Articles | Volume 23, issue 24
https://doi.org/10.5194/acp-23-15643-2023
https://doi.org/10.5194/acp-23-15643-2023
Research article
 | 
20 Dec 2023
Research article |  | 20 Dec 2023

Characterization of water-soluble brown carbon chromophores from wildfire plumes in the western USA using size-exclusion chromatography

Lisa Azzarello, Rebecca A. Washenfelder, Michael A. Robinson, Alessandro Franchin, Caroline C. Womack, Christopher D. Holmes, Steven S. Brown, Ann Middlebrook, Tim Newberger, Colm Sweeney, and Cora J. Young

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Cited articles

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We present a molecular size-resolved offline analysis of water-soluble brown carbon collected on an aircraft during FIREX-AQ. The smoke plumes were aged 0 to 5 h, where absorption was dominated by small molecular weight molecules, brown carbon absorption downwind did not consistently decrease, and the measurements differed from online absorption measurements of the same samples. We show how differences between online and offline absorption could be related to different measurement conditions.
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