Reduced ozone-temperature sensitivity has decreased the ozone enhancement from low to high temperatures by an average of 6.8 ppbv across the US.
Tong Sha, Siyu Yang, Qingcai Chen, Liangqing Li, Xiaoyan Ma, Yan-Lin Zhang, Zhaozhong Feng, K. Folkert Boersma, and Jun Wang
Atmos. Chem. Phys., 24, 8441–8455, https://doi.org/10.5194/acp-24-8441-2024, https://doi.org/10.5194/acp-24-8441-2024, 2024
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Using an updated soil reactive nitrogen emission scheme in the Unified Inputs for Weather Research and Forecasting coupled with Chemistry (UI-WRF-Chem) model, we investigate the role of soil NO and HONO (Nr) emissions in air quality and temperature in North China. Contributions of soil Nr emissions to O3 and secondary pollutants are revealed, exceeding effects of soil NOx or HONO emission. Soil Nr emissions play an important role in mitigating O3 pollution and addressing climate change.
Jian Zhu, Shanshan Wang, Chuanqi Gu, Zhiwen Jiang, Sanbao Zhang, Ruibin Xue, Yuhao Yan, and Bin Zhou
Atmos. Chem. Phys., 24, 8383–8395, https://doi.org/10.5194/acp-24-8383-2024, https://doi.org/10.5194/acp-24-8383-2024, 2024
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In 2022, Shanghai implemented city-wide static management measures during the high-ozone season in April and May, providing a chance to study ozone pollution control. Despite significant emissions reductions, ozone levels increased by 23 %. Statistically, the number of days with higher ozone diurnal variation types increased during the lockdown period. The uneven decline in VOC and NO2 emissions led to heightened photochemical processes, resulting in the observed ozone level rise.
Hiroo Hata, Norifumi Mizushima, and Tomohiko Ihara
EGUsphere, https://doi.org/10.5194/egusphere-2024-1961, https://doi.org/10.5194/egusphere-2024-1961, 2024
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The introduction of battery electric vehicles (BEV) is expected to reduce the primary air pollutants from vehicular exhaust and evaporative emissions while reducing the anthropogenic heat produced by vehicles, ultimately decreasing the urban heat island effect (UHI). This study revealed the impact of introducing BEVs on the decrease in UHI and the effects of BEVs on the formation of tropospheric ozone and fine particulate matter in the Greater Tokyo Area of Japan.
Matthew J. Rowlinson, Mat J. Evans, Lucy J. Carpenter, Katie A. Read, Shalini Punjabi, Adedayo Adedeji, Luke Fakes, Ally Lewis, Ben Richmond, Neil Passant, Tim Murrells, Barron Henderson, Kelvin H. Bates, and Detlev Helmig
Atmos. Chem. Phys., 24, 8317–8342, https://doi.org/10.5194/acp-24-8317-2024, https://doi.org/10.5194/acp-24-8317-2024, 2024
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Ethane and propane are volatile organic compounds emitted from human activities which help to form ozone, a pollutant and greenhouse gas, and also affect the chemistry of the lower atmosphere. Atmospheric models tend to do a poor job of reproducing the abundance of these compounds in the atmosphere. By using regional estimates of their emissions, rather than globally consistent estimates, we can significantly improve the simulation of ethane in the model and make some improvement for propane.
Rodrigo J. Seguel, Lucas Castillo, Charlie Opazo, Néstor Y. Rojas, Thiago Nogueira, María Cazorla, Mario Gavidia-Calderón, Laura Gallardo, René Garreaud, Tomás Carrasco-Escaff, and Yasin Elshorbany
Atmos. Chem. Phys., 24, 8225–8242, https://doi.org/10.5194/acp-24-8225-2024, https://doi.org/10.5194/acp-24-8225-2024, 2024
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Trends of surface ozone were examined across South America. Our findings indicate that ozone trends in major South American cities either increase or remain steady, with no signs of decline. The upward trends can be attributed to chemical regimes that efficiently convert nitric oxide into nitrogen dioxide. Additionally, our results suggest a climate penalty for ozone driven by meteorological conditions that favor wildfire propagation in Chile and extensive heat waves in southern Brazil.
Maarten Krol, Bart van Stratum, Isidora Anglou, and Klaas Folkert Boersma
Atmos. Chem. Phys., 24, 8243–8262, https://doi.org/10.5194/acp-24-8243-2024, https://doi.org/10.5194/acp-24-8243-2024, 2024
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This paper presents detailed plume simulations of nitrogen oxides and carbon dioxide that are emitted from four large industrial facilities world-wide. Results from the high-resolution simulations that include atmospheric chemistry are compared to nitrogen dioxide observations from satellites. We find good performance of the model and show that common assumptions that are used in simplified models need revision. This work is important for the monitoring of emissions using satellite data.
Robin Plauchu, Audrey Fortems-Cheiney, Grégoire Broquet, Isabelle Pison, Antoine Berchet, Elise Potier, Gaëlle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, and Henk Eskes
Atmos. Chem. Phys., 24, 8139–8163, https://doi.org/10.5194/acp-24-8139-2024, https://doi.org/10.5194/acp-24-8139-2024, 2024
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This study uses the Community Inversion Framework and CHIMERE model to assess the potential of TROPOMI-S5P PAL NO2 tropospheric column data to estimate NOx emissions in France (2019–2021). Results show a 3 % decrease in average emissions compared to the 2016 CAMS-REG/INS, lower than the 14 % decrease from CITEPA. The study highlights challenges in capturing emission anomalies due to limited data coverage and error levels but shows promise for local inventory improvements.
Chelsea E. Stockwell, Matthew M. Coggon, Rebecca H. Schwantes, Colin Harkins, Bert Verreyken, Congmeng Lyu, Qindan Zhu, Lu Xu, Jessica B. Gilman, Aaron Lamplugh, Jeff Peischl, Michael A. Robinson, Patrick R. Veres, Meng Li, Andrew W. Rollins, Kristen Zuraski, Sunil Baidar, Shang Liu, Toshihiro Kuwayama, Steven S. Brown, Brian C. McDonald, and Carsten Warneke
EGUsphere, https://doi.org/10.5194/egusphere-2024-1899, https://doi.org/10.5194/egusphere-2024-1899, 2024
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In urban areas, emissions from everyday products like paints, cleaners, and personal care products, along with non-traditional sources such as cooking are important sources that impact air quality. This study used a model to evaluate how these emissions impact ozone in the Los Angeles Basin, and quantifies the impact of gaseous cooking emissions for the first time. Accurate representation of these and other man-made sources in inventories is crucial to inform effective air quality policies.
Zhendong Lu, Jun Wang, Yi Wang, Daven K. Henze, Xi Chen, Tong Sha, and Kang Sun
Atmos. Chem. Phys., 24, 7793–7813, https://doi.org/10.5194/acp-24-7793-2024, https://doi.org/10.5194/acp-24-7793-2024, 2024
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In contrast with past work showing that the reduction of emissions was the dominant factor for the nationwide increase of surface O3 during the lockdown in China, this study finds that the variation in meteorology (temperature and other parameters) plays a more important role. This result is obtained through sensitivity simulations using a chemical transport model constrained by satellite (TROPOMI) data and calibrated with surface observations.
Xiaohong Yao and Leiming Zhang
Atmos. Chem. Phys., 24, 7773–7791, https://doi.org/10.5194/acp-24-7773-2024, https://doi.org/10.5194/acp-24-7773-2024, 2024
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This study investigates long-term trends of criteria air pollutants, including NO2, CO, SO2, O3 and PM2.5, and NO2+O3 measured in 10 Canadian cities during the last 2 to 3 decades. We also investigate associated driving forces in terms of emission reductions, perturbations from varying weather conditions and large-scale wildfires, as well as changes in O3 sources and sinks.
Yao Ge, Sverre Solberg, Mathew R. Heal, Stefan Reimann, Willem van Caspel, Bryan Hellack, Thérèse Salameh, and David Simpson
Atmos. Chem. Phys., 24, 7699–7729, https://doi.org/10.5194/acp-24-7699-2024, https://doi.org/10.5194/acp-24-7699-2024, 2024
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Atmospheric volatile organic compounds (VOCs) constitute many species, acting as precursors to ozone and aerosol. Given the uncertainties in VOC emissions, lack of evaluation studies, and recent changes in emissions, this work adapts the EMEP MSC-W to evaluate emission inventories in Europe. We focus on the varying agreement between modelled and measured VOCs across different species and underscore potential inaccuracies in total and sector-specific emission estimates.
Shuzhuang Feng, Fei Jiang, Tianlu Qian, Nan Wang, Mengwei Jia, Songci Zheng, Jiansong Chen, Fang Ying, and Weimin Ju
Atmos. Chem. Phys., 24, 7481–7498, https://doi.org/10.5194/acp-24-7481-2024, https://doi.org/10.5194/acp-24-7481-2024, 2024
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We developed a multi-air-pollutant inversion system to estimate non-methane volatile organic compound (NMVOC) emissions using TROPOMI formaldehyde retrievals. We found that the inversion significantly improved formaldehyde simulations and reduced NMVOC emission uncertainties. The optimized NMVOC emissions effectively corrected the overestimation of O3 levels, mainly by decreasing the rate of the RO2 + NO reaction and increasing the rate of the NO2 + OH reaction.
Yuqing Qiu, Xin Li, Wenxuan Chai, Yi Liu, Mengdi Song, Xudong Tian, Qiaoli Zou, Wenjun Lou, Wangyao Zhang, Juan Li, and Yuanhang Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-1576, https://doi.org/10.5194/egusphere-2024-1576, 2024
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The chemical reactions of ozone (O3) formation are related to meteorology and local emissions. Here, a random forest approach was used to eliminate the effects of meteorological factors (dispersion or transport) on O3 and its precursors. Variations in the sensitivity of O3 formation and the apportionment of emission sources were revealed after meteorological normalization. Our results suggest that meteorological variations should be considered when diagnosing O3 formation.
Haklim Choi, Alison L. Redington, Hyeri Park, Jooil Kim, Rona L. Thompson, Jens Mühle, Peter K. Salameh, Christina M. Harth, Ray F. Weiss, Alistair J. Manning, and Sunyoung Park
Atmos. Chem. Phys., 24, 7309–7330, https://doi.org/10.5194/acp-24-7309-2024, https://doi.org/10.5194/acp-24-7309-2024, 2024
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We analyzed with an inversion model the atmospheric abundance of hydrofluorocarbons (HFCs), potent greenhouse gases, from 2008 to 2020 at Gosan station in South Korea and revealed a significant increase in emissions, especially from eastern China and Japan. This increase contradicts reported data, underscoring the need for accurate monitoring and reporting. Our findings are crucial for understanding and managing global HFCs emissions, highlighting the importance of efforts to reduce HFCs.
Laura Hyesung Yang, Daniel J. Jacob, Ruijun Dang, Yujin J. Oak, Haipeng Lin, Jhoon Kim, Shixian Zhai, Nadia K. Colombi, Drew C. Pendergrass, Ellie Beaudry, Viral Shah, Xu Feng, Robert M. Yantosca, Heesung Chong, Junsung Park, Hanlim Lee, Won-Jin Lee, Soontae Kim, Eunhye Kim, Katherine R. Travis, James H. Crawford, and Hong Liao
Atmos. Chem. Phys., 24, 7027–7039, https://doi.org/10.5194/acp-24-7027-2024, https://doi.org/10.5194/acp-24-7027-2024, 2024
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The Geostationary Environment Monitoring Spectrometer (GEMS) provides hourly measurements of NO2. We use the chemical transport model to find how emissions, chemistry, and transport drive the changes in NO2 observed by GEMS at different times of the day. In winter, the chemistry plays a minor role, and high daytime emissions dominate the diurnal variation in NO2, balanced by transport. In summer, emissions, chemistry, and transport play an important role in shaping the diurnal variation in NO2.
M. Omar Nawaz, Jeremiah Johnson, Greg Yarwood, Benjamin de Foy, Laura Judd, and Daniel L. Goldberg
Atmos. Chem. Phys., 24, 6719–6741, https://doi.org/10.5194/acp-24-6719-2024, https://doi.org/10.5194/acp-24-6719-2024, 2024
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NO2 is a gas with implications for air pollution. A campaign conducted in Houston provided an opportunity to compare NO2 from different instruments and a model. Aircraft and satellite observations agreed well with measurements on the ground; however, the latter estimated lower values. We find that model-simulated NO2 was lower than observations, especially downtown, suggesting that NO2 sources associated with the urban core of Houston, such as vehicle emissions, may be underestimated.
Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonne, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1450, https://doi.org/10.5194/egusphere-2024-1450, 2024
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Processes influencing dispersion of local anthropogenic emissions in Arctic wintertime are investigated with dispersion model simulations. Modelled power plant plume rise that considers surface and elevated temperature inversions improves results compared to observations. Modelled near-surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching -35 °C are required to reproduce observed NOx.
Tianlang Zhao, Jingqiu Mao, Zolal Ayazpour, Gonzalo González Abad, Caroline R. Nowlan, and Yiqi Zheng
Atmos. Chem. Phys., 24, 6105–6121, https://doi.org/10.5194/acp-24-6105-2024, https://doi.org/10.5194/acp-24-6105-2024, 2024
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HCHO variability is a key tracer in understanding VOC emissions in response to climate change. We investigate the role of methane oxidation and biogenic and wildfire emissions in HCHO interannual variability over northern high latitudes in summer, emphasizing wildfires as a key driver of HCHO interannual variability in Alaska, Siberia and northern Canada using satellite HCHO and SIF retrievals and then GEOS-Chem model. We show SIF is a tool to understand biogenic HCHO variability in this region.
Jianghao Li, Alastair C. Lewis, Jim R. Hopkins, Stephen J. Andrews, Tim Murrells, Neil Passant, Ben Richmond, Siqi Hou, William J. Bloss, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 24, 6219–6231, https://doi.org/10.5194/acp-24-6219-2024, https://doi.org/10.5194/acp-24-6219-2024, 2024
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A summertime ozone event at an urban site in Birmingham is sensitive to volatile organic compounds (VOCs) – particularly those of oxygenated VOCs. The roles of anthropogenic VOC sources in urban ozone chemistry are examined by integrating the 1990–2019 national atmospheric emission inventory into model scenarios. Road transport remains the most powerful means of further reducing ozone in this case study, but the benefits may be offset if solvent emissions of VOCs continue to increase.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, Peter Effertz, Gary Morris, and Brian C. McDonald
Atmos. Chem. Phys., 24, 6197–6218, https://doi.org/10.5194/acp-24-6197-2024, https://doi.org/10.5194/acp-24-6197-2024, 2024
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A great majority of observational trend studies of free tropospheric ozone use sparsely sampled ozonesonde and aircraft measurements as reference data sets. A ubiquitous assumption is that trends are accurate and reliable so long as long-term records are available. We show that sampling bias due to sparse samples can persistently reduce the trend accuracy, and we highlight the importance of maintaining adequate frequency and continuity of observations.
Jin Ma, Linda M. J. Kooijmans, Norbert Glatthor, Stephen A. Montzka, Marc von Hobe, Thomas Röckmann, and Maarten C. Krol
Atmos. Chem. Phys., 24, 6047–6070, https://doi.org/10.5194/acp-24-6047-2024, https://doi.org/10.5194/acp-24-6047-2024, 2024
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The global budget of atmospheric COS can be optimised by inverse modelling using TM5-4DVAR, with the co-constraints of NOAA surface observations and MIPAS satellite data. We found reduced COS biosphere uptake from inversions and improved land and ocean separation using MIPAS satellite data assimilation. Further improvements are expected from better quantification of COS ocean and biosphere fluxes.
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Short summary
The carbon greenhouse gases (CO2, CH4 and CO) were proven to have a large impact on the global carbon cycle and our climate. To understand the variability of the carbon cycle and predict future climate change scenarios, we need to study the processes that drive the changes of these gases in the atmosphere. We study the sources and sinks of CO2, CH4 and CO with a combination of measurements and chemical transport modelling to identify missing, underestimated or overestimated sources in Australia.
The carbon greenhouse gases (CO2, CH4 and CO) were proven to have a large impact on the global...
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