Articles | Volume 14, issue 21
https://doi.org/10.5194/acp-14-11843-2014
https://doi.org/10.5194/acp-14-11843-2014
Research article
 | 
12 Nov 2014
Research article |  | 12 Nov 2014

HO2NO2 and HNO3 in the coastal Antarctic winter night: a "lab-in-the-field" experiment

A. E. Jones, N. Brough, P. S. Anderson, and E. W. Wolff

Related authors

Simultaneous organic aerosol source apportionment at two Antarctic sites reveals large-scale and ecoregion-specific components
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
Atmos. Chem. Phys., 24, 6305–6322, https://doi.org/10.5194/acp-24-6305-2024,https://doi.org/10.5194/acp-24-6305-2024, 2024
Short summary
Multiple eco-regions contribute to the seasonal cycle of Antarctic aerosol size distributions
James Brean, David C. S. Beddows, Eija Asmi, Ari Virkkula, Lauriane L. J. Quéléver, Mikko Sipilä, Floortje Van Den Heuvel, Thomas Lachlan-Cope, Anna Jones, Markus Frey, Angelo Lupi, Jiyeon Park, Young Jun Yoon, Ralf Weller, Giselle L. Marincovich, Gabriela C. Mulena, Roy M. Harrison, and Manuel Dall´Osto
EGUsphere, https://doi.org/10.5194/egusphere-2024-987,https://doi.org/10.5194/egusphere-2024-987, 2024
Short summary
Aircraft-based mass balance estimate of methane emissions from offshore gas facilities in the southern North Sea
Magdalena Pühl, Anke Roiger, Alina Fiehn, Alan M. Gorchov Negron, Eric A. Kort, Stefan Schwietzke, Ignacio Pisso, Amy Foulds, James Lee, James L. France, Anna E. Jones, Dave Lowry, Rebecca E. Fisher, Langwen Huang, Jacob Shaw, Prudence Bateson, Stephen Andrews, Stuart Young, Pamela Dominutti, Tom Lachlan-Cope, Alexandra Weiss, and Grant Allen
Atmos. Chem. Phys., 24, 1005–1024, https://doi.org/10.5194/acp-24-1005-2024,https://doi.org/10.5194/acp-24-1005-2024, 2024
Short summary
Snowpack nitrate photolysis drives the summertime atmospheric nitrous acid (HONO) budget in coastal Antarctica
Amelia M. H. Bond, Markus M. Frey, Jan Kaiser, Jörg Kleffmann, Anna E. Jones, and Freya A. Squires
Atmos. Chem. Phys., 23, 5533–5550, https://doi.org/10.5194/acp-23-5533-2023,https://doi.org/10.5194/acp-23-5533-2023, 2023
Short summary
Two decades of flask observations of atmospheric δ(O2∕N2), CO2, and APO at stations Lutjewad (the Netherlands) and Mace Head (Ireland), and 3 years from Halley station (Antarctica)
Linh N. T. Nguyen, Harro A. J. Meijer, Charlotte van Leeuwen, Bert A. M. Kers, Hubertus A. Scheeren, Anna E. Jones, Neil Brough, Thomas Barningham, Penelope A. Pickers, Andrew C. Manning, and Ingrid T. Luijkx
Earth Syst. Sci. Data, 14, 991–1014, https://doi.org/10.5194/essd-14-991-2022,https://doi.org/10.5194/essd-14-991-2022, 2022
Short summary

Related subject area

Subject: Gases | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station–airport distance
Honglei Wang, David W. Tarasick, Jane Liu, Herman G. J. Smit, Roeland Van Malderen, Lijuan Shen, Romain Blot, and Tianliang Zhao
Atmos. Chem. Phys., 24, 11927–11942, https://doi.org/10.5194/acp-24-11927-2024,https://doi.org/10.5194/acp-24-11927-2024, 2024
Short summary
CO2 and CO temporal variability over Mexico City from ground-based total column and surface measurements
Noémie Taquet, Wolfgang Stremme, María Eugenia González del Castillo, Victor Almanza, Alejandro Bezanilla, Olivier Laurent, Carlos Alberti, Frank Hase, Michel Ramonet, Thomas Lauvaux, Ke Che, and Michel Grutter
Atmos. Chem. Phys., 24, 11823–11848, https://doi.org/10.5194/acp-24-11823-2024,https://doi.org/10.5194/acp-24-11823-2024, 2024
Short summary
Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization
Akima Ringsdorf, Achim Edtbauer, Bruna Holanda, Christopher Poehlker, Marta O. Sá, Alessandro Araújo, Jürgen Kesselmeier, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 24, 11883–11910, https://doi.org/10.5194/acp-24-11883-2024,https://doi.org/10.5194/acp-24-11883-2024, 2024
Short summary
Measurement report: In-flight and ground-based measurements of nitrogen oxide emissions from latest-generation jet engines and 100 % sustainable aviation fuel
Theresa Harlass, Rebecca Dischl, Stefan Kaufmann, Raphael Märkl, Daniel Sauer, Monika Scheibe, Paul Stock, Tiziana Bräuer, Andreas Dörnbrack, Anke Roiger, Hans Schlager, Ulrich Schumann, Magdalena Pühl, Tobias Schripp, Tobias Grein, Linda Bondorf, Charles Renard, Maxime Gauthier, Mark Johnson, Darren Luff, Paul Madden, Peter Swann, Denise Ahrens, Reetu Sallinen, and Christiane Voigt
Atmos. Chem. Phys., 24, 11807–11822, https://doi.org/10.5194/acp-24-11807-2024,https://doi.org/10.5194/acp-24-11807-2024, 2024
Short summary
Measurement report: Sources, sinks, and lifetime of NOx in a suburban temperate forest at night
Simone T. Andersen, Max R. McGillen, Chaoyang Xue, Tobias Seubert, Patrick Dewald, Gunther N. T. E. Türk, Jan Schuladen, Cyrielle Denjean, Jean-Claude Etienne, Olivier Garrouste, Marina Jamar, Sergio Harb, Manuela Cirtog, Vincent Michoud, Mathieu Cazaunau, Antonin Bergé, Christopher Cantrell, Sebastien Dusanter, Bénédicte Picquet-Varrault, Alexandre Kukui, Abdelwahid Mellouki, Lucy J. Carpenter, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 24, 11603–11618, https://doi.org/10.5194/acp-24-11603-2024,https://doi.org/10.5194/acp-24-11603-2024, 2024
Short summary

Cited articles

Bartels-Rausch, T., Eichler, B., Zimmermann, P., Gäggeler, H. W., and Ammann, M.: The adsorption of nitrogen oxides on crystalline ice, Atmos. Chem. Phys., 2, 235–247, https://doi.org/10.5194/acp-2-235-2002, 2002.
Bartels-Rausch, T.: Ice-air partitioning of HNO3 and HNO4 drives winter mixing ratio, Atmos. Chem. Phys. Discuss., 14, C4673–C4694, 014.
Bauguitte, S. J.-B., Bloss, W. J., Evans, M. J., Salmon, R. A., Anderson, P. S., Jones, A. E., Lee, J. D., Saiz-Lopez, A., Roscoe, H. K., Wolff, E. W., and Plane, J. M. C.: Summertime NOx measurements during the CHABLIS campaign: can source and sink estimates unravel observed diurnal cycles?, Atmos. Chem. Phys., 12, 989–1002, https://doi.org/10.5194/acp-12-989-2012, 2012.
Buys, Z., Brough, N., Huey, L. G., Tanner, D. J., von Glasow, R., and Jones, A. E.: High temporal resolution Br2, BrCl and BrO observations in coastal Antarctica, Atmos. Chem. Phys., 13, 1329–1343, https://doi.org/10.5194/acp-13-1329-2013, 2013.
Chen, G., Davis, D., Crawford, J., Nowak, J. B., Eisele, F., Mauldin, R. L., Tanner, D., Buhr, M., Shetter, R., Lefer, B., Arimoto, R., Hogan, A., and Blake, D.: An investigation of South Pole HOx chemistry: Comparison of model results with ISCAT observations, Geophys. Res. Lett., 28, 3633–3636, 2001.
Download
Short summary
We report observations of nitric acid and peroxynitric acid, in coastal Antarctica during winter. During winter, it is dark 24h per day, so there is no influence of sunlight on atmospheric composition. We show that observed variability in concentrations is highly correlated with changes in temperature. We derive enthalpies of adsorption and show they are consistent with those derived in laboratory studies. The Antarctic, during winter, is an ideal natural laboratory to study air-snow exchange.
Altmetrics
Final-revised paper
Preprint