Articles | Volume 24, issue 1
https://doi.org/10.5194/acp-24-553-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-553-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Jan 2024
Research article |
| 15 Jan 2024
| 15 Jan 2024
Mass spectrometric analysis of unprecedented high levels of carbonaceous aerosol particles long-range transported from wildfires in the Siberian Arctic
Eric Schneider
Joint Mass Spectrometry Centre (JMSC), Chair of Analytical Chemistry, University of Rostock, 18059 Rostock, Germany
Department of Life, Light & Matter (LLM), University of Rostock, 18059 Rostock, Germany
Hendryk Czech
CORRESPONDING AUTHOR
Joint Mass Spectrometry Centre (JMSC), Chair of Analytical Chemistry, University of Rostock, 18059 Rostock, Germany
Olga Popovicheva
Skobeltsyn Institute of Nuclear Physics, Lomonosov Moscow State University, Leninskie Gory, 1, 119991 Moscow, Russia
Marina Chichaeva
Faculty of Geography, Lomonosov Moscow State University, Leninskie Gory, 1, 119991 Moscow, Russia
Vasily Kobelev
Faculty of Geography, Lomonosov Moscow State University, Leninskie Gory, 1, 119991 Moscow, Russia
Nikolay Kasimov
Faculty of Geography, Lomonosov Moscow State University, Leninskie Gory, 1, 119991 Moscow, Russia
Tatiana Minkina
Academy of Biology and Biotechnology, Southern Federal University, 344090 Rostov-on-Don, Russia
Christopher Paul Rüger
Joint Mass Spectrometry Centre (JMSC), Chair of Analytical Chemistry, University of Rostock, 18059 Rostock, Germany
Department of Life, Light & Matter (LLM), University of Rostock, 18059 Rostock, Germany
Ralf Zimmermann
Joint Mass Spectrometry Centre (JMSC), Chair of Analytical Chemistry, University of Rostock, 18059 Rostock, Germany
Department of Life, Light & Matter (LLM), University of Rostock, 18059 Rostock, Germany
Related authors
No articles found.
Anni Hartikainen, Mika Ihalainen, Deeksha Shukla, Marius Rohkamp, Arya Mukherjee, Quanfu He, Sandra Piel, Aki Virkkula, Delun Li, Tuukka Kokkola, Seongho Jeong, Hanna Koponen, Uwe Etzien, Anusmita Das, Krista Luoma, Lukas Schwalb, Thomas Gröger, Alexandre Barth, Martin Sklorz, Thorsten Streibel, Hendryk Czech, Benedikt Gündling, Markus Kalberer, Bert Buchholz, Andreas Hupfer, Thomas Adam, Thorsten Hohaus, Johan Øvrevik, Ralf Zimmermann, and Olli Sippula
Atmos. Chem. Phys., 25, 9275–9294, https://doi.org/10.5194/acp-25-9275-2025, https://doi.org/10.5194/acp-25-9275-2025, 2025
Short summary
Short summary
Photochemical reactions altered the properties of kerosene-operated jet engine burner exhaust emissions, which were studied in a laboratory using an oxidation flow reactor. Particle mass increased 300-fold as particles and gases became more oxidized. Light absorption increased, but the total direct radiative forcing efficiency was estimated to have shifted from positive to negative. The results highlight the importance of considering secondary aerosol formation when assessing the impacts of aviation.
Olga B. Popovicheva, Marina A. Chichaeva, Nikolaos Evangeliou, Sabine Eckhardt, Evangelia Diapouli, and Nikolay S. Kasimov
Atmos. Chem. Phys., 25, 7719–7739, https://doi.org/10.5194/acp-25-7719-2025, https://doi.org/10.5194/acp-25-7719-2025, 2025
Short summary
Short summary
High-quality measurements of light-absorbing carbon were performed at the polar aerosol station "Island Bely” (Western Siberian Arctic) from 2019 to 2022. The maximum light absorption coefficients were seen in summer due to gas flaring, which is the most significant source in the region. However, the increasing Siberian wildfires had a special share in carbon contribution at this high Arctic station, with a persistent smoke layer extending over the whole troposphere in summer.
Arya Mukherjee, Anni Hartikainen, Markus Somero, Viljami Luostari, Mika Ihalainen, Christopher P. Rüger, Timo Kekäläinen, Ville H. Nissinen, Luis M. F. Barreira, Hanna Koponen, Tuukka Kokkola, Delun Li, Lejish Vettikkat, Pasi Yli-Pirilä, Muhammad Shahzaib, Meri M. Ruppel, Ville Vakkari, Kerneels Jaars, Stefan J. Siebert, Angela Buchholz, Kajar Köster, Pieter G. van Zyl, Hilkka Timonen, Niko Kinnunen, Janne Jänis, Annele Virtanen, Aki Virkkula, and Olli Sippula
EGUsphere, https://doi.org/10.5194/egusphere-2025-2759, https://doi.org/10.5194/egusphere-2025-2759, 2025
Short summary
Short summary
Warming climate is predicted to increase boreal and peatland fires in Northern Eurasia. Limited studies have characterized light absorbing aerosol emissions from these biomasses, thus necessitating this work. Brown carbon (BrC) emitted from laboratory-scale biomass burning had weak light absorptivities based on their complex refractive index values. A combustion temperature dependent light absorptivity continuum existed for emitted BrC. Photochemical aging decreased BrC light absorptivity.
Marco Schmidt, Haseeb Hakkim, Lukas Anders, Aleksandrs Kalamašņikovs, Thomas Kröger-Badge, Robert Irsig, Norbert Graf, Reinhard Kelnberger, Johannes Passig, and Ralf Zimmermann
Atmos. Meas. Tech., 18, 2425–2437, https://doi.org/10.5194/amt-18-2425-2025, https://doi.org/10.5194/amt-18-2425-2025, 2025
Short summary
Short summary
Laser desorption of individual particles prior to ionization is the key to reveal their organic composition. The CO2 lasers required are bulky and maintenance-intensive, limiting their use in the field. We have developed a compact solid-state IR laser that is easily aligned with the particle beam. Mass spectra and hit rates are similar to those of the CO2 laser. For combined characterization of organic and inorganic particle compositions, both lasers are superior to conventional single UV pulses.
Battist Utinger, Alexandre Barth, Andreas Paul, Arya Mukherjee, Steven John Campbell, Christa-Maria Müller, Mika Ihalainen, Pasi Yli-Pirilä, Miika Kortelainen, Zheng Fang, Patrick Martens, Markus Somero, Juho Louhisalmi, Thorsten Hohaus, Hendryk Czech, Olli Sippula, Yinon Rudich, Ralf Zimmermann, and Markus Kalberer
Aerosol Research, 3, 205–218, https://doi.org/10.5194/ar-3-205-2025, https://doi.org/10.5194/ar-3-205-2025, 2025
Short summary
Short summary
The oxidative potential (OP) of air pollution particles might be a metric explaining particle toxicity. This study quantifies the OP of fresh and aged car and wood burning emission particles and explores how the OP changes over time, using novel high-temporal-resolution instruments. We show that emissions from wood burning are more toxic than car exhaust per unit particle mass, especially as they age in the atmosphere. We also calculate emission factors for the OP, which could help to improve air pollution policies.
Elisabeth Eckenberger, Andreas Mittereder, Nadine Gawlitta, Jürgen Schnelle-Kreis, Martin Sklorz, Dieter Brüggemann, Ralf Zimmermann, and Anke C. Nölscher
Aerosol Research, 3, 45–64, https://doi.org/10.5194/ar-3-45-2025, https://doi.org/10.5194/ar-3-45-2025, 2025
Short summary
Short summary
We assessed the performance of four cascade impactors for collecting and analyzing organic markers in airborne ultrafine particles (UFPs) under lab and field conditions. The cutoff was influenced by the impactor design and aerosol mixture. Two key factors caused variations in mass concentrations: the evaporation of semi-volatile compounds and the "bounce-off" of larger particles and fragments. Our findings reveal the challenges of analyzing organic marker mass concentrations in airborne UFPs.
Outi Meinander, Pavla Dagsson-Waldhauserova, Pavel Amosov, Elena Aseyeva, Cliff Atkins, Alexander Baklanov, Clarissa Baldo, Sarah L. Barr, Barbara Barzycka, Liane G. Benning, Bojan Cvetkovic, Polina Enchilik, Denis Frolov, Santiago Gassó, Konrad Kandler, Nikolay Kasimov, Jan Kavan, James King, Tatyana Koroleva, Viktoria Krupskaya, Markku Kulmala, Monika Kusiak, Hanna K. Lappalainen, Michał Laska, Jerome Lasne, Marek Lewandowski, Bartłomiej Luks, James B. McQuaid, Beatrice Moroni, Benjamin Murray, Ottmar Möhler, Adam Nawrot, Slobodan Nickovic, Norman T. O’Neill, Goran Pejanovic, Olga Popovicheva, Keyvan Ranjbar, Manolis Romanias, Olga Samonova, Alberto Sanchez-Marroquin, Kerstin Schepanski, Ivan Semenkov, Anna Sharapova, Elena Shevnina, Zongbo Shi, Mikhail Sofiev, Frédéric Thevenet, Throstur Thorsteinsson, Mikhail Timofeev, Nsikanabasi Silas Umo, Andreas Uppstu, Darya Urupina, György Varga, Tomasz Werner, Olafur Arnalds, and Ana Vukovic Vimic
Atmos. Chem. Phys., 22, 11889–11930, https://doi.org/10.5194/acp-22-11889-2022, https://doi.org/10.5194/acp-22-11889-2022, 2022
Short summary
Short summary
High-latitude dust (HLD) is a short-lived climate forcer, air pollutant, and nutrient source. Our results suggest a northern HLD belt at 50–58° N in Eurasia and 50–55° N in Canada and at >60° N in Eurasia and >58° N in Canada. Our addition to the previously identified global dust belt (GDB) provides crucially needed information on the extent of active HLD sources with both direct and indirect impacts on climate and environment in remote regions, which are often poorly understood and predicted.
Natalia E. Chubarova, Heike Vogel, Elizaveta E. Androsova, Alexander A. Kirsanov, Olga B. Popovicheva, Bernhard Vogel, and Gdaliy S. Rivin
Atmos. Chem. Phys., 22, 10443–10466, https://doi.org/10.5194/acp-22-10443-2022, https://doi.org/10.5194/acp-22-10443-2022, 2022
Short summary
Short summary
Effects of urban aerosol pollution in Moscow were analyzed using the COSMO-ART chemical transport model and intensive measurement campaigns. We show that urban aerosol comprises about 15–20% of columnar aerosol content, consisting mainly of fine aerosol mode. The black carbon (BC) fraction is about 5 %, depending on particle dispersion intensity (IPD). The BC fraction low value explains weak absorbing properties of the Moscow atmosphere. IPD also defines the daily cycle of urban aerosol species.
Olga B. Popovicheva, Nikolaos Evangeliou, Vasilii O. Kobelev, Marina A. Chichaeva, Konstantinos Eleftheriadis, Asta Gregorič, and Nikolay S. Kasimov
Atmos. Chem. Phys., 22, 5983–6000, https://doi.org/10.5194/acp-22-5983-2022, https://doi.org/10.5194/acp-22-5983-2022, 2022
Short summary
Short summary
Measurements of black carbon (BC) combined with atmospheric transport modeling reveal that gas flaring from oil and gas extraction in Kazakhstan, Volga-Ural, Komi, Nenets and western Siberia contributes the largest share of surface BC in the Russian Arctic dominating over domestic, industrial and traffic sectors. Pollution episodes show an increasing trend in concentration levels and frequency as the station is in the Siberian gateway of the highest anthropogenic pollution to the Russian Arctic.
Cynthia H. Whaley, Rashed Mahmood, Knut von Salzen, Barbara Winter, Sabine Eckhardt, Stephen Arnold, Stephen Beagley, Silvia Becagli, Rong-You Chien, Jesper Christensen, Sujay Manish Damani, Xinyi Dong, Konstantinos Eleftheriadis, Nikolaos Evangeliou, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Fabio Giardi, Wanmin Gong, Jens Liengaard Hjorth, Lin Huang, Ulas Im, Yugo Kanaya, Srinath Krishnan, Zbigniew Klimont, Thomas Kühn, Joakim Langner, Kathy S. Law, Louis Marelle, Andreas Massling, Dirk Olivié, Tatsuo Onishi, Naga Oshima, Yiran Peng, David A. Plummer, Olga Popovicheva, Luca Pozzoli, Jean-Christophe Raut, Maria Sand, Laura N. Saunders, Julia Schmale, Sangeeta Sharma, Ragnhild Bieltvedt Skeie, Henrik Skov, Fumikazu Taketani, Manu A. Thomas, Rita Traversi, Kostas Tsigaridis, Svetlana Tsyro, Steven Turnock, Vito Vitale, Kaley A. Walker, Minqi Wang, Duncan Watson-Parris, and Tahya Weiss-Gibbons
Atmos. Chem. Phys., 22, 5775–5828, https://doi.org/10.5194/acp-22-5775-2022, https://doi.org/10.5194/acp-22-5775-2022, 2022
Short summary
Short summary
Air pollutants, like ozone and soot, play a role in both global warming and air quality. Atmospheric models are often used to provide information to policy makers about current and future conditions under different emissions scenarios. In order to have confidence in those simulations, in this study we compare simulated air pollution from 18 state-of-the-art atmospheric models to measured air pollution in order to assess how well the models perform.
Hanna K. Lappalainen, Tuukka Petäjä, Timo Vihma, Jouni Räisänen, Alexander Baklanov, Sergey Chalov, Igor Esau, Ekaterina Ezhova, Matti Leppäranta, Dmitry Pozdnyakov, Jukka Pumpanen, Meinrat O. Andreae, Mikhail Arshinov, Eija Asmi, Jianhui Bai, Igor Bashmachnikov, Boris Belan, Federico Bianchi, Boris Biskaborn, Michael Boy, Jaana Bäck, Bin Cheng, Natalia Chubarova, Jonathan Duplissy, Egor Dyukarev, Konstantinos Eleftheriadis, Martin Forsius, Martin Heimann, Sirkku Juhola, Vladimir Konovalov, Igor Konovalov, Pavel Konstantinov, Kajar Köster, Elena Lapshina, Anna Lintunen, Alexander Mahura, Risto Makkonen, Svetlana Malkhazova, Ivan Mammarella, Stefano Mammola, Stephany Buenrostro Mazon, Outi Meinander, Eugene Mikhailov, Victoria Miles, Stanislav Myslenkov, Dmitry Orlov, Jean-Daniel Paris, Roberta Pirazzini, Olga Popovicheva, Jouni Pulliainen, Kimmo Rautiainen, Torsten Sachs, Vladimir Shevchenko, Andrey Skorokhod, Andreas Stohl, Elli Suhonen, Erik S. Thomson, Marina Tsidilina, Veli-Pekka Tynkkynen, Petteri Uotila, Aki Virkkula, Nadezhda Voropay, Tobias Wolf, Sayaka Yasunaka, Jiahua Zhang, Yubao Qiu, Aijun Ding, Huadong Guo, Valery Bondur, Nikolay Kasimov, Sergej Zilitinkevich, Veli-Matti Kerminen, and Markku Kulmala
Atmos. Chem. Phys., 22, 4413–4469, https://doi.org/10.5194/acp-22-4413-2022, https://doi.org/10.5194/acp-22-4413-2022, 2022
Short summary
Short summary
We summarize results during the last 5 years in the northern Eurasian region, especially from Russia, and introduce recent observations of the air quality in the urban environments in China. Although the scientific knowledge in these regions has increased, there are still gaps in our understanding of large-scale climate–Earth surface interactions and feedbacks. This arises from limitations in research infrastructures and integrative data analyses, hindering a comprehensive system analysis.
Zhi-Hui Zhang, Elena Hartner, Battist Utinger, Benjamin Gfeller, Andreas Paul, Martin Sklorz, Hendryk Czech, Bin Xia Yang, Xin Yi Su, Gert Jakobi, Jürgen Orasche, Jürgen Schnelle-Kreis, Seongho Jeong, Thomas Gröger, Michal Pardo, Thorsten Hohaus, Thomas Adam, Astrid Kiendler-Scharr, Yinon Rudich, Ralf Zimmermann, and Markus Kalberer
Atmos. Chem. Phys., 22, 1793–1809, https://doi.org/10.5194/acp-22-1793-2022, https://doi.org/10.5194/acp-22-1793-2022, 2022
Short summary
Short summary
Using a novel setup, we comprehensively characterized the formation of particle-bound reactive oxygen species (ROS) in anthropogenic and biogenic secondary organic aerosols (SOAs). We found that more than 90 % of all ROS components in both SOA types have a short lifetime. Our results also show that photochemical aging promotes particle-bound ROS production and enhances the oxidative potential of the aerosols. We found consistent results between chemical-based and biological-based ROS analyses.
Johannes Passig, Julian Schade, Robert Irsig, Thomas Kröger-Badge, Hendryk Czech, Thomas Adam, Henrik Fallgren, Jana Moldanova, Martin Sklorz, Thorsten Streibel, and Ralf Zimmermann
Atmos. Chem. Phys., 22, 1495–1514, https://doi.org/10.5194/acp-22-1495-2022, https://doi.org/10.5194/acp-22-1495-2022, 2022
Short summary
Short summary
The single-particle distribution of health-relevant polycyclic aromatic hydrocarbons (PAHs) was studied at the Swedish coast in autumn. We found PAHs bound to long-range transported particles from eastern and central Europe and also from ship emissions and local sources. This is the first field study using a new technology revealing single-particle data from both inorganic components and PAHs. We discuss PAH profiles that are indicative of several sources and atmospheric aging processes.
Dac-Loc Nguyen, Hendryk Czech, Simone M. Pieber, Jürgen Schnelle-Kreis, Martin Steinbacher, Jürgen Orasche, Stephan Henne, Olga B. Popovicheva, Gülcin Abbaszade, Guenter Engling, Nicolas Bukowiecki, Nhat-Anh Nguyen, Xuan-Anh Nguyen, and Ralf Zimmermann
Atmos. Chem. Phys., 21, 8293–8312, https://doi.org/10.5194/acp-21-8293-2021, https://doi.org/10.5194/acp-21-8293-2021, 2021
Short summary
Short summary
Southeast Asia is well-known for emission-intense and recurring wildfires and after-harvest crop residue burning during the pre-monsoon season from February to April. We describe a biomass burning (BB) plume arriving at remote Pha Din meteorological station, outline its carbonaceous particulate matter (PM) constituents based on more than 50 target compounds and discuss possible BB sources. This study adds valuable information on chemical PM composition for a region with scarce data availability.
Polina Enchilik, Ivan Semenkov, and Nikolay Kasimov
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2020-309, https://doi.org/10.5194/essd-2020-309, 2021
Revised manuscript not accepted
Short summary
Short summary
This study presents a dataset on seasonal soils sampling in the southern part of the Central Forest Reserve (SE Valdai Hills) within a catena with Retisols under coniferous-deciduous forest on loess-like loams underlain by carbonate moraine deposits. 152 soil samples were taken to define total concentration of 67 chemical elements, content of three mobile fractions. We measured pH-value, total organic carbon content, seven particle-size classes and basicity from carbonates.
Cited articles
Abatzoglou, J. T., Williams, A. P., and Barbero, R.: Global Emergence of Anthropogenic Climate Change in Fire Weather Indices, Geophys. Res. Lett., 46, 326–336, https://doi.org/10.1029/2018GL080959, 2019.
Al-Abadleh, H. A.: Aging of atmospheric aerosols and the role of iron in catalyzing brown carbon formation, Environ. Sci. Atmos., 1, 297–345, https://doi.org/10.1039/D1EA00038A, 2021.
Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006.
Bardyshev, I. I., Kryuk, S. I., and Pertsovskii, A. L.: Fatty acid composition of various balsams and rosins, Chem. Nat. Compd., 6, 360–361, https://doi.org/10.1007/BF00567321, 1970.
Bond, T. C., Doherty, S. J., Fahey, D. W., Forster, P. M., Berntsen, T., DeAngelo, B. J., Flanner, M. G., Ghan, S., Kärcher, B., Koch, D., Kinne, S., Kondo, Y., Quinn, P. K., Sarofim, M. C., Schultz, M. G., Schulz, M., Venkataraman, C., Zhang, H., Zhang, S., Bellouin, N., Guttikunda, S. K., Hopke, P. K., Jacobson, M. Z., Kaiser, J. W., Klimont, Z., Lohmann, U., Schwarz, J. P., Shindell, D., Storelvmo, T., Warren, S. G., and Zender, C. S.: Bounding the role of black carbon in the climate system: A scientific assessment, Geophys. Res. Atmos., 118, 5380–5552, https://doi.org/10.1002/jgrd.50171, 2013.
Brege, M. A., China, S., Schum, S., Zelenyuk, A., and Mazzoleni, L. R.: Extreme Molecular Complexity Resulting in a Continuum of Carbonaceous Species in Biomass Burning Tar Balls from Wildfire Smoke, ACS Earth Space Chem., 5, 2729–2739, https://doi.org/10.1021/acsearthspacechem.1c00141, 2021.
Calì Quaglia, F., Meloni, D., Muscari, G., Di Iorio, T., Ciardini, V., Pace, G., Becagli, S., Di Bernardino, A., Cacciani, M., Hannigan, J. W., Ortega, I., and Di Sarra, A. G.: On the Radiative Impact of Biomass-Burning Aerosols in the Arctic: The August 2017 Case Study, Remote Sens.-Basel, 14, 313, https://doi.org/10.3390/rs14020313, 2022.
Chacon-Madrid, H. J. and Donahue, N. M.: Fragmentation vs. functionalization: chemical aging and organic aerosol formation, Atmos. Chem. Phys., 11, 10553–10563, https://doi.org/10.5194/acp-11-10553-2011, 2011.
Chakrabarty, R. K., Moosmüller, H., Chen, L.-W. A., Lewis, K., Arnott, W. P., Mazzoleni, C., Dubey, M. K., Wold, C. E., Hao, W. M., and Kreidenweis, S. M.: Brown carbon in tar balls from smoldering biomass combustion, Atmos. Chem. Phys., 10, 6363–6370, https://doi.org/10.5194/acp-10-6363-2010, 2010.
Chen, G., Guo, Y., Yue, X., Tong, S., Gasparrini, A., Bell, M. L., Armstrong, B., Schwartz, J., Jaakkola, J. J. K., Zanobetti, A., Lavigne, E., Nascimento Saldiva, P. H., Kan, H., Royé, D., Milojevic, A., Overcenco, A., Urban, A., Schneider, A., Entezari, A., Vicedo-Cabrera, A. M., Zeka, A., Tobias, A., Nunes, B., Alahmad, B., Forsberg, B., Pan, S.-C., Íñiguez, C., Ameling, C., La Cruz Valencia, C. de, Åström, C., Houthuijs, D., van Dung, D., Samoli, E., Mayvaneh, F., Sera, F., Carrasco-Escobar, G., Lei, Y., Orru, H., Kim, H., Holobaca, I.-H., Kyselý, J., Teixeira, J. P., Madureira, J., Katsouyanni, K., Hurtado-Díaz, M., Maasikmets, M., Ragettli, M. S., Hashizume, M., Stafoggia, M., Pascal, M., Scortichini, M., Sousa Zanotti Stagliorio Coêlho, M. de, Valdés Ortega, N., Ryti, N. R. I., Scovronick, N., Matus, P., Goodman, P., Garland, R. M., Abrutzky, R., Garcia, S. O., Rao, S., Fratianni, S., Dang, T. N., Colistro, V., Huber, V., Lee, W., Seposo, X., Honda, Y., Guo, Y. L., Ye, T., Yu, W., Abramson, M. J., Samet, J. M., and Li, S.: Mortality risk attributable to wildfire-related PM2.5 pollution: a global time series study in 749 locations, Lancet Planetary Health, 5, e579-e587, https://doi.org/10.1016/S2542-5196(21)00200-X, 2021.
Chen, L.-W. A., Moosmüller, H., Arnott, W. P., Chow, J. C., Watson, J. G., Susott, R. A., Babbitt, R. E., Wold, C. E., Lincoln, E. N., and Hao, W. M.: Particle emissions from laboratory combustion of wildland fuels: In situ optical and mass measurements, Geophys. Res. Lett., 33, L04803, https://doi.org/10.1029/2005GL024838, 2006.
Chen, L.-W. A., Chow, J. C., Wang, X. L., Robles, J. A., Sumlin, B. J., Lowenthal, D. H., Zimmermann, R., and Watson, J. G.: Multi-wavelength optical measurement to enhance thermal/optical analysis for carbonaceous aerosol, Atmos. Meas. Tech., 8, 451–461, https://doi.org/10.5194/amt-8-451-2015, 2015.
Cheng, Y., Duan, F., He, K., Zheng, M., Du, Z., Ma, Y., and Tan, J.: Intercomparison of thermal-optical methods for the determination of organic and elemental carbon: influences of aerosol composition and implications, Environ. Sci. Technol., 45, 10117–10123, https://doi.org/10.1021/es202649g, 2011.
Cho, Y., Kim, Y. H., and Kim, S.: Planar limit-assisted structural interpretation of saturates/aromatics/resins/asphaltenes fractionated crude oil compounds observed by Fourier transform ion cyclotron resonance mass spectrometry, Anal. Chem., 83, 6068–6073, https://doi.org/10.1021/ac2011685, 2011.
Chow, J. C., Watson, J. G., Chen, L. W. A., Chang, M. C. O., Robinson, N. F., Trimble, D., and Kohl, S.: The IMPROVE_A temperature protocol for thermal/optical carbon analysis: maintaining consistency with a long-term database, J. Air Waste Manage. Assoc. (1995), 57, 1014–1023, https://doi.org/10.3155/1047-3289.57.9.1014, 2007.
Chow, J. C., Chen, L.-W. A., Wang, X., Green, M. C., and Watson, J. G.: Improved estimation of PM2.5 brown carbon contributions to filter light attenuation, Particuology, 56, 1–9, https://doi.org/10.1016/j.partic.2021.01.001, 2021.
Decker, Z. C. J., Robinson, M. A., Barsanti, K. C., Bourgeois, I., Coggon, M. M., DiGangi, J. P., Diskin, G. S., Flocke, F. M., Franchin, A., Fredrickson, C. D., Gkatzelis, G. I., Hall, S. R., Halliday, H., Holmes, C. D., Huey, L. G., Lee, Y. R., Lindaas, J., Middlebrook, A. M., Montzka, D. D., Moore, R., Neuman, J. A., Nowak, J. B., Palm, B. B., Peischl, J., Piel, F., Rickly, P. S., Rollins, A. W., Ryerson, T. B., Schwantes, R. H., Sekimoto, K., Thornhill, L., Thornton, J. A., Tyndall, G. S., Ullmann, K., Van Rooy, P., Veres, P. R., Warneke, C., Washenfelder, R. A., Weinheimer, A. J., Wiggins, E., Winstead, E., Wisthaler, A., Womack, C., and Brown, S. S.: Nighttime and daytime dark oxidation chemistry in wildfire plumes: an observation and model analysis of FIREX-AQ aircraft data, Atmos. Chem. Phys., 21, 16293–16317, https://doi.org/10.5194/acp-21-16293-2021, 2021.
Diab, J., Streibel, T., Cavalli, F., Lee, S. C., Saathoff, H., Mamakos, A., Chow, J. C., Chen, L.-W. A., Watson, J. G., Sippula, O., and Zimmermann, R.: Hyphenation of a EC / OC thermal–optical carbon analyzer to photo-ionization time-of-flight mass spectrometry: an off-line aerosol mass spectrometric approach for characterization of primary and secondary particulate matter, Atmos. Meas. Tech., 8, 3337–3353, https://doi.org/10.5194/amt-8-3337-2015, 2015.
Ditto, J. C., He, M., Hass-Mitchell, T. N., Moussa, S. G., Hayden, K., Li, S.-M., Liggio, J., Leithead, A., Lee, P., Wheeler, M. J., Wentzell, J. J. B., and Gentner, D. R.: Atmospheric evolution of emissions from a boreal forest fire: the formation of highly functionalized oxygen-, nitrogen-, and sulfur-containing organic compounds, Atmos. Chem. Phys., 21, 255–267, https://doi.org/10.5194/acp-21-255-2021, 2021.
Donahue, N. M., Epstein, S. A., Pandis, S. N., and Robinson, A. L.: A two-dimensional volatility basis set: 1. organic-aerosol mixing thermodynamics, Atmos. Chem. Phys., 11, 3303–3318, https://doi.org/10.5194/acp-11-3303-2011, 2011.
Donahue, N. M., Kroll, J. H., Pandis, S. N., and Robinson, A. L.: A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution, Atmos. Chem. Phys., 12, 615–634, https://doi.org/10.5194/acp-12-615-2012, 2012.
Eleftheriadis, K., Nyeki, S., Psomiadou, C., and Colbeck, I.: Background Aerosol Properties in the European Arctic, Water Air Soil Pollut. Focus, 4, 23–30, https://doi.org/10.1023/B:WAFO.0000044783.70114.19, 2004.
Fang, Z., Li, C., He, Q., Czech, H., Gröger, T., Zeng, J., Fang, H., Xiao, S., Pardo, M., Hartner, E., Meidan, D., Wang, X., Zimmermann, R., Laskin, A., and Rudich, Y.: Secondary organic aerosols produced from photochemical oxidation of secondarily evaporated biomass burning organic gases: Chemical composition, toxicity, optical properties, and climate effect, Environ. Int., 157, 106801, https://doi.org/10.1016/j.envint.2021.106801, 2021.
Farley, R., Bernays, N., Jaffe, D. A., Ketcherside, D., Hu, L., Zhou, S., Collier, S., and Zhang, Q.: Persistent Influence of Wildfire Emissions in the Western United States and Characteristics of Aged Biomass Burning Organic Aerosols under Clean Air Conditions, Environ. Sci. Technol., 56, 3645–3657, https://doi.org/10.1021/acs.est.1c07301, 2022.
Fendt, A., Streibel, T., Sklorz, M., Richter, D., Dahmen, N., and Zimmermann, R.: On-Line Process Analysis of Biomass Flash Pyrolysis Gases Enabled by Soft Photoionization Mass Spectrometry, Energy Fuels, 26, 701–711, https://doi.org/10.1021/ef2012613, 2012.
Fendt, A., Geissler, R., Streibel, T., Sklorz, M., and Zimmermann, R.: Hyphenation of two simultaneously employed soft photo ionization mass spectrometers with thermal analysis of biomass and biochar, Thermochim. Acta, 551, 155–163, https://doi.org/10.1016/j.tca.2012.10.002, 2013.
Flannigan, M. D., Krawchuk, M. A., Groot, W. J. de, Wotton, B. M., and Gowman, L. M.: Implications of changing climate for global wildland fire, Int. J. Wildland Fire, 18, 483, https://doi.org/10.1071/WF08187, 2009.
Fleming, L. T., Lin, P., Roberts, J. M., Selimovic, V., Yokelson, R., Laskin, J., Laskin, A., and Nizkorodov, S. A.: Molecular composition and photochemical lifetimes of brown carbon chromophores in biomass burning organic aerosol, Atmos. Chem. Phys., 20, 1105–1129, https://doi.org/10.5194/acp-20-1105-2020, 2020.
Forrister, H., Liu, J., Scheuer, E., Dibb, J., Ziemba, L., Thornhill, K. L., Anderson, B., Diskin, G., Perring, A. E., Schwarz, J. P., Campuzano-Jost, P., Day, D. A., Palm, B. B., Jimenez, J. L., Nenes, A., and Weber, R. J.: Evolution of brown carbon in wildfire plumes, Geophys. Res. Lett., 42, 4623–4630, https://doi.org/10.1002/2015GL063897, 2015.
Fuentes, M., Baigorri, R., González-Vila, F. J., González-Gaitano, G., and García-Mina, J. M.: Pyrolysis-gas chromatography/mass spectrometry identification of distinctive structures providing humic character to organic materials, J. Environ. Qual., 39, 1486–1497, https://doi.org/10.2134/jeq2009.0180, 2010.
Gehm, C., Streibel, T., Passig, J., and Zimmermann, R.: Determination of Relative Ionization Cross Sections for Resonance Enhanced Multiphoton Ionization of Polycyclic Aromatic Hydrocarbons, Appl. Sci.-Basel, 8, 1617, https://doi.org/10.3390/app8091617, 2018.
Grabowsky, J., Streibel, T., Sklorz, M., Chow, J. C., Watson, J. G., Mamakos, A., and Zimmermann, R.: Hyphenation of a carbon analyzer to photo-ionization mass spectrometry to unravel the organic composition of particulate matter on a molecular level, Anal. Bioanal. Chem., 401, 3153–3164, https://doi.org/10.1007/s00216-011-5425-1, 2011.
He, Q.-F., Ding, X., Wang, X.-M., Yu, J.-Z., Fu, X.-X., Liu, T.-Y., Zhang, Z., Xue, J., Chen, D.-H., Zhong, L.-J., and Donahue, N. M.: Organosulfates from pinene and isoprene over the Pearl River Delta, South China: seasonal variation and implication in formation mechanisms, Environ. Sci. Technol., 48, 9236–9245, https://doi.org/10.1021/es501299v, 2014.
Helin, A., Virkkula, A., Backman, J., Pirjola, L., Sippula, O., Aakko-Saksa, P., Väätäinen, S., Mylläri, F., Järvinen, A., Bloss, M., Aurela, M., Jakobi, G., Karjalainen, P., Zimmermann, R., Jokiniemi, J., Saarikoski, S., Tissari, J., Rönkkö, T., Niemi, J. V., and Timonen, H.: Variation of Absorption Ångström Exponent in Aerosols From Different Emission Sources, Geophys. Res. Atmos., 126, https://doi.org/10.1029/2020JD034094, 2021.
Hodshire, A. L., Ramnarine, E., Akherati, A., Alvarado, M. L., Farmer, D. K., Jathar, S. H., Kreidenweis, S. M., Lonsdale, C. R., Onasch, T. B., Springston, S. R., Wang, J., Wang, Y., Kleinman, L. I., Sedlacek III, A. J., and Pierce, J. R.: Dilution impacts on smoke aging: evidence in Biomass Burning Observation Project (BBOP) data, Atmos. Chem. Phys., 21, 6839–6855, https://doi.org/10.5194/acp-21-6839-2021, 2021.
Huba, A. K., Huba, K., and Gardinali, P. R.: Understanding the atmospheric pressure ionization of petroleum components: The effects of size, structure, and presence of heteroatoms, Sci. Total Environ., 568, 1018–1025, https://doi.org/10.1016/j.scitotenv.2016.06.044, 2016.
Ikeda, K. and Tanimoto, H.: Exceedances of air quality standard level of PM2.5 in Japan caused by Siberian wildfires, Environ. Res. Lett., 10, 105001, https://doi.org/10.1088/1748-9326/10/10/105001, 2015.
IPCC: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Stocker, T. F., Qin, D., Plattner, G.-K., Tignor, M., Allen, S. K., Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M., Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp., https://doi.org/10.1017/CBO9781107415324, 2013.
Kalogridis, A.-C., Popovicheva, O. B., Engling, G., Diapouli, E., Kawamura, K., Tachibana, E., Ono, K., Kozlov, V. S., and Eleftheriadis, K.: Smoke aerosol chemistry and aging of Siberian biomass burning emissions in a large aerosol chamber, Atmos. Environ., 185, 15–28, https://doi.org/10.1016/j.atmosenv.2018.04.033, 2018.
Kauppila, T. J., Syage, J. A., and Benter, T.: Recent developments in atmospheric pressure photoionization-mass spectrometry, Mass Spectrom. Rev., 36, 423–449, https://doi.org/10.1002/mas.21477, 2017.
Kharuk, V. I., Ponomarev, E. I., Ivanova, G. A., Dvinskaya, M. L., Coogan, S. C. P., and Flannigan, M. D.: Wildfires in the Siberian taiga, Ambio, 50, 1953–1974, https://doi.org/10.1007/s13280-020-01490-x, 2021.
Laflamme, R. E. and Hites, R. A.: The global distribution of polycyclic aromatic hydrocarbons in recent sediments, Geochim. Cosmochim. Ac., 42, 289–303, https://doi.org/10.1016/0016-7037(78)90182-5, 1978.
Laskin, A., Smith, J. S., and Laskin, J.: Molecular characterization of nitrogen-containing organic compounds in biomass burning aerosols using high-resolution mass spectrometry, Environ. Sci. Technol., 43, 3764–3771, https://doi.org/10.1021/es803456n, 2009.
Lavoué, D., Liousse, C., Cachier, H., Stocks, B. J., and Goldammer, J. G.: Modeling of carbonaceous particles emitted by boreal and temperate wildfires at northern latitudes, Geophys. Res. Atmos., 105, 26871–26890, https://doi.org/10.1029/2000JD900180, 2000.
Lee, J. E., Dubey, M. K., Aiken, A. C., Chylek, P., and Carrico, C. M.: Optical and Chemical Analysis of Absorption Enhancement by Mixed Carbonaceous Aerosols in the 2019 Woodbury, AZ, Fire Plume, Geophys. Res. Atmos., 125, https://doi.org/10.1029/2020JD032399, 2020.
Lennartz, S. T., Marandino, C. A., von Hobe, M., Cortes, P., Quack, B., Simo, R., Booge, D., Pozzer, A., Steinhoff, T., Arevalo-Martinez, D. L., Kloss, C., Bracher, A., Röttgers, R., Atlas, E., and Krüger, K.: Direct oceanic emissions unlikely to account for the missing source of atmospheric carbonyl sulfide, Atmos. Chem. Phys., 17, 385–402, https://doi.org/10.5194/acp-17-385-2017, 2017.
Li, C., He, Q., Hettiyadura, A. P. S., Käfer, U., Shmul, G., Meidan, D., Zimmermann, R., Brown, S. S., George, C., Laskin, A., and Rudich, Y.: Formation of Secondary Brown Carbon in Biomass Burning Aerosol Proxies through NO3 Radical Reactions, Environ. Sci. Technol., 54, 1395–1405, https://doi.org/10.1021/acs.est.9b05641, 2020.
Li, M., Li, J., Zhu, Y., Chen, J., Andreae, M. O., Pöschl, U., Su, H., Kulmala, M., Chen, C., Cheng, Y., and Zhao, J.: Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot, Chem, 8, 2688–2699, https://doi.org/10.1016/j.chempr.2022.06.011, 2022.
Lin, P., Liu, J., Shilling, J. E., Kathmann, S. M., Laskin, J., and Laskin, A.: Molecular characterization of brown carbon (BrC) chromophores in secondary organic aerosol generated from photo-oxidation of toluene, Phys. Chem. Chem. Phys., 17, 23312–23325, https://doi.org/10.1039/C5CP02563J, 2015.
Lindaas, J., Pollack, I. B., Garofalo, L. A., Pothier, M. A., Farmer, D. K., Kreidenweis, S. M., Campos, T. L., Flocke, F., Weinheimer, A. J., Montzka, D. D., Tyndall, G. S., Palm, B. B., Peng, Q., Thornton, J. A., Permar, W., Wielgasz, C., Hu, L., Ottmar, R. D., Restaino, J. C., Hudak, A. T., Ku, I.-T., Zhou, Y., Sive, B. C., Sullivan, A., Collett, J. L., and Fischer, E. V.: Emissions of Reactive Nitrogen From Western U. S. Wildfires During Summer 2018, J. Geophys. Res.-Atmos., 126, https://doi.org/10.1029/2020JD032657, 2021.
Liu, D., Li, S., Hu, D., Kong, S., Cheng, Y., Wu, Y., Ding, S., Hu, K., Zheng, S., Yan, Q., Zheng, H., Zhao, D., Tian, P., Ye, J., Huang, M., and Ding, D.: Evolution of Aerosol Optical Properties from Wood Smoke in Real Atmosphere Influenced by Burning Phase and Solar Radiation, Environ. Sci. Technol., 55, 5677–5688, https://doi.org/10.1021/acs.est.0c07569, 2021.
Manousakas, M., Popovicheva, O., Evangeliou, N., Diapouli, E., Sitnikov, N., Shonija, N., and Eleftheriadis, K.: Aerosol carbonaceous, elemental and ionic composition variability and origin at the Siberian High Arctic, Cape Baranova, Tellus B, 72, 1803708, https://doi.org/10.1080/16000889.2020.1803708, 2022.
Marchand-Geneste, N. and Carpy, A.: Theoretical study of the thermal degradation pathways of abietane skeleton diterpenoids: aromatization to retene, J. Mol. Struct.-THEOCHEM, 635, 55–82, https://doi.org/10.1016/S0166-1280(03)00401-9, 2003.
Martens, P., Czech, H., Orasche, J., Abbaszade, G., Sklorz, M., Michalke, B., Tissari, J., Bizjak, T., Ihalainen, M., Suhonen, H., Yli-Pirilä, P., Jokiniemi, J., Sippula, O., and Zimmermann, R.: Brown Coal and Logwood Combustion in a Modern Heating Appliance: The Impact of Combustion Quality and Fuel on Organic Aerosol Composition, Environ. Sci. Technol., 57, 5532–5543, https://doi.org/10.1021/acs.est.2c08787, 2023.
Matsui, H., Mori, T., Ohata, S., Moteki, N., Oshima, N., Goto-Azuma, K., Koike, M., and Kondo, Y.: Contrasting source contributions of Arctic black carbon to atmospheric concentrations, deposition flux, and atmospheric and snow radiative effects, Atmos. Chem. Phys., 22, 8989–9009, https://doi.org/10.5194/acp-22-8989-2022, 2022.
Merder, J., Röder, H., Dittmar, T., Feudel, U., Freund, J. A., Gerdts, G., Kraberg, A., and Niggemann, J.: Dissolved organic compounds with synchronous dynamics share chemical properties and origin, Limnol. Oceanogr., 66, 4001–4016, https://doi.org/10.1002/lno.11938, 2021.
MODIS Science Team: MOD021KM MODIS/Terra Calibrated Radiances 5-Min L1B Swath 1 km, NASA [data set], 2017a.
MODIS Science Team: MOD02HKM MODIS/Terra Calibrated Radiances 5-Min L1B Swath 500 m, NASA [data set], 2017b.
MODIS Science Team: MOD02QKM MODIS/Terra Calibrated Radiances 5-Min L1B Swath 250 m, NASA [data set], 2017c.
MODIS Science Team: MYD02QKM MODIS/Aqua Calibrated Radiances 5-Min L1B Swath 250 m, NASA [data set], 2017d.
Moschos, V., Dzepina, K., Bhattu, D., Lamkaddam, H., Casotto, R., Daellenbach, K. R., Canonaco, F., Rai, P., Aas, W., Becagli, S., Calzolai, G., Eleftheriadis, K., Moffett, C. E., Schnelle-Kreis, J., Severi, M., Sharma, S., Skov, H., Vestenius, M., Zhang, W., Hakola, H., Hellén, H., Huang, L., Jaffrezo, J.-L., Massling, A., Nøjgaard, J. K., Petäjä, T., Popovicheva, O., Sheesley, R. J., Traversi, R., Yttri, K. E., Schmale, J., Prévôt, A. S. H., Baltensperger, U., and El Haddad, I.: Equal abundance of summertime natural and wintertime anthropogenic Arctic organic aerosols, Nat. Geosci., 15, 196–202, https://doi.org/10.1038/s41561-021-00891-1, 2022.
Narita, D., Gavrilyeva, T., and Isaev, A.: Impacts and management of forest fires in the Republic of Sakha, Russia: A local perspective for a global problem, Polar Sci., 27, 100573, https://doi.org/10.1016/j.polar.2020.100573, 2021.
NASA: VIIRS and MODIS, NASA Earthdata [data set], https://www.earthdata.nasa.gov/ (last access: 3 April 2023), 2023.
NUR24.RU: 
, Gorodor, https://nur24.ru/news/ecologia/smog-ot-pozharov-v-yakutii-polnostyu-okutal-yamal-foto-video (last access: 7 February 2023), 2021.
, Gorodor, https://nur24.ru/news/ecologia/smog-ot-pozharov-v-yakutii-polnostyu-okutal-yamal-foto-video (last access: 7 February 2023), 2021.
Oros, D. R. and Simoneit, B. R.: Identification and emission factors of molecular tracers in organic aerosols from biomass burning Part 2. Deciduous trees, Appl. Geochem., 16, 1545–1565, https://doi.org/10.1016/S0883-2927(01)00022-1, 2001.
Ortega, A. M., Day, D. A., Cubison, M. J., Brune, W. H., Bon, D., de Gouw, J. A., and Jimenez, J. L.: Secondary organic aerosol formation and primary organic aerosol oxidation from biomass-burning smoke in a flow reactor during FLAME-3, Atmos. Chem. Phys., 13, 11551–11571, https://doi.org/10.5194/acp-13-11551-2013, 2013.
Palm, B. B., Peng, Q., Fredrickson, C. D., Lee, B. H., Garofalo, L. A., Pothier, M. A., Kreidenweis, S. M., Farmer, D. K., Pokhrel, R. P., Shen, Y., Murphy, S. M., Permar, W., Hu, L., Campos, T. L., Hall, S. R., Ullmann, K., Zhang, X., Flocke, F., Fischer, E. V., and Thornton, J. A.: Quantification of organic aerosol and brown carbon evolution in fresh wildfire plumes, P. Natl. Acad. Sci. USA, 117, 29469–29477, https://doi.org/10.1073/pnas.2012218117, 2020.
Palm, B. B., Peng, Q., Hall, S. R., Ullmann, K., Campos, T. L., Weinheimer, A., Montzka, D., Tyndall, G., Permar, W., Hu, L., Flocke, F., Fischer, E. V., and Thornton, J. A.: Spatially Resolved Photochemistry Impacts Emissions Estimates in Fresh Wildfire Plumes, Geophys. Res. Lett., 48, https://doi.org/10.1029/2021GL095443, 2021.
Pardo, M., Offer, S., Hartner, E., Di Bucchianico, S., Bisig, C., Bauer, S., Pantzke, J., Zimmermann, E. J., Cao, X., Binder, S., Kuhn, E., Huber, A., Jeong, S., Käfer, U., Schneider, E., Mesceriakovas, A., Bendl, J., Brejcha, R., Buchholz, A., Gat, D., Hohaus, T., Rastak, N., Karg, E., Jakobi, G., Kalberer, M., Kanashova, T., Hu, Y., Ogris, C., Marsico, A., Theis, F., Shalit, T., Gröger, T., Rüger, C. P., Oeder, S., Orasche, J., Paul, A., Ziehm, T., Zhang, Z.-H., Adam, T., Sippula, O., Sklorz, M., Schnelle-Kreis, J., Czech, H., Kiendler-Scharr, A., Zimmermann, R., and Rudich, Y.: Exposure to naphthalene and β-pinene-derived secondary organic aerosol induced divergent changes in transcript levels of BEAS-2B cells, Environ. Int., 166, 107366, https://doi.org/10.1016/j.envint.2022.107366, 2022.
Peng, Q., Palm, B. B., Fredrickson, C. D., Lee, B. H., Hall, S. R., Ullmann, K., Campos, T., Weinheimer, A. J., Apel, E. C., Flocke, F., Permar, W., Hu, L., Garofalo, L. A., Pothier, M. A., Farmer, D. K., Ku, I.-T., Sullivan, A. P., Collett, J. L., Fischer, E., and Thornton, J. A.: Observations and Modeling of NO x Photochemistry and Fate in Fresh Wildfire Plumes, ACS Earth Space Chem., 5, 2652–2667, https://doi.org/10.1021/acsearthspacechem.1c00086, 2021.
Popovicheva, O. and Kozlov, V.: Impact of combustion phase on scattering and spectral absorption of Siberian biomass burning: studies in Large Aerosol Chamber, 252, Proceedings Volume 11560, 26th International Symposium on Atmospheric and Ocean Optics, Atmospheric Physics, 115604N, https://doi.org/10.1117/12.2575583, 2020.
Popovicheva, O., Diapouli, E., Makshtas, A., Shonija, N., Manousakas, M., Saraga, D., Uttal, T., and Eleftheriadis, K.: East Siberian Arctic background and black carbon polluted aerosols at HMO Tiksi, Sci. Total Environ., 655, 924–938, https://doi.org/10.1016/j.scitotenv.2018.11.165, 2019.
Popovicheva, O. B., Kozlov, V. S., Engling, G., Diapouli, E., Persiantseva, N. M., Timofeev, M. A., Fan, T.-S., Saraga, D., and Eleftheriadis, K.: Small-Scale Study of Siberian Biomass Burning: I. Smoke Microstructure, Aerosol Air Qual. Res., 15, 117–128, https://doi.org/10.4209/aaqr.2014.09.0206, 2015.
Popovicheva, O. B., Kozlov, V. S., Rakhimov, R. F., Shmargunov, V. P., Kireeva, E. D., Persiantseva, N. M., Timofeev, M. A., Engling, G., Eleftheriadis, K., Diapouli, E., Panchenko, M. V., Zimmermann, R., and Schnelle-Kreis, J.: Optical-microphysical and physical-chemical characteristics of Siberian biomass burning: Experiments in Aerosol Chamber, Atmos. Oceanic Opt., 29, 492–500, https://doi.org/10.1134/S1024856016060129, 2016.
Popovicheva, O. B., Evangeliou, N., Eleftheriadis, K., Kalogridis, A. C., Sitnikov, N., Eckhardt, S., and Stohl, A.: Black Carbon Sources Constrained by Observations in the Russian High Arctic, Environ. Sci. Technol., 51, 3871–3879, https://doi.org/10.1021/acs.est.6b05832, 2017.
Popovicheva, O. B., Chichaeva, M., Kobelev, V., Sinitskiy, A., and Hansen, A.: Black Carbon in urban emissions on the Polar Circle, 344, Proceedings Volume 11560, 26th International Symposium on Atmospheric and Ocean Optics, Atmospheric Physics, 115605J, https://doi.org/10.1117/12.2577550, https://www.spiedigitallibrary.org/conference-proceedings-of-spie/11560/2577550/Black-Carbon-in-urban-emissions-on-the-Polar-Circle/10.1117/12.2577550.full (last access: 3 February 2023), 2020.
Popovicheva, O. B., Evangeliou, N., Kobelev, V. O., Chichaeva, M. A., Eleftheriadis, K., Gregorič, A., and Kasimov, N. S.: Siberian Arctic black carbon: gas flaring and wildfire impact, Atmos. Chem. Phys., 22, 5983–6000, https://doi.org/10.5194/acp-22-5983-2022, 2022.
Popovicheva, O. B., Chichaeva, M. A., Kobelev, V. O., and Kasimov, N. S.: Black Carbon Seasonal Trends and Regional Sources on Bely Island (Arctic), Atmos. Oceanic Opt., 36, 176–184, https://doi.org/10.1134/S1024856023030090, 2023.
QGIS: Geographical information for the creation of maps, QGIS [data set], https://qgis.org/en/site/ (last access: 3 April 2023), 2023.
Qu, B., Gabric, A. J., and Jackson, R.: Simulated perturbation in the sea-to-air flux of dimethylsulfide and the impact on polar climate, J. Oceanol. Limnol., 39, 110–121, https://doi.org/10.1007/s00343-020-0007-8, 2021.
Ramdahl, T.: Retene—a molecular marker of wood combustion in ambient air, Nature, 306, 580–582, https://doi.org/10.1038/306580a0, 1983.
Ren, Q. and Zhao, C.: Evolution of fuel-N in gas phase during biomass pyrolysis, Renew. Sust. Energ. Rev., 50, 408–418, https://doi.org/10.1016/j.rser.2015.05.043, 2015.
Riva, M., Budisulistiorini, S. H., Zhang, Z., Gold, A., and Surratt, J. D.: Chemical characterization of secondary organic aerosol constituents from isoprene ozonolysis in the presence of acidic aerosol, Atmos. Environ., 130, 5–13, https://doi.org/10.1016/j.atmosenv.2015.06.027, 2016.
Rüger, C. P., Schwemer, T., Sklorz, M., O'Connor, P. B., Barrow, M. P., and Zimmermann, R.: Comprehensive chemical comparison of fuel composition and aerosol particles emitted from a ship diesel engine by gas chromatography atmospheric pressure chemical ionisation ultra-high resolution mass spectrometry with improved data processing routines, Eur. J. Mass Spectrom., 23, 28–39, https://doi.org/10.1177/1469066717694286, 2017.
Salvador, C. M. G., Tang, R., Priestley, M., Li, L., Tsiligiannis, E., Le Breton, M., Zhu, W., Zeng, L., Wang, H., Yu, Y., Hu, M., Guo, S., and Hallquist, M.: Ambient nitro-aromatic compounds – biomass burning versus secondary formation in rural China, Atmos. Chem. Phys., 21, 1389–1406, https://doi.org/10.5194/acp-21-1389-2021, 2021.
Schmale, J., Zieger, P., and Ekman, A. M. L.: Aerosols in current and future Arctic climate, Nat. Clim. Change, 11, 95–105, https://doi.org/10.1038/s41558-020-00969-5, 2021.
Schneider, E., Czech, H., Popovicheva, O., Lütdke, H., Schnelle-Kreis, J., Khodzher, T., Rüger, C. P., and Zimmermann, R.: Molecular Characterization of Water-Soluble Aerosol Particle Extracts by Ultrahigh-Resolution Mass Spectrometry: Observation of Industrial Emissions and an Atmospherically Aged Wildfire Plume at Lake Baikal, ACS Earth Space Chem., 6, 1095–1107, https://doi.org/10.1021/acsearthspacechem.2c00017, 2022.
Schnitzler, E. G., Gerrebos, N. G. A., Carter, T. S., Huang, Y., Heald, C. L., Bertram, A. K., and Abbatt, J. P. D.: Rate of atmospheric brown carbon whitening governed by environmental conditions, P. Natl. Acad. Sci. USA, 119, e2205610119, https://doi.org/10.1073/pnas.2205610119, 2022.
Semoutnikova, E. G., Gorchakov, G. I., Sitnov, S. A., Kopeikin, V. M., Karpov, A. V., Gorchakova, I. A., Ponomareva, T. Y., Isakov, A. A., Gushchin, R. A., Datsenko, O. I., Kurbatov, G. A., and Kuznetsov, G. A.: Siberian Smoke Haze over European Territory of Russia in July 2016: Atmospheric Pollution and Radiative Effects, Atmos. Oceanic Opt., 31, 171–180, https://doi.org/10.1134/S1024856018020124, 2018.
Senkan, S.: Formation of polycyclic aromatic hydrocarbons (PAH) in methane combustion: Comparative new results from premixed flames, Combust. Flame, 107, 141–150, https://doi.org/10.1016/0010-2180(96)00044-2, 1996.
Simoneit, B. R.: Biomass burning — a review of organic tracers for smoke from incomplete combustion, Appl. Geochem., 17, 129–162, https://doi.org/10.1016/S0883-2927(01)00061-0, 2002.
Simoneit, B. R. and Elias, V. O.: Organic tracers from biomass burning in atmospheric particulate matter over the ocean, Mar. Chem., 69, 301–312, https://doi.org/10.1016/S0304-4203(00)00008-6, 2000.
Simoneit, B. R. T., Rogge, W. F., Mazurek, M. A., Standley, L. J., Hildemann, L. M., and Cass, G. R.: Lignin pyrolysis products, lignans, and resin acids as specific tracers of plant classes in emissions from biomass combustion, Environ. Sci. Technol., 27, 2533–2541, https://doi.org/10.1021/es00048a034, 1993.
SkyTruth: Oil and gas flare location data, SkyTruth [data set], https://skytruth.org/ (last access: 3 April 2023), 2023.
Slavinskaya, N. A. and Frank, P.: A modelling study of aromatic soot precursors formation in laminar methane and ethene flames, Combust. Flame, 156, 1705–1722, https://doi.org/10.1016/j.combustflame.2009.04.013, 2009.
Standley, L. J. and Simoneit, B. R. T.: Resin diterpenoids as tracers for biomass combustion aerosols, J. Atmos. Chem., 18, 1–15, https://doi.org/10.1007/BF00694371, 1994.
Stein, A. F., Draxler, R. R., Rolph, G. D., Stunder, B. J. B., Cohen, M. D., and Ngan, F.: NOAA's HYSPLIT Atmospheric Transport and Dispersion Modeling System, B. Am. Meteorol. Soc., 96, 2059–2077, https://doi.org/10.1175/BAMS-D-14-00110.1, 2015.
Stohl, A., Klimont, Z., Eckhardt, S., Kupiainen, K., Shevchenko, V. P., Kopeikin, V. M., and Novigatsky, A. N.: Black carbon in the Arctic: the underestimated role of gas flaring and residential combustion emissions, Atmos. Chem. Phys., 13, 8833–8855, https://doi.org/10.5194/acp-13-8833-2013, 2013.
Streibel, T. and Zimmermann, R.: Resonance-enhanced multiphoton ionization mass spectrometry (REMPI-MS): applications for process analysis, Annu. Rev. Anal. Chem., 7, 361–381, https://doi.org/10.1146/annurev-anchem-062012-092648, 2014.
Surratt, J. D., Gómez-González, Y., Chan, A. W. H., Vermeylen, R., Shahgholi, M., Kleindienst, T. E., Edney, E. O., Offenberg, J. H., Lewandowski, M., Jaoui, M., Maenhaut, W., Claeys, M., Flagan, R. C., and Seinfeld, J. H.: Organosulfate formation in biogenic secondary organic aerosol, J. Phys. Chem. A, 112, 8345–8378, https://doi.org/10.1021/jp802310p, 2008.
Tang, J., Li, J., Su, T., Han, Y., Mo, Y., Jiang, H., Cui, M., Jiang, B., Chen, Y., Tang, J., Song, J., Peng, P., and Zhang, G.: Molecular compositions and optical properties of dissolved brown carbon in biomass burning, coal combustion, and vehicle emission aerosols illuminated by excitation–emission matrix spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry analysis, Atmos. Chem. Phys., 20, 2513–2532, https://doi.org/10.5194/acp-20-2513-2020, 2020.
Tomshin, O. A. and Solovyev, V. S.: Detection of burnt areas in Yakutia on long-term NOAA satellites data (1985–2015), Proceedings Volume 10833, 24th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, 108338B, 288, https://doi.org/10.1117/12.2504569, 2018.
Torres, O. O.: OMPS-NPP L2 NM Aerosol Index swath orbital, NASA [data set], https://doi.org/10.5067/40L92G8144IV, 2019.
Vandergrift, G. W., Shawon, A. S. M., Dexheimer, D. N., Zawadowicz, M. A., Mei, F., and China, S.: Molecular Characterization of Organosulfate-Dominated Aerosols over Agricultural Fields from the Southern Great Plains by High-Resolution Mass Spectrometry, ACS Earth Space Chem., 6, 1733–1741, https://doi.org/10.1021/acsearthspacechem.2c00043, 2022.
Wang, X. K., Rossignol, S., Ma, Y., Yao, L., Wang, M. Y., Chen, J. M., George, C., and Wang, L.: Molecular characterization of atmospheric particulate organosulfates in three megacities at the middle and lower reaches of the Yangtze River, Atmos. Chem. Phys., 16, 2285–2298, https://doi.org/10.5194/acp-16-2285-2016, 2016.
Watson, J. G. and Chow, J. C.: Comparison and evaluation of in situ and filter carbon measurements at the Fresno Supersite, Geophys. Res. Atmos., 107, ICC 3-1–ICC 3-15, https://doi.org/10.1029/2001JD000573, 2002.
Yasunari, T. J., Nakamura, H., Kim, K.-M., Choi, N., Lee, M.-I., Tachibana, Y., and Da Silva, A. M.: Relationship between circum-Arctic atmospheric wave patterns and large-scale wildfires in boreal summer, Environ. Res. Lett., 16, 64009, https://doi.org/10.1088/1748-9326/abf7ef, 2021.
Ye, Y., Zhan, H., Yu, X., Li, J., Wang, X., and Xie, Z.: Detection of organosulfates and nitrooxy-organosulfates in Arctic and Antarctic atmospheric aerosols, using ultra-high resolution FT-ICR mass spectrometry, Sci. Total Environ., 767, 144339, https://doi.org/10.1016/j.scitotenv.2020.144339, 2021.
Yokelson, R. J., Griffith, D. W. T., and Ward, D. E.: Open-path Fourier transform infrared studies of large-scale laboratory biomass fires, Geophys. Res. Atmos., 101, 21067–21080, https://doi.org/10.1029/96JD01800, 1996.
Yue, S., Zhu, J., Chen, S., Xie, Q., Li, W., Li, L., Ren, H., Su, S., Li, P., Ma, H., Fan, Y., Cheng, B., Wu, L., Deng, J., Hu, W., Ren, L., Wei, L., Zhao, W., Tian, Y., Pan, X., Sun, Y., Wang, Z., Wu, F., Liu, C.-Q., Su, H., Penner, J. E., Pöschl, U., Andreae, M. O., Cheng, Y., and Fu, P.: Brown carbon from biomass burning imposes strong circum-Arctic warming, One Earth, 5, 293–304, https://doi.org/10.1016/j.oneear.2022.02.006, 2022.
Yunker, M. B., Macdonald, R. W., Vingarzan, R., Mitchell, R. H., Goyette, D., and Sylvestre, S.: PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition, Org. Geochem., 33, 489–515, https://doi.org/10.1016/S0146-6380(02)00002-5, 2002.
Zhang, M., Marandino, C. A., Yan, J., Lin, Q., Park, K., and Xu, G.: DMS sea-to-air fluxes and their influence on sulfate aerosols over the Southern Ocean, south-east Indian Ocean and north-west Pacific Ocean, Environ. Chem., 18, 193, https://doi.org/10.1071/EN21003, 2021.
Zhang, T., Mu, G., Zhang, S., and Hou, J.: Formation pathways of polycyclic aromatic hydrocarbons (PAHs) in butane or butadiene flames, RSC Adv., 11, 5629–5642, https://doi.org/10.1039/D0RA08744K, 2021.
Zhang, Y., Wang, K., Tong, H., Huang, R.-J., and Hoffmann, T.: The maximum carbonyl ratio (MCR) as a new index for the structural classification of secondary organic aerosol components, Rapid Commun. Mass Sp., 35, e9113, https://doi.org/10.1002/rcm.9113, 2021.
Short summary
This study provides insights into the complex chemical composition of long-range-transported wildfire plumes from Yakutia, which underwent different levels of atmospheric processing. With complementary mass spectrometric techniques, we improve our understanding of the chemical processes and atmospheric fate of wildfire plumes. Unprecedented high levels of carbonaceous aerosols crossed the polar circle with implications for the Arctic ecosystem and consequently climate.
This study provides insights into the complex chemical composition of long-range-transported...
Altmetrics
Final-revised paper
Preprint