Articles | Volume 9, issue 14
https://doi.org/10.5194/acp-9-5107-2009
© Author(s) 2009. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-9-5107-2009
© Author(s) 2009. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
28 Jul 2009
In-cloud processes of methacrolein under simulated conditions – Part 2: Formation of secondary organic aerosol
I. El Haddad
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264: Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
Yao Liu
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264: Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
L. Nieto-Gligorovski
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264: Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
V. Michaud
Laboratoire de Météorologie Physique (UMR 6016), Observatoire de Physique du Globe de Clermont-Ferrand, Université Blaise Pascal, 24 avenue des Landais, 63177 Aubière, France
B. Temime-Roussel
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264: Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
E. Quivet
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264: Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
N. Marchand
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264: Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
K. Sellegri
Laboratoire de Météorologie Physique (UMR 6016), Observatoire de Physique du Globe de Clermont-Ferrand, Université Blaise Pascal, 24 avenue des Landais, 63177 Aubière, France
A. Monod
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264: Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
Related subject area
Subject: Clouds and Precipitation | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Direct formation of HONO through aqueous-phase photolysis of organic nitrates
On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal
Effects of pH and light exposure on the survival of bacteria and their ability to biodegrade organic compounds in clouds: implications for microbial activity in acidic cloud water
Towards a chemical mechanism of the oxidation of aqueous sulfur dioxide via isoprene hydroxyl hydroperoxides (ISOPOOH)
On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation
Lignin's ability to nucleate ice via immersion freezing and its stability towards physicochemical treatments and atmospheric processing
Biodegradation of phenol and catechol in cloud water: comparison to chemical oxidation in the atmospheric multiphase system
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 2: Quartz and amorphous silica
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 3: Aluminosilicates
Aqueous reactions of organic triplet excited states with atmospheric alkenes
The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 1: The K-feldspar microcline
Direct molecular-level characterization of different heterogeneous freezing modes on mica – Part 1
Chemistry of riming: the retention of organic and inorganic atmospheric trace constituents
Surface-charge-induced orientation of interfacial water suppresses heterogeneous ice nucleation on α-alumina (0001)
Screening of cloud microorganisms isolated at the Puy de Dôme (France) station for the production of biosurfactants
Comparing contact and immersion freezing from continuous flow diffusion chambers
A better understanding of hydroxyl radical photochemical sources in cloud waters collected at the puy de Dôme station – experimental versus modelled formation rates
Deposition and immersion-mode nucleation of ice by three distinct samples of volcanic ash
Organic matter matters for ice nuclei of agricultural soil origin
Effect of atmospheric organic complexation on iron-bearing dust solubility
Are sesquiterpenes a good source of secondary organic cloud condensation nuclei (CCN)? Revisiting β-caryophyllene CCN
Ice nucleation efficiency of clay minerals in the immersion mode
Atmospheric chemistry of carboxylic acids: microbial implication versus photochemistry
Yields of hydrogen peroxide from the reaction of hydroxyl radical with organic compounds in solution and ice
In-cloud processes of methacrolein under simulated conditions – Part 1: Aqueous phase photooxidation
Juan Miguel González-Sánchez, Miquel Huix-Rotllant, Nicolas Brun, Julien Morin, Carine Demelas, Amandine Durand, Sylvain Ravier, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 23, 15135–15147, https://doi.org/10.5194/acp-23-15135-2023, https://doi.org/10.5194/acp-23-15135-2023, 2023
Short summary
Short summary
Organic nitrates play a crucial role in air pollution, as they are nitrogen oxide (NOx) reservoirs. This work investigated the reaction products and mechanisms of their reactivity with light in the aqueous phase (cloud and fog conditions and wet aerosol). Our findings reveal that this chemistry leads to the formation of atmospheric nitrous acid (HONO).
Juan Miguel González-Sánchez, Nicolas Brun, Junteng Wu, Sylvain Ravier, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 23, 5851–5866, https://doi.org/10.5194/acp-23-5851-2023, https://doi.org/10.5194/acp-23-5851-2023, 2023
Short summary
Short summary
Organic nitrates play a crucial role in air pollution, as they are NOx reservoirs. This work investigated for the first time their reactivity with light in the aqueous phase (cloud and fog and wet aerosol), proving it slower than in the gas phase. Therefore, our findings reveal that partitioning of organic nitrates in the aqueous phase leads to longer atmospheric lifetimes of these compounds and thus a broader spatial distribution of their related pollution.
Yushuo Liu, Chee Kent Lim, Zhiyong Shen, Patrick K. H. Lee, and Theodora Nah
Atmos. Chem. Phys., 23, 1731–1747, https://doi.org/10.5194/acp-23-1731-2023, https://doi.org/10.5194/acp-23-1731-2023, 2023
Short summary
Short summary
We investigated how cloud water pH and solar radiation impact the survival and energetic metabolism of two neutrophilic bacteria species and their biodegradation of organic acids. Experiments were performed using artificial cloud water that mimicked the pH and composition of cloud water in South China. We found that there is a minimum cloud water pH threshold at which neutrophilic bacteria will survive and biodegrade organic compounds in cloud water during the daytime and/or nighttime.
Eleni Dovrou, Kelvin H. Bates, Jean C. Rivera-Rios, Joshua L. Cox, Joshua D. Shutter, and Frank N. Keutsch
Atmos. Chem. Phys., 21, 8999–9008, https://doi.org/10.5194/acp-21-8999-2021, https://doi.org/10.5194/acp-21-8999-2021, 2021
Short summary
Short summary
We examined the mechanism and products of oxidation of dissolved sulfur dioxide with the main isomers of isoprene hydroxyl hydroperoxides, via laboratory and model analysis. Two chemical mechanism pathways are proposed and the results provide an improved understanding of the broader atmospheric chemistry and role of multifunctional organic hydroperoxides, which should be the dominant VOC oxidation products under low-NO conditions, highlighting their significant contribution to sulfate formation.
Juan Miguel González-Sánchez, Nicolas Brun, Junteng Wu, Julien Morin, Brice Temime-Roussel, Sylvain Ravier, Camille Mouchel-Vallon, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 21, 4915–4937, https://doi.org/10.5194/acp-21-4915-2021, https://doi.org/10.5194/acp-21-4915-2021, 2021
Short summary
Short summary
Organic nitrates play a crucial role in air pollution as they are considered NOx reservoirs. This work lights up the importance of their reactions with OH radicals in the aqueous phase (cloud/fog, wet aerosol), which is slower than in the gas phase. For compounds that significantly partition in water such as polyfunctional biogenic nitrates, these aqueous-phase reactions should drive their atmospheric removal, leading to a broader spatial distribution of NOx than previously accounted for.
Sophie Bogler and Nadine Borduas-Dedekind
Atmos. Chem. Phys., 20, 14509–14522, https://doi.org/10.5194/acp-20-14509-2020, https://doi.org/10.5194/acp-20-14509-2020, 2020
Short summary
Short summary
To study the role of organic matter in ice crystal formation, we investigated the ice nucleation ability of a subcomponent of organic aerosols, the biopolymer lignin, using a droplet-freezing technique. We found that lignin is an ice-active macromolecule with changing abilities based on dilutions. The effects of atmospheric processing and of physicochemical treatments on the ability of lignin solutions to freeze were negligible. Thus, lignin is a recalcitrant ice-nucleating macromolecule.
Saly Jaber, Audrey Lallement, Martine Sancelme, Martin Leremboure, Gilles Mailhot, Barbara Ervens, and Anne-Marie Delort
Atmos. Chem. Phys., 20, 4987–4997, https://doi.org/10.5194/acp-20-4987-2020, https://doi.org/10.5194/acp-20-4987-2020, 2020
Short summary
Short summary
Current atmospheric multiphase models do not include biotransformations of organic compounds by bacteria, although many previous studies of our and other research groups have shown microbial activity in cloud water. The current lab/model study shows that for water-soluble aromatic compounds, biodegradation by bacteria may be as efficient as chemical reactions in cloud water.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6035–6058, https://doi.org/10.5194/acp-19-6035-2019, https://doi.org/10.5194/acp-19-6035-2019, 2019
Short summary
Short summary
This paper not only interests the atmospheric science community but has a potential to cater to a broader audience. We discuss both long- and
short-term effects of various
atmospherically relevantchemical species on a fairly abundant mineral surface
Quartz. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6059–6084, https://doi.org/10.5194/acp-19-6059-2019, https://doi.org/10.5194/acp-19-6059-2019, 2019
Short summary
Short summary
This paper not only interests the Atmospheric Science community but has a potential to cater to a broader audience. We discuss both long- and short-term effects of various
atmospherically relevantchemical species on fairly abundant mineral surfaces like feldspars and clays. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Richie Kaur, Brandi M. Hudson, Joseph Draper, Dean J. Tantillo, and Cort Anastasio
Atmos. Chem. Phys., 19, 5021–5032, https://doi.org/10.5194/acp-19-5021-2019, https://doi.org/10.5194/acp-19-5021-2019, 2019
Short summary
Short summary
Organic triplets are an important class of aqueous photooxidants, but little is known about their reactions with most atmospheric organic compounds. We measured the reaction rate constants of a model triplet with 17 aliphatic alkenes; using their correlation with oxidation potential, we predicted rate constants for some atmospherically relevant alkenes. Depending on their reactivities, triplets can be minor to important sinks for isoprene- and limonene-derived alkenes in cloud or fog drops.
Julián Gelman Constantin, Melisa M. Gianetti, María P. Longinotti, and Horacio R. Corti
Atmos. Chem. Phys., 18, 14965–14978, https://doi.org/10.5194/acp-18-14965-2018, https://doi.org/10.5194/acp-18-14965-2018, 2018
Short summary
Short summary
Numerous studies have shown that ice surface is actually coated by a thin layer of water even for temperatures below melting temperature. This quasi-liquid layer is relevant in the atmospheric chemistry of clouds, polar regions, glaciers, and other cold regions. We present new results of atomic force microscopy on pure ice, which suggests a thickness for this layer below 1 nm between -7 ºC and -2 ºC. We propose that in many cases previous authors have overestimated this thickness.
Anand Kumar, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 18, 7057–7079, https://doi.org/10.5194/acp-18-7057-2018, https://doi.org/10.5194/acp-18-7057-2018, 2018
Short summary
Short summary
We have performed immersion freezing experiments with microcline (most active ice nucleation, IN, K-feldspar polymorph) and investigated the effect of ammonium and non-ammonium solutes on its IN efficiency. We report increased IN efficiency of microcline in dilute ammonia- or ammonium-containing solutions, which opens up a pathway for condensation freezing occurring at a warmer temperature than immersion freezing.
Ahmed Abdelmonem
Atmos. Chem. Phys., 17, 10733–10741, https://doi.org/10.5194/acp-17-10733-2017, https://doi.org/10.5194/acp-17-10733-2017, 2017
Short summary
Short summary
On the basis of supercooled SHG spectroscopy, I report molecular-level evidence for the existence of one- and two-step deposition freezing depending on the surface type and the supersaturation conditions. In addition, immersion freezing shows a transient ice phase with a lifetime of c. 1 min. This study provides new insights into atmospheric processes and can impact various industrial and research branches, particularly climate change, weather modification, and tracing water in the hydrosphere.
Alexander Jost, Miklós Szakáll, Karoline Diehl, Subir K. Mitra, and Stephan Borrmann
Atmos. Chem. Phys., 17, 9717–9732, https://doi.org/10.5194/acp-17-9717-2017, https://doi.org/10.5194/acp-17-9717-2017, 2017
Short summary
Short summary
During riming of graupel and hail, soluble chemical trace constituents contained in the liquid droplets could be retained while freezing onto the glaciated particle, or released back to the air potentially at other altitudes as retained. Quantification of retention constitutes a major uncertainty in numerical models for atmospheric chemistry and improvements hinge upon experimental determination of retention for carboxylic acids, aldehydes, SO2, H2O2, NH2, and others, as presented in this paper.
Ahmed Abdelmonem, Ellen H. G. Backus, Nadine Hoffmann, M. Alejandra Sánchez, Jenée D. Cyran, Alexei Kiselev, and Mischa Bonn
Atmos. Chem. Phys., 17, 7827–7837, https://doi.org/10.5194/acp-17-7827-2017, https://doi.org/10.5194/acp-17-7827-2017, 2017
Short summary
Short summary
We report the effect of surface charge on heterogeneous immersion freezing for the atmospherically relevant sapphire surface. Combining linear and nonlinear optical techniques and investigating isolated drops, we find that charge-induced surface templating is detrimental for ice nucleation on α-alumina surface. This study provides new insights into atmospheric processes and can impact various industrial and research branches, particularly climate change and tracing of water in the hydrosphere.
Pascal Renard, Isabelle Canet, Martine Sancelme, Nolwenn Wirgot, Laurent Deguillaume, and Anne-Marie Delort
Atmos. Chem. Phys., 16, 12347–12358, https://doi.org/10.5194/acp-16-12347-2016, https://doi.org/10.5194/acp-16-12347-2016, 2016
Short summary
Short summary
A total of 480 microorganisms collected from 39 clouds sampled in France were isolated and identified. This unique collection was screened for biosurfactant production by measuring the surface tension. 41 % of the tested strains were active producers. Pseudomonas, the most frequently detected genus in clouds, was the dominant group for the production of biosurfactants. Further, the potential impact of the production of biosurfactants by cloud microorganisms on atmospheric processes is discussed.
Baban Nagare, Claudia Marcolli, André Welti, Olaf Stetzer, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8899–8914, https://doi.org/10.5194/acp-16-8899-2016, https://doi.org/10.5194/acp-16-8899-2016, 2016
Short summary
Short summary
The relative importance of contact freezing and immersion freezing at mixed-phase cloud temperatures is the subject of debate. We performed experiments using continuous-flow diffusion chambers to compare the freezing efficiency of ice-nucleating particles for both these nucleation modes. Silver iodide, kaolinite and Arizona Test Dust were used as ice-nucleating particles. We could not confirm the dominance of contact freezing over immersion freezing for our experimental conditions.
A. Bianco, M. Passananti, H. Perroux, G. Voyard, C. Mouchel-Vallon, N. Chaumerliac, G. Mailhot, L. Deguillaume, and M. Brigante
Atmos. Chem. Phys., 15, 9191–9202, https://doi.org/10.5194/acp-15-9191-2015, https://doi.org/10.5194/acp-15-9191-2015, 2015
G. P. Schill, K. Genareau, and M. A. Tolbert
Atmos. Chem. Phys., 15, 7523–7536, https://doi.org/10.5194/acp-15-7523-2015, https://doi.org/10.5194/acp-15-7523-2015, 2015
Short summary
Short summary
Fine volcanic ash can influence cloud glaciation and, therefore, global climate. In this work we examined the heterogeneous ice nucleation properties of three distinct types of volcanic ash. We find that, in contrast to previous studies, these volcanic ash samples have different ice nucleation properties in the immersion mode. In the deposition mode, however, they nucleate ice with similar efficiency. We show that this behavior may be due to their mineralogy.
Y. Tobo, P. J. DeMott, T. C. J. Hill, A. J. Prenni, N. G. Swoboda-Colberg, G. D. Franc, and S. M. Kreidenweis
Atmos. Chem. Phys., 14, 8521–8531, https://doi.org/10.5194/acp-14-8521-2014, https://doi.org/10.5194/acp-14-8521-2014, 2014
R. Paris and K. V. Desboeufs
Atmos. Chem. Phys., 13, 4895–4905, https://doi.org/10.5194/acp-13-4895-2013, https://doi.org/10.5194/acp-13-4895-2013, 2013
X. Tang, D. R. Cocker III, and A. Asa-Awuku
Atmos. Chem. Phys., 12, 8377–8388, https://doi.org/10.5194/acp-12-8377-2012, https://doi.org/10.5194/acp-12-8377-2012, 2012
V. Pinti, C. Marcolli, B. Zobrist, C. R. Hoyle, and T. Peter
Atmos. Chem. Phys., 12, 5859–5878, https://doi.org/10.5194/acp-12-5859-2012, https://doi.org/10.5194/acp-12-5859-2012, 2012
M. Vaïtilingom, T. Charbouillot, L. Deguillaume, R. Maisonobe, M. Parazols, P. Amato, M. Sancelme, and A.-M. Delort
Atmos. Chem. Phys., 11, 8721–8733, https://doi.org/10.5194/acp-11-8721-2011, https://doi.org/10.5194/acp-11-8721-2011, 2011
T. Hullar and C. Anastasio
Atmos. Chem. Phys., 11, 7209–7222, https://doi.org/10.5194/acp-11-7209-2011, https://doi.org/10.5194/acp-11-7209-2011, 2011
Yao Liu, I. El Haddad, M. Scarfogliero, L. Nieto-Gligorovski, B. Temime-Roussel, E. Quivet, N. Marchand, B. Picquet-Varrault, and A. Monod
Atmos. Chem. Phys., 9, 5093–5105, https://doi.org/10.5194/acp-9-5093-2009, https://doi.org/10.5194/acp-9-5093-2009, 2009
Cited articles
Altieri, K. E., Carlton, A. G., Lim, H., Turpin, B. J., and Seitzinger, S. P.: Evidence for Oligomer Formation in Clouds: Reactions of Isoprene Oxidation Products. Environ. Sci. Technol., 40, 4956–4960, 2006.
Altieri, K. E., Seitzinger, S. P., Carlton, A. G., Turpin, B. J., Klein, G. C., and Marshall, A. G.: Oligomers formed through in-cloud methylglyoxal reactions: Chemical composition, properties, and mechanisms investigated by ultra-high resolution FT-ICR mass spectrometry, Atmos. Environ., 42, 1476–1490, 2008.
Blando, J. D. and Turpin, B. J.: Secondary organic aerosol formation in cloud and fog droplets: a literature evaluation of plausibility, Atmos. Environ., 34, 1623–1632, 2000.
Carlton, A. G., Turpin, B. J., Lim, H., Altieri, K. E., and Seitzinger, S.: Link between isoprene and secondary organic aerosol (SOA): pyruvic acid oxidation yields low volatility organic acids in clouds, Geophys. Res. Lett., 33, L06822/1–L06822/4, https://doi.org/10.1029/2005GL025374, 2006.
Carlton, A. G., Turpin, B. J., Altieri, K. E., Seitzinger, S., Reff, A., Lim, H., and Ervens, B.: Atmospheric oxalic acid and SOA production from glyoxal: Results of aqueous photooxidation experiments, Atmos. Environ., 41, 7588–7602, 2007.
Claeys, M., Graham, B., Vas, G., Wang, W., Vermeylen, R., Pashynska, V., Cafmeyer, J., Guyon, P., Andreae, M. O., Artaxo, P., and Maenhaut, W.: Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene, Science (Washington DC, USA), 303, 1173–1176, 2004a
Claeys, M., Wang, W., Ion, A. C., Kourtchev, I., Gelencser, A., and Maenhaut, W.: Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide, Atmos. Environ., 38, 4093–4098, 2004b.
Dommen, J., Metzger, A., Duplissy, J., Kalberer, M., Alfarra, M. R., Gascho, A., Weingartner, E., Prevot, A. S. H., Verheggen, B., and Baltensperger, U.: Laboratory observation of oligomers in the aerosol from isoprene/NOx photooxidation, Geophys. Res. Lett., 33, L13805/1–L13805/5, https://doi.org/10.1029/2006GL026523, 2006.
Dron, J., Eyglunent, G., Temime-Roussel, B., Marchand, N., and Wortham, H.: Carboxylic acid functional group analysis using constant neutral loss scanning-mass spectrometry, Anal. Chim. Acta, 605, 61–69, 2007.
Edney, E. O., Kleindienst, T. E., Jaoui, M., Lewandowski, M., Offenberg, J. H., Wang, W., and Claeys, M.: Formation of 2-methyl tetrols and 2-methylglyceric acid in secondary organic aerosol from laboratory irradiated isoprene/NOx/SO2/air mixtures and their detection in ambient PM2.5 samples collected in the eastern United States, Atmos. Environ., 39, 5281–5289, 2005.
Ervens, B., George, C., Williams, J. E., Buxton, G. V., Salmon, G. A., Bydder, M., Wilkinson, F., Dentener, F., Mirabel, P., Wolke, R., and Herrmann, H.: CAPRAM2.4 (MODAC mechanism): An extended and condensed tropospheric aqueous phase mechanism and its application, J. Geophys. Res., 108(D14), 4426, https://doi.org/10.1029/2002JD002202, 2003.
Ervens, B., Feingold, G., Frost, G. J., and Kreidenweis, S. M.: A modelling study of aqueous production of dicarboxylic acids, Part 1: Chemical pathways and organic mass production, J. Geophys. Res., 109, D15205, https://doi.org/10.1029/2003JD004387, 2004a.
Ervens, B., Feingold, G., Clegg, S. L., and Kreidenweis, S. M.: A modelling study of aqueous production of dicarboxylic acids, Part 2: Impact on cloud microphysics, J. Geophys. Res., 109, D15206, https://doi.org/10.1029/2003JD004575, 2004b.
Ervens, B., Carlton, A. G., Turpin, B. J., Altieri, K. E., Kreidensweis, S. M., and Feingold, G.: Secondary organic aerosol yields from cloud-processing of isoprene oxidation products, Geophys. Res. Lett., 35, L02816/1–L02816/5, https://doi.org/10.1029/2007GL031828, 2008.
Gelencsér, and Varga, Z.: Evaluation of the atmospheric significance of multiphase reactions in atmospheric secondary organic aerosol formation, Atmos. Chem. Phys., 5, 2823–2831, 2005.
Guzmán, M. I., Colussi, A. I., and Hoffmann, M. R.: Photoinduced oligomerization of aqueous pyruvic acid, J. Phys. Chem. A, 110, 3619–3626, 2006.
Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, Atmos. Chem. Phys., 5, 1053–1123, 2005.
Kawamura, K. and Sakaguchi, F.: Molecular distributions of water soluble dicarboxylic acids in marine aerosols over the Pacific Ocean including tropics. J. Geophys. Res., 104(D3), 3501–3509, 1999.
Kroll, J. H., Ng, N. L., Murphy, S. M., Flagan, R. C., and Seinfeld, J. H.: Secondary Organic Aerosol Formation from Isoprene Photooxidation, Environ. Sci. Technol., 40, 1869–1877, 2006.
Lee, W., Baasandorj, M., Stevens P. S., and Hites, R. A.: Monitoring OH-Initiated Oxidation Kinetics of Isoprene and Its Products Using Online Mass Spectrometry, Environ. Sci. Technol., 39, 1030–1036, 2005.
Liao, H., Adams, P. J., Seinfeld, J. H., Mickley, L. J., and Jacob, D. J.: Interactions between tropospheric chemistry and aerosols in a unified GCM simulation, J. Geophys. Res., 108(D1), 4001, https://doi.org/10.1029/2001JD001260, 2003.
Lim H., Carlton A. G., and Turpin B. J.: Isoprene forms secondary organic aerosol through cloud processing: model simulations. Environ. Sci. Technol., 39, 4441–4446, 2005.
Liu, Y., El Haddad, I., Scarfogliero, M., Nieto-Gligorovski, L., Temime-Roussel, B., Quivet, E., Marchand, N., Piquet-Varrault, B. and Monod, A.: In-cloud processes of methacrolein under simulated conditions – Part 1: Aqueous phase photooxidation, Atmos. Chem. Phys., submitted, 2009.
Loeffler, K. W., Koehler, C. A., Paul, N. M., and De Haan, D. O.: Oligomer formation in evaporating aqueous glyoxal and methyl glyoxal solutions, Environ. Sci. Technol., 40, 6318–6323, 2006.
Michaud, V., Sellegri, K., Laj, P., Villani, V., Picard, D., El Haddad, I., Liu, Y., Marchand, N., and Monod, A.: In-cloud processes of methacrolein under simulated conditions – Part 3: Hygroscopic and volatility properties of the formed secondary organic aerosol, Atmos. Chem. Phys. Discuss., submitted, 2009.
Monod, A., Chebbi, A., Durand-Jolibois, R., and Carlier, P.: Oxidation of methanol by hydroxyl radicals in aqueous solution under simulated cloud droplet conditions, Atmos. Environ., 34, 5283–5294, 2000.
Müller, J.-F., Stavrakou, T., Wallens, S., De Smedt, I., Van Roozendael, M., Potosnak, M. J., Rinne, J., Munger, B., Goldstein, A., and Guenther, A. B.: Global isoprene emissions estimated using MEGAN, ECMWF analyses and a detailed canopy environment model, Atmos. Chem. Phys., 8, 1329–1341, 2008.
Paulsen, D., Weingartner, E., Alfarra, M. R., and Baltensperger, U.: Volatility measurements of photochemically and nebulizer-generated organic aerosol particles, J. Aerosol Sci., 37, 1025–1051, 2006.
Poulain, L., Monod, A., and Wortham, H.: Development of a new on-line mass spectrometer to study the reactivity of soluble organic compounds in the aqueous phase under tropospheric conditions: Application to OH-oxidation of N-methylpyrrolidone, J. Photoch. Photobio. A, 187, 10–23, 2007.
Sempere, R. and Kawamura, K.: Low molecular weight dicarboxylic acids and related polar compounds in the remote marine rain samples collected from western Pacific, Atmos. Environ., 30, 1609–1619, 1996.
Sokal, R. R. and Rohlf, F. J.: Biometry, 2 ed., Freeman, New York, USA, 1981.
Surratt, J. D., Murphy, S. M., Kroll, J. H., Ng, N. L., Hildebrandt, L., Sorooshian, A., Szmigielski, R., Vermeylen, R., Maenhaut, W., Claeys, M., Flagan, R. C., and Seinfeld, J. H.: Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene, J. Phys. Chem. A, 110, 9665–9690, 2006.
van Pinxteren, D., Plewka, A., Hofmann, D., Mueller, K.; Kramberger, H., Svrcina, B., Baechmann, K., Jaeschke, W., Mertes, S., Collett, J. L., and Herrmann, H.: Schmuecke hill cap cloud and valley stations aerosol characterisation during FEBUKO (II): Organic compounds, Atmos. Environ., 39, 4305–4320, 2005.
Altmetrics
Final-revised paper
Preprint