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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 16, issue 1
Atmos. Chem. Phys., 16, 123–134, 2016
https://doi.org/10.5194/acp-16-123-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 16, 123–134, 2016
https://doi.org/10.5194/acp-16-123-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 15 Jan 2016

Research article | 15 Jan 2016

A two-dimensional volatility basis set – Part 3: Prognostic modeling and NOx dependence

W. K. Chuang and N. M. Donahue

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Cited articles

Aiken, A. C., de Foy, B., Wiedinmyer, C., DeCarlo, P. F., Ulbrich, I. M., Wehrli, M. N., Szidat, S., Prevot, A. S. H., Noda, J., Wacker, L., Volkamer, R., Fortner, E., Wang, J., Laskin, A., Shutthanandan, V., Zheng, J., Zhang, R., Paredes-Miranda, G., Arnott, W. P., Molina, L. T., Sosa, G., Querol, X., and Jimenez, J. L.: Mexico city aerosol analysis during MILAGRO using high resolution aerosol mass spectrometry at the urban supersite (T0) – Part 2: Analysis of the biomass burning contribution and the non-fossil carbon fraction, Atmos. Chem. Phys., 10, 5315–5341, https://doi.org/10.5194/acp-10-5315-2010, 2010.
Andreae, M. O. and Crutzen, P. J.: Atmospheric Aerosols: Biogeochemical Sources and Role in Atmospheric Chemistry, Science, 276, 1052–1058, 1997.
Arey, J., Aschmann, S. M., Kwok, E. S. C., and Atkinson, R.: Alkyl Nitrate , Hydroxyalkyl Nitrate , and Hydroxycarbonyl Formation from the NOx – Air Photooxidations of C5–C8 n-Alkanes, J. Phys. Chem. A., 105, 1020–1027, 2001.
Atherton, C. S.: Organic nitrates in remote marine environments: Evidence for long-range transport, Geophys. Res. Lett., 16, 1289–1292, 1989.
Atkinson, R. and Arey, J.: Atmospheric degradation of volatile organic compounds, Chem. Rev., 103, 4605–38, 2003.
Publications Copernicus
Short summary
NOx is formed under high-temperature conditions such as combustion. When NOx enters the atmosphere, it alters the chemistry of organic emissions and can form organonitrates. Depending on the conditions, NOx may increase or decrease resulting aerosol concentrations. We expanded the two-dimensional volatility basis set (2D-VBS) to model organonitrates and the effect on aerosol concentrations. We discuss the mathematical framework of the model and include the code in the Supplement.
NOx is formed under high-temperature conditions such as combustion. When NOx enters the...
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