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Atmospheric Chemistry and Physics
An interactive open-access journal of the European Geosciences Union
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IF5.414
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5.958
5.958
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9.7
9.7
SNIP1.517
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Volume 17, issue 22
Atmos. Chem. Phys., 17, 14039–14054, 2017
https://doi.org/10.5194/acp-17-14039-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-14039-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 17, 14039–14054, 2017
https://doi.org/10.5194/acp-17-14039-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-14039-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article 24 Nov 2017
Research article | 24 Nov 2017
Year-round records of bulk and size-segregated aerosol composition in central Antarctica (Concordia site) – Part 1: Fractionation of sea-salt particles
Michel Legrand et al.
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Stanislav Kutuzov, Michel Legrand, Susanne Preunkert, Patrick Ginot, Vladimir Mikhalenko, Karim Shukurov, Aleksei Poliukhov, and Pavel Toropov
Atmos. Chem. Phys., 19, 14133–14148, https://doi.org/10.5194/acp-19-14133-2019, https://doi.org/10.5194/acp-19-14133-2019, 2019
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Ice cores are one of the most valuable paleo-archives. Here we present analysis of the concentrations of calcium, recorded in ice core from the Caucasus over the past 240 years. We found a correlation between dust in ice and precipitation and soil moisture content in the Middle East and North Africa. The prominent increase in dust concentration in the ice core confirms that the recent droughts in the Fertile Crescent were most severe at least for the past two centuries.
Susanne Preunkert, Michel Legrand, Stanislav Kutuzov, Patrick Ginot, Vladimir Mikhalenko, and Ronny Friedrich
Atmos. Chem. Phys., 19, 14119–14132, https://doi.org/10.5194/acp-19-14119-2019, https://doi.org/10.5194/acp-19-14119-2019, 2019
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This paper reports on an ice core drilled to bedrock at Mt Elbrus (5115 m a.s.l., Russia) to reconstruct the atmospheric pollution since the 19th century in south-eastern Europe. The annual dust-free sulfate record indicates a 7-fold increase from prior to 1900 to 1980–1995. Consistent with past SO2 emission inventories, a much earlier onset and a more pronounced decrease in the sulfur pollution over the last 3 decades are observed in western Europe than in south-eastern and eastern Europe.
Sentia Goursaud, Valérie Masson-Delmotte, Vincent Favier, Suzanne Preunkert, Michel Legrand, Bénédicte Minster, and Martin Werner
The Cryosphere, 13, 1297–1324, https://doi.org/10.5194/tc-13-1297-2019, https://doi.org/10.5194/tc-13-1297-2019, 2019
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We report new water stable isotope records from the first highly resolved firn core drilled in Adélie Land and covering 1998–2014. Using an updated database, we show that mean values are in line with the range of coastal values. Statistical analyses show no relationship between our record and local surface air temperature. Atmospheric back trajectories and isotopic simulations suggest that water stable isotopes in Adélie provide a fingerprint of the variability of atmospheric dynamics.
Rolf Weller, Michel Legrand, and Susanne Preunkert
Atmos. Chem. Phys., 18, 2413–2430, https://doi.org/10.5194/acp-18-2413-2018, https://doi.org/10.5194/acp-18-2413-2018, 2018
Short summary
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We measured aerosol size distributions and the composition of summer aerosol at the continental Antarctic station Kohnen. Two different weather conditions mediated the transport of aerosol: (1) the intermittent impact of cyclones associated with outstanding marine aerosol concentrations and new particle formation and (2) steady long-range transport under prevailing clear sky conditions. The latter air masses were characterized by aged aerosol and less aerosol load.
Michel Legrand, Susanne Preunkert, Rolf Weller, Lars Zipf, Christoph Elsässer, Silke Merchel, Georg Rugel, and Dietmar Wagenbach
Atmos. Chem. Phys., 17, 14055–14073, https://doi.org/10.5194/acp-17-14055-2017, https://doi.org/10.5194/acp-17-14055-2017, 2017
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Levels of MSA and sulfate at inland Antarctica are documented from multiple year-round records of bulk and size-segregated aerosol samplings. A striking difference in the seasonality of sulfur aerosol composition, characterized by a MSA to nssSO4 ratio reaching a minimum in summer over the Antarctic plateau (0.05) and a maximum at the coast (up to 0.40), is clearly established. An efficient chemical destruction of MSA is suggested to take place over the Antarctic plateau in summer.
Anna Kozachek, Vladimir Mikhalenko, Valérie Masson-Delmotte, Alexey Ekaykin, Patrick Ginot, Stanislav Kutuzov, Michel Legrand, Vladimir Lipenkov, and Susanne Preunkert
Clim. Past, 13, 473–489, https://doi.org/10.5194/cp-13-473-2017, https://doi.org/10.5194/cp-13-473-2017, 2017
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
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We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
Sentia Goursaud, Valérie Masson-Delmotte, Vincent Favier, Susanne Preunkert, Michel Fily, Hubert Gallée, Bruno Jourdain, Michel Legrand, Olivier Magand, Bénédicte Minster, and Martin Werner
The Cryosphere, 11, 343–362, https://doi.org/10.5194/tc-11-343-2017, https://doi.org/10.5194/tc-11-343-2017, 2017
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Uncertainty of sea level changes is a challenge. As Antarctica is the biggest water reservoir, it is necessary to know how it will contribute. To be able to simulate it, an understanding of past climate is to be achieved, for instance, by studying the ice cores. As climate change is different in different regions, observations are needed all over the continent. Studying an ice core in Adélie Land, we can conclude that there are no changes there at decadal scale over the period 1947–2007.
Michel Legrand, Joseph McConnell, Hubertus Fischer, Eric W. Wolff, Susanne Preunkert, Monica Arienzo, Nathan Chellman, Daiana Leuenberger, Olivia Maselli, Philip Place, Michael Sigl, Simon Schüpbach, and Mike Flannigan
Clim. Past, 12, 2033–2059, https://doi.org/10.5194/cp-12-2033-2016, https://doi.org/10.5194/cp-12-2033-2016, 2016
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Here, we review previous attempts made to reconstruct past forest fire using chemical signals recorded in Greenland ice. We showed that the Greenland ice records of ammonium, found to be a good fire proxy, consistently indicate changing fire activity in Canada in response to past climatic conditions that occurred since the last 15 000 years, including the Little Ice Age and the last large climatic transition.
Hélène Angot, Iris Dion, Nicolas Vogel, Michel Legrand, Olivier Magand, and Aurélien Dommergue
Atmos. Chem. Phys., 16, 8265–8279, https://doi.org/10.5194/acp-16-8265-2016, https://doi.org/10.5194/acp-16-8265-2016, 2016
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This paper presents a multi-year record of atmospheric gaseous elemental mercury (Hg(0)) at Dumont d’Urville (DDU) on the East Antarctic coast. This record reveals particularities that are not seen at other coastal Antarctic sites, likely due to the more frequent arrival of inland air masses at DDU than at other coastal sites, and to the influence of oceanic air masses. This study confirms the influence of processes observed inland on the cycle of atmospheric mercury at a continental scale.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
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Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
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Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
N. Zannoni, V. Gros, M. Lanza, R. Sarda, B. Bonsang, C. Kalogridis, S. Preunkert, M. Legrand, C. Jambert, C. Boissard, and J. Lathiere
Atmos. Chem. Phys., 16, 1619–1636, https://doi.org/10.5194/acp-16-1619-2016, https://doi.org/10.5194/acp-16-1619-2016, 2016
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Our manuscript shows results of OH reactivity and Biogenic Volatile Organic Compounds (BVOCs) concentration during a field experiment conducted in late spring 2014 at the Observatoire de Haute Provence (OHP) site. We found that OH reactivity is among the highest measured in forests globally (69 s−1) and it is mainly due to isoprene. No missing reactivity was present during daytime inside or above the canopy, while 50 % missing reactivity was found by night at both heights.
V. Mikhalenko, S. Sokratov, S. Kutuzov, P. Ginot, M. Legrand, S. Preunkert, I. Lavrentiev, A. Kozachek, A. Ekaykin, X. Faïn, S. Lim, U. Schotterer, V. Lipenkov, and P. Toropov
The Cryosphere, 9, 2253–2270, https://doi.org/10.5194/tc-9-2253-2015, https://doi.org/10.5194/tc-9-2253-2015, 2015
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For the first time an ice core unaffected by melting was recovered from the western Elbrus plateau in the Caucasus. The preserved chemical and isotopic data are considered a source of paleo-climate information for southern/eastern Europe. Considerable snow accumulation (about 1500mm w.e.) and high sampling resolution allowed seasonal variability to be obtained in climate signals, covering a time period of about 200 years. Ice flow models suggest that the basal ice age can be more than 600 years.
A. Kukui, M. Legrand, S. Preunkert, M. M. Frey, R. Loisil, J. Gil Roca, B. Jourdain, M. D. King, J. L. France, and G. Ancellet
Atmos. Chem. Phys., 14, 12373–12392, https://doi.org/10.5194/acp-14-12373-2014, https://doi.org/10.5194/acp-14-12373-2014, 2014
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Concentrations of OH radicals and the sum of peroxy radicals, RO2, were measured in the boundary layer for the first time on the East Antarctic Plateau at the Concordia Station during the austral summer 2011/2012. The concentrations of radicals were comparable to those observed at the South Pole, confirming that the elevated oxidative capacity of the Antarctic atmospheric boundary layer found at the South Pole is not restricted to the South Pole but common over the high Antarctic plateau.
X. Faïn, J. Chappellaz, R. H. Rhodes, C. Stowasser, T. Blunier, J. R. McConnell, E. J. Brook, S. Preunkert, M. Legrand, T. Debois, and D. Romanini
Clim. Past, 10, 987–1000, https://doi.org/10.5194/cp-10-987-2014, https://doi.org/10.5194/cp-10-987-2014, 2014
Christian Vincent, Diego Cusicanqui, Bruno Jourdain, Olivier Laarman, Delphine Six, Adrien Gilbert, Andrea Walpersdorf, Antoine Rabatel, Luc Piard, Florent Gimbert, Olivier Gagliardini, Vincent Peyaud, Laurent Arnaud, Emmanuel Thibert, Fanny Brun, and Ugo Nanni
The Cryosphere Discuss., https://doi.org/10.5194/tc-2020-239, https://doi.org/10.5194/tc-2020-239, 2020
Preprint under review for TC
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In situ glacier point mass-balances data are crucial to assess climate change in different regions of the world. Unfortunately, these data are rare because huge efforts are required to conduct in situ measurements on glaciers. Here, we propose a new approach from remote sensing observations. The method has been tested on Argentière and Mer de Glace glaciers (France). It should be possible to apply this method to high spatial resolution satellite images as well on numerous glaciers in the world.
Paolo Laj, Alessandro Bigi, Clémence Rose, Elisabeth Andrews, Cathrine Lund Myhre, Martine Collaud Coen, Yong Lin, Alfred Wiedensohler, Michael Schulz, John A. Ogren, Markus Fiebig, Jonas Gliß, Augustin Mortier, Marco Pandolfi, Tuukka Petäja, Sang-Woo Kim, Wenche Aas, Jean-Philippe Putaud, Olga Mayol-Bracero, Melita Keywood, Lorenzo Labrador, Pasi Aalto, Erik Ahlberg, Lucas Alados Arboledas, Andrés Alastuey, Marcos Andrade, Begoña Artíñano, Stina Ausmeel, Todor Arsov, Eija Asmi, John Backman, Urs Baltensperger, Susanne Bastian, Olaf Bath, Johan Paul Beukes, Benjamin T. Brem, Nicolas Bukowiecki, Sébastien Conil, Cedric Couret, Derek Day, Wan Dayantolis, Anna Degorska, Konstantinos Eleftheriadis, Prodromos Fetfatzis, Olivier Favez, Harald Flentje, Maria I. Gini, Asta Gregorič, Martin Gysel-Beer, A. Gannet Hallar, Jenny Hand, Andras Hoffer, Christoph Hueglin, Rakesh K. Hooda, Antti Hyvärinen, Ivo Kalapov, Nikos Kalivitis, Anne Kasper-Giebl, Jeong Eun Kim, Giorgos Kouvarakis, Irena Kranjc, Radovan Krejci, Markku Kulmala, Casper Labuschagne, Hae-Jung Lee, Heikki Lihavainen, Neng-Huei Lin, Gunter Löschau, Krista Luoma, Angela Marinoni, Sebastiao Martins Dos Santos, Frank Meinhardt, Maik Merkel, Jean-Marc Metzger, Nikolaos Mihalopoulos, Nhat Anh Nguyen, Jakub Ondracek, Noemi Pérez, Maria Rita Perrone, Jean-Eudes Petit, David Picard, Jean-Marc Pichon, Veronique Pont, Natalia Prats, Anthony Prenni, Fabienne Reisen, Salvatore Romano, Karine Sellegri, Sangeeta Sharma, Gerhard Schauer, Patrick Sheridan, James Patrick Sherman, Maik Schütze, Andreas Schwerin, Ralf Sohmer, Mar Sorribas, Martin Steinbacher, Junying Sun, Gloria Titos, Barbara Toczko, Thomas Tuch, Pierre Tulet, Peter Tunved, Ville Vakkari, Fernando Velarde, Patricio Velasquez, Paolo Villani, Sterios Vratolis, Sheng-Hsiang Wang, Kay Weinhold, Rolf Weller, Margarita Yela, Jesus Yus-Diez, Vladimir Zdimal, Paul Zieger, and Nadezda Zikova
Atmos. Meas. Tech., 13, 4353–4392, https://doi.org/10.5194/amt-13-4353-2020, https://doi.org/10.5194/amt-13-4353-2020, 2020
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The paper establishes the fiducial reference of the GAW aerosol network providing the fully characterized value chain to the provision of four climate-relevant aerosol properties from ground-based sites. Data from almost 90 stations worldwide are reported for a reference year, 2017, providing a unique and very robust view of the variability of these variables worldwide. Current gaps in the GAW network are analysed and requirements for the Global Climate Monitoring System are proposed.
Martine Collaud Coen, Elisabeth Andrews, Andrés Alastuey, Todor Petkov Arsov, John Backman, Benjamin T. Brem, Nicolas Bukowiecki, Cédric Couret, Konstantinos Eleftheriadis, Harald Flentje, Markus Fiebig, Martin Gysel-Beer, Jenny L. Hand, András Hoffer, Rakesh Hooda, Christoph Hueglin, Warren Joubert, Melita Keywood, Jeong Eun Kim, Sang-Woo Kim, Casper Labuschagne, Neng-Huei Lin, Yong Lin, Cathrine Lund Myhre, Krista Luoma, Hassan Lyamani, Angela Marinoni, Olga L. Mayol-Bracero, Nikos Mihalopoulos, Marco Pandolfi, Natalia Prats, Anthony J. Prenni, Jean-Philippe Putaud, Ludwig Ries, Fabienne Reisen, Karine Sellegri, Sangeeta Sharma, Patrick Sheridan, James Patrick Sherman, Junying Sun, Gloria Titos, Elvis Torres, Thomas Tuch, Rolf Weller, Alfred Wiedensohler, Paul Zieger, and Paolo Laj
Atmos. Chem. Phys., 20, 8867–8908, https://doi.org/10.5194/acp-20-8867-2020, https://doi.org/10.5194/acp-20-8867-2020, 2020
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Long-term trends of aerosol radiative properties (52 stations) prove that aerosol load has significantly decreased over the last 20 years. Scattering trends are negative in Europe (EU) and North America (NA), not ss in Asia, and show a mix of positive and negative trends at polar stations. Absorption has mainly negative trends. The single scattering albedo has positive trends in Asia and eastern EU and negative in western EU and NA, leading to a global positive median trend of 0.02 % per year.
Christian Vincent, Adrien Gilbert, Bruno Jourdain, Luc Piard, Patrick Ginot, Vladimir Mikhalenko, Philippe Possenti, Emmanuel Le Meur, Olivier Laarman, and Delphine Six
The Cryosphere, 14, 925–934, https://doi.org/10.5194/tc-14-925-2020, https://doi.org/10.5194/tc-14-925-2020, 2020
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We observed very low glacier thickness changes over the last decades at very-high-elevation glaciated areas on Mont Blanc. Conversely, measurements performed in deep boreholes since 1994 reveal strong changes in englacial temperature reaching 1.5 °C at a depth of 50 m. We conclude that at such very high elevations, current changes in climate do not lead to visible changes in glacier thickness but cause invisible changes within the glacier in terms of englacial temperatures.
Markus M. Frey, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Xin Yang, Anna E. Jones, Michelle G. Nerentorp Mastromonaco, David H. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 20, 2549–2578, https://doi.org/10.5194/acp-20-2549-2020, https://doi.org/10.5194/acp-20-2549-2020, 2020
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A winter sea ice expedition to Antarctica provided the first direct observations of sea salt aerosol (SSA) production during snow storms above sea ice, thereby validating a model hypothesis to account for winter time SSA maxima in Antarctica not explained otherwise. Defining SSA sources is important given the critical roles that aerosol plays for climate, for air quality and as a potential ice core proxy for sea ice conditions in the past.
Bette L. Otto-Bliesner, Esther C. Brady, Anni Zhao, Chris Brierley, Yarrow Axford, Emilie Capron, Aline Govin, Jeremy Hoffman, Elizabeth Isaacs, Masa Kageyama, Paolo Scussolini, Polychronis C. Tzedakis, Charlie Williams, Eric Wolff, Ayako Abe-Ouchi, Pascale Braconnot, Silvana Ramos Buarque, Jian Cao, Anne de Vernal, Maria Vittoria Guarino, Chuncheng Guo, Allegra N. LeGrande, Gerrit Lohmann, Katrin Meissner, Laurie Menviel, Kerim Nisancioglu, Ryouta O'ishi, David Salas Y Melia, Xioaoxu Shi, Marie Sicard, Louise Sime, Robert Tomas, Evgeny Volodin, Nicolas Yeung, Qiong Zhang, Zhonghi Zhang, and Weipeng Zheng
Clim. Past Discuss., https://doi.org/10.5194/cp-2019-174, https://doi.org/10.5194/cp-2019-174, 2020
Revised manuscript under review for CP
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The CMIP6-PMIP4 Tier 1 lig127k experiment was designed to address the climate responses to strong orbital forcing. We present a multi-model ensemble of 17 climate models, most of which have also completed the CMIP6 DECK experiments and thus important for assessing future projections. The lig127k simulations show strong summer warming over the NH continents. More than half of the models simulate a retreat of the Arctic minimum summer ice edge similar to the average of the last 2 decades.
Zsófia Jurányi and Rolf Weller
Atmos. Chem. Phys., 19, 14417–14430, https://doi.org/10.5194/acp-19-14417-2019, https://doi.org/10.5194/acp-19-14417-2019, 2019
Stanislav Kutuzov, Michel Legrand, Susanne Preunkert, Patrick Ginot, Vladimir Mikhalenko, Karim Shukurov, Aleksei Poliukhov, and Pavel Toropov
Atmos. Chem. Phys., 19, 14133–14148, https://doi.org/10.5194/acp-19-14133-2019, https://doi.org/10.5194/acp-19-14133-2019, 2019
Short summary
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Ice cores are one of the most valuable paleo-archives. Here we present analysis of the concentrations of calcium, recorded in ice core from the Caucasus over the past 240 years. We found a correlation between dust in ice and precipitation and soil moisture content in the Middle East and North Africa. The prominent increase in dust concentration in the ice core confirms that the recent droughts in the Fertile Crescent were most severe at least for the past two centuries.
Susanne Preunkert, Michel Legrand, Stanislav Kutuzov, Patrick Ginot, Vladimir Mikhalenko, and Ronny Friedrich
Atmos. Chem. Phys., 19, 14119–14132, https://doi.org/10.5194/acp-19-14119-2019, https://doi.org/10.5194/acp-19-14119-2019, 2019
Short summary
Short summary
This paper reports on an ice core drilled to bedrock at Mt Elbrus (5115 m a.s.l., Russia) to reconstruct the atmospheric pollution since the 19th century in south-eastern Europe. The annual dust-free sulfate record indicates a 7-fold increase from prior to 1900 to 1980–1995. Consistent with past SO2 emission inventories, a much earlier onset and a more pronounced decrease in the sulfur pollution over the last 3 decades are observed in western Europe than in south-eastern and eastern Europe.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell N. Drysdale, Philip L. Gibbard, Lauren Gregoire, Feng He, Ruza F. Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis C. Tzedakis, Eric Wolff, and Xu Zhang
Geosci. Model Dev., 12, 3649–3685, https://doi.org/10.5194/gmd-12-3649-2019, https://doi.org/10.5194/gmd-12-3649-2019, 2019
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As part of the Past Global Changes (PAGES) working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation for the Paleoclimate Modelling Intercomparison Project (PMIP4). This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. Key paleo-records for model-data comparison are also included.
Xin Yang, Markus M. Frey, Rachael H. Rhodes, Sarah J. Norris, Ian M. Brooks, Philip S. Anderson, Kouichi Nishimura, Anna E. Jones, and Eric W. Wolff
Atmos. Chem. Phys., 19, 8407–8424, https://doi.org/10.5194/acp-19-8407-2019, https://doi.org/10.5194/acp-19-8407-2019, 2019
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This is a comprehensive model–data comparison aiming to evaluate the proposed mechanism of sea salt aerosol (SSA) production from blowing snow on sea ice. Some key parameters such as snow salinity and blowing-snow size distribution were constrained by data collected in the Weddell Sea. The good agreement between modelled SSA and the cruise data strongly indicates that sea ice surface is a large SSA source in polar regions, a process which has not been considered in current climate models.
Sentia Goursaud, Valérie Masson-Delmotte, Vincent Favier, Suzanne Preunkert, Michel Legrand, Bénédicte Minster, and Martin Werner
The Cryosphere, 13, 1297–1324, https://doi.org/10.5194/tc-13-1297-2019, https://doi.org/10.5194/tc-13-1297-2019, 2019
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We report new water stable isotope records from the first highly resolved firn core drilled in Adélie Land and covering 1998–2014. Using an updated database, we show that mean values are in line with the range of coastal values. Statistical analyses show no relationship between our record and local surface air temperature. Atmospheric back trajectories and isotopic simulations suggest that water stable isotopes in Adélie provide a fingerprint of the variability of atmospheric dynamics.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell Drysdale, Philip Gibbard, Lauren Gregoire, Feng He, Ruza Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis Tzedakis, Eric Wolff, and Xu Zhang
Clim. Past Discuss., https://doi.org/10.5194/cp-2018-106, https://doi.org/10.5194/cp-2018-106, 2018
Preprint withdrawn
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The penultimate deglaciation (~ 138–128 ka), which represents the transition into the Last Interglacial period, provides a framework to investigate the climate and environmental response to large changes in boundary conditions. Here, as part of the PAGES-PMIP working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation as well as a selection of paleo records for upcoming model-data comparisons.
Rolf Weller, Michel Legrand, and Susanne Preunkert
Atmos. Chem. Phys., 18, 2413–2430, https://doi.org/10.5194/acp-18-2413-2018, https://doi.org/10.5194/acp-18-2413-2018, 2018
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We measured aerosol size distributions and the composition of summer aerosol at the continental Antarctic station Kohnen. Two different weather conditions mediated the transport of aerosol: (1) the intermittent impact of cyclones associated with outstanding marine aerosol concentrations and new particle formation and (2) steady long-range transport under prevailing clear sky conditions. The latter air masses were characterized by aged aerosol and less aerosol load.
Michel Legrand, Susanne Preunkert, Rolf Weller, Lars Zipf, Christoph Elsässer, Silke Merchel, Georg Rugel, and Dietmar Wagenbach
Atmos. Chem. Phys., 17, 14055–14073, https://doi.org/10.5194/acp-17-14055-2017, https://doi.org/10.5194/acp-17-14055-2017, 2017
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Levels of MSA and sulfate at inland Antarctica are documented from multiple year-round records of bulk and size-segregated aerosol samplings. A striking difference in the seasonality of sulfur aerosol composition, characterized by a MSA to nssSO4 ratio reaching a minimum in summer over the Antarctic plateau (0.05) and a maximum at the coast (up to 0.40), is clearly established. An efficient chemical destruction of MSA is suggested to take place over the Antarctic plateau in summer.
Rachael H. Rhodes, Xin Yang, Eric W. Wolff, Joseph R. McConnell, and Markus M. Frey
Atmos. Chem. Phys., 17, 9417–9433, https://doi.org/10.5194/acp-17-9417-2017, https://doi.org/10.5194/acp-17-9417-2017, 2017
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Sea salt aerosol comes from the open ocean or the sea ice surface. In the polar regions, this opens up the possibility of reconstructing sea ice history using sea salt recorded in ice cores. We use a chemical transport model to demonstrate that the sea ice source of aerosol is important in the Arctic. For the first time, we simulate realistic Greenland ice core sea salt in a process-based model. The importance of the sea ice source increases from south to north across the Greenland ice sheet.
Anna Kozachek, Vladimir Mikhalenko, Valérie Masson-Delmotte, Alexey Ekaykin, Patrick Ginot, Stanislav Kutuzov, Michel Legrand, Vladimir Lipenkov, and Susanne Preunkert
Clim. Past, 13, 473–489, https://doi.org/10.5194/cp-13-473-2017, https://doi.org/10.5194/cp-13-473-2017, 2017
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
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We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
Sentia Goursaud, Valérie Masson-Delmotte, Vincent Favier, Susanne Preunkert, Michel Fily, Hubert Gallée, Bruno Jourdain, Michel Legrand, Olivier Magand, Bénédicte Minster, and Martin Werner
The Cryosphere, 11, 343–362, https://doi.org/10.5194/tc-11-343-2017, https://doi.org/10.5194/tc-11-343-2017, 2017
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Uncertainty of sea level changes is a challenge. As Antarctica is the biggest water reservoir, it is necessary to know how it will contribute. To be able to simulate it, an understanding of past climate is to be achieved, for instance, by studying the ice cores. As climate change is different in different regions, observations are needed all over the continent. Studying an ice core in Adélie Land, we can conclude that there are no changes there at decadal scale over the period 1947–2007.
Michel Legrand, Joseph McConnell, Hubertus Fischer, Eric W. Wolff, Susanne Preunkert, Monica Arienzo, Nathan Chellman, Daiana Leuenberger, Olivia Maselli, Philip Place, Michael Sigl, Simon Schüpbach, and Mike Flannigan
Clim. Past, 12, 2033–2059, https://doi.org/10.5194/cp-12-2033-2016, https://doi.org/10.5194/cp-12-2033-2016, 2016
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Here, we review previous attempts made to reconstruct past forest fire using chemical signals recorded in Greenland ice. We showed that the Greenland ice records of ammonium, found to be a good fire proxy, consistently indicate changing fire activity in Canada in response to past climatic conditions that occurred since the last 15 000 years, including the Little Ice Age and the last large climatic transition.
Emma J. Stone, Emilie Capron, Daniel J. Lunt, Antony J. Payne, Joy S. Singarayer, Paul J. Valdes, and Eric W. Wolff
Clim. Past, 12, 1919–1932, https://doi.org/10.5194/cp-12-1919-2016, https://doi.org/10.5194/cp-12-1919-2016, 2016
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Climate models forced only with greenhouse gas concentrations and orbital parameters representative of the early Last Interglacial are unable to reproduce the observed colder-than-present temperatures in the North Atlantic and the warmer-than-present temperatures in the Southern Hemisphere. Using a climate model forced also with a freshwater amount derived from data representing melting from the remnant Northern Hemisphere ice sheets accounts for this response via the bipolar seesaw mechanism.
Hilkka Timonen, Mike Cubison, Minna Aurela, David Brus, Heikki Lihavainen, Risto Hillamo, Manjula Canagaratna, Bettina Nekat, Rolf Weller, Douglas Worsnop, and Sanna Saarikoski
Atmos. Meas. Tech., 9, 3263–3281, https://doi.org/10.5194/amt-9-3263-2016, https://doi.org/10.5194/amt-9-3263-2016, 2016
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The applicability, methods and limitations of constrained peak fitting on mass spectra of low mass resolving power (m∕Δm50 ∼ 500) recorded with a time-of-flight aerosol chemical speciation monitor (ToF-ACSM) are explored. Calibration measurements and ambient data are used to exemplify the methods that should be applied to maximise data quality and assess confidence in peak-fitting results.
Hélène Angot, Iris Dion, Nicolas Vogel, Michel Legrand, Olivier Magand, and Aurélien Dommergue
Atmos. Chem. Phys., 16, 8265–8279, https://doi.org/10.5194/acp-16-8265-2016, https://doi.org/10.5194/acp-16-8265-2016, 2016
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This paper presents a multi-year record of atmospheric gaseous elemental mercury (Hg(0)) at Dumont d’Urville (DDU) on the East Antarctic coast. This record reveals particularities that are not seen at other coastal Antarctic sites, likely due to the more frequent arrival of inland air masses at DDU than at other coastal sites, and to the influence of oceanic air masses. This study confirms the influence of processes observed inland on the cycle of atmospheric mercury at a continental scale.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
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Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Ikumi Oyabu, Yoshinori Iizuka, Eric Wolff, and Margareta Hansson
Clim. Past Discuss., https://doi.org/10.5194/cp-2016-42, https://doi.org/10.5194/cp-2016-42, 2016
Manuscript not accepted for further review
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This study presented the chemical compositions of non-volatile particles around the last termination in the Dome C ice core by using the sublimation-EDS method. The major soluble salt particles are CaSO4, Na2SO4, and NaCl, and time-series changes in the composition of these salts are similar to those for the Dome Fuji ice core. However, some differences occurred. The sulfatization rate of NaCl at Dome C is higher than that at Dome Fuji.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
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Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
N. Zannoni, V. Gros, M. Lanza, R. Sarda, B. Bonsang, C. Kalogridis, S. Preunkert, M. Legrand, C. Jambert, C. Boissard, and J. Lathiere
Atmos. Chem. Phys., 16, 1619–1636, https://doi.org/10.5194/acp-16-1619-2016, https://doi.org/10.5194/acp-16-1619-2016, 2016
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Our manuscript shows results of OH reactivity and Biogenic Volatile Organic Compounds (BVOCs) concentration during a field experiment conducted in late spring 2014 at the Observatoire de Haute Provence (OHP) site. We found that OH reactivity is among the highest measured in forests globally (69 s−1) and it is mainly due to isoprene. No missing reactivity was present during daytime inside or above the canopy, while 50 % missing reactivity was found by night at both heights.
V. Mikhalenko, S. Sokratov, S. Kutuzov, P. Ginot, M. Legrand, S. Preunkert, I. Lavrentiev, A. Kozachek, A. Ekaykin, X. Faïn, S. Lim, U. Schotterer, V. Lipenkov, and P. Toropov
The Cryosphere, 9, 2253–2270, https://doi.org/10.5194/tc-9-2253-2015, https://doi.org/10.5194/tc-9-2253-2015, 2015
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For the first time an ice core unaffected by melting was recovered from the western Elbrus plateau in the Caucasus. The preserved chemical and isotopic data are considered a source of paleo-climate information for southern/eastern Europe. Considerable snow accumulation (about 1500mm w.e.) and high sampling resolution allowed seasonal variability to be obtained in climate signals, covering a time period of about 200 years. Ice flow models suggest that the basal ice age can be more than 600 years.
S. Fujita, F. Parrenin, M. Severi, H. Motoyama, and E. W. Wolff
Clim. Past, 11, 1395–1416, https://doi.org/10.5194/cp-11-1395-2015, https://doi.org/10.5194/cp-11-1395-2015, 2015
R. Weller, K. Schmidt, K. Teinilä, and R. Hillamo
Atmos. Chem. Phys., 15, 11399–11410, https://doi.org/10.5194/acp-15-11399-2015, https://doi.org/10.5194/acp-15-11399-2015, 2015
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We measured condensation particle (CP) concentrations and particle size distributions at the coastal Antarctic station Neumayer. Several nucleation events were observed, but particles did not grow up to sizes required for acting as cloud condensation nuclei. A simple estimation indicated that apart from sulfuric acid, the derived growth rates required other low volatile precursor vapours.
T. A. Berhanu, J. Savarino, J. Erbland, W. C. Vicars, S. Preunkert, J. F. Martins, and M. S. Johnson
Atmos. Chem. Phys., 15, 11243–11256, https://doi.org/10.5194/acp-15-11243-2015, https://doi.org/10.5194/acp-15-11243-2015, 2015
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In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
M. M. Frey, H. K. Roscoe, A. Kukui, J. Savarino, J. L. France, M. D. King, M. Legrand, and S. Preunkert
Atmos. Chem. Phys., 15, 7859–7875, https://doi.org/10.5194/acp-15-7859-2015, https://doi.org/10.5194/acp-15-7859-2015, 2015
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Surprisingly large concentrations and flux of atmospheric nitrogen oxides were measured at Dome C, East Antarctica. It was found that the surface snow holds a significant reservoir of photochemically produced NOx and is a sink of gas-phase ozone. Main drivers of NOx snow emissions were large snow nitrate concentrations, with contributions of increased UV from decreases in stratospheric ozone. Observed halogen and hydroxyl radical concentrations were too low to explain large NO2:NO ratios.
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
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During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
H. Gallée, S. Preunkert, S. Argentini, M. M. Frey, C. Genthon, B. Jourdain, I. Pietroni, G. Casasanta, H. Barral, E. Vignon, C. Amory, and M. Legrand
Atmos. Chem. Phys., 15, 6225–6236, https://doi.org/10.5194/acp-15-6225-2015, https://doi.org/10.5194/acp-15-6225-2015, 2015
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Regional climate model MAR was run for the region of Dome C located on the East Antarctic plateau, during summer 2011–2012, with a high vertical resolution in the lower troposphere. MAR is generally in very good agreement with the observations and provides sufficiently reliable information about surface turbulent fluxes and vertical profiles of vertical diffusion coefficients when discussing the representativeness of chemical measurements made nearby the ground surface at Dome C.
F. Parrenin, S. Fujita, A. Abe-Ouchi, K. Kawamura, V. Masson-Delmotte, H. Motoyama, F. Saito, M. Severi, B. Stenni, R. Uemura, and E. Wolff
Clim. Past Discuss., https://doi.org/10.5194/cpd-11-377-2015, https://doi.org/10.5194/cpd-11-377-2015, 2015
Revised manuscript has not been submitted
A. Kukui, M. Legrand, S. Preunkert, M. M. Frey, R. Loisil, J. Gil Roca, B. Jourdain, M. D. King, J. L. France, and G. Ancellet
Atmos. Chem. Phys., 14, 12373–12392, https://doi.org/10.5194/acp-14-12373-2014, https://doi.org/10.5194/acp-14-12373-2014, 2014
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Concentrations of OH radicals and the sum of peroxy radicals, RO2, were measured in the boundary layer for the first time on the East Antarctic Plateau at the Concordia Station during the austral summer 2011/2012. The concentrations of radicals were comparable to those observed at the South Pole, confirming that the elevated oxidative capacity of the Antarctic atmospheric boundary layer found at the South Pole is not restricted to the South Pole but common over the high Antarctic plateau.
A. E. Jones, N. Brough, P. S. Anderson, and E. W. Wolff
Atmos. Chem. Phys., 14, 11843–11851, https://doi.org/10.5194/acp-14-11843-2014, https://doi.org/10.5194/acp-14-11843-2014, 2014
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We report observations of nitric acid and peroxynitric acid, in coastal Antarctica during winter. During winter, it is dark 24h per day, so there is no influence of sunlight on atmospheric composition. We show that observed variability in concentrations is highly correlated with changes in temperature. We derive enthalpies of adsorption and show they are consistent with those derived in laboratory studies. The Antarctic, during winter, is an ideal natural laboratory to study air-snow exchange.
M. Legrand, S. Preunkert, M. Frey, Th. Bartels-Rausch, A. Kukui, M. D. King, J. Savarino, M. Kerbrat, and B. Jourdain
Atmos. Chem. Phys., 14, 9963–9976, https://doi.org/10.5194/acp-14-9963-2014, https://doi.org/10.5194/acp-14-9963-2014, 2014
X. Faïn, J. Chappellaz, R. H. Rhodes, C. Stowasser, T. Blunier, J. R. McConnell, E. J. Brook, S. Preunkert, M. Legrand, T. Debois, and D. Romanini
Clim. Past, 10, 987–1000, https://doi.org/10.5194/cp-10-987-2014, https://doi.org/10.5194/cp-10-987-2014, 2014
R. Weller, I. Levin, D. Schmithüsen, M. Nachbar, J. Asseng, and D. Wagenbach
Atmos. Chem. Phys., 14, 3843–3853, https://doi.org/10.5194/acp-14-3843-2014, https://doi.org/10.5194/acp-14-3843-2014, 2014
A. M. Foley, D. Dalmonech, A. D. Friend, F. Aires, A. T. Archibald, P. Bartlein, L. Bopp, J. Chappellaz, P. Cox, N. R. Edwards, G. Feulner, P. Friedlingstein, S. P. Harrison, P. O. Hopcroft, C. D. Jones, J. Kolassa, J. G. Levine, I. C. Prentice, J. Pyle, N. Vázquez Riveiros, E. W. Wolff, and S. Zaehle
Biogeosciences, 10, 8305–8328, https://doi.org/10.5194/bg-10-8305-2013, https://doi.org/10.5194/bg-10-8305-2013, 2013
H. Fischer, J. Severinghaus, E. Brook, E. Wolff, M. Albert, O. Alemany, R. Arthern, C. Bentley, D. Blankenship, J. Chappellaz, T. Creyts, D. Dahl-Jensen, M. Dinn, M. Frezzotti, S. Fujita, H. Gallee, R. Hindmarsh, D. Hudspeth, G. Jugie, K. Kawamura, V. Lipenkov, H. Miller, R. Mulvaney, F. Parrenin, F. Pattyn, C. Ritz, J. Schwander, D. Steinhage, T. van Ommen, and F. Wilhelms
Clim. Past, 9, 2489–2505, https://doi.org/10.5194/cp-9-2489-2013, https://doi.org/10.5194/cp-9-2489-2013, 2013
M. Legrand, S. Preunkert, B. Jourdain, J. Guilhermet, X. Fa{ï}n, I. Alekhina, and J. R. Petit
Clim. Past, 9, 2195–2211, https://doi.org/10.5194/cp-9-2195-2013, https://doi.org/10.5194/cp-9-2195-2013, 2013
L. Bazin, A. Landais, B. Lemieux-Dudon, H. Toyé Mahamadou Kele, D. Veres, F. Parrenin, P. Martinerie, C. Ritz, E. Capron, V. Lipenkov, M.-F. Loutre, D. Raynaud, B. Vinther, A. Svensson, S. O. Rasmussen, M. Severi, T. Blunier, M. Leuenberger, H. Fischer, V. Masson-Delmotte, J. Chappellaz, and E. Wolff
Clim. Past, 9, 1715–1731, https://doi.org/10.5194/cp-9-1715-2013, https://doi.org/10.5194/cp-9-1715-2013, 2013
D. Veres, L. Bazin, A. Landais, H. Toyé Mahamadou Kele, B. Lemieux-Dudon, F. Parrenin, P. Martinerie, E. Blayo, T. Blunier, E. Capron, J. Chappellaz, S. O. Rasmussen, M. Severi, A. Svensson, B. Vinther, and E. W. Wolff
Clim. Past, 9, 1733–1748, https://doi.org/10.5194/cp-9-1733-2013, https://doi.org/10.5194/cp-9-1733-2013, 2013
S. Preunkert and M. Legrand
Clim. Past, 9, 1403–1416, https://doi.org/10.5194/cp-9-1403-2013, https://doi.org/10.5194/cp-9-1403-2013, 2013
M. M. Frey, N. Brough, J. L. France, P. S. Anderson, O. Traulle, M. D. King, A. E. Jones, E. W. Wolff, and J. Savarino
Atmos. Chem. Phys., 13, 3045–3062, https://doi.org/10.5194/acp-13-3045-2013, https://doi.org/10.5194/acp-13-3045-2013, 2013
R. Weller, A. Minikin, A. Petzold, D. Wagenbach, and G. König-Langlo
Atmos. Chem. Phys., 13, 1579–1590, https://doi.org/10.5194/acp-13-1579-2013, https://doi.org/10.5194/acp-13-1579-2013, 2013
A. E. Jones, E. W. Wolff, N. Brough, S. J.-B. Bauguitte, R. Weller, M. Yela, M. Navarro-Comas, H. A. Ochoa, and N. Theys
Atmos. Chem. Phys., 13, 1457–1467, https://doi.org/10.5194/acp-13-1457-2013, https://doi.org/10.5194/acp-13-1457-2013, 2013
M. Collaud Coen, E. Andrews, A. Asmi, U. Baltensperger, N. Bukowiecki, D. Day, M. Fiebig, A. M. Fjaeraa, H. Flentje, A. Hyvärinen, A. Jefferson, S. G. Jennings, G. Kouvarakis, H. Lihavainen, C. Lund Myhre, W. C. Malm, N. Mihapopoulos, J. V. Molenar, C. O'Dowd, J. A. Ogren, B. A. Schichtel, P. Sheridan, A. Virkkula, E. Weingartner, R. Weller, and P. Laj
Atmos. Chem. Phys., 13, 869–894, https://doi.org/10.5194/acp-13-869-2013, https://doi.org/10.5194/acp-13-869-2013, 2013
A. Asmi, M. Collaud Coen, J. A. Ogren, E. Andrews, P. Sheridan, A. Jefferson, E. Weingartner, U. Baltensperger, N. Bukowiecki, H. Lihavainen, N. Kivekäs, E. Asmi, P. P. Aalto, M. Kulmala, A. Wiedensohler, W. Birmili, A. Hamed, C. O'Dowd, S. G Jennings, R. Weller, H. Flentje, A. M. Fjaeraa, M. Fiebig, C. L. Myhre, A. G. Hallar, E. Swietlicki, A. Kristensson, and P. Laj
Atmos. Chem. Phys., 13, 895–916, https://doi.org/10.5194/acp-13-895-2013, https://doi.org/10.5194/acp-13-895-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
The impact of traffic on air quality in Ireland: insights from the simultaneous kerbside and suburban monitoring of submicron aerosols
Vertical distribution of particle-phase dicarboxylic acids, oxoacids and α-dicarbonyls in the urban boundary layer based on the 325 m tower in Beijing
Characterization and source apportionment of aerosol light scattering in a typical polluted city in the Yangtze River Delta, China
Molecular insights into new particle formation in Barcelona, Spain
Tracking separate contributions of diesel and gasoline vehicles to roadside PM2.5 through online monitoring of volatile organic compounds and PM2.5 organic and elemental carbon: a 6-year study in Hong Kong
Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere
Variations in Ncn and Nccn over marginal seas in China related to marine traffic emissions, new particle formation and aerosol aging
Simultaneous measurements of urban and rural particles in Beijing – Part 1: Chemical composition and mixing state
Simultaneous measurements of urban and rural particles in Beijing – Part 2: Case studies of haze events and regional transport
Ship plumes in the Baltic Sea Sulfur Emission Control Area: chemical characterization and contribution to coastal aerosol concentrations
Contrasting sources and processes of particulate species in haze days with low and high relative humidity in wintertime Beijing
Overview: Integrative and Comprehensive Understanding on Polar Environments (iCUPE) – concept and initial results
Chemical characterization of secondary organic aerosol at a rural site in the southeastern US: insights from simultaneous high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and FIGAERO chemical ionization mass spectrometer (CIMS) measurements
Sea spray aerosol organic enrichment, water uptake and surface tension effects
A 1-year characterization of organic aerosol composition and sources using an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF)
Decadal changes in anthropogenic source contribution of PM2.5 pollution and related health impacts in China, 1990–2015
Characterization of submicron particles by time-of-flight aerosol chemical speciation monitor (ToF-ACSM) during wintertime: aerosol composition, sources, and chemical processes in Guangzhou, China
Strong anthropogenic control of secondary organic aerosol formation from isoprene in Beijing
Synergistic enhancement of urban haze by nitrate uptake into transported hygroscopic particles in the Asian continental outflow
Long-term brown carbon and smoke tracer observations in Bogotá, Colombia: association with medium-range transport of biomass burning plumes
Importance of gas-particle partitioning of ammonia in haze formation in the rural agricultural environment
Resonance-enhanced detection of metals in aerosols using single-particle mass spectrometry
Measurement report: Characterization of severe spring haze episodes and influences of long-range transport in the Seoul metropolitan area in March 2019
Air mass physiochemical characteristics over New Delhi: impacts on aerosol hygroscopicity and cloud condensation nuclei (CCN) formation
Marine organic matter in the remote environment of the Cape Verde islands – an introduction and overview to the MarParCloud campaign
Molecular and spatial distributions of dicarboxylic acids, oxocarboxylic acids, and α-dicarbonyls in marine aerosols from the South China Sea to the eastern Indian Ocean
Molecular characterization of firework-related urban aerosols using Fourier transform ion cyclotron resonance mass spectrometry
Measurement report: Vertical distribution of atmospheric particulate matter within the urban boundary layer in southern China – size-segregated chemical composition and secondary formation through cloud processing and heterogeneous reactions
Mixing states of Amazon-basin aerosol particles transported over long distances using transmission electron microscopy
Hygroscopicity of urban aerosols and its link to size-resolved chemical composition during spring/summertime in Seoul, Korea
Direct links between hygroscopicity and mixing state of ambient aerosols: estimating particle hygroscopicity from their single-particle mass spectra
Characterization of carbonaceous aerosols in Singapore: insight from black carbon fragments and trace metal ions detected by a soot particle aerosol mass spectrometer
Contribution of hydroxymethanesulfonate (HMS) to severe winter haze in the North China Plain
Characteristics of methanesulfonic acid, non-sea-salt sulfate and organic carbon aerosols over the Amundsen Sea, Antarctica
Exploring wintertime regional haze in northeast China: role of coal and biomass burning
Transformation and ageing of biomass burning carbonaceous aerosol over tropical South America from aircraft in situ measurements during SAMBBA
Physico-chemical characterization of urban aerosols from specific combustion sources in West Africa at Abidjan in Côte d'Ivoire and Cotonou in Benin in the frame of the DACCIWA program
Characterization and comparison of PM2.5 oxidative potential assessed by two acellular assays
Characterization of the light-absorbing properties, chromophore composition and sources of brown carbon aerosol in Xi'an, northwestern China
Nitrate-dominated PM2.5 and elevation of particle pH observed in urban Beijing during the winter of 2017
Tracer-based investigation of organic aerosols in marine atmospheres from marginal seas of China to the northwest Pacific Ocean
Optical properties and molecular compositions of water-soluble and water-insoluble brown carbon (BrC) aerosols in northwest China
Influence of vessel characteristics and atmospheric processes on the gas and particle phase of ship emission plumes: in situ measurements in the Mediterranean Sea and around the Arabian Peninsula
Seasonal source variability of carbonaceous aerosols at the Rwanda Climate Observatory
Formation and sink of glyoxal and methylglyoxal in a polluted subtropical environment: observation-based photochemical analysis and impact evaluation
Fossil fuel combustion, biomass burning and biogenic sources of fine carbonaceous aerosol in the Carpathian Basin
Shipborne measurements of Antarctic submicron organic aerosols: an NMR perspective linking multiple sources and bioregions
Formation mechanisms of atmospheric nitrate and sulfate during the winter haze pollution periods in Beijing: gas-phase, heterogeneous and aqueous-phase chemistry
Heterogeneous formation of particulate nitrate under ammonium-rich regimes during the high-PM2.5 events in Nanjing, China
Summertime and wintertime atmospheric processes of secondary aerosol in Beijing
Chunshui Lin, Darius Ceburnis, Wei Xu, Eimear Heffernan, Stig Hellebust, John Gallagher, Ru-Jin Huang, Colin O'Dowd, and Jurgita Ovadnevaite
Atmos. Chem. Phys., 20, 10513–10529, https://doi.org/10.5194/acp-20-10513-2020, https://doi.org/10.5194/acp-20-10513-2020, 2020
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Chemical composition and sources of submicron aerosols (PM1) were simultaneously investigated at a kerbside site in the Dublin city center and at a residential site in suburban Dublin (~5 km apart) during both a nonheating and a heating period in 2018. This study highlights the temporal and spatial variability of sources within the Dublin city center and the need for additional aerosol characterization studies to improve targeted mitigation solutions for a greater impact on urban air quality.
Wanyu Zhao, Hong Ren, Kimitaka Kawamura, Huiyun Du, Xueshun Chen, Siyao Yue, Qiaorong Xie, Lianfang Wei, Ping Li, Xin Zeng, Shaofei Kong, Yele Sun, Zifa Wang, and Pingqing Fu
Atmos. Chem. Phys., 20, 10331–10350, https://doi.org/10.5194/acp-20-10331-2020, https://doi.org/10.5194/acp-20-10331-2020, 2020
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Our observations provide detailed information on the abundance and vertical distribution of dicarboxylic acids, oxoacids and α-dicarbonyls in PM2.5 collected at three heights based on a 325 m meteorological tower in Beijing in summer. Our results demonstrate that organic acids at the ground surface are largely associated with local traffic emissions, while long-range atmospheric transport followed by photochemical ageing contributes more in the urban boundary layer than the ground surface.
Dong Chen, Yu Zhao, Jie Zhang, Huan Yu, and Xingna Yu
Atmos. Chem. Phys., 20, 10193–10210, https://doi.org/10.5194/acp-20-10193-2020, https://doi.org/10.5194/acp-20-10193-2020, 2020
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We studied the characteristics and sources of aerosol scattering for Nanjing. The method of aerosol scattering estimation was optimized based on field measurements, and the impacts of aerosol size and composition were quantified. To explore the reasons for the reduced visibility, source apportionment of aerosol scattering was conducted by pollution level. This work stressed the linkage between aerosols and visibility and improved the understanding of emissions and their role in air quality.
James Brean, David C. S. Beddows, Zongbo Shi, Brice Temime-Roussel, Nicolas Marchand, Xavier Querol, Andrés Alastuey, María Cruz Minguillón, and Roy M. Harrison
Atmos. Chem. Phys., 20, 10029–10045, https://doi.org/10.5194/acp-20-10029-2020, https://doi.org/10.5194/acp-20-10029-2020, 2020
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New particle formation is a key process influencing both local air quality and climatically active cloud condensation nuclei concentrations. This study has carried out fundamental measurements of nucleation processes in Barcelona, Spain, and concludes that a mechanism involving stabilisation of sulfuric acid clusters by low molecular weight amines is primarily responsible for new particle formation events.
Yee Ka Wong, X. H. Hilda Huang, Peter K. K. Louie, Alfred L. C. Yu, Damgy H. L. Chan, and Jian Zhen Yu
Atmos. Chem. Phys., 20, 9871–9882, https://doi.org/10.5194/acp-20-9871-2020, https://doi.org/10.5194/acp-20-9871-2020, 2020
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We present an approach to track separate contributions to PM2.5 by gasoline and diesel vehicles through a positive matrix factorization analysis of online monitoring data measurable by relatively inexpensive analytical instruments. They are PM2.5 organic and elemental carbon, C2–C9 volatile organic compounds, and nitrogen oxide concentrations. The method was demonstrated to be effective by applying monitoring data spanning 6 years (2011–2017) from a roadside environment in Hong Kong.
Yibei Wan, Xiangpeng Huang, Bin Jiang, Binyu Kuang, Manfei Lin, Deming Xia, Yuhong Liao, Jingwen Chen, Jian Zhen Yu, and Huan Yu
Atmos. Chem. Phys., 20, 9821–9835, https://doi.org/10.5194/acp-20-9821-2020, https://doi.org/10.5194/acp-20-9821-2020, 2020
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Biogenic iodine emission from macroalgae and microalgae could initiate atmospheric new particle formation (NPF). But it is unknown if other species are needed to drive the growth of new iodine particles in the marine boundary layer. Unlike the deeper understanding of organic compounds driving continental NPF, little is known about the organics involved in coastal or open-ocean NPF. This article reveals a new group of important organic compounds involved in this process.
Yang Gao, Deqiang Zhang, Juntao Wang, Huiwang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 20, 9665–9677, https://doi.org/10.5194/acp-20-9665-2020, https://doi.org/10.5194/acp-20-9665-2020, 2020
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Through the cruise campaign conducted over marginal seas in China, we found that the concentrations of condensation nuclei (Ncn) and cloud condensation nuclei (Nccn) were 1 order of magnitude larger than those in remote clear marine atmospheres, indicating overwhelming contributions from marine traffic emissions and long-range continental transport. Moreover, we derived regression equations used to estimate Ncn and Nccn from SO2 when the direct observations of Ncn and Nccn are not available.
Yang Chen, Jing Cai, Zhichao Wang, Chao Peng, Xiaojiang Yao, Mi Tian, Yiqun Han, Guangming Shi, Zongbo Shi, Yue Liu, Xi Yang, Mei Zheng, Tong Zhu, Kebin He, Qiang Zhang, and Fumo Yang
Atmos. Chem. Phys., 20, 9231–9247, https://doi.org/10.5194/acp-20-9231-2020, https://doi.org/10.5194/acp-20-9231-2020, 2020
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Patterns of particle transport, accumulation, and evolution in both urban and rural areas of Beijing are investigated. The two sites shared 17 common particle types in different stages of atmospheric processing.
Yang Chen, Guangming Shi, Jing Cai, Zongbo Shi, Zhichao Wang, Xiaojiang Yao, Mi Tian, Chao Peng, Yiqun Han, Tong Zhu, Yue Liu, Xi Yang, Mei Zheng, Fumo Yang, Qiang Zhang, and Kebin He
Atmos. Chem. Phys., 20, 9249–9263, https://doi.org/10.5194/acp-20-9249-2020, https://doi.org/10.5194/acp-20-9249-2020, 2020
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Individual particles were observed in two field studies during winter 2016 in the urban and rural areas of Beijing. An online single-particle chemical composition analysis was used as a tracing system to investigate the impact of heating activities and the formation of haze events. During the pollution events, a pattern of transport and accumulation was found with evidence of single particles. The transport from Pinggu to Peking University was significant but PKU to PG occurred occasionally.
Stina Ausmeel, Axel Eriksson, Erik Ahlberg, Moa K. Sporre, Mårten Spanne, and Adam Kristensson
Atmos. Chem. Phys., 20, 9135–9151, https://doi.org/10.5194/acp-20-9135-2020, https://doi.org/10.5194/acp-20-9135-2020, 2020
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Emissions from shipping have an impact on air quality, especially in coastal areas. We have measured properties of the airborne particles in several plumes from ships that are sailing within an Emission Control Area. Individual ships showed large variability in contribution to total particle mass and nitrogen dioxide. Organics and sulfate dominated the particle mass, and most plumes contained very little or no soot. We also present recommendations for future stationary ship plume measurements.
Ru-Jin Huang, Yao He, Jing Duan, Yongjie Li, Qi Chen, Yan Zheng, Yang Chen, Weiwei Hu, Chunshui Lin, Haiyan Ni, Wenting Dai, Junji Cao, Yunfei Wu, Renjian Zhang, Wei Xu, Jurgita Ovadnevaite, Darius Ceburnis, Thorsten Hoffmann, and Colin D. O'Dowd
Atmos. Chem. Phys., 20, 9101–9114, https://doi.org/10.5194/acp-20-9101-2020, https://doi.org/10.5194/acp-20-9101-2020, 2020
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We systematically compared the submicron particle (PM1) processes in haze days with low and high relative humidity (RH) in wintertime Beijing. Nitrate had similar daytime growth rates in low-RH and high-RH pollution. OOA had a higher growth rate in low-RH pollution than in high-RH pollution. Sulfate had a decreasing trend in low-RH pollution, while it increased significantly in high-RH pollution. This distinction may be explained by the different processes affected by meteorological conditions.
Tuukka Petäjä, Ella-Maria Duplissy, Ksenia Tabakova, Julia Schmale, Barbara Altstädter, Gerard Ancellet, Mikhail Arshinov, Yurii Balin, Urs Baltensperger, Jens Bange, Alison Beamish, Boris Belan, Antoine Berchet, Rossana Bossi, Warren R. L. Cairns, Ralf Ebinghaus, Imad El Haddad, Beatriz Ferreira-Araujo, Anna Franck, Lin Huang, Antti Hyvärinen, Angelika Humbert, Athina-Cerise Kalogridis, Pavel Konstantinov, Astrid Lampert, Matthew MacLeod, Olivier Magand, Alexander Mahura, Louis Marelle, Vladimir Masloboev, Dmitri Moisseev, Vaios Moschos, Niklas Neckel, Tatsuo Onishi, Stefan Osterwalder, Aino Ovaska, Pauli Paasonen, Mikhail Panchenko, Fidel Pankratov, Jakob B. Pernov, Andreas Platis, Olga Popovicheva, Jean-Christophe Raut, Aurélie Riandet, Torsten Sachs, Rosamaria Salvatori, Roberto Salzano, Ludwig Schröder, Martin Schön, Vladimir Shevchenko, Henrik Skov, Jeroen E. Sonke, Andrea Spolaor, Vasileios K. Stathopoulos, Mikko Strahlendorff, Jennie L. Thomas, Vito Vitale, Sterios Vratolis, Carlo Barbante, Sabine Chabrillat, Aurélien Dommergue, Konstantinos Eleftheriadis, Jyri Heilimo, Kathy S. Law, Andreas Massling, Steffen M. Noe, Jean-Daniel Paris, André S. H. Prévôt, Ilona Riipinen, Birgit Wehner, Zhiyong Xie, and Hanna K. Lappalainen
Atmos. Chem. Phys., 20, 8551–8592, https://doi.org/10.5194/acp-20-8551-2020, https://doi.org/10.5194/acp-20-8551-2020, 2020
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The role of polar regions is increasing in terms of megatrends such as globalization, new transport routes, demography, and the use of natural resources with consequent effects on regional and transported pollutant concentrations. Here we summarize initial results from our integrative project exploring the Arctic environment and pollution to deliver data products, metrics, and indicators for stakeholders.
Yunle Chen, Masayuki Takeuchi, Theodora Nah, Lu Xu, Manjula R. Canagaratna, Harald Stark, Karsten Baumann, Francesco Canonaco, André S. H. Prévôt, L. Gregory Huey, Rodney J. Weber, and Nga L. Ng
Atmos. Chem. Phys., 20, 8421–8440, https://doi.org/10.5194/acp-20-8421-2020, https://doi.org/10.5194/acp-20-8421-2020, 2020
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Two online mass spectrometry instruments, an aerosol mass spectrometer and a chemical ionization mass spectrometer equipped with a filter inlet for gases and aerosols, were deployed at Yorkville, GA, for a comprehensive characterization of organic aerosol. We observed notable secondary organic aerosol formation from isoprene and monoterpenes via different pathways during both day and night, and a series of highly oxidized acid-like compounds was found to be closely related to aged SOA.
Luke T. Cravigan, Marc D. Mallet, Petri Vaattovaara, Mike J. Harvey, Cliff S. Law, Robin L. Modini, Lynn M. Russell, Ed Stelcer, David D. Cohen, Greg Olsen, Karl Safi, Timothy J. Burrell, and Zoran Ristovski
Atmos. Chem. Phys., 20, 7955–7977, https://doi.org/10.5194/acp-20-7955-2020, https://doi.org/10.5194/acp-20-7955-2020, 2020
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Aerosol–cloud interactions in remote marine environments are poorly represented in atmospheric modelling, particularly over the Southern Hemisphere. This work reports in situ chamber observations of sea spray aerosol composition and water uptake during the Surface Ocean Aerosol Production (SOAP) voyage. Observations were compared with currently applied models for sea spray organic enrichment. The sea spray hygroscopicity was persistently high, even at high organic fractions.
Lu Qi, Alexander L. Vogel, Sepideh Esmaeilirad, Liming Cao, Jing Zheng, Jean-Luc Jaffrezo, Paola Fermo, Anne Kasper-Giebl, Kaspar R. Daellenbach, Mindong Chen, Xinlei Ge, Urs Baltensperger, André S. H. Prévôt, and Jay G. Slowik
Atmos. Chem. Phys., 20, 7875–7893, https://doi.org/10.5194/acp-20-7875-2020, https://doi.org/10.5194/acp-20-7875-2020, 2020
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We present the first application of this online and offline strategy using the new extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF), which achieves increased chemical specificity relative to other online techniques. Measurement and source apportionment of 1 year of filter samples collected in Zurich, Switzerland, show seasonal contributions from fresh and aged wood combustion in winter and biogenic emission-derived SOA in summer, as well as other sources.
Jun Liu, Yixuan Zheng, Guannan Geng, Chaopeng Hong, Meng Li, Xin Li, Fei Liu, Dan Tong, Ruili Wu, Bo Zheng, Kebin He, and Qiang Zhang
Atmos. Chem. Phys., 20, 7783–7799, https://doi.org/10.5194/acp-20-7783-2020, https://doi.org/10.5194/acp-20-7783-2020, 2020
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Ambient PM2.5 pollution contributed substantially to premature mortality in China. The contributions of various sectors to anthropogenic PM2.5-related premature mortality have changed substantially during 1990–2015. In 1990, the residential sector was the leading source, followed by industry, power, agriculture, and transportation, whereas in 2015, the industrial sector became the largest contributor, followed by the residential sector, agriculture, transportation, and power.
Junchen Guo, Shengzhen Zhou, Mingfu Cai, Jun Zhao, Wei Song, Weixiong Zhao, Weiwei Hu, Yele Sun, Yao He, Chengqiang Yang, Xuezhe Xu, Zhisheng Zhang, Peng Cheng, Qi Fan, Jian Hang, Shaojia Fan, Xinming Wang, and Xuemei Wang
Atmos. Chem. Phys., 20, 7595–7615, https://doi.org/10.5194/acp-20-7595-2020, https://doi.org/10.5194/acp-20-7595-2020, 2020
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We characterized non-refractory submicron particulate matter (PM1.0) during winter in Guangzhou, south China. Chemical composition and key sources of ambient PM1.0 are revealed, highlighting the significant role of SOA. The relationship with SOA and peroxy radicals indicated gas-phase oxidation contributed predominantly to SOA formation during non-pollution periods, while heterogeneous/multiphase reactions played more important roles in SOA formation during pollution periods.
Daniel J. Bryant, William J. Dixon, James R. Hopkins, Rachel E. Dunmore, Kelly L. Pereira, Marvin Shaw, Freya A. Squires, Thomas J. Bannan, Archit Mehra, Stephen D. Worrall, Asan Bacak, Hugh Coe, Carl J. Percival, Lisa K. Whalley, Dwayne E. Heard, Eloise J. Slater, Bin Ouyang, Tianqu Cui, Jason D. Surratt, Di Liu, Zongbo Shi, Roy Harrison, Yele Sun, Weiqi Xu, Alastair C. Lewis, James D. Lee, Andrew R. Rickard, and Jacqueline F. Hamilton
Atmos. Chem. Phys., 20, 7531–7552, https://doi.org/10.5194/acp-20-7531-2020, https://doi.org/10.5194/acp-20-7531-2020, 2020
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Using the chemical composition of offline filter samples, we report that a large share of oxidized organic aerosol in Beijing during summer is due to isoprene secondary organic aerosol (iSOA). iSOA organosulfates showed a strong correlation with the product of ozone and particulate sulfate. This highlights the role of both photochemistry and the availability of particulate sulfate in heterogeneous reactions and further demonstrates that iSOA formation is controlled by anthropogenic emissions.
Jihoon Seo, Yong Bin Lim, Daeok Youn, Jin Young Kim, and Hyoun Cher Jin
Atmos. Chem. Phys., 20, 7575–7594, https://doi.org/10.5194/acp-20-7575-2020, https://doi.org/10.5194/acp-20-7575-2020, 2020
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This study investigates the synergistic role of transported regional haze in increasing local inorganic aerosols. PM2.5 data measured at Seoul, South Korea, together with a thermodynamic model show that the transported haze particles from the polluted continent are richer in inorganics and wetter than the local haze particles. The transported wet particles readily increase the inorganic aerosols through the uptake of HNO3 in NOx- and NH3-rich urban environments like Seoul.
Juan Manuel Rincón-Riveros, Maria Alejandra Rincón-Caro, Amy P. Sullivan, Juan Felipe Mendez-Espinosa, Luis Carlos Belalcazar, Miguel Quirama Aguilar, and Ricardo Morales Betancourt
Atmos. Chem. Phys., 20, 7459–7472, https://doi.org/10.5194/acp-20-7459-2020, https://doi.org/10.5194/acp-20-7459-2020, 2020
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Air pollution affects health for millions of people worldwide. This is particularly worrisome for citizens in emerging economies where air quality is often heavily deteriorated. We show how, every year, agricultural burns and forest fires in the grasslands of northern South America increase the concentration of harmful particles in the environment, further worsening air quality for nearly 60 million in this region, even when the fires occur hundreds of kilometers away from urban areas.
Jian Xu, Jia Chen, Na Zhao, Guochen Wang, Guangyuan Yu, Hao Li, Juntao Huo, Yanfen Lin, Qingyan Fu, Hongyu Guo, Congrui Deng, Shan-Hu Lee, Jianmin Chen, and Kan Huang
Atmos. Chem. Phys., 20, 7259–7269, https://doi.org/10.5194/acp-20-7259-2020, https://doi.org/10.5194/acp-20-7259-2020, 2020
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This study provided evidence that gas-particle partitioning of ammonia, as opposed to ammonia concentration, plays a critical role in the haze formation. A reduction in ammonia emissions alone may not reduce air pollution effectively, at least at rural agricultural sites in China.
Johannes Passig, Julian Schade, Ellen Iva Rosewig, Robert Irsig, Thomas Kröger-Badge, Hendryk Czech, Martin Sklorz, Thorsten Streibel, Lei Li, Xue Li, Zhen Zhou, Henrik Fallgren, Jana Moldanova, and Ralf Zimmermann
Atmos. Chem. Phys., 20, 7139–7152, https://doi.org/10.5194/acp-20-7139-2020, https://doi.org/10.5194/acp-20-7139-2020, 2020
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Particle-bound metals in both natural dusts and polluted air can induce severe health effects. They are also transported by the wind into the oceans; provide micronutrients; and thus modulate biodiversity, fisheries, and climate. We show a way to more efficiently detect metals in individual particles while preserving source information. Our detection scheme is less dependent on the particle type and atmospheric changes and is thus valuable to the study of biogechemical cycles and air pollution.
Hwajin Kim, Qi Zhang, and Yele Sun
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-382, https://doi.org/10.5194/acp-2020-382, 2020
Revised manuscript accepted for ACP
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Severe spring haze and influences of long-range transport in the Seoul metropolitan area in March 2019 was investigated. Simultaneous downwind (SMA) and upwind (Beijing) measurements using AMS and ACSM over the same period showed that the PM species can be transported approximately in two days. Nitrate was the most responsible and sulfate and two regional transport influenced SOAs also contributed. Enhancement of Pb also showed that the haze in SMA was influenced by the regional transport.
Zainab Arub, Sahil Bhandari, Shahzad Gani, Joshua S. Apte, Lea Hildebrandt Ruiz, and Gazala Habib
Atmos. Chem. Phys., 20, 6953–6971, https://doi.org/10.5194/acp-20-6953-2020, https://doi.org/10.5194/acp-20-6953-2020, 2020
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Aerosol physiochemical properties were characterized for three prominent air masses over New Delhi, a highly polluted megacity. The chemical composition and size distribution data were used to deduce the hygroscopicity parameter and cloud condensation nuclei (CCN) number concentration. The activated fraction was the highest in the world for any continental site. The aerosol physiochemical properties and their diurnal patterns were interlinked and impacted aerosol hygroscopicity and CCN activity.
Manuela van Pinxteren, Khanneh Wadinga Fomba, Nadja Triesch, Christian Stolle, Oliver Wurl, Enno Bahlmann, Xianda Gong, Jens Voigtländer, Heike Wex, Tiera-Brandy Robinson, Stefan Barthel, Sebastian Zeppenfeld, Erik Hans Hoffmann, Marie Roveretto, Chunlin Li, Benoit Grosselin, Veronique Daële, Fabian Senf, Dominik van Pinxteren, Malena Manzi, Nicolás Zabalegui, Sanja Frka, Blaženka Gašparović, Ryan Pereira, Tao Li, Liang Wen, Jiarong Li, Chao Zhu, Hui Chen, Jianmin Chen, Björn Fiedler, Wolf von Tümpling, Katie Alana Read, Shalini Punjabi, Alastair Charles Lewis, James Roland Hopkins, Lucy Jane Carpenter, Ilka Peeken, Tim Rixen, Detlef Schulz-Bull, María Eugenia Monge, Abdelwahid Mellouki, Christian George, Frank Stratmann, and Hartmut Herrmann
Atmos. Chem. Phys., 20, 6921–6951, https://doi.org/10.5194/acp-20-6921-2020, https://doi.org/10.5194/acp-20-6921-2020, 2020
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An introduction to a comprehensive field campaign performed at the Cape Verde Atmospheric Observatory regarding ocean–atmosphere interactions is given. Chemical, physical, biological and meteorological techniques were applied, and measurements of bulk water, the sea surface microlayer, cloud water and ambient aerosol particles took place. Oceanic compounds were found to be transferred to atmospheric aerosol and to the cloud level; however, sea spray contributions to CCN and INPs were limited.
Jing Yang, Wanyu Zhao, Lianfang Wei, Qiang Zhang, Yue Zhao, Wei Hu, Libin Wu, Xiaodong Li, Chandra Mouli Pavuluri, Xiaole Pan, Yele Sun, Zifa Wang, Cong-Qiang Liu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 20, 6841–6860, https://doi.org/10.5194/acp-20-6841-2020, https://doi.org/10.5194/acp-20-6841-2020, 2020
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Our observations provide novel detailed information on the atmospheric abundances and spatial distributions of dicarboxylic acids, oxoacids, and α-dicarbonyls in marine aerosols collected from the South China Sea to the East Indian Ocean. Our results demonstrate that the continental outflow of both biogenic and anthropogenic precursors followed by photochemical aging is one of the main sources and formation processes of marine organic aerosols over the tropical oceanic regions.
Qiaorong Xie, Sihui Su, Shuang Chen, Yisheng Xu, Dong Cao, Jing Chen, Lujie Ren, Siyao Yue, Wanyu Zhao, Yele Sun, Zifa Wang, Haijie Tong, Hang Su, Yafang Cheng, Kimitaka Kawamura, Guibin Jiang, Cong-Qiang Liu, and Pingqing Fu
Atmos. Chem. Phys., 20, 6803–6820, https://doi.org/10.5194/acp-20-6803-2020, https://doi.org/10.5194/acp-20-6803-2020, 2020
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Current knowledge on firework-related organic aerosols is very limited. Here the detailed molecular composition of organics in urban aerosols was characterized using ultrahigh-resolution FT-ICR mass spectrometry. Our findings highlight that firework emission leads to a sharp increase in CHO, CHNO, and CHOS containing high-molecular-weight species, particularly aromatic-like substances, which affect the physicochemical properties such as the light absorption and health effects of urban aerosols.
Shengzhen Zhou, Luolin Wu, Junchen Guo, Weihua Chen, Xuemei Wang, Jun Zhao, Yafang Cheng, Zuzhao Huang, Jinpu Zhang, Yele Sun, Pingqing Fu, Shiguo Jia, Jun Tao, Yanning Chen, and Junxia Kuang
Atmos. Chem. Phys., 20, 6435–6453, https://doi.org/10.5194/acp-20-6435-2020, https://doi.org/10.5194/acp-20-6435-2020, 2020
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In this work, measurements of size-segregated aerosols were conducted at three altitudes (ground level, 118 m, and 488 m) on the 610 m high Canton Tower in southern China. Vertical variations of PM and size-segregated chemical compositions were investigated. The results indicated that meteorological parameters and atmospheric aqueous and heterogeneous reactions together led to aerosol formation and haze episodes in the Pearl River Delta region during the measurement periods.
Kouji Adachi, Naga Oshima, Zhaoheng Gong, Suzane de Sá, Adam P. Bateman, Scot T. Martin, Joel F. de Brito, Paulo Artaxo, Glauber G. Cirino, Arthur J. Sedlacek III, and Peter R. Buseck
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-452, https://doi.org/10.5194/acp-2020-452, 2020
Revised manuscript accepted for ACP
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Occurrences, size distributions, and number fractions of individual aerosol particles from the Amazon basin during the GoAmazon2014/5 campaign were analyzed using transmission electron microscopy. Aerosol particles from natural sources (e.g., mineral dust, primary biological aerosols, and sea salts) during the wet season originated from the Amazon forest and long-range transports (the Saharan desert and the Atlantic Ocean). They commonly mix at an individual particle scale during transport.
Najin Kim, Seong Soo Yum, Minsu Park, Jong Sung Park, Hye Jung Shin, and Joon Young Ahn
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-450, https://doi.org/10.5194/acp-2020-450, 2020
Revised manuscript accepted for ACP
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Chemical effects on the size-resolved hygroscopicity of urban aerosols were examined based on the KORUS-AQ field campaign data (HTDMA and HR-ToF-AMS). The size-resolved chemical composition data were found to be critical in explaining the size-dependent hygroscopicity as well as the diurnal variation of κ for small particles. Aerosol mixing state information was associated with the size-resolved chemical composition data to reveal chemical information of different hygroscopicity modes.
Xinning Wang, Xingnan Ye, Jianmin Chen, Xiaofei Wang, Xin Yang, Tzung-May Fu, Lei Zhu, and Chongxuan Liu
Atmos. Chem. Phys., 20, 6273–6290, https://doi.org/10.5194/acp-20-6273-2020, https://doi.org/10.5194/acp-20-6273-2020, 2020
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Hygroscopicity plays several key roles in determining aerosol optical properties and aging processes in the atmosphere. However, it is quite difficult to study aerosol hygroscopicity at the single-particle level. In this study, we built a comprehensive database linking hygroscopicities and mass spectra of individual particles. Based on the measured hygroscopicity–composition relations, we developed a statistical method to estimate ambient particle hygroscopicity just from their mass spectra.
Laura-Hélèna Rivellini, Max Gerrit Adam, Nethmi Kasthuriarachchi, and Alex King Yin Lee
Atmos. Chem. Phys., 20, 5977–5993, https://doi.org/10.5194/acp-20-5977-2020, https://doi.org/10.5194/acp-20-5977-2020, 2020
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This work highlights that trace metals and refractory black carbon (rBC), and their inclusion in a source–receptor model, can provide important insight into the source apportionment of carbonaceous aerosols. In Singapore, we evidenced that 90 % of rBC originated from traffic/industrial emissions. The association of aged OA with K and Rb underlines the influence of regional biomass burning sources, while rBC fragmentation patterns and V/Ni were used to identify industrial and shipping pollutants.
Tao Ma, Hiroshi Furutani, Fengkui Duan, Takashi Kimoto, Jingkun Jiang, Qiang Zhang, Xiaobin Xu, Ying Wang, Jian Gao, Guannan Geng, Meng Li, Shaojie Song, Yongliang Ma, Fei Che, Jie Wang, Lidan Zhu, Tao Huang, Michisato Toyoda, and Kebin He
Atmos. Chem. Phys., 20, 5887–5897, https://doi.org/10.5194/acp-20-5887-2020, https://doi.org/10.5194/acp-20-5887-2020, 2020
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The formation mechanisms of organic matter and sulfate in winter haze in the North China Plain remain unclear. This paper presents the identification and quantification of hydroxymethanesulfonate (HMS) in PM2.5 in Beijing winter and elucidates the heterogeneous HMS chemistry in favorable winter haze conditions. We show that the HMS not only contributes a substantial mass of organic matter, but also leads to an overestimation of sulfate in conventional measurements.
Jinyoung Jung, Sang-Bum Hong, Meilian Chen, Jin Hur, Liping Jiao, Youngju Lee, Keyhong Park, Doshik Hahm, Jung-Ok Choi, Eun Jin Yang, Jisoo Park, Tae-Wan Kim, and SangHoon Lee
Atmos. Chem. Phys., 20, 5405–5424, https://doi.org/10.5194/acp-20-5405-2020, https://doi.org/10.5194/acp-20-5405-2020, 2020
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Characteristics of atmospheric sulfur and organic carbon species in marine aerosols and the environmental factors influencing their distributions were investigated over the Southern Ocean and the Amundsen Sea, Antarctica, during austral summer. The simultaneous measurements of chemical species in aerosols as well as the chemical and biological properties of seawater in the Amundsen Sea allowed for a better understanding of the effect of the ocean ecosystem on marine aerosols.
Jian Zhang, Lei Liu, Liang Xu, Qiuhan Lin, Hujia Zhao, Zhibin Wang, Song Guo, Min Hu, Dantong Liu, Zongbo Shi, Dao Huang, and Weijun Li
Atmos. Chem. Phys., 20, 5355–5372, https://doi.org/10.5194/acp-20-5355-2020, https://doi.org/10.5194/acp-20-5355-2020, 2020
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Northeast China faces severe air pollution in regional haze in wintertime. In this study, we revealed a contrasting formation mechanism of two typical haze events: Haze-I was induced by adverse meteorological conditions together with residential coal burning emissions; Haze-II was caused by agricultural biomass waste burning. In particular, we observed large numbers of tar balls as the primary brown carbon in northeast China.
William T. Morgan, James D. Allan, Stéphane Bauguitte, Eoghan Darbyshire, Michael J. Flynn, James Lee, Dantong Liu, Ben Johnson, Jim Haywood, Karla M. Longo, Paulo E. Artaxo, and Hugh Coe
Atmos. Chem. Phys., 20, 5309–5326, https://doi.org/10.5194/acp-20-5309-2020, https://doi.org/10.5194/acp-20-5309-2020, 2020
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We flew a large atmospheric research aircraft across a number of different environments in the Amazon basin during the 2012 biomass burning season. Smoke from fires builds up and has a significant impact on weather, climate, health and natural ecosystems. Our goal was to quantify changes in the properties of the smoke emitted by fires as it is transported through the atmosphere. We found that the major control on the properties of the smoke was due to differences in the fires themselves.
Aka Jacques Adon, Catherine Liousse, Elhadji Thierno Doumbia, Armelle Baeza-Squiban, Hélène Cachier, Jean-Francois Léon, Véronique Yoboué, Aristique Barthel Akpo, Corinne Galy-Lacaux, Benjamin Guinot, Cyril Zouiten, Hongmei Xu, Eric Gardrat, and Sekou Keita
Atmos. Chem. Phys., 20, 5327–5354, https://doi.org/10.5194/acp-20-5327-2020, https://doi.org/10.5194/acp-20-5327-2020, 2020
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It is our responsibility to establish a link between emissions, air pollution, and health impacts for urban combustion sources, typical of Africa.
Our results show that the particulate concentrations observed at all sites far exceed the recommendations of WHO. The site influenced by domestic fires is the most polluted site, dominated by a significant fraction of ultrafine particles. These studies will eventually lead to the implementation of emission reduction solutions to improve air quality.
Dong Gao, Krystal J. Godri Pollitt, James A. Mulholland, Armistead G. Russell, and Rodney J. Weber
Atmos. Chem. Phys., 20, 5197–5210, https://doi.org/10.5194/acp-20-5197-2020, https://doi.org/10.5194/acp-20-5197-2020, 2020
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This study provides a direct intercomparison between two assays for quantifying oxidative potential (OP) of ambient particles: the synthetic respiratory-tract-lining fluid (RTLF) assay and the dithiothreitol (DTT) assay. The results suggest that the DTT assay and the ascorbic acid depletion in RTLF are associated with organic species, transition metal ions, and antagonistic interactions between species. The glutathione depletion in RTLF is strongly dependent on water-soluble copper.
Wei Yuan, Ru-Jin Huang, Lu Yang, Jie Guo, Ziyi Chen, Jing Duan, Ting Wang, Haiyan Ni, Yongming Han, Yongjie Li, Qi Chen, Yang Chen, Thorsten Hoffmann, and Colin O'Dowd
Atmos. Chem. Phys., 20, 5129–5144, https://doi.org/10.5194/acp-20-5129-2020, https://doi.org/10.5194/acp-20-5129-2020, 2020
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We characterized light-absorbing properties, chromophore composition and sources of brown carbon (BrC) in Xi'an; identified three groups of light-absorbing organics; and quantified their contribution to overall BrC absorption. Our results showed that vehicle emissions and secondary formation are major sources of BrC in spring, coal combustion and vehicle emissions are major sources in fall, biomass burning and coal combustion become major sources in winter, and secondary BrC dominates in summer.
Yuning Xie, Gehui Wang, Xinpei Wang, Jianmin Chen, Yubao Chen, Guiqian Tang, Lili Wang, Shuangshuang Ge, Guoyan Xue, Yuesi Wang, and Jian Gao
Atmos. Chem. Phys., 20, 5019–5033, https://doi.org/10.5194/acp-20-5019-2020, https://doi.org/10.5194/acp-20-5019-2020, 2020
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As a result of strict emission control, nitrate-dominated PM2.5 in pollution episodes was observed in urban Beijing during the winter of 2017–2018. With the help of sufficient ammonia, particle pH could increase to near neutral (5.4) as particulate nitrate fraction increases. Further tests imply that airborne particle hygroscopicity would be enhanced at moderate RH in nitrate-dominated particles, and pH elevation will be accelerated when ammonia and particulate nitrate both increase.
Tianfeng Guo, Zhigang Guo, Juntao Wang, Jialiang Feng, Huiwang Gao, and Xiaohong Yao
Atmos. Chem. Phys., 20, 5055–5070, https://doi.org/10.5194/acp-20-5055-2020, https://doi.org/10.5194/acp-20-5055-2020, 2020
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This study investigated tracer-based organic matter observations over two marginal seas of China and the northwest Pacific Ocean in spring, when the East Asian monsoon carries biogenic and anthropogenic aerosols over these oceanic zones. The geographical difference may be related to emissions of primary particulate organics and gaseous precursors as well as formation processing of secondary organics in various atmospheres. Furthermore, we present the tracer-based estimation of organic carbon.
Jianjun Li, Qi Zhang, Gehui Wang, Jin Li, Can Wu, Lang Liu, Jiayuan Wang, Wenqing Jiang, Lijuan Li, Kin Fai Ho, and Junji Cao
Atmos. Chem. Phys., 20, 4889–4904, https://doi.org/10.5194/acp-20-4889-2020, https://doi.org/10.5194/acp-20-4889-2020, 2020
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We examined light absorption properties and molecular composition of water-soluble (WS) and water-insoluble (WI) BrC in PM2.5 collected from northwest China. We found that photochemical formation contributes significantly to light absorption of WI-BrC in summer, whereas aqueous-phase reactions play an important role in secondary WS-BrC formation in winter. BrC was estimated to account for 1.36 % and 3.74 %, respectively, of total down-welling solar radiation in the UV range in summer and winter.
Siddika Celik, Frank Drewnick, Friederike Fachinger, James Brooks, Eoghan Darbyshire, Hugh Coe, Jean-Daniel Paris, Philipp G. Eger, Jan Schuladen, Ivan Tadic, Nils Friedrich, Dirk Dienhart, Bettina Hottmann, Horst Fischer, John N. Crowley, Hartwig Harder, and Stephan Borrmann
Atmos. Chem. Phys., 20, 4713–4734, https://doi.org/10.5194/acp-20-4713-2020, https://doi.org/10.5194/acp-20-4713-2020, 2020
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Analysis of 252 ship emission plumes in the Mediterranean Sea and around the Arabian Peninsula examined particulate- and gas-phase characteristics. By identifying the corresponding ships, source features and plume age were determined. Emission factors (amount of pollutant per kilogram of fuel burned) were calculated and investigated for dependencies on source characteristics, atmospheric conditions, and transport time, providing insight into the most relevant influences on ship emissions.
August Andersson, Elena N. Kirillova, Stefano Decesari, Langley DeWitt, Jimmy Gasore, Katherine E. Potter, Ronald G. Prinn, Maheswar Rupakheti, Jean de Dieu Ndikubwimana, Julius Nkusi, and Bonfils Safari
Atmos. Chem. Phys., 20, 4561–4573, https://doi.org/10.5194/acp-20-4561-2020, https://doi.org/10.5194/acp-20-4561-2020, 2020
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Large-scale biomass burning events seasonally cover sub-Saharan Africa with air particles. In this study, we find that the concentrations of these particles at a remote mountain site in Rwanda may increase by a factor of 10 during such dry biomass burning periods, with strong implications for the regional climate and human health. These results provide quantitative constraints that could contribute to reducing the large uncertainties regarding the environmental impact of these fires.
Zhenhao Ling, Qianqian Xie, Zhe Wang, Tao Wang, Hai Guo, and Xuemei Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-212, https://doi.org/10.5194/acp-2020-212, 2020
Revised manuscript accepted for ACP
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The observation data from a receptor site in the Pearl River Delta region was analyzed by a photochemical box model with near-explicit chemical mechanisms (i.e., the master chemical mechanism, MCM), and improvements with reversible and irreversible heterogeneous processes of Glyoxal and Methylglyoxal, and the gas-particle partitioning of oxidation products in the present study.
Imre Salma, Anikó Vasanits-Zsigrai, Attila Machon, Tamás Varga, István Major, Virág Gergely, and Mihály Molnár
Atmos. Chem. Phys., 20, 4295–4312, https://doi.org/10.5194/acp-20-4295-2020, https://doi.org/10.5194/acp-20-4295-2020, 2020
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Major carbonaceous aerosol species were apportioned among FF combustion, BB and biogenic sources in various types of atmospheric environments of interest in the Carpathian Basin in different months representing different seasons. The conclusions present novel and valuable research contributions on a large area in central Europe.
Stefano Decesari, Marco Paglione, Matteo Rinaldi, Manuel Dall'Osto, Rafel Simó, Nicola Zanca, Francesca Volpi, Maria Cristina Facchini, Thorsten Hoffmann, Sven Götz, Christopher Johannes Kampf, Colin O'Dowd, Darius Ceburnis, Jurgita Ovadnevaite, and Emilio Tagliavini
Atmos. Chem. Phys., 20, 4193–4207, https://doi.org/10.5194/acp-20-4193-2020, https://doi.org/10.5194/acp-20-4193-2020, 2020
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Atmospheric aerosols in Antarctica contribute to regulate the delicate budget of cloud formation and precipitations. Besides the well-known biogenic production of sulfur-containing aerosol components such as methanesulfonate (MSA), the assessment of biological sources of organic particles in Antarctica remains an active area of research. Here we present the results of aerosol organic characterization during a research cruise performed in the Weddell Sea and in the Southern Ocean in Jan–Feb 2015.
Pengfei Liu, Can Ye, Chaoyang Xue, Chenglong Zhang, Yujing Mu, and Xu Sun
Atmos. Chem. Phys., 20, 4153–4165, https://doi.org/10.5194/acp-20-4153-2020, https://doi.org/10.5194/acp-20-4153-2020, 2020
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A vast area in China is currently going through severe haze episodes with drastically elevated concentrations of PM2.5 in winter. Nitrate and sulfate are main constituents of PM2.5, but their formations via NO2 and SO2 oxidation are still not comprehensively understood. Our results found that the gas-phase reaction of NO2 with OH and the heterogeneous hydrolysis of N2O5 play key roles in nitrate formation, and SO2 aqueous-phase oxidation with H2O2 rather than NO2 contributed greatly to sulfate.
Yu-Chi Lin, Yan-Lin Zhang, Mei-Yi Fan, and Mengying Bao
Atmos. Chem. Phys., 20, 3999–4011, https://doi.org/10.5194/acp-20-3999-2020, https://doi.org/10.5194/acp-20-3999-2020, 2020
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(1) Nitrate was a dominant contributing species in water-soluble inorganic ions during the high PM2.5 events in Nanjing.
(2) Nitrate aerosols in Nanjing during the PM2.5 events were mainly produced by hydrolysis of N2O5 in preexisting aerosols under ammonium-rich regimes.
(3) Control in NOx emissions would inhibit production of nitrate aerosols since NH4NO3 formation was HNO3 limited in Nanjing.
Jing Duan, Ru-Jin Huang, Yongjie Li, Qi Chen, Yan Zheng, Yang Chen, Chunshui Lin, Haiyan Ni, Meng Wang, Jurgita Ovadnevaite, Darius Ceburnis, Chunying Chen, Douglas R. Worsnop, Thorsten Hoffmann, Colin O'Dowd, and Junji Cao
Atmos. Chem. Phys., 20, 3793–3807, https://doi.org/10.5194/acp-20-3793-2020, https://doi.org/10.5194/acp-20-3793-2020, 2020
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We characterized secondary aerosol formation in Beijing. Our results showed that relative humidity (RH) and Ox have opposite effects on sulfate and nitrate formation in summer and winter. The wintertime more-oxidized OOA (MO-OOA) showed a good correlation with aerosol liquid water content (ALWC). Meanwhile, the dependence of less-oxidized OOA (LO-OOA) and the mass ratio of LO-OOA to MO-OOA in Ox both degraded when RH > 60 %, suggesting that RH or ALWC may also affect LO-OOA formation.
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Search articles
Short summary
Multiple year-round records of bulk and size-segregated composition of sea-salt aerosol and acidic gases (HCl and HNO3) were obtained at inland Antarctica. Both acidic sulfur particles and nitric acid are involved in the observed sea-salt dechlorination in spring/summer. The observed sulfate to sodium mass ratio of sea-salt aerosol in winter (0.16 ± 0.05) suggests on average a similar contribution of sea-ice and open-ocean emissions to the sea-salt load over inland Antarctica at that season.
Multiple year-round records of bulk and size-segregated composition of sea-salt aerosol and...
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