Articles | Volume 20, issue 23
https://doi.org/10.5194/acp-20-14509-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-14509-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Lignin's ability to nucleate ice via immersion freezing and its stability towards physicochemical treatments and atmospheric processing
Sophie Bogler
Institute for Biogeochemistry and Pollutant Dynamics, ETH Zurich,
Zurich, 8092, Switzerland
Nadine Borduas-Dedekind
CORRESPONDING AUTHOR
Institute for Biogeochemistry and Pollutant Dynamics, ETH Zurich,
Zurich, 8092, Switzerland
Institute for Atmospheric and Climate Sciences, ETH Zurich, Zurich,
8092, Switzerland
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To characterize atmospheric ice nuclei, we present (1) the development of our home-built droplet freezing technique (DFT), which involves the Freezing Ice Nuclei Counter (FINC), (2) an intercomparison campaign using NX-illite and an ambient sample with two other DFTs, and (3) the application of lignin as a soluble and commercial ice nuclei standard with three DFTs. We further compiled the growing number of DFTs in use for atmospheric ice nucleation since 2000 and add FINC.
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Preprint withdrawn
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For characterizing atmospheric ice nuclei, we present (1) the development of our home-built droplet freezing technique (DFT), the Freezing Ice Nuclei Counter (FINC), (2) an intercomparison campaign using NX-illite and an ambient sample with three DFTs, and (3) the application of lignin as a soluble and commercial ice nuclei standard with four DFTs. We further compiled the growing number of DFTs in use for atmospheric ice nucleation since 2000, to which we add FINC.
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Short summary
To study the role of organic matter in ice crystal formation, we investigated the ice nucleation ability of a subcomponent of organic aerosols, the biopolymer lignin, using a droplet-freezing technique. We found that lignin is an ice-active macromolecule with changing abilities based on dilutions. The effects of atmospheric processing and of physicochemical treatments on the ability of lignin solutions to freeze were negligible. Thus, lignin is a recalcitrant ice-nucleating macromolecule.
To study the role of organic matter in ice crystal formation, we investigated the ice nucleation...
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