Articles | Volume 25, issue 1
https://doi.org/10.5194/acp-25-425-2025
https://doi.org/10.5194/acp-25-425-2025
Research article
 | 
13 Jan 2025
Research article |  | 13 Jan 2025

Enhanced sulfate formation in mixed biomass burning and sea-salt interactions mediated by photosensitization: effects of chloride, nitrogen-containing compounds, and atmospheric aging

Rongzhi Tang, Jialiang Ma, Ruifeng Zhang, Weizhen Cui, Yuanyuan Qin, Yangxi Chu, Yiming Qin, Alexander L. Vogel, and Chak K. Chan

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Cited articles

Alexander, B., Allman, D. J., Amos, H. M., Fairlie, T. D., Dachs, J., Hegg, D. A., and Sletten, R. S.: Isotopic constraints on the formation pathways of sulfate aerosol in the marine boundary layer of the subtropical northeast Atlantic Ocean, J. Geophys. Res.-Atmos., 117, D06304, https://doi.org/10.1029/2011JD016773, 2012. 
Anastasio, C. and Newberg, J. T.: Sources and sinks of hydroxyl radical in sea-salt particles, J. Geophys. Res.-Atmos., 112, D10306, https://doi.org/10.1029/2006JD008061, 2007. 
Andreae, M. O.: Emission of trace gases and aerosols from biomass burning – an updated assessment, Atmos. Chem. Phys., 19, 8523–8546, https://doi.org/10.5194/acp-19-8523-2019, 2019. 
Cai, J., Zeng, X., Zhi, G., Gligorovski, S., Sheng, G., Yu, Z., Wang, X., and Peng, P.: Molecular composition and photochemical evolution of water-soluble organic carbon (WSOC) extracted from field biomass burning aerosols using high-resolution mass spectrometry, Atmos. Chem. Phys., 20, 6115–6128, https://doi.org/10.5194/acp-20-6115-2020, 2020. 
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Short summary
This study provides laboratory evidence that the photosensitizers in biomass burning extracts can enhance sulfate formation in NaCl particles, primarily by triggering the formation of secondary oxidants under light and air conditions, with a lower contribution of direct photosensitization via triplets.
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