Articles | Volume 16, issue 13
https://doi.org/10.5194/acp-16-8081-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-8081-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Heterogeneous reactions of NO2 with CaCO3–(NH4)2SO4 mixtures at different relative humidities
Fang Tan
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Shengrui Tong
CORRESPONDING AUTHOR
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Siqi Hou
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Qifan Liu
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Kun Li
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Ying Zhang
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory for Structural Chemistry of Unstable and Stable
Species, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Viewed
Total article views: 4,544 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 29 Mar 2016)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
2,444 | 2,022 | 78 | 4,544 | 468 | 72 | 91 |
- HTML: 2,444
- PDF: 2,022
- XML: 78
- Total: 4,544
- Supplement: 468
- BibTeX: 72
- EndNote: 91
Total article views: 3,820 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 04 Jul 2016)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
2,067 | 1,681 | 72 | 3,820 | 283 | 68 | 87 |
- HTML: 2,067
- PDF: 1,681
- XML: 72
- Total: 3,820
- Supplement: 283
- BibTeX: 68
- EndNote: 87
Total article views: 724 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 29 Mar 2016)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
377 | 341 | 6 | 724 | 185 | 4 | 4 |
- HTML: 377
- PDF: 341
- XML: 6
- Total: 724
- Supplement: 185
- BibTeX: 4
- EndNote: 4
Cited
51 citations as recorded by crossref.
- Understanding the Impact of Relative Humidity and Coexisting Soluble Iron on the OH-Initiated Heterogeneous Oxidation of Organophosphate Flame Retardants Q. Liu et al. 10.1021/acs.est.9b01758
- A diurnal story of Δ17O($$\rm{NO}_{3}^{-}$$) in urban Nanjing and its implication for nitrate aerosol formation Y. Zhang et al. 10.1038/s41612-022-00273-3
- Seasonal size distribution and mixing state of black carbon aerosols in a polluted urban environment of the Yangtze River Delta region, China Y. Yang et al. 10.1016/j.scitotenv.2018.11.087
- Incorporation and improvement of a heterogeneous chemistry mechanism in the atmospheric chemistry model GRAPES_Meso5.1/CUACE and its impacts on secondary inorganic aerosol and PM2.5 simulations in Middle-Eastern China Z. Liu et al. 10.1016/j.scitotenv.2022.157530
- Heterogeneous uptake of NO2 by sodium acetate droplets and secondary nitrite aerosol formation W. Pei et al. 10.1016/j.jes.2022.05.048
- Mass Size Distributions of Water-soluble Aerosol Particles during High Fine Particulate Matter Episode over Gwangju in November 2018 S. Son & S. Park 10.5572/KOSAE.2019.35.4.423
- Heterogeneous reaction of NO2 with hematite, goethite and magnetite: Implications for nitrate formation and iron solubility enhancement R. Li et al. 10.1016/j.chemosphere.2019.125273
- Investigation of electrochemical and photoluminescence properties of Dy3+ doped SrO/BaO/Al2O3 nanocomposite for supercapacitor and display applications L. Manjunath et al. 10.1016/j.ceramint.2024.05.052
- Size-resolved hygroscopic behaviour and mixing state of submicron aerosols in a megacity of the Sichuan Basin during pollution and fireworks episodes L. Yuan et al. 10.1016/j.atmosenv.2020.117393
- Real-time observational evidence of changing Asian dust morphology with the mixing of heavy anthropogenic pollution X. Pan et al. 10.1038/s41598-017-00444-w
- Molecular Insights into NO-Promoted Sulfate Formation on Model TiO2 Nanoparticles with Different Exposed Facets W. Yang et al. 10.1021/acs.est.8b02688
- Photocatalytic Oxidation of SO2 by TiO2: Aerosol Formation and the Key Role of Gaseous Reactive Oxygen Species Y. Chen et al. 10.1021/acs.est.1c01608
- Role of NH3 in the Heterogeneous Formation of Secondary Inorganic Aerosols on Mineral Oxides W. Yang et al. 10.1021/acs.jpca.8b05130
- Effects of NO2 and SO2 on the heterogeneous reaction of acetic acid on α-Al2O3 in the presence and absence of simulated irradiation N. Yang et al. 10.1039/C9EM00550A
- Moisture-induced secondary inorganic aerosol formation dominated the light absorption enhancement of refractory black carbon at an urban site in northwest China Z. Chen et al. 10.1016/j.atmosenv.2023.120113
- Effects of heterogeneous reaction with NO2 on ice nucleation activities of feldspar and Arizona Test Dust L. Chen et al. 10.1016/j.jes.2022.04.034
- Investigating the effect of volatility on the hygroscopicities of acetate nanoparticle aerosols by surface plasmon resonance microscopy B. Yang et al. 10.1016/j.jes.2023.03.013
- A metallurgical approach for separation and recovery of Cu, Cr, and Ni from electroplating sludge Y. Xiao et al. 10.1016/j.scitotenv.2024.171130
- A Study of Chemical Processes of Nitrate in Atmospheric Aerosol and Snow Based on Stable Isotopes M. Chen et al. 10.3390/atmos15010059
- Heterogeneous Reaction of HCOOH on NaCl Particles at Different Relative Humidities K. Xia et al. 10.1021/acs.jpca.8b02790
- Pollution Characteristics of PM2.5 Observed during Winter and Summer in Baengryeongdo and Seoul G. Yu et al. 10.5572/KOSAE.2018.34.1.038
- Real-time application and modelling of the NOx-sorption reaction on a particulate calcium carbonate surface-flow filter exposed to combustion exhaust N. Barać et al. 10.1007/s11356-024-32743-x
- Heterogeneous Reaction of CaCO3 With NO2 at Different Relative Humidities: Kinetics, Mechanisms, and Impacts on Aerosol Hygroscopicity X. Jia et al. 10.1029/2021JD034826
- Modification of CaCO3 and CaCO3 pin-coated cellulose paper under supercritical carbon dioxide–ethanol mixture for enhanced NO2 capture N. Barac et al. 10.1007/s11356-021-16503-9
- Investigating the hygroscopicities of calcium and magnesium salt particles aged with SO2 using surface plasmon resonance microscopy B. Yang et al. 10.1016/j.scitotenv.2023.161588
- A new parameterization of uptake coefficients for heterogeneous reactions on multi-component atmospheric aerosols Y. Zhou et al. 10.1016/j.scitotenv.2021.146372
- Relative importance of gas uptake on aerosol and ground surfaces characterized by equivalent uptake coefficients M. Li et al. 10.5194/acp-19-10981-2019
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- Heterogeneous reaction of SO2 on CaCO3 particles: Different impacts of NO2 and acetic acid on the sulfite and sulfate formation R. Wang et al. 10.1016/j.jes.2021.08.017
- The Role of Clouds in the Tropospheric NOx Cycle: A New Modeling Approach for Cloud Chemistry and Its Global Implications C. Holmes et al. 10.1029/2019GL081990
- Multi-year observations of particulate matter and gases over Mumbai: Spatio-temporal variation, oxidation ratios, and secondary aerosols N. Korhale et al. 10.1016/j.apr.2023.101917
- The formation and growth of calcium sulfate crystals through oxidation of SO2by O3on size-resolved calcium carbonate Y. Zhang et al. 10.1039/C8RA02050G
- Measurement of heterogeneous uptake of NO2 on inorganic particles, sea water and urban grime C. Yu et al. 10.1016/j.jes.2021.01.018
- A comprehensive study of hygroscopic properties of calcium- and magnesium-containing salts: implication for hygroscopicity of mineral dust and sea salt aerosols L. Guo et al. 10.5194/acp-19-2115-2019
- Photochemical reaction of NO2 on photoactive mineral dust: Mechanism and irradiation intensity dependence T. Wang et al. 10.1016/j.jphotochem.2021.113319
- The mixing state of mineral dusts with typical anthropogenic pollutants: A mechanism study Y. Ji et al. 10.1016/j.atmosenv.2019.04.035
- Asian dust observed during KORUS-AQ facilitates the uptake and incorporation of soluble pollutants during transport to South Korea E. Heim et al. 10.1016/j.atmosenv.2020.117305
- Roles of regional transport and heterogeneous reactions in the PM2.5 increase during winter haze episodes in Beijing Q. Ma et al. 10.1016/j.scitotenv.2017.04.193
- A review of experimental techniques for aerosol hygroscopicity studies M. Tang et al. 10.5194/acp-19-12631-2019
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- The effects of coexisting Na2SO4 on heterogeneous uptake of NO2 on CaCO3 particles at various RHs F. Tan et al. 10.1016/j.scitotenv.2017.02.072
- Hygroscopic behavior of atmospheric aerosols containing nitrate salts and water-soluble organic acids B. Jing et al. 10.5194/acp-18-5115-2018
- The combined effects of heterogeneous chemistry and aerosol-radiation interaction on severe haze simulation by atmospheric chemistry model in Middle-Eastern China Z. Liu et al. 10.1016/j.atmosenv.2023.119729
- Characterizing nighttime vertical profiles of atmospheric particulate matter and ozone in a megacity of south China using unmanned aerial vehicle measurements Z. Wang et al. 10.1016/j.envres.2023.116854
- Important Role of NO3 Radical to Nitrate Formation Aloft in Urban Beijing: Insights from Triple Oxygen Isotopes Measured at the Tower M. Fan et al. 10.1021/acs.est.1c02843
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al. 10.1029/2021JD034688
- Effects of relative humidity on heterogeneous reaction of SO2 with CaCO3 particles and formation of CaSO4·2H2O crystal as secondary aerosol Y. Yue et al. 10.1016/j.atmosenv.2021.118776
- Effect of changing NO<sub><i>x</i></sub> lifetime on the seasonality and long-term trends of satellite-observed tropospheric NO<sub>2</sub> columns over China V. Shah et al. 10.5194/acp-20-1483-2020
- The influence of relative humidity on the heterogeneous oxidation of sulfur dioxide by ozone on calcium carbonate particles Y. Zhang et al. 10.1016/j.scitotenv.2018.03.288
- Hygroscopic behavior and aerosol chemistry of atmospheric particles containing organic acids and inorganic salts F. Tan et al. 10.1038/s41612-024-00752-9
- Review of Chinese atmospheric science research over the past 70 years: Atmospheric physics and atmospheric environment T. Wang et al. 10.1007/s11430-019-9536-1
51 citations as recorded by crossref.
- Understanding the Impact of Relative Humidity and Coexisting Soluble Iron on the OH-Initiated Heterogeneous Oxidation of Organophosphate Flame Retardants Q. Liu et al. 10.1021/acs.est.9b01758
- A diurnal story of Δ17O($$\rm{NO}_{3}^{-}$$) in urban Nanjing and its implication for nitrate aerosol formation Y. Zhang et al. 10.1038/s41612-022-00273-3
- Seasonal size distribution and mixing state of black carbon aerosols in a polluted urban environment of the Yangtze River Delta region, China Y. Yang et al. 10.1016/j.scitotenv.2018.11.087
- Incorporation and improvement of a heterogeneous chemistry mechanism in the atmospheric chemistry model GRAPES_Meso5.1/CUACE and its impacts on secondary inorganic aerosol and PM2.5 simulations in Middle-Eastern China Z. Liu et al. 10.1016/j.scitotenv.2022.157530
- Heterogeneous uptake of NO2 by sodium acetate droplets and secondary nitrite aerosol formation W. Pei et al. 10.1016/j.jes.2022.05.048
- Mass Size Distributions of Water-soluble Aerosol Particles during High Fine Particulate Matter Episode over Gwangju in November 2018 S. Son & S. Park 10.5572/KOSAE.2019.35.4.423
- Heterogeneous reaction of NO2 with hematite, goethite and magnetite: Implications for nitrate formation and iron solubility enhancement R. Li et al. 10.1016/j.chemosphere.2019.125273
- Investigation of electrochemical and photoluminescence properties of Dy3+ doped SrO/BaO/Al2O3 nanocomposite for supercapacitor and display applications L. Manjunath et al. 10.1016/j.ceramint.2024.05.052
- Size-resolved hygroscopic behaviour and mixing state of submicron aerosols in a megacity of the Sichuan Basin during pollution and fireworks episodes L. Yuan et al. 10.1016/j.atmosenv.2020.117393
- Real-time observational evidence of changing Asian dust morphology with the mixing of heavy anthropogenic pollution X. Pan et al. 10.1038/s41598-017-00444-w
- Molecular Insights into NO-Promoted Sulfate Formation on Model TiO2 Nanoparticles with Different Exposed Facets W. Yang et al. 10.1021/acs.est.8b02688
- Photocatalytic Oxidation of SO2 by TiO2: Aerosol Formation and the Key Role of Gaseous Reactive Oxygen Species Y. Chen et al. 10.1021/acs.est.1c01608
- Role of NH3 in the Heterogeneous Formation of Secondary Inorganic Aerosols on Mineral Oxides W. Yang et al. 10.1021/acs.jpca.8b05130
- Effects of NO2 and SO2 on the heterogeneous reaction of acetic acid on α-Al2O3 in the presence and absence of simulated irradiation N. Yang et al. 10.1039/C9EM00550A
- Moisture-induced secondary inorganic aerosol formation dominated the light absorption enhancement of refractory black carbon at an urban site in northwest China Z. Chen et al. 10.1016/j.atmosenv.2023.120113
- Effects of heterogeneous reaction with NO2 on ice nucleation activities of feldspar and Arizona Test Dust L. Chen et al. 10.1016/j.jes.2022.04.034
- Investigating the effect of volatility on the hygroscopicities of acetate nanoparticle aerosols by surface plasmon resonance microscopy B. Yang et al. 10.1016/j.jes.2023.03.013
- A metallurgical approach for separation and recovery of Cu, Cr, and Ni from electroplating sludge Y. Xiao et al. 10.1016/j.scitotenv.2024.171130
- A Study of Chemical Processes of Nitrate in Atmospheric Aerosol and Snow Based on Stable Isotopes M. Chen et al. 10.3390/atmos15010059
- Heterogeneous Reaction of HCOOH on NaCl Particles at Different Relative Humidities K. Xia et al. 10.1021/acs.jpca.8b02790
- Pollution Characteristics of PM2.5 Observed during Winter and Summer in Baengryeongdo and Seoul G. Yu et al. 10.5572/KOSAE.2018.34.1.038
- Real-time application and modelling of the NOx-sorption reaction on a particulate calcium carbonate surface-flow filter exposed to combustion exhaust N. Barać et al. 10.1007/s11356-024-32743-x
- Heterogeneous Reaction of CaCO3 With NO2 at Different Relative Humidities: Kinetics, Mechanisms, and Impacts on Aerosol Hygroscopicity X. Jia et al. 10.1029/2021JD034826
- Modification of CaCO3 and CaCO3 pin-coated cellulose paper under supercritical carbon dioxide–ethanol mixture for enhanced NO2 capture N. Barac et al. 10.1007/s11356-021-16503-9
- Investigating the hygroscopicities of calcium and magnesium salt particles aged with SO2 using surface plasmon resonance microscopy B. Yang et al. 10.1016/j.scitotenv.2023.161588
- A new parameterization of uptake coefficients for heterogeneous reactions on multi-component atmospheric aerosols Y. Zhou et al. 10.1016/j.scitotenv.2021.146372
- Relative importance of gas uptake on aerosol and ground surfaces characterized by equivalent uptake coefficients M. Li et al. 10.5194/acp-19-10981-2019
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- Heterogeneous reaction of SO2 on CaCO3 particles: Different impacts of NO2 and acetic acid on the sulfite and sulfate formation R. Wang et al. 10.1016/j.jes.2021.08.017
- The Role of Clouds in the Tropospheric NOx Cycle: A New Modeling Approach for Cloud Chemistry and Its Global Implications C. Holmes et al. 10.1029/2019GL081990
- Multi-year observations of particulate matter and gases over Mumbai: Spatio-temporal variation, oxidation ratios, and secondary aerosols N. Korhale et al. 10.1016/j.apr.2023.101917
- The formation and growth of calcium sulfate crystals through oxidation of SO2by O3on size-resolved calcium carbonate Y. Zhang et al. 10.1039/C8RA02050G
- Measurement of heterogeneous uptake of NO2 on inorganic particles, sea water and urban grime C. Yu et al. 10.1016/j.jes.2021.01.018
- A comprehensive study of hygroscopic properties of calcium- and magnesium-containing salts: implication for hygroscopicity of mineral dust and sea salt aerosols L. Guo et al. 10.5194/acp-19-2115-2019
- Photochemical reaction of NO2 on photoactive mineral dust: Mechanism and irradiation intensity dependence T. Wang et al. 10.1016/j.jphotochem.2021.113319
- The mixing state of mineral dusts with typical anthropogenic pollutants: A mechanism study Y. Ji et al. 10.1016/j.atmosenv.2019.04.035
- Asian dust observed during KORUS-AQ facilitates the uptake and incorporation of soluble pollutants during transport to South Korea E. Heim et al. 10.1016/j.atmosenv.2020.117305
- Roles of regional transport and heterogeneous reactions in the PM2.5 increase during winter haze episodes in Beijing Q. Ma et al. 10.1016/j.scitotenv.2017.04.193
- A review of experimental techniques for aerosol hygroscopicity studies M. Tang et al. 10.5194/acp-19-12631-2019
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- The effects of coexisting Na2SO4 on heterogeneous uptake of NO2 on CaCO3 particles at various RHs F. Tan et al. 10.1016/j.scitotenv.2017.02.072
- Hygroscopic behavior of atmospheric aerosols containing nitrate salts and water-soluble organic acids B. Jing et al. 10.5194/acp-18-5115-2018
- The combined effects of heterogeneous chemistry and aerosol-radiation interaction on severe haze simulation by atmospheric chemistry model in Middle-Eastern China Z. Liu et al. 10.1016/j.atmosenv.2023.119729
- Characterizing nighttime vertical profiles of atmospheric particulate matter and ozone in a megacity of south China using unmanned aerial vehicle measurements Z. Wang et al. 10.1016/j.envres.2023.116854
- Important Role of NO3 Radical to Nitrate Formation Aloft in Urban Beijing: Insights from Triple Oxygen Isotopes Measured at the Tower M. Fan et al. 10.1021/acs.est.1c02843
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al. 10.1029/2021JD034688
- Effects of relative humidity on heterogeneous reaction of SO2 with CaCO3 particles and formation of CaSO4·2H2O crystal as secondary aerosol Y. Yue et al. 10.1016/j.atmosenv.2021.118776
- Effect of changing NO<sub><i>x</i></sub> lifetime on the seasonality and long-term trends of satellite-observed tropospheric NO<sub>2</sub> columns over China V. Shah et al. 10.5194/acp-20-1483-2020
- The influence of relative humidity on the heterogeneous oxidation of sulfur dioxide by ozone on calcium carbonate particles Y. Zhang et al. 10.1016/j.scitotenv.2018.03.288
- Hygroscopic behavior and aerosol chemistry of atmospheric particles containing organic acids and inorganic salts F. Tan et al. 10.1038/s41612-024-00752-9
- Review of Chinese atmospheric science research over the past 70 years: Atmospheric physics and atmospheric environment T. Wang et al. 10.1007/s11430-019-9536-1
Latest update: 14 Dec 2024
Short summary
The heterogeneous reactions of NO2 with CaCO3–(NH4)2SO4 mixtures were markedly dependent on RH. Calcium nitrate was formed under both dry and wet conditions; bassanite, gypsum, and koktaite were produced depending on RH. The heterogeneous uptake of NO2 on the CaCO3–(NH4)2SO4 mixtures was similar to that on pure CaCO3 particles under the dry condition, whereas the mixtures exhibited a promotive effect on the heterogeneous uptake of NO2 and the formation of nitrate, especially at medium RHs.
The heterogeneous reactions of NO2 with CaCO3–(NH4)2SO4 mixtures were markedly dependent on RH....
Altmetrics
Final-revised paper
Preprint