Articles | Volume 25, issue 9
https://doi.org/10.5194/acp-25-4943-2025
https://doi.org/10.5194/acp-25-4943-2025
Research article
 | 
12 May 2025
Research article |  | 12 May 2025

Validation and uncertainty quantification of three state-of-the-art ammonia surface exchange schemes using NH3 flux measurements in a dune ecosystem

Tycho Jongenelen, Margreet van Zanten, Enrico Dammers, Roy Wichink Kruit, Arjan Hensen, Leon Geers, and Jan Willem Erisman

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Cited articles

Benner, W. H., Ogorevc, B., and Novakov, T.: Oxidation of SO2 in thin water films containing NH3, Atmos. Environ. A-Gen., 26, 1713–1723, https://doi.org/10.1016/0960-1686(92)90069-W, 1992. 
Brandsma, T.: Parallel air temperature measurements at the KNMI-terrain in De Bilt (the Netherlands) May 2003–April 2005, KNMI, https://www.knmi.nl/kennis-en-datacentrum/publicatie/parallel-air-temperature-measurements-at-the-knmi-terrain-in (last access: 12 April 2024), 2004. 
Burkhardt, J., Flechard, C. R., Gresens, F., Mattsson, M., Jongejan, P. A. C., Erisman, J. W., Weidinger, T., Meszaros, R., Nemitz, E., and Sutton, M. A.: Modelling the dynamic chemical interactions of atmospheric ammonia with leaf surface wetness in a managed grassland canopy, Biogeosciences, 6, 67–84, https://doi.org/10.5194/bg-6-67-2009, 2009. 
Bytnerowicz, A., Johnson, R. F., Zhang, L., Jenerette, G. D., Fenn, M. E., Schilling, S. L., and Gonzalez-Fernandez, I.: An empirical inferential method of estimating nitrogen deposition to Mediterranean-type ecosystems: the San Bernardino Mountains case study, Environ. Pollut., 203, 69–88, https://doi.org/10.1016/j.envpol.2015.03.028, 2015. 
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This article compares three ammonia (NH3) deposition models in a dune ecosystem and investigates the uncertainty of these models. The Zhang model aligned best with the measurements, whereas the DEPAC (DEPosition of Acidifying Compounds) and Massad models overestimated and underestimated the NH3 deposition respectively. The study found that NH3 exchange with wet plant leaves was an important but uncertain process. It offers recommendations to improve future models and suggests measurements to lower the existing uncertainty.
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