Articles | Volume 25, issue 15
https://doi.org/10.5194/acp-25-8493-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-25-8493-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note: Towards a stronger observational support for haze pollution control by interpreting carbonaceous aerosol results derived from different measurement approaches
Yuan Cheng
State Key Laboratory of Urban-rural Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, China
Ying-jie Zhong
State Key Laboratory of Urban-rural Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, China
Zhi-qing Zhang
State Key Laboratory of Urban-rural Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, China
Xu-bing Cao
State Key Laboratory of Urban-rural Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, China
State Key Laboratory of Urban-rural Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, China
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Cited articles
Aakko-Saksa, P., Koponen, P., Aurela, M., Vesala, H., Piimäkorpi, P., Murtonen, T., Sippula, O., Koponen, H., Karjalainen, P., Kuittinen, N., Panteliadis, P., Rönkkö, T., and Timonen, H.: Considerations in analysing elemental carbon from marine engine exhaust using residual, distillate and biofuels, J. Aerosol Sci., 126, 191–204, 2018.
Andela, N., Morton, D. C., Schroeder, W., Chen, Y., Brando, P. M., and Randerson, J. T.: Tracking and classifying Amazon fire events in near real time, Sci. Adv., 8, eabd2713, https://doi.org/10.1126/sciadv.abd2713, 2022.
Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006.
Buffaloe, G. M., Lack, D. A., Williams, E. J., Coffman, D., Hayden, K. L., Lerner, B. M., Li, S.-M., Nuaaman, I., Massoli, P., Onasch, T. B., Quinn, P. K., and Cappa, C. D.: Black carbon emissions from in-use ships: a California regional assessment, Atmos. Chem. Phys., 14, 1881–1896, https://doi.org/10.5194/acp-14-1881-2014, 2014.
Cavalli, F., Viana, M., Yttri, K. E., Genberg, J., and Putaud, J.-P.: Toward a standardised thermal-optical protocol for measuring atmospheric organic and elemental carbon: the EUSAAR protocol, Atmos. Meas. Tech., 3, 79–89, https://doi.org/10.5194/amt-3-79-2010, 2010.
Chakrabarty, R. K., Shetty, N. J., Thind, A. S., Beeler, P., Sumlin, B. J., Zhang, C. C., Liu, P., Idrobo, J. C., Adachi, K., Wagner, N. L., Schwarz, J. P., Ahern, A., Sedlacek, A. J., Lambe, A., Daube, C., Lyu, M., Liu, C., Herndon, S., Onasch, T. B., and Mishra, R.: Shortwave absorption by wildfire smoke dominated by dark brown carbon, Nat. Geosci., 16, 683–688, 2023.
Chang, X., Zhao, B., Zheng, H. T., Wang, S. X., Cai, S. Y., Guo, F. Q., Gui, P., Huang, G. H., Wu, D., Han, L. C., Xing, J., Man, H. Y., Hu, R. L., Liang, C. R., Xu, Q. C., Qiu, X. H., Ding, D., Liu, K. Y., Han, R., Robinson, A. L., and Donahue, N. M.: Full-volatility emission framework corrects missing and underestimated secondary organic aerosol sources, One Earth, 5, 403–412, 2022.
Chen, P. F., Kang, S. C., Tripathee, L., Ram, K., Rupakheti, M., Panday, A. K., Zhang, Q., Guo, J. M., Wang, X. X., Pu, T., and Li, C. L.: Light absorption properties of elemental carbon (EC) and water-soluble brown carbon (WS-BrC) in the Kathmandu Valley, Nepal: a 5 year study, Environ. Pollut., 261, 114239, https://doi.org/10.1016/j.envpol.2020.114239, 2020.
Cheng, J., Tong, D., Zhang, Q., Liu, Y., Lei, Y., Yan, G., Yan, L., Yu, S., Cui, R. Y., Clarke, L., Geng, G. N., Zheng, B., Zhang, X. Y., Davis, S. J., and He, K. B.: Pathways of China's PM2.5 air quality 2015–2060 in the context of carbon neutrality, Natl. Sci. Rev., 8, nwab078, https://doi.org/10.1093/nsr/nwab078, 2021.
Cheng, Y., Cao, X. B., Yu, Q. Q., Liu, J. M., Ma, W. L., Qi, H., Zhang, Q., and He, K. B.: Synergy of multiple drivers leading to severe winter haze pollution in a megacity in Northeast China, Atmos. Res., 270, 106075, https://doi.org/10.1016/j.atmosres.2022.106075, 2022.
Cheng, Y., Cao, X., Zhu, S., Zhang, Z., Liu, J., Zhang, H., Zhang, Q., and He, K.: Exploring the sources of light-absorbing carbonaceous aerosols by integrating observational and modeling results: insights from Northeast China, Atmos. Chem. Phys., 24, 9869–9883, https://doi.org/10.5194/acp-24-9869-2024, 2024.
Chiappini, L., Verlhac, S., Aujay, R., Maenhaut, W., Putaud, J. P., Sciare, J., Jaffrezo, J. L., Liousse, C., Galy-Lacaux, C., Alleman, L. Y., Panteliadis, P., Leoz, E., and Favez, O.: Clues for a standardised thermal-optical protocol for the assessment of organic and elemental carbon within ambient air particulate matter, Atmos. Meas. Tech., 7, 1649–1661, https://doi.org/10.5194/amt-7-1649-2014, 2014.
Collaud Coen, M., Weingartner, E., Apituley, A., Ceburnis, D., Fierz-Schmidhauser, R., Flentje, H., Henzing, J. S., Jennings, S. G., Moerman, M., Petzold, A., Schmid, O., and Baltensperger, U.: Minimizing light absorption measurement artifacts of the Aethalometer: evaluation of five correction algorithms, Atmos. Meas. Tech., 3, 457–474, https://doi.org/10.5194/amt-3-457-2010, 2010.
Costa, V., Bacco, D., Castellazzi, S., Ricciardelli, I., Vecchietti, R., Zigola, C., and Pietrogrande, M. C.: Characteristics of carbonaceous aerosols in Emilia-Romagna (Northern Italy) based on two fall/winter field campaigns, Atmos. Res., 167, 100–107, 2016.
Dao, X., Lin, Y. C., Cao, F., Di, S. Y., Hong, Y. H., Xing, G. H., Li, J. J., Fu, P. Q., and Zhang, Y. L.: Introduction to the national aerosol chemical composition monitoring network of China: objectives, current status, and outlook, B. Am. Meteorol. Soc., 100, ES337–ES351, 2019.
Eckhardt, S., Pisso, I., Evangeliou, N., Zwaaftink, C. G., Plach, A., McConnell, J. R., Sigl, M., Ruppel, M., Zdanowicz, C., Lim, S., Chellman, N., Opel, T., Meyer, H., Steffensen, J. P., Schwikowski, M., and Stohl, A.: Revised historical Northern Hemisphere black carbon emissions based on inverse modeling of ice core records, Nat. Commun., 14, 271, https://doi.org/10.1038/s41467-022-35660-0, 2023.
Fuzzi, S., Baltensperger, U., Carslaw, K., Decesari, S., Denier van der Gon, H., Facchini, M. C., Fowler, D., Koren, I., Langford, B., Lohmann, U., Nemitz, E., Pandis, S., Riipinen, I., Rudich, Y., Schaap, M., Slowik, J. G., Spracklen, D. V., Vignati, E., Wild, M., Williams, M., and Gilardoni, S.: Particulate matter, air quality and climate: lessons learned and future needs, Atmos. Chem. Phys., 15, 8217–8299, https://doi.org/10.5194/acp-15-8217-2015, 2015.
Gao, C. Y., Heald, C. L., Katich, J. M., Luo, G., and Yu, F. Q.: Remote aerosol simulated during the Atmospheric Tomography (ATom) campaign and implications for aerosol lifetime, J. Geophys. Res.-Atmos., 127, e2022JD036524, https://doi.org/10.1029/2022JD036524, 2022.
Gao, S., Hegg, D. A., Hobbs, P. V., Kirchstetter, T. W., Magi, B. I., and Sadilek, M.: Water-soluble organic components in aerosols associated with savanna fires in southern Africa: identification, evolution, and distribution, J. Geophys. Res., 108, 8491, https://doi.org/10.1029/2002JD002324, 2003.
Garofalo, L. A., Pothier, M. A., Levin, E. J. T., Campos, T., Kreidenweis, S. M., and Farmer, D. K.: Emission and evolution of submicron organic aerosol in smoke from wildfires in the Western United States, ACS Earth Space Chem., 3, 1237–1247, 2019.
Giannoni, M., Calzolai, G., Chiari,M., Cincinelli, A., Lucarelli, F., Martellini, T., and Nava, S.: A comparison between thermal-optical transmittance elemental carbon measured by different protocols in PM2.5 samples, Sci. Total Environ., 571, 195–205, 2016.
Gkatzelis, G. I., Coggon, M. M., Stockwell, C. E., Hornbrook, R. S., Allen, H., Apel, E. C., Bela, M. M., Blake, D. R., Bourgeois, I., Brown, S. S., Campuzano-Jost, P., St. Clair, J. M., Crawford, J. H., Crounse, J. D., Day, D. A., DiGangi, J. P., Diskin, G. S., Fried, A., Gilman, J. B., Guo, H., Hair, J. W., Halliday, H. S., Hanisco, T. F., Hannun, R., Hills, A., Huey, L. G., Jimenez, J. L., Katich, J. M., Lamplugh, A., Lee, Y. R., Liao, J., Lindaas, J., McKeen, S. A., Mikoviny, T., Nault, B. A., Neuman, J. A., Nowak, J. B., Pagonis, D., Peischl, J., Perring, A. E., Piel, F., Rickly, P. S., Robinson, M. A., Rollins, A. W., Ryerson, T. B., Schueneman, M. K., Schwantes, R. H., Schwarz, J. P., Sekimoto, K., Selimovic, V., Shingler, T., Tanner, D. J., Tomsche, L., Vasquez, K. T., Veres, P. R., Washenfelder, R., Weibring, P., Wennberg, P. O., Wisthaler, A., Wolfe, G. M., Womack, C. C., Xu, L., Ball, K., Yokelson, R. J., and Warneke, C.: Parameterizations of US wildfire and prescribed fire emission ratios and emission factors based on FIREX-AQ aircraft measurements, Atmos. Chem. Phys., 24, 929–956, https://doi.org/10.5194/acp-24-929-2024, 2024.
Hand, J. L., Prenni, A. J., Raffuse, S. M., Hyslop, N. P., Malm, W. C., and Schichtel, B. A.: Spatial and seasonal variability of remote and urban speciated fine particulate matter in the United States, J. Geophys. Res.-Atmos., 129, e2024JD042579, https://doi.org/10.1029/2024JD042579, 2024.
Hecobian, A., Zhang, X., Zheng, M., Frank, N., Edgerton, E. S., and Weber, R. J.: Water-Soluble Organic Aerosol material and the light-absorption characteristics of aqueous extracts measured over the Southeastern United States, Atmos. Chem. Phys., 10, 5965–5977, https://doi.org/10.5194/acp-10-5965-2010, 2010.
Hu, Z. F., Kang, S. C., Xu, J. Z., Zhang, C., Li, X. F., Yan, F. P., Zhang, Y. L., Chen, P. F., and Li, C. L.: Significant overestimation of black carbon concentration caused by high organic carbon in aerosols of the Tibetan Plateau, Atmos. Environ., 294, 119486, https://doi.org/10.1016/j.atmosenv.2022.119486, 2023.
Knox, A., Evans, G. J., Brook, J. R., Yao, X., Jeong, C. H., Godri, K. J., Sabaliauskas, K., and Slowik, J. G.: Mass absorption cross-section of ambient black carbon aerosol in relation to chemical age, Aerosol Sci. Tech., 43, 522–532, 2009.
Laborde, M., Schnaiter, M., Linke, C., Saathoff, H., Naumann, K.-H., Möhler, O., Berlenz, S., Wagner, U., Taylor, J. W., Liu, D., Flynn, M., Allan, J. D., Coe, H., Heimerl, K., Dahlkötter, F., Weinzierl, B., Wollny, A. G., Zanatta, M., Cozic, J., Laj, P., Hitzenberger, R., Schwarz, J. P., and Gysel, M.: Single Particle Soot Photometer intercomparison at the AIDA chamber, Atmos. Meas. Tech., 5, 3077–3097, https://doi.org/10.5194/amt-5-3077-2012, 2012.
Lack, D. A., Moosmüller, H., McMeeking, G. R., Chakrabarty, R. K., and Baumgardner, D.: Characterizing elemental, equivalent black, and refractory black carbon aerosol particles: a review of techniques, their limitations and uncertainties, Anal. Bioanal. Chem., 406, 99–122, 2014.
Lappi, M. K. and Ristimäki, J. M.: Evaluation of thermal optical analysis method of elemental carbon for marine fuel exhaust, J. Air Waste Manage., 67, 1298–1318, 2017.
Li, H. Y., Lamb, K. D., Schwarz, J. P., Selimovic, V., Yokelson, R. J., McMeeking, G. R., and May, A. A.: Inter-comparison of black carbon measurement methods for simulated open biomass burning emissions, Atmos. Environ., 206, 156–169, 2019.
Li, J., Carlson, B. E., Yung, Y. L., Lv, D. R., Hansen, J., Penner, J. E., Liao, H., Ramaswamy, V., Kahn, R. A., Zhang, P., Dubovik, O., Ding, A. J., Lacis, A. A., Zhang, L., and Dong, Y. M.: Scattering and absorbing aerosols in the climate system, Nat. Rev. Earth Environ., 3, 363–379, 2022.
Liu, J. M., Du, Z. Y., Liang, L. L., Yu, Q. Q., Shen, G. F., Ma, Y. L., Zheng, M., Cheng, Y., and He, K. B.: Uncertainties in thermal-optical measurements of black carbon: insights from source and ambient samples, Sci. Total Environ., 656, 239–249, 2019.
Liu, J. M., Wang, P. F., Zhang, H. L., Du, Z. Y., Zheng, B., Yu, Q. Q., Zheng, G. J., Ma, Y. L., Zheng, M., Cheng, Y., Zhang, Q., and He, K. B.: Integration of field observation and air quality modeling to characterize Beijing aerosol in different seasons, Chemosphere, 242, 125195, https://doi.org/10.1016/j.atmosenv.2022.119486, 2020.
Liu, S. G., Geng, G. N., Xiao, Q. Y., Zheng, Y. X., Liu, X. D., Cheng, J., and Zhang, Q.: Tracking daily concentrations of PM2.5 chemical composition in China since 2000, Environ. Sci. Technol., 56, 16517–16527, 2022.
Liu, X. X., Zhang, Y., Huey, L. G., Yokelson, R. J., Wang, Y., Jimenez, J. L., Campuzano-Jost, P., Beyersdorf, A. J., Blake, D. R., Choi, Y., St Clair, J. M., Crounse, J. D., Day, D. A., Diskin, G. S., Fried, A., Hall, S. R., Hanisco, T. F., King, L. E., Meinardi, S., Mikoviny, T., Palm, B. B., Peischl, J., Perring, A. E., Pollack, I. B., Ryerson, T. B., Sachse, G., Schwarz, J. P., Simpson, I. J., Tanner, D. J., Thornhill, K. L., Ullmann, K., Weber, R. J., Wennberg, P. O., Wisthaler, A., Wolfe, G. M., and Ziemba, L. D.: Agricultural fires in the southeastern U. S. during SEAC4RS: Emissions of trace gases and particles and evolution of ozone, reactive nitrogen, and organic aerosol, J. Geophys. Res.-Atmos., 121, 7383–7414, 2016.
Petzold, A., Schloesser, H., Sheridan, P. J., Arnott, W. P., Ogren, J. A., and Virkkula, A.: Evaluation of multiangle absorption photometry for measuring aerosol light absorption, Aerosol Sci. Tech., 39, 40–51, 2005.
Petzold, A., Ogren, J. A., Fiebig, M., Laj, P., Li, S.-M., Baltensperger, U., Holzer-Popp, T., Kinne, S., Pappalardo, G., Sugimoto, N., Wehrli, C., Wiedensohler, A., and Zhang, X.-Y.: Recommendations for reporting “black carbon” measurements, Atmos. Chem. Phys., 13, 8365–8379, https://doi.org/10.5194/acp-13-8365-2013, 2013.
Philip, S., Martin, R., van Donkelaar, A., Lo, J. W. H., Wang, Y. X., Chen, D., Zhang, L., Kasibhatla, P. S., Wang, S. W., Zhang, Q., Lu, Z., Streets, D. G., Bittman, S., and MacDonald, D. J.: Global chemical composition of ambient fine particulate matter for exposure assessment, Environ. Sci. Technol., 48, 13060–13068, 2014.
Piazzalunga, A., Bernardoni, V., Fermo, P., Valli, G., and Vecchi, R.: Technical Note: On the effect of water-soluble compounds removal on EC quantification by TOT analysis in urban aerosol samples, Atmos. Chem. Phys., 11, 10193–10203, https://doi.org/10.5194/acp-11-10193-2011, 2011.
Pileci, R. E., Modini, R. L., Bertò, M., Yuan, J., Corbin, J. C., Marinoni, A., Henzing, B., Moerman, M. M., Putaud, J. P., Spindler, G., Wehner, B., Müller, T., Tuch, T., Trentini, A., Zanatta, M., Baltensperger, U., and Gysel-Beer, M.: Comparison of co-located refractory black carbon (rBC) and elemental carbon (EC) mass concentration measurements during field campaigns at several European sites, Atmos. Meas. Tech., 14, 1379–1403, https://doi.org/10.5194/amt-14-1379-2021, 2021.
Pöschl, U.: Atmospheric aerosols: composition, transformation, climate and health effects, Angew. Chem. Int. Edit., 44, 7520–7540, 2005.
Putaud, J. P., Van Dingenen, R., Alastuey, A., Bauer, H., Birmili, W., Cyrys, J., Flentje, H., Fuzzi, S., Gehrig, R., Hansson, H. C., Harrison, R. M., Herrmann, H., Hitzenberger, R., Hüglin, C., Jones, A. M., Kasper-Giebl, A., Kiss, G., Kousa, A., Kuhlbusch, T. A. J., Löschau, G., Maenhaut, W., Molnar, A., Moreno, T., Pekkanen, J., Perrino, C., Pitz, M., Puxbaum, H., Querol, X., Rodriguez, S., Salma, I., Schwarz, J., Smolik, J., Schneider, J., Spindler, G., ten Brink, H., Tursic, J., Viana, M., Wiedensohler, A., and Raes, F.: A European aerosol phenomenology-3: Physical and chemical characteristics of particulate matter from 60 rural, urban, and kerbside sites across Europe, Atmos. Environ., 44, 1308–1320, 2010.
Qin, Y. M., Tan, H. B., Li, Y. J., Li, Z. J., Schurman, M. I., Liu, L., Wu, C., and Chan, C. K.: Chemical characteristics of brown carbon in atmospheric particles at a suburban site near Guangzhou, China, Atmos. Chem. Phys., 18, 16409–16418, https://doi.org/10.5194/acp-18-16409-2018, 2018.
Samset, B. H., Myhre, G., Herber, A., Kondo, Y., Li, S.-M., Moteki, N., Koike, M., Oshima, N., Schwarz, J. P., Balkanski, Y., Bauer, S. E., Bellouin, N., Berntsen, T. K., Bian, H., Chin, M., Diehl, T., Easter, R. C., Ghan, S. J., Iversen, T., Kirkevåg, A., Lamarque, J.-F., Lin, G., Liu, X., Penner, J. E., Schulz, M., Seland, Ø., Skeie, R. B., Stier, P., Takemura, T., Tsigaridis, K., and Zhang, K.: Modelled black carbon radiative forcing and atmospheric lifetime in AeroCom Phase II constrained by aircraft observations, Atmos. Chem. Phys., 14, 12465–12477, https://doi.org/10.5194/acp-14-12465-2014, 2014.
Shen, G. F., Chen, Y. C., Wei, S. Y., Fu, X. F., Zhu, Y., and Tao, S.: Mass absorption efficiency of elemental carbon for source samples from residential biomass and coal combustions, Atmos. Environ., 79, 79–84, 2013.
State Council: Circular on Further Promoting the Pollution Prevention and Control Battle, https://www.gov.cn/zhengce/2021-11/07/content_5649656.htm (last access: 31 July 2025), 2021.
Subramanian, R., Khlystov, A. Y., and Robinson, A. L.: Effect of peak inert-mode temperature on elemental carbon measured using thermal-optical analysis, Aerosol Sci. Tech., 40, 763–780, 2006.
Sullivan, A. P., Guo, H., Schroder, J. C., Campuzano-Jost, P., Jimenez, J. L., Campos, T., Shah, V., Jaeglé, L., Lee, B. H., Lopez-Hilfiker, F. D., Thornton, J. A., Brown, S. S., and Weber, R. J.: Biomass burning markers and residential burning in the WINTER aircraft campaign, J. Geophys. Res.-Atmos., 124, 1846–1861, 2019.
Tinorua, S., Denjean, C., Nabat, P., Pont, V., Arnaud, M., Bourrianne, T., Dias Alves, M., and Gardrat, E.: A 2 year intercomparison of three methods for measuring black carbon concentration at a high-altitude research station in Europe, Atmos. Meas. Tech., 17, 3897–3915, https://doi.org/10.5194/amt-17-3897-2024, 2024.
von Schneidemesser, E., Monks, P. S., Allan, J. D., Bruhwiler, L., Forster, P., Fowler, D., Lauer, A., Morgan, W. T., Paasonen, P., Righi, M., Sindelarova, K., and Sutton, M. A.: Chemistry and the linkages between air quality and climate change, Chem. Rev., 115, 3856–3897, 2015.
Wang, G. H., Cheng, C. L., Huang, Y., Tao, J., Ren, Y. Q., Wu, F., Meng, J. J., Li, J. J., Cheng, Y. T., Cao, J. J., Liu, S. X., Zhang, T., Zhang, R., and Chen, Y. B.: Evolution of aerosol chemistry in Xi'an, inland China, during the dust storm period of 2013 – Part 1: Sources, chemical forms and formation mechanisms of nitrate and sulfate, Atmos. Chem. Phys., 14, 11571–11585, https://doi.org/10.5194/acp-14-11571-2014, 2014a.
Wang, R., Tao, S., Balkanski, Y., Ciais, P., Boucher, O., Liu, J. F., Piao, S. L., Shen, H. Z., Vuolo, M. R., Valari, M., Chen, H., Chen, Y. C., Cozic, A., Huang, Y., Li, B. G., Li, W., Shen, G. F., Wang, B., and Zhang, Y. Y.: Exposure to ambient black carbon derived from a unique inventory and high-resolution model, P. Natl. Acad. Sci. USA, 111, 2459–2463, 2014b.
Wang, X., Heald, C. L., Liu, J., Weber, R. J., Campuzano-Jost, P., Jimenez, J. L., Schwarz, J. P., and Perring, A. E.: Exploring the observational constraints on the simulation of brown carbon, Atmos. Chem. Phys., 18, 635–653, https://doi.org/10.5194/acp-18-635-2018, 2018.
Wei, J., Li, Z. Q., Lyapustin, A., Wang, J., Dubovik, O., Schwartz, J., Sun, L., Li, C., Liu, S., and Zhu, T.: First close insight into global daily gapless 1 km PM2.5 pollution, variability, and health impact, Nat. Commun., 14, 8349, https://doi.org/10.1038/s41467-023-43862-3, 2023.
Xiao, Q. Y., Geng, G. N., Xue, T., Liu, S. G., Cai, C. L., He, K. B., and Zhang, Q.: Tracking PM2.5 and O3 Pollution and the related health burden in China 2013–2020, Environ. Sci. Technol., 56, 6922–6932, 2022.
Yang, H. and Yu, J. Z.: Uncertainties in charring correction in the analysis of elemental and organic carbon in atmospheric particles by thermal/optical methods, Environ. Sci. Technol., 36, 5199–5204, 2002.
Yu, J. Z., Xu, J. H., and Yang, H.: Charring characteristics of atmospheric organic particulate matter in thermal analysis, Environ. Sci. Technol., 36, 754–761, 2002.
Zheng, G. J., Duan, F. K., Su, H., Ma, Y. L., Cheng, Y., Zheng, B., Zhang, Q., Huang, T., Kimoto, T., Chang, D., Pöschl, U., Cheng, Y. F., and He, K. B.: Exploring the severe winter haze in Beijing: the impact of synoptic weather, regional transport and heterogeneous reactions, Atmos. Chem. Phys., 15, 2969–2983, https://doi.org/10.5194/acp-15-2969-2015, 2015.
Zhong, Q. R., Schutgens, N., van der Werf, G. R., Takemura, T., van Noije, T., Mielonen, T., Checa-Garcia, R., Lohmann, U., Kirkevåg, A., Olivié, D. J. L., Kokkola, H., Matsui, H., Kipling, Z., Ginoux, P., Le Sager, P., Rémy, S., Bian, H. S., Chin, M., Zhang, K., Bauer, S. E., and Tsigaridis, K.: Threefold reduction of modeled uncertainty in direct radiative effects over biomass burning regions by constraining absorbing aerosols, Sci. Adv., 9, eadi3568, https://doi.org/10.1126/sciadv.adi3568, 2023.
Short summary
As an emerging hotspot of atmospheric sciences, northeastern China is distinct due to the frigid winter and the strong emissions from agricultural fires. Based on field campaigns conducted in Harbin, we successively identified the analytical method that could lead to proper results of organic and elemental carbon. Our results are believed to be a support for future efforts in the exploration of PM2.5 sources in northeastern China, which are essential for further improving the regional air quality.
As an emerging hotspot of atmospheric sciences, northeastern China is distinct due to the frigid...
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