Articles | Volume 22, issue 4
https://doi.org/10.5194/acp-22-2817-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-2817-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
02 Mar 2022
Research article |
| 02 Mar 2022
| 02 Mar 2022
Volatile organic compound fluxes over a winter wheat field by PTR-Qi-TOF-MS and eddy covariance
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Pauline Buysse
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Lais Gonzaga-Gomez
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Florence Lafouge
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Raluca Ciuraru
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Céline Decuq
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Julien Kammer
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
now at: Aix Marseille Univ., CNRS, LCE, Marseille, France
Sandy Bsaibes
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Laboratoire des Sciences du Climat et de l'Environnement, LSCE, UMR
CNRS-CEA-UVSQ, IPSL, 91191 Gif-sur-Yvette, Île-de-France, France
Christophe Boissard
Laboratoire des Sciences du Climat et de l'Environnement, LSCE, UMR
CNRS-CEA-UVSQ, IPSL, 91191 Gif-sur-Yvette, Île-de-France, France
Université de Paris and Univ. Paris Est Creteil, CNRS, LISA, 75013 Paris, France
Brigitte Durand
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Jean-Christophe Gueudet
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Olivier Fanucci
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Olivier Zurfluh
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
Letizia Abis
UMR ECOSYS, INRAE, AgroParisTech, Université Paris-Saclay, 78850, Thiverval-Grignon, France
now at: Umweltchemie und Luftreinhaltung, Technische Universität Berlin, Straße des 17. Juni 135, Berlin, 10623, Germany
Nora Zannoni
Laboratoire des Sciences du Climat et de l'Environnement, LSCE, UMR
CNRS-CEA-UVSQ, IPSL, 91191 Gif-sur-Yvette, Île-de-France, France
now at: Max-Planck Institute for Chemistry, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
François Truong
Laboratoire des Sciences du Climat et de l'Environnement, LSCE, UMR
CNRS-CEA-UVSQ, IPSL, 91191 Gif-sur-Yvette, Île-de-France, France
Dominique Baisnée
Laboratoire des Sciences du Climat et de l'Environnement, LSCE, UMR
CNRS-CEA-UVSQ, IPSL, 91191 Gif-sur-Yvette, Île-de-France, France
Roland Sarda-Estève
Laboratoire des Sciences du Climat et de l'Environnement, LSCE, UMR
CNRS-CEA-UVSQ, IPSL, 91191 Gif-sur-Yvette, Île-de-France, France
Michael Staudt
CEFE, CNRS, EPHE, IRD, Univ Montpellier, Montpellier, France
Valérie Gros
Laboratoire des Sciences du Climat et de l'Environnement, LSCE, UMR
CNRS-CEA-UVSQ, IPSL, 91191 Gif-sur-Yvette, Île-de-France, France
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Preprint archived
Short summary
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Victor Moinard, Antoine Savoie, Catherine Pasquier, Adeline Besnault, Yolaine Goubard-Delaunay, Baptiste Esnault, Marco Carozzi, Polina Voylokov, Sophie Génermont, Benjamin Loubet, Catherine Hénault, Florent Levavasseur, Jean-Marie Paillat, and Sabine Houot
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Preprint archived
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Pauline Buysse, Benjamin Loubet, Raluca Ciuraru, Florence Lafouge, Brigitte Durand, Olivier Zurfluh, Céline Décuq, Olivier Fanucci, Lais Gonzaga Gomez, Jean-Christophe Gueudet, Sandy Bsaibes, Nora Zannoni, and Valérie Gros
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Preprint withdrawn
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Short summary
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Our study presents, for the first time, a detailed source identification of aerosols at an urban background site in Cyprus (eastern Mediterranean), a region strongly impacted by climate change and air pollution. Here, we identify an unexpected high contribution of long-range transported pollution from fossil fuel sources in the Middle East, highlighting an urgent need to further characterize these fast-growing emissions and their impacts on regional atmospheric composition, climate, and health.
Leïla Simon, Valérie Gros, Jean-Eudes Petit, François Truong, Roland Sarda-Estève, Carmen Kalalian, Alexia Baudic, Caroline Marchand, and Olivier Favez
Earth Syst. Sci. Data, 15, 1947–1968, https://doi.org/10.5194/essd-15-1947-2023, https://doi.org/10.5194/essd-15-1947-2023, 2023
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Long-term measurements of volatile organic compounds (VOCs) have been set up to better characterize the atmospheric chemistry at the SIRTA national facility (Paris area, France). Results obtained from the first 2 years (2020–2021) confirm the importance of local sources for short-lived compounds and the role played by meteorology and air mass origins in the long-term analysis of VOCs. They also point to a substantial influence of anthropogenic on the monoterpene loadings.
Valérie Gros, Bernard Bonsang, Roland Sarda-Estève, Anna Nikolopoulos, Katja Metfies, Matthias Wietz, and Ilka Peeken
Biogeosciences, 20, 851–867, https://doi.org/10.5194/bg-20-851-2023, https://doi.org/10.5194/bg-20-851-2023, 2023
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The oceans are both sources and sinks for trace gases important for atmospheric chemistry and marine ecology. Here, we quantified selected trace gases (including the biological metabolites dissolved dimethyl sulfide, methanethiol and isoprene) along a 2500 km transect from the North Atlantic to the Arctic Ocean. In the context of phytoplankton and bacterial communities, our study suggests that methanethiol (rarely measured before) might substantially influence ocean–atmosphere cycling.
Denis Leppla, Nora Zannoni, Leslie Kremper, Jonathan Williams, Christopher Pöhlker, Marta Sá, Maria Christina Solci, and Thorsten Hoffmann
Atmos. Chem. Phys., 23, 809–820, https://doi.org/10.5194/acp-23-809-2023, https://doi.org/10.5194/acp-23-809-2023, 2023
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Chiral chemodiversity plays a critical role in biochemical processes such as insect and plant communication. Here we report on the measurement of chiral-specified secondary organic aerosol in the Amazon rainforest. The results show that the chiral ratio is mainly determined by large-scale emission processes. Characteristic emissions of chiral aerosol precursors from different forest ecosystems can thus provide large-scale information on different biogenic sources via chiral particle analysis.
Michael Staudt, Juliane Daussy, Joseph Ingabire, and Nafissa Dehimeche
Biogeosciences, 19, 4945–4963, https://doi.org/10.5194/bg-19-4945-2022, https://doi.org/10.5194/bg-19-4945-2022, 2022
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We studied the short- and long-term effects of CO2 as a function of temperature on monoterpene emissions from holm oak. Similarly to isoprene, emissions decreased non-linearly with increasing CO2, with no differences among compounds and chemotypes. The CO2 response was modulated by actual leaf and growth temperature but not by growth CO2. Estimates of annual monoterpene release under double CO2 suggest that CO2 inhibition does not offset the increase in emissions due to expected warming.
Jean-Eudes Petit, Jean-Charles Dupont, Olivier Favez, Valérie Gros, Yunjiang Zhang, Jean Sciare, Leila Simon, François Truong, Nicolas Bonnaire, Tanguy Amodeo, Robert Vautard, and Martial Haeffelin
Atmos. Chem. Phys., 21, 17167–17183, https://doi.org/10.5194/acp-21-17167-2021, https://doi.org/10.5194/acp-21-17167-2021, 2021
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The COVID-19 outbreak led to lockdowns at national scales in spring 2020. Large cuts in emissions occurred, but the quantitative assessment of their role from observations is hindered by weather and interannual variability. That is why we developed an innovative methodology in order to best characterize the impact of lockdown on atmospheric chemistry. We find that a local decrease in traffic-related pollutants triggered a decrease of secondary aerosols and an increase in ozone.
Alexandre Kukui, Michel Chartier, Jinhe Wang, Hui Chen, Sébastien Dusanter, Stéphane Sauvage, Vincent Michoud, Nadine Locoge, Valérie Gros, Thierry Bourrianne, Karine Sellegri, and Jean-Marc Pichon
Atmos. Chem. Phys., 21, 13333–13351, https://doi.org/10.5194/acp-21-13333-2021, https://doi.org/10.5194/acp-21-13333-2021, 2021
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Sulfuric acid, H2SO4, plays a key role in formation of secondary atmospheric aerosol particles. It is generally accepted that the major atmospheric source of H2SO4 is the reaction of OH radicals with SO2. In this study, importance of an additional H2SO4 source via oxidation of SO2 by stabilized Criegee intermediates was estimated based on measurements at a remote site on Cape Corsica. It was found that the oxidation of SO2 by SCI may be an important source of H2SO4, especially during nighttime.
Letizia Abis, Carmen Kalalian, Bastien Lunardelli, Tao Wang, Liwu Zhang, Jianmin Chen, Sébastien Perrier, Benjamin Loubet, Raluca Ciuraru, and Christian George
Atmos. Chem. Phys., 21, 12613–12629, https://doi.org/10.5194/acp-21-12613-2021, https://doi.org/10.5194/acp-21-12613-2021, 2021
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Biogenic volatile organic compound (BVOC) emissions from rapeseed leaf litter have been investigated by means of a controlled atmospheric simulation chamber. The diversity of emitted VOCs increased also in the presence of UV light irradiation. SOA formation was observed when leaf litter was exposed to both UV light and ozone, indicating a potential contribution to particle formation or growth at local scales.
Sara M. Defratyka, Jean-Daniel Paris, Camille Yver-Kwok, Daniel Loeb, James France, Jon Helmore, Nigel Yarrow, Valérie Gros, and Philippe Bousquet
Atmos. Meas. Tech., 14, 5049–5069, https://doi.org/10.5194/amt-14-5049-2021, https://doi.org/10.5194/amt-14-5049-2021, 2021
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We consider the possibility of using the CRDS Picarro G2201-i instrument, originally designed for isotopic CH4 and CO2, for measurements of ethane : methane in near-source conditions. The work involved laboratory tests, a controlled release experiment and mobile measurements. We show the potential of determining ethane : methane with 50 ppb ethane uncertainty. The instrument can correctly estimate the ratio in CH4 enhancements of 1 ppm and more, as can be found at strongly emitting sites.
Eva Y. Pfannerstill, Nina G. Reijrink, Achim Edtbauer, Akima Ringsdorf, Nora Zannoni, Alessandro Araújo, Florian Ditas, Bruna A. Holanda, Marta O. Sá, Anywhere Tsokankunku, David Walter, Stefan Wolff, Jošt V. Lavrič, Christopher Pöhlker, Matthias Sörgel, and Jonathan Williams
Atmos. Chem. Phys., 21, 6231–6256, https://doi.org/10.5194/acp-21-6231-2021, https://doi.org/10.5194/acp-21-6231-2021, 2021
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Tropical forests are globally significant for atmospheric chemistry. However, the mixture of reactive organic gases emitted by these ecosystems is poorly understood. By comprehensive observations at an Amazon forest site, we show that oxygenated species were previously underestimated in their contribution to the tropical-forest reactant mix. Our results show rain and temperature effects and have implications for models and the understanding of ozone and particle formation above tropical forests.
Cécile Debevec, Stéphane Sauvage, Valérie Gros, Thérèse Salameh, Jean Sciare, François Dulac, and Nadine Locoge
Atmos. Chem. Phys., 21, 1449–1484, https://doi.org/10.5194/acp-21-1449-2021, https://doi.org/10.5194/acp-21-1449-2021, 2021
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This study provides a better characterization of the seasonal variations in VOC sources impacting the western Mediterranean region, based on a comprehensive chemical composition measured over 25 months at a representative receptor site (Ersa) and by determining factors controlling their temporal variations. Some insights into dominant drivers for VOC concentration variations in Europe are also provided, built on comparisons of Ersa observations with the concomitant ones of 17 European sites.
Ashish Kumar, Vinayak Sinha, Muhammed Shabin, Haseeb Hakkim, Bernard Bonsang, and Valerie Gros
Atmos. Chem. Phys., 20, 12133–12152, https://doi.org/10.5194/acp-20-12133-2020, https://doi.org/10.5194/acp-20-12133-2020, 2020
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Source apportionment studies require information on the chemical fingerprints of pollution sources to correctly quantify source contributions to ambient composition. These chemical fingerprints vary from region to region, depending on fuel composition and combustion conditions, and are poorly constrained over developing regions such as South Asia. This work characterises the chemical fingerprints of urban and agricultural sources using 49 non-methane hydrocarbons and their environmental impacts.
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Short summary
Volatile organic compounds (VOCs) are precursors of tropospheric pollutants like ozone or aerosols. Emission by agricultural land was still poorly characterized. We report experimental measurements of ecosystem-scale VOC fluxes above a wheat field with a highly sensitive proton transfer mass spectrometer. We report the fluxes of 123 compounds and confirm that methanol is the most emitted VOC by wheat. The second most emitted compound was C6H4O. Around 75 % of the compounds were deposited.
Volatile organic compounds (VOCs) are precursors of tropospheric pollutants like ozone or...
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