Articles | Volume 26, issue 3
https://doi.org/10.5194/acp-26-1699-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-26-1699-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
03 Feb 2026
Research article |
| 03 Feb 2026
| 03 Feb 2026
Aerosol organic nitrogen across the global marine boundary layer: distribution patterns and controlling factors
Ningning Sun
Key Laboratory of Geographic Information Science (Ministry of Education), School of Geographic Sciences and State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, China
Division of Environment and Sustainability, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
Xu Yu
Division of Environment and Sustainability, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Joint International Research Laboratory of Climate and Environment Change, School of Environmental Science and Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu, China
Division of Environment and Sustainability, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
Department of Chemistry, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
Bo Zhang
Key Laboratory of Geographic Information Science (Ministry of Education), School of Geographic Sciences and State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, China
Yilan Li
Key Laboratory of Geographic Information Science (Ministry of Education), School of Geographic Sciences and State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, China
Department of Chemistry, State University of New York College of Environmental Science and Forestry, Syracuse, NY, USA
Key Laboratory of Geographic Information Science (Ministry of Education), School of Geographic Sciences and State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, China
Zhe Li
Key Laboratory of Geographic Information Science (Ministry of Education), School of Geographic Sciences and State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, China
Zhenlou Chen
Key Laboratory of Geographic Information Science (Ministry of Education), School of Geographic Sciences and State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, China
Key Laboratory of Geographic Information Science (Ministry of Education), School of Geographic Sciences and State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, China
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EGUsphere, https://doi.org/10.5194/egusphere-2025-6487, https://doi.org/10.5194/egusphere-2025-6487, 2026
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
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We developed a high-resolution computer model to simulate how the ocean, sea ice, and ice shelves interact around Antarctica. This helps us understand their critical role in global climate and sea-level rise. Our model successfully captures essential features like major currents and seasonal ice changes. Despite some remaining biases, it provides a useful tool for predicting future changes in this vital and rapidly evolving region.
Xueying Liu, Yeqi Huang, Yao Chen, Xin Feng, Jiading Li, Yang Xu, Yi Chen, Dasa Gu, Hao Sun, Zhi Ning, Jianzhen Yu, Wing Sze Chow, Changqing Lin, Yan Xiang, Tianshu Zhang, Claire Granier, Guy Brasseur, Zhe Wang, and Jimmy C. H. Fung
Atmos. Chem. Phys., 25, 17629–17649, https://doi.org/10.5194/acp-25-17629-2025, https://doi.org/10.5194/acp-25-17629-2025, 2025
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Volatile organic compounds (VOCs) affect ozone formation and air quality. However, our understanding is limited due to insufficient measurements, especially for oxygenated VOCs. This study combines land, ship, and satellite data in Hong Kong, showing that oxygenated VOCs make up a significant portion of total VOCs. Despite their importance, many are underestimated in current models. These findings highlight the need to improve VOC representation in models to enhance air quality management.
Biao Zhou, Kun Zhang, Qiongqiong Wang, Jiqi Zhu, Li Li, and Jian Zhen Yu
EGUsphere, https://doi.org/10.5194/egusphere-2025-5481, https://doi.org/10.5194/egusphere-2025-5481, 2025
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Anhydro-saccharides are key organic markers for biomass burning, but their decay rates and driving factors in real ambient environments remain unclear. This study conducted an online field measurement of PM₂.₅-bound saccharides in three eastern Chinese cities. Daytime levoglucosan decay rates were calculated, and the driving factors were investigated using a machine learning model. Findings of this study offers a strong scientific basis to support air pollution management.
Shubin Li, Yujue Wang, Yiwen Zhang, Yizhe Yi, Yuchen Wang, Yuqi Guo, Chao Yu, Yue Jiang, Jinhui Shi, Chao Zhang, Jialei Zhu, Wei Hu, Jianzhen Yu, Xiaohong Yao, Huiwang Gao, and Min Hu
Atmos. Chem. Phys., 25, 12585–12598, https://doi.org/10.5194/acp-25-12585-2025, https://doi.org/10.5194/acp-25-12585-2025, 2025
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Organosulfates (OSs) are an unrecognized and potentially important component in marine organic aerosols. In this study, we quantified and characterized the OSs over East Asian marginal seas. The chemical nature and spatiotemporal distribution of OSs were modified by the joint influence of marine emissions and transported terrestrial pollutants. The results highlight the vital roles of OSs in shaping organic aerosol formation and sulfur cycle during summer in the marine boundary layer.
Donger Lai, Yanxin Bai, Zijing Zhang, Pui-Kin So, Yong Jie Li, Ying-Lung Steve Tse, Ying-Yeung Yeung, Thomas Schaefer, Hartmut Herrmann, Jian Zhen Yu, Yuchen Wang, and Man Nin Chan
Atmos. Chem. Phys., 25, 12569–12584, https://doi.org/10.5194/acp-25-12569-2025, https://doi.org/10.5194/acp-25-12569-2025, 2025
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Aqueous-phase •OH oxidation can potentially act as an important atmospheric sink for α-pinene-derived organosulfates (OSs). Such oxidation can also generate a variety of new OS products, and can be as a potential source for some atmospheric OSs with previously unknown origins.
Rui Li, Xing Liu, Yubing Shen, Yumeng Shao, Yining Gao, Ziwei Yao, Xi Liu, and Guitao Shi
Atmos. Chem. Phys., 25, 9263–9274, https://doi.org/10.5194/acp-25-9263-2025, https://doi.org/10.5194/acp-25-9263-2025, 2025
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We reveal for the first time the global variations of PAHs and derivatives in marine air. We found that marine aerosols in East China Sea (ECS) and Western Pacific (WP) were significantly affected by coal and engine combustion, while those in Bismarck Sea (BS) and East Australian Sea (EAS) were mainly influenced by wildfire and coal combustion. The Antarctic Ocean (AO) was dominated by biomass burning and local shipping emissions. This finding helps elucidate the mechanism of the global PAH cycle.
Xu Yu, Min Zhou, Shuhui Zhu, Liping Qiao, Jinjian Li, Yingge Ma, Zijing Zhang, Kezheng Liao, Hongli Wang, and Jian Zhen Yu
Atmos. Chem. Phys., 25, 9061–9074, https://doi.org/10.5194/acp-25-9061-2025, https://doi.org/10.5194/acp-25-9061-2025, 2025
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Online measurements of bulk aerosol organic nitrogen (ON), in conjunction with a comprehensive array of source markers, have revealed five emission sources and five potentially significant formation processes of nitrogenous organic aerosols. This study provides a first quantitative source analysis of ON aerosol and valuable observational evidence of secondary ON aerosol formation through NH3 and NOx chemistries.
Anyao Jiang, Xin Meng, Yan Huang, and Guitao Shi
The Cryosphere, 18, 5347–5364, https://doi.org/10.5194/tc-18-5347-2024, https://doi.org/10.5194/tc-18-5347-2024, 2024
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Landlocked lakes are crucial to the Antarctic ecosystem and sensitive to climate change. Limited research on their distribution prompted us to develop an automated detection process using deep learning and multi-source satellite imagery. This allowed us to accurately determine the landlocked lake open water (LLOW) area in Antarctica, generating high-resolution time series data. We find that the changes in positive and negative degree days predominantly drive variations in the LLOW area.
Liyuan Zhou, Qianyun Liu, Christian M. Salvador, Michael Le Breton, Mattias Hallquist, Jian Zhen Yu, Chak K. Chan, and Åsa M. Hallquist
Atmos. Chem. Phys., 24, 11045–11061, https://doi.org/10.5194/acp-24-11045-2024, https://doi.org/10.5194/acp-24-11045-2024, 2024
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Our research on city bus emissions reveals that alternative fuels (compressed natural gas and biofuels) reduce fresh particle emissions compared to diesel. However, all fuels lead to secondary air pollution. Aiming at guiding better environmental policies, we studied 76 buses using advanced emission measurement techniques. This work sheds light on the complex effects of bus fuels on urban air quality, emphasizing the need for comprehensive evaluations of future transportation technologies.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 5803–5821, https://doi.org/10.5194/acp-24-5803-2024, https://doi.org/10.5194/acp-24-5803-2024, 2024
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In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal-scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Zhengyi Hu, Wei Jiang, Yuzhen Yan, Yan Huang, Xueyuan Tang, Lin Li, Florian Ritterbusch, Guo-Min Yang, Zheng-Tian Lu, and Guitao Shi
The Cryosphere, 18, 1647–1652, https://doi.org/10.5194/tc-18-1647-2024, https://doi.org/10.5194/tc-18-1647-2024, 2024
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The age of the surface blue ice in the Grove Mountains area is dated to be about 140 000 years, and one meteorite found here is 260 000 years old. It is inferred that the Grove Mountains blue-ice area holds considerable potential for paleoclimate studies.
Qiongqiong Wang, Shuhui Zhu, Shan Wang, Cheng Huang, Yusen Duan, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 475–486, https://doi.org/10.5194/acp-24-475-2024, https://doi.org/10.5194/acp-24-475-2024, 2024
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We investigated short-term source apportionment of PM2.5 utilizing rolling positive matrix factorization (PMF) and online PM chemical speciation data, which included source-specific organic tracers collected over a period of 37 d during the winter of 2019–2020 in suburban Shanghai, China. The findings highlight that by imposing constraints on the primary source profiles, short-term PMF analysis successfully replicated both the individual primary sources and the total secondary sources.
Ting Yang, Yu Xu, Qing Ye, Yi-Jia Ma, Yu-Chen Wang, Jian-Zhen Yu, Yu-Sen Duan, Chen-Xi Li, Hong-Wei Xiao, Zi-Yue Li, Yue Zhao, and Hua-Yun Xiao
Atmos. Chem. Phys., 23, 13433–13450, https://doi.org/10.5194/acp-23-13433-2023, https://doi.org/10.5194/acp-23-13433-2023, 2023
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In this study, 130 OS species were quantified in ambient fine particulate matter (PM2.5) collected in urban and suburban Shanghai (East China) in the summer of 2021. The daytime OS formation was concretized based on the interactions among OSs, ultraviolet (UV), ozone (O3), and sulfate. Our finding provides field evidence for the influence of photochemical process and anthropogenic sulfate on OS formation and has important implications for the mitigation of organic particulate pollution.
Shuhui Zhu, Min Zhou, Liping Qiao, Dan Dan Huang, Qiongqiong Wang, Shan Wang, Yaqin Gao, Shengao Jing, Qian Wang, Hongli Wang, Changhong Chen, Cheng Huang, and Jian Zhen Yu
Atmos. Chem. Phys., 23, 7551–7568, https://doi.org/10.5194/acp-23-7551-2023, https://doi.org/10.5194/acp-23-7551-2023, 2023
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Organic aerosol (OA) is increasingly important in urban PM2.5 pollution as inorganic ions are becoming lower. We investigated the chemical characteristics of OA during nine episodes in Shanghai. The availability of bi-hourly measured molecular markers revealed that the control of local urban sources such as vehicular and cooking emissions lessened the severity of local episodes. Regional control of precursors and biomass burning would reduce PM2.5 episodes influenced by regional transport.
Rui Li, Kun Zhang, Qing Li, Liumei Yang, Shunyao Wang, Zhiqiang Liu, Xiaojuan Zhang, Hui Chen, Yanan Yi, Jialiang Feng, Qiongqiong Wang, Ling Huang, Wu Wang, Yangjun Wang, Jian Zhen Yu, and Li Li
Atmos. Chem. Phys., 23, 3065–3081, https://doi.org/10.5194/acp-23-3065-2023, https://doi.org/10.5194/acp-23-3065-2023, 2023
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Molecular markers in organic aerosol (OA) provide specific source information on PM2.5, and the contribution of cooking emissions to OA is significant, especially in urban environments. This study investigates the variation in concentrations and oxidative degradation of fatty acids and corresponding oxidation products in ambient air, which can be a guide for the refinement of aerosol source apportionment and provide scientific support for the development of emission source control policies.
Wing Sze Chow, Kezheng Liao, X. H. Hilda Huang, Ka Fung Leung, Alexis K. H. Lau, and Jian Zhen Yu
Atmos. Chem. Phys., 22, 11557–11577, https://doi.org/10.5194/acp-22-11557-2022, https://doi.org/10.5194/acp-22-11557-2022, 2022
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Long-term monitoring data of PM2.5 chemical composition provide essential information for evaluation and planning of control measures. Here we present a 10-year (2008–2017) time series of PM2.5, its major components, and select source markers in an urban site in Hong Kong. The dataset verified the success of local vehicular emission control measures as well as reduction of sulfate and regional sources such as industrial and coal combustion and crop residue burning emissions over the decade.
Qiongqiong Wang, Shan Wang, Yuk Ying Cheng, Hanzhe Chen, Zijing Zhang, Jinjian Li, Dasa Gu, Zhe Wang, and Jian Zhen Yu
Atmos. Chem. Phys., 22, 11239–11253, https://doi.org/10.5194/acp-22-11239-2022, https://doi.org/10.5194/acp-22-11239-2022, 2022
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Secondary organic aerosol (SOA) is often enhanced during fine-particulate-matter (PM2.5) episodes. We examined bi-hourly measurements of SOA molecular tracers in suburban Hong Kong during 11 city-wide PM2.5 episodes. The tracers showed regional characteristics for both anthropogenic and biogenic SOA as well as biomass-burning-derived SOA. Multiple tracers of the same precursor revealed the dominance of low-NOx formation pathways for isoprene SOA and less-aged monoterpene SOA during winter.
Rongshuang Xu, Sze In Madeleine Ng, Wing Sze Chow, Yee Ka Wong, Yuchen Wang, Donger Lai, Zhongping Yao, Pui-Kin So, Jian Zhen Yu, and Man Nin Chan
Atmos. Chem. Phys., 22, 5685–5700, https://doi.org/10.5194/acp-22-5685-2022, https://doi.org/10.5194/acp-22-5685-2022, 2022
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To date, while over a hundred organosulfates (OSs) have been detected in atmospheric aerosols, many of them are still unidentified, with unknown precursors and formation processes. We found the heterogeneous OH oxidation of an α-pinene-derived organosulfate (C10H17O5SNa, αpOS-249, αpOS-249) can proceed at an efficient rate and transform into more oxygenated OSs, which have been commonly detected in atmospheric aerosols and α-pinene-derived SOA in chamber studies.
Yee Ka Wong, Kin Man Liu, Claisen Yeung, Kenneth K. M. Leung, and Jian Zhen Yu
Atmos. Chem. Phys., 22, 5017–5031, https://doi.org/10.5194/acp-22-5017-2022, https://doi.org/10.5194/acp-22-5017-2022, 2022
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Coarse particulate matter (PM) has been shown to cause adverse health impacts, but compared to PM2.5, the source of coarse PM is less studied through field measurements. We collected chemical composition data for coarse PM in Hong Kong for a 1-year period. Using statistical models, we found that regional transport of fugitive dust is responsible for the elevated coarse PM. This work sets an example of how field measurements can be effectively utilized for evidence-based policymaking.
Guitao Shi, Hongmei Ma, Zhengyi Hu, Zhenlou Chen, Chunlei An, Su Jiang, Yuansheng Li, Tianming Ma, Jinhai Yu, Danhe Wang, Siyu Lu, Bo Sun, and Meredith G. Hastings
The Cryosphere, 15, 1087–1095, https://doi.org/10.5194/tc-15-1087-2021, https://doi.org/10.5194/tc-15-1087-2021, 2021
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It is important to understand atmospheric chemistry over Antarctica under a changing climate. Thus snow collected on a traverse from the coast to Dome A was used to investigate variations in snow chemistry. The non-sea-salt fractions of K+, Mg2+, and Ca2+ are associated with terrestrial inputs, and nssCl− is from HCl. In general, proportions of non-sea-salt fractions of ions to the totals are higher in the interior areas than on the coast, and the proportions are higher in summer than in winter.
Yao Wang, Yue Zhao, Yuchen Wang, Jian-Zhen Yu, Jingyuan Shao, Ping Liu, Wenfei Zhu, Zhen Cheng, Ziyue Li, Naiqiang Yan, and Huayun Xiao
Atmos. Chem. Phys., 21, 2959–2980, https://doi.org/10.5194/acp-21-2959-2021, https://doi.org/10.5194/acp-21-2959-2021, 2021
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Organosulfates (OSs) are important constituents and tracers of secondary organic aerosols (SOAs) in the atmosphere. Here we characterized the OS species in ambient aerosols in Shanghai, China. We find that the contributions of OSs and SOAs to organic aerosols have increased in recent years and that OS production was largely controlled by the oxidant level (Ox), particularly in summer. We infer that mitigation of Ox pollution can effectively reduce the production of OSs and SOAs in eastern China.
Cited articles
Almeida, J., Schobesberger, S., Kürten, A., Ortega, I. K., Kupiainen-Määttä, O., Praplan, A. P., Adamov, A., Amorim, A., Bianchi, F., Breitenlechner, M., David, A., Dommen, J., Donahue, N. M., Downard, A., Dunne, E., Duplissy, J., Ehrhart, S., Flagan, R. C., Franchin, A., Guida, R., Hakala, J., Hansel, A., Heinritzi, M., Henschel, H., Jokinen, T., Junninen, H., Kajos, M., Kangasluoma, J., Keskinen, H., Kupc, A., Kurtén, T., Kvashin, A. N., Laaksonen, A., Lehtipalo, K., Leiminger, M., Leppä, J., Loukonen, V., Makhmutov, V., Mathot, S., McGrath, M. J., Nieminen, T., Olenius, T., Onnela, A., Petäjä, T., Riccobono, F., Riipinen, I., Rissanen, M., Rondo, L., Ruuskanen, T., Santos, F. D., Sarnela, N., Schallhart, S., Schnitzhofer, R., Seinfeld, J. H., Simon, M., Sipilä, M., Stozhkov, Y., Stratmann, F., Tomé, A., Tröstl, J., Tsagkogeorgas, G., Vaattovaara, P., Viisanen, Y., Virtanen, A., Vrtala, A., Wagner, P. E., Weingartner, E., Wex, H., Williamson, C., Wimmer, D., Ye, P., Yli-Juuti, T., Carslaw, K. S., Kulmala, M., Curtius, J., Baltensperger, U., Worsnop, D. R., Vehkamäki, H., and Kirkby, J.: Molecular understanding of sulphuric acid–amine particle nucleation in the atmosphere, Nature, 502, 359–363, https://doi.org/10.1038/nature12663, 2013.
Alsante, A. N., Thornton, D. C. O., and Brooks, S. D.: Effect of Aggregation and Molecular Size on the Ice Nucleation Efficiency of Proteins, Environ. Sci. Technol., 58, 4594–4605, https://doi.org/10.1021/acs.est.3c06835, 2024.
Altieri, K. E., Fawcett, S. E., Peters, A. J., Sigman, D. M., and Hastings, M. G.: Marine biogenic source of atmospheric organic nitrogen in the subtropical North Atlantic, Proc. Natl. Acad. Sci. USA, 113, 925–930, https://doi.org/10.1073/pnas.1516847113, 2016.
Altieri, K. E., Fawcett, S. E., and Hastings, M. G.: Reactive Nitrogen Cycling in the Atmosphere and Ocean, Annu. Rev. Earth Planet. Sci., 49, 523–550, https://doi.org/10.1146/annurev-earth-083120-052147, 2021.
Anonymous: A fresh look at element distribution in the North Pacific Ocean, Eos Trans. Am. Geophys. Union, 78, 221–221, https://doi.org/10.1029/97EO00148, 1997.
Arrigo, K. R., Van Dijken, G. L., and Bushinsky, S.: Primary production in the Southern Ocean, 1997–2006, J. Geophys. Res., 113, 2007JC004551, https://doi.org/10.1029/2007JC004551, 2008.
Ashbaugh, L. L., Malm, W. C., and Sadeh, W. Z.: A residence time probability analysis of sulfur concentrations at grand Canyon National Park, Atmos. Environ., 19, 1263–1270, https://doi.org/10.1016/0004-6981(85)90256-2, 1985.
Baker, A. R., Kanakidou, M., Altieri, K. E., Daskalakis, N., Okin, G. S., Myriokefalitakis, S., Dentener, F., Uematsu, M., Sarin, M. M., Duce, R. A., Galloway, J. N., Keene, W. C., Singh, A., Zamora, L., Lamarque, J.-F., Hsu, S.-C., Rohekar, S. S., and Prospero, J. M.: Observation- and model-based estimates of particulate dry nitrogen deposition to the oceans, Atmos. Chem. Phys., 17, 8189–8210, https://doi.org/10.5194/acp-17-8189-2017, 2017.
Blazina, T., Läderach, A., Jones, G. D., Sodemann, H., Wernli, H., Kirchner, J. W., and Winkel, L. H. E.: Marine Primary Productivity as a Potential Indirect Source of Selenium and Other Trace Elements in Atmospheric Deposition, Environ. Sci. Technol., 51, 108–118, https://doi.org/10.1021/acs.est.6b03063, 2017.
Brean, J., Dall'Osto, M., Simó, R., Shi, Z., Beddows, D. C. S., and Harrison, R. M.: Open ocean and coastal new particle formation from sulfuric acid and amines around the Antarctic Peninsula, Nat. Geosci., 14, 383–388, https://doi.org/10.1038/s41561-021-00751-y, 2021.
Cape, J. N., Cornell, S. E., Jickells, T. D., and Nemitz, E.: Organic nitrogen in the atmosphere – Where does it come from? A review of sources and methods, Atmos. Res., 102, 30–48, https://doi.org/10.1016/j.atmosres.2011.07.009, 2011.
Cavalieri, D. J., Gloersen, P., Parkinson, C. L., Comiso, J. C., and Zwally, H. J.: Observed Hemispheric Asymmetry in Global Sea Ice Changes, Science, 278, 1104–1106, https://doi.org/10.1126/science.278.5340.1104, 1997.
Chan, M. N., Choi, M. Y., Ng, N. L., and Chan, C. K.: Hygroscopicity of Water-Soluble Organic Compounds in Atmospheric Aerosols: Amino Acids and Biomass Burning Derived Organic Species, Environ. Sci. Technol., 39, 1555–1562, https://doi.org/10.1021/es049584l, 2005.
Chen, H. Y. and Chen, L.-D.: Occurrence of water soluble organic nitrogen in aerosols at a coastal area, J. Atmos. Chem., 65, 49–71, https://doi.org/10.1007/s10874-010-9181-y, 2010.
Choi, J. H., Jang, E., Yoon, Y. J., Park, J. Y., Kim, T.-W., Becagli, S., Caiazzo, L., Cappelletti, D., Krejci, R., Eleftheriadis, K., Park, K.-T., and Jang, K. S.: Influence of Biogenic Organics on the Chemical Composition of Arctic Aerosols, Global Biogeochem. Cycles, 33, 1238–1250, https://doi.org/10.1029/2019GB006226, 2019.
Chuck, A. L., Turner, S. M., and Liss, P. S.: Direct Evidence for a Marine Source of C1 and C2 Alkyl Nitrates, Science, 297, 1151–1154, https://doi.org/10.1126/science.1073896, 2002.
Cornell, S.: Water-soluble organic nitrogen in atmospheric aerosol: a comparison of UV and persulfate oxidation methods, Atmos. Environ., 33, 833–840, https://doi.org/10.1016/S1352-2310(98)00139-3, 1999.
Cornell, S., Mace, K., Coeppicus, S., Duce, R., Huebert, B., Jickells, T., and Zhuang, L.-Z.: Organic nitrogen in Hawaiian rain and aerosol, J. Geophys. Res., 106, 7973–7983, https://doi.org/10.1029/2000JD900655, 2001.
Creamean, J. M., Barry, K., Hill, T. C. J., Hume, C., DeMott, P. J., Shupe, M. D., Dahlke, S., Willmes, S., Schmale, J., Beck, I., Hoppe, C. J. M., Fong, A., Chamberlain, E., Bowman, J., Scharien, R., and Persson, O.: Annual cycle observations of aerosols capable of ice formation in central Arctic clouds, Nat. Commun., 13, 3537, https://doi.org/10.1038/s41467-022-31182-x, 2022.
Dall'Osto, M., Ovadnevaite, J., Paglione, M., Beddows, D. C. S., Ceburnis, D., Cree, C., Cortés, P., Zamanillo, M., Nunes, S. O., Pérez, G. L., Ortega-Retuerta, E., Emelianov, M., Vaqué, D., Marrasé, C., Estrada, M., Sala, M. M., Vidal, M., Fitzsimons, M. F., Beale, R., Airs, R., Rinaldi, M., Decesari, S., Cristina Facchini, M., Harrison, R. M., O'Dowd, C., and Simó, R.: Antarctic sea ice region as a source of biogenic organic nitrogen in aerosols, Sci. Rep., 7, 6047, https://doi.org/10.1038/s41598-017-06188-x, 2017.
Dall'Osto, M., Airs, R. L., Beale, R., Cree, C., Fitzsimons, M. F., Beddows, D., Harrison, R. M., Ceburnis, D., O'Dowd, C., Rinaldi, M., Paglione, M., Nenes, A., Decesari, S., and Simó, R.: Simultaneous Detection of Alkylamines in the Surface Ocean and Atmosphere of the Antarctic Sympagic Environment, ACS Earth Space Chem., 3, 854–862, https://doi.org/10.1021/acsearthspacechem.9b00028, 2019.
Dawson, M. L., Varner, M. E., Perraud, V., Ezell, M. J., Gerber, R. B., and Finlayson-Pitts, B. J.: Simplified mechanism for new particle formation from methanesulfonic acid, amines, and water via experiments and ab initio calculations, Proc. Natl. Acad. Sci. USA, 109, 18719–18724, https://doi.org/10.1073/pnas.1211878109, 2012.
DeMott, P. J., Hill, T. C. J., McCluskey, C. S., Prather, K. A., Collins, D. B., Sullivan, R. C., Ruppel, M. J., Mason, R. H., Irish, V. E., Lee, T., Hwang, C. Y., Rhee, T. S., Snider, J. R., McMeeking, G. R., Dhaniyala, S., Lewis, E. R., Wentzell, J. J. B., Abbatt, J., Lee, C., Sultana, C. M., Ault, A. P., Axson, J. L., Diaz Martinez, M., Venero, I., Santos-Figueroa, G., Stokes, M. D., Deane, G. B., Mayol-Bracero, O. L., Grassian, V. H., Bertram, T. H., Bertram, A. K., Moffett, B. F., and Franc, G. D.: Sea spray aerosol as a unique source of ice nucleating particles, Proc. Natl. Acad. Sci. USA, 113, 5797–5803, https://doi.org/10.1073/pnas.1514034112, 2016.
Deng, O., Wang, S., Ran, J., Huang, S., Zhang, X., Duan, J., Zhang, L., Xia, Y., Reis, S., Xu, J., Xu, J., De Vries, W., Sutton, M. A., and Gu, B.: Managing urban development could halve nitrogen pollution in China, Nat. Commun., 15, 401, https://doi.org/10.1038/s41467-023-44685-y, 2024.
Duce, R. A., LaRoche, J., Altieri, K., Arrigo, K. R., Baker, A. R., Capone, D. G., Cornell, S., Dentener, F., Galloway, J., Ganeshram, R. S., Geider, R. J., Jickells, T., Kuypers, M. M., Langlois, R., Liss, P. S., Liu, S. M., Middelburg, J. J., Moore, C. M., Nickovic, S., Oschlies, A., Pedersen, T., Prospero, J., Schlitzer, R., Seitzinger, S., Sorensen, L. L., Uematsu, M., Ulloa, O., Voss, M., Ward, B., and Zamora, L.: Impacts of Atmospheric Anthropogenic Nitrogen on the Open Ocean, Science, 320, 893–897, https://doi.org/10.1126/science.1150369, 2008.
Facchini, M. C., Decesari, S., Rinaldi, M., Carbone, C., Finessi, E., Mircea, M., Fuzzi, S., Moretti, F., Tagliavini, E., Ceburnis, D., and O'Dowd, C. D.: Important Source of Marine Secondary Organic Aerosol from Biogenic Amines, Environ. Sci. Technol., 42, 9116–9121, https://doi.org/10.1021/es8018385, 2008.
Fetterer, F., Knowles, K., Meier, W. N., Savoie, M., and Windnagel, A. K.: Sea Ice Index. (G02135, Version 3), National Snow and Ice Data Center, Boulder, Colorado USA [data set], https://doi.org/10.7265/N5K072F8, 2017.
Fisher, J. A., Jacob, D. J., Travis, K. R., Kim, P. S., Marais, E. A., Chan Miller, C., Yu, K., Zhu, L., Yantosca, R. M., Sulprizio, M. P., Mao, J., Wennberg, P. O., Crounse, J. D., Teng, A. P., Nguyen, T. B., St. Clair, J. M., Cohen, R. C., Romer, P., Nault, B. A., Wooldridge, P. J., Jimenez, J. L., Campuzano-Jost, P., Day, D. A., Hu, W., Shepson, P. B., Xiong, F., Blake, D. R., Goldstein, A. H., Misztal, P. K., Hanisco, T. F., Wolfe, G. M., Ryerson, T. B., Wisthaler, A., and Mikoviny, T.: Organic nitrate chemistry and its implications for nitrogen budgets in an isoprene- and monoterpene-rich atmosphere: constraints from aircraft (SEAC4RS) and ground-based (SOAS) observations in the Southeast US, Atmos. Chem. Phys., 16, 5969–5991, https://doi.org/10.5194/acp-16-5969-2016, 2016.
Fitzsimons, M. F., Tilley, M., and Cree, C. H. L.: The determination of volatile amines in aquatic marine systems: A review, Anal. Chim. Acta, 1241, 340707, https://doi.org/10.1016/j.aca.2022.340707, 2023.
Galgani, L., Piontek, J., and Engel, A.: Biopolymers form a gelatinous microlayer at the air-sea interface when Arctic sea ice melts, Sci. Rep., 6, 29465, https://doi.org/10.1038/srep29465, 2016.
Jang, J., Park, J., Park, J., Yoon, Y. J., Dall'Osto, M., Park, K.-T., Jang, E., Lee, J. Y., Cho, K. H., and Lee, B. Y.: Ocean-atmosphere interactions: Different organic components across Pacific and Southern Oceans, Sci. Total Environ., 878, 162969, https://doi.org/10.1016/j.scitotenv.2023.162969, 2023.
Jickells, T., Baker, A. R., Cape, J. N., Cornell, S. E., and Nemitz, E.: The cycling of organic nitrogen through the atmosphere, Philos. Trans. R. Soc. B, 368, 20130115, https://doi.org/10.1098/rstb.2013.0115, 2013.
Jung, J., Han, B., Rodriguez, B., Miyazaki, Y., Chung, H. Y., Kim, K., Choi, J.-O., Park, K., Kim, I.-N., Kim, S., Yang, E. J., and Kang, S.-H.: Atmospheric Dry Deposition of Water-Soluble Nitrogen to the Subarctic Western North Pacific Ocean during Summer, Atmosphere, 10, 351, https://doi.org/10.3390/atmos10070351, 2019.
Keene, W. C., Pszenny, A. A. P., Galloway, J. N., and Hawley, M. E.: Sea-salt corrections and interpretation of constituent ratios in marine precipitation, J. Geophys. Res., 91, 6647–6658, https://doi.org/10.1029/JD091iD06p06647, 1986.
Lesworth, T., Baker, A. R., and Jickells, T.: Aerosol organic nitrogen over the remote Atlantic Ocean, Atmos. Environ., 44, 1887–1893, https://doi.org/10.1016/j.atmosenv.2010.02.021, 2010.
Li, Y., Fu, T.-M., Yu, J. Z., Yu, X., Chen, Q., Miao, R., Zhou, Y., Zhang, A., Ye, J., Yang, X., Tao, S., Liu, H., and Yao, W.: Dissecting the contributions of organic nitrogen aerosols to global atmospheric nitrogen deposition and implications for ecosystems, Natl. Sci. Rev., 10, nwad244, https://doi.org/10.1093/nsr/nwad244, 2023.
Li, Y., Fu, T.-M., Yu, J. Z., Zhang, A., Yu, X., Ye, J., Zhu, L., Shen, H., Wang, C., Yang, X., Tao, S., Chen, Q., Li, Y., Li, L., Che, H., and Heald, C. L.: Nitrogen dominates global atmospheric organic aerosol absorption, Science, 387, 989–995, https://doi.org/10.1126/science.adr4473, 2025.
Luo, L., Kao, S.-J., Bao, H., Xiao, H., Xiao, H., Yao, X., Gao, H., Li, J., and Lu, Y.: Sources of reactive nitrogen in marine aerosol over the Northwest Pacific Ocean in spring, Atmos. Chem. Phys., 18, 6207–6222, https://doi.org/10.5194/acp-18-6207-2018, 2018.
Mace, K. A., Duce, R. A., and Tindale, N. W.: Organic nitrogen in rain and aerosol at Cape Grim, Tasmania, Australia, J. Geophys. Res., 108, 2002JD003051, https://doi.org/10.1029/2002JD003051, 2003.
Matsumoto, K., Yamamoto, Y., Nishizawa, K., Kaneyasu, N., Irino, T., and Yoshikawa-Inoue, H.: Origin of the water-soluble organic nitrogen in the maritime aerosol, Atmos. Environ., 167, 97–103, https://doi.org/10.1016/j.atmosenv.2017.07.050, 2017.
Matsumoto, K., Kobayashi, H., Hara, K., Ishino, S., and Hayashi, M.: Water-soluble organic nitrogen in fine aerosols over the Southern Ocean, Atmos. Environ., 287, 119287, https://doi.org/10.1016/j.atmosenv.2022.119287, 2022.
Mirrielees, J. A., Kirpes, R. M., Costa, E. J., Porter, G. C. E., Murray, B. J., Lata, N. N., Boschi, V., China, S., Grannas, A. M., Ault, A. P., Matrai, P. A., and Pratt, K. A.: Marine aerosol generation experiments in the High Arctic during summertime, Elementa Sci. Anth., 12, 00134, https://doi.org/10.1525/elementa.2023.00134, 2024.
Miyazaki, Y., Kawamura, K., Jung, J., Furutani, H., and Uematsu, M.: Latitudinal distributions of organic nitrogen and organic carbon in marine aerosols over the western North Pacific, Atmos. Chem. Phys., 11, 3037–3049, https://doi.org/10.5194/acp-11-3037-2011, 2011.
Ng, N. L., Brown, S. S., Archibald, A. T., Atlas, E., Cohen, R. C., Crowley, J. N., Day, D. A., Donahue, N. M., Fry, J. L., Fuchs, H., Griffin, R. J., Guzman, M. I., Herrmann, H., Hodzic, A., Iinuma, Y., Jimenez, J. L., Kiendler-Scharr, A., Lee, B. H., Luecken, D. J., Mao, J., McLaren, R., Mutzel, A., Osthoff, H. D., Ouyang, B., Picquet-Varrault, B., Platt, U., Pye, H. O. T., Rudich, Y., Schwantes, R. H., Shiraiwa, M., Stutz, J., Thornton, J. A., Tilgner, A., Williams, B. J., and Zaveri, R. A.: Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol, Atmos. Chem. Phys., 17, 2103–2162, https://doi.org/10.5194/acp-17-2103-2017, 2017.
Nøjgaard, J. K., Peker, L., Pernov, J. B., Johnson, M. S., Bossi, R., Massling, A., Lange, R., Nielsen, I. E., Prevot, A. S. H., Eriksson, A. C., Canonaco, F., and Skov, H.: A local marine source of atmospheric particles in the High Arctic, Atmos. Environ., 285, 119241, https://doi.org/10.1016/j.atmosenv.2022.119241, 2022.
Park, K., Lee, K., Kim, T., Yoon, Y. J., Jang, E., Jang, S., Lee, B., and Hermansen, O.: Atmospheric DMS in the Arctic Ocean and Its Relation to Phytoplankton Biomass, Global Biogeochemical Cy., 32, 351–359, https://doi.org/10.1002/2017GB005805, 2018.
Pavuluri, C. M., Kawamura, K., and Fu, P. Q.: Atmospheric chemistry of nitrogenous aerosols in northeastern Asia: biological sources and secondary formation, Atmos. Chem. Phys., 15, 9883–9896, https://doi.org/10.5194/acp-15-9883-2015, 2015.
Quinby-Hunt, M. S. and Turehian, K. K.: Distribution of elements in sea water, EoS Trans. Am. Geophys. Union, 64, 130–130, https://doi.org/10.1029/EO064i014p00130, 1983.
Shi, G., Ma, H., Zhu, Z., Hu, Z., Chen, Z., Jiang, S., An, C., Yu, J., Ma, T., Li, Y., Sun, B., and Hastings, M. G.: Using stable isotopes to distinguish atmospheric nitrate production and its contribution to the surface ocean across hemispheres, Earth Planet. Sci. Lett., 564, 116914, https://doi.org/10.1016/j.epsl.2021.116914, 2021.
Shubhankar, B. and Ambade, B.: Chemical characterization of carbonaceous carbon from industrial and semi urban site of eastern India, SpringerPlus, 5, 837, https://doi.org/10.1186/s40064-016-2506-9, 2016.
Siegel, D. A., Behrenfeld, M. J., Maritorena, S., McClain, C. R., Antoine, D., Bailey, S. W., Bontempi, P. S., Boss, E. S., Dierssen, H. M., Doney, S. C., Eplee, R. E., Evans, R. H., Feldman, G. C., Fields, E., Franz, B. A., Kuring, N. A., Mengelt, C., Nelson, N. B., Patt, F. S., Robinson, W. D., Sarmiento, J. L., Swan, C. M., Werdell, P. J., Westberry, T. K., Wilding, J. G., and Yoder, J. A.: Regional to global assessments of phytoplankton dynamics from the SeaWiFS mission, Remote Sens. Environ., 135, 77–91, https://doi.org/10.1016/j.rse.2013.03.025, 2013.
Song, J., Zhao, Y., Zhang, Y., Fu, P., Zheng, L., Yuan, Q., Wang, S., Huang, X., Xu, W., Cao, Z., Gromov, S., and Lai, S.: Influence of biomass burning on atmospheric aerosols over the western South China Sea: Insights from ions, carbonaceous fractions and stable carbon isotope ratios, Environ. Pollut., 242, 1800–1809, https://doi.org/10.1016/j.envpol.2018.07.088, 2018.
Stein, A. F., Draxler, R. R., Rolph, G. D., Stunder, B. J. B., Cohen, M. D., and Ngan, F.: NOAA's HYSPLIT Atmospheric Transport and Dispersion Modeling System, B. Am. Meteorol. Soc., 96, 2059–2077, https://doi.org/10.1175/BAMS-D-14-00110.1, 2015.
Sun, N.: Spatial distribution of organic nitrogen in the global marine boundary layer from Arctic to Antarctic, National Tibetan Plateau/Third Pole Environment Data Center [data set], https://doi.org/10.11888/Atmos.tpdc.303043, 2025.
Taubert, M., Grob, C., Howat, A. M., Burns, O. J., Pratscher, J., Jehmlich, N., Von Bergen, M., Richnow, H. H., Chen, Y., and Murrell, J. C.: Methylamine as a nitrogen source for microorganisms from a coastal marine environment, Environ. Microbiol., 19, 2246–2257, https://doi.org/10.1111/1462-2920.13709, 2017.
Tian, M., Li, H., Wang, G., Fu, M., Qin, X., Lu, D., Liu, C., Zhu, Y., Luo, X., Deng, C., Abdullaev, S. F., and Huang, K.: Seasonal source identification and formation processes of marine particulate water soluble organic nitrogen over an offshore island in the East China Sea, Sci. Total Environ., 863, 160895, https://doi.org/10.1016/j.scitotenv.2022.160895, 2023.
Violaki, K., Sciare, J., Williams, J., Baker, A. R., Martino, M., and Mihalopoulos, N.: Atmospheric water-soluble organic nitrogen (WSON) over marine environments: a global perspective, Biogeosciences, 12, 3131–3140, https://doi.org/10.5194/bg-12-3131-2015, 2015.
Wilson, T. W., Ladino, L. A., Alpert, P. A., Breckels, M. N., Brooks, I. M., Browse, J., Burrows, S. M., Carslaw, K. S., Huffman, J. A., Judd, C., Kilthau, W. P., Mason, R. H., McFiggans, G., Miller, L. A., Nájera, J. J., Polishchuk, E., Rae, S., Schiller, C. L., Si, M., Temprado, J. V., Whale, T. F., Wong, J. P. S., Wurl, O., Yakobi-Hancock, J. D., Abbatt, J. P. D., Aller, J. Y., Bertram, A. K., Knopf, D. A., and Murray, B. J.: A marine biogenic source of atmospheric ice-nucleating particles, Nature, 525, 234–238, https://doi.org/10.1038/nature14986, 2015.
Wu, C. and Yu, J. Z.: Determination of primary combustion source organic carbon-to-elemental carbon (
Wu, G., Hu, Y., Gong, C., Wang, D., Zhang, F., Herath, I. K., Chen, Z., and Shi, G.: Spatial distribution, sources, and direct radiative effect of carbonaceous aerosol along a transect from the Arctic Ocean to Antarctica, Sci. Total Environ., 916, 170136, https://doi.org/10.1016/j.scitotenv.2024.170136, 2024.
Xiao, H.-W., Xiao, H.-Y., Luo, L., Shen, C.-Y., Long, A.-M., Chen, L., Long, Z.-H., and Li, D.-N.: Atmospheric aerosol compositions over the South China Sea: temporal variability and source apportionment, Atmos. Chem. Phys., 17, 3199–3214, https://doi.org/10.5194/acp-17-3199-2017, 2017.
Yan, J., Jung, J., Lin, Q., Zhang, M., Xu, S., and Zhao, S.: Effect of sea ice retreat on marine aerosol emissions in the Southern Ocean, Antarctica, Sci. Total Environ., 745, 140773, https://doi.org/10.1016/j.scitotenv.2020.140773, 2020.
Yan, S., Xu, G., Zhang, H., Wang, J., Xu, F., Gao, X., Zhang, J., Wu, J., and Yang, G.: Factors Controlling DMS Emission and Atmospheric Sulfate Aerosols in the Western Pacific Continental Sea, J. Geophys. Res., 129, e2024JC020886, https://doi.org/10.1029/2024JC020886, 2024.
Yu, X., Li, Q., Ge, Y., Li, Y., Liao, K., Huang, X. H., Li, J., and Yu, J. Z.: Simultaneous Determination of Aerosol Inorganic and Organic Nitrogen by Thermal Evolution and Chemiluminescence Detection, Environ. Sci. Technol., 55, 11579–11589, https://doi.org/10.1021/acs.est.1c04876, 2021.
Zamora, L. M., Prospero, J. M., and Hansell, D. A.: Organic nitrogen in aerosols and precipitation at Barbados and Miami: Implications regarding sources, transport and deposition to the western subtropical North Atlantic, J. Geophys. Res., 116, D20309, https://doi.org/10.1029/2011JD015660, 2011.
Zhou, S., Chen, Y., Paytan, A., Li, H., Wang, F., Zhu, Y., Yang, T., Zhang, Y., and Zhang, R.: Non-Marine Sources Contribute to Aerosol Methanesulfonate Over Coastal Seas, J. Geophys. Res.: Atmospheres, 126, e2021JD034960, https://doi.org/10.1029/2021JD034960, 2021.
Zhou, S., Chen, Y., Wang, F., Bao, Y., Ding, X., and Xu, Z.: Assessing the Intensity of Marine Biogenic Influence on the Lower Atmosphere: An Insight into the Distribution of Marine Biogenic Aerosols over the Eastern China Seas, Environ. Sci. Technol., 57, 12741–12751, https://doi.org/10.1021/acs.est.3c04382, 2023.
Short summary
Atmospheric particles over the ocean contain organic nitrogen, affecting climate and ecosystems. This first pole-to-pole study of marine air reveals a strong latitudinal divide, with higher concentrations in the polluted Northern Hemisphere. A key discovery is that air influenced by Antarctic sea ice is enriched in organic nitrogen, revealing a major natural source. Our new dataset improves climate models by clarifying how human emissions and natural processes shape the atmosphere.
Atmospheric particles over the ocean contain organic nitrogen, affecting climate and ecosystems....
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