Articles | Volume 15, issue 14
https://doi.org/10.5194/acp-15-7859-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-15-7859-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
17 Jul 2015
Research article |
| 17 Jul 2015
Atmospheric nitrogen oxides (NO and NO2) at Dome C, East Antarctica, during the OPALE campaign
British Antarctic Survey, Natural Environment Research Council, Cambridge, UK
H. K. Roscoe
British Antarctic Survey, Natural Environment Research Council, Cambridge, UK
A. Kukui
Laboratoire Atmosphère, Milieux et Observations Spatiales (LATMOS), UMR8190, CNRS-Université de Versailles Saint Quentin, Université Pierre et Marie Curie, Paris, France
Laboratoire de Physique et Chimie de l'Environnement et de l'Éspace (LPC2E), UMR6115 CNRS-Université d'Orléans, 45071 Orléans CEDEX 2, France
J. Savarino
Université Grenoble Alpes, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
J. L. France
School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK
M. D. King
Department of Earth Sciences, Royal Holloway University of London, Egham, Surrey, TW20 0EX, UK
M. Legrand
Université Grenoble Alpes, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
S. Preunkert
Université Grenoble Alpes, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
Viewed
Total article views: 4,682 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 11 Dec 2014)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 2,528 | 2,030 | 124 | 4,682 | 135 | 139 |
- HTML: 2,528
- PDF: 2,030
- XML: 124
- Total: 4,682
- BibTeX: 135
- EndNote: 139
Total article views: 3,907 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 17 Jul 2015)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 2,057 | 1,752 | 98 | 3,907 | 89 | 110 |
- HTML: 2,057
- PDF: 1,752
- XML: 98
- Total: 3,907
- BibTeX: 89
- EndNote: 110
Total article views: 775 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 11 Dec 2014)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 471 | 278 | 26 | 775 | 46 | 29 |
- HTML: 471
- PDF: 278
- XML: 26
- Total: 775
- BibTeX: 46
- EndNote: 29
Cited
41 citations as recorded by crossref.
- Inter-annual variability of surface ozone at coastal (Dumont d'Urville, 2004–2014) and inland (Concordia, 2007–2014) sites in East Antarctica M. Legrand et al. 10.5194/acp-16-8053-2016
- Atmospheric chemistry of perfluoronitriles: Environmental impact and experimental evidence related to N2O and NO formation Q. Guo et al. 10.1016/j.atmosenv.2018.10.066
- Fostering multidisciplinary research on interactions between chemistry, biology, and physics within the coupled cryosphere-atmosphere system J. Thomas et al. 10.1525/elementa.396
- Year-long ground-based observations of bromine oxide over Bharati Station, Antarctica S. Wagh et al. 10.1016/j.polar.2023.100977
- Quantum Yield of Nitrite from the Photolysis of Aqueous Nitrate above 300 nm K. Benedict et al. 10.1021/acs.est.6b06370
- Chemical cycling and deposition of atmospheric mercury in polar regions: review of recent measurements and comparison with models H. Angot et al. 10.5194/acp-16-10735-2016
- Interferences in photolytic NO<sub>2</sub> measurements: explanation for an apparent missing oxidant? C. Reed et al. 10.5194/acp-16-4707-2016
- New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale H. Angot et al. 10.5194/acp-16-8249-2016
- The meteorology and chemistry of high nitrogen oxide concentrations in the stable boundary layer at the South Pole W. Neff et al. 10.5194/acp-18-3755-2018
- Analysis of multi-year near-surface ozone observations at the WMO/GAW “Concordia” station (75°06′S, 123°20′E, 3280 m a.s.l. – Antarctica) P. Cristofanelli et al. 10.1016/j.atmosenv.2018.01.007
- Deposition, recycling, and archival of nitrate stable isotopes between the air–snow interface: comparison between Dronning Maud Land and Dome C, Antarctica V. Winton et al. 10.5194/acp-20-5861-2020
- Oxygen isotope mass balance of atmospheric nitrate at Dome C, East Antarctica, during the OPALE campaign J. Savarino et al. 10.5194/acp-16-2659-2016
- Spatial variations of particulate-bound mercury in the atmosphere along a transect from the mid-Northern Hemisphere to the high southern latitudes G. Wu et al. 10.1016/j.atmosenv.2022.119470
- Momentum- and Heat-Flux Parametrization at Dome C, Antarctica: A Sensitivity Study E. Vignon et al. 10.1007/s10546-016-0192-3
- Impact of exhaust emissions on chemical snowpack composition at Concordia Station, Antarctica D. Helmig et al. 10.5194/tc-14-199-2020
- Dynamics of ozone and nitrogen oxides at Summit, Greenland: I. Multi-year observations in the snowpack B. Van Dam et al. 10.1016/j.atmosenv.2015.09.060
- Atmospheric sea-salt and halogen cycles in the Antarctic K. Hara et al. 10.1039/D0EM00092B
- Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records J. Erbland et al. 10.5194/acp-15-12079-2015
- Modification of a conventional photolytic converter for improving aircraft measurements of NO<sub>2</sub> via chemiluminescence C. Nussbaumer et al. 10.5194/amt-14-6759-2021
- The Role of Snow in Controlling Halogen Chemistry and Boundary Layer Oxidation During Arctic Spring: A 1D Modeling Case Study S. Ahmed et al. 10.1029/2021JD036140
- Modeling the Complete Nitrogen and Oxygen Isotopic Imprint of Nitrate Photolysis in Snow G. Shi et al. 10.1029/2023GL103778
- Distinguishing summertime atmospheric production of nitrate across the East Antarctic Ice Sheet G. Shi et al. 10.1016/j.gca.2018.03.025
- Impacts of post-depositional processing on nitrate isotopes in the snow and the overlying atmosphere at Summit, Greenland Z. Jiang et al. 10.5194/tc-16-2709-2022
- The Antarctic Astronomical Observations Intelligent Support Equipment “Dome A” Site-Testing Observatory: Electric Power Generation and Control Systems S. Fang et al. 10.3390/en13174308
- Seasonal Variation of Mercury and Its Isotopes in Atmospheric Particles at the Coastal Zhongshan Station, Eastern Antarctica C. Li et al. 10.1021/acs.est.0c04462
- Summer variability of the atmospheric NO2 : NO ratio at Dome C on the East Antarctic Plateau A. Barbero et al. 10.5194/acp-22-12025-2022
- Understanding mercury oxidation and air–snow exchange on the East Antarctic Plateau: a modeling study S. Song et al. 10.5194/acp-18-15825-2018
- Quantum Yields of Nitrite (NO2–) from the Photolysis of Nitrate (NO3–) in Ice at 313 nm K. Benedict & C. Anastasio 10.1021/acs.jpca.7b08839
- A compact incoherent broadband cavity-enhanced absorption spectrometer for trace detection of nitrogen oxides, iodine oxide and glyoxal at levels below parts per billion for field applications A. Barbero et al. 10.5194/amt-13-4317-2020
- New Estimation of the NOx Snow‐Source on the Antarctic Plateau A. Barbero et al. 10.1029/2021JD035062
- Reactive bromine in the low troposphere of Antarctica: estimations at two research sites C. Prados-Roman et al. 10.5194/acp-18-8549-2018
- Year‐round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites M. Legrand et al. 10.1002/2015JD024066
- Year-round record of near-surface ozone and O3 enhancement events (OEEs) at Dome A, East Antarctica M. Ding et al. 10.5194/essd-12-3529-2020
- Seasonal variations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica S. Ishino et al. 10.5194/acp-17-3713-2017
- Multi-year variation of near-surface ozone at Zhongshan Station, Antarctica B. Tian et al. 10.1088/1748-9326/ac583c
- Influences of downward transport and photochemistry on surface ozone over East Antarctica during austral summer: in situ observations and model simulations I. Girach et al. 10.5194/acp-24-1979-2024
- Homogeneous and heterogeneous photolysis of nitrate in the atmosphere: state of the science, current research needs, and future prospects Y. Cao et al. 10.1007/s11783-023-1648-6
- Measurements of OH and RO<sub>2</sub> radicals at Dome C, East Antarctica A. Kukui et al. 10.5194/acp-14-12373-2014
- Formaldehyde (HCHO) in air, snow, and interstitial air at Concordia (East Antarctic Plateau) in summer S. Preunkert et al. 10.5194/acp-15-6689-2015
- Large mixing ratios of atmospheric nitrous acid (HONO) at Concordia (East Antarctic Plateau) in summer: a strong source from surface snow? M. Legrand et al. 10.5194/acp-14-9963-2014
- Characterization of the boundary layer at Dome C (East Antarctica) during the OPALE summer campaign H. Gallée et al. 10.5194/acp-15-6225-2015
37 citations as recorded by crossref.
- Inter-annual variability of surface ozone at coastal (Dumont d'Urville, 2004–2014) and inland (Concordia, 2007–2014) sites in East Antarctica M. Legrand et al. 10.5194/acp-16-8053-2016
- Atmospheric chemistry of perfluoronitriles: Environmental impact and experimental evidence related to N2O and NO formation Q. Guo et al. 10.1016/j.atmosenv.2018.10.066
- Fostering multidisciplinary research on interactions between chemistry, biology, and physics within the coupled cryosphere-atmosphere system J. Thomas et al. 10.1525/elementa.396
- Year-long ground-based observations of bromine oxide over Bharati Station, Antarctica S. Wagh et al. 10.1016/j.polar.2023.100977
- Quantum Yield of Nitrite from the Photolysis of Aqueous Nitrate above 300 nm K. Benedict et al. 10.1021/acs.est.6b06370
- Chemical cycling and deposition of atmospheric mercury in polar regions: review of recent measurements and comparison with models H. Angot et al. 10.5194/acp-16-10735-2016
- Interferences in photolytic NO<sub>2</sub> measurements: explanation for an apparent missing oxidant? C. Reed et al. 10.5194/acp-16-4707-2016
- New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale H. Angot et al. 10.5194/acp-16-8249-2016
- The meteorology and chemistry of high nitrogen oxide concentrations in the stable boundary layer at the South Pole W. Neff et al. 10.5194/acp-18-3755-2018
- Analysis of multi-year near-surface ozone observations at the WMO/GAW “Concordia” station (75°06′S, 123°20′E, 3280 m a.s.l. – Antarctica) P. Cristofanelli et al. 10.1016/j.atmosenv.2018.01.007
- Deposition, recycling, and archival of nitrate stable isotopes between the air–snow interface: comparison between Dronning Maud Land and Dome C, Antarctica V. Winton et al. 10.5194/acp-20-5861-2020
- Oxygen isotope mass balance of atmospheric nitrate at Dome C, East Antarctica, during the OPALE campaign J. Savarino et al. 10.5194/acp-16-2659-2016
- Spatial variations of particulate-bound mercury in the atmosphere along a transect from the mid-Northern Hemisphere to the high southern latitudes G. Wu et al. 10.1016/j.atmosenv.2022.119470
- Momentum- and Heat-Flux Parametrization at Dome C, Antarctica: A Sensitivity Study E. Vignon et al. 10.1007/s10546-016-0192-3
- Impact of exhaust emissions on chemical snowpack composition at Concordia Station, Antarctica D. Helmig et al. 10.5194/tc-14-199-2020
- Dynamics of ozone and nitrogen oxides at Summit, Greenland: I. Multi-year observations in the snowpack B. Van Dam et al. 10.1016/j.atmosenv.2015.09.060
- Atmospheric sea-salt and halogen cycles in the Antarctic K. Hara et al. 10.1039/D0EM00092B
- Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records J. Erbland et al. 10.5194/acp-15-12079-2015
- Modification of a conventional photolytic converter for improving aircraft measurements of NO<sub>2</sub> via chemiluminescence C. Nussbaumer et al. 10.5194/amt-14-6759-2021
- The Role of Snow in Controlling Halogen Chemistry and Boundary Layer Oxidation During Arctic Spring: A 1D Modeling Case Study S. Ahmed et al. 10.1029/2021JD036140
- Modeling the Complete Nitrogen and Oxygen Isotopic Imprint of Nitrate Photolysis in Snow G. Shi et al. 10.1029/2023GL103778
- Distinguishing summertime atmospheric production of nitrate across the East Antarctic Ice Sheet G. Shi et al. 10.1016/j.gca.2018.03.025
- Impacts of post-depositional processing on nitrate isotopes in the snow and the overlying atmosphere at Summit, Greenland Z. Jiang et al. 10.5194/tc-16-2709-2022
- The Antarctic Astronomical Observations Intelligent Support Equipment “Dome A” Site-Testing Observatory: Electric Power Generation and Control Systems S. Fang et al. 10.3390/en13174308
- Seasonal Variation of Mercury and Its Isotopes in Atmospheric Particles at the Coastal Zhongshan Station, Eastern Antarctica C. Li et al. 10.1021/acs.est.0c04462
- Summer variability of the atmospheric NO2 : NO ratio at Dome C on the East Antarctic Plateau A. Barbero et al. 10.5194/acp-22-12025-2022
- Understanding mercury oxidation and air–snow exchange on the East Antarctic Plateau: a modeling study S. Song et al. 10.5194/acp-18-15825-2018
- Quantum Yields of Nitrite (NO2–) from the Photolysis of Nitrate (NO3–) in Ice at 313 nm K. Benedict & C. Anastasio 10.1021/acs.jpca.7b08839
- A compact incoherent broadband cavity-enhanced absorption spectrometer for trace detection of nitrogen oxides, iodine oxide and glyoxal at levels below parts per billion for field applications A. Barbero et al. 10.5194/amt-13-4317-2020
- New Estimation of the NOx Snow‐Source on the Antarctic Plateau A. Barbero et al. 10.1029/2021JD035062
- Reactive bromine in the low troposphere of Antarctica: estimations at two research sites C. Prados-Roman et al. 10.5194/acp-18-8549-2018
- Year‐round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites M. Legrand et al. 10.1002/2015JD024066
- Year-round record of near-surface ozone and O3 enhancement events (OEEs) at Dome A, East Antarctica M. Ding et al. 10.5194/essd-12-3529-2020
- Seasonal variations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica S. Ishino et al. 10.5194/acp-17-3713-2017
- Multi-year variation of near-surface ozone at Zhongshan Station, Antarctica B. Tian et al. 10.1088/1748-9326/ac583c
- Influences of downward transport and photochemistry on surface ozone over East Antarctica during austral summer: in situ observations and model simulations I. Girach et al. 10.5194/acp-24-1979-2024
- Homogeneous and heterogeneous photolysis of nitrate in the atmosphere: state of the science, current research needs, and future prospects Y. Cao et al. 10.1007/s11783-023-1648-6
4 citations as recorded by crossref.
- Measurements of OH and RO<sub>2</sub> radicals at Dome C, East Antarctica A. Kukui et al. 10.5194/acp-14-12373-2014
- Formaldehyde (HCHO) in air, snow, and interstitial air at Concordia (East Antarctic Plateau) in summer S. Preunkert et al. 10.5194/acp-15-6689-2015
- Large mixing ratios of atmospheric nitrous acid (HONO) at Concordia (East Antarctic Plateau) in summer: a strong source from surface snow? M. Legrand et al. 10.5194/acp-14-9963-2014
- Characterization of the boundary layer at Dome C (East Antarctica) during the OPALE summer campaign H. Gallée et al. 10.5194/acp-15-6225-2015
Saved (final revised paper)
Saved (preprint)
Latest update: 20 Apr 2024
Short summary
Surprisingly large concentrations and flux of atmospheric nitrogen oxides were measured at Dome C, East Antarctica. It was found that the surface snow holds a significant reservoir of photochemically produced NOx and is a sink of gas-phase ozone. Main drivers of NOx snow emissions were large snow nitrate concentrations, with contributions of increased UV from decreases in stratospheric ozone. Observed halogen and hydroxyl radical concentrations were too low to explain large NO2:NO ratios.
Surprisingly large concentrations and flux of atmospheric nitrogen oxides were measured at Dome...
Special issue
Altmetrics
Final-revised paper
Preprint