Articles | Volume 21, issue 20
https://doi.org/10.5194/acp-21-15725-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-15725-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note
| 
21 Oct 2021
Technical note |
| 21 Oct 2021
| 21 Oct 2021
Technical note: Adsorption and desorption equilibria from statistical thermodynamics and rates from transition state theory
Daniel A. Knopf
CORRESPONDING AUTHOR
School of Marine and Atmospheric Sciences, Stony Brook University, Stony Brook, New York, USA
Laboratory of Environmental Chemistry, Paul Scherrer Institute, Villigen, Switzerland
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17 citations as recorded by crossref.
- Selective sensing of DNA/RNA nucleobases by metal-functionalized silicon nanowires: A DFT approach J. Santana et al. 10.1016/j.surfin.2022.102529
- NH3 capture and detection by metal-decorated germanene: a DFT study A. Sosa et al. 10.1007/s10853-022-06955-w
- Laponite vs. Montmorillonite as Eugenol Nanocarriers for Low Density Polyethylene Active Packaging Films A. Kechagias et al. 10.3390/nano14231938
- Structure regulation of PDMS coating on PTFE membrane surface to achieve efficient separation of gaseous peppermint aromatic water Q. Liu et al. 10.1016/j.apsusc.2024.160354
- Towards a fast and stable tachypnea monitor: a C60-Lys enabled optical fiber sensor for humidity tracking in breath progress F. Wang et al. 10.3788/COL202422.021201
- Effects of vacancies and doping on the sensitivity of arsenene/graphene heterostructure toward NH3 S. Ye et al. 10.1088/1402-4896/acf006
- Computational Study of Solvent Incorporation into a Porphyrin Monolayer K. Hipps & U. Mazur 10.1021/acs.jpcc.3c07274
- Derivation of an Adsorption Isotherm, Chemical Potential, and Entropy for 2D Gas Adsorbates with Packing Exclusions and Attractive Interactions A. Savara 10.1021/acs.jpcc.3c00497
- HOSO2 Released from Mineral Dust: A Novel Channel of Heterogeneous Oxidation of Sulfur Dioxide during Dust Storms K. Chen et al. 10.1021/acsearthspacechem.4c00189
- Ethanol properties effects on its reaction with Mo-doped SnO2 clusters: A gas sensor model M. Abdulsattar et al. 10.1016/j.rsurfi.2024.100291
- First-Principles Microkinetic Modeling Unravelling the Performance of Edge-Decorated Nanocarbons for Hydrogen Production from Methane N. Xavier et al. 10.1021/acsami.2c20937
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Theoretical insights into the methane catalytic decomposition on graphene nanoribbons edges N. Xavier et al. 10.3389/fchem.2023.1172687
- Use of different food wastes as green biosorbent: isotherm, kinetic, and thermodynamic studies of Pb2+ T. Bahadir et al. 10.1007/s11356-023-29745-6
- Adsorption and desorption of acetone by TiO2 clusters: Transition state theory and sensing analysis M. Abdulsattar et al. 10.1016/j.chphma.2023.05.001
- Catalytic Reactor-Utilized Ammonia Adsorption, Absorption, and Storage Materials: Mechanism, Nanostructure, and Ab Initio Design A. Zamljen & B. Likozar 10.1021/acssuschemeng.4c06100
- Elucidating gas–surface interactions relevant to atmospheric particle growth using combined temperature programmed desorption and temperature-dependent uptake K. Johnson et al. 10.1039/D4CP02528H
Latest update: 24 Dec 2024
Short summary
Adsorption on and desorption of gas molecules from solid or liquid surfaces or interfaces represent the initial interaction of gas-to-condensed-phase processes that can define the physicochemical evolution of the condensed phase. We apply a thermodynamic and microscopic treatment of these multiphase processes to evaluate how adsorption and desorption rates and surface accommodation depend on the choice of adsorption model and standard states with implications for desorption energy and lifetimes.
Adsorption on and desorption of gas molecules from solid or liquid surfaces or interfaces...
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