Articles | Volume 21, issue 20
https://doi.org/10.5194/acp-21-15725-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-15725-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note: Adsorption and desorption equilibria from statistical thermodynamics and rates from transition state theory
Daniel A. Knopf
CORRESPONDING AUTHOR
School of Marine and Atmospheric Sciences, Stony Brook University, Stony Brook, New York, USA
Laboratory of Environmental Chemistry, Paul Scherrer Institute, Villigen, Switzerland
Viewed
Total article views: 9,549 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 08 Jun 2021)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 5,724 | 3,712 | 113 | 9,549 | 1,270 | 128 | 182 |
- HTML: 5,724
- PDF: 3,712
- XML: 113
- Total: 9,549
- Supplement: 1,270
- BibTeX: 128
- EndNote: 182
Total article views: 7,265 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 21 Oct 2021)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 5,174 | 1,996 | 95 | 7,265 | 506 | 120 | 170 |
- HTML: 5,174
- PDF: 1,996
- XML: 95
- Total: 7,265
- Supplement: 506
- BibTeX: 120
- EndNote: 170
Total article views: 2,284 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 08 Jun 2021)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 550 | 1,716 | 18 | 2,284 | 764 | 8 | 12 |
- HTML: 550
- PDF: 1,716
- XML: 18
- Total: 2,284
- Supplement: 764
- BibTeX: 8
- EndNote: 12
Viewed (geographical distribution)
Total article views: 9,549 (including HTML, PDF, and XML)
Thereof 9,337 with geography defined
and 212 with unknown origin.
Total article views: 7,265 (including HTML, PDF, and XML)
Thereof 7,066 with geography defined
and 199 with unknown origin.
Total article views: 2,284 (including HTML, PDF, and XML)
Thereof 2,271 with geography defined
and 13 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
42 citations as recorded by crossref.
- NH3 capture and detection by metal-decorated germanene: a DFT study A. Sosa et al.
- Computational design of 2D BC6Si for efficient hydrogen storage: insights into strong adsorption, high storage capacity, and desorption kinetics via DFT and AIMD M. Achqraoui et al.
- Towards a fast and stable tachypnea monitor: a C60-Lys enabled optical fiber sensor for humidity tracking in breath progress F. Wang et al.
- Engineering protein-based fiber-reinforced pneumatic actuators S. Edward et al.
- Effects of vacancies and doping on the sensitivity of arsenene/graphene heterostructure toward NH3 S. Ye et al.
- Computational Study of Solvent Incorporation into a Porphyrin Monolayer K. Hipps & U. Mazur
- DFT investigation of NH3 trapping and sensing by metal-decorated SnC nanosheets K. García-Caraveo et al.
- Ethanol properties effects on its reaction with Mo-doped SnO2 clusters: A gas sensor model M. Abdulsattar et al.
- An ontology-driven framework for digital transformation and performance assessment of building materials J. Kaltenegger et al.
- Adsorption of CO, NO, and SO2 on hexagonal BaO monolayer: Insights from DFT supported by machine learning H. Van Ngoc & M. Hao
- Thermodynamically consistent incorporation of the Langmuir adsorption model into compressible fluctuating hydrodynamics H. Jung et al.
- Eugenol@natural Zeolite vs. Citral@natural Zeolite Nanohybrids for Gelatin-Based Edible-Active Packaging Films A. Kechagias et al.
- Characterization and evaluation of immobilized bimetallic and trimetallic nanoparticles fabricated using grape leaf extract and glass waste for cefixime removal T. Merjan & Z. Abd Ali
- Unravelling the Epitaxial Growth Mechanism of Hexagonal and Nanoporous Boron Nitride: A First‐Principles Microkinetic Model A. Payne et al.
- Design of Pt-C3N2 composites for efficient real-time monitoring of fluorocarbon insulation gas decomposition and its application in GIS equipment T. Wang et al.
- Eugenol@Montmorillonite vs. Citral@Montmorillonite Nanohybrids for Gelatin-Based Extruded, Edible, High Oxygen Barrier, Active Packaging Films A. Kechagias et al.
- First-principles insights into structural, electronic, optical, thermal, and hydrogen storage properties of double perovskite hydrides Cs2BGaH6 (B K/Rb) N. Israr et al.
- Realizing fast response speed and enhanced selectivity for ethanol gas sensors with Au modified NiO/ZnO heterostructures Y. Wan et al.
- Selective sensing of DNA/RNA nucleobases by metal-functionalized silicon nanowires: A DFT approach J. Santana et al.
- Laponite vs. Montmorillonite as Eugenol Nanocarriers for Low Density Polyethylene Active Packaging Films A. Kechagias et al.
- Geomechanical integrity and geochemical reactions of shale caprocks for hydrogen storage: A comprehensive review A. Fatah & A. Al-Yaseri
- Structure regulation of PDMS coating on PTFE membrane surface to achieve efficient separation of gaseous peppermint aromatic water Q. Liu et al.
- Silver nanowire-tungsten oxide hybrids: Rapid-kinetic amine sensor for food freshness monitoring J. Liang et al.
- Controlling NO2 adsorption on defective graphene through strain: A DFT study M. Yin et al.
- Diversity-induced resonance at surfactant-laden interfaces S. Scialla
- First-principles studies of the SCl2 adsorption on the doped boron phosphide monolayer A. Sosa et al.
- Derivation of an Adsorption Isotherm, Chemical Potential, and Entropy for 2D Gas Adsorbates with Packing Exclusions and Attractive Interactions A. Savara
- HOSO2 Released from Mineral Dust: A Novel Channel of Heterogeneous Oxidation of Sulfur Dioxide during Dust Storms K. Chen et al.
- First-Principles Microkinetic Modeling Unravelling the Performance of Edge-Decorated Nanocarbons for Hydrogen Production from Methane N. Xavier et al.
- DNA/RNA nucleobases sensing by silicon nanowires: A DFT study K. García et al.
- Synergistic Recovery of Dysprosium(III) from Water via an Emulsion Liquid Membrane at Low Concentrations of Cyanex 272–D2EHPA: Impact of Process Factors and Water Sources A. Taamallah & O. Hamdaoui
- Recyclable tannic acid modified magnetic nanoparticles for ciprofloxacin adsorption M. Hamelian et al.
- Rationally Designed Recyclable Alginate Composite Hydrogel Beads to Remove Cationic and Anionic Dyes From Synthetic Wastewater A. Ali et al.
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al.
- Theoretical insights into the methane catalytic decomposition on graphene nanoribbons edges N. Xavier et al.
- Use of different food wastes as green biosorbent: isotherm, kinetic, and thermodynamic studies of Pb2+ T. Bahadir et al.
- Novel Carvacrol@activated Carbon Nanohybrid for Innovative Poly(lactide Acid)/Triethyl Citrate Based Sustainable Active Packaging Films V. Karabagias et al.
- Adsorption and desorption of acetone by TiO2 clusters: Transition state theory and sensing analysis M. Abdulsattar et al.
- Catalytic Reactor-Utilized Ammonia Adsorption, Absorption, and Storage Materials: Mechanism, Nanostructure, and Ab Initio Design A. Zamljen & B. Likozar
- Spin-state effect on the efficiency of a post-synthetic modification reaction on a spin crossover complex A. Enríquez-Cabrera et al.
- Tailoring Pt-loaded MoS2/SnO2 heterostructures for high-sensitivity room-temperature ammonia detection: a DFT and COMSOL analysis R. Al Nahean et al.
- Elucidating gas–surface interactions relevant to atmospheric particle growth using combined temperature programmed desorption and temperature-dependent uptake K. Johnson et al.
42 citations as recorded by crossref.
- NH3 capture and detection by metal-decorated germanene: a DFT study A. Sosa et al.
- Computational design of 2D BC6Si for efficient hydrogen storage: insights into strong adsorption, high storage capacity, and desorption kinetics via DFT and AIMD M. Achqraoui et al.
- Towards a fast and stable tachypnea monitor: a C60-Lys enabled optical fiber sensor for humidity tracking in breath progress F. Wang et al.
- Engineering protein-based fiber-reinforced pneumatic actuators S. Edward et al.
- Effects of vacancies and doping on the sensitivity of arsenene/graphene heterostructure toward NH3 S. Ye et al.
- Computational Study of Solvent Incorporation into a Porphyrin Monolayer K. Hipps & U. Mazur
- DFT investigation of NH3 trapping and sensing by metal-decorated SnC nanosheets K. García-Caraveo et al.
- Ethanol properties effects on its reaction with Mo-doped SnO2 clusters: A gas sensor model M. Abdulsattar et al.
- An ontology-driven framework for digital transformation and performance assessment of building materials J. Kaltenegger et al.
- Adsorption of CO, NO, and SO2 on hexagonal BaO monolayer: Insights from DFT supported by machine learning H. Van Ngoc & M. Hao
- Thermodynamically consistent incorporation of the Langmuir adsorption model into compressible fluctuating hydrodynamics H. Jung et al.
- Eugenol@natural Zeolite vs. Citral@natural Zeolite Nanohybrids for Gelatin-Based Edible-Active Packaging Films A. Kechagias et al.
- Characterization and evaluation of immobilized bimetallic and trimetallic nanoparticles fabricated using grape leaf extract and glass waste for cefixime removal T. Merjan & Z. Abd Ali
- Unravelling the Epitaxial Growth Mechanism of Hexagonal and Nanoporous Boron Nitride: A First‐Principles Microkinetic Model A. Payne et al.
- Design of Pt-C3N2 composites for efficient real-time monitoring of fluorocarbon insulation gas decomposition and its application in GIS equipment T. Wang et al.
- Eugenol@Montmorillonite vs. Citral@Montmorillonite Nanohybrids for Gelatin-Based Extruded, Edible, High Oxygen Barrier, Active Packaging Films A. Kechagias et al.
- First-principles insights into structural, electronic, optical, thermal, and hydrogen storage properties of double perovskite hydrides Cs2BGaH6 (B K/Rb) N. Israr et al.
- Realizing fast response speed and enhanced selectivity for ethanol gas sensors with Au modified NiO/ZnO heterostructures Y. Wan et al.
- Selective sensing of DNA/RNA nucleobases by metal-functionalized silicon nanowires: A DFT approach J. Santana et al.
- Laponite vs. Montmorillonite as Eugenol Nanocarriers for Low Density Polyethylene Active Packaging Films A. Kechagias et al.
- Geomechanical integrity and geochemical reactions of shale caprocks for hydrogen storage: A comprehensive review A. Fatah & A. Al-Yaseri
- Structure regulation of PDMS coating on PTFE membrane surface to achieve efficient separation of gaseous peppermint aromatic water Q. Liu et al.
- Silver nanowire-tungsten oxide hybrids: Rapid-kinetic amine sensor for food freshness monitoring J. Liang et al.
- Controlling NO2 adsorption on defective graphene through strain: A DFT study M. Yin et al.
- Diversity-induced resonance at surfactant-laden interfaces S. Scialla
- First-principles studies of the SCl2 adsorption on the doped boron phosphide monolayer A. Sosa et al.
- Derivation of an Adsorption Isotherm, Chemical Potential, and Entropy for 2D Gas Adsorbates with Packing Exclusions and Attractive Interactions A. Savara
- HOSO2 Released from Mineral Dust: A Novel Channel of Heterogeneous Oxidation of Sulfur Dioxide during Dust Storms K. Chen et al.
- First-Principles Microkinetic Modeling Unravelling the Performance of Edge-Decorated Nanocarbons for Hydrogen Production from Methane N. Xavier et al.
- DNA/RNA nucleobases sensing by silicon nanowires: A DFT study K. García et al.
- Synergistic Recovery of Dysprosium(III) from Water via an Emulsion Liquid Membrane at Low Concentrations of Cyanex 272–D2EHPA: Impact of Process Factors and Water Sources A. Taamallah & O. Hamdaoui
- Recyclable tannic acid modified magnetic nanoparticles for ciprofloxacin adsorption M. Hamelian et al.
- Rationally Designed Recyclable Alginate Composite Hydrogel Beads to Remove Cationic and Anionic Dyes From Synthetic Wastewater A. Ali et al.
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al.
- Theoretical insights into the methane catalytic decomposition on graphene nanoribbons edges N. Xavier et al.
- Use of different food wastes as green biosorbent: isotherm, kinetic, and thermodynamic studies of Pb2+ T. Bahadir et al.
- Novel Carvacrol@activated Carbon Nanohybrid for Innovative Poly(lactide Acid)/Triethyl Citrate Based Sustainable Active Packaging Films V. Karabagias et al.
- Adsorption and desorption of acetone by TiO2 clusters: Transition state theory and sensing analysis M. Abdulsattar et al.
- Catalytic Reactor-Utilized Ammonia Adsorption, Absorption, and Storage Materials: Mechanism, Nanostructure, and Ab Initio Design A. Zamljen & B. Likozar
- Spin-state effect on the efficiency of a post-synthetic modification reaction on a spin crossover complex A. Enríquez-Cabrera et al.
- Tailoring Pt-loaded MoS2/SnO2 heterostructures for high-sensitivity room-temperature ammonia detection: a DFT and COMSOL analysis R. Al Nahean et al.
- Elucidating gas–surface interactions relevant to atmospheric particle growth using combined temperature programmed desorption and temperature-dependent uptake K. Johnson et al.
Saved (final revised paper)
Latest update: 28 Apr 2026
Short summary
Adsorption on and desorption of gas molecules from solid or liquid surfaces or interfaces represent the initial interaction of gas-to-condensed-phase processes that can define the physicochemical evolution of the condensed phase. We apply a thermodynamic and microscopic treatment of these multiphase processes to evaluate how adsorption and desorption rates and surface accommodation depend on the choice of adsorption model and standard states with implications for desorption energy and lifetimes.
Adsorption on and desorption of gas molecules from solid or liquid surfaces or interfaces...
Altmetrics
Final-revised paper
Preprint