Articles | Volume 15, issue 21
https://doi.org/10.5194/acp-15-12267-2015
https://doi.org/10.5194/acp-15-12267-2015
Research article
 | 
05 Nov 2015
Research article |  | 05 Nov 2015

A qualitative comparison of secondary organic aerosol yields and composition from ozonolysis of monoterpenes at varying concentrations of NO2

D. C. Draper, D. K. Farmer, Y. Desyaterik, and J. L. Fry

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Cited articles

Atkinson, R. and Arey, J.: Atmospheric Degradation of Volatile Organic Compounds, Chem. Rev., 103, 4605–4638, https://doi.org/10.1021/cr0206420, 2003.
Atkinson, R., Aschmann, S. M., Arey, J., and Shorees, B.: Formation of OH radicals in the gas phase reactions of O3 with a series of terpenes, J. Geophys. Res.-Atmos., 97, 6065–6073, https://doi.org/10.1029/92JD00062, 1992.
Barthelmie, R. J. and Pryor, S. C.: A model mechanism to describe oxidation of monoterpenes leading to secondary organic aerosol: 1. α-pinene and β-pinene, J. Geophys. Res.-Atmos., 104, 23657–23699, https://doi.org/10.1029/1999JD900382, 1999.
Bateman, A. P., Walser, M. L., Desyaterik, Y., Laskin, J., Laskin, A., and Nizkorodov, S. A.: The Effect of Solvent on the Analysis of Secondary Organic Aerosol Using Electrospray Ionization Mass Spectrometry, Environ. Sci. Technol., 42, 7341–7346, https://doi.org/10.1021/es801226w, 2008.
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Short summary
The addition of NO2 to atmospheric particle formation simulations based on ozone reactions with tree-emitted monoterpenes results in changing particle composition and mass yields, with effects that vary across the range of studied monoterpenes. For alpha-pinene, a dominantly emitted terpene in the United States, NO2 addition suppresses particle formation, while for others, particle yields remain high.
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