Articles | Volume 16, issue 13
https://doi.org/10.5194/acp-16-8081-2016
https://doi.org/10.5194/acp-16-8081-2016
Research article
 | 
04 Jul 2016
Research article |  | 04 Jul 2016

Heterogeneous reactions of NO2 with CaCO3–(NH4)2SO4 mixtures at different relative humidities

Fang Tan, Shengrui Tong, Bo Jing, Siqi Hou, Qifan Liu, Kun Li, Ying Zhang, and Maofa Ge

Related authors

Hygroscopic behavior of atmospheric aerosols containing nitrate salts and water-soluble organic acids
Bo Jing, Zhen Wang, Fang Tan, Yucong Guo, Shengrui Tong, Weigang Wang, Yunhong Zhang, and Maofa Ge
Atmos. Chem. Phys., 18, 5115–5127, https://doi.org/10.5194/acp-18-5115-2018,https://doi.org/10.5194/acp-18-5115-2018, 2018
Short summary
Hygroscopic behavior and chemical composition evolution of internally mixed aerosols composed of oxalic acid and ammonium sulfate
Xiaowei Wang, Bo Jing, Fang Tan, Jiabi Ma, Yunhong Zhang, and Maofa Ge
Atmos. Chem. Phys., 17, 12797–12812, https://doi.org/10.5194/acp-17-12797-2017,https://doi.org/10.5194/acp-17-12797-2017, 2017
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
The role of surface-active macromolecules in the ice-nucleating ability of lignin, Snomax, and agricultural soil extracts
Kathleen A. Alden, Paul Bieber, Anna J. Miller, Nicole Link, Benjamin J. Murray, and Nadine Borduas-Dedekind
Atmos. Chem. Phys., 25, 6179–6195, https://doi.org/10.5194/acp-25-6179-2025,https://doi.org/10.5194/acp-25-6179-2025, 2025
Short summary
Secondary organic aerosol formation from nitrate radical oxidation of styrene: aerosol yields, chemical composition, and hydrolysis of organic nitrates
Yuchen Wang, Xiang Zhang, Yuanlong Huang, Yutong Liang, and Nga L. Ng
Atmos. Chem. Phys., 25, 5215–5231, https://doi.org/10.5194/acp-25-5215-2025,https://doi.org/10.5194/acp-25-5215-2025, 2025
Short summary
Hydrogen peroxide photoformation in particulate matter and its contribution to S(IV) oxidation during winter in Fairbanks, Alaska
Michael Oluwatoyin Sunday, Laura Marie Dahler Heinlein, Junwei He, Allison Moon, Sukriti Kapur, Ting Fang, Kasey C. Edwards, Fangzhou Guo, Jack Dibb, James H. Flynn III, Becky Alexander, Manabu Shiraiwa, and Cort Anastasio
Atmos. Chem. Phys., 25, 5087–5100, https://doi.org/10.5194/acp-25-5087-2025,https://doi.org/10.5194/acp-25-5087-2025, 2025
Short summary
Insight into the size-resolved markers and eco-health significance of microplastics from typical sources in northwest China
Liyan Liu, Hongmei Xu, Mengyun Yang, Abdullah Akhtar, Jian Sun, and Zhenxing Shen
EGUsphere, https://doi.org/10.5194/egusphere-2025-1821,https://doi.org/10.5194/egusphere-2025-1821, 2025
Short summary
Laboratory studies on the optical, physical, and chemical properties of fresh and aged biomass burning aerosols
Zheng Yang, Qiaoqiao Wang, Qiyuan Wang, Nan Ma, Jie Tian, Yaqing Zhou, Ge Xu, Miao Gao, Xiaoxian Zhou, Yang Zhang, Weikang Ran, Ning Yang, Jiangchuan Tao, Juan Hong, Yunfei Wu, Junji Cao, Hang Su, and Yafang Cheng
EGUsphere, https://doi.org/10.5194/egusphere-2025-1020,https://doi.org/10.5194/egusphere-2025-1020, 2025
Short summary

Cited articles

Al-Abadleh, H. A., Al-Hosney, H. A., and Grassian, V. H.: Oxide and carbonate surfaces as environmental interfaces: the importance of water in surface composition and surface reactivity, J. Mol. Catal. A-Chem., 228, 47–54, https://doi.org/10.1016/j.molcata.2004.09.059, 2004.
Al-Hosney, H. A. and Grassian, V. H.: Carbonic Acid: an important intermediate in the surface chemistry of calcium carbonate, J. Am. Chem. Soc., 126, 8068–8069, https://doi.org/10.1021/ja0490774, 2004.
Al-Hosney, H. A. and Grassian, V. H.: Water, sulfur dioxide and nitric acid adsorption on calcium carbonate: A transmission and ATR-FTIR study, Phys. Chem. Chem. Phys., 7, 1266–1276, https://doi.org/10.1039/b417872f, 2005.
Allen, H. C., Laux, J. M., Vogt, R., Finlayson-Pitts, B. J., and Hemminger, J. C.: Water-induced reorganization of ultrathin nitrate films on NaCl: Implications for the tropospheric chemistry of sea salt particles, J. Phys. Chem., 100, 6371–6375, https://doi.org/10.1021/jp953675a, 1996.
Börensen, C., Kirchner, U., Scheer, V., Vogt, R., and Zellner, R.: Mechanism and kinetics of the reactions of NO2 or HNO3 with alumina as a mineral dust model compound, J. Phys. Chem. A, 104, 5036–5045, https://doi.org/10.1021/jp994170d, 2000.
Download
Short summary
The heterogeneous reactions of NO2 with CaCO3–(NH4)2SO4 mixtures were markedly dependent on RH. Calcium nitrate was formed under both dry and wet conditions; bassanite, gypsum, and koktaite were produced depending on RH. The heterogeneous uptake of NO2 on the CaCO3–(NH4)2SO4 mixtures was similar to that on pure CaCO3 particles under the dry condition, whereas the mixtures exhibited a promotive effect on the heterogeneous uptake of NO2 and the formation of nitrate, especially at medium RHs.
Share
Altmetrics
Final-revised paper
Preprint