Research article
| Highlight paper
11 Mar 2016
Research article
| Highlight paper
| 11 Mar 2016
Phase, composition, and growth mechanism for secondary organic aerosol from the ozonolysis of α-cedrene
Yue Zhao et al.
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Cited
23 citations as recorded by crossref.
- Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.9b05514
- Different roles of water in secondary organic aerosol formation from toluene and isoprene L. Jia & Y. Xu 10.5194/acp-18-8137-2018
- An electrospray chemical ionization source for real-time measurement of atmospheric organic and inorganic vapors Y. Zhao et al. 10.5194/amt-10-3609-2017
- Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of <i>β</i>-caryophyllene S. Richters et al. 10.5194/acp-16-9831-2016
- Models of Isotopic Water Diffusion in Spherical Aerosol Particles A. Moridnejad & T. Preston 10.1021/acs.jpca.6b11241
- Probing surfaces of atmospherically relevant organic particles by easy ambient sonic-spray ionization mass spectrometry (EASI-MS) L. Wingen & B. Finlayson-Pitts 10.1039/C8SC03851A
- Diurnal variation and size dependence of the hygroscopicity of organic aerosol at a forest site in Wakayama, Japan: their relationship to CCN concentrations Y. Deng et al. 10.5194/acp-19-5889-2019
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- Criegee Chemistry on Aqueous Organic Surfaces S. Enami & A. Colussi 10.1021/acs.jpclett.7b00434
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- New insights into atmospherically relevant reaction systems using direct analysis in real-time mass spectrometry (DART-MS) Y. Zhao et al. 10.5194/amt-10-1373-2017
- Aerosol Chemistry Resolved by Mass Spectrometry: Insights into Particle Growth after Ambient New Particle Formation A. Vogel et al. 10.1021/acs.est.6b01673
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Growth Kinetics and Size Distribution Dynamics of Viscous Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.7b04623
- Enhanced Gas Uptake during α-Pinene Ozonolysis Points to a Burying Mechanism A. Vander Wall et al. 10.1021/acsearthspacechem.0c00163
- Easily fabricated ion source for characterizing mixtures of organic compounds by direct analysis in real time mass spectrometry K. Upton et al. 10.1039/C7AY00971B
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
- Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry Y. Zhao et al. 10.1073/pnas.1812147115
- Emulsified and Liquid–Liquid Phase-Separated States of α-Pinene Secondary Organic Aerosol Determined Using Aerosol Optical Tweezers K. Gorkowski et al. 10.1021/acs.est.7b03250
- Ozonolysis of <i>α</i>-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. 10.5194/acp-18-4673-2018
- Nontargeted Tandem Mass Spectrometry Analysis Reveals Diversity and Variability in Aerosol Functional Groups across Multiple Sites, Seasons, and Times of Day J. Ditto et al. 10.1021/acs.estlett.9b00702
- The influence of UV-light irradiation and stable Criegee intermediate scavengers on secondary organic aerosol formation from isoprene ozonolysis M. Song et al. 10.1016/j.atmosenv.2018.08.014
22 citations as recorded by crossref.
- Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.9b05514
- Different roles of water in secondary organic aerosol formation from toluene and isoprene L. Jia & Y. Xu 10.5194/acp-18-8137-2018
- An electrospray chemical ionization source for real-time measurement of atmospheric organic and inorganic vapors Y. Zhao et al. 10.5194/amt-10-3609-2017
- Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of <i>β</i>-caryophyllene S. Richters et al. 10.5194/acp-16-9831-2016
- Models of Isotopic Water Diffusion in Spherical Aerosol Particles A. Moridnejad & T. Preston 10.1021/acs.jpca.6b11241
- Probing surfaces of atmospherically relevant organic particles by easy ambient sonic-spray ionization mass spectrometry (EASI-MS) L. Wingen & B. Finlayson-Pitts 10.1039/C8SC03851A
- Diurnal variation and size dependence of the hygroscopicity of organic aerosol at a forest site in Wakayama, Japan: their relationship to CCN concentrations Y. Deng et al. 10.5194/acp-19-5889-2019
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- Criegee Chemistry on Aqueous Organic Surfaces S. Enami & A. Colussi 10.1021/acs.jpclett.7b00434
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- New insights into atmospherically relevant reaction systems using direct analysis in real-time mass spectrometry (DART-MS) Y. Zhao et al. 10.5194/amt-10-1373-2017
- Aerosol Chemistry Resolved by Mass Spectrometry: Insights into Particle Growth after Ambient New Particle Formation A. Vogel et al. 10.1021/acs.est.6b01673
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Growth Kinetics and Size Distribution Dynamics of Viscous Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.7b04623
- Enhanced Gas Uptake during α-Pinene Ozonolysis Points to a Burying Mechanism A. Vander Wall et al. 10.1021/acsearthspacechem.0c00163
- Easily fabricated ion source for characterizing mixtures of organic compounds by direct analysis in real time mass spectrometry K. Upton et al. 10.1039/C7AY00971B
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
- Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry Y. Zhao et al. 10.1073/pnas.1812147115
- Emulsified and Liquid–Liquid Phase-Separated States of α-Pinene Secondary Organic Aerosol Determined Using Aerosol Optical Tweezers K. Gorkowski et al. 10.1021/acs.est.7b03250
- Ozonolysis of <i>α</i>-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. 10.5194/acp-18-4673-2018
- Nontargeted Tandem Mass Spectrometry Analysis Reveals Diversity and Variability in Aerosol Functional Groups across Multiple Sites, Seasons, and Times of Day J. Ditto et al. 10.1021/acs.estlett.9b00702
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Latest update: 29 Jan 2023
Short summary
A significant fraction of airborne particles, which have significant impacts on human health, visibility, and climate, are formed from the oxidation of gaseous precursors to generate low-volatility products. We show here that a sesquiterpene, α-cedrene, efficiently forms high-viscosity semisolid particles with complex composition via mechanisms that involve the highly reactive Criegee intermediate and that high molecular weight products play an important role in new particle formation.
A significant fraction of airborne particles, which have significant impacts on human health,...
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