Articles | Volume 24, issue 4
https://doi.org/10.5194/acp-24-2491-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-2491-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
27 Feb 2024
Research article |
| 27 Feb 2024
| 27 Feb 2024
Influences of sources and weather dynamics on atmospheric deposition of Se species and other trace elements
Esther S. Breuninger
CORRESPONDING AUTHOR
Eawag, Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, 8600 Dübendorf, Switzerland
Institute of Biogeochemistry and Pollutant Dynamics, ETH Zurich, 8092 Zurich, Switzerland
Julie Tolu
CORRESPONDING AUTHOR
Eawag, Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, 8600 Dübendorf, Switzerland
Institute of Biogeochemistry and Pollutant Dynamics, ETH Zurich, 8092 Zurich, Switzerland
Iris Thurnherr
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
Franziska Aemisegger
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
Aryeh Feinberg
Institute for Data, Systems, and Society, Massachusetts Institute of Technology, Cambridge, MA 02142, USA
Sylvain Bouchet
Eawag, Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, 8600 Dübendorf, Switzerland
Institute of Biogeochemistry and Pollutant Dynamics, ETH Zurich, 8092 Zurich, Switzerland
Jeroen E. Sonke
Géosciences Environnement Toulouse, CNRS, IRD, Université de Toulouse, 31400 Toulouse, France
Véronique Pont
LAERO, Université de Toulouse, CNRS, IRD, UT3, 31400 Toulouse, France
Heini Wernli
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
Lenny H. E. Winkel
CORRESPONDING AUTHOR
Eawag, Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, 8600 Dübendorf, Switzerland
Institute of Biogeochemistry and Pollutant Dynamics, ETH Zurich, 8092 Zurich, Switzerland
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EGUsphere, https://doi.org/10.5194/egusphere-2026-1522, https://doi.org/10.5194/egusphere-2026-1522, 2026
This preprint is open for discussion and under review for Weather and Climate Dynamics (WCD).
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We systematically investigate vertical temperature anomaly profiles during heat extremes on a global scale. Three distinct clusters emerge, aligning closely with the polar, mid-latitude, and tropical climate zones and capturing the key characteristics of the vertical profiles. While mid-latitude and polar profiles feature anomalies throughout the troposphere, with the highest temperature anomalies in the boundary layer, tropical temperature anomalies are confined to the boundary layer.
Tuule Müürsepp, Michael Sprenger, Heini Wernli, and Hanna Joos
Weather Clim. Dynam., 7, 547–565, https://doi.org/10.5194/wcd-7-547-2026, https://doi.org/10.5194/wcd-7-547-2026, 2026
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The tropopause region of the atmosphere is greatly impacted by the exchange of mass and constituents between the troposphere and the stratosphere. This study quantifies the role of radiation in troposphere-to-stratosphere transport using reanalysis data. We find that radiation contributes to this transport most of the time, albeit it might not be the dominant process. We provide a new insight into the complex interplay of processes that air parcels experience on their way to the stratosphere.
Jize Jiang, Lenny H. E. Winkel, Chloé Wüst-Galley, Daniel Bretscher, Magdalena Necpalova, Andrea Stenke, and Johan Six
EGUsphere, https://doi.org/10.5194/egusphere-2026-1287, https://doi.org/10.5194/egusphere-2026-1287, 2026
This preprint is open for discussion and under review for Biogeosciences (BG).
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We studied nitrogen use in Swiss agriculture for four decades using detailed data and modelling. We found that nitrogen use efficiency improved, while nitrogen losses decreased. Yet, modelling results suggested that cropland soils may lose nitrogen. The results show that policies implementation benefited productivity and reduced pollution. On the other hand, soil nitrogen balance should also be monitored, underscoring the need for integrated nitrogen management.
Nora Zilibotti, Heini Wernli, and Sebastian Schemm
Weather Clim. Dynam., 7, 201–221, https://doi.org/10.5194/wcd-7-201-2026, https://doi.org/10.5194/wcd-7-201-2026, 2026
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This study investigates the relationship between jet strength and storm track activity in the North Pacific and North Atlantic with a new approach that does not rely on monthly averaging. We find a consistent behaviour in the two basins, with two distinct relationships on seasonal and sub-monthly timescales emerging. This work underlines the importance of separating different timescales of variability to understand the interplay of jet characteristics and storm track activity.
Katharina Hartmuth, Dominik Büeler, and Heini Wernli
Weather Clim. Dynam., 7, 129–148, https://doi.org/10.5194/wcd-7-129-2026, https://doi.org/10.5194/wcd-7-129-2026, 2026
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This study presents three case studies of applying a newly developed method to quantify the uncertainty of the operational ensemble from the European Centre for Medium-Range Weather Forecasts in forecasting precipitation and wind extremes associated with Mediterranean cyclones. We find that the cyclones as well as their associated extremes are predicted well for lead times ≤ 48 h; however, for longer lead times there is large case-to-case variability in the ensemble performance.
Jacopo Riboldi, Robin Noyelle, Ellina Agayar, Hanin Binder, Marc Federer, Katharina Hartmuth, Michael Sprenger, Iris Thurnherr, and Selvakumar Vishnupriya
Weather Clim. Dynam., 7, 65–87, https://doi.org/10.5194/wcd-7-65-2026, https://doi.org/10.5194/wcd-7-65-2026, 2026
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Storm Boris led to record-breaking precipitation over central Europe in September 2024. By incorporating event-specific meteorological information, this work introduces a methodology to strengthen our comprehension of how global warming affects similar hazards. Furthermore, it contextualizes how the answer to the question "How will Boris-like storms change in a warmer climate?" depends on explicit and implicit methodological choices, with the aim to inform future attribution research.
Ellina Agayar, Moshe Armon, Michael Sprenger, and Heini Wernli
EGUsphere, https://doi.org/10.5194/egusphere-2025-5942, https://doi.org/10.5194/egusphere-2025-5942, 2025
This preprint is open for discussion and under review for Natural Hazards and Earth System Sciences (NHESS).
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This study examines the hydrometeorological features of the major floods of 2008, 2010, and 2020 in western Ukraine. All cases were linked to upper-level PV anomalies. We also conducted a climatological analysis of PV structure associated with 22 summer heavy precipitation cases (2000–2022), highlighting their key role in determining the location and intensity of flood-inducing rainfall events in the Carpathians.
Emmanouil Flaounas, Stavros Dafis, Silvio Davolio, Davide Faranda, Christian Ferrarin, Katharina Hartmuth, Assaf Hochman, Aristeidis Koutroulis, Samira Khodayar, Mario Marcello Miglietta, Florian Pantillon, Platon Patlakas, Michael Sprenger, and Iris Thurnherr
Weather Clim. Dynam., 6, 1515–1538, https://doi.org/10.5194/wcd-6-1515-2025, https://doi.org/10.5194/wcd-6-1515-2025, 2025
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Storm Daniel (2023) is one of the most catastrophic storms ever documented in the Mediterranean. Our results highlight the different dynamics and therefore the different predictability skill of precipitation, its extremes and impacts that have been produced in Greece and Libya, the two most affected countries. Our approach concerns an analysis of the storm by articulating dynamics, weather prediction, hydrological and oceanographic implications, climate extremes, and attribution theory.
Alena Dekhtyareva, Harald Sodemann, Tim Carlsen, Iris Thurnherr, Aina Johannessen, Andrew Seidl, David M. Chandler, Daniele Zannoni, Alexandra Touzeau, Marvin Kähnert, Astrid B. Gjelsvik, Franziska Hellmuth, Britta Schäfer, and Robert O. David
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-548, https://doi.org/10.5194/essd-2025-548, 2025
Revised manuscript accepted for ESSD
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During a recent field campaign from 15 to 30 March 2021 at Andenes, Norway, we collected a set of observations that allows to better constrain how clouds and precipitation processes work. Frequent alternations between mid-latitude and arctic weather systems were encountered during the campaign. Our dataset is unique in combining measurements in both vapour and precipitation, aerosols, ice nucleating particles, and was made simultaneously at different elevations at a high latitude location.
Franziska Schnyder, Ming Hon Franco Lee, and Heini Wernli
Weather Clim. Dynam., 6, 1319–1337, https://doi.org/10.5194/wcd-6-1319-2025, https://doi.org/10.5194/wcd-6-1319-2025, 2025
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In this study, we investigate a particularly long-lived example of a Siberian summer cyclone, which originates during a heat wave in Kazakhstan in July 2021 and propagates into the Arctic, where it leads to heavy precipitation and alters the Arctic tropopause. Although a rare event in current climate, this case reveals how compounding events may be linked by one weather system and portrays a type of cyclone event which is likely to become more frequent in a warmer climate.
Matthias Röthlisberger, Michael Sprenger, Urs Beyerle, Erich M. Fischer, and Heini Wernli
EGUsphere, https://doi.org/10.5194/egusphere-2025-5146, https://doi.org/10.5194/egusphere-2025-5146, 2025
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This study investigates yearly heat extremes simulated with the global climate model CESM2. A trajectory-based method is used, which allows quantifying the contributions to temperature anomalies from advection, subsidence, and diabatic heating. The results show that the magnitude of CESM2 heat extremes agrees fairly well with ERA5 reanalyses, but it is often “right for the partly wrong physical reasons”.
Selvakumar Vishnupriya, Michael Sprenger, Hanna Joos, and Heini Wernli
Weather Clim. Dynam., 6, 1195–1219, https://doi.org/10.5194/wcd-6-1195-2025, https://doi.org/10.5194/wcd-6-1195-2025, 2025
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Extratropical cyclones feature rapidly ascending airstreams known as warm conveyor belts, which could influence upper-level flow dynamics. This study classifies interactions between warm conveyor belt outflows and the jet stream into four types: no interactions, ridges, blocks, and tropospheric cutoffs. We use reanalysis data to demonstrate that the interaction type depends on the structure of the ambient flow than on the outflow, improving our understanding of extratropical flow variability.
Excellent O. Eboigbe, Nimelan Veerasamy, Abiodun M. Odukoya, Nnamdi C. Anene, Jeroen E. Sonke, Sayuri Sagisaka Méndez, and David S. McLagan
Biogeosciences, 22, 5591–5605, https://doi.org/10.5194/bg-22-5591-2025, https://doi.org/10.5194/bg-22-5591-2025, 2025
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Air, soil, and three common staple crops were assessed at an artisanal and small-scale gold mining (ASGM) processing site, and mercury (Hg) contamination was observed at a farm ≈ 500 m from the processing site. Of the crop tissues examined, foliage had the highest concentrations. Mercury stable isotopes indicate uptake of mercury from the air to the foliage as the dominant uptake pathway. Using typical dietary data for Nigerians, Hg intake from these crops was below reference dose levels and generally safe for consumption.
Rafael Pedro Fernandez, Carlos Alberto Cuevas, Julián Villamayor, Aryeh Feinberg, Douglas E. Kinnison, Francis Vitt, Adriana Bossolasco, Javier A. Barrera, Amelia Reynoso, Orlando G. Tomazzeli, Qinyi Li, and Alfonso Saiz-Lopez
EGUsphere, https://doi.org/10.5194/egusphere-2025-3250, https://doi.org/10.5194/egusphere-2025-3250, 2025
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In this work we summarize 15 years of research and developments of short-lived halogens (SLH) using the Community Earth System Model (CESM) and present a complete description of the implementation and capabilities achieved with the new released version CESM2-SLH, including specific namelist options, input files and technical notes detailing the most important SLH updates that must be considered for the different model configurations and resolutions.
Killian P. Brennan, Iris Thurnherr, Michael Sprenger, and Heini Wernli
Nat. Hazards Earth Syst. Sci., 25, 3693–3712, https://doi.org/10.5194/nhess-25-3693-2025, https://doi.org/10.5194/nhess-25-3693-2025, 2025
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Hailstorms can cause severe damage to homes, crops, and infrastructure. Using high-resolution climate simulations, we tracked thousands of hailstorms across Europe to study future changes. Large hail will become more frequent, hail-covered areas will expand, and instances of extreme hail combined with heavy rain will double. These shifts could increase risks for communities and businesses, highlighting the need for better preparedness and adaptation.
Théo Segur and Jeroen E. Sonke
Biogeosciences, 22, 5139–5156, https://doi.org/10.5194/bg-22-5139-2025, https://doi.org/10.5194/bg-22-5139-2025, 2025
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Our paper provides a quantification of plastic pollution in the Mediterranean region and several policy scenario projections based on OECD (Organisation for Economic Co-operation and Development) data toward 2100. We estimate a 4-fold increase in Mediterranean marine plastic stock by 2060 and that the implementation of terrestrial plastic cleanup can significantly help to reduce plastic pollution transfer from land to sea. Our results provide insight for policymakers, which is needed at the regional scale in the context of the UNEP (United Nations Environment Programme) plastic treaty.
Luise J. Fischer, David N. Bresch, Dominik Büeler, Christian M. Grams, Robin Noyelle, Matthias Röthlisberger, and Heini Wernli
Weather Clim. Dynam., 6, 1027–1043, https://doi.org/10.5194/wcd-6-1027-2025, https://doi.org/10.5194/wcd-6-1027-2025, 2025
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Atmospheric flows over the North Atlantic can be meaningfully classified into weather regimes, and climate simulations suggest that the regime frequencies might change in the future. We provide a quantitative framework that helps assess whether these regime frequency changes are relevant to understanding climate change signals in precipitation. At least in our example application, in most regions, regime frequency changes explain little of the projected precipitation changes.
Charikleia Gournia, Noelle E. Selin, and Aryeh Feinberg
EGUsphere, https://doi.org/10.5194/egusphere-2025-4018, https://doi.org/10.5194/egusphere-2025-4018, 2025
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Human activities release mercury into the air, but current estimates of these emissions vary widely. Our study examines how the uncertainty in global anthropogenic mercury emission estimates impacts the model’s ability to reproduce observations. We found that differences in emissions inventories significantly change results, especially in Asia. The work highlights where increased monitoring is needed to improve estimates and better inform global mercury reduction policies.
Guangyi Su, Julie Tolu, Clemens Glombitza, Jakob Zopfi, Moritz F. Lehmann, Mark A. Lever, and Carsten J. Schubert
Biogeosciences, 22, 4449–4466, https://doi.org/10.5194/bg-22-4449-2025, https://doi.org/10.5194/bg-22-4449-2025, 2025
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In Lake Geneva, we studied how different types of organic matter affect methane production. Despite varying sources, like algae and land-based materials, both deep and delta areas are significant methane sources, and methane was mainly produced through CO2 reduction. Surprisingly, the origin of organic matter did not strongly influence methane production rates or pathways. Our findings highlight the need to better understand microbial processes to predict methane emissions from lakes.
Daniele Zannoni, Hans Christian Steen-Larsen, Harald Sodemann, Iris Thurnherr, Cyrille Flamant, Patrick Chazette, Julien Totems, Martin Werner, and Myriam Raybaut
Atmos. Chem. Phys., 25, 9471–9495, https://doi.org/10.5194/acp-25-9471-2025, https://doi.org/10.5194/acp-25-9471-2025, 2025
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High-resolution airborne observations reveal that mixing between the free troposphere and surface evapotranspiration flux primarily modulates the water vapor isotopic composition in the lower troposphere. Water vapor isotope structure variations occur on the scale of hundreds of meters, underlining the utility of stable isotopes for studying microscale atmospheric dynamics. This study also provides the basis for better validation of water vapor isotope remote sensing retrievals with surface observations.
Guangyu Li, André Welti, Iris Thurnherr, Ulrike Lohmann, and Zamin A. Kanji
EGUsphere, https://doi.org/10.5194/egusphere-2025-2798, https://doi.org/10.5194/egusphere-2025-2798, 2025
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This study presents ship-based measurements of summertime ice-nucleating particles (INPs) over the data-scarce Eurasian-Arctic Seas. We found that INPs are driven by both local and regional sources, with the highest levels observed near land and over ice-free waters. This study is highlighted for improving the understanding of INP abundance, sources, and their role in cloud processes in the rapidly warming Arctic.
Killian P. Brennan, Michael Sprenger, André Walser, Marco Arpagaus, and Heini Wernli
Weather Clim. Dynam., 6, 645–668, https://doi.org/10.5194/wcd-6-645-2025, https://doi.org/10.5194/wcd-6-645-2025, 2025
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We studied severe hailstorms that occurred in Switzerland on 28 June 2021 using a weather prediction model to understand how they evolved. We found that the storms moved toward areas with more storm energy. Hailfall was quickly followed by heavy rain. Just before the storms died out, the air feeding them stopped coming from near the ground. We also observed a delay between different types of precipitation forming in the incoming air.
Ashu Dastoor, Hélène Angot, Johannes Bieser, Flora Brocza, Brock Edwards, Aryeh Feinberg, Xinbin Feng, Benjamin Geyman, Charikleia Gournia, Yipeng He, Ian M. Hedgecock, Ilia Ilyin, Jane Kirk, Che-Jen Lin, Igor Lehnherr, Robert Mason, David McLagan, Marilena Muntean, Peter Rafaj, Eric M. Roy, Andrei Ryjkov, Noelle E. Selin, Francesco De Simone, Anne L. Soerensen, Frits Steenhuisen, Oleg Travnikov, Shuxiao Wang, Xun Wang, Simon Wilson, Rosa Wu, Qingru Wu, Yanxu Zhang, Jun Zhou, Wei Zhu, and Scott Zolkos
Geosci. Model Dev., 18, 2747–2860, https://doi.org/10.5194/gmd-18-2747-2025, https://doi.org/10.5194/gmd-18-2747-2025, 2025
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This paper introduces the Multi-Compartment Mercury (Hg) Modeling and Analysis Project (MCHgMAP) aimed at informing the effectiveness evaluations of two multilateral environmental agreements: the Minamata Convention on Mercury and the Convention on Long-Range Transboundary Air Pollution. The experimental design exploits a variety of models (atmospheric, land, oceanic ,and multimedia mass balance models) to assess the short- and long-term influences of anthropogenic Hg releases into the environment.
Katharina Hartmuth, Heini Wernli, and Lukas Papritz
Weather Clim. Dynam., 6, 505–520, https://doi.org/10.5194/wcd-6-505-2025, https://doi.org/10.5194/wcd-6-505-2025, 2025
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In this study, we use large-ensemble climate model simulations to analyze extreme winters in the Barents Sea in a changing climate. We find that variability in both atmospheric processes and sea ice conditions determines the formation of such seasons in the present-day climate. The reduction in sea ice variability results in a decreasing importance of surface boundary conditions in a warmer climate, while the robust link shown for surface weather systems persists.
Nicolai Krieger, Heini Wernli, Michael Sprenger, and Christian Kühnlein
Weather Clim. Dynam., 6, 447–469, https://doi.org/10.5194/wcd-6-447-2025, https://doi.org/10.5194/wcd-6-447-2025, 2025
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This study investigates the Laseyer, a local windstorm in a narrow Swiss valley characterized by strong southeasterly winds during northwesterly ambient flow. Using large-eddy simulations (LESs) with 30 m grid spacing, this is the first study to reveal that the extreme gusts in the valley are caused by an amplifying interplay of two recirculation regions. Modifying terrain and ambient wind conditions affects the windstorm's intensity and highlights the importance of topographic details in LES.
Joëlle C. Rieder, Franziska Aemisegger, Elad Dente, and Moshe Armon
Hydrol. Earth Syst. Sci., 29, 1395–1427, https://doi.org/10.5194/hess-29-1395-2025, https://doi.org/10.5194/hess-29-1395-2025, 2025
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The Sahara was wetter in the past and may become wetter in the future. Lake remnants are evidence of the desert’s wetter past. If the Sahara gets wetter in the future, these lakes may serve as a water resource. However, it is unclear how these lakes get filled and how moisture is carried into the desert and converted into rain in the first place. Therefore, we examine processes currently leading to the filling of a dry lake in the Sahara, which can help assess future water availability.
Hanin Binder and Heini Wernli
Weather Clim. Dynam., 6, 151–170, https://doi.org/10.5194/wcd-6-151-2025, https://doi.org/10.5194/wcd-6-151-2025, 2025
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This study presents a systematic analysis of frequency anomalies and characteristics of extratropical cyclones during extremely wet, dry, windy, and calm winter and summer seasons in the extratropics based on 1050 years of present-day climate simulations. We show that anomalies in cyclone frequency, intensity, and stationarity are crucial to the occurrence of many extreme seasons and that these anomaly patterns exhibit substantial regional and seasonal variability.
Stefano Ubbiali, Christian Kühnlein, Christoph Schär, Linda Schlemmer, Thomas C. Schulthess, Michael Staneker, and Heini Wernli
Geosci. Model Dev., 18, 529–546, https://doi.org/10.5194/gmd-18-529-2025, https://doi.org/10.5194/gmd-18-529-2025, 2025
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We explore a high-level programming model for porting numerical weather prediction (NWP) model codes to graphics processing units (GPUs). We present a Python rewrite with the domain-specific library GT4Py (GridTools for Python) of two renowned cloud microphysics schemes and the associated tangent-linear and adjoint algorithms. We find excellent portability, competitive GPU performance, robust execution on diverse computing architectures, and enhanced code maintainability and user productivity.
Stephanie Mayer, Martin Hendrick, Adrien Michel, Bettina Richter, Jürg Schweizer, Heini Wernli, and Alec van Herwijnen
The Cryosphere, 18, 5495–5517, https://doi.org/10.5194/tc-18-5495-2024, https://doi.org/10.5194/tc-18-5495-2024, 2024
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Understanding the impact of climate change on snow avalanche activity is crucial for safeguarding lives and infrastructure. Here, we project changes in avalanche activity in the Swiss Alps throughout the 21st century. Our findings reveal elevation-dependent patterns of change, indicating a decrease in dry-snow avalanches alongside an increase in wet-snow avalanches at elevations above the current treeline. These results underscore the necessity to revisit measures for avalanche risk mitigation.
Sandro Vattioni, Rahel Weber, Aryeh Feinberg, Andrea Stenke, John A. Dykema, Beiping Luo, Georgios A. Kelesidis, Christian A. Bruun, Timofei Sukhodolov, Frank N. Keutsch, Thomas Peter, and Gabriel Chiodo
Geosci. Model Dev., 17, 7767–7793, https://doi.org/10.5194/gmd-17-7767-2024, https://doi.org/10.5194/gmd-17-7767-2024, 2024
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We quantified impacts and efficiency of stratospheric solar climate intervention via solid particle injection. Microphysical interactions of solid particles with the sulfur cycle were interactively coupled to the heterogeneous chemistry scheme and the radiative transfer code of an aerosol–chemistry–climate model. Compared to injection of SO2 we only find a stronger cooling efficiency for solid particles when normalizing to the aerosol load but not when normalizing to the injection rate.
Marie Lothon, François Gheusi, Fabienne Lohou, Véronique Pont, Serge Soula, Corinne Jambert, Solène Derrien, Yannick Bezombes, Emmanuel Leclerc, Gilles Athier, Antoine Vial, Alban Philibert, Bernard Campistron, Frédérique Saïd, Jeroen Sonke, Julien Amestoy, Erwan Bargain, Pierre Bosser, Damien Boulanger, Guillaume Bret, Renaud Bodichon, Laurent Cabanas, Guylaine Canut, Jean-Bernard Estrampes, Eric Gardrat, Zaida Gomez Kuri, Jérémy Gueffier, Fabienne Guesdon, Morgan Lopez, Olivier Masson, Pierre-Yves Meslin, Yves Meyerfeld, Nicolas Pascal, Eric Pique, Michel Ramonet, Felix Starck, and Romain Vidal
Atmos. Meas. Tech., 17, 6265–6300, https://doi.org/10.5194/amt-17-6265-2024, https://doi.org/10.5194/amt-17-6265-2024, 2024
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The Pyrenean Platform for Observation of the Atmosphere (P2OA) is a coupled plain–mountain instrumented platform in southwestern France for the monitoring of climate variables and the study of meteorological processes in a mountainous region. A comprehensive description of this platform is presented for the first time: its instrumentation, the associated dataset, and a meteorological characterization the site. The potential of the P2OA is illustrated through several examples of process studies.
Heini Wernli and Suzanne L. Gray
Weather Clim. Dynam., 5, 1299–1408, https://doi.org/10.5194/wcd-5-1299-2024, https://doi.org/10.5194/wcd-5-1299-2024, 2024
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The science of extratropical dynamics has reached a new level where the interplay of dry dynamics with effects of latent heating in clouds and other diabatic processes is considered central to the field. This review documents how research about the role of diabatic processes evolved over more than a century; it highlights that progress relied essentially on the integration of theory, field campaigns, novel diagnostics, and numerical modelling, and it outlines avenues for future research.
Sonja Wahl, Benjamin Walter, Franziska Aemisegger, Luca Bianchi, and Michael Lehning
The Cryosphere, 18, 4493–4515, https://doi.org/10.5194/tc-18-4493-2024, https://doi.org/10.5194/tc-18-4493-2024, 2024
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Wind-driven airborne transport of snow is a frequent phenomenon in snow-covered regions and a process difficult to study in the field as it is unfolding over large distances. Thus, we use a ring wind tunnel with infinite fetch positioned in a cold laboratory to study the evolution of the shape and size of airborne snow. With the help of stable water isotope analyses, we identify the hitherto unobserved process of airborne snow metamorphism that leads to snow particle rounding and growth.
Ellina Agayar, Franziska Aemisegger, Moshe Armon, Alexander Scherrmann, and Heini Wernli
Nat. Hazards Earth Syst. Sci., 24, 2441–2459, https://doi.org/10.5194/nhess-24-2441-2024, https://doi.org/10.5194/nhess-24-2441-2024, 2024
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This study presents the results of a climatological investigation of extreme precipitation events (EPEs) in Ukraine for the period 1979–2019. During all seasons EPEs are associated with pronounced upper-level potential vorticity (PV) anomalies. In addition, we find distinct seasonal and regional differences in moisture sources. Several extreme precipitation cases demonstrate the importance of these processes, complemented by a detailed synoptic analysis.
Sarah Tinorua, Cyrielle Denjean, Pierre Nabat, Véronique Pont, Mathilde Arnaud, Thierry Bourrianne, Maria Dias Alves, and Eric Gardrat
Atmos. Meas. Tech., 17, 3897–3915, https://doi.org/10.5194/amt-17-3897-2024, https://doi.org/10.5194/amt-17-3897-2024, 2024
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The three most widely used techniques for measuring black carbon (BC) have been deployed continuously for 2 years at a French high-altitude research station. Despite a similar temporal variation in the BC load, we found significant biases by up to a factor of 8 between the three instruments. This study raises questions about the relevance of using these instruments for specific background sites, as well as the processing of their data, which can vary according to the atmospheric conditions.
Katharina Heitmann, Michael Sprenger, Hanin Binder, Heini Wernli, and Hanna Joos
Weather Clim. Dynam., 5, 537–557, https://doi.org/10.5194/wcd-5-537-2024, https://doi.org/10.5194/wcd-5-537-2024, 2024
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Warm conveyor belts (WCBs) are coherently ascending air streams that occur in extratropical cyclones where they form precipitation and often affect the large-scale flow. We quantified the key characteristics and impacts of WCBs and linked them to different phases in the cyclone life cycle and to different WCB branches. A climatology of these metrics revealed that WCBs are most intense during cyclone intensification and that the cyclonic and anticyclonic WCB branches show distinct differences.
Alexander Scherrmann, Heini Wernli, and Emmanouil Flaounas
Weather Clim. Dynam., 5, 419–438, https://doi.org/10.5194/wcd-5-419-2024, https://doi.org/10.5194/wcd-5-419-2024, 2024
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We show that the formation of Mediterranean cyclones follows the presence of cyclones over the North Atlantic. The distinct regions of cyclone activity in the Mediterranean in the different seasons can be linked to the atmospheric state, in particular the position of the polar jet over the North Atlantic. With this we now better understand the processes that lead to the formation of Mediterranean cyclones. We used a novel simulation framework in which we directly show and probe this connection.
Sarah Tinorua, Cyrielle Denjean, Pierre Nabat, Thierry Bourrianne, Véronique Pont, François Gheusi, and Emmanuel Leclerc
Atmos. Chem. Phys., 24, 1801–1824, https://doi.org/10.5194/acp-24-1801-2024, https://doi.org/10.5194/acp-24-1801-2024, 2024
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At a French high-altitude site, where many complex interactions between black carbon (BC), radiation, clouds and snow impact climate, 2 years of refractive BC (rBC) and aerosol optical and microphysical measurements have been made. We observed strong seasonal rBC properties variations, with an enhanced absorption in summer compared to winter. The combination of rBC emission sources, transport pathways, atmospheric dynamics and chemical processes explains the rBC light absorption seasonality.
Roman Pohorsky, Andrea Baccarini, Julie Tolu, Lenny H. E. Winkel, and Julia Schmale
Atmos. Meas. Tech., 17, 731–754, https://doi.org/10.5194/amt-17-731-2024, https://doi.org/10.5194/amt-17-731-2024, 2024
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This manuscript presents a new tethered-balloon-based platform for in situ vertical measurements of aerosols and trace gases in the lower atmosphere of polar and alpine regions. The system can host various instrumental setups to target different research questions and features new instruments, in particular a miniaturized scanning electrical mobility spectrometer, deployed for the first time in a tethered balloon.
Leonie Villiger and Franziska Aemisegger
Atmos. Chem. Phys., 24, 957–976, https://doi.org/10.5194/acp-24-957-2024, https://doi.org/10.5194/acp-24-957-2024, 2024
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Three numerical simulations performed with an isotope-enabled weather forecast model are used to investigate the cloud–circulation coupling between shallow trade-wind cumulus clouds and atmospheric circulations on different scales. It is shown that stable water isotopes near cloud base in the tropics reflect (1) the diel cycle of the atmospheric circulation, which drives the formation and dissipation of clouds, and (2) changes in the large-scale circulation over the North Atlantic.
Julian F. Quinting, Christian M. Grams, Edmund Kar-Man Chang, Stephan Pfahl, and Heini Wernli
Weather Clim. Dynam., 5, 65–85, https://doi.org/10.5194/wcd-5-65-2024, https://doi.org/10.5194/wcd-5-65-2024, 2024
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Research in the last few decades has revealed that rapidly ascending airstreams in extratropical cyclones have an important effect on the evolution of downstream weather and predictability. In this study, we show that the occurrence of these airstreams over the North Pacific is modulated by tropical convection. Depending on the modulation, known atmospheric circulation patterns evolve quite differently, which may affect extended-range predictions in the Atlantic–European region.
Jérémy Gueffier, François Gheusi, Marie Lothon, Véronique Pont, Alban Philibert, Fabienne Lohou, Solène Derrien, Yannick Bezombes, Gilles Athier, Yves Meyerfeld, Antoine Vial, and Emmanuel Leclerc
Atmos. Chem. Phys., 24, 287–316, https://doi.org/10.5194/acp-24-287-2024, https://doi.org/10.5194/acp-24-287-2024, 2024
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This study investigates the link between weather regime and atmospheric composition at a Pyrenean observatory. Five years of meteorological data were synchronized on a daily basis and then, using a clustering method, separated into six groups of observation days, with most showing marked characteristics of different weather regimes (fair and disturbed weather, winter windstorms, foehn). Statistical differences in gas and particle concentrations appeared between the groups and are discussed.
Leonie Villiger, Marina Dütsch, Sandrine Bony, Marie Lothon, Stephan Pfahl, Heini Wernli, Pierre-Etienne Brilouet, Patrick Chazette, Pierre Coutris, Julien Delanoë, Cyrille Flamant, Alfons Schwarzenboeck, Martin Werner, and Franziska Aemisegger
Atmos. Chem. Phys., 23, 14643–14672, https://doi.org/10.5194/acp-23-14643-2023, https://doi.org/10.5194/acp-23-14643-2023, 2023
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This study evaluates three numerical simulations performed with an isotope-enabled weather forecast model and investigates the coupling between shallow trade-wind cumulus clouds and atmospheric circulations on different scales. We show that the simulations reproduce key characteristics of shallow trade-wind clouds as observed during the field experiment EUREC4A and that the spatial distribution of stable-water-vapour isotopes is shaped by the overturning circulation associated with these clouds.
Elena De La Torre Castro, Tina Jurkat-Witschas, Armin Afchine, Volker Grewe, Valerian Hahn, Simon Kirschler, Martina Krämer, Johannes Lucke, Nicole Spelten, Heini Wernli, Martin Zöger, and Christiane Voigt
Atmos. Chem. Phys., 23, 13167–13189, https://doi.org/10.5194/acp-23-13167-2023, https://doi.org/10.5194/acp-23-13167-2023, 2023
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In this study, we show the differences in the microphysical properties between high-latitude (HL) cirrus and mid-latitude (ML) cirrus over the Arctic, North Atlantic, and central Europe during summer. The in situ measurements are combined with backward trajectories to investigate the influence of the region on cloud formation. We show that HL cirrus are characterized by a lower concentration of larger ice crystals when compared to ML cirrus.
Mark J. Rodwell and Heini Wernli
Weather Clim. Dynam., 4, 591–615, https://doi.org/10.5194/wcd-4-591-2023, https://doi.org/10.5194/wcd-4-591-2023, 2023
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Midlatitude storms and their downstream impacts have a major impact on society, yet their prediction is especially prone to uncertainty. While this can never be fully eliminated, we find that the initial rate of growth of uncertainty varies for a range of forecast models. Examination of the model of the European Centre for Medium-Range Weather Forecasts (ECMWF) suggests ways in which uncertainty growth could be reduced, leading to sharper and more reliable forecasts over the first few days.
Thomas Berkemeier, Matteo Krüger, Aryeh Feinberg, Marcel Müller, Ulrich Pöschl, and Ulrich K. Krieger
Geosci. Model Dev., 16, 2037–2054, https://doi.org/10.5194/gmd-16-2037-2023, https://doi.org/10.5194/gmd-16-2037-2023, 2023
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Kinetic multi-layer models (KMs) successfully describe heterogeneous and multiphase atmospheric chemistry. In applications requiring repeated execution, however, these models can be too expensive. We trained machine learning surrogate models on output of the model KM-SUB and achieved high correlations. The surrogate models run orders of magnitude faster, which suggests potential applicability in global optimization tasks and as sub-modules in large-scale atmospheric models.
Mauro Hermann, Matthias Röthlisberger, Arthur Gessler, Andreas Rigling, Cornelius Senf, Thomas Wohlgemuth, and Heini Wernli
Biogeosciences, 20, 1155–1180, https://doi.org/10.5194/bg-20-1155-2023, https://doi.org/10.5194/bg-20-1155-2023, 2023
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This study examines the multi-annual meteorological history of low-forest-greenness events in Europe's temperate and Mediterranean biome in 2002–2022. We systematically identify anomalies in temperature, precipitation, and weather systems as event precursors, with noteworthy differences between the two biomes. We also quantify the impact of the most extensive event in 2022 (37 % coverage), underlining the importance of understanding the forest–meteorology interaction in a changing climate.
Adriana Bailey, Franziska Aemisegger, Leonie Villiger, Sebastian A. Los, Gilles Reverdin, Estefanía Quiñones Meléndez, Claudia Acquistapace, Dariusz B. Baranowski, Tobias Böck, Sandrine Bony, Tobias Bordsdorff, Derek Coffman, Simon P. de Szoeke, Christopher J. Diekmann, Marina Dütsch, Benjamin Ertl, Joseph Galewsky, Dean Henze, Przemyslaw Makuch, David Noone, Patricia K. Quinn, Michael Rösch, Andreas Schneider, Matthias Schneider, Sabrina Speich, Bjorn Stevens, and Elizabeth J. Thompson
Earth Syst. Sci. Data, 15, 465–495, https://doi.org/10.5194/essd-15-465-2023, https://doi.org/10.5194/essd-15-465-2023, 2023
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One of the novel ways EUREC4A set out to investigate trade wind clouds and their coupling to the large-scale circulation was through an extensive network of isotopic measurements in water vapor, precipitation, and seawater. Samples were taken from the island of Barbados, from aboard two aircraft, and from aboard four ships. This paper describes the full collection of EUREC4A isotopic in situ data and guides readers to complementary remotely sensed water vapor isotope ratios.
Alexander Scherrmann, Heini Wernli, and Emmanouil Flaounas
Weather Clim. Dynam., 4, 157–173, https://doi.org/10.5194/wcd-4-157-2023, https://doi.org/10.5194/wcd-4-157-2023, 2023
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We investigate the dynamical origin of the lower-atmospheric potential vorticity (PV; linked to the intensity of cyclones) in Mediterranean cyclones. We quantify the contribution of the cyclone and the environment by tracing PV backward in time and space and linking it to the track of the cyclone. We find that the lower-tropospheric PV is produced shortly before the cyclone's stage of highest intensity. We investigate the driving processes and use a global dataset and a process-resolving one.
Hanna Joos, Michael Sprenger, Hanin Binder, Urs Beyerle, and Heini Wernli
Weather Clim. Dynam., 4, 133–155, https://doi.org/10.5194/wcd-4-133-2023, https://doi.org/10.5194/wcd-4-133-2023, 2023
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Warm conveyor belts (WCBs) are strongly ascending, cloud- and precipitation-forming airstreams in extratropical cyclones. In this study we assess their representation in a climate simulation and their changes under global warming. They become moister, become more intense, and reach higher altitudes in a future climate, implying that they potentially have an increased impact on the mid-latitude flow.
Alkuin M. Koenig, Olivier Magand, Bert Verreyken, Jerome Brioude, Crist Amelynck, Niels Schoon, Aurélie Colomb, Beatriz Ferreira Araujo, Michel Ramonet, Mahesh K. Sha, Jean-Pierre Cammas, Jeroen E. Sonke, and Aurélien Dommergue
Atmos. Chem. Phys., 23, 1309–1328, https://doi.org/10.5194/acp-23-1309-2023, https://doi.org/10.5194/acp-23-1309-2023, 2023
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The global distribution of mercury, a potent neurotoxin, depends on atmospheric transport, chemistry, and interactions between the Earth’s surface and the air. Our understanding of these processes is still hampered by insufficient observations. Here, we present new data from a mountain observatory in the Southern Hemisphere. We give insights into mercury concentrations in air masses coming from aloft, and we show that tropical mountain vegetation may be a daytime source of mercury to the air.
Andreas Schäfler, Michael Sprenger, Heini Wernli, Andreas Fix, and Martin Wirth
Atmos. Chem. Phys., 23, 999–1018, https://doi.org/10.5194/acp-23-999-2023, https://doi.org/10.5194/acp-23-999-2023, 2023
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In this study, airborne lidar profile measurements of H2O and O3 across a midlatitude jet stream are combined with analyses in tracer–trace space and backward trajectories. We highlight that transport and mixing processes in the history of the observed air masses are governed by interacting tropospheric weather systems on synoptic timescales. We show that these weather systems play a key role in the high variability of the paired H2O and O3 distributions near the tropopause.
Hanin Binder, Hanna Joos, Michael Sprenger, and Heini Wernli
Weather Clim. Dynam., 4, 19–37, https://doi.org/10.5194/wcd-4-19-2023, https://doi.org/10.5194/wcd-4-19-2023, 2023
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Warm conveyor belts (WCBs) are the main cloud- and precipitation-producing airstreams in extratropical cyclones. The latent heat release that occurs during cloud formation often contributes to the intensification of the associated cyclone. Based on the Community Earth System Model Large Ensemble coupled climate simulations, we show that WCBs and associated latent heating will become stronger in a future climate and be even more important for explosive cyclone intensification than in the present.
Iris Thurnherr and Franziska Aemisegger
Atmos. Chem. Phys., 22, 10353–10373, https://doi.org/10.5194/acp-22-10353-2022, https://doi.org/10.5194/acp-22-10353-2022, 2022
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Stable water isotopes in marine boundary layer vapour are strongly influenced by the strength of air–sea fluxes. Here, we investigate a distinct vapour isotope signal observed in the warm sector of Southern Ocean cyclones. Single-process air parcel models are used together with high-resolution isotope-enabled simulations with the weather prediction model COSMOiso to improve our understanding of the importance of air–sea fluxes for the moisture cycling in the context of extratropical cyclones.
Andries Jan de Vries, Franziska Aemisegger, Stephan Pfahl, and Heini Wernli
Atmos. Chem. Phys., 22, 8863–8895, https://doi.org/10.5194/acp-22-8863-2022, https://doi.org/10.5194/acp-22-8863-2022, 2022
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The Earth's water cycle contains the common H2O molecule but also the less abundant, heavier HDO. We use their different physical properties to study tropical ice clouds in model simulations of the West African monsoon. Isotope signals reveal different processes through which ice clouds form and decay in deep-convective and widespread cirrus. Previously observed variations in upper-tropospheric vapour isotopes are explained by microphysical processes in convective updraughts and downdraughts.
Sandrine Bony, Marie Lothon, Julien Delanoë, Pierre Coutris, Jean-Claude Etienne, Franziska Aemisegger, Anna Lea Albright, Thierry André, Hubert Bellec, Alexandre Baron, Jean-François Bourdinot, Pierre-Etienne Brilouet, Aurélien Bourdon, Jean-Christophe Canonici, Christophe Caudoux, Patrick Chazette, Michel Cluzeau, Céline Cornet, Jean-Philippe Desbios, Dominique Duchanoy, Cyrille Flamant, Benjamin Fildier, Christophe Gourbeyre, Laurent Guiraud, Tetyana Jiang, Claude Lainard, Christophe Le Gac, Christian Lendroit, Julien Lernould, Thierry Perrin, Frédéric Pouvesle, Pascal Richard, Nicolas Rochetin, Kevin Salaün, Alfons Schwarzenboeck, Guillaume Seurat, Bjorn Stevens, Julien Totems, Ludovic Touzé-Peiffer, Gilles Vergez, Jessica Vial, Leonie Villiger, and Raphaela Vogel
Earth Syst. Sci. Data, 14, 2021–2064, https://doi.org/10.5194/essd-14-2021-2022, https://doi.org/10.5194/essd-14-2021-2022, 2022
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The French ATR42 research aircraft participated in the EUREC4A international field campaign that took place in 2020 over the tropical Atlantic, east of Barbados. We present the extensive instrumentation of the aircraft, the research flights and the different measurements. We show that the ATR measurements of humidity, wind, aerosols and cloudiness in the lower atmosphere are robust and consistent with each other. They will make it possible to advance understanding of cloud–climate interactions.
Andreas Schneider, Tobias Borsdorff, Joost aan de Brugh, Alba Lorente, Franziska Aemisegger, David Noone, Dean Henze, Rigel Kivi, and Jochen Landgraf
Atmos. Meas. Tech., 15, 2251–2275, https://doi.org/10.5194/amt-15-2251-2022, https://doi.org/10.5194/amt-15-2251-2022, 2022
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This paper presents an extended H₂O/HDO total column dataset from short-wave infrared measurements by TROPOMI including cloudy and clear-sky scenes. Coverage is tremendously increased compared to previous TROPOMI HDO datasets. The new dataset is validated against recent ground-based FTIR measurements from TCCON and against aircraft measurements over the ocean. The use of the new dataset is demonstrated with a case study of a cold air outbreak in January 2020.
Philipp Zschenderlein and Heini Wernli
Weather Clim. Dynam., 3, 391–411, https://doi.org/10.5194/wcd-3-391-2022, https://doi.org/10.5194/wcd-3-391-2022, 2022
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Precipitation and temperature are two of the most important variables describing our weather and climate. The relationship between these variables has been studied extensively; however, the role of specific weather systems in shaping this relationship has not been analysed yet. We therefore analyse whether intense precipitation occurs on warmer or on colder days and identify the relevant weather systems. In general, weather systems strongly influence this relationship, especially in winter.
Jan Clemens, Felix Ploeger, Paul Konopka, Raphael Portmann, Michael Sprenger, and Heini Wernli
Atmos. Chem. Phys., 22, 3841–3860, https://doi.org/10.5194/acp-22-3841-2022, https://doi.org/10.5194/acp-22-3841-2022, 2022
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Highly polluted air flows from the surface to higher levels of the atmosphere during the Asian summer monsoon. At high levels, the air is trapped within eddies. Here, we study how air masses can leave the eddy within its cutoff, how they distribute, and how their chemical composition changes. We found evidence for transport from the eddy to higher latitudes over the North Pacific and even Alaska. During transport, trace gas concentrations within cutoffs changed gradually, showing steady mixing.
Katharina Hartmuth, Maxi Boettcher, Heini Wernli, and Lukas Papritz
Weather Clim. Dynam., 3, 89–111, https://doi.org/10.5194/wcd-3-89-2022, https://doi.org/10.5194/wcd-3-89-2022, 2022
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In this study, we introduce a novel method to objectively define and identify extreme Arctic seasons based on different surface variables. We find that such seasons are resulting from various combinations of unusual seasonal conditions. The occurrence or absence of different atmospheric processes strongly affects the character of extreme Arctic seasons. Further, changes in sea ice and sea surface temperature can strongly influence the formation of such a season in distinct regions.
Leonie Villiger, Heini Wernli, Maxi Boettcher, Martin Hagen, and Franziska Aemisegger
Weather Clim. Dynam., 3, 59–88, https://doi.org/10.5194/wcd-3-59-2022, https://doi.org/10.5194/wcd-3-59-2022, 2022
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The coupling between the large-scale atmospheric circulation and the clouds in the trade-wind region is complex and not yet fully understood. In this study, the formation pathway of two anomalous cloud layers over Barbados during the field campaign EUREC4A is described. The two case studies highlight the influence of remote weather systems on the local environmental conditions in Barbados.
Philipp Zschenderlein and Heini Wernli
Nat. Hazards Earth Syst. Sci. Discuss., https://doi.org/10.5194/nhess-2021-396, https://doi.org/10.5194/nhess-2021-396, 2022
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In early January 2021, Spain was affected by two extreme events – an unusually long cold spell and a heavy snowfall event associated with extratropical cyclone Filomena. In the study, we analyse the synoptic-dynamic development of the two extreme events. Cold air from the north was advected towards Spain and between 07 and 10 January, cyclone Filomena was responsible for major parts of the snowfall event. During this event, temperature and moisture contrasts accross Spain were very high.
Sebastian Landwehr, Michele Volpi, F. Alexander Haumann, Charlotte M. Robinson, Iris Thurnherr, Valerio Ferracci, Andrea Baccarini, Jenny Thomas, Irina Gorodetskaya, Christian Tatzelt, Silvia Henning, Rob L. Modini, Heather J. Forrer, Yajuan Lin, Nicolas Cassar, Rafel Simó, Christel Hassler, Alireza Moallemi, Sarah E. Fawcett, Neil Harris, Ruth Airs, Marzieh H. Derkani, Alberto Alberello, Alessandro Toffoli, Gang Chen, Pablo Rodríguez-Ros, Marina Zamanillo, Pau Cortés-Greus, Lei Xue, Conor G. Bolas, Katherine C. Leonard, Fernando Perez-Cruz, David Walton, and Julia Schmale
Earth Syst. Dynam., 12, 1295–1369, https://doi.org/10.5194/esd-12-1295-2021, https://doi.org/10.5194/esd-12-1295-2021, 2021
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The Antarctic Circumnavigation Expedition surveyed a large number of variables describing the dynamic state of ocean and atmosphere, freshwater cycle, atmospheric chemistry, ocean biogeochemistry, and microbiology in the Southern Ocean. To reduce the dimensionality of the dataset, we apply a sparse principal component analysis and identify temporal patterns from diurnal to seasonal cycles, as well as geographical gradients and
hotspotsof interaction. Code and data are open access.
Clémence Rose, Martine Collaud Coen, Elisabeth Andrews, Yong Lin, Isaline Bossert, Cathrine Lund Myhre, Thomas Tuch, Alfred Wiedensohler, Markus Fiebig, Pasi Aalto, Andrés Alastuey, Elisabeth Alonso-Blanco, Marcos Andrade, Begoña Artíñano, Todor Arsov, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Juan Andrés Casquero-Vera, Sébastien Conil, Konstantinos Eleftheriadis, Olivier Favez, Harald Flentje, Maria I. Gini, Francisco Javier Gómez-Moreno, Martin Gysel-Beer, Anna Gannet Hallar, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Melita Keywood, Jeong Eun Kim, Sang-Woo Kim, Adam Kristensson, Markku Kulmala, Heikki Lihavainen, Neng-Huei Lin, Hassan Lyamani, Angela Marinoni, Sebastiao Martins Dos Santos, Olga L. Mayol-Bracero, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Jakub Ondracek, Marco Pandolfi, Noemi Pérez, Tuukka Petäjä, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Jean-Philippe Putaud, Fabienne Reisen, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Junying Sun, Pierre Tulet, Ville Vakkari, Pieter Gideon van Zyl, Fernando Velarde, Paolo Villani, Stergios Vratolis, Zdenek Wagner, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Vladimir Zdimal, and Paolo Laj
Atmos. Chem. Phys., 21, 17185–17223, https://doi.org/10.5194/acp-21-17185-2021, https://doi.org/10.5194/acp-21-17185-2021, 2021
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Aerosol particles are a complex component of the atmospheric system the effects of which are among the most uncertain in climate change projections. Using data collected at 62 stations, this study provides the most up-to-date picture of the spatial distribution of particle number concentration and size distribution worldwide, with the aim of contributing to better representation of aerosols and their interactions with clouds in models and, therefore, better evaluation of their impact on climate.
Roman Attinger, Elisa Spreitzer, Maxi Boettcher, Heini Wernli, and Hanna Joos
Weather Clim. Dynam., 2, 1073–1091, https://doi.org/10.5194/wcd-2-1073-2021, https://doi.org/10.5194/wcd-2-1073-2021, 2021
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Diabatic processes affect the development of extratropical cyclones. This work provides a systematic assessment of the diabatic processes that modify potential vorticity (PV) in model simulations. PV is primarily produced by condensation and convection. Given favorable environmental conditions, long-wave radiative cooling and turbulence become the primary process at the cold and warm fronts, respectively. Turbulence and long-wave radiative heating produce negative PV anomalies at the fronts.
Fabienne Dahinden, Franziska Aemisegger, Heini Wernli, Matthias Schneider, Christopher J. Diekmann, Benjamin Ertl, Peter Knippertz, Martin Werner, and Stephan Pfahl
Atmos. Chem. Phys., 21, 16319–16347, https://doi.org/10.5194/acp-21-16319-2021, https://doi.org/10.5194/acp-21-16319-2021, 2021
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We use high-resolution numerical isotope modelling and Lagrangian backward trajectories to identify moisture transport pathways and governing physical and dynamical processes that affect the free-tropospheric humidity and isotopic variability over the eastern subtropical North Atlantic. Furthermore, we conduct a thorough isotope modelling validation with aircraft and remote-sensing observations of water vapour isotopes.
Timofei Sukhodolov, Tatiana Egorova, Andrea Stenke, William T. Ball, Christina Brodowsky, Gabriel Chiodo, Aryeh Feinberg, Marina Friedel, Arseniy Karagodin-Doyennel, Thomas Peter, Jan Sedlacek, Sandro Vattioni, and Eugene Rozanov
Geosci. Model Dev., 14, 5525–5560, https://doi.org/10.5194/gmd-14-5525-2021, https://doi.org/10.5194/gmd-14-5525-2021, 2021
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This paper features the new atmosphere–ocean–aerosol–chemistry–climate model SOCOLv4.0 and its validation. The model performance is evaluated against reanalysis products and observations of atmospheric circulation and trace gas distribution, with a focus on stratospheric processes. Although we identified some problems to be addressed in further model upgrades, we demonstrated that SOCOLv4.0 is already well suited for studies related to chemistry–climate–aerosol interactions.
Bjorn Stevens, Sandrine Bony, David Farrell, Felix Ament, Alan Blyth, Christopher Fairall, Johannes Karstensen, Patricia K. Quinn, Sabrina Speich, Claudia Acquistapace, Franziska Aemisegger, Anna Lea Albright, Hugo Bellenger, Eberhard Bodenschatz, Kathy-Ann Caesar, Rebecca Chewitt-Lucas, Gijs de Boer, Julien Delanoë, Leif Denby, Florian Ewald, Benjamin Fildier, Marvin Forde, Geet George, Silke Gross, Martin Hagen, Andrea Hausold, Karen J. Heywood, Lutz Hirsch, Marek Jacob, Friedhelm Jansen, Stefan Kinne, Daniel Klocke, Tobias Kölling, Heike Konow, Marie Lothon, Wiebke Mohr, Ann Kristin Naumann, Louise Nuijens, Léa Olivier, Robert Pincus, Mira Pöhlker, Gilles Reverdin, Gregory Roberts, Sabrina Schnitt, Hauke Schulz, A. Pier Siebesma, Claudia Christine Stephan, Peter Sullivan, Ludovic Touzé-Peiffer, Jessica Vial, Raphaela Vogel, Paquita Zuidema, Nicola Alexander, Lyndon Alves, Sophian Arixi, Hamish Asmath, Gholamhossein Bagheri, Katharina Baier, Adriana Bailey, Dariusz Baranowski, Alexandre Baron, Sébastien Barrau, Paul A. Barrett, Frédéric Batier, Andreas Behrendt, Arne Bendinger, Florent Beucher, Sebastien Bigorre, Edmund Blades, Peter Blossey, Olivier Bock, Steven Böing, Pierre Bosser, Denis Bourras, Pascale Bouruet-Aubertot, Keith Bower, Pierre Branellec, Hubert Branger, Michal Brennek, Alan Brewer, Pierre-Etienne Brilouet, Björn Brügmann, Stefan A. Buehler, Elmo Burke, Ralph Burton, Radiance Calmer, Jean-Christophe Canonici, Xavier Carton, Gregory Cato Jr., Jude Andre Charles, Patrick Chazette, Yanxu Chen, Michal T. Chilinski, Thomas Choularton, Patrick Chuang, Shamal Clarke, Hugh Coe, Céline Cornet, Pierre Coutris, Fleur Couvreux, Susanne Crewell, Timothy Cronin, Zhiqiang Cui, Yannis Cuypers, Alton Daley, Gillian M. Damerell, Thibaut Dauhut, Hartwig Deneke, Jean-Philippe Desbios, Steffen Dörner, Sebastian Donner, Vincent Douet, Kyla Drushka, Marina Dütsch, André Ehrlich, Kerry Emanuel, Alexandros Emmanouilidis, Jean-Claude Etienne, Sheryl Etienne-Leblanc, Ghislain Faure, Graham Feingold, Luca Ferrero, Andreas Fix, Cyrille Flamant, Piotr Jacek Flatau, Gregory R. Foltz, Linda Forster, Iulian Furtuna, Alan Gadian, Joseph Galewsky, Martin Gallagher, Peter Gallimore, Cassandra Gaston, Chelle Gentemann, Nicolas Geyskens, Andreas Giez, John Gollop, Isabelle Gouirand, Christophe Gourbeyre, Dörte de Graaf, Geiske E. de Groot, Robert Grosz, Johannes Güttler, Manuel Gutleben, Kashawn Hall, George Harris, Kevin C. Helfer, Dean Henze, Calvert Herbert, Bruna Holanda, Antonio Ibanez-Landeta, Janet Intrieri, Suneil Iyer, Fabrice Julien, Heike Kalesse, Jan Kazil, Alexander Kellman, Abiel T. Kidane, Ulrike Kirchner, Marcus Klingebiel, Mareike Körner, Leslie Ann Kremper, Jan Kretzschmar, Ovid Krüger, Wojciech Kumala, Armin Kurz, Pierre L'Hégaret, Matthieu Labaste, Tom Lachlan-Cope, Arlene Laing, Peter Landschützer, Theresa Lang, Diego Lange, Ingo Lange, Clément Laplace, Gauke Lavik, Rémi Laxenaire, Caroline Le Bihan, Mason Leandro, Nathalie Lefevre, Marius Lena, Donald Lenschow, Qiang Li, Gary Lloyd, Sebastian Los, Niccolò Losi, Oscar Lovell, Christopher Luneau, Przemyslaw Makuch, Szymon Malinowski, Gaston Manta, Eleni Marinou, Nicholas Marsden, Sebastien Masson, Nicolas Maury, Bernhard Mayer, Margarette Mayers-Als, Christophe Mazel, Wayne McGeary, James C. McWilliams, Mario Mech, Melina Mehlmann, Agostino Niyonkuru Meroni, Theresa Mieslinger, Andreas Minikin, Peter Minnett, Gregor Möller, Yanmichel Morfa Avalos, Caroline Muller, Ionela Musat, Anna Napoli, Almuth Neuberger, Christophe Noisel, David Noone, Freja Nordsiek, Jakub L. Nowak, Lothar Oswald, Douglas J. Parker, Carolyn Peck, Renaud Person, Miriam Philippi, Albert Plueddemann, Christopher Pöhlker, Veronika Pörtge, Ulrich Pöschl, Lawrence Pologne, Michał Posyniak, Marc Prange, Estefanía Quiñones Meléndez, Jule Radtke, Karim Ramage, Jens Reimann, Lionel Renault, Klaus Reus, Ashford Reyes, Joachim Ribbe, Maximilian Ringel, Markus Ritschel, Cesar B. Rocha, Nicolas Rochetin, Johannes Röttenbacher, Callum Rollo, Haley Royer, Pauline Sadoulet, Leo Saffin, Sanola Sandiford, Irina Sandu, Michael Schäfer, Vera Schemann, Imke Schirmacher, Oliver Schlenczek, Jerome Schmidt, Marcel Schröder, Alfons Schwarzenboeck, Andrea Sealy, Christoph J. Senff, Ilya Serikov, Samkeyat Shohan, Elizabeth Siddle, Alexander Smirnov, Florian Späth, Branden Spooner, M. Katharina Stolla, Wojciech Szkółka, Simon P. de Szoeke, Stéphane Tarot, Eleni Tetoni, Elizabeth Thompson, Jim Thomson, Lorenzo Tomassini, Julien Totems, Alma Anna Ubele, Leonie Villiger, Jan von Arx, Thomas Wagner, Andi Walther, Ben Webber, Manfred Wendisch, Shanice Whitehall, Anton Wiltshire, Allison A. Wing, Martin Wirth, Jonathan Wiskandt, Kevin Wolf, Ludwig Worbes, Ethan Wright, Volker Wulfmeyer, Shanea Young, Chidong Zhang, Dongxiao Zhang, Florian Ziemen, Tobias Zinner, and Martin Zöger
Earth Syst. Sci. Data, 13, 4067–4119, https://doi.org/10.5194/essd-13-4067-2021, https://doi.org/10.5194/essd-13-4067-2021, 2021
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The EUREC4A field campaign, designed to test hypothesized mechanisms by which clouds respond to warming and benchmark next-generation Earth-system models, is presented. EUREC4A comprised roughly 5 weeks of measurements in the downstream winter trades of the North Atlantic – eastward and southeastward of Barbados. It was the first campaign that attempted to characterize the full range of processes and scales influencing trade wind clouds.
Raphael Portmann, Michael Sprenger, and Heini Wernli
Weather Clim. Dynam., 2, 507–534, https://doi.org/10.5194/wcd-2-507-2021, https://doi.org/10.5194/wcd-2-507-2021, 2021
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We explore the three-dimensional life cycle of cyclonic structures
(so-called PV cutoffs) near the tropopause. PV cutoffs are frequent weather systems in the extratropics that lead to high-impact weather. However, many unknowns exist regarding their evolution. We present a new method to track PV cutoffs as 3D objects in reanalysis data by following air parcels along the flow. We study the climatological life cycles of PV cutoffs in detail and propose a classification into three types.
Yafei Li, Franziska Aemisegger, Andreas Riedl, Nina Buchmann, and Werner Eugster
Hydrol. Earth Syst. Sci., 25, 2617–2648, https://doi.org/10.5194/hess-25-2617-2021, https://doi.org/10.5194/hess-25-2617-2021, 2021
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During dry spells, dew and fog potentially play an increasingly important role in temperate grasslands. Research on the combined mechanisms of dew and fog inputs to ecosystems and distillation of water vapor from soil to plant surfaces is rare. Our results using stable water isotopes highlight the importance of dew and fog inputs to temperate grasslands during dry spells and reveal the complexity of the local water cycling in such conditions, including different pathways of dew and fog inputs.
Iris Thurnherr, Katharina Hartmuth, Lukas Jansing, Josué Gehring, Maxi Boettcher, Irina Gorodetskaya, Martin Werner, Heini Wernli, and Franziska Aemisegger
Weather Clim. Dynam., 2, 331–357, https://doi.org/10.5194/wcd-2-331-2021, https://doi.org/10.5194/wcd-2-331-2021, 2021
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Extratropical cyclones are important for the transport of moisture from low to high latitudes. In this study, we investigate how the isotopic composition of water vapour is affected by horizontal temperature advection associated with extratropical cyclones using measurements and modelling. It is shown that air–sea moisture fluxes induced by this horizontal temperature advection lead to the strong variability observed in the isotopic composition of water vapour in the marine boundary layer.
Maxi Boettcher, Andreas Schäfler, Michael Sprenger, Harald Sodemann, Stefan Kaufmann, Christiane Voigt, Hans Schlager, Donato Summa, Paolo Di Girolamo, Daniele Nerini, Urs Germann, and Heini Wernli
Atmos. Chem. Phys., 21, 5477–5498, https://doi.org/10.5194/acp-21-5477-2021, https://doi.org/10.5194/acp-21-5477-2021, 2021
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Warm conveyor belts (WCBs) are important airstreams in extratropical cyclones, often leading to the formation of intense precipitation. We present a case study that involves aircraft, lidar and radar observations of water and clouds in a WCB ascending from western Europe across the Alps towards the Baltic Sea during the field campaigns HyMeX and T-NAWDEX-Falcon in October 2012. A probabilistic trajectory measure and an airborne tracer experiment were used to confirm the long pathway of the WCB.
Cited articles
Aemisegger, F., Pfahl, S., Sodemann, H., Lehner, I., Seneviratne, S. I., and Wernli, H.: Deuterium excess as a proxy for continental moisture recycling and plant transpiration, Atmos. Chem. Phys., 14, 4029–4054, https://doi.org/10.5194/acp-14-4029-2014, 2014.
Ali, F., Peng, Q., Wang, D., Cui, Z., Huang, J., Fu, D., and Liang, D.: Effects of selenite and selenate application on distribution and transformation of selenium fractions in soil and its bioavailability for wheat (Triticum aestivum L.), Environ. Sci. Pollut. Res., 24, 8315–8325, https://doi.org/10.1007/s11356-017-8512-9, 2017.
Aller, J. Y., Radway, J. C., Kilthau, W. P., Bothe, D. W., Wilson, T. W., Vaillancourt, R. D., Quinn, P. K., Coffman, D. J., Murray, B. J., and Knopf, D. A.: Size-resolved characterization of the polysaccharidic and proteinaceous components of sea spray aerosol, Atmos. Environ., 154, 331–347, https://doi.org/10.1016/j.atmosenv.2017.01.053, 2017.
Amouroux, D. and Donard, O. F. X.: Maritime emission of selenium to the atmosphere in Eastern Mediterranean seas, Geophys. Res. Lett., 23, 1777–1780, https://doi.org/10.1029/96GL01271, 1996.
Amouroux, D., Liss, P. S., Tessier, E., Hamren-Larsson, M., and Donard, O. F. X.: Role of oceans as biogenic sources of selenium, Earth Planet. Sci. Lett., 189, 277–283, https://doi.org/10.1016/S0012-821X(01)00370-3, 2001.
Andres, R. J. and Kasgnoc, A. D.: A time-averaged inventory of subaerial volcanic sulfur emissions, J. Geophys. Res.-Atmos., 103, 25251–25261, https://doi.org/10.1029/98JD02091, 1998.
Angle, K. J., Crocker, D. R., Simpson, R. M. C., Mayer, K. J., Garofalo, L. A., Moore, A. N., Garcia, S. L. M., Or, V. W., Srinivasan, S., Farhan, M., Sauer, J. S., Lee, C., Pothier, M. A., Farmer, D. K., Martz, T. R., Bertram, T. H., Cappa, C. D., Prather, K. A., and Grassian, V. H.: Acidity across the interface from the ocean surface to sea spray aerosol, P. Natl. Acad. Sci. USA, 118, e2018397118, https://doi.org/10.1073/pnas.2018397118, 2021.
Arimoto, R., Duce, R. A., Ray, B. J., and Unni, C. K.: Atmospheric trace elements at Enewetak Atoll: 2. Transport to the ocean by wet and dry deposition, J. Geophys. Res.-Atmos., 90, 2391–2408, https://doi.org/10.1029/JD090iD01p02391, 1985.
Atkinson, R., Aschmann, S. M., Hasegawa, D., Thompson-Eagle, E. T., and Frankenberger, W. T.: Kinetics of the atmospherically important reactions of dimethyl selenide, Environ. Sci. Technol., 24, 1326–1332, https://doi.org/10.1021/es00079a005, 1990.
Blazina, T., Läderach, A., Jones, G. D., Sodemann, H., Wernli, H., Kirchner, J. W., and Winkel, L. H. E.: Marine Primary Productivity as a Potential Indirect Source of Selenium and Other Trace Elements in Atmospheric Deposition, Environ. Sci. Technol., 51, 108–118, https://doi.org/10.1021/acs.est.6b03063, 2017.
Breuninger, E. S., Tolu, J., Thurnherr, I., and Winkel, L. H. E. : Chemical data of atmospheric deposition samples collected at Pic du Midi Observatory (French Pyrenees), ETZ Zürich [data set], https://doi.org/10.3929/ethz-b-000647996, 2023.
Chen, Q., Sherwen, T., Evans, M., and Alexander, B.: DMS oxidation and sulfur aerosol formation in the marine troposphere: a focus on reactive halogen and multiphase chemistry, Atmos. Chem. Phys., 18, 13617–13637, https://doi.org/10.5194/acp-18-13617-2018, 2018.
Chester, R., Keyse, S., and Nimmo, M.: The Influence of Saharan and Middle Eastern Desert-Derived Dust on the Trace Metal Composition of Mediterranean Aerosols and Rainwaters: An Overview, in: The Impact of Desert Dust Across the Mediterranean, edited by: Guerzoni, S. and Chester, R., Springer Netherlands, Dordrecht, 253–273, https://doi.org/10.1007/978-94-017-3354-0_26, 1996.
Collett, J. L., Daube, B. C., and Hoffmann, M. R.: The chemical composition of intercepted cloudwater in the Sierra Nevada, Atmos. Environ., Part A, 24, 959–972, https://doi.org/10.1016/0960-1686(90)90298-2, 1990.
Cutter, G. A.: Species determination of selenium in natural waters, Anal. Chim. Acta, 98, 59–66, https://doi.org/10.1016/S0003-2670(01)83238-4, 1978.
Cutter, G. A.: Metalloids in wet deposition on Bermuda: Concentrations, sources, and fluxes, J. Geophys. Res.-Atmos., 98, 16777–16786, https://doi.org/10.1029/93JD01689, 1993.
Cutter, G. A. and Church, T. M.: Selenium in western Atlantic precipitation, Nature, 322, 720–722, 10.1038/322720a0, 1986.
Dansgaard, W.: Stable isotopes in precipitation, Tellus, 16, 436–468, https://doi.org/10.1111/j.2153-3490.1964.tb00181.x, 1964.
De Gregori, I., Lobos, M. A. G., and Pinochet, H.: Selenium and its redox speciation in rainwater from sites of Valparaýìso region in Chile, impacted by mining activities of copper ores, Water Res., 36, 115–122, https://doi.org/10.1016/S0043-1354(01)00240-8, 2002.
Dentener, F., Kinne, S., Bond, T., Boucher, O., Cofala, J., Generoso, S., Ginoux, P., Gong, S., Hoelzemann, J. J., Ito, A., Marelli, L., Penner, J. E., Putaud, J.-P., Textor, C., Schulz, M., van der Werf, G. R., and Wilson, J.: Emissions of primary aerosol and precursor gases in the years 2000 and 1750 prescribed data-sets for AeroCom, Atmos. Chem. Phys., 6, 4321–4344, https://doi.org/10.5194/acp-6-4321-2006, 2006.
De Santiago, A., Longo, A. F., Ingall, E. D., Diaz, J. M., King, L. E., Lai, B., Weber, R. J., Russell, A. G., and Oakes, M.: Characterization of Selenium in Ambient Aerosols and Primary Emission Sources, Environ. Sci. Technol., 48, 8988–8994, https://doi.org/10.1021/es500379y, 2014.
Donner, M. W. and Siddique, T.: A rapid and sensitive IC-ICP-MS method for determining selenium speciation in natural waters, Can. J. Chem., 96, 795–802, https://doi.org/10.1139/cjc-2017-0637, 2018.
Dovrou, E., Lim, C. Y., Canagaratna, M. R., Kroll, J. H., Worsnop, D. R., and Keutsch, F. N.: Measurement techniques for identifying and quantifying hydroxymethanesulfonate (HMS) in an aqueous matrix and particulate matter using aerosol mass spectrometry and ion chromatography, Atmos. Meas. Tech., 12, 5303–5315, https://doi.org/10.5194/amt-12-5303-2019, 2019.
Fabbri, D., Modelli, S., Torri, C., Cemin, A., Ragazzi, M., and Scaramuzza, P.: GC-MS determination of levoglucosan in atmospheric particulate matter collected over different filter materials, J. Environ. Monit., 10, 1519–1523, https://doi.org/10.1039/B808976K, 2008.
Fabbri, D., Adamiano, A., Falini, G., De Marco, R., and Mancini, I.: Analytical pyrolysis of dipeptides containing proline and amino acids with polar side chains. Novel 2,5-diketopiperazine markers in the pyrolysates of proteins, J. Anal. Appl. Pyrol., 95, 145–155, https://doi.org/10.1016/j.jaap.2012.02.001, 2012.
Feinberg, A., Sukhodolov, T., Luo, B.-P., Rozanov, E., Winkel, L. H. E., Peter, T., and Stenke, A.: Improved tropospheric and stratospheric sulfur cycle in the aerosol–chemistry–climate model SOCOL-AERv2, Geosci. Model Dev., 12, 3863–3887, https://doi.org/10.5194/gmd-12-3863-2019, 2019.
Feinberg, A., Stenke, A., Peter, T., and Winkel, L. H. E.: Constraining Atmospheric Selenium Emissions Using Observations, Global Modeling, and Bayesian Inference, Environ. Sci. Technol., 54, 7146–7155, https://doi.org/10.1021/acs.est.0c01408, 2020a.
Feinberg, A., Maliki, M., Stenke, A., Sudret, B., Peter, T., and Winkel, L. H. E.: Mapping the drivers of uncertainty in atmospheric selenium deposition with global sensitivity analysis, Atmos. Chem. Phys., 20, 1363–1390, https://doi.org/10.5194/acp-20-1363-2020, 2020b.
Feinberg, A., Stenke, A., Peter, T., Hinckley, E.-L. S., Driscoll, C. T., and Winkel, L. H. E.: Reductions in the deposition of sulfur and selenium to agricultural soils pose risk of future nutrient deficiencies, Commun. Earth Environ., 2, 101, https://doi.org/10.1038/s43247-021-00172-0, 2021.
Fernández-Martínez, A. and Charlet, L.: Selenium environmental cycling and bioavailability: a structural chemist point of view, Rev. Environ. Sci. Bio/Technol., 8, 81–110, https://doi.org/10.1007/s11157-009-9145-3, 2009.
Fraser, M. P. and Lakshmanan, K.: Using Levoglucosan as a Molecular Marker for the Long-Range Transport of Biomass Combustion Aerosols, Environ. Sci. Technol., 34, 4560–4564, https://doi.org/10.1021/es991229l, 2000.
Fu, X., Marusczak, N., Wang, X., Gheusi, F., and Sonke, J. E.: Isotopic Composition of Gaseous Elemental Mercury in the Free Troposphere of the Pic du Midi Observatory, France, Environ. Sci. Technol., 50, 5641–5650, https://doi.org/10.1021/acs.est.6b00033, 2016.
Gat, J. R. and Gonfiantini, R.: Stable isotope hydrology Deuterium and oxygen-18 in the water cycle, IAEA, International Atomic Energy Agency (IAEA), ISBN 92-0-145281-0, 339 p., 1981.
Gatz, D. F. and Nelson Dingle, A.: Trace substances in rain water: concentration variations during convective rains, and their interpretation, Tellus, 23, 14–27, https://doi.org/10.3402/tellusa.v23i1.10286, 1971.
Ghauri, B. M., Ishaq Mirza, M., Richter, R., Dutkiewicz, V. A., Rusheed, A., Khan, A. R., and Husain, L.: Composition of aerosols and cloud water at a remote mountain site (2.8 kms) in Pakistan, Chemosphere – Global Change Science, 3, 51–63, https://doi.org/10.1016/S1465-9972(00)00038-6, 2001.
Gheusi, F., Ravetta, F., Delbarre, H., Tsamalis, C., Chevalier-Rosso, A., Leroy, C., Augustin, P., Delmas, R., Ancellet, G., Athier, G., Bouchou, P., Campistron, B., Cousin, J. M., Fourmentin, M., and Meyerfeld, Y.: Pic 2005, a field campaign to investigate low-tropospheric ozone variability in the Pyrenees, Atmos. Res., 101, 640–665, https://doi.org/10.1016/j.atmosres.2011.04.014, 2011.
Giannoni, M., Martellini, T., Del Bubba, M., Gambaro, A., Zangrando, R., Chiari, M., Lepri, L., and Cincinelli, A.: The use of levoglucosan for tracing biomass burning in PM2.5 samples in Tuscany (Italy), Environ. Pollut., 167, 7–15, https://doi.org/10.1016/j.envpol.2012.03.016, 2012.
Granier, C., Darras, S., Denier van der Gon, H., Doubalova, J., Elguindi, N., Galle, B., Gauss, M., Guevara, M., Jalkanen, J.-P., Kuenen, J., Liousse, C., Quack, B., Simpson, D., and Sindelarova, K.: The Copernicus Atmosphere Monitoring Service global and regional emissions (April 2019 version) Copernicus Atmosphere Monitoring Service, https://doi.org/10.24380/d0bn-kx16, 2019.
Harvey, G. R. and Lang, R. F.: Dimethylsulfoxide and dimethylsulfone in the marine atmosphere, Geophys. Res. Lett., 13, 49–51, https://doi.org/10.1029/GL013i001p00049, 1986.
Heine, P. A. and Borduas-Dedekind, N.: The Ozonolysis of Methylated Selenide Compounds in the Atmosphere: Isotopes, Kinetics, Products, and Mechanisms, Environ. Sci. Technol., 57, 13079–13087, https://doi.org/10.1021/acs.est.3c01586, 2023.
Henne, S., Brunner, D., Folini, D., Solberg, S., Klausen, J., and Buchmann, B.: Assessment of parameters describing representativeness of air quality in-situ measurement sites, Atmos. Chem. Phys., 10, 3561–3581, https://doi.org/10.5194/acp-10-3561-2010, 2010.
Hersbach, H., Bell, B., Berrisford, P., Horányi, A. J. M. S., Sabater, J. M., Nicolas, J., Radu, R., Schepers, D., Simmons, A., Soci, C., and Dee, D.: Global reanalysis: goodbye ERA-Interim, hello ERA5, ECMWF newsletter, 17–24, https://doi.org/10.21957/vf291hehd7, 2019.
Hersbach, H., Bell, B., Berrisford, P., Hirahara, S., Horányi, A., Muñoz-Sabater, J., Nicolas, J., Peubey, C., Radu, R., Schepers, D., Simmons, A., Soci, C., Abdalla, S., Abellan, X., Balsamo, G., Bechtold, P., Biavati, G., Bidlot, J., Bonavita, M., De Chiara, G., Dahlgren, P., Dee, D., Diamantakis, M., Dragani, R., Flemming, J., Forbes, R., Fuentes, M., Geer, A., Haimberger, L., Healy, S., Hogan, R. J., Hólm, E., Janisková, M., Keeley, S., Laloyaux, P., Lopez, P., Lupu, C., Radnoti, G., de Rosnay, P., Rozum, I., Vamborg, F., Villaume, S., and Thépaut, J.-N.: The ERA5 global reanalysis, Q. J. Roy. Meteorol. Soc., 146, 1999–2049, https://doi.org/10.1002/qj.3803, 2020.
Holmes, C. D., Krishnamurthy, N. P., Caffrey, J. M., Landing, W. M., Edgerton, E. S., Knapp, K. R., and Nair, U. S.: Thunderstorms Increase Mercury Wet Deposition, Environ. Sci. Technol., 50, 9343–9350, https://doi.org/10.1021/acs.est.6b02586, 2016.
Hulin, M., Gheusi, F., Lothon, M., Pont, V., Lohou, F., Ramonet, M., Delmotte, M., Derrien, S., Athier, G., Meyerfeld, Y., Bezombes, Y., Augustin, P., and Ravetta, F.: Observations of Thermally Driven Circulations in the Pyrenees: Comparison of Detection Methods and Impact on Atmospheric Composition Measured at a Mountaintop, J. Appl. Meteorol. Climatol., 58, 717–740, https://doi.org/10.1175/jamc-d-17-0268.1, 2019.
IAEA: International Atomic Energy Agency: Reference sheet for VSMOW2 and SLAP2 international measurement standards, Vienna, 8 pp., RS_VSMOW2_SLAP2_rev1/2017-07-11, 2017.
Kagawa, M., Ishizaka, Y., and Ohta, K.: Sources of sulfate in winter aerosols over the Sea of Japan, as inferred from selenium composition, Atmos. Environ., 37, 1593–1600, https://doi.org/10.1016/S1352-2310(03)00006-2, 2003.
Kagawa, M., Katsuta, N., and Ishizaka, Y.: Selenite and selenate in clouds at a high-altitude mountain location in central Japan, Atmos. Res., 276, 106253, https://doi.org/10.1016/j.atmosres.2022.106253, 2022.
Kanji, Z. A., Ladino, L. A., Wex, H., Boose, Y., Burkert-Kohn, M., Cziczo, D. J., and Krämer, M.: Overview of Ice Nucleating Particles, Meteor. Mon., 58, 1.1–1.33, https://doi.org/10.1175/amsmonographs-d-16-0006.1, 2017.
Kulkarni, P., Chellam, S., Flanagan, J. B., and Jayanty, R. K. M.: Microwave digestion—ICP-MS for elemental analysis in ambient airborne fine particulate matter: Rare earth elements and validation using a filter borne fine particle certified reference material, Anal. Chim. Acta, 599, 170–176, https://doi.org/10.1016/j.aca.2007.08.014, 2007.
Lana, A., Bell, T. G., Simó, R., Vallina, S. M., Ballabrera-Poy, J., Kettle, A. J., Dachs, J., Bopp, L., Saltzman, E. S., Stefels, J., Johnson, J. E., and Liss, P. S.: An updated climatology of surface dimethlysulfide concentrations and emission fluxes in the global ocean, Global Biogeochem. Cy., 25, GB1004, https://doi.org/10.1029/2010GB003850, 2011.
Lazard, M., Dauplais, M., Blanquet, S., and Plateau, P.: Recent advances in the mechanism of selenoamino acids toxicity in eukaryotic cells, Biomolecular Concepts, 8, 93–104, https://doi.org/10.1515/bmc-2017-0007, 2017.
Lobanov, A. V., Hatfield, D. L., and Gladyshev, V. N.: Eukaryotic selenoproteins and selenoproteomes, Biochimica et Biophysica Acta (BBA) – General Subjects, 1790, 1424–1428, https://doi.org/10.1016/j.bbagen.2009.05.014, 2009.
Marenco, A., Gouget, H., Nédélec, P., Pagés, J.-P., and Karcher, F.: Evidence of a long-term increase in tropospheric ozone from Pic du Midi data series: Consequences: Positive radiative forcing, J. Geophys. Res.-Atmos., 99, 16617–16632, https://doi.org/10.1029/94JD00021, 1994.
Müller, E., von Gunten, U., Bouchet, S., Droz, B., and Winkel, L. H. E.: Hypobromous Acid as an Unaccounted Sink for Marine Dimethyl Sulfide?, Environ. Sci. Technol., 53, 13146–13157, https://doi.org/10.1021/acs.est.9b04310, 2019.
Nightingale, P. D., Malin, G., Law, C. S., Watson, A. J., Liss, P. S., Liddicoat, M. I., Boutin, J., and Upstill-Goddard, R. C.: In situ evaluation of air-sea gas exchange parameterizations using novel conservative and volatile tracers, Global Biogeochem. Cy., 14, 373–387, https://doi.org/10.1029/1999GB900091, 2000.
Pan, Z., Mao, F., Rosenfeld, D., Zhu, Y., Zang, L., Lu, X., Thornton, J. A., Holzworth, R. H., Yin, J., Efraim, A., and Gong, W.: Coarse sea spray inhibits lightning, Nat. Commun., 13, 4289, https://doi.org/10.1038/s41467-022-31714-5, 2022.
Pavageau, M.-P., Morin, A., Séby, F., Guimon, C., Krupp, E., Pécheyran, C., Poulleau, J., and Donard, O. F. X.: Partitioning of Metal Species during an Enriched Fuel Combustion Experiment. Speciation in the Gaseous and Particulate Phases, Environ. Sci. Technol., 38, 2252–2263, https://doi.org/10.1021/es034408i, 2004.
Pfahl, S. and Wernli, H.: Air parcel trajectory analysis of stable isotopes in water vapor in the eastern Mediterranean, J. Geophys. Res.-Atmos., 113, D20104, https://doi.org/10.1029/2008JD009839, 2008.
Pszenny, A. A. P., Harvey, G. R., Brown, C. J., Lang, R. F., Keene, W. C., Galloway, J. N., and Merrill, J. T.: Measurements of dimethyl sulfide oxidation products in the summertime North Atlantic marine boundary layer, Global Biogeochem. Cy., 4, 367–379, https://doi.org/10.1029/GB004i004p00367, 1990.
Pye, H. O. T., Nenes, A., Alexander, B., Ault, A. P., Barth, M. C., Clegg, S. L., Collett Jr., J. L., Fahey, K. M., Hennigan, C. J., Herrmann, H., Kanakidou, M., Kelly, J. T., Ku, I.-T., McNeill, V. F., Riemer, N., Schaefer, T., Shi, G., Tilgner, A., Walker, J. T., Wang, T., Weber, R., Xing, J., Zaveri, R. A., and Zuend, A.: The acidity of atmospheric particles and clouds, Atmos. Chem. Phys., 20, 4809–4888, https://doi.org/10.5194/acp-20-4809-2020, 2020.
Richter, R. C., Swami, K., Chace, S., and Husain, L.: Determination of arsenic, selenium, and antimony in cloud water by inductively coupled plasma mass spectrometry, Fresenius J. Anal. Chem., 361, 168–173, https://doi.org/10.1007/s002160050856, 1998.
Roulier, M., Bueno, M., Coppin, F., Nicolas, M., Thiry, Y., Rigal, F., Le Hécho, I., and Pannier, F.: Atmospheric iodine, selenium and caesium depositions in France: I. Spatial and seasonal variations, Chemosphere, 273, 128971, https://doi.org/10.1016/j.chemosphere.2020.128971, 2021.
Savage, L., Carey, M., Hossain, M., Islam, M. R., de Silva, P. M. C. S., Williams, P. N., and Meharg, A. A.: Elevated Trimethylarsine Oxide and Inorganic Arsenic in Northern Hemisphere Summer Monsoonal Wet Deposition, Environ. Sci. Technol., 51, 12210–12218, https://doi.org/10.1021/acs.est.7b04356, 2017.
Schkolnik, G. and Rudich, Y.: Detection and quantification of levoglucosan in atmospheric aerosols: a review, Anal. Bioanal. Chem., 385, 26–33, https://doi.org/10.1007/s00216-005-0168-5, 2006.
Séby, F., Potin-Gautier, M., Giffaut, E., Borge, G., and Donard, O. F. X.: A critical review of thermodynamic data for selenium species at 25 °C, Chem. Geol., 171, 173–194, https://doi.org/10.1016/S0009-2541(00)00246-1, 2001.
Sindelarova, K., Granier, C., Bouarar, I., Guenther, A., Tilmes, S., Stavrakou, T., Müller, J.-F., Kuhn, U., Stefani, P., and Knorr, W.: Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years, Atmos. Chem. Phys., 14, 9317–9341, https://doi.org/10.5194/acp-14-9317-2014, 2014.
Sodemann, H., Schwierz, C., and Wernli, H.: Interannual variability of Greenland winter precipitation sources: Lagrangian moisture diagnostic and North Atlantic Oscillation influence, J. Geophys. Res.-Atmos., 113, D03107, https://doi.org/10.1029/2007JD008503, 2008.
Sprenger, M. and Wernli, H.: The LAGRANTO Lagrangian analysis tool – version 2.0, Geosci. Model Dev., 8, 2569–2586, https://doi.org/10.5194/gmd-8-2569-2015, 2015.
Suess, E., Aemisegger, F., Sonke, J. E., Sprenger, M., Wernli, H., and Winkel, L. H. E.: Marine versus Continental Sources of Iodine and Selenium in Rainfall at Two European High-Altitude Locations, Environ. Sci. Technol., 53, 1905–1917, https://doi.org/10.1021/acs.est.8b05533, 2019.
Suzuki, Y., Sugimura, Y., and Miyake, Y.: The Content of Selenium and Its Chemical Form in Rain Water and Aerosol in Tokyo, J. Meteorol. Soc. JPN II, 59, 405–409, https://doi.org/10.2151/jmsj1965.59.3_405, 1981.
Thermo Fisher: Measuring pH of Pure Water and Other Low Conductivity Waters, Water Analysis Instruments, Application Note 005, AN-PHPURE-E 0914 RevA 1–4 pp., 2014.
Thornton, J. A., Virts, K. S., Holzworth, R. H., and Mitchell, T. P.: Lightning enhancement over major oceanic shipping lanes, Geophys. Res. Lett., 44, 9102–9111, https://doi.org/10.1002/2017GL074982, 2017.
Tolu, J., Gerber, L., Boily, J.-F., and Bindler, R.: High-throughput characterization of sediment organic matter by pyrolysis–gas chromatography/mass spectrometry and multivariate curve resolution: A promising analytical tool in (paleo)limnology, Anal. Chim. Acta, 880, 93–102, https://doi.org/10.1016/j.aca.2015.03.043, 2015.
Tolu, J., Le Hécho, I., Bueno, M., Thiry, Y., and Potin-Gautier, M.: Selenium speciation analysis at trace level in soils, Anal. Chim. Acta, 684, 126–133, https://doi.org/10.1016/j.aca.2010.10.044, 2011.
Tost, H., Jöckel, P., Kerkweg, A., Sander, R., and Lelieveld, J.: Technical note: A new comprehensive SCAVenging submodel for global atmospheric chemistry modelling, Atmos. Chem. Phys., 6, 565–574, https://doi.org/10.5194/acp-6-565-2006, 2006.
von Freyberg, J., Rücker, A., Zappa, M., Schlumpf, A., Studer, B., and Kirchner, J. W.: Four years of daily stable water isotope data in stream water and precipitation from three Swiss catchments, Sci. Data, 9, 46, https://doi.org/10.1038/s41597-022-01148-1, 2022.
Voorhees, K. J., DeLuca, S. J., and Noguerola, A.: Identification of chemical biomarker compounds in bacteria and other biomaterials by pyrolysis – tandem mass spectrometry, J. Anal. Appl. Pyrol., 24, 1–21, https://doi.org/10.1016/0165-2370(92)80001-3, 1992.
Voorhees, K. J., Basile, F., Beverly, M. B., Abbas-Hawks, C., Hendricker, A., Cody, R. B., and Hadfield, T. L.: The use of biomarker compounds for the identification of bacteria by pyrolysis-mass spectrometry, J. Anal. Appl. Pyrol., 40–41, 111–134, https://doi.org/10.1016/S0165-2370(97)00035-1, 1997.
Vriens, B., Lenz, M., Charlet, L., Berg, M., and Winkel, L. H. E.: Natural wetland emissions of methylated trace elements, Nat. Commun., 5, 3035, https://doi.org/10.1038/ncomms4035, 2014a.
Vriens, B., Ammann, A. A., Hagendorfer, H., Lenz, M., Berg, M., and Winkel, L. H. E.: Quantification of Methylated Selenium, Sulfur, and Arsenic in the Environment, PLOS ONE, 9, e102906, https://doi.org/10.1371/journal.pone.0102906, 2014b.
Wallschläger, D. and London, J.: Determination of inorganic selenium species in rain and sea waters by anion exchange chromatography-hydride generation-inductively-coupled plasma-dynamic reaction cell-mass spectrometry (AEC-HG-ICP-DRC-MS), J. Anal. Atom. Spectro., 19, 1119–1127, https://doi.org/10.1039/B401616E, 2004.
Wang, D., Alfthan, G., and Aro, A.: Determination of total selenium and dissolved selenium species in natural waters by fluorometry, Environ. Sci. Technol., 28, 383–387, https://doi.org/10.1021/es00052a007, 1994.
Watts, S. F., Watson, A., and Brimblecombe, P.: Measurements of the aerosol concentrations of methanesulphonic acid, dimethyl sulphoxide and dimethyl sulphone in the marine atmosphere of the British Isles, Atmos. Environ. (1967), 21, 2667–2672, https://doi.org/10.1016/0004-6981(87)90198-3, 1987.
Weller, R., Wöltjen, J., Piel, C., Resenberg, R., Wagenbach, D., König-Langlo, G., and Kriews, M.: Seasonal variability of crustal and marine trace elements in the aerosol at Neumayer station, Antarctica, Tellus B, 60, 742–752, https://doi.org/10.1111/j.1600-0889.2008.00372.x, 2008.
Wen, H. and Carignan, J.: Reviews on atmospheric selenium: Emissions, speciation and fate, Atmos. Environ., 41, 7151–7165, https://doi.org/10.1016/j.atmosenv.2007.07.035, 2007.
Wernli, H. and Davies, H. C.: A Lagrangian-based analysis of extratropical cyclones. I: The method and some applications, Q. J. Roy. Meteorol. Soc., 123, 467–489, https://doi.org/10.1002/qj.49712353811, 1997.
Willey, J. D., Mullaugh, K. M., Kieber, R. J., Avery Jr., G. B., and Mead, R. N.: Controls on the redox potential of rainwater, Environ. Sci. Technol., 46, 13103–13111, https://doi.org/10.1021/es302569j, 2012.
Williams, E. and Stanfill, S.: The physical origin of the land–ocean contrast in lightning activity, C. R. Phys., 3, 1277–1292, https://doi.org/10.1016/S1631-0705(02)01407-X, 2002.
Winkel, L. H. E., Vriens, B., Jones, G. D., Schneider, L. S., Pilon-Smits, E., and Bañuelos, G. S.: Selenium Cycling Across Soil-Plant-Atmosphere Interfaces: A Critical Review, Nutrients, 7, 4199–4239, https://doi.org/10.3390/nu7064199, 2015.
Yan, R., Gauthier, D., Flamant, G., and Wang, Y.: Behavior of selenium in the combustion of coal or coke spiked with Se, Combust. Flame, 138, 20–29, https://doi.org/10.1016/j.combustflame.2004.03.010, 2004.
Yang, K. X. and Husain, L.: Ultratrace Determination of Selenium by Hydride Generation–Inductively Coupled Plasma Mass Spectrometry Operated Under Nonrobust Plasma Conditions, Spectrosc. Lett., 39, 187–201, https://doi.org/10.1080/00387010500531233, 2006.
Zhao, J., Peng, P. A., Song, J., Ma, S., Sheng, G., and Fu, J.: Characterization of organic matter in total suspended particles by thermodesorption and pyrolysis-gas chromatography-mass spectrometry, J. Environ. Sci., 21, 1658–1666, https://doi.org/10.1016/S1001-0742(08)62470-5, 2009.
Zhao, P., Yin, Y., and Xiao, H.: The effects of aerosol on development of thunderstorm electrification: A numerical study, Atmos. Res., 153, 376–391, https://doi.org/10.1016/j.atmosres.2014.09.011, 2015.
Short summary
Atmospheric deposition is an important source of selenium (Se) and other health-relevant trace elements in surface environments. We found that the variability in elemental concentrations in atmospheric deposition reflects not only changes in emission sources but also weather conditions during atmospheric removal. Depending on the sources and if Se is derived more locally or from further away, the Se forms can be different, affecting the bioavailability of Se atmospherically supplied to soils.
Atmospheric deposition is an important source of selenium (Se) and other health-relevant trace...
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