Articles | Volume 16, issue 5
Atmos. Chem. Phys., 16, 3245–3264, 2016
https://doi.org/10.5194/acp-16-3245-2016
Atmos. Chem. Phys., 16, 3245–3264, 2016
https://doi.org/10.5194/acp-16-3245-2016
Research article
 | Highlight paper
11 Mar 2016
Research article  | Highlight paper | 11 Mar 2016

Phase, composition, and growth mechanism for secondary organic aerosol from the ozonolysis of α-cedrene

Yue Zhao et al.

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Cited articles

Abramson, E., Imre, D., Beranek, J., Wilson, J., and Zelenyuk, A.: Experimental determination of chemical diffusion within secondary organic aerosol particles, Phys. Chem. Chem. Phys., 15, 2983–2991, https://doi.org/10.1039/C2cp44013j, 2013.
Alfarra, M. R., Hamilton, J. F., Wyche, K. P., Good, N., Ward, M. W., Carr, T., Barley, M. H., Monks, P. S., Jenkin, M. E., Lewis, A. C., and McFiggans, G. B.: The effect of photochemical ageing and initial precursor concentration on the composition and hygroscopic properties of β-caryophyllene secondary organic aerosol, Atmos. Chem. Phys., 12, 6417–6436, https://doi.org/10.5194/acp-12-6417-2012, 2012.
Anglada, J. M., Gonzalez, J., and Torrent-Sucarrat, M.: Effects of the substituents on the reactivity of carbonyl oxides. A theoretical study on the reaction of substituted carbonyl oxides with water, Phys. Chem. Chem. Phys., 13, 13034–13045, https://doi.org/10.1039/c1cp20872a, 2011.
Bateman, A. P., Bertram, A. K., and Martin, S. T.: Hygroscopic Influence on the Semisolid-to-Liquid Transition of Secondary Organic Materials, J. Phys. Chem. A, 119, 4386–4395, https://doi.org/10.1021/jp508521c, 2015.
Berndt, T., Kaethner, R., Voigtlander, J., Stratmann, F., Pfeifle, M., Reichle, P., Sipila, M., Kulmala, M., and Olzmann, M.: Kinetics of the unimolecular reaction of CH2OO and the bimolecular reactions with the water monomer, acetaldehyde and acetone under atmospheric conditions, Phys. Chem. Chem. Phys., 17, 19862–19873, https://doi.org/10.1039/c5cp02224j, 2015.
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Short summary
A significant fraction of airborne particles, which have significant impacts on human health, visibility, and climate, are formed from the oxidation of gaseous precursors to generate low-volatility products. We show here that a sesquiterpene, α-cedrene, efficiently forms high-viscosity semisolid particles with complex composition via mechanisms that involve the highly reactive Criegee intermediate and that high molecular weight products play an important role in new particle formation.
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