Articles | Volume 21, issue 21
https://doi.org/10.5194/acp-21-16387-2021
https://doi.org/10.5194/acp-21-16387-2021
Research article
 | 
08 Nov 2021
Research article |  | 08 Nov 2021

A predictive thermodynamic framework of cloud droplet activation for chemically unresolved aerosol mixtures, including surface tension, non-ideality, and bulk–surface partitioning

Nønne L. Prisle

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Cited articles

Adamson, A. and Gast, A.: Physical Chemistry of Surfaces, John Wiley & Sons, Inc., sixth edn., 808 pp., 1997. a
Alvarez, N. J., Walker, L. M., and Anna, S. L.: A Microtensiometer To Probe the Effect of Radius of Curvature on Surfactant Transport to a Spherical Interface, Langmuir, 26, 13310–13319, https://doi.org/10.1021/la101870m, 2010. a, b
Asa-Awuku, A., Sullivan, A. P., Hennigan, C. J., Weber, R. J., and Nenes, A.: Investigation of molar volume and surfactant characteristics of water-soluble organic compounds in biomass burning aerosol, Atmos. Chem. Phys., 8, 799–812, https://doi.org/10.5194/acp-8-799-2008, 2008. a
Aumann, E., Hildemann, L., and Tabazadeh, A.: Measuring and modeling the composition and temperature-dependence of surface tension for organic solutions, Atmos. Environ., 44, 329–337, 1967. a
Bianco, H. and Marmur, A.: The Dependence of the Surface Tension of Surfactant Solutions on Drop Size, Journal of Colloid and Interface Science, 151, 517–522, 1992. a
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Short summary
A mass-based Gibbs adsorption model is presented to enable predictive Köhler calculations of droplet growth and activation with considerations of surface partitioning, surface tension, and non-ideal water activity for chemically complex and unresolved surface active aerosol mixtures, including actual atmospheric samples. The model is used to calculate cloud condensation nuclei (CCN) activity of aerosol particles comprising strongly surface-active model atmospheric humic-like substances (HULIS).
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