Articles | Volume 22, issue 21
https://doi.org/10.5194/acp-22-14283-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-22-14283-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Dynamical linear modeling estimates of long-term ozone trends from homogenized Dobson Umkehr profiles at Arosa/Davos, Switzerland
Eliane Maillard Barras
CORRESPONDING AUTHOR
Federal Office of Meteorology and Climatology, MeteoSwiss (MCH), Payerne, Switzerland
Alexander Haefele
Federal Office of Meteorology and Climatology, MeteoSwiss (MCH), Payerne, Switzerland
René Stübi
Federal Office of Meteorology and Climatology, MeteoSwiss (MCH), Payerne, Switzerland
Achille Jouberton
now at: Swiss Federal Institute for Forest, Snow and Landscape Research (WSL), Birmensdorf, Switzerland
Herbert Schill
Physikalisch-Meteorologisches Observatorium Davos, World Radiation Center, Davos, Switzerland
Irina Petropavlovskikh
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
National Oceanic and Atmospheric Administration (NOAA), Global Monitoring Lab, Boulder, CO, USA
Koji Miyagawa
National Oceanic and Atmospheric Administration (NOAA), Global Monitoring Lab, Boulder, CO, USA
Martin Stanek
Solar and Ozone Observatory, Czech Hydrometeorological Institute, Hradec Králové, Czech Republic
Lucien Froidevaux
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA
Related authors
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 7187–7225, https://doi.org/10.5194/acp-25-7187-2025, https://doi.org/10.5194/acp-25-7187-2025, 2025
Short summary
Short summary
Tropospheric ozone is an important greenhouse gas and is an air pollutant. The time variability of tropospheric ozone is mainly driven by anthropogenic emissions. In this paper, we study the distribution and time variability of ozone from harmonized ground-based observations from five different measurement techniques. Our findings provide clear standard references for atmospheric models and evolving tropospheric ozone satellite data for the 2000–2022 period.
Irina Petropavlovskikh, Jeannette D. Wild, Kari Abromitis, Peter Effertz, Koji Miyagawa, Lawrence E. Flynn, Eliane Maillard Barras, Robert Damadeo, Glen McConville, Bryan Johnson, Patrick Cullis, Sophie Godin-Beekmann, Gerard Ancellet, Richard Querel, Roeland Van Malderen, and Daniel Zawada
Atmos. Chem. Phys., 25, 2895–2936, https://doi.org/10.5194/acp-25-2895-2025, https://doi.org/10.5194/acp-25-2895-2025, 2025
Short summary
Short summary
Observational records show that stratospheric ozone is recovering in accordance with the implementation of the Montreal Protocol and its amendments. Natural ozone variability complicates the detection of small trends. This study optimizes a statistical model fit in ground-station-based observational records by adding parameters that interpret seasonal and long-term changes in atmospheric circulation and airmass mixing, which reduces uncertainties in detecting the stratospheric ozone recovery.
Gaëlle Dufour, Maxim Eremenko, Juan Cuesta, Gérard Ancellet, Michael Gill, Eliane Maillard Barras, and Roeland Van Malderen
EGUsphere, https://doi.org/10.5194/egusphere-2024-4096, https://doi.org/10.5194/egusphere-2024-4096, 2025
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The IASI-O3 KOPRA v3.0 product shows strong consistency (<1 %) for the three IASI instruments. The validation against homogenized ozone sondes reveals an overall good agreement with slight biases (3–6 %) in tropospheric ozone and a possible temporal drift but difficult to assess due to the limited number of sites. No specific trends are estimated for the tropospheric ozone column for 2008–2022, but persistent negative trends are observed in the lower troposphere.
Roeland Van Malderen, Zhou Zang, Kai-Lan Chang, Robin Björklund, Owen R. Cooper, Jane Liu, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, Audrey Gaudel, David W. Tarasick, Herman G. J. Smit, Anne M. Thompson, Ryan M. Stauffer, Debra E. Kollonige, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Isamu Morino, Glen McConville, Katrin Müller, Isao Murata, Justus Notholt, Ankie Piters, Maxime Prignon, Richard Querel, Vincenzo Rizi, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3745, https://doi.org/10.5194/egusphere-2024-3745, 2025
Short summary
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Tropospheric ozone is an important greenhouse gas and an air pollutant, whose distribution and time variability is mainly governed by anthropogenic emissions and dynamics. In this paper, we assess regional trends of tropospheric ozone column amounts, based on two different approaches of merging or synthesizing ground-based observations and their trends within specific regions. Our findings clearly demonstrate regional trend differences, but also consistently higher pre- than post-COVID trends.
Eric Sauvageat, Klemens Hocke, Eliane Maillard Barras, Shengyi Hou, Quentin Errera, Alexander Haefele, and Axel Murk
Atmos. Chem. Phys., 23, 7321–7345, https://doi.org/10.5194/acp-23-7321-2023, https://doi.org/10.5194/acp-23-7321-2023, 2023
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In Switzerland, two microwave radiometers can measure continuous ozone profiles in the middle atmosphere. From these instruments, we can study the diurnal variation of ozone, which is difficult to observe otherwise. It is valuable to validate the model simulations of diurnal variations in this region. We present results obtained during the last decade and compare them against various models. For the first time, we also show that the winter diurnal variations have some short-term fluctuations.
Luca Egli, Julian Gröbner, Herbert Schill, and Eliane Maillard Barras
Atmos. Meas. Tech., 16, 2889–2902, https://doi.org/10.5194/amt-16-2889-2023, https://doi.org/10.5194/amt-16-2889-2023, 2023
Short summary
Short summary
This paper introduces a new method to retrieve total column ozone with spectral ground-based measurements from a novel array spectroradiometer. Total column ozone estimates using the small, cost-effective, and robust instrument and the new retrieval method are compared with other co-located total column ozone instruments. The comparison shows that the new system performs similarly to other well-established instruments, which require substantially more maintenance than the system introduced here.
Xiaoyi Zhao, Vitali Fioletov, Alberto Redondas, Julian Gröbner, Luca Egli, Franz Zeilinger, Javier López-Solano, Alberto Berjón Arroyo, James Kerr, Eliane Maillard Barras, Herman Smit, Michael Brohart, Reno Sit, Akira Ogyu, Ihab Abboud, and Sum Chi Lee
Atmos. Meas. Tech., 16, 2273–2295, https://doi.org/10.5194/amt-16-2273-2023, https://doi.org/10.5194/amt-16-2273-2023, 2023
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The Brewer ozone spectrophotometer is one of the World Meteorological Organization (WMO) Global Atmosphere Watch (GAW)'s standard ozone monitoring instruments since the 1980s. This work is aimed at obtaining answers to (1) why Brewer primary calibration work can only be performed at certain sites (e.g., Izaña and MLO) and (2) what is needed to assure the equivalence of calibration quality from different sites.
Eric Sauvageat, Eliane Maillard Barras, Klemens Hocke, Alexander Haefele, and Axel Murk
Atmos. Meas. Tech., 15, 6395–6417, https://doi.org/10.5194/amt-15-6395-2022, https://doi.org/10.5194/amt-15-6395-2022, 2022
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We present new harmonized ozone time series from two ground-based microwave radiometers in Switzerland. The new series consist of hourly ozone profiles in the middle atmosphere (~ 20–70 km) from 2009 until 2021. Cross-validation of the new data series shows the benefit of the harmonization process compared to the previous versions. Comparisons with collocated satellite observations is used to further validate these time series for long-term ozone monitoring over central Europe.
Sophie Godin-Beekmann, Niramson Azouz, Viktoria F. Sofieva, Daan Hubert, Irina Petropavlovskikh, Peter Effertz, Gérard Ancellet, Doug A. Degenstein, Daniel Zawada, Lucien Froidevaux, Stacey Frith, Jeannette Wild, Sean Davis, Wolfgang Steinbrecht, Thierry Leblanc, Richard Querel, Kleareti Tourpali, Robert Damadeo, Eliane Maillard Barras, René Stübi, Corinne Vigouroux, Carlo Arosio, Gerald Nedoluha, Ian Boyd, Roeland Van Malderen, Emmanuel Mahieu, Dan Smale, and Ralf Sussmann
Atmos. Chem. Phys., 22, 11657–11673, https://doi.org/10.5194/acp-22-11657-2022, https://doi.org/10.5194/acp-22-11657-2022, 2022
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An updated evaluation up to 2020 of stratospheric ozone profile long-term trends at extrapolar latitudes based on satellite and ground-based records is presented. Ozone increase in the upper stratosphere is confirmed, with significant trends at most latitudes. In this altitude region, a very good agreement is found with trends derived from chemistry–climate model simulations. Observed and modelled trends diverge in the lower stratosphere, but the differences are non-significant.
René Stübi, Herbert Schill, Jörg Klausen, Eliane Maillard Barras, and Alexander Haefele
Atmos. Meas. Tech., 14, 5757–5769, https://doi.org/10.5194/amt-14-5757-2021, https://doi.org/10.5194/amt-14-5757-2021, 2021
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In the first half of the 20th century, Prof. Dobson developed an instrument to measure the ozone column. Around 50 of these Dobson instruments, manufactured in the second half of the 20th century, are still used today to monitor the state of the ozone layer. Started in 1926, the Arosa series was, until recently, based on manually operated Dobsons. To ensure its future operation, a fully automated version of the Dobson has been developed. This well-working automated system is described here.
René Stübi, Herbert Schill, Eliane Maillard Barras, Jörg Klausen, and Alexander Haefele
Atmos. Meas. Tech., 14, 4203–4217, https://doi.org/10.5194/amt-14-4203-2021, https://doi.org/10.5194/amt-14-4203-2021, 2021
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Total ozone column has been measured since 1926 in the Swiss Alps station Arosa. These worldwide series are based on Dobson sun spectrophotometers. To assure the continuity of these series, a two-stage project was realized at MeteoSwiss: first, Dobson instruments were automated, and then parallel measurements between Arosa and a nearby site in Davos were carried out. The analysis of the data of the manual-to-automated transition and coincident data between the two sites are presented here.
Wanmin Gong, Stephen R. Beagley, Kenjiro Toyota, Henrik Skov, Jesper Heile Christensen, Alex Lupu, Diane Pendlebury, Junhua Zhang, Ulas Im, Yugo Kanaya, Alfonso Saiz-Lopez, Roberto Sommariva, Peter Effertz, John W. Halfacre, Nis Jepsen, Rigel Kivi, Theodore K. Koenig, Katrin Müller, Claus Nordstrøm, Irina Petropavlovskikh, Paul B. Shepson, William R. Simpson, Sverre Solberg, Ralf M. Staebler, David W. Tarasick, Roeland Van Malderen, and Mika Vestenius
Atmos. Chem. Phys., 25, 8355–8405, https://doi.org/10.5194/acp-25-8355-2025, https://doi.org/10.5194/acp-25-8355-2025, 2025
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This study showed that the springtime O3 depletion plays a critical role in driving the surface O3 seasonal cycle in the central Arctic. The O3 depletion events, while occurring most notably within the lowest few hundred metres above the Arctic Ocean, can induce a 5–7 % loss in the pan-Arctic tropospheric O3 burden during springtime. The study also found enhancements in O3 and NOy (mostly peroxyacetyl nitrate) concentrations in the Arctic due to northern boreal wildfires, particularly at higher altitudes.
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 7187–7225, https://doi.org/10.5194/acp-25-7187-2025, https://doi.org/10.5194/acp-25-7187-2025, 2025
Short summary
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Tropospheric ozone is an important greenhouse gas and is an air pollutant. The time variability of tropospheric ozone is mainly driven by anthropogenic emissions. In this paper, we study the distribution and time variability of ozone from harmonized ground-based observations from five different measurement techniques. Our findings provide clear standard references for atmospheric models and evolving tropospheric ozone satellite data for the 2000–2022 period.
Peter Hrabčák, Meritxell Garcia-Suñer, Violeta Matos, Víctor Estellés, Anna Pribullová, Jozef Depta, Martin Staněk, and Martin Stráník
EGUsphere, https://doi.org/10.5194/egusphere-2025-2887, https://doi.org/10.5194/egusphere-2025-2887, 2025
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This study analyses 30 years of total ozone and aerosol optical depth measurements from Slovakia. It shows clear seasonal patterns and a long-term decrease in atmospheric particles, likely due to reduced pollution. We also found that changes in the height of the tropopause may influence ozone levels. The research helps us understand how human activity and climate change affect the atmosphere over time.
Vasura Jayaweera, Robert J. Sica, Giovanni Martucci, and Alexander Haefele
Atmos. Meas. Tech., 18, 1461–1469, https://doi.org/10.5194/amt-18-1461-2025, https://doi.org/10.5194/amt-18-1461-2025, 2025
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Our study presents a new method, the solar background calibration method, which improves temperature determinations in rotational Raman lidar systems. By utilizing background solar radiation, this technique offers more continuous and reliable temperatures independent of external measuring instruments. This new method enhances our ability to monitor and understand atmospheric trends and their association with climate change with greater accuracy.
Irina Petropavlovskikh, Jeannette D. Wild, Kari Abromitis, Peter Effertz, Koji Miyagawa, Lawrence E. Flynn, Eliane Maillard Barras, Robert Damadeo, Glen McConville, Bryan Johnson, Patrick Cullis, Sophie Godin-Beekmann, Gerard Ancellet, Richard Querel, Roeland Van Malderen, and Daniel Zawada
Atmos. Chem. Phys., 25, 2895–2936, https://doi.org/10.5194/acp-25-2895-2025, https://doi.org/10.5194/acp-25-2895-2025, 2025
Short summary
Short summary
Observational records show that stratospheric ozone is recovering in accordance with the implementation of the Montreal Protocol and its amendments. Natural ozone variability complicates the detection of small trends. This study optimizes a statistical model fit in ground-station-based observational records by adding parameters that interpret seasonal and long-term changes in atmospheric circulation and airmass mixing, which reduces uncertainties in detecting the stratospheric ozone recovery.
Gaëlle Dufour, Maxim Eremenko, Juan Cuesta, Gérard Ancellet, Michael Gill, Eliane Maillard Barras, and Roeland Van Malderen
EGUsphere, https://doi.org/10.5194/egusphere-2024-4096, https://doi.org/10.5194/egusphere-2024-4096, 2025
Short summary
Short summary
The IASI-O3 KOPRA v3.0 product shows strong consistency (<1 %) for the three IASI instruments. The validation against homogenized ozone sondes reveals an overall good agreement with slight biases (3–6 %) in tropospheric ozone and a possible temporal drift but difficult to assess due to the limited number of sites. No specific trends are estimated for the tropospheric ozone column for 2008–2022, but persistent negative trends are observed in the lower troposphere.
Roeland Van Malderen, Zhou Zang, Kai-Lan Chang, Robin Björklund, Owen R. Cooper, Jane Liu, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, Audrey Gaudel, David W. Tarasick, Herman G. J. Smit, Anne M. Thompson, Ryan M. Stauffer, Debra E. Kollonige, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Isamu Morino, Glen McConville, Katrin Müller, Isao Murata, Justus Notholt, Ankie Piters, Maxime Prignon, Richard Querel, Vincenzo Rizi, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3745, https://doi.org/10.5194/egusphere-2024-3745, 2025
Short summary
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Tropospheric ozone is an important greenhouse gas and an air pollutant, whose distribution and time variability is mainly governed by anthropogenic emissions and dynamics. In this paper, we assess regional trends of tropospheric ozone column amounts, based on two different approaches of merging or synthesizing ground-based observations and their trends within specific regions. Our findings clearly demonstrate regional trend differences, but also consistently higher pre- than post-COVID trends.
Robin Björklund, Corinne Vigouroux, Peter Effertz, Omaira E. García, Alex Geddes, James Hannigan, Koji Miyagawa, Michael Kotkamp, Bavo Langerock, Gerald Nedoluha, Ivan Ortega, Irina Petropavlovskikh, Deniz Poyraz, Richard Querel, John Robinson, Hisako Shiona, Dan Smale, Penny Smale, Roeland Van Malderen, and Martine De Mazière
Atmos. Meas. Tech., 17, 6819–6849, https://doi.org/10.5194/amt-17-6819-2024, https://doi.org/10.5194/amt-17-6819-2024, 2024
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Different ground-based ozone measurements from the last 2 decades at Lauder are compared to each other. We want to know why different trends have been observed in the stratosphere. Also, the quality and relevance of tropospheric datasets need to be evaluated. While remaining drifts are still present, our study explains roughly half of the differences in observed trends in previous studies and shows the necessity for continuous review and improvement of the measurements.
Andrew O. Langford, Raul J. Alvarez II, Kenneth C. Aikin, Sunil Baidar, W. Alan Brewer, Steven S. Brown, Matthew M. Coggan, Patrick D. Cullis, Jessica Gilman, Georgios I. Gkatzelis, Detlev Helmig, Bryan J. Johnson, K. Emma Knowland, Rajesh Kumar, Aaron D. Lamplugh, Audra McClure-Begley, Brandi J. McCarty, Ann M. Middlebrook, Gabriele Pfister, Jeff Peischl, Irina Petropavlovskikh, Pamela S. Rickley, Andrew W. Rollins, Scott P. Sandberg, Christoph J. Senff, and Carsten Warneke
EGUsphere, https://doi.org/10.5194/egusphere-2024-1938, https://doi.org/10.5194/egusphere-2024-1938, 2024
Preprint withdrawn
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High ozone (O3) formed by reactions of nitrogen oxides (NOx) and volatile organic compounds (VOCs) can harm human health and welfare. High O3 is usually associated with hot summer days, but under certain conditions, high O3 can also form under winter conditions. In this study, we describe a high O3 event that occurred in Colorado during the COVID-19 quarantine that was caused in part by the decrease in traffic, and in part by a shallow inversion created by descent of stratospheric air.
Luis F. Millán, Peter Hoor, Michaela I. Hegglin, Gloria L. Manney, Harald Boenisch, Paul Jeffery, Daniel Kunkel, Irina Petropavlovskikh, Hao Ye, Thierry Leblanc, and Kaley Walker
Atmos. Chem. Phys., 24, 7927–7959, https://doi.org/10.5194/acp-24-7927-2024, https://doi.org/10.5194/acp-24-7927-2024, 2024
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In the Observed Composition Trends And Variability in the UTLS (OCTAV-UTLS) Stratosphere-troposphere Processes And their Role in Climate (SPARC) activity, we have mapped multiplatform ozone datasets into coordinate systems to systematically evaluate the influence of these coordinates on binned climatological variability. This effort unifies the work of studies that focused on individual coordinate system variability. Our goal was to create the most comprehensive assessment of this topic.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, Peter Effertz, Gary Morris, and Brian C. McDonald
Atmos. Chem. Phys., 24, 6197–6218, https://doi.org/10.5194/acp-24-6197-2024, https://doi.org/10.5194/acp-24-6197-2024, 2024
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A great majority of observational trend studies of free tropospheric ozone use sparsely sampled ozonesonde and aircraft measurements as reference data sets. A ubiquitous assumption is that trends are accurate and reliable so long as long-term records are available. We show that sampling bias due to sparse samples can persistently reduce the trend accuracy, and we highlight the importance of maintaining adequate frequency and continuity of observations.
Davide Putero, Paolo Cristofanelli, Kai-Lan Chang, Gaëlle Dufour, Gregory Beachley, Cédric Couret, Peter Effertz, Daniel A. Jaffe, Dagmar Kubistin, Jason Lynch, Irina Petropavlovskikh, Melissa Puchalski, Timothy Sharac, Barkley C. Sive, Martin Steinbacher, Carlos Torres, and Owen R. Cooper
Atmos. Chem. Phys., 23, 15693–15709, https://doi.org/10.5194/acp-23-15693-2023, https://doi.org/10.5194/acp-23-15693-2023, 2023
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We investigated the impact of societal restriction measures during the COVID-19 pandemic on surface ozone at 41 high-elevation sites worldwide. Negative ozone anomalies were observed for spring and summer 2020 for all of the regions considered. In 2021, negative anomalies continued for Europe and partially for the eastern US, while western US sites showed positive anomalies due to wildfires. IASI satellite data and the Carbon Monitor supported emission reductions as a cause of the anomalies.
Alexandra Tsekeri, Anna Gialitaki, Marco Di Paolantonio, Davide Dionisi, Gian Luigi Liberti, Alnilam Fernandes, Artur Szkop, Aleksander Pietruczuk, Daniel Pérez-Ramírez, Maria J. Granados Muñoz, Juan Luis Guerrero-Rascado, Lucas Alados-Arboledas, Diego Bermejo Pantaleón, Juan Antonio Bravo-Aranda, Anna Kampouri, Eleni Marinou, Vassilis Amiridis, Michael Sicard, Adolfo Comerón, Constantino Muñoz-Porcar, Alejandro Rodríguez-Gómez, Salvatore Romano, Maria Rita Perrone, Xiaoxia Shang, Mika Komppula, Rodanthi-Elisavet Mamouri, Argyro Nisantzi, Diofantos Hadjimitsis, Francisco Navas-Guzmán, Alexander Haefele, Dominika Szczepanik, Artur Tomczak, Iwona S. Stachlewska, Livio Belegante, Doina Nicolae, Kalliopi Artemis Voudouri, Dimitris Balis, Athena A. Floutsi, Holger Baars, Linda Miladi, Nicolas Pascal, Oleg Dubovik, and Anton Lopatin
Atmos. Meas. Tech., 16, 6025–6050, https://doi.org/10.5194/amt-16-6025-2023, https://doi.org/10.5194/amt-16-6025-2023, 2023
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EARLINET/ACTRIS organized an intensive observational campaign in May 2020, with the objective of monitoring the atmospheric state over Europe during the COVID-19 lockdown and relaxation period. The work presented herein focuses on deriving a common methodology for applying a synergistic retrieval that utilizes the network's ground-based passive and active remote sensing measurements and deriving the aerosols from anthropogenic activities over Europe.
Vitali Fioletov, Xiaoyi Zhao, Ihab Abboud, Michael Brohart, Akira Ogyu, Reno Sit, Sum Chi Lee, Irina Petropavlovskikh, Koji Miyagawa, Bryan J. Johnson, Patrick Cullis, John Booth, Glen McConville, and C. Thomas McElroy
Atmos. Chem. Phys., 23, 12731–12751, https://doi.org/10.5194/acp-23-12731-2023, https://doi.org/10.5194/acp-23-12731-2023, 2023
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Stratospheric ozone within the Southern Hemisphere springtime polar vortex has been a subject of intense research since the discovery of the Antarctic ozone hole. The wintertime ozone in the vortex is less studied. We show that the recent wintertime ozone values over the South Pole were about 12 % below the pre-1980s level; i.e., the decline there was nearly twice as large as that over southern midlatitudes. Thus, wintertime ozone there can be used as an indicator of the ozone layer state.
Eric Sauvageat, Klemens Hocke, Eliane Maillard Barras, Shengyi Hou, Quentin Errera, Alexander Haefele, and Axel Murk
Atmos. Chem. Phys., 23, 7321–7345, https://doi.org/10.5194/acp-23-7321-2023, https://doi.org/10.5194/acp-23-7321-2023, 2023
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In Switzerland, two microwave radiometers can measure continuous ozone profiles in the middle atmosphere. From these instruments, we can study the diurnal variation of ozone, which is difficult to observe otherwise. It is valuable to validate the model simulations of diurnal variations in this region. We present results obtained during the last decade and compare them against various models. For the first time, we also show that the winter diurnal variations have some short-term fluctuations.
Luis F. Millán, Gloria L. Manney, Harald Boenisch, Michaela I. Hegglin, Peter Hoor, Daniel Kunkel, Thierry Leblanc, Irina Petropavlovskikh, Kaley Walker, Krzysztof Wargan, and Andreas Zahn
Atmos. Meas. Tech., 16, 2957–2988, https://doi.org/10.5194/amt-16-2957-2023, https://doi.org/10.5194/amt-16-2957-2023, 2023
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The determination of atmospheric composition trends in the upper troposphere and lower stratosphere (UTLS) is still highly uncertain. We present the creation of dynamical diagnostics to map several ozone datasets (ozonesondes, lidars, aircraft, and satellite measurements) in geophysically based coordinate systems. The diagnostics can also be used to analyze other greenhouse gases relevant to surface climate and UTLS chemistry.
Luca Egli, Julian Gröbner, Herbert Schill, and Eliane Maillard Barras
Atmos. Meas. Tech., 16, 2889–2902, https://doi.org/10.5194/amt-16-2889-2023, https://doi.org/10.5194/amt-16-2889-2023, 2023
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This paper introduces a new method to retrieve total column ozone with spectral ground-based measurements from a novel array spectroradiometer. Total column ozone estimates using the small, cost-effective, and robust instrument and the new retrieval method are compared with other co-located total column ozone instruments. The comparison shows that the new system performs similarly to other well-established instruments, which require substantially more maintenance than the system introduced here.
Xiaoyi Zhao, Vitali Fioletov, Alberto Redondas, Julian Gröbner, Luca Egli, Franz Zeilinger, Javier López-Solano, Alberto Berjón Arroyo, James Kerr, Eliane Maillard Barras, Herman Smit, Michael Brohart, Reno Sit, Akira Ogyu, Ihab Abboud, and Sum Chi Lee
Atmos. Meas. Tech., 16, 2273–2295, https://doi.org/10.5194/amt-16-2273-2023, https://doi.org/10.5194/amt-16-2273-2023, 2023
Short summary
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The Brewer ozone spectrophotometer is one of the World Meteorological Organization (WMO) Global Atmosphere Watch (GAW)'s standard ozone monitoring instruments since the 1980s. This work is aimed at obtaining answers to (1) why Brewer primary calibration work can only be performed at certain sites (e.g., Izaña and MLO) and (2) what is needed to assure the equivalence of calibration quality from different sites.
Klára Čížková, Kamil Láska, Ladislav Metelka, and Martin Staněk
Atmos. Chem. Phys., 23, 4617–4636, https://doi.org/10.5194/acp-23-4617-2023, https://doi.org/10.5194/acp-23-4617-2023, 2023
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The study deals with ultraviolet (UV) radiation in southern polar conditions, where ozone depletion occurs each spring. A 10-year-long time series of UV spectra from Marambio Base, Antarctic Peninsula, has been studied, with a focus on the changes of UV radiation at different wavelengths and the effects of atmospheric and terrestrial variables like ozone, solar elevation, or cloudiness. At the very short wavelengths, the effect of ozone and its deficiency was clearly observed.
Bryan J. Johnson, Patrick Cullis, John Booth, Irina Petropavlovskikh, Glen McConville, Birgit Hassler, Gary A. Morris, Chance Sterling, and Samuel Oltmans
Atmos. Chem. Phys., 23, 3133–3146, https://doi.org/10.5194/acp-23-3133-2023, https://doi.org/10.5194/acp-23-3133-2023, 2023
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In 1986, soon after the discovery of the Antarctic ozone hole, NOAA began year-round ozonesonde observations at South Pole Station to measure vertical profiles of ozone and temperature from the surface to 35 km. Balloon-borne ozonesondes launched at this unique site allow for tracking all phases of the yearly springtime ozone hole beginning in late winter and after sunrise, when rapid ozone depletion begins over the South Pole throughout the month of September.
Michael J. Prather, Lucien Froidevaux, and Nathaniel J. Livesey
Atmos. Chem. Phys., 23, 843–849, https://doi.org/10.5194/acp-23-843-2023, https://doi.org/10.5194/acp-23-843-2023, 2023
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From satellite data for nitrous oxide (N2O), ozone and temperature, we calculate the monthly loss of N2O and find it is increasing faster than expected, resulting in a shorter lifetime, which reduces the impact of anthropogenic emissions. We identify the cause as enhanced vertical lofting of high-N2O air into the tropical middle stratosphere, where it is destroyed photochemically. Because global warming is due in part to N2O, this finding presents a new negative climate-chemistry feedback.
Cynthia H. Whaley, Kathy S. Law, Jens Liengaard Hjorth, Henrik Skov, Stephen R. Arnold, Joakim Langner, Jakob Boyd Pernov, Garance Bergeron, Ilann Bourgeois, Jesper H. Christensen, Rong-You Chien, Makoto Deushi, Xinyi Dong, Peter Effertz, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Greg Huey, Ulas Im, Rigel Kivi, Louis Marelle, Tatsuo Onishi, Naga Oshima, Irina Petropavlovskikh, Jeff Peischl, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Tom Ryerson, Ragnhild Skeie, Sverre Solberg, Manu A. Thomas, Chelsea Thompson, Kostas Tsigaridis, Svetlana Tsyro, Steven T. Turnock, Knut von Salzen, and David W. Tarasick
Atmos. Chem. Phys., 23, 637–661, https://doi.org/10.5194/acp-23-637-2023, https://doi.org/10.5194/acp-23-637-2023, 2023
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This study summarizes recent research on ozone in the Arctic, a sensitive and rapidly warming region. We find that the seasonal cycles of near-surface atmospheric ozone are variable depending on whether they are near the coast, inland, or at high altitude. Several global model simulations were evaluated, and we found that because models lack some of the ozone chemistry that is important for the coastal Arctic locations, they do not accurately simulate ozone there.
Eric Sauvageat, Eliane Maillard Barras, Klemens Hocke, Alexander Haefele, and Axel Murk
Atmos. Meas. Tech., 15, 6395–6417, https://doi.org/10.5194/amt-15-6395-2022, https://doi.org/10.5194/amt-15-6395-2022, 2022
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We present new harmonized ozone time series from two ground-based microwave radiometers in Switzerland. The new series consist of hourly ozone profiles in the middle atmosphere (~ 20–70 km) from 2009 until 2021. Cross-validation of the new data series shows the benefit of the harmonization process compared to the previous versions. Comparisons with collocated satellite observations is used to further validate these time series for long-term ozone monitoring over central Europe.
Kostas Eleftheratos, John Kapsomenakis, Ilias Fountoulakis, Christos S. Zerefos, Patrick Jöckel, Martin Dameris, Alkiviadis F. Bais, Germar Bernhard, Dimitra Kouklaki, Kleareti Tourpali, Scott Stierle, J. Ben Liley, Colette Brogniez, Frédérique Auriol, Henri Diémoz, Stana Simic, Irina Petropavlovskikh, Kaisa Lakkala, and Kostas Douvis
Atmos. Chem. Phys., 22, 12827–12855, https://doi.org/10.5194/acp-22-12827-2022, https://doi.org/10.5194/acp-22-12827-2022, 2022
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We present the future evolution of DNA-active ultraviolet (UV) radiation in view of increasing greenhouse gases (GHGs) and decreasing ozone depleting substances (ODSs). It is shown that DNA-active UV radiation might increase after 2050 between 50° N–50° S due to GHG-induced reductions in clouds and ozone, something that is likely not to happen at high latitudes, where DNA-active UV radiation will continue its downward trend mainly due to stratospheric ozone recovery from the reduction in ODSs.
Sophie Godin-Beekmann, Niramson Azouz, Viktoria F. Sofieva, Daan Hubert, Irina Petropavlovskikh, Peter Effertz, Gérard Ancellet, Doug A. Degenstein, Daniel Zawada, Lucien Froidevaux, Stacey Frith, Jeannette Wild, Sean Davis, Wolfgang Steinbrecht, Thierry Leblanc, Richard Querel, Kleareti Tourpali, Robert Damadeo, Eliane Maillard Barras, René Stübi, Corinne Vigouroux, Carlo Arosio, Gerald Nedoluha, Ian Boyd, Roeland Van Malderen, Emmanuel Mahieu, Dan Smale, and Ralf Sussmann
Atmos. Chem. Phys., 22, 11657–11673, https://doi.org/10.5194/acp-22-11657-2022, https://doi.org/10.5194/acp-22-11657-2022, 2022
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An updated evaluation up to 2020 of stratospheric ozone profile long-term trends at extrapolar latitudes based on satellite and ground-based records is presented. Ozone increase in the upper stratosphere is confirmed, with significant trends at most latitudes. In this altitude region, a very good agreement is found with trends derived from chemistry–climate model simulations. Observed and modelled trends diverge in the lower stratosphere, but the differences are non-significant.
Fernando Chouza, Thierry Leblanc, Mark Brewer, Patrick Wang, Giovanni Martucci, Alexander Haefele, Hélène Vérèmes, Valentin Duflot, Guillaume Payen, and Philippe Keckhut
Atmos. Meas. Tech., 15, 4241–4256, https://doi.org/10.5194/amt-15-4241-2022, https://doi.org/10.5194/amt-15-4241-2022, 2022
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The comparison of water vapor lidar measurements with co-located radiosondes and aerosol backscatter profiles indicates that laser-induced aerosol fluorescence in smoke layers injected into the stratosphere can introduce very large and chronic wet biases above 15 km, thus impacting the ability of these systems to accurately estimate long-term water vapor trends. The proposed correction method presented in this work is able to reduce this fluorescence-induced bias from 75 % to under 5 %.
Noah Bernays, Daniel A. Jaffe, Irina Petropavlovskikh, and Peter Effertz
Atmos. Meas. Tech., 15, 3189–3192, https://doi.org/10.5194/amt-15-3189-2022, https://doi.org/10.5194/amt-15-3189-2022, 2022
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Ozone is an important pollutant that impacts millions of people worldwide. It is therefore important to ensure accurate measurements. A recent surge in wildfire activity in the USA has resulted in significant enhancements in ozone concentration. However given the nature of wildfire smoke, there are questions about our ability to accurately measure ozone. In this comment, we discuss possible biases in the UV measurements of ozone in the presence of smoke.
Shima Bahramvash Shams, Von P. Walden, James W. Hannigan, William J. Randel, Irina V. Petropavlovskikh, Amy H. Butler, and Alvaro de la Cámara
Atmos. Chem. Phys., 22, 5435–5458, https://doi.org/10.5194/acp-22-5435-2022, https://doi.org/10.5194/acp-22-5435-2022, 2022
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Large-scale atmospheric circulation has a strong influence on ozone in the Arctic, and certain anomalous dynamical events, such as sudden stratospheric warmings, cause dramatic alterations of the large-scale circulation. A reanalysis model is evaluated and then used to investigate the impact of sudden stratospheric warmings on mid-atmospheric ozone. Results show that the position of the cold jet stream over the Arctic before these events influences the variability of ozone.
Luca Egli, Julian Gröbner, Gregor Hülsen, Herbert Schill, and René Stübi
Atmos. Meas. Tech., 15, 1917–1930, https://doi.org/10.5194/amt-15-1917-2022, https://doi.org/10.5194/amt-15-1917-2022, 2022
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This study presents traceable total column ozone retrievals from direct solar spectral irradiance measurements. The retrieved ozone does not require any field calibration with a reference instrument as it is required for other operational network instruments such as Brewer or Dobson. Total column ozone can be retrieved with a traceable overall standard uncertainty of less than 0.8 % indicating a benchmark uncertainty for total column ozone measurements.
Irina Petropavlovskikh, Koji Miyagawa, Audra McClure-Beegle, Bryan Johnson, Jeannette Wild, Susan Strahan, Krzysztof Wargan, Richard Querel, Lawrence Flynn, Eric Beach, Gerard Ancellet, and Sophie Godin-Beekmann
Atmos. Meas. Tech., 15, 1849–1870, https://doi.org/10.5194/amt-15-1849-2022, https://doi.org/10.5194/amt-15-1849-2022, 2022
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The Montreal Protocol and its amendments assure the recovery of the stratospheric ozone layer that protects the Earth from harmful ultraviolet radiation. To monitor ozone recovery, multiple satellites and ground-based observational platforms collect ozone data. The changes in instruments can influence the continuation of the ozone data. We discuss a method to remove instrumental artifacts from ozone records to improve the internal consistency among multiple observational records.
Andrew O. Langford, Christoph J. Senff, Raul J. Alvarez II, Ken C. Aikin, Sunil Baidar, Timothy A. Bonin, W. Alan Brewer, Jerome Brioude, Steven S. Brown, Joel D. Burley, Dani J. Caputi, Stephen A. Conley, Patrick D. Cullis, Zachary C. J. Decker, Stéphanie Evan, Guillaume Kirgis, Meiyun Lin, Mariusz Pagowski, Jeff Peischl, Irina Petropavlovskikh, R. Bradley Pierce, Thomas B. Ryerson, Scott P. Sandberg, Chance W. Sterling, Ann M. Weickmann, and Li Zhang
Atmos. Chem. Phys., 22, 1707–1737, https://doi.org/10.5194/acp-22-1707-2022, https://doi.org/10.5194/acp-22-1707-2022, 2022
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The Fires, Asian, and Stratospheric Transport–Las Vegas Ozone Study (FAST-LVOS) combined lidar, aircraft, and in situ measurements with global models to investigate the contributions of stratospheric intrusions, regional and Asian pollution, and wildfires to background ozone in the southwestern US during May and June 2017 and demonstrated that these processes contributed to background ozone levels that exceeded 70 % of the US National Ambient Air Quality Standard during the 6-week campaign.
Hugues Brenot, Nicolas Theys, Lieven Clarisse, Jeroen van Gent, Daniel R. Hurtmans, Sophie Vandenbussche, Nikolaos Papagiannopoulos, Lucia Mona, Timo Virtanen, Andreas Uppstu, Mikhail Sofiev, Luca Bugliaro, Margarita Vázquez-Navarro, Pascal Hedelt, Michelle Maree Parks, Sara Barsotti, Mauro Coltelli, William Moreland, Simona Scollo, Giuseppe Salerno, Delia Arnold-Arias, Marcus Hirtl, Tuomas Peltonen, Juhani Lahtinen, Klaus Sievers, Florian Lipok, Rolf Rüfenacht, Alexander Haefele, Maxime Hervo, Saskia Wagenaar, Wim Som de Cerff, Jos de Laat, Arnoud Apituley, Piet Stammes, Quentin Laffineur, Andy Delcloo, Robertson Lennart, Carl-Herbert Rokitansky, Arturo Vargas, Markus Kerschbaum, Christian Resch, Raimund Zopp, Matthieu Plu, Vincent-Henri Peuch, Michel Van Roozendael, and Gerhard Wotawa
Nat. Hazards Earth Syst. Sci., 21, 3367–3405, https://doi.org/10.5194/nhess-21-3367-2021, https://doi.org/10.5194/nhess-21-3367-2021, 2021
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The purpose of the EUNADICS-AV (European Natural Airborne Disaster Information and Coordination System for Aviation) prototype early warning system (EWS) is to develop the combined use of harmonised data products from satellite, ground-based and in situ instruments to produce alerts of airborne hazards (volcanic, dust, smoke and radionuclide clouds), satisfying the requirement of aviation air traffic management (ATM) stakeholders (https://cordis.europa.eu/project/id/723986).
René Stübi, Herbert Schill, Jörg Klausen, Eliane Maillard Barras, and Alexander Haefele
Atmos. Meas. Tech., 14, 5757–5769, https://doi.org/10.5194/amt-14-5757-2021, https://doi.org/10.5194/amt-14-5757-2021, 2021
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In the first half of the 20th century, Prof. Dobson developed an instrument to measure the ozone column. Around 50 of these Dobson instruments, manufactured in the second half of the 20th century, are still used today to monitor the state of the ozone layer. Started in 1926, the Arosa series was, until recently, based on manually operated Dobsons. To ensure its future operation, a fully automated version of the Dobson has been developed. This well-working automated system is described here.
René Stübi, Herbert Schill, Eliane Maillard Barras, Jörg Klausen, and Alexander Haefele
Atmos. Meas. Tech., 14, 4203–4217, https://doi.org/10.5194/amt-14-4203-2021, https://doi.org/10.5194/amt-14-4203-2021, 2021
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Total ozone column has been measured since 1926 in the Swiss Alps station Arosa. These worldwide series are based on Dobson sun spectrophotometers. To assure the continuity of these series, a two-stage project was realized at MeteoSwiss: first, Dobson instruments were automated, and then parallel measurements between Arosa and a nearby site in Davos were carried out. The analysis of the data of the manual-to-automated transition and coincident data between the two sites are presented here.
Marek Šmíd, Geiland Porrovecchio, Jiří Tesař, Tim Burnitt, Luca Egli, Julian Grőbner, Petr Linduška, and Martin Staněk
Atmos. Meas. Tech., 14, 3573–3582, https://doi.org/10.5194/amt-14-3573-2021, https://doi.org/10.5194/amt-14-3573-2021, 2021
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We designed and developed a tuneable and portable radiation source (TuPS) to provide a reference wavelength scale, with a bandwidth of emitted radiation of 0.13 nm and uncertainty in wavelength of 0.02 nm. TuPS was successfully used for the in-field characterization of 14 Dobson spectrophotometers in campaigns in Europe. The line spread functions of Dobsons measured by TuPS in conjunction with the cross-sections from IUP improves the consistency between the Dobson and Brewer from 3 % to 1 %.
Julian Gröbner, Herbert Schill, Luca Egli, and René Stübi
Atmos. Meas. Tech., 14, 3319–3331, https://doi.org/10.5194/amt-14-3319-2021, https://doi.org/10.5194/amt-14-3319-2021, 2021
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The world's longest continuous total column ozone time series was initiated in 1926 at the Lichtklimatisches Observatorium (LKO), at Arosa, in the Swiss Alps. The measurements between Dobson and Brewer spectroradiometers have shown seasonal variations of the order of 2 %. The results of the study show that the consistency between the two instrument types can be significantly improved when the ozone cross-sections from Serdyuchenko et al. (2013) and the measured slit functions are used.
Giovanni Martucci, Francisco Navas-Guzmán, Ludovic Renaud, Gonzague Romanens, S. Mahagammulla Gamage, Maxime Hervo, Pierre Jeannet, and Alexander Haefele
Atmos. Meas. Tech., 14, 1333–1353, https://doi.org/10.5194/amt-14-1333-2021, https://doi.org/10.5194/amt-14-1333-2021, 2021
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This article presents a validation of 1.5 years of pure rotational temperature data measured by the Raman lidar RALMO installed at the MeteoSwiss station of Payerne. The statistical results are in terms of bias and standard deviation with respect to two well-established radiosounding systems. The statistics are divided into daytime (bias = 0.28 K, SD = 0.62±0.03 K) and nighttime (bias = 0.29 K, SD = 0.66±0.06 K). The lidar temperature profiles are applied to cloud supersaturation studies.
Simone Brunamonti, Giovanni Martucci, Gonzague Romanens, Yann Poltera, Frank G. Wienhold, Maxime Hervo, Alexander Haefele, and Francisco Navas-Guzmán
Atmos. Chem. Phys., 21, 2267–2285, https://doi.org/10.5194/acp-21-2267-2021, https://doi.org/10.5194/acp-21-2267-2021, 2021
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Lidar (light detection and ranging) is a class of remote-sensing instruments that are widely used for the monitoring of aerosol properties in the lower levels of the atmosphere, yet their measurements are affected by several sources of uncertainty. Here we present the first comparison of two lidar systems against a fully independent instrument carried by meteorological balloons. We show that both lidars achieve a good agreement with the high-precision balloon measurements up to 6 km altitude.
Xin Yang, Anne-M. Blechschmidt, Kristof Bognar, Audra McClure-Begley, Sara Morris, Irina Petropavlovskikh, Andreas Richter, Henrik Skov, Kimberly Strong, David W. Tarasick, Taneil Uttal, Mika Vestenius, and Xiaoyi Zhao
Atmos. Chem. Phys., 20, 15937–15967, https://doi.org/10.5194/acp-20-15937-2020, https://doi.org/10.5194/acp-20-15937-2020, 2020
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This is a modelling-based study on Arctic surface ozone, with a particular focus on spring ozone depletion events (i.e. with concentrations < 10 ppbv). Model experiments show that model runs with blowing-snow-sourced sea salt aerosols implemented as a source of reactive bromine can reproduce well large-scale ozone depletion events observed in the Arctic. This study supplies modelling evidence of the proposed mechanism of reactive-bromine release from blowing snow on sea ice (Yang et al., 2008).
Li Zhang, Meiyun Lin, Andrew O. Langford, Larry W. Horowitz, Christoph J. Senff, Elizabeth Klovenski, Yuxuan Wang, Raul J. Alvarez II, Irina Petropavlovskikh, Patrick Cullis, Chance W. Sterling, Jeff Peischl, Thomas B. Ryerson, Steven S. Brown, Zachary C. J. Decker, Guillaume Kirgis, and Stephen Conley
Atmos. Chem. Phys., 20, 10379–10400, https://doi.org/10.5194/acp-20-10379-2020, https://doi.org/10.5194/acp-20-10379-2020, 2020
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Measuring and quantifying the sources of elevated springtime ozone in the southwestern US is challenging but relevant to the implications for control policy. Here we use intensive field measurements and two global models to study ozone sources in the region. We find that ozone from the stratosphere, wildfires, and Asia is an important source of high-ozone events in the region. Our analysis also helps understand the uncertainties in ozone simulations with individual models.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, and Valérie Thouret
Atmos. Chem. Phys., 20, 9915–9938, https://doi.org/10.5194/acp-20-9915-2020, https://doi.org/10.5194/acp-20-9915-2020, 2020
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We provide a statistical framework for detecting trends of multiple autocorrelated time series from sparsely sampled profile data. The result is a better and more consistent quantification of trend estimates of vertical profile data. The focus was placed on the long-term ozone time series from commercial aircraft and balloon-borne ozonesonde measurements. This framework can be applied to other trace gases in the atmosphere.
Cited articles
Alsing, J.:
dlmmc: Dynamical linear model regression for atmospheric time-series analysis, J. Open Source Softw., 4, 1157, https://doi.org/10.21105/joss.01157, 2019. a
Arosio, C., Rozanov, A., Malinina, E., Weber, M., and Burrows, J. P.:
Merging of ozone profiles from SCIAMACHY, OMPS and SAGE II observations to study stratospheric ozone changes, Atmos. Meas. Tech., 12, 2423–2444, https://doi.org/10.5194/amt-12-2423-2019, 2019. a
Ball, W. T., Alsing, J., Mortlock, D. J., Rozanov, E. V., Tummon, F., and Haigh, J. D.:
Reconciling differences in stratospheric ozone composites, Atmos. Chem. Phys., 17, 12269–12302, https://doi.org/10.5194/acp-17-12269-2017, 2017. a
Ball, W. T., Alsing, J., Mortlock, D. J., Staehelin, J., Haigh, J. D., Peter, T., Tummon, F., Stübi, R., Stenke, A., Anderson, J., Bourassa, A., Davis, S. M., Degenstein, D., Frith, S., Froidevaux, L., Roth, C., Sofieva, V., Wang, R., Wild, J., Yu, P., Ziemke, J. R., and Rozanov, E. V.:
Evidence for a continuous decline in lower stratospheric ozone offsetting ozone layer recovery, Atmos. Chem. Phys., 18, 1379–1394, https://doi.org/10.5194/acp-18-1379-2018, 2018. a, b, c
Ball, W. T., Alsing, J., Staehelin, J., Davis, S. M., Froidevaux, L., and Peter, T.:
Stratospheric ozone trends for 1985–2018: sensitivity to recent large variability, Atmos. Chem. Phys., 19, 12731–12748, https://doi.org/10.5194/acp-19-12731-2019, 2019. a
Basher, R.:
Review of the Dobson spectrophotometer and its accuracy, WMO Global Ozone Research and Monitoring, Project, Report No. 13, Geneva, Switzerland, https://gml.noaa.gov/ozwv/dobson/papers/report13/report13.html (last access: 28 October 2022), 1982. a
Bernet, L., von Clarmann, T., Godin-Beekmann, S., Ancellet, G., Maillard Barras, E., Stübi, R., Steinbrecht, W., Kämpfer, N., and Hocke, K.:
Ground-based ozone profiles over central Europe: incorporating anomalous observations into the analysis of stratospheric ozone trends, Atmos. Chem. Phys., 19, 4289–4309, https://doi.org/10.5194/acp-19-4289-2019, 2019. a, b
Bernet, L., Boyd, I., Nedoluha, G., Querel, R., Swart, D., and Hocke, K.:
Validation and trend analysis of stratospheric ozone data from ground-based observations at Lauder, New Zealand, Remote Sens.-Basel, 13, 1–15, https://doi.org/10.3390/rs13010109, 2021. a
Bhartia, P. K., McPeters, R. D., Flynn, L. E., Taylor, S., Kramarova, N. A., Frith, S., Fisher, B., and DeLand, M.:
Solar Backscatter UV (SBUV) total ozone and profile algorithm, Atmos. Meas. Tech., 6, 2533–2548, https://doi.org/10.5194/amt-6-2533-2013, 2013. a
Bognar, K., Tegtmeier, S., Bourassa, A., Roth, C., Warnock, T., Zawada, D., and Degenstein, D.:
Stratospheric ozone trends for 1984–2021 in the SAGE II–OSIRIS–SAGE III/ISS composite dataset, Atmos. Chem. Phys., 22, 9553–9569, https://doi.org/10.5194/acp-22-9553-2022, 2022. a
Bowerman, B. L. and O'Connell, R. T.:
Linear statistical Models: An Applied Approach, PWS-Kent, Boston, ISBN 10: 0534921779, ISBN 13: 9780534921774, 1990. a
Chipperfield, M. P., Dhomse, S., Hossaini, R., Feng, W., Santee, M. L., Weber, M., Burrows, J. P., Wild, J. D., Loyola, D., and Coldewey-Egbers, M.:
On the Cause of Recent Variations in Lower Stratospheric Ozone, Geophys. Res. Lett., 45, 5718–5726, https://doi.org/10.1029/2018GL078071, 2018. a
Cochrane, D. and Orcutt, G. H.:
Application of least squares regression to relationships containing auto-correlated error terms, J. Am. Stat. Assoc., 44, 32–61, 1949. a
Dietmüller, S., Garny, H., Eichinger, R., and Ball, W. T.:
Analysis of recent lower-stratospheric ozone trends in chemistry climate models, Atmos. Chem. Phys., 21, 6811–6837, https://doi.org/10.5194/acp-21-6811-2021, 2021. a, b
Fitzka, M., Hadzimustafic, J., and Simic, S.:
Total ozone and Umkehr observations at Hoher Sonnblick 1994–2011: Climatology and extreme events, J. Geophys. Res.-Atmos., 119, 739–752, https://doi.org/10.1002/2013JD021173, 2004. a
Fragkos, K. I. P., Dotsas, M., Bais, A., Taylor, M., Hurtmans, D., Fountoulakis, I., Koukouli, M. E., Balis, D., and Stanek, M.:
Umkehr ozone profiles over Thessaloniki and comparison with satellite overpasses, in: 20th EGU General Assembly 2018, 8–13 April 2018, Vienna, Austria, X5.142, 2018. a
Gelaro, R., McCarty, W., Suárez, M. J., Todling, R., Molod, A., Takacs, L., Randles, C. A., Darmenov, A., Bosilovich, M. G., Reichle, R., Wargan, K., Coy, L., Cullather, R., Draper, C., Akella, S., Buchard, V., Conaty, A., da Silva, A. M., Gu, W., Kim, G. K., Koster, R., Lucchesi, R., Merkova, D., Nielsen, J. E., Partyka, G., Pawson, S., Putman, W., Rienecker, M., Schubert, S. D., Sienkiewicz, M., and Zhao, B.:
The modern-era retrospective analysis for research and applications, version 2 (MERRA-2), J. Climate, 30, 5419–5454, https://doi.org/10.1175/JCLI-D-16-0758.1, 2017. a
Godin-Beekmann, S., Azouz, N., Sofieva, V. F., Hubert, D., Petropavlovskikh, I., Effertz, P., Ancellet, G., Degenstein, D. A., Zawada, D., Froidevaux, L., Frith, S., Wild, J., Davis, S., Steinbrecht, W., Leblanc, T., Querel, R., Tourpali, K., Damadeo, R., Maillard Barras, E., Stübi, R., Vigouroux, C., Arosio, C., Nedoluha, G., Boyd, I., Van Malderen, R., Mahieu, E., Smale, D., and Sussmann, R.:
Updated trends of the stratospheric ozone vertical distribution in the 60∘ S–60∘ N latitude range based on the LOTUS regression model , Atmos. Chem. Phys., 22, 11657–11673, https://doi.org/10.5194/acp-22-11657-2022, 2022. a, b, c, d, e
Godson, W. L.:
The representation and analysis of vertical distributions of ozone, Q. J. Roy. Meteor. Soc., 88, 220–232, https://doi.org/10.1002/qj.49708837703, 1962. a
Gröbner, J., Schill, H., Egli, L., and Stübi, R.:
Consistency of total column ozone measurements between the Brewer and Dobson spectroradiometers of the LKO Arosa and PMOD/WRC Davos, Atmos. Meas. Tech., 14, 3319–3331, https://doi.org/10.5194/amt-14-3319-2021, 2021. a, b
Götz, F. W. P., Meetham, A. R., and Dobson, G. M. B.:
The vertical distribution of ozone in the atmosphere, P. Roy. Soc. A-Math. Phy., 416–443, 1934. a
Harris, N. R. P., Hassler, B., Tummon, F., Bodeker, G. E., Hubert, D., Petropavlovskikh, I., Steinbrecht, W., Anderson, J., Bhartia, P. K., Boone, C. D., Bourassa, A., Davis, S. M., Degenstein, D., Delcloo, A., Frith, S. M., Froidevaux, L., Godin-Beekmann, S., Jones, N., Kurylo, M. J., Kyrölä, E., Laine, M., Leblanc, S. T., Lambert, J.-C., Liley, B., Mahieu, E., Maycock, A., de Mazière, M., Parrish, A., Querel, R., Rosenlof, K. H., Roth, C., Sioris, C., Staehelin, J., Stolarski, R. S., Stübi, R., Tamminen, J., Vigouroux, C., Walker, K. A., Wang, H. J., Wild, J., and Zawodny, J. M.:
Past changes in the vertical distribution of ozone – Part 3: Analysis and interpretation of trends, Atmos. Chem. Phys., 15, 9965–9982, https://doi.org/10.5194/acp-15-9965-2015, 2015. a
Hubert, D., Lambert, J.-C., Verhoelst, T., Granville, J., Keppens, A., Baray, J.-L., Bourassa, A. E., Cortesi, U., Degenstein, D. A., Froidevaux, L., Godin-Beekmann, S., Hoppel, K. W., Johnson, B. J., Kyrölä, E., Leblanc, T., Lichtenberg, G., Marchand, M., McElroy, C. T., Murtagh, D., Nakane, H., Portafaix, T., Querel, R., Russell III, J. M., Salvador, J., Smit, H. G. J., Stebel, K., Steinbrecht, W., Strawbridge, K. B., Stübi, R., Swart, D. P. J., Taha, G., Tarasick, D. W., Thompson, A. M., Urban, J., van Gijsel, J. A. E., Van Malderen, R., von der Gathen, P., Walker, K. A., Wolfram, E., and Zawodny, J. M.:
Ground-based assessment of the bias and long-term stability of 14 limb and occultation ozone profile data records, Atmos. Meas. Tech., 9, 2497–2534, https://doi.org/10.5194/amt-9-2497-2016, 2016. a
Kyrölä, E., Laine, M., Sofieva, V., Tamminen, J., Päivärinta, S.-M., Tukiainen, S., Zawodny, J., and Thomason, L.:
Combined SAGE II–GOMOS ozone profile data set for 1984–2011 and trend analysis of the vertical distribution of ozone, Atmos. Chem. Phys., 13, 10645–10658, https://doi.org/10.5194/acp-13-10645-2013, 2013. a
Laine, M., Latva-Pukkila, N., and Kyrölä, E.:
Analysing time-varying trends in stratospheric ozone time series using the state space approach, Atmos. Chem. Phys., 14, 9707–9725, https://doi.org/10.5194/acp-14-9707-2014, 2014. a, b
Livesey, N. J., Read, W. G., Wagner, P. A., Froidevaux, L., Lambert, A., Manney, G. L., Millán Valle, L. F., Pumphrey, H. C., Santee, M. L., Schwartz, M. J., Wang, S., Fuller, R. A., Jarnot, R. F., Knosp, B. W., Martinez, E., and Lay, R. R.:
Earth Observing System (EOS) Aura Microwave Limb Sounder (MLS) Version 4.2x Level 2 data quality and description document, 1–168, https://mls.jpl.nasa.gov/data/v4-2_data_quality_document.pdf (last access: April 2020), 2018. a
Maillard Barras, E.: data sets of “Dynamic Linear Modeling estimates of long-term ozone trends from homogenized Dobson Umkehr profiles at Arosa, Switzerland”, Zenodo [data set], https://doi.org/10.5281/zenodo.7185409, 2022. a
Maillard Barras, E., Haefele, A., Nguyen, L., Tummon, F., Ball, W. T., Rozanov, E. V., Rüfenacht, R., Hocke, K., Bernet, L., Kämpfer, N., Nedoluha, G., and Boyd, I.:
Study of the dependence of long-term stratospheric ozone trends on local solar time, Atmos. Chem. Phys., 20, 8453–8471, https://doi.org/10.5194/acp-20-8453-2020, 2020. a
Mateer, C. L.:
On the information content of Umkehr observations, J. Atmos. Sci., 22, 370–382, https://doi.org/10.1175/1520-0469(1965)022<0370:OTICOU>2.0.CO;2, 1965. a
McElroy, C. T. and Kerr, J. B.:
Table Mountain ozone intercomparison: Brewer ozone spectrophotometer Umkehr observations, J. Geophys. Res., 100, 9293–9300, https://doi.org/10.1029/94JD03250, 1995. a
McPeters, R. D. and Labow, G. J.:
Climatology 2011: An MLS and sonde derived ozone climatology for satellite retrieval algorithms, J. Geophys. Res.-Atmos., 117, D10303, https://doi.org/10.1029/2011JD017006, 2012. a
McPeters, R. D., Bhartia, P. K., Krueger, A. J., Herman, J. R., Schlesinger, B. M., Wellemeyer, C. G., Seftor, C. J., Jaross, G., Taylor, S. L., Swissler, T., Torres, O., Labow, G., Byerly, W., and Cebula, R. P.:
Nimbus-7 Total Ozone Mapping Spectrometer Data Products User's Guide, NASA Ref. Publ., p. 75, 1996a. a
McPeters, R. D., Hollandsworth, S. M., Flynn, L. E., Herman, J. R., and Seftor, C. J.:
Long-term ozone trends derived from the 16 year combined Nimbus 7/Meteor 3 TOMS Version 7 Record, Geophys. Res. Lett., 23, 3699–3702, https://doi.org/10.1029/96GL03540, 1996b. a
Miller, A. J., Tiao, G., Reinsel, G., Wuebbles, D., Bishop, L., Kerr, J., Nagatani, R., DeLuisi, J., and Mateer, C.:
Comparisons of observed ozone trends in the stratosphere through examination of Umkehr and balloon ozonesonde data, J. Geophys. Res., 100, 11209–11217, https://doi.org/10.1029/95jd00632, 1995. a
Miyagawa, K., Sasaki, T., Nakane, H., Petropavlovskikh, I., and Evans, R.:
Reevaluation of long-term Umkehr data and ozone profiles at Japanese stations, J. Geophys. Res., 114, D07108, https://doi.org/10.1029/2008JD010658, 2009. a
MontrealProtocol: The Montreal Protocol on Substances that Deplete the Ozone Layer, International Legal Materials, 26, WMO, https://ozone.unep.org/treaties/montreal-protocol/montreal-protocol-substances-deplete-ozone-layer (last access: 28 October 2022), 1987. a
Orbe, C., Oman, L. D., Strahan, S. E., Waugh, D. W., Pawson, S., Takacs, L. L., and Molod, A. M.:
Large-Scale Atmospheric Transport in GEOS Replay Simulations, J. Adv. Model. Earth Sy., 9, 2545–2560, https://doi.org/10.1002/2017MS001053, 2017. a, b
Orbe, C., Wargan, K., Pawson, S., and Oman, L. D.:
Mechanisms Linked to Recent Ozone Decreases in the Northern Hemisphere Lower Stratosphere, J. Geophys. Res.-Atmos., 125, 1–23, https://doi.org/10.1029/2019JD031631, 2020. a
Park, A., Guillas, S., and Petropavlovskikh, I.:
Trends in stratospheric ozone profiles using functional mixed models, Atmos. Chem. Phys., 13, 11473–11501, https://doi.org/10.5194/acp-13-11473-2013, 2013. a, b
Petropavlovskikh, I. and Miyagawa, K.: NOAA Dobson Umkehr
Operational, StrayLight, and Optimized Ozone Profile Data,
Monthly Averages, NOAA GML [data set], https://gml.noaa.gov/aftp/data/ozwv/Dobson/AC4/Umkehr/Monthly/, last access:
28 October 2022. a
Petropavlovskikh, I., Bhartia, P. K., and DeLuisi, J.:
New Umkehr ozone profile retrieval algorithm optimized for climatological studies, Geophys. Res. Lett., 32, 1–5, https://doi.org/10.1029/2005GL023323, 2005a. a, b
Petropavlovskikh, I., Kireev, S., Maillard, E., Stuebi, R., and Bhartia, P. K.:
New Brewer algorithm for a single pair, WMO TD No. 1419, 25–27, WMO, https://library.wmo.int/doc_num.php?explnum_id=9374 (last access: 28 October 2022), 2005b. a
Petropavlovskikh, I., Evans, R., McConville, G., Miyagawa, K., and Oltmans, S.:
Effect of the out-of-band stray light on the retrieval of the Umkehr Dobson ozone profiles, Int. J. Remote Sens., 30, 6461–6482, https://doi.org/10.1080/01431160902865806, 2009. a, b
Petropavlovskikh, I., Evans, R., McConville, G., Oltmans, S., Quincy, D., Lantz, K., Disterhoft, P., Stanek, M., and Flynn, L.:
Sensitivity of Dobson and Brewer Umkehr ozone profile retrievals to ozone cross-sections and stray light effects, Atmos. Meas. Tech., 4, 1841–1853, https://doi.org/10.5194/amt-4-1841-2011, 2011. a
Petropavlovskikh, I., Godin-Beekmann, S., Hubert, D., Damadeo, R. P., Hassler, B., Sofieva, V. F., Frith, S. M., and Tourpali, K.:
SPARC/IOC/GAW report on Long-term Ozone Trends and Uncertainties in the Stratosphere, SPARC report No. 9, GAW Report No. 241, WCRP-17/2018, https://doi.org/10.17874/f899e57a20b, 2019. a, b, c, d, e, f
Petropavlovskikh, I., Miyagawa, K., McClure-Beegle, A., Johnson, B., Wild, J., Strahan, S., Wargan, K., Querel, R., Flynn, L., Beach, E., Ancellet, G., and Godin-Beekmann, S.:
Optimized Umkehr profile algorithm for ozone trend analyses, Atmos. Meas. Tech., 15, 1849–1870, https://doi.org/10.5194/amt-15-1849-2022, 2022. a, b, c, d, e, f, g
Randel, W., Stolarski, R., Cunnold, D., Logan, J., Newchurch, M., and Zawodny, J.:
Trends in the vertical distribution of ozone, Science, 285, 1689–1692, 1999. a
Reinsel, G. C., Tiao, G. C., DeLuisi, J. J., Basu, S., and Carriere, K.:
Trend analysis of aerosol-corrected Umkehr ozone profile data through 1987, J. Geophys. Res., 94, 16373–16386, https://doi.org/10.1029/jd094id13p16373, 1989. a
Reinsel, G. C., Weatherhead, E., Tiao, G. C., Miller, A. J., Nagatani, R. M., Wuebbles, D. J., and Flynn, L. E.:
On detection of turnaround and recovery in trend for ozone, J. Geophys. Res.-Atmos., 107, D104078, https://doi.org/10.1029/2001JD000500, 2002. a
Rodgers, C. D.:
Inverse Methods for Atmospheric Sounding – Theory and Practice, vol. 2 of Series on Atmospheric Oceanic and Planetary Physics, World Scientific Publishing Co. Pte. Ltd., Singapore, https://doi.org/10.1142/9789812813718, 2000. a
Schwartz, M., Froidevaux, L., Livesey, N. and Read, W.: MLS/Aura Level 2 Ozone (O3) Mixing Ratio V004, Greenbelt, MD, USA, Goddard Earth Sciences Data and Information Services Center (GES DISC) [data set], https://doi.org/10.5067/Aura/MLS/DATA2017, 2015. a
Serdyuchenko, A., Gorshelev, V., Weber, M., Chehade, W., and Burrows, J. P.:
High spectral resolution ozone absorption cross-sections – Part 2: Temperature dependence, Atmos. Meas. Tech., 7, 625–636, https://doi.org/10.5194/amt-7-625-2014, 2014. a
Smit, H. G., Straeter, W., Johnson, B. J., Oltmans, S. J., Davies, J., Tarasick, D. W., Hoegger, B., Stubi, R., Schmidlin, F. J., Northam, T., Thompson, A. M., Witte, J. C., Boyd, I., and Posny, F.:
Assessment of the performance of ECC-ozonesondes under quasi-flight conditions in the environmental simulation chamber: Insights from the Juelich Ozone Sonde Intercomparison Experiment (JOSIE), J. Geophys. Res.-Atmos., 112, D19306, https://doi.org/10.1029/2006JD007308, 2007. a
Sofieva, V. F., Szela̧g, M., Tamminen, J., Kyrölä, E., Degenstein, D., Roth, C., Zawada, D., Rozanov, A., Arosio, C., Burrows, J. P., Weber, M., Laeng, A., Stiller, G. P., von Clarmann, T., Froidevaux, L., Livesey, N., van Roozendael, M., and Retscher, C.:
Measurement report: regional trends of stratospheric ozone evaluated using the MErged GRIdded Dataset of Ozone Profiles (MEGRIDOP), Atmos. Chem. Phys., 21, 6707–6720, https://doi.org/10.5194/acp-21-6707-2021, 2021. a
Staehelin, J., Harris, N. R. P., Appenzeller, C., and Eberhard, J.:
Ozone trends: a review, Rev. Geophys., 39, 231–290, 2001. a
Staehelin, J., Kerr, J., Evans, R., and Vanicek, K.:
Comparison of total ozone measurements of Dobson and Brewer spectrophotometers and recommended transfer functions, WMO, https://library.wmo.int/doc_num.php?explnum_id=9226 (last access: 28 October 2022), 2003. a
Staehelin, J., Viatte, P., Stübi, R., Tummon, F., and Peter, T.:
Stratospheric ozone measurements at Arosa (Switzerland): history and scientific relevance, Atmos. Chem. Phys., 18, 6567–6584, https://doi.org/10.5194/acp-18-6567-2018, 2018. a
Steinbrecht, W., Froidevaux, L., Fuller, R., Wang, R., Anderson, J., Roth, C., Bourassa, A., Degenstein, D., Damadeo, R., Zawodny, J., Frith, S., McPeters, R., Bhartia, P., Wild, J., Long, C., Davis, S., Rosenlof, K., Sofieva, V., Walker, K., Rahpoe, N., Rozanov, A., Weber, M., Laeng, A., von Clarmann, T., Stiller, G., Kramarova, N., Godin-Beekmann, S., Leblanc, T., Querel, R., Swart, D., Boyd, I., Hocke, K., Kämpfer, N., Maillard Barras, E., Moreira, L., Nedoluha, G., Vigouroux, C., Blumenstock, T., Schneider, M., García, O., Jones, N., Mahieu, E., Smale, D., Kotkamp, M., Robinson, J., Petropavlovskikh, I., Harris, N., Hassler, B., Hubert, D., and Tummon, F.:
An update on ozone profile trends for the period 2000 to 2016, Atmos. Chem. Phys., 17, 10675–10690, https://doi.org/10.5194/acp-17-10675-2017, 2017. a
Stone, K., Tully, M. B., Rhodes, S. K., and Schofield, R.:
A new Dobson Umkehr ozone profile retrieval method optimising information content and resolution, Atmos. Meas. Tech., 8, 1043–1053, https://doi.org/10.5194/amt-8-1043-2015, 2015. a, b, c
Stübi, R., Schill, H., Klausen, J., Vuilleumier, L., Gröbner, J., Egli, L., and Ruffieux, D.:
On the compatibility of Brewer total column ozone measurements in two adjacent valleys (Arosa and Davos) in the Swiss Alps, Atmos. Meas. Tech., 10, 4479–4490, https://doi.org/10.5194/amt-10-4479-2017, 2017a. a, b, c, d
Stübi, R., Schill, H., Klausen, J., Vuilleumier, L., and Ruffieux, D.:
Reproducibility of total ozone column monitoring by the Arosa Brewer spectrophotometer triad, J. Geophys. Res.-Atmos., 122, 4735–4745, https://doi.org/10.1002/2016JD025735, 2017b. a
Stübi, R., Schill, H., Klausen, J., Maillard Barras, E., and Haefele, A.:
A fully automated Dobson sun spectrophotometer for total column ozone and Umkehr measurements, Atmos. Meas. Tech., 14, 5757–5769, https://doi.org/10.5194/amt-14-5757-2021, 2021a. a, b
Tarasick, D., Galbally, I. E., Cooper, O. R., Schultz, M. G., Ancellet, G., Leblanc, T., Wallington, T. J., Ziemke, J., Liu, X., Steinbacher, M., Staehelin, J., Vigouroux, C., Hannigan, J. W., García, O., Foret, G., Zanis, P., Weatherhead, E., Petropavlovskikh, I., Worden, H., Osman, M., Liu, J., Chang, K. L., Gaudel, A., Lin, M., Granados-Muñoz, M., Thompson, A. M., Oltmans, S. J., Cuesta, J., Dufour, G., Thouret, V., Hassler, B., Trickl, T., and Neu, J. L.:
Tropospheric ozone assessment report: Tropospheric ozone from 1877 to 2016, observed levels, trends and uncertainties, Elementa, 7, 1–56, https://doi.org/10.1525/elementa.376, 2019. a
Tummon, F., Hassler, B., Harris, N. R. P., Staehelin, J., Steinbrecht, W., Anderson, J., Bodeker, G. E., Bourassa, A., Davis, S. M., Degenstein, D., Frith, S. M., Froidevaux, L., Kyrölä, E., Laine, M., Long, C., Penckwitt, A. A., Sioris, C. E., Rosenlof, K. H., Roth, C., Wang, H.-J., and Wild, J.:
Intercomparison of vertically resolved merged satellite ozone data sets: interannual variability and long-term trends, Atmos. Chem. Phys., 15, 3021–3043, https://doi.org/10.5194/acp-15-3021-2015, 2015. a
Wargan, K., Orbe, C., Pawson, S., Ziemke, J. R., Oman, L. D., Olsen, M. A., Coy, L., and Emma Knowland, K.:
Recent Decline in Extratropical Lower Stratospheric Ozone Attributed to Circulation Changes, Geophys. Res. Lett., 45, 5166–5176, https://doi.org/10.1029/2018GL077406, 2018. a, b
Waters, J., Froidevaux, L., Harwood, R., Jarnot, R., Pickett, H., Read, W., Siegel, P., Cofield, R., Filipiak, M., Flower, D., Holden, J., Lau, G., Livesey, N., Manney, G., Pumphrey, H., Santee, M., Wu, D., Cuddy, D., Lay, R., Loo, M., Perun, V., Schwartz, M., Stek, P., Thurstans, R., Boyles, M., Chandra, K., Chavez, M., Gun-Shing Chen, Chudasama, B., Dodge, R., Fuller, R., Girard, M., Jiang, J., Yibo Jiang, Knosp, B., LaBelle, R., Lam, J., Lee, K., Miller, D., Oswald, J., Patel, N., Pukala, D., Quintero, O., Scaff, D., Van Snyder, W., Tope, M., Wagner, P., and Walch, M.:
The Earth observing system microwave limb sounder (EOS MLS) on the aura Satellite, IEEE T. Geosci. Remote, 44, 1075–1092, https://doi.org/10.1109/TGRS.2006.873771, 2006. a
WMO: SPARC/IOC/GAW Assessment of trends in the vertical distribution of ozone, Stratospheric Processes and Their Role in Climate, Global Ozone Research and Monitoring Project–Report No. 43, edited by: Harris, N., Hudson, R. and Phillips, C., 289 pp., Geneva, Switzerland, 1998. a
Zanis, P., Maillard, E., Staehelin, J., Zerefos, C., Kosmidis, E., Tourpali, K., and Wohltmann, I.:
On the turnaround of stratospheric ozone trends deduced from the reevaluated Umkehr record of Arosa, Switzerland, J. Geophys. Res. Atmos., 111, 1–15, https://doi.org/10.1029/2005JD006886, 2006. a, b
Short summary
Intercomparisons of three Dobson and three Brewer spectrophotometers at Arosa/Davos, Switzerland, are used for the homogenization of the longest Umkehr ozone profiles time series worldwide. Dynamic linear modeling (DLM) reveals a significant positive trend after 2004 in the upper stratosphere, a persistent negative trend between 25 and 30 km in the middle stratosphere, and a negative trend at 20 km in the lower stratosphere, with different levels of significance depending on the dataset.
Intercomparisons of three Dobson and three Brewer spectrophotometers at Arosa/Davos,...
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