Articles | Volume 15, issue 14
https://doi.org/10.5194/acp-15-7859-2015
https://doi.org/10.5194/acp-15-7859-2015
Research article
 | 
17 Jul 2015
Research article |  | 17 Jul 2015

Atmospheric nitrogen oxides (NO and NO2) at Dome C, East Antarctica, during the OPALE campaign

M. M. Frey, H. K. Roscoe, A. Kukui, J. Savarino, J. L. France, M. D. King, M. Legrand, and S. Preunkert

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Cited articles

Anderson, P. S. and Neff, W. D.: Boundary layer physics over snow and ice, Atmos. Chem. Phys., 8, 3563–3582, https://doi.org/10.5194/acp-8-3563-2008, 2008.
Argentini, S., Petenko, I., Viola, A., Mastrantonio, G., Pietroni, I., Casasanta, G., Aristidi, E., and Genthon, C.: The surface layer observed by a high-resolution sodar at DOME C, Antarctica, Annals of Geophysics, 56, 1–10, https://doi.org/10.4401/ag-6347, 2014.
Bauguitte, S. J.-B., Bloss, W. J., Evans, M. J., Salmon, R. A., Anderson, P. S., Jones, A. E., Lee, J. D., Saiz-Lopez, A., Roscoe, H. K., Wolff, E. W., and Plane, J. M. C.: Summertime NOx measurements during the CHABLIS campaign: can source and sink estimates unravel observed diurnal cycles?, Atmos. Chem. Phys., 12, 989–1002, https://doi.org/10.5194/acp-12-989-2012, 2012
Berhanu, T. A., Savarino, J., Erbland, J., Vicars, W. C., Preunkert, S., Martins, J. F., and Johnson, M. S.: Isotopic effects of nitrate photochemistry in snow: a field study at Dome C, Antarctica, Atmos. Chem. Phys. Discuss., 14, 33045–33088, https://doi.org/10.5194/acpd-14-33045-2014, 2014.
Chu, L. and Anastasio, C.: Quantum yields of hydroxyl radical and nitrogen dioxide from the photolysis of nitrate on ice, J. Phys. Chem. A, 107, 9594–9602, 2003.
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Short summary
Surprisingly large concentrations and flux of atmospheric nitrogen oxides were measured at Dome C, East Antarctica. It was found that the surface snow holds a significant reservoir of photochemically produced NOx and is a sink of gas-phase ozone. Main drivers of NOx snow emissions were large snow nitrate concentrations, with contributions of increased UV from decreases in stratospheric ozone. Observed halogen and hydroxyl radical concentrations were too low to explain large NO2:NO ratios.
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