Articles | Volume 16, issue 5
https://doi.org/10.5194/acp-16-3245-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-3245-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
11 Mar 2016
Research article | Highlight paper |
| 11 Mar 2016
Phase, composition, and growth mechanism for secondary organic aerosol from the ozonolysis of α-cedrene
Department of Chemistry, University of California,
Irvine, CA 92697, USA
Lisa M. Wingen
Department of Chemistry, University of California,
Irvine, CA 92697, USA
Véronique Perraud
Department of Chemistry, University of California,
Irvine, CA 92697, USA
Barbara J. Finlayson-Pitts
CORRESPONDING AUTHOR
Department of Chemistry, University of California,
Irvine, CA 92697, USA
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30 citations as recorded by crossref.
- An electrospray chemical ionization source for real-time measurement of atmospheric organic and inorganic vapors Y. Zhao et al. 10.5194/amt-10-3609-2017
- Probing surfaces of atmospherically relevant organic particles by easy ambient sonic-spray ionization mass spectrometry (EASI-MS) L. Wingen & B. Finlayson-Pitts 10.1039/C8SC03851A
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- Temperature-dependent kinetics of the atmospheric reaction between CH2OO and acetone P. Wang et al. 10.1039/D2CP01118B
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- Criegee Chemistry on Aqueous Organic Surfaces S. Enami & A. Colussi 10.1021/acs.jpclett.7b00434
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- New insights into atmospherically relevant reaction systems using direct analysis in real-time mass spectrometry (DART-MS) Y. Zhao et al. 10.5194/amt-10-1373-2017
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- Growth Kinetics and Size Distribution Dynamics of Viscous Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.7b04623
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Emulsified and Liquid–Liquid Phase-Separated States of α-Pinene Secondary Organic Aerosol Determined Using Aerosol Optical Tweezers K. Gorkowski et al. 10.1021/acs.est.7b03250
- Ozonolysis of α-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. 10.5194/acp-18-4673-2018
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al. 10.1016/j.jes.2022.06.021
- Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.9b05514
- Different roles of water in secondary organic aerosol formation from toluene and isoprene L. Jia & Y. Xu 10.5194/acp-18-8137-2018
- Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of β-caryophyllene S. Richters et al. 10.5194/acp-16-9831-2016
- Models of Isotopic Water Diffusion in Spherical Aerosol Particles A. Moridnejad & T. Preston 10.1021/acs.jpca.6b11241
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- A first comprehensive insight into the sesquiterpene oxidation and sequential HOMs formation in the marine atmosphere: A case study of α-Cedrene H. Wu et al. 10.1016/j.jece.2024.112098
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Enhanced Gas Uptake during α-Pinene Ozonolysis Points to a Burying Mechanism A. Vander Wall et al. 10.1021/acsearthspacechem.0c00163
- Easily fabricated ion source for characterizing mixtures of organic compounds by direct analysis in real time mass spectrometry K. Upton et al. 10.1039/C7AY00971B
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- Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry Y. Zhao et al. 10.1073/pnas.1812147115
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
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Saved (preprint)
Latest update: 30 Jun 2025
Short summary
A significant fraction of airborne particles, which have significant impacts on human health, visibility, and climate, are formed from the oxidation of gaseous precursors to generate low-volatility products. We show here that a sesquiterpene, α-cedrene, efficiently forms high-viscosity semisolid particles with complex composition via mechanisms that involve the highly reactive Criegee intermediate and that high molecular weight products play an important role in new particle formation.
A significant fraction of airborne particles, which have significant impacts on human health,...
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