Articles | Volume 16, issue 1
https://doi.org/10.5194/acp-16-123-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-123-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
15 Jan 2016
Research article |
| 15 Jan 2016
A two-dimensional volatility basis set – Part 3: Prognostic modeling and NOx dependence
W. K. Chuang
Carnegie Mellon University Center for Atmospheric Particle Studies, Pittsburgh, USA
Carnegie Mellon University Center for Atmospheric Particle Studies, Pittsburgh, USA
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Cited
26 citations as recorded by crossref.
- Predicting the importance of oxidative aging on indoor organic aerosol concentrations using the two‐dimensional volatility basis set (2D‐ VBS ) B. Cummings & M. Waring 10.1111/ina.12552
- Seasonal distribution and drivers of surface fine particulate matter and organic aerosol over the Indo-Gangetic Plain C. Mogno et al. 10.5194/acp-21-10881-2021
- Tutorial: Dynamic organic growth modeling with a volatility basis set D. Stolzenburg et al. 10.1016/j.jaerosci.2022.106063
- Reaction Mechanisms Underlying Unfunctionalized Alkyl Nitrate Hydrolysis in Aqueous Aerosols F. Keshavarz et al. 10.1021/acsearthspacechem.0c00253
- Characterization of particulate organic nitrates in the Yangtze River Delta, East China, using the time-of-flight aerosol chemical speciation monitor D. Ge et al. 10.1016/j.atmosenv.2021.118927
- Peroxy radical chemistry and the volatility basis set M. Schervish & N. Donahue 10.5194/acp-20-1183-2020
- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
- Modeling the Formation of Organic Compounds across Full Volatility Ranges and Their Contribution to Nanoparticle Growth in a Polluted Atmosphere Z. Li et al. 10.1021/acs.est.3c06708
- Formation and Evolution of Catechol-Derived SOA Mass, Composition, Volatility, and Light Absorption C. Fredrickson et al. 10.1021/acsearthspacechem.2c00007
- Fostering a Holistic Understanding of the Full Volatility Spectrum of Organic Compounds from Benzene Series Precursors through Mechanistic Modeling D. Yin et al. 10.1021/acs.est.3c07128
- Using GECKO-A to derive mechanistic understanding of secondary organic aerosol formation from the ubiquitous but understudied camphene I. Afreh et al. 10.5194/acp-21-11467-2021
- Volatile Chemical Product Enhancements to Criteria Pollutants in the United States K. Seltzer et al. 10.1021/acs.est.1c04298
- Understanding the Evolution of Smoke Mass Extinction Efficiency Using Field Campaign Measurements P. Saide et al. 10.1029/2022GL099175
- Technical note: Relating functional group measurements to carbon types for improved model–measurement comparisons of organic aerosol composition S. Takahama & G. Ruggeri 10.5194/acp-17-4433-2017
- The Synergistic Role of Sulfuric Acid, Bases, and Oxidized Organics Governing New‐Particle Formation in Beijing C. Yan et al. 10.1029/2020GL091944
- Intermediate Volatile Organic Compound Emissions from Residential Solid Fuel Combustion Based on Field Measurements in Rural China Z. Qian et al. 10.1021/acs.est.0c07908
- Secondary organic aerosol production from pinanediol, a semi-volatile surrogate for first-generation oxidation products of monoterpenes P. Ye et al. 10.5194/acp-18-6171-2018
- Evolution of aerosol chemistry in Xi'an during the spring dust storm periods: Implications for heterogeneous formation of secondary organic aerosols on the dust surface Y. Ren et al. 10.1016/j.chemosphere.2018.10.064
- NO3·-Initiated Gas-Phase Formation of Nitrated Phenolic Compounds in Polluted Atmosphere S. Wang & H. Li 10.1021/acs.est.0c08041
- Formation of secondary organic aerosol from wildfire emissions enhanced by long-time ageing Y. He et al. 10.1038/s41561-023-01355-4
- Gas–particle partitioning and hydrolysis of organic nitrates formed from the oxidation of <i>α</i>-pinene in environmental chamber experiments J. Bean & L. Hildebrandt Ruiz 10.5194/acp-16-2175-2016
- Why would apparent κ linearly change with O/C? Assessing the role of volatility, solubility, and surface activity of organic aerosols S. Nakao 10.1080/02786826.2017.1352082
- Size-dependent influence of NO x on the growth rates of organic aerosol particles C. Yan et al. 10.1126/sciadv.aay4945
- Interactions of peroxy radicals from monoterpene and isoprene oxidation simulated in the radical volatility basis set M. Schervish et al. 10.1039/D4EA00056K
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning B. Murphy et al. 10.5194/acp-17-11107-2017
26 citations as recorded by crossref.
- Predicting the importance of oxidative aging on indoor organic aerosol concentrations using the two‐dimensional volatility basis set (2D‐ VBS ) B. Cummings & M. Waring 10.1111/ina.12552
- Seasonal distribution and drivers of surface fine particulate matter and organic aerosol over the Indo-Gangetic Plain C. Mogno et al. 10.5194/acp-21-10881-2021
- Tutorial: Dynamic organic growth modeling with a volatility basis set D. Stolzenburg et al. 10.1016/j.jaerosci.2022.106063
- Reaction Mechanisms Underlying Unfunctionalized Alkyl Nitrate Hydrolysis in Aqueous Aerosols F. Keshavarz et al. 10.1021/acsearthspacechem.0c00253
- Characterization of particulate organic nitrates in the Yangtze River Delta, East China, using the time-of-flight aerosol chemical speciation monitor D. Ge et al. 10.1016/j.atmosenv.2021.118927
- Peroxy radical chemistry and the volatility basis set M. Schervish & N. Donahue 10.5194/acp-20-1183-2020
- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
- Modeling the Formation of Organic Compounds across Full Volatility Ranges and Their Contribution to Nanoparticle Growth in a Polluted Atmosphere Z. Li et al. 10.1021/acs.est.3c06708
- Formation and Evolution of Catechol-Derived SOA Mass, Composition, Volatility, and Light Absorption C. Fredrickson et al. 10.1021/acsearthspacechem.2c00007
- Fostering a Holistic Understanding of the Full Volatility Spectrum of Organic Compounds from Benzene Series Precursors through Mechanistic Modeling D. Yin et al. 10.1021/acs.est.3c07128
- Using GECKO-A to derive mechanistic understanding of secondary organic aerosol formation from the ubiquitous but understudied camphene I. Afreh et al. 10.5194/acp-21-11467-2021
- Volatile Chemical Product Enhancements to Criteria Pollutants in the United States K. Seltzer et al. 10.1021/acs.est.1c04298
- Understanding the Evolution of Smoke Mass Extinction Efficiency Using Field Campaign Measurements P. Saide et al. 10.1029/2022GL099175
- Technical note: Relating functional group measurements to carbon types for improved model–measurement comparisons of organic aerosol composition S. Takahama & G. Ruggeri 10.5194/acp-17-4433-2017
- The Synergistic Role of Sulfuric Acid, Bases, and Oxidized Organics Governing New‐Particle Formation in Beijing C. Yan et al. 10.1029/2020GL091944
- Intermediate Volatile Organic Compound Emissions from Residential Solid Fuel Combustion Based on Field Measurements in Rural China Z. Qian et al. 10.1021/acs.est.0c07908
- Secondary organic aerosol production from pinanediol, a semi-volatile surrogate for first-generation oxidation products of monoterpenes P. Ye et al. 10.5194/acp-18-6171-2018
- Evolution of aerosol chemistry in Xi'an during the spring dust storm periods: Implications for heterogeneous formation of secondary organic aerosols on the dust surface Y. Ren et al. 10.1016/j.chemosphere.2018.10.064
- NO3·-Initiated Gas-Phase Formation of Nitrated Phenolic Compounds in Polluted Atmosphere S. Wang & H. Li 10.1021/acs.est.0c08041
- Formation of secondary organic aerosol from wildfire emissions enhanced by long-time ageing Y. He et al. 10.1038/s41561-023-01355-4
- Gas–particle partitioning and hydrolysis of organic nitrates formed from the oxidation of <i>α</i>-pinene in environmental chamber experiments J. Bean & L. Hildebrandt Ruiz 10.5194/acp-16-2175-2016
- Why would apparent κ linearly change with O/C? Assessing the role of volatility, solubility, and surface activity of organic aerosols S. Nakao 10.1080/02786826.2017.1352082
- Size-dependent influence of NO x on the growth rates of organic aerosol particles C. Yan et al. 10.1126/sciadv.aay4945
- Interactions of peroxy radicals from monoterpene and isoprene oxidation simulated in the radical volatility basis set M. Schervish et al. 10.1039/D4EA00056K
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning B. Murphy et al. 10.5194/acp-17-11107-2017
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Short summary
NOx is formed under high-temperature conditions such as combustion. When NOx enters the atmosphere, it alters the chemistry of organic emissions and can form organonitrates. Depending on the conditions, NOx may increase or decrease resulting aerosol concentrations. We expanded the two-dimensional volatility basis set (2D-VBS) to model organonitrates and the effect on aerosol concentrations. We discuss the mathematical framework of the model and include the code in the Supplement.
NOx is formed under high-temperature conditions such as combustion. When NOx enters the...
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