Articles | Volume 19, issue 17
https://doi.org/10.5194/acp-19-11071-2019
https://doi.org/10.5194/acp-19-11071-2019
Research article
 | 
02 Sep 2019
Research article |  | 02 Sep 2019

High time-resolved measurement of stable carbon isotope composition in water-soluble organic aerosols: method optimization and a case study during winter haze in eastern China

Wenqi Zhang, Yan-Lin Zhang, Fang Cao, Yankun Xiang, Yuanyuan Zhang, Mengying Bao, Xiaoyan Liu, and Yu-Chi Lin

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Cited articles

Agarwal, S., Aggarwal, S. G., Okuzawa, K., and Kawamura, K.: Size distributions of dicarboxylic acids, ketoacids, α-dicarbonyls, sugars, WSOC, OC, EC and inorganic ions in atmospheric particles over Northern Japan: implication for long-range transport of Siberian biomass burning and East Asian polluted aerosols, Atmos. Chem. Phys., 10, 5839–5858, https://doi.org/10.5194/acp-10-5839-2010, 2010. 
Aggarwal, S. G. and Kawamura, K.: Molecular distributions and stable carbon isotopic compositions of dicarboxylic acids and related compounds in aerosols from Sapporo, Japan: Implications for photochemical aging during long-range atmospheric transport, J. Geophys. Res.-Atmos., 113, 1–13, https://doi.org/10.1029/2007JD009365, 2008. 
Anderson, R. S., Iannone, R., Thompson, A. E., Rudolph, J., and Huang, L.: Carbon kinetic isotope effects in the gas-phase reactions of aromatic hydrocarbons with the OH radical at 296±4 K, Geophys. Res. Lett., 31, L15108, https://doi.org/10.1029/2004GL020089, 2004. 
Anderson, C., Dibb, J. E., Griffin, R. J., and Bergin, M. H.: Simultaneous measurements of particulate and gas-phase water-soluble organic carbon concentrations at remote and urban-influenced locations, Geophys. Res. Lett., 35, 2–5, https://doi.org/10.1029/2008GL033966, 2008. 
Asa-Awuku, A., Moore, R. H., Nenes, A., Bahreini, R., Holloway, J. S., Brock, C. A., Middlebrook, A. M., Ryerson, T. B., Jimenez, J. L., DeCarlo, P. F., Hecobian, A., Weber R. J., Stickel, R., Tanner D. J., and Huey, L. G.: Airborne Cloud Condensation Nuclei Measurements during the 2006 Texas Air Quality Study, J. Geophys. Res.-Atmos., 116, 1–18. https://doi.org/10.1029/2010JD014874, 2011. 
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Short summary
A novel method to determine the concentration and the isotopes of WSOC in aerosols is established and applied in the analysis of a severe haze in eastern China. The results show that the studied site is affected by the photochemical aging, biomass burning and dust aerosols in different episodes during the sampling period. The analysis of WSOC and its isotopes offers a great potential to better understand the source emission, the atmospheric aging and the secondary production of WSOC.
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