Articles | Volume 16, issue 13
https://doi.org/10.5194/acp-16-8081-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-8081-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
04 Jul 2016
Research article |
| 04 Jul 2016
Heterogeneous reactions of NO2 with CaCO3–(NH4)2SO4 mixtures at different relative humidities
Fang Tan
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Shengrui Tong
CORRESPONDING AUTHOR
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Siqi Hou
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Qifan Liu
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Kun Li
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Ying Zhang
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
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Latest update: 18 Apr 2024
Short summary
The heterogeneous reactions of NO2 with CaCO3–(NH4)2SO4 mixtures were markedly dependent on RH. Calcium nitrate was formed under both dry and wet conditions; bassanite, gypsum, and koktaite were produced depending on RH. The heterogeneous uptake of NO2 on the CaCO3–(NH4)2SO4 mixtures was similar to that on pure CaCO3 particles under the dry condition, whereas the mixtures exhibited a promotive effect on the heterogeneous uptake of NO2 and the formation of nitrate, especially at medium RHs.
The heterogeneous reactions of NO2 with CaCO3–(NH4)2SO4 mixtures were markedly dependent on RH....
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