Articles | Volume 9, issue 14
https://doi.org/10.5194/acp-9-5093-2009
© Author(s) 2009. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-9-5093-2009
© Author(s) 2009. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
28 Jul 2009
In-cloud processes of methacrolein under simulated conditions – Part 1: Aqueous phase photooxidation
Yao Liu
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264, Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
I. El Haddad
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264, Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
M. Scarfogliero
Laboratoire Interuniversitaire des Systèmes Atmosphériques (UMR 7583), Université Paris, France
L. Nieto-Gligorovski
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264, Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
B. Temime-Roussel
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264, Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
E. Quivet
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264, Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
N. Marchand
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264, Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
B. Picquet-Varrault
Laboratoire Interuniversitaire des Systèmes Atmosphériques (UMR 7583), Université Paris, France
A. Monod
Universités d'Aix-Marseille I, II et III – CNRS, UMR 6264, Laboratoire Chimie Provence, Equipe: IRA, 3 place Victor Hugo, 13331 Marseilles Cedex 3, France
Related subject area
Subject: Clouds and Precipitation | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Direct formation of HONO through aqueous-phase photolysis of organic nitrates
On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal
Effects of pH and light exposure on the survival of bacteria and their ability to biodegrade organic compounds in clouds: implications for microbial activity in acidic cloud water
Towards a chemical mechanism of the oxidation of aqueous sulfur dioxide via isoprene hydroxyl hydroperoxides (ISOPOOH)
On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation
Lignin's ability to nucleate ice via immersion freezing and its stability towards physicochemical treatments and atmospheric processing
Biodegradation of phenol and catechol in cloud water: comparison to chemical oxidation in the atmospheric multiphase system
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 2: Quartz and amorphous silica
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 3: Aluminosilicates
Aqueous reactions of organic triplet excited states with atmospheric alkenes
The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 1: The K-feldspar microcline
Direct molecular-level characterization of different heterogeneous freezing modes on mica – Part 1
Chemistry of riming: the retention of organic and inorganic atmospheric trace constituents
Surface-charge-induced orientation of interfacial water suppresses heterogeneous ice nucleation on α-alumina (0001)
Screening of cloud microorganisms isolated at the Puy de Dôme (France) station for the production of biosurfactants
Comparing contact and immersion freezing from continuous flow diffusion chambers
A better understanding of hydroxyl radical photochemical sources in cloud waters collected at the puy de Dôme station – experimental versus modelled formation rates
Deposition and immersion-mode nucleation of ice by three distinct samples of volcanic ash
Organic matter matters for ice nuclei of agricultural soil origin
Effect of atmospheric organic complexation on iron-bearing dust solubility
Are sesquiterpenes a good source of secondary organic cloud condensation nuclei (CCN)? Revisiting β-caryophyllene CCN
Ice nucleation efficiency of clay minerals in the immersion mode
Atmospheric chemistry of carboxylic acids: microbial implication versus photochemistry
Yields of hydrogen peroxide from the reaction of hydroxyl radical with organic compounds in solution and ice
In-cloud processes of methacrolein under simulated conditions – Part 2: Formation of secondary organic aerosol
Juan Miguel González-Sánchez, Miquel Huix-Rotllant, Nicolas Brun, Julien Morin, Carine Demelas, Amandine Durand, Sylvain Ravier, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 23, 15135–15147, https://doi.org/10.5194/acp-23-15135-2023, https://doi.org/10.5194/acp-23-15135-2023, 2023
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Organic nitrates play a crucial role in air pollution, as they are nitrogen oxide (NOx) reservoirs. This work investigated the reaction products and mechanisms of their reactivity with light in the aqueous phase (cloud and fog conditions and wet aerosol). Our findings reveal that this chemistry leads to the formation of atmospheric nitrous acid (HONO).
Juan Miguel González-Sánchez, Nicolas Brun, Junteng Wu, Sylvain Ravier, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 23, 5851–5866, https://doi.org/10.5194/acp-23-5851-2023, https://doi.org/10.5194/acp-23-5851-2023, 2023
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Organic nitrates play a crucial role in air pollution, as they are NOx reservoirs. This work investigated for the first time their reactivity with light in the aqueous phase (cloud and fog and wet aerosol), proving it slower than in the gas phase. Therefore, our findings reveal that partitioning of organic nitrates in the aqueous phase leads to longer atmospheric lifetimes of these compounds and thus a broader spatial distribution of their related pollution.
Yushuo Liu, Chee Kent Lim, Zhiyong Shen, Patrick K. H. Lee, and Theodora Nah
Atmos. Chem. Phys., 23, 1731–1747, https://doi.org/10.5194/acp-23-1731-2023, https://doi.org/10.5194/acp-23-1731-2023, 2023
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We investigated how cloud water pH and solar radiation impact the survival and energetic metabolism of two neutrophilic bacteria species and their biodegradation of organic acids. Experiments were performed using artificial cloud water that mimicked the pH and composition of cloud water in South China. We found that there is a minimum cloud water pH threshold at which neutrophilic bacteria will survive and biodegrade organic compounds in cloud water during the daytime and/or nighttime.
Eleni Dovrou, Kelvin H. Bates, Jean C. Rivera-Rios, Joshua L. Cox, Joshua D. Shutter, and Frank N. Keutsch
Atmos. Chem. Phys., 21, 8999–9008, https://doi.org/10.5194/acp-21-8999-2021, https://doi.org/10.5194/acp-21-8999-2021, 2021
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We examined the mechanism and products of oxidation of dissolved sulfur dioxide with the main isomers of isoprene hydroxyl hydroperoxides, via laboratory and model analysis. Two chemical mechanism pathways are proposed and the results provide an improved understanding of the broader atmospheric chemistry and role of multifunctional organic hydroperoxides, which should be the dominant VOC oxidation products under low-NO conditions, highlighting their significant contribution to sulfate formation.
Juan Miguel González-Sánchez, Nicolas Brun, Junteng Wu, Julien Morin, Brice Temime-Roussel, Sylvain Ravier, Camille Mouchel-Vallon, Jean-Louis Clément, and Anne Monod
Atmos. Chem. Phys., 21, 4915–4937, https://doi.org/10.5194/acp-21-4915-2021, https://doi.org/10.5194/acp-21-4915-2021, 2021
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Organic nitrates play a crucial role in air pollution as they are considered NOx reservoirs. This work lights up the importance of their reactions with OH radicals in the aqueous phase (cloud/fog, wet aerosol), which is slower than in the gas phase. For compounds that significantly partition in water such as polyfunctional biogenic nitrates, these aqueous-phase reactions should drive their atmospheric removal, leading to a broader spatial distribution of NOx than previously accounted for.
Sophie Bogler and Nadine Borduas-Dedekind
Atmos. Chem. Phys., 20, 14509–14522, https://doi.org/10.5194/acp-20-14509-2020, https://doi.org/10.5194/acp-20-14509-2020, 2020
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To study the role of organic matter in ice crystal formation, we investigated the ice nucleation ability of a subcomponent of organic aerosols, the biopolymer lignin, using a droplet-freezing technique. We found that lignin is an ice-active macromolecule with changing abilities based on dilutions. The effects of atmospheric processing and of physicochemical treatments on the ability of lignin solutions to freeze were negligible. Thus, lignin is a recalcitrant ice-nucleating macromolecule.
Saly Jaber, Audrey Lallement, Martine Sancelme, Martin Leremboure, Gilles Mailhot, Barbara Ervens, and Anne-Marie Delort
Atmos. Chem. Phys., 20, 4987–4997, https://doi.org/10.5194/acp-20-4987-2020, https://doi.org/10.5194/acp-20-4987-2020, 2020
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Current atmospheric multiphase models do not include biotransformations of organic compounds by bacteria, although many previous studies of our and other research groups have shown microbial activity in cloud water. The current lab/model study shows that for water-soluble aromatic compounds, biodegradation by bacteria may be as efficient as chemical reactions in cloud water.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6035–6058, https://doi.org/10.5194/acp-19-6035-2019, https://doi.org/10.5194/acp-19-6035-2019, 2019
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This paper not only interests the atmospheric science community but has a potential to cater to a broader audience. We discuss both long- and
short-term effects of various
atmospherically relevantchemical species on a fairly abundant mineral surface
Quartz. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6059–6084, https://doi.org/10.5194/acp-19-6059-2019, https://doi.org/10.5194/acp-19-6059-2019, 2019
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This paper not only interests the Atmospheric Science community but has a potential to cater to a broader audience. We discuss both long- and short-term effects of various
atmospherically relevantchemical species on fairly abundant mineral surfaces like feldspars and clays. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Richie Kaur, Brandi M. Hudson, Joseph Draper, Dean J. Tantillo, and Cort Anastasio
Atmos. Chem. Phys., 19, 5021–5032, https://doi.org/10.5194/acp-19-5021-2019, https://doi.org/10.5194/acp-19-5021-2019, 2019
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Organic triplets are an important class of aqueous photooxidants, but little is known about their reactions with most atmospheric organic compounds. We measured the reaction rate constants of a model triplet with 17 aliphatic alkenes; using their correlation with oxidation potential, we predicted rate constants for some atmospherically relevant alkenes. Depending on their reactivities, triplets can be minor to important sinks for isoprene- and limonene-derived alkenes in cloud or fog drops.
Julián Gelman Constantin, Melisa M. Gianetti, María P. Longinotti, and Horacio R. Corti
Atmos. Chem. Phys., 18, 14965–14978, https://doi.org/10.5194/acp-18-14965-2018, https://doi.org/10.5194/acp-18-14965-2018, 2018
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Numerous studies have shown that ice surface is actually coated by a thin layer of water even for temperatures below melting temperature. This quasi-liquid layer is relevant in the atmospheric chemistry of clouds, polar regions, glaciers, and other cold regions. We present new results of atomic force microscopy on pure ice, which suggests a thickness for this layer below 1 nm between -7 ºC and -2 ºC. We propose that in many cases previous authors have overestimated this thickness.
Anand Kumar, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 18, 7057–7079, https://doi.org/10.5194/acp-18-7057-2018, https://doi.org/10.5194/acp-18-7057-2018, 2018
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We have performed immersion freezing experiments with microcline (most active ice nucleation, IN, K-feldspar polymorph) and investigated the effect of ammonium and non-ammonium solutes on its IN efficiency. We report increased IN efficiency of microcline in dilute ammonia- or ammonium-containing solutions, which opens up a pathway for condensation freezing occurring at a warmer temperature than immersion freezing.
Ahmed Abdelmonem
Atmos. Chem. Phys., 17, 10733–10741, https://doi.org/10.5194/acp-17-10733-2017, https://doi.org/10.5194/acp-17-10733-2017, 2017
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On the basis of supercooled SHG spectroscopy, I report molecular-level evidence for the existence of one- and two-step deposition freezing depending on the surface type and the supersaturation conditions. In addition, immersion freezing shows a transient ice phase with a lifetime of c. 1 min. This study provides new insights into atmospheric processes and can impact various industrial and research branches, particularly climate change, weather modification, and tracing water in the hydrosphere.
Alexander Jost, Miklós Szakáll, Karoline Diehl, Subir K. Mitra, and Stephan Borrmann
Atmos. Chem. Phys., 17, 9717–9732, https://doi.org/10.5194/acp-17-9717-2017, https://doi.org/10.5194/acp-17-9717-2017, 2017
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During riming of graupel and hail, soluble chemical trace constituents contained in the liquid droplets could be retained while freezing onto the glaciated particle, or released back to the air potentially at other altitudes as retained. Quantification of retention constitutes a major uncertainty in numerical models for atmospheric chemistry and improvements hinge upon experimental determination of retention for carboxylic acids, aldehydes, SO2, H2O2, NH2, and others, as presented in this paper.
Ahmed Abdelmonem, Ellen H. G. Backus, Nadine Hoffmann, M. Alejandra Sánchez, Jenée D. Cyran, Alexei Kiselev, and Mischa Bonn
Atmos. Chem. Phys., 17, 7827–7837, https://doi.org/10.5194/acp-17-7827-2017, https://doi.org/10.5194/acp-17-7827-2017, 2017
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We report the effect of surface charge on heterogeneous immersion freezing for the atmospherically relevant sapphire surface. Combining linear and nonlinear optical techniques and investigating isolated drops, we find that charge-induced surface templating is detrimental for ice nucleation on α-alumina surface. This study provides new insights into atmospheric processes and can impact various industrial and research branches, particularly climate change and tracing of water in the hydrosphere.
Pascal Renard, Isabelle Canet, Martine Sancelme, Nolwenn Wirgot, Laurent Deguillaume, and Anne-Marie Delort
Atmos. Chem. Phys., 16, 12347–12358, https://doi.org/10.5194/acp-16-12347-2016, https://doi.org/10.5194/acp-16-12347-2016, 2016
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A total of 480 microorganisms collected from 39 clouds sampled in France were isolated and identified. This unique collection was screened for biosurfactant production by measuring the surface tension. 41 % of the tested strains were active producers. Pseudomonas, the most frequently detected genus in clouds, was the dominant group for the production of biosurfactants. Further, the potential impact of the production of biosurfactants by cloud microorganisms on atmospheric processes is discussed.
Baban Nagare, Claudia Marcolli, André Welti, Olaf Stetzer, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8899–8914, https://doi.org/10.5194/acp-16-8899-2016, https://doi.org/10.5194/acp-16-8899-2016, 2016
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The relative importance of contact freezing and immersion freezing at mixed-phase cloud temperatures is the subject of debate. We performed experiments using continuous-flow diffusion chambers to compare the freezing efficiency of ice-nucleating particles for both these nucleation modes. Silver iodide, kaolinite and Arizona Test Dust were used as ice-nucleating particles. We could not confirm the dominance of contact freezing over immersion freezing for our experimental conditions.
A. Bianco, M. Passananti, H. Perroux, G. Voyard, C. Mouchel-Vallon, N. Chaumerliac, G. Mailhot, L. Deguillaume, and M. Brigante
Atmos. Chem. Phys., 15, 9191–9202, https://doi.org/10.5194/acp-15-9191-2015, https://doi.org/10.5194/acp-15-9191-2015, 2015
G. P. Schill, K. Genareau, and M. A. Tolbert
Atmos. Chem. Phys., 15, 7523–7536, https://doi.org/10.5194/acp-15-7523-2015, https://doi.org/10.5194/acp-15-7523-2015, 2015
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Fine volcanic ash can influence cloud glaciation and, therefore, global climate. In this work we examined the heterogeneous ice nucleation properties of three distinct types of volcanic ash. We find that, in contrast to previous studies, these volcanic ash samples have different ice nucleation properties in the immersion mode. In the deposition mode, however, they nucleate ice with similar efficiency. We show that this behavior may be due to their mineralogy.
Y. Tobo, P. J. DeMott, T. C. J. Hill, A. J. Prenni, N. G. Swoboda-Colberg, G. D. Franc, and S. M. Kreidenweis
Atmos. Chem. Phys., 14, 8521–8531, https://doi.org/10.5194/acp-14-8521-2014, https://doi.org/10.5194/acp-14-8521-2014, 2014
R. Paris and K. V. Desboeufs
Atmos. Chem. Phys., 13, 4895–4905, https://doi.org/10.5194/acp-13-4895-2013, https://doi.org/10.5194/acp-13-4895-2013, 2013
X. Tang, D. R. Cocker III, and A. Asa-Awuku
Atmos. Chem. Phys., 12, 8377–8388, https://doi.org/10.5194/acp-12-8377-2012, https://doi.org/10.5194/acp-12-8377-2012, 2012
V. Pinti, C. Marcolli, B. Zobrist, C. R. Hoyle, and T. Peter
Atmos. Chem. Phys., 12, 5859–5878, https://doi.org/10.5194/acp-12-5859-2012, https://doi.org/10.5194/acp-12-5859-2012, 2012
M. Vaïtilingom, T. Charbouillot, L. Deguillaume, R. Maisonobe, M. Parazols, P. Amato, M. Sancelme, and A.-M. Delort
Atmos. Chem. Phys., 11, 8721–8733, https://doi.org/10.5194/acp-11-8721-2011, https://doi.org/10.5194/acp-11-8721-2011, 2011
T. Hullar and C. Anastasio
Atmos. Chem. Phys., 11, 7209–7222, https://doi.org/10.5194/acp-11-7209-2011, https://doi.org/10.5194/acp-11-7209-2011, 2011
I. El Haddad, Yao Liu, L. Nieto-Gligorovski, V. Michaud, B. Temime-Roussel, E. Quivet, N. Marchand, K. Sellegri, and A. Monod
Atmos. Chem. Phys., 9, 5107–5117, https://doi.org/10.5194/acp-9-5107-2009, https://doi.org/10.5194/acp-9-5107-2009, 2009
Cited articles
Altieri, K. E., Seitzinger, S. P., Carlton, A. G., Turpin, B. J., Klein, G. C., and Marshall, A. G.: Oligomers formed through in-cloud méthylglyoxal reactions : Chemical composition, properties, and mechanisms investigated by ultra-high resolution FT-ICR mass spectrometry, Atmos. Environ, 42, 1476–1490, 2008.
Altieri, K. E., Carlton, A. G., Lim, H. J., Turpin, B. J., and Seitzinger, S. P.: Evidence for Oligomer Formation in Clouds: Reactions of Isoprene Oxidation Products, Environ. Sci. Technol., 40, 4956–4960, 2006.
Bell, R. P.: The reversible hydration of carbonyl compounds, in: Advances in physical organic chemistry, edited by: Gold, V., Academic press London and New York, 1–27, 1966.
Biesenthal, T. A. and Shepson, P. B.: Observations of anthropogenic inputs of the isoprene oxidation products methyl vinyl ketone and methacrolein to the atmosphere, Geophys. Res. Lett. 24, 1375–1378, 1997.
Brauers, T. and Finlayson-Pitts, B. J.: Analysis of relative rate measurements, Int. J. Chem. Kinet., 29, 665–672, 1997.
Buxton, G. V., Salmon, G. A., and Williams, J. E.: The reactivity of biogenic monoterpenes towards OH and SO4- radicals in De-oxygenated acidic solution, J. Atmos. Chem., 36, 111–134, 2000.
Carlton, A. G., Turpin, B. J., Altieri, K. E., Seitzinger, S., Reff, A., Lim, H. J., and Ervens, B.: Atmospheric oxalic acid and SOA production from glyoxal: results of aqueous photooxidation experiments, Atmos. Environ., 41, 7588–7602, 2007.
Chen, Z. M., Wang, H. L., Zhu, L. H., Wang, C. X., Jie, C. Y., and Hua, W.: Aqueous-phase ozonolysis of methacrolein and methyl vinyl ketone: a potentially important source of atmospheric aqueous oxidants, Atmos. Chem. Phys., 8, 2255–2265, 2008.
Chuong, B. and Stevens, P. S.: Measurements of the kinetics of the OH-Initiated oxidation of methyl vinyl ketone and methacrolein Inc., Int. J. Chem. Kinet., 36, 12–25, 2004.
Claeys, M., Graham, B., Vas, G., Wang, W., Vermeylen, R., Pashynska, V., Cafmeyer, J., Guyon, P., Andreae, M., Artaxo, P., and Maenhaut, W.: Formation of secondary organic aerosols through photooxidation of isoprene, Science, 303, 1173–1176, 2004a.
Claeys, M., Wang, W., Ion, A. C., Kourtchev, I., Gelencsér, A., and Maenhaut, W.: Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide, Atmos. Environ., 38, 4093–4098, 2004b.
Docherty, K. S., Wu, W., Lim, Y. B., and Ziemann, P. J.: Contributions of Organic Peroxides to Secondary Aerosol Formed from Reactions of Monoterpenes with O3, Environ. Sci. Technol, 39, 4049–4059, 2005.
El Haddad, I., Liu, Y., Nieto-Gligorovski, L., Michaud, V., Temime-Roussel, B., Quivet, E., Marchand, N., Sellegri, K., and Monod, A.: In-cloud processes of methacrolein under simulated conditions –Part 2: Formation of Secondary Organic Aerosol, Atmos. Chem. Phys. Discuss., 9, 6425–6449, 2009.
Ervens, B., Gligorovski, S., and Herrmann, H.: Temperaturedependent rate constants for hydroxyl radical reactions with organic compounds in aqueous solutions, Phys. Chem. Chem. Phys., 5, 1811–1824, 2003.
Gierczak, T., Burkholder, J. B., Talukdar, R. K., Mellouki, A., Barone, S. B., and Ravishankara, A. R.: Atmospheric fate of methyl vinyl ketone and methacrolein, J. Photoch. Photobio. A, 110, 1–10, 1997.
Gligorovski, S. and Herrmann, H.: Kinetics of reactions of OH with organic carbonyl compounds in aqueous solution, Phys. Chem. Chem. Phys., 6, 4118–4126, 2004.
Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., and Geron, C.: Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 3181–3210, 2006.
Guthrie, J. P.: Hydration of Carbonyl Compounds, an Analysis in Terms of Multidimensional Marcus Theory, J. Am. Chem. Soc., 122, 5529–5538, 2000.
Guzmán, M. I., Colussi, A. I., and Hoffmann, M. R.: Photoinduced oligomerization of aqueous pyruvic acid, J. Phys. Chem. A, 110, 3619–3626, 2006.
Herrmann, H.: Kinetics of aqueous phase reactions relevant for atmospheric chemistry, Chem. Rev., 103, 4691–4716, 2003.
Hilal, S. H., Bornander, L. L., Carreira, L. A., and Karickhoff, S. W.: Hydration equilibrium constants of aldehydes, ketones and quinazolines, QSAR Comb. Sci., 24, 631–638, 2005.
Ion, A. C., Vermeylen, R., Kourtchev, I., Cafmeyer, J., Chi, X., Gelencsér, A., Maenhaut, W., and Claeys, M.: Polar organic compounds in rural PM2.5 aerosols from K-puszta, Hungary, during a 2003 summer field campaign: Sources and diel variations, Atmos. Chem. Phys., 5, 1805–1814, 2005.
Iraci, L. T., Baker, B. M., Tyndall, G. S., and Orlando, J. J.: Measurements of the Henry's Law coefficients of 2-methyl-3-buten-2-ol, methacrolein, and methylvinyl ketone, J. Atmos. Chem., 33, 321–330, 1999.
Lee, W., Baasandorj, M., Stevens, P. S., and Hites, R. A.: Monitoring OH-Initiated Oxidation Kinetics of Isoprene and Its Products Using Online Mass Spectrometry, Environ. Sci. Technol., 39, 1030–1036, 2005.
Lelieveld, J. and Crutzen, P. J.: The role of clouds in tropospheric photochemistry, J. Atmos. Chem., 12, 229–267, 1991.
Lilie, J. and Henglein, A.: Pulse radiolytic study of unsaturated carbonyl compound oxidation in aqueous solution. Hydrated enols as intermediates, Ber. Bunsen-Ges., 74, 388–393, 1970.
Mc Elroy, W. J. and Waygood, S. J.: Oxidation of formaldehyde by the hydroxyl radical in aqueous solution, J. Chem. Soc. Faraday T., 87, 1513–1521, 1991.
Melichercik, M. and Treindl, L.: Kinetics and mechanism of the oxidation of acrolein, crotonaldehyde, and methacrolein with cerium(IV) sulphate, Chem. Zvesti, 35, 153–63, 1981.
Mellouki, A., Le Bras, G., and Sidebottom, H.: Kinetics and mechanisms of the oxidation of oxygenated organic compounds in the gas phase, Chem. Rev., 103, 5077–5096, 2003.
Michaud, V., El Haddad, I., Liu, Y., Sellegri, K., Laj, P., Villani, P., Picard, D., Marchand, N., and Monod, A.: In-cloud processes of methacrolein under simulated conditions – Part 3: Hygroscopic and volatility properties of the formed Secondary Organic Aerosol, Atmos. Chem. Phys. Discuss., 9, 6451–6482, 2009.
Monod, A., Chebbi, A., Durand-Jolibois, R., and Carlier, P.: Oxidation of methanol by hydroxyl radicals in aqueous solution under simulated cloud droplet conditions, Atmos. Environ., 34, 5283–5294, 2000.
Monod, A., Poulain, L., Grubert, S., Voisin, D., and Wortham, H.: Kinetics of OH-initiated oxydation of oxigenated organic compounds in the aqueous phase: new rate constants, structure-activity relationships and atmospheric implications, Atmos. Environ., 39, 7667–7688, 2005.
Monod, A., Chevallier, E., Durand-Jolibois, R., Doussin, J. F., Picquet-Varrault, B., and Carlier, P.: Photooxidation of methylhydroperoxide and ethylhydroperoxide in the aqueous phase under simulated cloud droplet conditions, Atmos. Environ., 41, 2412–2426, 2007.
Monod, A. and Doussin, J. F.: Structure-activity relationship for the estimation of OH-oxidation rate constant of aliphatic organic compounds in the aqueous phase: alkanes, alcohols, organic acids and bases, Atmos. Environ., 42, 7611–7622, 2008.
Orlando, J. J., Tyndall, G. S., and Paulson, S. E.: Mechanism of the OH-initiated oxidation of methacrole, Geophys. Res. Lett., 26(14), 2191–2194, 1999.
Pedersen, T. and Sehested, K.: Rate constants and activation energies for ozonolysis of isoprene methacrolein and methyl-vinyl-ketone in aqueous solution: significance to the in-cloud ozonation of isoprene, Int. J. Chem. Kinet., 33, 182–190, 2001.
Pimentel, A. S. and Arbilla, G.: Kinetic Analysis of the Gas-Phase Reactions of Methacrolein with the OH Radical in the Presence of NOx, J. Braz. Chem. Soc., 10(6), 483–491, 1999.
Poulain, L., Monod, A., and Wortham, H.: Development of a new on-line mass spectrometer to study the reactivity of soluble organic compounds in the aqueous phase under tropospheric conditions: Application to OH-oxidation of N-methylpyrrolidone, J. Photoch. Photobio. A, 187, 10–23, 2007.
Schuchmann, M. N. and von Sonntag, C.: The rapid hydratation of the Acetyl Radical - A pulse radiolysis study of Acetaldehyde in aqueous solution, J. Am. Chem. Soc., 110, 5698–5701, 1988.
Smith Ian, W. M. and Ravishankara, A. R.: Role of hydrogen-bonded intermediates in the bimolecular reactions of the hydroxyl radical, J. Phys. Chem. A, 106, 4798–4807, 2002.
SPARC on-line v4.2: online available at: http://ibmlc2.chem.uga.edu/sparc/, 2009.
Szeremeta, E., Barzaghi, P., Böge, O., Herrmann, H., Gmachowski, L., and Rudzinski, K. J.: Aqueous-phase reactions of isoprene oxidation products with hydroxyl radicals, in: Atmospheric composition Change – Causes and Consequences – Local to Global, edited by: Maione, M. and Fuzzi, S., Aracne editrice S.r.l., 2009.
Umschlag, T., Herrmann, H., and Zellner, R.: A kinetic study of aqueous phase nitrate (NO3) radical reactions with aldehydes and their impact on atmospheric clouds and aerosols chemistry, PSI-Proceedings, 97-02, 47–49, 1997.
Umschlag, T., Herrmann, H., and Zellner, R.: A kinetic study of aqueous-phase reactions of the nitrate radical (NO3) with aldehydes, Proceedings of EUROTRAC Symposium '98: Transport and Chemical Transformation in the Troposphere, Garmisch-Partenkirchen, Germany, 694–698, 1999.
Van Pinxteren, D., Plewka, A., Hofmann, D., Mueller, K., Kramberger, H., Svrcina, B., Baechmann, K., Jaeschke, W., Mertes, S., Collett, J. L., and Herrmann, H.: Schmuecke hill cap cloud and valley stations aerosol characterisation during FEBUKO (II): Organic compounds, Atmos. Environ., 39, 4305–4320, 2005.
Von Sonntag, C. and Schuchmann, H. P.: Peroxyl radicals in aqueous solutions, Peroxyl Radicals The chemistry of free radicals, edited by: Wiley, J., New York, 173–234, 1997.
Warneck, P.: In-cloud chemstry opens pathway to the formation of oxalic acid in the marine atmosphere, Atmos. Environ., 37, 2423–2427, 2003.
Zhu, L. and Chen, Z.: Ozonolysis of methacrolein and methyl vinyl ketone in aqueous solutions, Huanjing Kexue, 26, 83–86, 2005.
Zimmermann, J. and Poppe, D.: A supplement for the RADM2 chemical mechanism: the photooxidation of isoprene, Atmos. Environ., 30, 1255–1269, 1995.
