Articles | Volume 23, issue 2
https://doi.org/10.5194/acp-23-1565-2023
https://doi.org/10.5194/acp-23-1565-2023
Research article
 | 
27 Jan 2023
Research article |  | 27 Jan 2023

Fates of secondary organic aerosols in the atmosphere identified from compound-specific dual-carbon isotope analysis of oxalic acid

Buqing Xu, Jiao Tang, Tiangang Tang, Shizhen Zhao, Guangcai Zhong, Sanyuan Zhu, Jun Li, and Gan Zhang

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Cited articles

Aggarwal, S. G. and Kawamura, K.: Molecular distributions and stable carbon isotopic compositions of dicarboxylic acids and related compounds in aerosols from Sapporo, Japan: Implications for photochemical aging during long-range atmospheric transport, J. Geophys. Res.-Atmos., 113, D14301, https://doi.org/10.1029/2007jd009365, 2008. 
Anderson, R. S., Huang, L., Iannone, R., Thompson, A. E., and Rudolph, J.: Carbon Kinetic Isotope Effects in the Gas Phase Reactions of Light Alkanes and Ethene with the OH Radical at 296 ± 4 K, J. Phys. Chem. A, 108, 11537–11544, https://doi.org/10.1021/jp0472008, 2004. 
Andersson, A., Deng, J., Du, K., Zheng, M., Yan, C., Skold, M., and Gustafsson, O.: Regionally-varying combustion sources of the January 2013 severe haze events over eastern China, Environ. Sci. Technol., 49, 2038–2043, https://doi.org/10.1021/es503855e, 2015. 
Bikkina, S., Kawamura, K., Miyazaki, Y., and Fu, P.: High abundances of oxalic, azelaic, and glyoxylic acids and methylglyoxal in the open ocean with high biological activity: Implication for secondary OA formation from isoprene, Geophys. Res. Lett., 41, 3649–3657, https://doi.org/10.1002/2014gl059913, 2014. 
Bikkina, S., Kawamura, K., and Sarin, M.: Secondary organic aerosol formation over coastal ocean: inferences from atmospheric water-soluble low molecular weight organic compounds, Environ. Sci. Technol., 51, 4347–4357, https://doi.org/10.1021/acs.est.6b05986, 2017a. 
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We analyzed compound-specific dual-carbon isotope signatures (Δ14C and δ13C) of dominant secondary organic aerosol (SOA) tracer molecules (i.e., oxalic acid) to investigate the fates of SOAs in the atmosphere at five emission hotspots in China. The results indicated that SOA carbon sources and chemical processes producing SOAs vary spatially and seasonally, and these variations need to be included in Chinese climate projection models and air quality management practices.
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