Articles | Volume 24, issue 7
https://doi.org/10.5194/acp-24-3989-2024
https://doi.org/10.5194/acp-24-3989-2024
Research article
 | 
03 Apr 2024
Research article |  | 03 Apr 2024

Molecular-level study on the role of methanesulfonic acid in iodine oxoacid nucleation

Jing Li, Nan Wu, Biwu Chu, An Ning, and Xiuhui Zhang

Related authors

Investigating the contribution of grown new particles to cloud condensation nuclei with largely varying preexisting particles – Part 2: Modeling chemical drivers and 3-D new particle formation occurrence
Ming Chu, Xing Wei, Shangfei Hai, Yang Gao, Huiwang Gao, Yujiao Zhu, Biwu Chu, Nan Ma, Juan Hong, Yele Sun, and Xiaohong Yao
Atmos. Chem. Phys., 24, 6769–6786, https://doi.org/10.5194/acp-24-6769-2024,https://doi.org/10.5194/acp-24-6769-2024, 2024
Short summary
Rapid iodine oxoacid nucleation enhanced by dimethylamine in broad marine regions
Haotian Zu, Biwu Chu, Yiqun Lu, Ling Liu, and Xiuhui Zhang
Atmos. Chem. Phys., 24, 5823–5835, https://doi.org/10.5194/acp-24-5823-2024,https://doi.org/10.5194/acp-24-5823-2024, 2024
Short summary
Cluster Dynamics-based Parameterization for Sulfuric Acid-Dimethylamine Nucleation: Comparison and Selection through Box- and Three-Dimensional- Modeling
Jiewen Shen, Bin Zhao, Shuxiao Wang, An Ning, Yuyang Li, Runlong Cai, Da Gao, Biwu Chu, Yang Gao, Manish Shrivastava, Jingkun Jiang, Xiuhui Zhang, and Hong He
EGUsphere, https://doi.org/10.5194/egusphere-2024-642,https://doi.org/10.5194/egusphere-2024-642, 2024
Short summary
A study on the influence of inorganic ions, organic carbon and microstructure on the hygroscopic property of soot
Zhanyu Su, Lanxiadi Chen, Yuan Liu, Peng Zhang, Tianzeng Chen, Biwu Chu, Mingjin Tang, Qingxin Ma, and Hong He
Atmos. Chem. Phys., 24, 993–1003, https://doi.org/10.5194/acp-24-993-2024,https://doi.org/10.5194/acp-24-993-2024, 2024
Short summary
The effect of COVID-19 restrictions on atmospheric new particle formation in Beijing
Chao Yan, Yicheng Shen, Dominik Stolzenburg, Lubna Dada, Ximeng Qi, Simo Hakala, Anu-Maija Sundström, Yishuo Guo, Antti Lipponen, Tom V. Kokkonen, Jenni Kontkanen, Runlong Cai, Jing Cai, Tommy Chan, Liangduo Chen, Biwu Chu, Chenjuan Deng, Wei Du, Xiaolong Fan, Xu-Cheng He, Juha Kangasluoma, Joni Kujansuu, Mona Kurppa, Chang Li, Yiran Li, Zhuohui Lin, Yiliang Liu, Yuliang Liu, Yiqun Lu, Wei Nie, Jouni Pulliainen, Xiaohui Qiao, Yonghong Wang, Yifan Wen, Ye Wu, Gan Yang, Lei Yao, Rujing Yin, Gen Zhang, Shaojun Zhang, Feixue Zheng, Ying Zhou, Antti Arola, Johanna Tamminen, Pauli Paasonen, Yele Sun, Lin Wang, Neil M. Donahue, Yongchun Liu, Federico Bianchi, Kaspar R. Daellenbach, Douglas R. Worsnop, Veli-Matti Kerminen, Tuukka Petäjä, Aijun Ding, Jingkun Jiang, and Markku Kulmala
Atmos. Chem. Phys., 22, 12207–12220, https://doi.org/10.5194/acp-22-12207-2022,https://doi.org/10.5194/acp-22-12207-2022, 2022
Short summary

Related subject area

Subject: Aerosols | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Role of atmospheric aerosols in severe winter fog over the Indo-Gangetic Plain of India: a case study
Chandrakala Bharali, Mary Barth, Rajesh Kumar, Sachin D. Ghude, Vinayak Sinha, and Baerbel Sinha
Atmos. Chem. Phys., 24, 6635–6662, https://doi.org/10.5194/acp-24-6635-2024,https://doi.org/10.5194/acp-24-6635-2024, 2024
Short summary
Long-term variability in black carbon emissions constrained by gap-filled absorption aerosol optical depth and associated premature mortality in China
Wenxin Zhao, Yu Zhao, Yu Zheng, Dong Chen, Jinyuan Xin, Kaitao Li, Huizheng Che, Zhengqiang Li, Mingrui Ma, and Yun Hang
Atmos. Chem. Phys., 24, 6593–6612, https://doi.org/10.5194/acp-24-6593-2024,https://doi.org/10.5194/acp-24-6593-2024, 2024
Short summary
Intercomparison of aerosol optical depths from four reanalyses and their multi-reanalysis consensus
Peng Xian, Jeffrey S. Reid, Melanie Ades, Angela Benedetti, Peter R. Colarco, Arlindo da Silva, Tom F. Eck, Johannes Flemming, Edward J. Hyer, Zak Kipling, Samuel Rémy, Tsuyoshi Thomas Sekiyama, Taichu Tanaka, Keiya Yumimoto, and Jianglong Zhang
Atmos. Chem. Phys., 24, 6385–6411, https://doi.org/10.5194/acp-24-6385-2024,https://doi.org/10.5194/acp-24-6385-2024, 2024
Short summary
Global aviation contrail climate effects from 2019 to 2021
Roger Teoh, Zebediah Engberg, Ulrich Schumann, Christiane Voigt, Marc Shapiro, Susanne Rohs, and Marc E. J. Stettler
Atmos. Chem. Phys., 24, 6071–6093, https://doi.org/10.5194/acp-24-6071-2024,https://doi.org/10.5194/acp-24-6071-2024, 2024
Short summary
Rapid iodine oxoacid nucleation enhanced by dimethylamine in broad marine regions
Haotian Zu, Biwu Chu, Yiqun Lu, Ling Liu, and Xiuhui Zhang
Atmos. Chem. Phys., 24, 5823–5835, https://doi.org/10.5194/acp-24-5823-2024,https://doi.org/10.5194/acp-24-5823-2024, 2024
Short summary

Cited articles

Ahlrichs, R., Bär, M., Häser, M., Horn, H., and Kölmel, C.: Electronic structure calculations on workstation computers: The program system turbomole, Chem. Phys. Lett., 162, 165–169, https://doi.org/10.1016/0009-2614(89)85118-8, 1989. 
Baccarini, A., Karlsson, L., Dommen, J., Duplessis, P., Vullers, J., Brooks, I. M., Saiz-Lopez, A., Salter, M., Tjernstrom, M., Baltensperger, U., Zieger, P., and Schmale, J.: Frequent new particle formation over the high Arctic pack ice by enhanced iodine emissions, Nat. Commun., 11, 4924, https://doi.org/10.1038/s41467-020-18551-0, 2020. 
Berresheim, H., Elste, T., Rosman, K., Dal Maso, M., Tremmel, H. G., Mäkelä, J. M., Allen, A. G., Kulmala, M., and Hansson, H.-C.: Gas-aerosol relationships of H2SO4, MSA, and OH: Observations in the coastal marine boundary layer at Mace Head, Ireland, J. Geophys. Res.-Atmos., 107, PAR 5-1–PAR 5-12, https://doi.org/10.1029/2000jd000229, 2002. 
Download
Short summary
Iodic acid (HIO3) nucleates with iodous acid (HIO2) efficiently in marine areas; however, whether methanesulfonic acid (MSA) can synergistically participate in the HIO3–HIO2-based nucleation is unclear. We provide molecular-level evidence that MSA can efficiently promote the formation of HIO3–HIO2-based clusters using a theoretical approach. The proposed MSA-enhanced iodine nucleation mechanism may help us to deeply understand marine new particle formation events with bursts of iodine particles.
Altmetrics
Final-revised paper
Preprint