Articles | Volume 21, issue 20
Atmos. Chem. Phys., 21, 15725–15753, 2021
https://doi.org/10.5194/acp-21-15725-2021
Atmos. Chem. Phys., 21, 15725–15753, 2021
https://doi.org/10.5194/acp-21-15725-2021

Technical note 21 Oct 2021

Technical note | 21 Oct 2021

Technical note: Adsorption and desorption equilibria from statistical thermodynamics and rates from transition state theory

Daniel A. Knopf and Markus Ammann

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Interactive discussion

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on acp-2021-451', Anonymous Referee #1, 09 Jul 2021
  • RC2: 'Comment on acp-2021-451', Anonymous Referee #2, 19 Jul 2021

Peer review completion

AR: Author's response | RR: Referee report | ED: Editor decision
AR by Daniel Knopf on behalf of the Authors (21 Aug 2021)  Author's response    Author's tracked changes    Manuscript
ED: Referee Nomination & Report Request started (23 Aug 2021) by Andreas Hofzumahaus
RR by Anonymous Referee #1 (29 Aug 2021)
ED: Publish as is (06 Sep 2021) by Andreas Hofzumahaus
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Short summary
Adsorption on and desorption of gas molecules from solid or liquid surfaces or interfaces represent the initial interaction of gas-to-condensed-phase processes that can define the physicochemical evolution of the condensed phase. We apply a thermodynamic and microscopic treatment of these multiphase processes to evaluate how adsorption and desorption rates and surface accommodation depend on the choice of adsorption model and standard states with implications for desorption energy and lifetimes.
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