Articles | Volume 22, issue 18
https://doi.org/10.5194/acp-22-12629-2022
https://doi.org/10.5194/acp-22-12629-2022
Research article
 | 
28 Sep 2022
Research article |  | 28 Sep 2022

Seasonal modeling analysis of nitrate formation pathways in Yangtze River Delta region, China

Jinjin Sun, Momei Qin, Xiaodong Xie, Wenxing Fu, Yang Qin, Li Sheng, Lin Li, Jingyi Li, Ishaq Dimeji Sulaymon, Lei Jiang, Lin Huang, Xingna Yu, and Jianlin Hu

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Cited articles

Alexander, B., Sherwen, T., Holmes, C. D., Fisher, J. A., Chen, Q., Evans, M. J., and Kasibhatla, P.: Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations, Atmos. Chem. Phys., 20, 3859–3877, https://doi.org/10.5194/acp-20-3859-2020, 2020. 
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Chan, Y.-C., Evans, M. J., He, P., Holmes, C. D., Jaeglé, L., Kasibhatla, P., Liu, X.-Y., Sherwen, T., Thornton, J. A., Wang, X., Xie, Z., Zhai, S., and Alexander, B.: Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain, J. Geophys. Res.-Atmos., 126, e2021JD034688, https://doi.org/10.1029/2021JD034688, 2021. 
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Short summary
NO3- has become the dominant and the least reduced chemical component of fine particulate matter in China. NO3- formation is mostly in the NH3-rich regime in the Yangtze River Delta (YRD). OH + NO2 contributes 60 %–83 % of the TNO3 production rates, and the N2O5 heterogeneous pathway contributes 10 %–36 %. The N2O5 heterogeneous pathway becomes more important in cold seasons. Local emissions and regional transportation contribute 50 %–62 % and 38 %–50 % to YRD NO3- concentrations, respectively.
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