Articles | Volume 14, issue 23
https://doi.org/10.5194/acp-14-12815-2014
https://doi.org/10.5194/acp-14-12815-2014
Research article
 | 
08 Dec 2014
Research article |  | 08 Dec 2014

Henry's law constants of polyols

S. Compernolle and J.-F. Müller

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Cited articles

Apelblat, A.: Dissociation constants and limiting conductances of organic acids in water, J. Mol. Liq., 95, 99–145, 2002.
Atkins, P. and de Paula, J.: Physical Chemistry, Oxford University Pres, 2006.
Badea, E., Nowicka, B., and Della Gatta, G.: Thermodynamics of fusion and sublimation for a homologous series of eleven alkane-α, ω-diols HO-\chem(CH_2)_n-OH: structure-related odd-even effect, J. Chem. Thermodyn., 68, 90–97, 2014.
Bao, L., Matsumoto, M., Kubota, T., Sekiguchi, K., Wang, Q., and Sakamoto, K.: Gas/particle partitioning of low-molecular-weight dicarboxylic acids at a suburban site in Saitama, Japan, Atmos. Environ., 47, 546–553, 2012.
Barone, G., Gatta, G. D., Ferro, D., and Piacente, V.: Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc. Faraday T., 86, 75–79, 1990.
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Short summary
Aqueous phase occurs in the atmosphere as cloud droplets and aqueous aerosol. The Henry's law constant regulates the water-gas partitioning of a molecule, but experimental data on polyols are limited. New values are derived for molecules with 2-6 hydroxyl groups, by combining other thermophysical data (e.g. vapour pressure, water activity, solubility). It is analysed which molecules will stay mostly in the gas phase, and which will preferably partition to droplet or aqueous aerosol.
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