Articles | Volume 21, issue 10
https://doi.org/10.5194/acp-21-7963-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-7963-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 May 2021
Research article |
| 25 May 2021
| 25 May 2021
SO2 and NH3 emissions enhance organosulfur compounds and fine particle formation from the photooxidation of a typical aromatic hydrocarbon
Zhaomin Yang
Environment Research Institute, Shandong University, Qingdao, 266237,
China
Li Xu
Environment Research Institute, Shandong University, Qingdao, 266237,
China
Narcisse T. Tsona
Environment Research Institute, Shandong University, Qingdao, 266237,
China
Jianlong Li
Environment Research Institute, Shandong University, Qingdao, 266237,
China
Xin Luo
Technology Center of Qingdao Customs, Qingdao, 266003, China
Environment Research Institute, Shandong University, Qingdao, 266237,
China
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Short summary
The promotion effects of SO2 and NH3 on particle and organosulfur compound formation from 1,2,4-trimethylbenzene (TMB) photooxidation were observed for the first time. The enhanced organosulfur compounds included hitherto unidentified aromatic sulfonates and organosulfates (OSs). OSs were produced via acid-driven heterogeneous chemistry of hydroperoxides. The production of organosulfur compounds might provide a new pathway for the fate of TMB in regions with considerable SO2 emissions.
The promotion effects of SO2 and NH3 on particle and organosulfur compound formation from...
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