Articles | Volume 25, issue 22
https://doi.org/10.5194/acp-25-16315-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-25-16315-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Measurement report: Molecular characterization of organic aerosol in coastal environments using offline FIGAERO-I-CIMS
Yuping Chen
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
Lingling Xu
CORRESPONDING AUTHOR
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Xiaolong Fan
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Ziyi Lin
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
Chen Yang
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
Gaojie Chen
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
Ronghua Zheng
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Youwei Hong
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Mengren Li
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Yanru Zhang
Xiamen Environmental Monitoring Station, Xiamen 361021, China
State Key Laboratory of Advanced Environmental Technology, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Fujian Key Laboratory of Atmospheric Ozone Pollution Prevention, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
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Cited articles
An, Y., Xu, J., Feng, L., Zhang, X., Liu, Y., Kang, S., Jiang, B., and Liao, Y.: Molecular characterization of organic aerosol in the Himalayas: insight from ultra-high-resolution mass spectrometry, Atmos. Chem. Phys., 19, 1115–1128, https://doi.org/10.5194/acp-19-1115-2019, 2019.
Berndt, T., Hyttinen, N., Herrmann, H., and Hansel A.: First oxidation products from the reaction of hydroxyl radicals with isoprene for pristine environmental conditions, Commun. Chem., 2, 21, https://doi.org/10.1038/s42004-019-0120-9, 2019.
Bianchi, F., Kurten, T., Riva, M., Mohr, C., Rissanen, M., Roldin, P., Berndt, T., Crounse, J., Wennberg, P., Mentel, T., Wildt, J., Junninen, H., Jokinen, T., Kulmala, M., Worsnop, D., Thornton, J., Donahue, N., Kjaergaard, H., and Ehn, M. Highly oxygenated organic molecules (HOM) from gas-phase autoxidation involving peroxy radicals: A key contributor to atmospheric aerosol, Chem. Rev., 119, 3472–509, https://doi.org/10.1021/acs.chemrev.8b00395, 2019.
Bianchi, F., Sinclair, V. A., Aliaga, D., Zha, Q., Scholz, W., Wu, C., Heikkinen, L., Modini, R., Partoll, E., Velarde, F., Moreno, I., Gramlich, Y., Huang, W., Leiminger, M., Enroth, J., Peräkylä, O., Marinoni, A., Xuemeng, C., Blacutt, L., Forno, R., Gutierrez, R., Ginot, P., Uzu, G., Facchini, M. C., Gilardoni, S., GyselBeer, M., Cai, R., Petäjä, T., Rinaldi, M., Saathoff, H., Sellegri, K., Worsnop, D., Artaxo, P., Hansel, A., Kulmala, M., Wiedensohler, A., Laj, P., Krejci, R., Carbone, S., Andrade, M., and Mohr, C.: The SALTENA Experiment: Comprehensive Observations of Aerosol Sources, Formation, and Processes in the South American Andes, B. Am. Meteorol. Soc., 103, E212–E229, https://doi.org/10.1175/BAMS-D-20-0187.1, 2022.
Boyd, C. M., Sanchez, J., Xu, L., Eugene, A. J., Nah, T., Tuet, W. Y., Guzman, M. I., and Ng, N. L.: Secondary organic aerosol formation from the β-pinene + NO3 system: effect of humidity and peroxy radical fate, Atmos. Chem. Phys., 15, 7497–7522, https://doi.org/10.5194/acp-15-7497-2015, 2015.
Brege, M., Paglione, M., Gilardoni, S., Decesari, S., Facchini, M. C., and Mazzoleni, L. R.: Molecular insights on aging and aqueous-phase processing from ambient biomass burning emissions-influenced Po Valley fog and aerosol, Atmos. Chem. Phys., 18, 13197–13214, https://doi.org/10.5194/acp-18-13197-2018, 2018.
Cai, J., Wu, C., Wang, J., Du, W., Zheng, F., Hakala, S., Fan, X., Chu, B., Yao, L., Feng, Z., Liu, Y., Sun, Y., Zheng, J., Yan, C., Bianchi, F., Kulmala, M., Mohr, C., and Daellenbach, K. R.: Influence of organic aerosol molecular composition on particle absorptive properties in autumn Beijing, Atmos. Chem. Phys., 22, 1251–1269, https://doi.org/10.5194/acp-22-1251-2022, 2022.
Cai, J., Daellenbach, K. R., Wu, C., Zheng, Y., Zheng, F., Du, W., Haslett, S. L., Chen, Q., Kulmala, M., and Mohr, C.: Characterization of offline analysis of particulate matter with FIGAERO-CIMS, Atmos. Meas. Tech., 16, 1147–1165, https://doi.org/10.5194/amt-16-1147-2023, 2023.
Chan, M. N., Surratt, J. D., Chan, A. W. H., Schilling, K., Offenberg, J. H., Lewandowski, M., Edney, E. O., Kleindienst, T. E., Jaoui, M., Edgerton, E. S., Tanner, R. L., Shaw, S. L., Zheng, M., Knipping, E. M., and Seinfeld, J. H.: Influence of aerosol acidity on the chemical composition of secondary organic aerosol from β-caryophyllene, Atmos. Chem. Phys., 11, 1735–1751, https://doi.org/10.5194/acp-11-1735-2011, 2011.
Chazeau, B., Temime-Roussel, B., Gille, G., Mesbah, B., D'Anna, B., Wortham, H., and Marchand, N.: Measurement report: Fourteen months of real-time characterisation of the submicronic aerosol and its atmospheric dynamics at the Marseille–Longchamp supersite, Atmos. Chem. Phys., 21, 7293–7319, https://doi.org/10.5194/acp-21-7293-2021, 2021.
Chen, G., Xu, L., Yu, S., Xue, L., Lin, Z., Yang, C., Ji, X., Fan, X., Tham, Y., Wang, H., Hong, Y., Li, M., Seinfeld, J., and Chen, J.: Increasing Contribution of Chlorine Chemistry to Wintertime Ozone Formation Promoted by Enhanced Nitrogen Chemistry, Environ. Sci. Technol., 58, 22714–22721, https://doi.org/10.1021/acs.est.4c09523, 2024.
Chen, Y.: Dataset for Molecular characterization of organic aerosol.xlsx, figshare [data set], https://doi.org/10.6084/m9.figshare.28956629.v1, 2025.
Chen, Y., Takeuchi, M., Nah, T., Xu, L., Canagaratna, M. R., Stark, H., Baumann, K., Canonaco, F., Prévôt, A. S. H., Huey, L. G., Weber, R. J., and Ng, N. L.: Chemical characterization of secondary organic aerosol at a rural site in the southeastern US: insights from simultaneous high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and FIGAERO chemical ionization mass spectrometer (CIMS) measurements, Atmos. Chem. Phys., 20, 8421–8440, https://doi.org/10.5194/acp-20-8421-2020, 2020.
Chen, Y., Yang, C., Xu, L., Chen, J., Zhang, Y., Shi, J., Fan, X., Zheng, R., Hong, Y., and Li, M.: Chemical composition of NR-PM1 in a coastal city of Southeast China: Temporal variations and formation pathways, Atmos. Environ., 285, https://doi.org/10.1016/j.atmosenv.2022.119243, 2022.
Chow, C., Watson, J., Lu, Z., Lowenthal, D., Frazier, C., Solomon, P., Thuillier, R., and Magliano, K.: Descriptive analysis of PM2.5 and PM10 at regionally representative locations during SJVAQS/AUSPEX, Atmos. Environ., 30, 2079–2112, https://doi.org/10.1016/1352-2310(95)00402-5, 1996.
Coward, E., Ohno, T., and Sparks, D.: Direct evidence for temporal molecular fractionation of dissolved organic matter at the iron oxyhydroxide interface, Environ. Sci. Technol., 53, 642–650, https://doi.org/10.1021/acs.est.8b04687, 2019.
Cui, M., Li, C., Chen, Y., Zhang, F., Li, J., Jiang, B., Mo, Y., Li, J., Yan, C., Zheng, M., Xie, Z., Zhang, G., and Zheng, J.: Molecular characterization of polar organic aerosol constituents in off-road engine emissions using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS): implications for source apportionment, Atmos. Chem. Phys., 19, 13945–13956, https://doi.org/10.5194/acp-19-13945-2019, 2019.
Cui, M., Han, Y., Yan, C., Zhang, F., Li, J., and Chen, Y.: Characteristics of polar organic compounds from diesel truck emissions measured by FT-ICR MS, Atmos. Environ., 319, 120319, https://doi.org/10.1016/j.atmosenv.2023.120319, 2024.
Daellenbach, K., Cai, j., Hakala, S., Dada, L., Yan, C., Du, W., Yao, L., Zheng, F., Ma, J., Ungeheuer, F., Vogel, A., Stolzenburg, D., Hao, Y., Liu, Y., Bianchi, F., Uzu, G., Jaffrezo, J., Worsnop, D., Donahue N., and Kulmala, M.: Substantial contribution of transported emissions to organic aerosol in Beijing, Nat. Geosci., 17, 747–754, https://doi.org/10.1038/s41561-024-01493-3, 2024.
Du, M., Voliotis, A., Shao, Y., Wang, Y., Bannan, T. J., Pereira, K. L., Hamilton, J. F., Percival, C. J., Alfarra, M. R., and McFiggans, G.: Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies, Atmos. Meas. Tech., 15, 4385–4406, https://doi.org/10.5194/amt-15-4385-2022, 2022.
Du, Y., Che, H., Bao, Z., Liu, Y., Li, Q., Hu, M., Zhou, J., Zhang, S., Yao, X., Shi, Q., Chen, C., Han, Y., Meng, L., Long, X., Qi, X., He, C., and Chen, Y.: Characterization of Organosulfates (OSs) in typical urban areas in Eastern China: Source, Process, and Volatility, Atmos. Res., 301, 107258, https://doi.org/10.1016/j.atmosres.2024.107258, 2024.
Ervens, B., Turpin, B. J., and Weber, R. J.: Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies, Atmos. Chem. Phys., 11, 11069–11102, https://doi.org/10.5194/acp-11-11069-2011, 2011.
Faxon, C., Hammes, J., Le Breton, M., Pathak, R. K., and Hallquist, M.: Characterization of organic nitrate constituents of secondary organic aerosol (SOA) from nitrate-radical-initiated oxidation of limonene using high-resolution chemical ionization mass spectrometry, Atmos. Chem. Phys., 18, 5467–5481, https://doi.org/10.5194/acp-18-5467-2018, 2018.
Frka, S., Sala, M., Kroflic, A., Hus, M., Cusak, A., and Grgic, I.: Quantum chemical calculations resolved identification of methylnitrocatechols in atmospheric aerosols, Environ. Sci. Technol., 50, 5526–5535, https://doi.org/10.1021/acs.est.6b00823, 2016.
Haslett, S. L., Bell, D. M., Kumar, V., Slowik, J. G., Wang, D. S., Mishra, S., Rastogi, N., Singh, A., Ganguly, D., Thornton, J., Zheng, F., Li, Y., Nie, W., Liu, Y., Ma, W., Yan, C., Kulmala, M., Daellenbach, K. R., Hadden, D., Baltensperger, U., Prevot, A. S. H., Tripathi, S. N., and Mohr, C.: Nighttime NO emissions strongly suppress chlorine and nitrate radical formation during the winter in Delhi, Atmos. Chem. Phys., 23, 9023–9036, https://doi.org/10.5194/acp-23-9023-2023, 2023.
Hong, Y., Xu, X., Liao, D., Liu, T., Ji, X., Xu, K., Liao, C., Wang, T., Lin, C., and Chen, J.: Measurement report: Effects of anthropogenic emissions and environmental factors on the formation of biogenic secondary organic aerosol (BSOA) in a coastal city of southeastern China, Atmos. Chem. Phys., 22, 7827–7841, https://doi.org/10.5194/acp-22-7827-2022, 2022.
Hong, Z., Zhang, H., Zhang, Y., Xu, L., Liu, T., Xiao, H., Hong, Y., Chen, J., Li, M., Deng, J., Wu, X., Hu, B., and Chen, X.: Secondary organic aerosol of PM2.5 in a mountainous forest area in southeastern China: Molecular compositions and tracers implication, Sci. Total Environ., 653, 496–503, https://doi.org/10.1016/j.scitotenv.2018.10.370, 2019.
Huang, R. J., Zhang, Y., Bozzetti, C., Ho, K. F., Cao, J. J., Han, Y., Daellenbach, K. R., Slowik, J. G., Platt, S. M., Canonaco, F., Zotter, P., Wolf, R., Pieber, S. M., Bruns, E. A., Crippa, M., Ciarelli, G., Piazzalunga, A., Schwikowski, M., Abbaszade, G., Schnelle-Kreis, J., Zimmermann, R., An, Z., Szidat, S., Baltensperger, U., El Haddad, I., and Prevot, A. S.: High secondary aerosol contribution to particulate pollution during haze events in China, Nature, 514, 218–222, https://doi.org/10.1038/nature13774, 2014.
Huang, W., Saathoff, H., Shen, X., Ramisetty, R., Leisner, T., and Mohr, C.: Seasonal characteristics of organic aerosol chemical composition and volatility in Stuttgart, Germany, Atmos. Chem. Phys., 19, 11687–11700, https://doi.org/10.5194/acp-19-11687-2019, 2019.
Huang, W., Wu, C., Gao, L., Gramlich, Y., Haslett, S. L., Thornton, J., Lopez-Hilfiker, F. D., Lee, B. H., Song, J., Saathoff, H., Shen, X., Ramisetty, R., Tripathi, S. N., Ganguly, D., Jiang, F., Vallon, M., Schobesberger, S., Yli-Juuti, T., and Mohr, C.: Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments, Atmos. Chem. Phys., 24, 2607–2624, https://doi.org/10.5194/acp-24-2607-2024, 2024.
Junninen, H., Ehn, M., Petäjä, T., Luosujärvi, L., Kotiaho, T., Kostiainen, R., Rohner, U., Gonin, M., Fuhrer, K., Kulmala, M., and Worsnop, D. R.: A high-resolution mass spectrometer to measure atmospheric ion composition, Atmos. Meas. Tech., 3, 1039–1053, https://doi.org/10.5194/amt-3-1039-2010, 2010.
Kawamura, K. and Bikkina, S.: A review of dicarboxylic acids and related compounds in atmospheric aerosols: Molecular distributions, sources and transformation, Atmos. Res., 170, 140–160, https://doi.org/10.1016/j.atmosres.2015.11.018, 2016.
Koch, B. and Dittmar, T.: From Mass to Structure: An Aromaticity Index for High-Resolution Mass Data of Natural Organic Matter, Rapid Commun. Mass Spectrom., 20, 926–932, https://doi.org/10.1002/rcm.2386, 2006.
Koch, B. and Dittmar, T.: From Mass to Structure: An Aromaticity Index for High-Resolution Mass Data of Natural Organic Matter. Rapid Commun. Mass Spectrom., 30, 250, https://doi.org/10.1002/rcm.7433, 2016.
Kroll, J., Donahue, N., Jimenez, J., Kessler, S., Canagaratna, M., Wilson, K., Altieri, K., Mazzoleni, L., Wozniak, A., Bluhm, H., Mysak, E., Smith, J., Kolb C., and Worsnop, D.: Carbon Oxidation State as a Metric for Describing the Chemistry of Atmospheric Organic Aerosol, Nat. Chem., 3, 133–139, https://doi.org/10.1038/nchem.948, 2011.
Lee, B. H., Lopez-Hilfiker, F., Mohr, C., Kurten, T., Worsnop, D., and Thornton. J.: An iodide-adduct high-resolution time-of-flight chemical-ionization mass spectrometer: Application to atmospheric inorganic and organic compounds, Environ. Sci. Technol., 48, 6309–6317, https://doi.org/10.1021/es500362a, 2014.
Lee, B. H., Mohr, C., Lopez-Hilfiker, F. D., Lutz, A., Hallquist, M., Lee, L., Romer, P., Cohen, R. C., Iyer, S., Kurtén, T., Hu, W., Day, D. A., Campuzano-Jost, P., Jimenez, J. L., Xu, L., Ng, N. L., Guo, H., Weber, R. J., Wild, R. J., Brown, S. S., Koss, A., Gouw, J. de, Olson, K., Goldstein, A. H., Seco, R., Kim, S., McAvey, K., Shepson, P. B., Starn, T., Baumann, K., Edgerton, E. S., Liu, J., Shilling, J. E., Miller, D. O., Brune, W., Schobesberger, S., D'Ambro, E. L., and Thornton, J. A.: Highly functionalized organic nitrates in the southeast United States: Contribution to secondary organic aerosol and reactive nitrogen budgets, P. Natl. Acad. Sci. USA, 113, 1516–1521, https://doi.org/10.1073/PNAS.1508108113, 2016.
Lim, Y. B., Tan, Y., Perri, M. J., Seitzinger, S. P., and Turpin, B. J.: Aqueous chemistry and its role in secondary organic aerosol (SOA) formation, Atmos. Chem. Phys., 10, 10521–10539, https://doi.org/10.5194/acp-10-10521-2010, 2010.
Lin, P., Rincon, A., Kalberer, M., and Yu, J.: Elemental composition of HULIS in the Pearl River Delta Region, China: Results inferred from positive and negative electrospray high resolution mass spectrometric data, Environ. Sci. Technol., 46, 7454–7462, https://doi.org/10.1021/es300285d, 2012.
Lopez-Hilfiker, F. D., Mohr, C., Ehn, M., Rubach, F., Kleist, E., Wildt, J., Mentel, Th. F., Lutz, A., Hallquist, M., Worsnop, D., and Thornton, J. A.: A novel method for online analysis of gas and particle composition: description and evaluation of a Filter Inlet for Gases and AEROsols (FIGAERO), Atmos. Meas. Tech., 7, 983–1001, https://doi.org/10.5194/amt-7-983-2014, 2014.
Lopez-Hilfiker, F. D., Mohr, C., D'Ambro, E. L., Lutz, A., Riedel, T. P., Gaston, C. J., Iyer, S., Zhang, Z., Gold, A., Surratt, J. D., Lee, B. H., Kurten, T., Hu, W. W., Jimenez, J., Hallquist, M., and Thornton, J. A.: Molecular composition and volatility of organic aerosol in the Southeastern U.S.: Implications for IEPOX derived SOA, Environ. Sci. Technol., 50, 2200–2209, https://doi.org/10.1021/acs.est.5b04769, 2016.
Lopez-Hilfiker, F. D., Pospisilova, V., Huang, W., Kalberer, M., Mohr, C., Stefenelli, G., Thornton, J. A., Baltensperger, U., Prevot, A. S. H., and Slowik, J. G.: An extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF) for online measurement of atmospheric aerosol particles, Atmos. Meas. Tech., 12, 4867–4886, https://doi.org/10.5194/amt-12-4867-2019, 2019.
Lu, C. Y., Wang, X. F., Dong, S. W., Zhang, J., Li, J., Zhao, Y. N., Liang, Y. H., Xue, L. K., Xie, H. J., Zhang, Q. Z., and Wang, W. X.: Emissions of fine particulate nitrated phenols from various on-road vehicles in China, Environ. Res., 179, 108709, https://doi.org/10.1016/j.envres.2019.108709, 2019a.
Lu, C. Y., Wang, X. F., Li, R., Gu, R. R., Zhang, Y. X., Li, W. J., Gao, R., Chen, B., Xue, L. K., and Wang, W. X.: Emissions of fine particulate nitrated phenols from residential coal combustion in China, Atmos. Environ., 203, 10–17, https://doi.org/10.1016/j.atmosenv.2019.01.047, 2019b.
Lu, C., Wang, X., Zhang, J., Liu, Z., Liang, Y., Dong, S., Li, M., Chen, J., Chen, H., Xie, H., Xue, L., and Wang, W.: Substantial emissions of nitrated aromatic compounds in the particle and gas phases in the waste gases from eight industries, Environ. Pollut., 283, 117132, https://doi.org/10.1016/j.envpol.2021.117132, 2021.
Nah, T., Sanchez, J., Boyd, C. M., and Ng, N. L.: Photochemical Aging of α-pinene and β-pinene Secondary Organic Aerosol formed from Nitrate Radical Oxidation. Environ. Sci. Technol., 50, 222–231, https://doi.org/10.1021/acs.est.5b04594, 2016.
Ng, N. L., Brown, S. S., Archibald, A. T., Atlas, E., Cohen, R. C., Crowley, J. N., Day, D. A., Donahue, N. M., Fry, J. L., Fuchs, H., Griffin, R. J., Guzman, M. I., Herrmann, H., Hodzic, A., Iinuma, Y., Jimenez, J. L., Kiendler-Scharr, A., Lee, B. H., Luecken, D. J., Mao, J., McLaren, R., Mutzel, A., Osthoff, H. D., Ouyang, B., Picquet-Varrault, B., Platt, U., Pye, H. O. T., Rudich, Y., Schwantes, R. H., Shiraiwa, M., Stutz, J., Thornton, J. A., Tilgner, A., Williams, B. J., and Zaveri, R. A.: Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol, Atmos. Chem. Phys., 17, 2103–2162, https://doi.org/10.5194/acp-17-2103-2017, 2017.
Nguyen, T., Lee, P., Updyke, K., Bones, D., Laskin, J., Laskin, A., and Nizkorodov, S.: Formation of nitrogen- and sulfur-containing light-absorbing compounds accelerated by evaporation of water from secondary organic aerosols, J. Geophys. Res.-Atmos., 117, https://doi.org/10.1029/2011JD016944, 2012.
Noziere, B., Ekstrom, S., Alsberg, T., and Holmstrom, S.: Radical-initiated formation of organosulfates and surfactants in atmospheric aerosols, Geophys. Res. Lett., 37, https://doi.org/10.1029/2009GL041683, 2010.
Peng, Y., Yuan, B., Yang, S., Wang, S., Yang, X., Wang, W., Li, J., Song, X., Wu, C., Qi, J., Zheng, E., Ye, C., Huang, S., Hu, W., Song, W., Wang, X., Wang, B., and Shao, M.: Photolysis frequency of nitrophenols derived from ambient measurements, Sci. Total Environ., 869, 161810, https://doi.org/10.1016/j.scitotenv.2023.161810, 2023.
Putman, A., Offenberg, J., Fisseha, R., Kundu, S., Rahn, T., and Mazzoleni, L.: Ultrahigh-resolution FT-ICR mass spectrometry characterization of α-pinene ozonolysis SOA, Atmos. Environ., 46, 164–172, https://doi.org/10.1016/j.atmosenv.2011.10.003, 2012.
Qi, J., Zheng, B., Li, M., Yu, F., Chen, C., Liu, F., Zhou, X., Yuan, J., Zhang, Q., and He, K.: A high-resolution air pollutants emission inventory in 2013 for the Beijing-Tianjin-Hebei region, China, Atmos. Environ., 170, 156–168, https://doi.org/10.1016/j.atmosenv.2017.09.039, 2017.
Redman, A., Macalady, D., and Ahmann, D.: Natural organic matter affects arsenic speciation and sorption onto hematite, Environ. Sci. Technol., 36, 2889–2896, https://doi.org/10.1021/es0112801, 2002.
Shang, Y., Li, L., Sun, T., Kong, X., Wang, S., and Hallquist M.: Characterization and Seasonal Variation of PM2.5 Composition in Xi'an, Northwest China: Oxygenated and Nitrogenous Organic Aerosol, ACS Earth Space Chem., 8, 1370–1384, https://doi.org/10.1021/acsearthspacechem.4c00042, 2024.
Shen, J., Scholz, W., He, X.-C., Zhou, P., Marie, G., Wang, M., Marten, R., Surdu, M., Rörup, B., Baalbaki, R., Amorim, A., Ataei, F., Bell, D. M., Bertozzi, B., Brasseur, Z., Caudillo, L., Chen, D., Chu, B., Dada, L., Duplissy, J., Finkenzeller, H., Granzin, M., Guida, R., Heinritzi, M., Hofbauer, V., Iyer, S., Kemppainen, D., Kong, W., Krechmer, J. E., Kürten, A., Lamkaddam, H., Lee, C. P., Lopez, B., Mahfouz, N. G. A., Manninen, H. E., Massabò, D., Mauldin, R. L., Mentler, B., Müller, T., Pfeifer, J., Philippov, M., Piedehierro, A. A., Roldin, P., Schobesberger, S., Simon, M., Stolzenburg, D., Tham, Y. J., Tomé, A., Umo, N. S., Wang, D., Wang, Y., Weber, S. K., Welti, A., Wollesen de Jonge, R., Wu, Y., Zauner-Wieczorek, M., Zust, F., Baltensperger, U., Curtius, J., Flagan, R. C., Hansel, A., Möhler, O., Petäjä, T., Volkamer, R., Kulmala, M., Lehtipalo, K., Rissanen, M., Kirkby, J., El-Haddad, I., Bianchi, F., Sipilä, M., Donahue, N. M., and Worsnop, D. R.: High Gas-Phase Methanesulfonic Acid Production in the OH-Initiated Oxidation of Dimethyl Sulfide at Low Temperatures, Environ. Sci. Technol., 56, 13931–13944, https://doi.org/10.1021/acs.est.2c05154, 2022.
Siegel, K., Karlsson, L., Zieger, P., Baccarini, A., Schmale, J., Lawler, M., Salter, M., Leck, C., Ekman, A., Riipinen I., and Mohr, C.: Insights into the molecular composition of semivolatile aerosols in the summertime central Arctic Ocean using FIGAERO-CIMS, Environ. Sci.-Atmos., 1, 161, https://doi.org/10.1039/d0ea00023j, 2021.
Stark, H., Yatavelli, R. L. N., Thompson, S. L., Kang, H., Krechmer, J. E., Kimmel, J. R., Palm, B. B., Hu, W., Hayes, P. L., Day, D. A., Campuzano-Jost, P., Canagaratna, M. R., Jayne, J. T., Worsnop D. R., and Jimenez, J. L.: Impact of Thermal Decomposition on Thermal Desorption Instruments: Advantage of Thermogram Analysis for Quantifying Volatility Distributions of Organic Species, Environ. Sci. Technol., 51, 8491–8500, https://doi.org/10.1021/acs.est.7b00160, 2017.
Sun, Y., Xu, W., Zhang, Q., Jiang, Q., Canonaco, F., Prévôt, A. S. H., Fu, P., Li, J., Jayne, J., Worsnop, D. R., and Wang, Z.: Source apportionment of organic aerosol from 2-year highly time-resolved measurements by an aerosol chemical speciation monitor in Beijing, China, Atmos. Chem. Phys., 18, 8469–8489, https://doi.org/10.5194/acp-18-8469-2018, 2018.
Vidovic, K., Lasic Jurkovic, D., Sala, M., Kroflic, A., and Grgic, I.: Nighttime aqueous-phase formation of nitrocatechols in the atmospheric condensed phase, Environ. Sci. Technol., 52, 9722–9730, https://doi.org/10.1021/acs.est.8b01161, 2018.
Wan, Y., Huang, X., Jiang, B., Kuang, B., Lin, M., Xia, D., Liao, Y., Chen, J., Yu, J. Z., and Yu, H.: Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere, Atmos. Chem. Phys., 20, 9821–9835, https://doi.org/10.5194/acp-20-9821-2020, 2020.
Wang, Y., Hu, M., Wang, Y., Zheng, J., Shang, D., Yang, Y., Liu, Y., Li, X., Tang, R., Zhu, W., Du, Z., Wu, Y., Guo, S., Wu, Z., Lou, S., Hallquist, M., and Yu, J. Z.: The formation of nitro-aromatic compounds under high NOx and anthropogenic VOC conditions in urban Beijing, China, Atmos. Chem. Phys., 19, 7649–7665, https://doi.org/10.5194/acp-19-7649-2019, 2019.
Xia, M., Chen, X., Ma, W., Guo, Y., Yin, R., Zhan, J., Zhang, Y., Wang, Z., Zheng, F., Xie, J., Wang, Y., Hua, C., Liu, Y., Yan, C., and Kulmala, M.: Observations and Modeling of Gaseous Nitrated Phenols in Urban Beijing: Insights From Seasonal Comparison and Budget Analysis, J. Geophys. Res.-Atmos., 128, e2023JD039551, https://doi.org/10.1029/2023JD039551, 2023.
Xie, M., Chen, X., Hays, M. D., Lewandowski, M., Offenberg, J., Kleindienst, T. E., and Holder, A. L.: Light absorption of secondary organic aerosol: composition and contribution of nitroaromatic compounds, Environ. Sci. Technol., 51, 11607–11616, https://doi.org/10.1021/acs.est.7b03263, 2017.
Xie, Q., Li, Y., Yue, S., Su, S., Cao, D., Xu, Y., Chen, J., Tong, H., Su, H., Cheng, Y., Zhao, W., Hu, W., Wang, Z., Yang, T., Pan, X., Sun, Y., Wang, Z., Liu, C., Kawamura, K., Jiang, G., Shiraiwa, M., and Fu P.: Increase of high molecular weight organosulfate with intensifying urban air pollution in the Megacity Beijing, J. Geophys. Res.-Atmos., 125, e2019JD032200, https://doi.org/10.1029/2019JD032200, 2020.
Xin, X., Zhao, Y., Wan, Y., Zhang H., and Yu, H.: Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS, Aerosol Sci. and Tech., 58, 1142–1156, https://doi.org/10.1080/02786826.2024.2377394, 2024.
Xu, L., Guo, H., Weber R. J., and Ng, N. L.: Chemical Characterization of Water-Soluble Organic Aerosol in Contrasting Rural and Urban Environments in the Southeastern United States, Environ. Sci. Technol., 51, 78–88, https://doi.org/10.1021/acs.est.6b05002, 2017a.
Xu, W., Han, T., Du, W., Wang, Q., Chen, C., Zhao, J., Zhang, Y., Li, J., Fu, P., Wang, Z., Worsnop, D., and Sun, Y.: Effects of Aqueous-Phase and Photochemical Processing on Secondary Organic Aerosol Formation and Evolution in Beijing, China, Environ. Sci. Technol., 51, 762–770, https://doi.org/10.1021/acs.est.6b04498, 2017b.
Xu, W., Kuang, Y., Liang, L., He, Y., Cheng, H., Bian, Y., Tao, J., Zhang, G., Zhao, P., Ma, N., Zhao, H., Zhou, G., Su, H., Cheng, Y., Xu, X., Shao, M., and Sun, Y.: Dust-dominated coarse particles as a medium for rapid secondary organic and inorganic aerosol formation in highly polluted air, Environ. Sci. Technol., 54, 15710–15721, https://doi.org/10.1021/acs.est.0c07243, 2020.
Yan, C., Nie, W., Äijälä, M., Rissanen, M. P., Canagaratna, M. R., Massoli, P., Junninen, H., Jokinen, T., Sarnela, N., Häme, S. A. K., Schobesberger, S., Canonaco, F., Yao, L., Prévôt, A. S. H., Petäjä, T., Kulmala, M., Sipilä, M., Worsnop, D. R., and Ehn, M.: Source characterization of highly oxidized multifunctional compounds in a boreal forest environment using positive matrix factorization, Atmos. Chem. Phys., 16, 12715–12731, https://doi.org/10.5194/acp-16-12715-2016, 2016.
Yang, Y., Huang, L., Zhao, M., Wu, Y., Xu, Y., Li, Q., Wang, W., and Xue, L.: Multiphase reactions of organic peroxides and nitrite as a source of atmospheric organic nitrates, Nat. Commun., 16, 5437, https://doi.org/10.1038/s41467-025-60696-3, 2025.
Ye, C., Yuan, B., Lin, Y., Wang, Z., Hu, W., Li, T., Chen, W., Wu, C., Wang, C., Huang, S., Qi, J., Wang, B., Wang, C., Song, W., Wang, X., Zheng, E., Krechmer, J. E., Ye, P., Zhang, Z., Wang, X., Worsnop, D. R., and Shao, M.: Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air, Atmos. Chem. Phys., 21, 8455–8478, https://doi.org/10.5194/acp-21-8455-2021, 2021.
Ye, Z., Hu, D., Wang, Z., Wang, H., and Ge, X.: Aqueous photochemical aging of water-soluble smoke particles from crop straws burning, Atmos. Environ., 40, 120897, https://doi.org/10.1016/j.atmosenv.2024.120897, 2025.
Yu, L., Smith, J., Laskin, A., George, K. M., Anastasio, C., Laskin, J., Dillner, A. M., and Zhang, Q.: Molecular transformations of phenolic SOA during photochemical aging in the aqueous phase: competition among oligomerization, functionalization, and fragmentation, Atmos. Chem. Phys., 16, 4511–4527, https://doi.org/10.5194/acp-16-4511-2016, 2016.
Zhang, M., Cai, D., Lin, Z., Liu, Z., Li, M., Wang, Y., and Chen, J.: Molecular characterization of atmospheric organic aerosols in typical megacities in China, npj Clim. Atmos. Sci., 7, 230, https://doi.org/10.1038/s41612-024-00784-1, 2024.
Zhang, Y., Xu, L., Zhuang, M., Zhao, G., Chen, Y., Tong, L., Yang, C., Xiao, H., Chen, J., Wu, X., Hong, Y., Li, M., Bian, Y., and Chen, Y.: Chemical composition and sources of submicron aerosol in a coastal city of China: Results from the 2017 BRICS summit study, Sci. Total Environ., 741, 140470, https://doi.org/10.1016/j.scitotenv.2020.140470, 2020.
Zhao, R., Mungall, E. L., Lee, A. K. Y., Aljawhary, D., and Abbatt, J. P. D.: Aqueous-phase photooxidation of levoglucosan – a mechanistic study using aerosol time-of-flight chemical ionization mass spectrometry (Aerosol ToF-CIMS), Atmos. Chem. Phys., 14, 9695–9706, https://doi.org/10.5194/acp-14-9695-2014, 2014.
Zheng, Y., Chen, Q., Cheng, X., Mohr, C., Cai, J., Huang, W., Shrivastava, M., Ye, P., Fu, P., Shi, X., Ge, Y., Liao, K., Miao, R., Qiu, X., Koenig, T., and Chen S.: Precursors and Pathways Leading to Enhanced Secondary Organic Aerosol Formation during Severe Haze Episodes, Environ. Sci. Technol., 55, 15680–15693, https://doi.org/10.1021/acs.est.1c04255, 2021.
Zhou, W., Xu, W., Kim, H., Zhang, Q., Fu, P., Worsnop, D. R., and Sun, Y.: A review of aerosol chemistry in Asia: insights from aerosol mass spectrometer measurements, Environ. Sci. Process Impacts, 22, 1616–1653, https://doi.org/10.1039/d0em00212g, 2020.
Short summary
This study investigates the molecular characteristics and chemical evolution of organic aerosol (OA) in contrasting urban and seaside environments by offline Chemical Ionization Mass Spectrometry. Urban OA was enriched in aromatic species, while seaside OA featured aliphatic and highly oxidized compounds. Marine-derived humid air masses promoted aqueous/heterogeneous phase OA formation, leading to a higher oxidation state.
This study investigates the molecular characteristics and chemical evolution of organic aerosol...
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