Articles | Volume 23, issue 5
https://doi.org/10.5194/acp-23-3133-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-23-3133-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
10 Mar 2023
Research article |
| 10 Mar 2023
| 10 Mar 2023
South Pole Station ozonesondes: variability and trends in the springtime Antarctic ozone hole 1986–2021
Bryan J. Johnson
CORRESPONDING AUTHOR
Global Monitoring Laboratory Earth System Research Laboratory, NOAA,
Boulder, CO 80305, USA
Patrick Cullis
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, Boulder, CO 80309, USA
Global Monitoring Laboratory Earth System Research Laboratory, NOAA,
Boulder, CO 80305, USA
John Booth
Global Monitoring Laboratory Earth System Research Laboratory, NOAA,
Boulder, CO 80305, USA
deceased
Irina Petropavlovskikh
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, Boulder, CO 80309, USA
Global Monitoring Laboratory Earth System Research Laboratory, NOAA,
Boulder, CO 80305, USA
Glen McConville
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, Boulder, CO 80309, USA
Global Monitoring Laboratory Earth System Research Laboratory, NOAA,
Boulder, CO 80305, USA
Birgit Hassler
Institut für
Physik der Atmosphäre, Deutsches Zentrum für Luft & Raumfahrt (DLR), Oberpfaffenhofen, Germany
Gary A. Morris
Global Monitoring Laboratory Earth System Research Laboratory, NOAA,
Boulder, CO 80305, USA
Chance Sterling
Cooperative Institute for Research in Environmental Sciences,
University of Colorado, Boulder, CO 80309, USA
C&D Technologies/Trojan Battery Company, Horsham, PA 19044, USA
Samuel Oltmans
Global Monitoring Laboratory Earth System Research Laboratory, NOAA,
Boulder, CO 80305, USA
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Chance W. Sterling, Bryan J. Johnson, Samuel J. Oltmans, Herman G. J. Smit, Allen F. Jordan, Patrick D. Cullis, Emrys G. Hall, Anne M. Thompson, and Jacquelyn C. Witte
Atmos. Meas. Tech., 11, 3661–3687, https://doi.org/10.5194/amt-11-3661-2018, https://doi.org/10.5194/amt-11-3661-2018, 2018
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Atmos. Meas. Tech., 10, 3865–3876, https://doi.org/10.5194/amt-10-3865-2017, https://doi.org/10.5194/amt-10-3865-2017, 2017
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Terry Deshler, Rene Stübi, Francis J. Schmidlin, Jennifer L. Mercer, Herman G. J. Smit, Bryan J. Johnson, Rigel Kivi, and Bruno Nardi
Atmos. Meas. Tech., 10, 2021–2043, https://doi.org/10.5194/amt-10-2021-2017, https://doi.org/10.5194/amt-10-2021-2017, 2017
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Gerard Ancellet, Nikos Daskalakis, Jean Christophe Raut, David Tarasick, Jonathan Hair, Boris Quennehen, François Ravetta, Hans Schlager, Andrew J. Weinheimer, Anne M. Thompson, Bryan Johnson, Jennie L. Thomas, and Katharine S. Law
Atmos. Chem. Phys., 16, 13341–13358, https://doi.org/10.5194/acp-16-13341-2016, https://doi.org/10.5194/acp-16-13341-2016, 2016
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Daan Hubert, Jean-Christopher Lambert, Tijl Verhoelst, José Granville, Arno Keppens, Jean-Luc Baray, Adam E. Bourassa, Ugo Cortesi, Doug A. Degenstein, Lucien Froidevaux, Sophie Godin-Beekmann, Karl W. Hoppel, Bryan J. Johnson, Erkki Kyrölä, Thierry Leblanc, Günter Lichtenberg, Marion Marchand, C. Thomas McElroy, Donal Murtagh, Hideaki Nakane, Thierry Portafaix, Richard Querel, James M. Russell III, Jacobo Salvador, Herman G. J. Smit, Kerstin Stebel, Wolfgang Steinbrecht, Kevin B. Strawbridge, René Stübi, Daan P. J. Swart, Ghassan Taha, David W. Tarasick, Anne M. Thompson, Joachim Urban, Joanna A. E. van Gijsel, Roeland Van Malderen, Peter von der Gathen, Kaley A. Walker, Elian Wolfram, and Joseph M. Zawodny
Atmos. Meas. Tech., 9, 2497–2534, https://doi.org/10.5194/amt-9-2497-2016, https://doi.org/10.5194/amt-9-2497-2016, 2016
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A more detailed understanding of satellite O3 profile data records is vital for further progress in O3 research. To this end, we made a comprehensive assessment of 14 limb/occultation profilers using ground-based reference data. The mutual consistency of satellite O3 in terms of bias, short-term variability and decadal stability is generally good over most of the stratosphere. However, we identified some exceptions that impact the quality of recently merged data sets and ozone trend assessments.
R. Ahmadov, S. McKeen, M. Trainer, R. Banta, A. Brewer, S. Brown, P. M. Edwards, J. A. de Gouw, G. J. Frost, J. Gilman, D. Helmig, B. Johnson, A. Karion, A. Koss, A. Langford, B. Lerner, J. Olson, S. Oltmans, J. Peischl, G. Pétron, Y. Pichugina, J. M. Roberts, T. Ryerson, R. Schnell, C. Senff, C. Sweeney, C. Thompson, P. R. Veres, C. Warneke, R. Wild, E. J. Williams, B. Yuan, and R. Zamora
Atmos. Chem. Phys., 15, 411–429, https://doi.org/10.5194/acp-15-411-2015, https://doi.org/10.5194/acp-15-411-2015, 2015
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High 2013 wintertime O3 pollution events associated with oil/gas production within the Uinta Basin are studied using a 3D model. It's able quantitatively to reproduce these events using emission estimates of O3 precursors based on ambient measurements (top-down approach), but unable to reproduce them using a recent bottom-up emission inventory for the oil/gas industry. The role of various physical and meteorological processes, chemical species and pathways contributing to high O3 are quantified.
S. J. Oltmans, A. Karion, R. C. Schnell, G. Pétron, C. Sweeney, S. Wolter, D. Neff, S. A. Montzka, B. R. Miller, D. Helmig, B. J. Johnson, and J. Hueber
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-20117-2014, https://doi.org/10.5194/acpd-14-20117-2014, 2014
Revised manuscript not accepted
M. C. Parrondo, M. Gil, M. Yela, B. J. Johnson, and H. A. Ochoa
Atmos. Chem. Phys., 14, 217–229, https://doi.org/10.5194/acp-14-217-2014, https://doi.org/10.5194/acp-14-217-2014, 2014
Wanmin Gong, Stephen R. Beagley, Kenjiro Toyota, Henrik Skov, Jesper Heile Christensen, Alex Lupu, Diane Pendlebury, Junhua Zhang, Ulas Im, Yugo Kanaya, Alfonso Saiz-Lopez, Roberto Sommariva, Peter Effertz, John W. Halfacre, Nis Jepsen, Rigel Kivi, Theodore K. Koenig, Katrin Müller, Claus Nordstrøm, Irina Petropavlovskikh, Paul B. Shepson, William R. Simpson, Sverre Solberg, Ralf M. Staebler, David W. Tarasick, Roeland Van Malderen, and Mika Vestenius
Atmos. Chem. Phys., 25, 8355–8405, https://doi.org/10.5194/acp-25-8355-2025, https://doi.org/10.5194/acp-25-8355-2025, 2025
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This study showed that the springtime O3 depletion plays a critical role in driving the surface O3 seasonal cycle in the central Arctic. The O3 depletion events, while occurring most notably within the lowest few hundred metres above the Arctic Ocean, can induce a 5–7 % loss in the pan-Arctic tropospheric O3 burden during springtime. The study also found enhancements in O3 and NOy (mostly peroxyacetyl nitrate) concentrations in the Arctic due to northern boreal wildfires, particularly at higher altitudes.
Yue Li, Gang Tang, Eleanor O’Rourke, Samar Minallah, Martim Mas e Braga, Sophie Nowicki, Robin S. Smith, David M. Lawrence, George C. Hurtt, Daniele Peano, Gesa Meyer, Birgit Hassler, Jiafu Mao, Yongkang Xue, and Martin Juckes
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This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
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Land and Land Ice Theme Opportunities describe a list that contains 25 variable groups with 716 variables, which are potentially available to the broad scientific audience for performing analysis in land-atmosphere coupling, hydrological processes and freshwater systems, glacier and ice sheet mass balance and their influence on the sea levels, land use, and plant phenology.
Alex C. Ruane, Charlotte L. Pascoe, Claas Teichmann, David J. Brayshaw, Carlo Buontempo, Ibrahima Diouf, Jesus Fernandez, Paula L. M. Gonzalez, Birgit Hassler, Vanessa Hernaman, Ulas Im, Doroteaciro Iovino, Martin Juckes, Iréne L. Lake, Timothy Lam, Xiaomao Lin, Jiafu Mao, Negin Nazarian, Sylvie Parey, Indrani Roy, Wan-Ling Tseng, Briony Turner, Andrew Wiebe, Lei Zhao, and Damaris Zurell
EGUsphere, https://doi.org/10.5194/egusphere-2025-3408, https://doi.org/10.5194/egusphere-2025-3408, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
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This paper describes how the Coupled Model Intercomparison Project organized its 7th phase (CMIP7) to encourage the production of Earth system model outputs relevant for impacts and adaptation. Community engagement identified 13 opportunities for application across human and natural systems, 60 variable groups and 539 unique variables. We also show how simulations can more efficiently meet applications needs by targeting appropriate resolution, time slices, experiments and variable groups.
Mara Y. McPartland, Tomas Lovato, Charles D. Koven, Jamie D. Wilson, Briony Turner, Colleen M. Petrik, José Licón-Saláiz, Fang Li, Fanny Lhardy, Jaclyn Clement Kinney, Michio Kawamiya, Birgit Hassler, Nathan P. Gillett, Cheikh Modou Noreyni Fall, Christopher Danek, Chris M. Brierley, Ana Bastos, and Oliver Andrews
EGUsphere, https://doi.org/10.5194/egusphere-2025-3246, https://doi.org/10.5194/egusphere-2025-3246, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
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The Coupled Model Intercomparison Project (CMIP) is an international consortium of climate modeling groups that produce coordinated experiments in order to evaluate human influence on the climate and test knowledge of Earth systems. This paper describes the data requested for Earth systems research in CMIP7. We detail the request for model output of the carbon cycle, the flows of energy among the atmosphere, land and the oceans, and interactions between these and the global climate.
Roeland Van Malderen, Anne M. Thompson, Debra E. Kollonige, Ryan M. Stauffer, Herman G. J. Smit, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, David W. Tarasick, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Stéphanie Evan, Victoria Flood, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Marco Iarlori, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Glen McConville, Katrin Müller, Tomoo Nagahama, Justus Notholt, Ankie Piters, Natalia Prats, Richard Querel, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
Atmos. Chem. Phys., 25, 7187–7225, https://doi.org/10.5194/acp-25-7187-2025, https://doi.org/10.5194/acp-25-7187-2025, 2025
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Tropospheric ozone is an important greenhouse gas and is an air pollutant. The time variability of tropospheric ozone is mainly driven by anthropogenic emissions. In this paper, we study the distribution and time variability of ozone from harmonized ground-based observations from five different measurement techniques. Our findings provide clear standard references for atmospheric models and evolving tropospheric ozone satellite data for the 2000–2022 period.
Forrest M. Hoffman, Birgit Hassler, Ranjini Swaminathan, Jared Lewis, Bouwe Andela, Nathaniel Collier, Dóra Hegedűs, Jiwoo Lee, Charlotte Pascoe, Mika Pflüger, Martina Stockhause, Paul Ullrich, Min Xu, Lisa Bock, Felicity Chun, Bettina K. Gier, Douglas I. Kelley, Axel Lauer, Julien Lenhardt, Manuel Schlund, Mohanan G. Sreeush, Katja Weigel, Ed Blockley, Rebecca Beadling, Romain Beucher, Demiso D. Dugassa, Valerio Lembo, Jianhua Lu, Swen Brands, Jerry Tjiputra, Elizaveta Malinina, Brian Mederios, Enrico Scoccimarro, Jeremy Walton, Philip Kershaw, André L. Marquez, Malcolm J. Roberts, Eleanor O’Rourke, Elisabeth Dingley, Briony Turner, Helene Hewitt, and John P. Dunne
EGUsphere, https://doi.org/10.5194/egusphere-2025-2685, https://doi.org/10.5194/egusphere-2025-2685, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
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As Earth system models become more complex, rapid and comprehensive evaluation through comparison with observational data is necessary. The upcoming Assessment Fast Track for the Seventh Phase of the Coupled Model Intercomparison Project (CMIP7) will require fast analysis. This paper describes a new Rapid Evaluation Framework (REF) that was developed for the Assessment Fast Track that will be run at the Earth System Grid Federation (ESGF) to inform the community about the performance of models.
Beth Dingley, James A. Anstey, Marta Abalos, Carsten Abraham, Tommi Bergman, Lisa Bock, Sonya Fiddes, Birgit Hassler, Ryan J. Kramer, Fei Luo, Fiona M. O'Connor, Petr Šácha, Isla R. Simpson, Laura J. Wilcox, and Mark D. Zelinka
EGUsphere, https://doi.org/10.5194/egusphere-2025-3189, https://doi.org/10.5194/egusphere-2025-3189, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
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This manuscript defines as a list of variables and scientific opportunities which are requested from the CMIP7 Assessment Fast Track to address open atmospheric science questions. The list reflects the output of a large public community engagement effort, coordinated across autumn 2025 through to summer 2025.
Manuel Schlund, Bouwe Andela, Jörg Benke, Ruth Comer, Birgit Hassler, Emma Hogan, Peter Kalverla, Axel Lauer, Bill Little, Saskia Loosveldt Tomas, Francesco Nattino, Patrick Peglar, Valeriu Predoi, Stef Smeets, Stephen Worsley, Martin Yeo, and Klaus Zimmermann
Geosci. Model Dev., 18, 4009–4021, https://doi.org/10.5194/gmd-18-4009-2025, https://doi.org/10.5194/gmd-18-4009-2025, 2025
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The Earth System Model Evaluation Tool (ESMValTool) is a community diagnostics and performance metrics tool for the evaluation of Earth system models. Here, we describe recent significant improvements of ESMValTool’s computational efficiency including parallel, out-of-core, and distributed computing. Evaluations with the enhanced version of ESMValTool are faster, use less computational resources, and can handle input data larger than the available memory.
Aytaç Paçal, Birgit Hassler, Katja Weigel, Miguel-Ángel Fernández-Torres, Gustau Camps-Valls, and Veronika Eyring
EGUsphere, https://doi.org/10.5194/egusphere-2025-2460, https://doi.org/10.5194/egusphere-2025-2460, 2025
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Heatwaves are among the deadliest natural hazards, yet their causes and changes over time are not fully understood. We analyzed European heatwaves using a machine learning method that detects atmospheric patterns from these data. Our findings show that recent summer heatwaves differ from historical ones, indicating a shift in atmospheric dynamics consistent with climate change. This approach improves our understanding of the temporal evolution of heatwaves.
Lukas Lindenlaub, Katja Weigel, Birgit Hassler, Colin Jones, and Veronika Eyring
EGUsphere, https://doi.org/10.5194/egusphere-2025-1517, https://doi.org/10.5194/egusphere-2025-1517, 2025
This preprint is open for discussion and under review for Earth System Dynamics (ESD).
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This study explores changes in drought characteristic based on projections by 18 different Earth system models. Their performance is evaluated by comparing historical simulations to observation based reanalysis. The analysis of a standardized drought index under different future scenarios revealed that the harvest area that is projected to experience extreme drought conditions towards the end of this century ranges from 10 % to 40 % depending on the emission scenario.
Irina Petropavlovskikh, Jeannette D. Wild, Kari Abromitis, Peter Effertz, Koji Miyagawa, Lawrence E. Flynn, Eliane Maillard Barras, Robert Damadeo, Glen McConville, Bryan Johnson, Patrick Cullis, Sophie Godin-Beekmann, Gerard Ancellet, Richard Querel, Roeland Van Malderen, and Daniel Zawada
Atmos. Chem. Phys., 25, 2895–2936, https://doi.org/10.5194/acp-25-2895-2025, https://doi.org/10.5194/acp-25-2895-2025, 2025
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Observational records show that stratospheric ozone is recovering in accordance with the implementation of the Montreal Protocol and its amendments. Natural ozone variability complicates the detection of small trends. This study optimizes a statistical model fit in ground-station-based observational records by adding parameters that interpret seasonal and long-term changes in atmospheric circulation and airmass mixing, which reduces uncertainties in detecting the stratospheric ozone recovery.
Axel Lauer, Lisa Bock, Birgit Hassler, Patrick Jöckel, Lukas Ruhe, and Manuel Schlund
Geosci. Model Dev., 18, 1169–1188, https://doi.org/10.5194/gmd-18-1169-2025, https://doi.org/10.5194/gmd-18-1169-2025, 2025
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Earth system models are important tools to improve our understanding of current climate and to project climate change. Thus, it is crucial to understand possible shortcomings in the models. New features of the ESMValTool software package allow one to compare and visualize a model's performance with respect to reproducing observations in the context of other climate models in an easy and user-friendly way. We aim to help model developers assess and monitor climate simulations more efficiently.
Jingyu Wang, Gabriel Chiodo, Timofei Sukhodolov, Blanca Ayarzagüena, William T. Ball, Mohamadou Diallo, Birgit Hassler, James Keeble, Peer Nowack, Clara Orbe, and Sandro Vattioni
EGUsphere, https://doi.org/10.5194/egusphere-2025-340, https://doi.org/10.5194/egusphere-2025-340, 2025
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We analyzed the ozone response under elevated CO2 using the data from CMIP6 DECK experiments. We then looked at the relations between ozone response and temperature and circulation changes to identify drivers of the ozone change. The climate feedback of ozone is investigated by doing offline calculations and comparing models with and without interactive chemistry. We find that ozone-climate interactions are important for Earth System Models, thus should be considered in future model development.
Roeland Van Malderen, Zhou Zang, Kai-Lan Chang, Robin Björklund, Owen R. Cooper, Jane Liu, Eliane Maillard Barras, Corinne Vigouroux, Irina Petropavlovskikh, Thierry Leblanc, Valérie Thouret, Pawel Wolff, Peter Effertz, Audrey Gaudel, David W. Tarasick, Herman G. J. Smit, Anne M. Thompson, Ryan M. Stauffer, Debra E. Kollonige, Deniz Poyraz, Gérard Ancellet, Marie-Renée De Backer, Matthias M. Frey, James W. Hannigan, José L. Hernandez, Bryan J. Johnson, Nicholas Jones, Rigel Kivi, Emmanuel Mahieu, Isamu Morino, Glen McConville, Katrin Müller, Isao Murata, Justus Notholt, Ankie Piters, Maxime Prignon, Richard Querel, Vincenzo Rizi, Dan Smale, Wolfgang Steinbrecht, Kimberly Strong, and Ralf Sussmann
EGUsphere, https://doi.org/10.5194/egusphere-2024-3745, https://doi.org/10.5194/egusphere-2024-3745, 2025
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Tropospheric ozone is an important greenhouse gas and an air pollutant, whose distribution and time variability is mainly governed by anthropogenic emissions and dynamics. In this paper, we assess regional trends of tropospheric ozone column amounts, based on two different approaches of merging or synthesizing ground-based observations and their trends within specific regions. Our findings clearly demonstrate regional trend differences, but also consistently higher pre- than post-COVID trends.
John Patrick Dunne, Helene T. Hewitt, Julie Arblaster, Frédéric Bonou, Olivier Boucher, Tereza Cavazos, Paul J. Durack, Birgit Hassler, Martin Juckes, Tomoki Miyakawa, Matthew Mizielinski, Vaishali Naik, Zebedee Nicholls, Eleanor O’Rourke, Robert Pincus, Benjamin M. Sanderson, Isla R. Simpson, and Karl E. Taylor
EGUsphere, https://doi.org/10.5194/egusphere-2024-3874, https://doi.org/10.5194/egusphere-2024-3874, 2024
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This manuscript provides the motivation and experimental design for the seventh phase of the Coupled Model Intercomparison Project (CMIP7) to coordinate community based efforts to answer key and timely climate science questions and facilitate delivery of relevant multi-model simulations for: prediction and projection, characterization, attribution and process understanding; vulnerability, impacts and adaptations analysis; national and international climate assessments; and society at large.
Zhou Zang, Jane Liu, David Tarasick, Omid Moeini, Jianchun Bian, Jinqiang Zhang, Anne M. Thompson, Roeland Van Malderen, Herman G. J. Smit, Ryan M. Stauffer, Bryan J. Johnson, and Debra E. Kollonige
Atmos. Chem. Phys., 24, 13889–13912, https://doi.org/10.5194/acp-24-13889-2024, https://doi.org/10.5194/acp-24-13889-2024, 2024
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The Trajectory-mapped Ozonesonde dataset for the Stratosphere and Troposphere (TOST) provides a global-scale, long-term ozone climatology that is horizontally and vertically resolved. In this study, we improved, updated and validated TOST from 1970 to 2021. Based on this TOST dataset, we characterized global ozone variations spatially in both the troposphere and stratosphere and temporally by season and decade. We also showed a stagnant lower stratospheric ozone variation since the late 1990s.
Robin Björklund, Corinne Vigouroux, Peter Effertz, Omaira E. García, Alex Geddes, James Hannigan, Koji Miyagawa, Michael Kotkamp, Bavo Langerock, Gerald Nedoluha, Ivan Ortega, Irina Petropavlovskikh, Deniz Poyraz, Richard Querel, John Robinson, Hisako Shiona, Dan Smale, Penny Smale, Roeland Van Malderen, and Martine De Mazière
Atmos. Meas. Tech., 17, 6819–6849, https://doi.org/10.5194/amt-17-6819-2024, https://doi.org/10.5194/amt-17-6819-2024, 2024
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Different ground-based ozone measurements from the last 2 decades at Lauder are compared to each other. We want to know why different trends have been observed in the stratosphere. Also, the quality and relevance of tropospheric datasets need to be evaluated. While remaining drifts are still present, our study explains roughly half of the differences in observed trends in previous studies and shows the necessity for continuous review and improvement of the measurements.
Andrew O. Langford, Raul J. Alvarez II, Kenneth C. Aikin, Sunil Baidar, W. Alan Brewer, Steven S. Brown, Matthew M. Coggan, Patrick D. Cullis, Jessica Gilman, Georgios I. Gkatzelis, Detlev Helmig, Bryan J. Johnson, K. Emma Knowland, Rajesh Kumar, Aaron D. Lamplugh, Audra McClure-Begley, Brandi J. McCarty, Ann M. Middlebrook, Gabriele Pfister, Jeff Peischl, Irina Petropavlovskikh, Pamela S. Rickley, Andrew W. Rollins, Scott P. Sandberg, Christoph J. Senff, and Carsten Warneke
EGUsphere, https://doi.org/10.5194/egusphere-2024-1938, https://doi.org/10.5194/egusphere-2024-1938, 2024
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High ozone (O3) formed by reactions of nitrogen oxides (NOx) and volatile organic compounds (VOCs) can harm human health and welfare. High O3 is usually associated with hot summer days, but under certain conditions, high O3 can also form under winter conditions. In this study, we describe a high O3 event that occurred in Colorado during the COVID-19 quarantine that was caused in part by the decrease in traffic, and in part by a shallow inversion created by descent of stratospheric air.
Luis F. Millán, Peter Hoor, Michaela I. Hegglin, Gloria L. Manney, Harald Boenisch, Paul Jeffery, Daniel Kunkel, Irina Petropavlovskikh, Hao Ye, Thierry Leblanc, and Kaley Walker
Atmos. Chem. Phys., 24, 7927–7959, https://doi.org/10.5194/acp-24-7927-2024, https://doi.org/10.5194/acp-24-7927-2024, 2024
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In the Observed Composition Trends And Variability in the UTLS (OCTAV-UTLS) Stratosphere-troposphere Processes And their Role in Climate (SPARC) activity, we have mapped multiplatform ozone datasets into coordinate systems to systematically evaluate the influence of these coordinates on binned climatological variability. This effort unifies the work of studies that focused on individual coordinate system variability. Our goal was to create the most comprehensive assessment of this topic.
Arno Keppens, Serena Di Pede, Daan Hubert, Jean-Christopher Lambert, Pepijn Veefkind, Maarten Sneep, Johan De Haan, Mark ter Linden, Thierry Leblanc, Steven Compernolle, Tijl Verhoelst, José Granville, Oindrila Nath, Ann Mari Fjæraa, Ian Boyd, Sander Niemeijer, Roeland Van Malderen, Herman G. J. Smit, Valentin Duflot, Sophie Godin-Beekmann, Bryan J. Johnson, Wolfgang Steinbrecht, David W. Tarasick, Debra E. Kollonige, Ryan M. Stauffer, Anne M. Thompson, Angelika Dehn, and Claus Zehner
Atmos. Meas. Tech., 17, 3969–3993, https://doi.org/10.5194/amt-17-3969-2024, https://doi.org/10.5194/amt-17-3969-2024, 2024
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The Sentinel-5P satellite operated by the European Space Agency has carried the TROPOspheric Monitoring Instrument (TROPOMI) around the Earth since October 2017. This mission also produces atmospheric ozone profile data which are described in detail for May 2018 to April 2023. Independent validation using ground-based reference measurements demonstrates that the operational ozone profile product mostly fully and at least partially complies with all mission requirements.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, Peter Effertz, Gary Morris, and Brian C. McDonald
Atmos. Chem. Phys., 24, 6197–6218, https://doi.org/10.5194/acp-24-6197-2024, https://doi.org/10.5194/acp-24-6197-2024, 2024
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A great majority of observational trend studies of free tropospheric ozone use sparsely sampled ozonesonde and aircraft measurements as reference data sets. A ubiquitous assumption is that trends are accurate and reliable so long as long-term records are available. We show that sampling bias due to sparse samples can persistently reduce the trend accuracy, and we highlight the importance of maintaining adequate frequency and continuity of observations.
Ryan M. Stauffer, Anne M. Thompson, Debra E. Kollonige, Ninong Komala, Habib Khirzin Al-Ghazali, Dian Yudha Risdianto, Ambun Dindang, Ahmad Fairudz bin Jamaluddin, Mohan Kumar Sammathuria, Norazura Binti Zakaria, Bryan J. Johnson, and Patrick D. Cullis
Atmos. Chem. Phys., 24, 5221–5234, https://doi.org/10.5194/acp-24-5221-2024, https://doi.org/10.5194/acp-24-5221-2024, 2024
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SHADOZ balloon-borne ozone measurements over equatorial Southeast Asia from 1998–2022 reveal that ozone increases during the early months of the year are linked to reduced convective storm activity, which typically redistributes and cleans the atmosphere of ozone. These findings challenge models to replicate the trends produced by the SHADOZ and meteorological observations and emphasize the importance of studying monthly or seasonal instead of annual changes for understanding ozone trends.
Joseph Michalsky and Glen McConville
Atmos. Meas. Tech., 17, 1017–1022, https://doi.org/10.5194/amt-17-1017-2024, https://doi.org/10.5194/amt-17-1017-2024, 2024
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The ozone in the atmosphere is measured by looking at the sun and measuring how diminished the light in the ultraviolet is relative to how bright it is above the Earth's atmosphere. This typically uses spectral instruments that are either costly or no longer manufactured. This paper uses a relatively inexpensive interference filter instrument to perform the same task. Daily ozone measurements with the latter and this filter instrument are compared. Aerosols are calculated as a by-product.
Herman G. J. Smit, Deniz Poyraz, Roeland Van Malderen, Anne M. Thompson, David W. Tarasick, Ryan M. Stauffer, Bryan J. Johnson, and Debra E. Kollonige
Atmos. Meas. Tech., 17, 73–112, https://doi.org/10.5194/amt-17-73-2024, https://doi.org/10.5194/amt-17-73-2024, 2024
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This paper revisits fundamentals of ECC ozonesonde measurements to develop and characterize a methodology to correct for the fast and slow time responses using the JOSIE (Jülich Ozone Sonde Intercomparison Experiment) simulation chamber data. Comparing the new corrected ozonesonde profiles to an accurate ozone UV photometer (OPM) as reference allows us to evaluate the time response correction (TRC) method and to determine calibration functions traceable to one reference with 5 % uncertainty.
Davide Putero, Paolo Cristofanelli, Kai-Lan Chang, Gaëlle Dufour, Gregory Beachley, Cédric Couret, Peter Effertz, Daniel A. Jaffe, Dagmar Kubistin, Jason Lynch, Irina Petropavlovskikh, Melissa Puchalski, Timothy Sharac, Barkley C. Sive, Martin Steinbacher, Carlos Torres, and Owen R. Cooper
Atmos. Chem. Phys., 23, 15693–15709, https://doi.org/10.5194/acp-23-15693-2023, https://doi.org/10.5194/acp-23-15693-2023, 2023
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We investigated the impact of societal restriction measures during the COVID-19 pandemic on surface ozone at 41 high-elevation sites worldwide. Negative ozone anomalies were observed for spring and summer 2020 for all of the regions considered. In 2021, negative anomalies continued for Europe and partially for the eastern US, while western US sites showed positive anomalies due to wildfires. IASI satellite data and the Carbon Monitor supported emission reductions as a cause of the anomalies.
Vitali Fioletov, Xiaoyi Zhao, Ihab Abboud, Michael Brohart, Akira Ogyu, Reno Sit, Sum Chi Lee, Irina Petropavlovskikh, Koji Miyagawa, Bryan J. Johnson, Patrick Cullis, John Booth, Glen McConville, and C. Thomas McElroy
Atmos. Chem. Phys., 23, 12731–12751, https://doi.org/10.5194/acp-23-12731-2023, https://doi.org/10.5194/acp-23-12731-2023, 2023
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Stratospheric ozone within the Southern Hemisphere springtime polar vortex has been a subject of intense research since the discovery of the Antarctic ozone hole. The wintertime ozone in the vortex is less studied. We show that the recent wintertime ozone values over the South Pole were about 12 % below the pre-1980s level; i.e., the decline there was nearly twice as large as that over southern midlatitudes. Thus, wintertime ozone there can be used as an indicator of the ozone layer state.
Luis F. Millán, Gloria L. Manney, Harald Boenisch, Michaela I. Hegglin, Peter Hoor, Daniel Kunkel, Thierry Leblanc, Irina Petropavlovskikh, Kaley Walker, Krzysztof Wargan, and Andreas Zahn
Atmos. Meas. Tech., 16, 2957–2988, https://doi.org/10.5194/amt-16-2957-2023, https://doi.org/10.5194/amt-16-2957-2023, 2023
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The determination of atmospheric composition trends in the upper troposphere and lower stratosphere (UTLS) is still highly uncertain. We present the creation of dynamical diagnostics to map several ozone datasets (ozonesondes, lidars, aircraft, and satellite measurements) in geophysically based coordinate systems. The diagnostics can also be used to analyze other greenhouse gases relevant to surface climate and UTLS chemistry.
Cynthia H. Whaley, Kathy S. Law, Jens Liengaard Hjorth, Henrik Skov, Stephen R. Arnold, Joakim Langner, Jakob Boyd Pernov, Garance Bergeron, Ilann Bourgeois, Jesper H. Christensen, Rong-You Chien, Makoto Deushi, Xinyi Dong, Peter Effertz, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Greg Huey, Ulas Im, Rigel Kivi, Louis Marelle, Tatsuo Onishi, Naga Oshima, Irina Petropavlovskikh, Jeff Peischl, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Tom Ryerson, Ragnhild Skeie, Sverre Solberg, Manu A. Thomas, Chelsea Thompson, Kostas Tsigaridis, Svetlana Tsyro, Steven T. Turnock, Knut von Salzen, and David W. Tarasick
Atmos. Chem. Phys., 23, 637–661, https://doi.org/10.5194/acp-23-637-2023, https://doi.org/10.5194/acp-23-637-2023, 2023
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This study summarizes recent research on ozone in the Arctic, a sensitive and rapidly warming region. We find that the seasonal cycles of near-surface atmospheric ozone are variable depending on whether they are near the coast, inland, or at high altitude. Several global model simulations were evaluated, and we found that because models lack some of the ozone chemistry that is important for the coastal Arctic locations, they do not accurately simulate ozone there.
Manuel Schlund, Birgit Hassler, Axel Lauer, Bouwe Andela, Patrick Jöckel, Rémi Kazeroni, Saskia Loosveldt Tomas, Brian Medeiros, Valeriu Predoi, Stéphane Sénési, Jérôme Servonnat, Tobias Stacke, Javier Vegas-Regidor, Klaus Zimmermann, and Veronika Eyring
Geosci. Model Dev., 16, 315–333, https://doi.org/10.5194/gmd-16-315-2023, https://doi.org/10.5194/gmd-16-315-2023, 2023
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The Earth System Model Evaluation Tool (ESMValTool) is a community diagnostics and performance metrics tool for routine evaluation of Earth system models. Originally, ESMValTool was designed to process reformatted output provided by large model intercomparison projects like the Coupled Model Intercomparison Project (CMIP). Here, we describe a new extension of ESMValTool that allows for reading and processing native climate model output, i.e., data that have not been reformatted before.
Eliane Maillard Barras, Alexander Haefele, René Stübi, Achille Jouberton, Herbert Schill, Irina Petropavlovskikh, Koji Miyagawa, Martin Stanek, and Lucien Froidevaux
Atmos. Chem. Phys., 22, 14283–14302, https://doi.org/10.5194/acp-22-14283-2022, https://doi.org/10.5194/acp-22-14283-2022, 2022
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Intercomparisons of three Dobson and three Brewer spectrophotometers at Arosa/Davos, Switzerland, are used for the homogenization of the longest Umkehr ozone profiles time series worldwide. Dynamic linear modeling (DLM) reveals a significant positive trend after 2004 in the upper stratosphere, a persistent negative trend between 25 and 30 km in the middle stratosphere, and a negative trend at 20 km in the lower stratosphere, with different levels of significance depending on the dataset.
Kostas Eleftheratos, John Kapsomenakis, Ilias Fountoulakis, Christos S. Zerefos, Patrick Jöckel, Martin Dameris, Alkiviadis F. Bais, Germar Bernhard, Dimitra Kouklaki, Kleareti Tourpali, Scott Stierle, J. Ben Liley, Colette Brogniez, Frédérique Auriol, Henri Diémoz, Stana Simic, Irina Petropavlovskikh, Kaisa Lakkala, and Kostas Douvis
Atmos. Chem. Phys., 22, 12827–12855, https://doi.org/10.5194/acp-22-12827-2022, https://doi.org/10.5194/acp-22-12827-2022, 2022
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We present the future evolution of DNA-active ultraviolet (UV) radiation in view of increasing greenhouse gases (GHGs) and decreasing ozone depleting substances (ODSs). It is shown that DNA-active UV radiation might increase after 2050 between 50° N–50° S due to GHG-induced reductions in clouds and ozone, something that is likely not to happen at high latitudes, where DNA-active UV radiation will continue its downward trend mainly due to stratospheric ozone recovery from the reduction in ODSs.
Sophie Godin-Beekmann, Niramson Azouz, Viktoria F. Sofieva, Daan Hubert, Irina Petropavlovskikh, Peter Effertz, Gérard Ancellet, Doug A. Degenstein, Daniel Zawada, Lucien Froidevaux, Stacey Frith, Jeannette Wild, Sean Davis, Wolfgang Steinbrecht, Thierry Leblanc, Richard Querel, Kleareti Tourpali, Robert Damadeo, Eliane Maillard Barras, René Stübi, Corinne Vigouroux, Carlo Arosio, Gerald Nedoluha, Ian Boyd, Roeland Van Malderen, Emmanuel Mahieu, Dan Smale, and Ralf Sussmann
Atmos. Chem. Phys., 22, 11657–11673, https://doi.org/10.5194/acp-22-11657-2022, https://doi.org/10.5194/acp-22-11657-2022, 2022
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An updated evaluation up to 2020 of stratospheric ozone profile long-term trends at extrapolar latitudes based on satellite and ground-based records is presented. Ozone increase in the upper stratosphere is confirmed, with significant trends at most latitudes. In this altitude region, a very good agreement is found with trends derived from chemistry–climate model simulations. Observed and modelled trends diverge in the lower stratosphere, but the differences are non-significant.
Subin Yoon, Alexander Kotsakis, Sergio L. Alvarez, Mark G. Spychala, Elizabeth Klovenski, Paul Walter, Gary Morris, Ernesto Corrales, Alfredo Alan, Jorge A. Diaz, and James H. Flynn
Atmos. Meas. Tech., 15, 4373–4384, https://doi.org/10.5194/amt-15-4373-2022, https://doi.org/10.5194/amt-15-4373-2022, 2022
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SO2 is adverse to human health and the environment. A single SO2 sonde was developed to provide direct SO2 measurement with a greater vertical extent, a lower limit of detection, and less uncertainty relative to the previous dual-sonde method. The single sonde was tested in the field near volcanoes and anthropogenic sources where the sonde measured SO2 ranging from 0.5 to 940 ppb. This lighter-weight payload can be a great candidate to attach to small drones and unmanned aerial vehicles.
Noah Bernays, Daniel A. Jaffe, Irina Petropavlovskikh, and Peter Effertz
Atmos. Meas. Tech., 15, 3189–3192, https://doi.org/10.5194/amt-15-3189-2022, https://doi.org/10.5194/amt-15-3189-2022, 2022
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Ozone is an important pollutant that impacts millions of people worldwide. It is therefore important to ensure accurate measurements. A recent surge in wildfire activity in the USA has resulted in significant enhancements in ozone concentration. However given the nature of wildfire smoke, there are questions about our ability to accurately measure ozone. In this comment, we discuss possible biases in the UV measurements of ozone in the presence of smoke.
Shima Bahramvash Shams, Von P. Walden, James W. Hannigan, William J. Randel, Irina V. Petropavlovskikh, Amy H. Butler, and Alvaro de la Cámara
Atmos. Chem. Phys., 22, 5435–5458, https://doi.org/10.5194/acp-22-5435-2022, https://doi.org/10.5194/acp-22-5435-2022, 2022
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Large-scale atmospheric circulation has a strong influence on ozone in the Arctic, and certain anomalous dynamical events, such as sudden stratospheric warmings, cause dramatic alterations of the large-scale circulation. A reanalysis model is evaluated and then used to investigate the impact of sudden stratospheric warmings on mid-atmospheric ozone. Results show that the position of the cold jet stream over the Arctic before these events influences the variability of ozone.
Irina Petropavlovskikh, Koji Miyagawa, Audra McClure-Beegle, Bryan Johnson, Jeannette Wild, Susan Strahan, Krzysztof Wargan, Richard Querel, Lawrence Flynn, Eric Beach, Gerard Ancellet, and Sophie Godin-Beekmann
Atmos. Meas. Tech., 15, 1849–1870, https://doi.org/10.5194/amt-15-1849-2022, https://doi.org/10.5194/amt-15-1849-2022, 2022
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The Montreal Protocol and its amendments assure the recovery of the stratospheric ozone layer that protects the Earth from harmful ultraviolet radiation. To monitor ozone recovery, multiple satellites and ground-based observational platforms collect ozone data. The changes in instruments can influence the continuation of the ozone data. We discuss a method to remove instrumental artifacts from ozone records to improve the internal consistency among multiple observational records.
Andrew O. Langford, Christoph J. Senff, Raul J. Alvarez II, Ken C. Aikin, Sunil Baidar, Timothy A. Bonin, W. Alan Brewer, Jerome Brioude, Steven S. Brown, Joel D. Burley, Dani J. Caputi, Stephen A. Conley, Patrick D. Cullis, Zachary C. J. Decker, Stéphanie Evan, Guillaume Kirgis, Meiyun Lin, Mariusz Pagowski, Jeff Peischl, Irina Petropavlovskikh, R. Bradley Pierce, Thomas B. Ryerson, Scott P. Sandberg, Chance W. Sterling, Ann M. Weickmann, and Li Zhang
Atmos. Chem. Phys., 22, 1707–1737, https://doi.org/10.5194/acp-22-1707-2022, https://doi.org/10.5194/acp-22-1707-2022, 2022
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The Fires, Asian, and Stratospheric Transport–Las Vegas Ozone Study (FAST-LVOS) combined lidar, aircraft, and in situ measurements with global models to investigate the contributions of stratospheric intrusions, regional and Asian pollution, and wildfires to background ozone in the southwestern US during May and June 2017 and demonstrated that these processes contributed to background ozone levels that exceeded 70 % of the US National Ambient Air Quality Standard during the 6-week campaign.
Daan Hubert, Klaus-Peter Heue, Jean-Christopher Lambert, Tijl Verhoelst, Marc Allaart, Steven Compernolle, Patrick D. Cullis, Angelika Dehn, Christian Félix, Bryan J. Johnson, Arno Keppens, Debra E. Kollonige, Christophe Lerot, Diego Loyola, Matakite Maata, Sukarni Mitro, Maznorizan Mohamad, Ankie Piters, Fabian Romahn, Henry B. Selkirk, Francisco R. da Silva, Ryan M. Stauffer, Anne M. Thompson, J. Pepijn Veefkind, Holger Vömel, Jacquelyn C. Witte, and Claus Zehner
Atmos. Meas. Tech., 14, 7405–7433, https://doi.org/10.5194/amt-14-7405-2021, https://doi.org/10.5194/amt-14-7405-2021, 2021
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We assess the first 2 years of TROPOMI tropical tropospheric ozone column data. Comparisons to reference measurements by ozonesonde and satellite sensors show that TROPOMI bias (−0.1 to +2.3 DU) and precision (1.5 to 2.5 DU) meet mission requirements. Potential causes of bias and its spatio-temporal structure are discussed, as well as ways to identify sampling errors. Our analysis of known geophysical patterns demonstrates the improved performance of TROPOMI with respect to its predecessors.
James Keeble, Birgit Hassler, Antara Banerjee, Ramiro Checa-Garcia, Gabriel Chiodo, Sean Davis, Veronika Eyring, Paul T. Griffiths, Olaf Morgenstern, Peer Nowack, Guang Zeng, Jiankai Zhang, Greg Bodeker, Susannah Burrows, Philip Cameron-Smith, David Cugnet, Christopher Danek, Makoto Deushi, Larry W. Horowitz, Anne Kubin, Lijuan Li, Gerrit Lohmann, Martine Michou, Michael J. Mills, Pierre Nabat, Dirk Olivié, Sungsu Park, Øyvind Seland, Jens Stoll, Karl-Hermann Wieners, and Tongwen Wu
Atmos. Chem. Phys., 21, 5015–5061, https://doi.org/10.5194/acp-21-5015-2021, https://doi.org/10.5194/acp-21-5015-2021, 2021
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Stratospheric ozone and water vapour are key components of the Earth system; changes to both have important impacts on global and regional climate. We evaluate changes to these species from 1850 to 2100 in the new generation of CMIP6 models. There is good agreement between the multi-model mean and observations, although there is substantial variation between the individual models. The future evolution of both ozone and water vapour is strongly dependent on the assumed future emissions scenario.
Paul T. Griffiths, Lee T. Murray, Guang Zeng, Youngsub Matthew Shin, N. Luke Abraham, Alexander T. Archibald, Makoto Deushi, Louisa K. Emmons, Ian E. Galbally, Birgit Hassler, Larry W. Horowitz, James Keeble, Jane Liu, Omid Moeini, Vaishali Naik, Fiona M. O'Connor, Naga Oshima, David Tarasick, Simone Tilmes, Steven T. Turnock, Oliver Wild, Paul J. Young, and Prodromos Zanis
Atmos. Chem. Phys., 21, 4187–4218, https://doi.org/10.5194/acp-21-4187-2021, https://doi.org/10.5194/acp-21-4187-2021, 2021
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We analyse the CMIP6 Historical and future simulations for tropospheric ozone, a species which is important for many aspects of atmospheric chemistry. We show that the current generation of models agrees well with observations, being particularly successful in capturing trends in surface ozone and its vertical distribution in the troposphere. We analyse the factors that control ozone and show that they evolve over the period of the CMIP6 experiments.
Xin Yang, Anne-M. Blechschmidt, Kristof Bognar, Audra McClure-Begley, Sara Morris, Irina Petropavlovskikh, Andreas Richter, Henrik Skov, Kimberly Strong, David W. Tarasick, Taneil Uttal, Mika Vestenius, and Xiaoyi Zhao
Atmos. Chem. Phys., 20, 15937–15967, https://doi.org/10.5194/acp-20-15937-2020, https://doi.org/10.5194/acp-20-15937-2020, 2020
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This is a modelling-based study on Arctic surface ozone, with a particular focus on spring ozone depletion events (i.e. with concentrations < 10 ppbv). Model experiments show that model runs with blowing-snow-sourced sea salt aerosols implemented as a source of reactive bromine can reproduce well large-scale ozone depletion events observed in the Arctic. This study supplies modelling evidence of the proposed mechanism of reactive-bromine release from blowing snow on sea ice (Yang et al., 2008).
Holger Vömel, Herman G. J. Smit, David Tarasick, Bryan Johnson, Samuel J. Oltmans, Henry Selkirk, Anne M. Thompson, Ryan M. Stauffer, Jacquelyn C. Witte, Jonathan Davies, Roeland van Malderen, Gary A. Morris, Tatsumi Nakano, and Rene Stübi
Atmos. Meas. Tech., 13, 5667–5680, https://doi.org/10.5194/amt-13-5667-2020, https://doi.org/10.5194/amt-13-5667-2020, 2020
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The time response of electrochemical concentration cell (ECC) ozonesondes points to at least two distinct reaction pathways with time constants of approximately 20 s and 25 min. Properly considering these time constants eliminates the need for a poorly defined "background" and allows reducing ad hoc corrections based on laboratory tests. This reduces the uncertainty of ECC ozonesonde measurements throughout the profile and especially in regions of low ozone and strong gradients of ozone.
Ilann Bourgeois, Jeff Peischl, Chelsea R. Thompson, Kenneth C. Aikin, Teresa Campos, Hannah Clark, Róisín Commane, Bruce Daube, Glenn W. Diskin, James W. Elkins, Ru-Shan Gao, Audrey Gaudel, Eric J. Hintsa, Bryan J. Johnson, Rigel Kivi, Kathryn McKain, Fred L. Moore, David D. Parrish, Richard Querel, Eric Ray, Ricardo Sánchez, Colm Sweeney, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Jacquelyn C. Witte, Steve C. Wofsy, and Thomas B. Ryerson
Atmos. Chem. Phys., 20, 10611–10635, https://doi.org/10.5194/acp-20-10611-2020, https://doi.org/10.5194/acp-20-10611-2020, 2020
Li Zhang, Meiyun Lin, Andrew O. Langford, Larry W. Horowitz, Christoph J. Senff, Elizabeth Klovenski, Yuxuan Wang, Raul J. Alvarez II, Irina Petropavlovskikh, Patrick Cullis, Chance W. Sterling, Jeff Peischl, Thomas B. Ryerson, Steven S. Brown, Zachary C. J. Decker, Guillaume Kirgis, and Stephen Conley
Atmos. Chem. Phys., 20, 10379–10400, https://doi.org/10.5194/acp-20-10379-2020, https://doi.org/10.5194/acp-20-10379-2020, 2020
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Measuring and quantifying the sources of elevated springtime ozone in the southwestern US is challenging but relevant to the implications for control policy. Here we use intensive field measurements and two global models to study ozone sources in the region. We find that ozone from the stratosphere, wildfires, and Asia is an important source of high-ozone events in the region. Our analysis also helps understand the uncertainties in ozone simulations with individual models.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, and Valérie Thouret
Atmos. Chem. Phys., 20, 9915–9938, https://doi.org/10.5194/acp-20-9915-2020, https://doi.org/10.5194/acp-20-9915-2020, 2020
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We provide a statistical framework for detecting trends of multiple autocorrelated time series from sparsely sampled profile data. The result is a better and more consistent quantification of trend estimates of vertical profile data. The focus was placed on the long-term ozone time series from commercial aircraft and balloon-borne ozonesonde measurements. This framework can be applied to other trace gases in the atmosphere.
Veronika Eyring, Lisa Bock, Axel Lauer, Mattia Righi, Manuel Schlund, Bouwe Andela, Enrico Arnone, Omar Bellprat, Björn Brötz, Louis-Philippe Caron, Nuno Carvalhais, Irene Cionni, Nicola Cortesi, Bas Crezee, Edouard L. Davin, Paolo Davini, Kevin Debeire, Lee de Mora, Clara Deser, David Docquier, Paul Earnshaw, Carsten Ehbrecht, Bettina K. Gier, Nube Gonzalez-Reviriego, Paul Goodman, Stefan Hagemann, Steven Hardiman, Birgit Hassler, Alasdair Hunter, Christopher Kadow, Stephan Kindermann, Sujan Koirala, Nikolay Koldunov, Quentin Lejeune, Valerio Lembo, Tomas Lovato, Valerio Lucarini, François Massonnet, Benjamin Müller, Amarjiit Pandde, Núria Pérez-Zanón, Adam Phillips, Valeriu Predoi, Joellen Russell, Alistair Sellar, Federico Serva, Tobias Stacke, Ranjini Swaminathan, Verónica Torralba, Javier Vegas-Regidor, Jost von Hardenberg, Katja Weigel, and Klaus Zimmermann
Geosci. Model Dev., 13, 3383–3438, https://doi.org/10.5194/gmd-13-3383-2020, https://doi.org/10.5194/gmd-13-3383-2020, 2020
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The Earth System Model Evaluation Tool (ESMValTool) is a community diagnostics and performance metrics tool designed to improve comprehensive and routine evaluation of earth system models (ESMs) participating in the Coupled Model Intercomparison Project (CMIP). It has undergone rapid development since the first release in 2016 and is now a well-tested tool that provides end-to-end provenance tracking to ensure reproducibility.
Mattia Righi, Bouwe Andela, Veronika Eyring, Axel Lauer, Valeriu Predoi, Manuel Schlund, Javier Vegas-Regidor, Lisa Bock, Björn Brötz, Lee de Mora, Faruk Diblen, Laura Dreyer, Niels Drost, Paul Earnshaw, Birgit Hassler, Nikolay Koldunov, Bill Little, Saskia Loosveldt Tomas, and Klaus Zimmermann
Geosci. Model Dev., 13, 1179–1199, https://doi.org/10.5194/gmd-13-1179-2020, https://doi.org/10.5194/gmd-13-1179-2020, 2020
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This paper describes the second major release of ESMValTool, a community diagnostic and performance metrics tool for the evaluation of Earth system models. This new version features a brand new design, with an improved interface and a revised preprocessor. It takes advantage of state-of-the-art computational libraries and methods to deploy efficient and user-friendly data processing, improving the performance over its predecessor by more than a factor of 30.
Shima Bahramvash Shams, Von P. Walden, Irina Petropavlovskikh, David Tarasick, Rigel Kivi, Samuel Oltmans, Bryan Johnson, Patrick Cullis, Chance W. Sterling, Laura Thölix, and Quentin Errera
Atmos. Chem. Phys., 19, 9733–9751, https://doi.org/10.5194/acp-19-9733-2019, https://doi.org/10.5194/acp-19-9733-2019, 2019
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The Arctic plays a very important role in the global ozone cycle. We use balloon-borne sampling and satellite data to create a high-quality dataset of the vertical profile of ozone from 2005 to 2017 to analyze ozone variations over four high-latitude Arctic locations. No significant annual trend is found at any of the studied locations. We develop a mathematical model to understand how deseasonalized ozone fluctuations can be influenced by various parameters.
Corinna Kloss, Marc von Hobe, Michael Höpfner, Kaley A. Walker, Martin Riese, Jörn Ungermann, Birgit Hassler, Stefanie Kremser, and Greg E. Bodeker
Atmos. Meas. Tech., 12, 2129–2138, https://doi.org/10.5194/amt-12-2129-2019, https://doi.org/10.5194/amt-12-2129-2019, 2019
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Are regional and seasonal averages from only a few satellite measurements, all aligned along a specific path, representative? Probably not. We present a method to adjust for the so-called
sampling biasand investigate its influence on derived long-term trends. The method is illustrated and validated for a long-lived trace gas (carbonyl sulfide), and it is shown that the influence of the sampling bias is too small to change scientific conclusions on long-term trends.
Kenneth Minschwaner, Anthony T. Giljum, Gloria L. Manney, Irina Petropavlovskikh, Bryan J. Johnson, and Allen F. Jordan
Atmos. Chem. Phys., 19, 1853–1865, https://doi.org/10.5194/acp-19-1853-2019, https://doi.org/10.5194/acp-19-1853-2019, 2019
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We analyzed balloon measurements of ozone between the surface and 25 km altitude above Boulder, Colorado, and developed an algorithm to detect and classify layers of either unusually high or unusually low ozone. These layers range in vertical thickness from a few hundred meters to a few kilometers. We found that these laminae are an important contributor to the overall variability in ozone, especially in the transition region between the troposphere and stratosphere.
Omid Moeini, Zahra Vaziri Zanjani, C. Thomas McElroy, David W. Tarasick, Robert D. Evans, Irina Petropavlovskikh, and Keh-Harng Feng
Atmos. Meas. Tech., 12, 327–343, https://doi.org/10.5194/amt-12-327-2019, https://doi.org/10.5194/amt-12-327-2019, 2019
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This study documents the error caused by the effect of stray light in the Brewer and Dobson total ozone measurements using a mathematical model for each instrument. The errors caused by stray light are particularly significant at high latitudes in the late winter and early spring when measurements are made at large solar zenith angles and large total ozone column. Such errors are of considerable importance if those data are to be used for trend analysis or satellite data validation.
Marina Astitha, Ioannis Kioutsioukis, Ghezae Araya Fisseha, Roberto Bianconi, Johannes Bieser, Jesper H. Christensen, Owen R. Cooper, Stefano Galmarini, Christian Hogrefe, Ulas Im, Bryan Johnson, Peng Liu, Uarporn Nopmongcol, Irina Petropavlovskikh, Efisio Solazzo, David W. Tarasick, and Greg Yarwood
Atmos. Chem. Phys., 18, 13925–13945, https://doi.org/10.5194/acp-18-13925-2018, https://doi.org/10.5194/acp-18-13925-2018, 2018
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This work is unique in the detailed analyses of modeled ozone vertical profiles from sites in North America through the collaboration of four research groups from the US and EU. We assess the air quality models' performance and model inter-comparison for ozone vertical profiles and stratospheric ozone intrusions. Lastly, we designate the important role of lateral boundary conditions in the ozone vertical profiles using chemically inert tracers.
Birgit Hassler, Stefanie Kremser, Greg E. Bodeker, Jared Lewis, Kage Nesbit, Sean M. Davis, Martyn P. Chipperfield, Sandip S. Dhomse, and Martin Dameris
Earth Syst. Sci. Data, 10, 1473–1490, https://doi.org/10.5194/essd-10-1473-2018, https://doi.org/10.5194/essd-10-1473-2018, 2018
Elpida Leventidou, Mark Weber, Kai-Uwe Eichmann, John P. Burrows, Klaus-Peter Heue, Anne M. Thompson, and Bryan J. Johnson
Atmos. Chem. Phys., 18, 9189–9205, https://doi.org/10.5194/acp-18-9189-2018, https://doi.org/10.5194/acp-18-9189-2018, 2018
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Three individual tropical tropospheric ozone (TTCO) datasets (1996–2015) retrieved with the convective-cloud differential method (Leventidou et al., 2016) have been harmonised in order to study the global and regional TTCO trends. The trends range between −4 to 4 DU per decade testing six different merging scenarios. No trend has been found for the global tropics using the preferred scenario. It is concluded that harmonisation is one of the major sources of uncertainty in the trend estimates.
Chance W. Sterling, Bryan J. Johnson, Samuel J. Oltmans, Herman G. J. Smit, Allen F. Jordan, Patrick D. Cullis, Emrys G. Hall, Anne M. Thompson, and Jacquelyn C. Witte
Atmos. Meas. Tech., 11, 3661–3687, https://doi.org/10.5194/amt-11-3661-2018, https://doi.org/10.5194/amt-11-3661-2018, 2018
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The electrochemical concentration cell ozonesonde is a balloon-borne instrument that measures ozone to an altitude of ~30 km. This work summarizes the National Oceanic and Atmospheric Administration's 50+ year, eight-site ozonesonde network history, the processing techniques utilized to account for instrumental changes, and the uncertainty of the measurement. The ozonesonde measurements were compared to satellite measurements and agreed well. This important data set is more useful and robust.
Sandip S. Dhomse, Douglas Kinnison, Martyn P. Chipperfield, Ross J. Salawitch, Irene Cionni, Michaela I. Hegglin, N. Luke Abraham, Hideharu Akiyoshi, Alex T. Archibald, Ewa M. Bednarz, Slimane Bekki, Peter Braesicke, Neal Butchart, Martin Dameris, Makoto Deushi, Stacey Frith, Steven C. Hardiman, Birgit Hassler, Larry W. Horowitz, Rong-Ming Hu, Patrick Jöckel, Beatrice Josse, Oliver Kirner, Stefanie Kremser, Ulrike Langematz, Jared Lewis, Marion Marchand, Meiyun Lin, Eva Mancini, Virginie Marécal, Martine Michou, Olaf Morgenstern, Fiona M. O'Connor, Luke Oman, Giovanni Pitari, David A. Plummer, John A. Pyle, Laura E. Revell, Eugene Rozanov, Robyn Schofield, Andrea Stenke, Kane Stone, Kengo Sudo, Simone Tilmes, Daniele Visioni, Yousuke Yamashita, and Guang Zeng
Atmos. Chem. Phys., 18, 8409–8438, https://doi.org/10.5194/acp-18-8409-2018, https://doi.org/10.5194/acp-18-8409-2018, 2018
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We analyse simulations from the Chemistry-Climate Model Initiative (CCMI) to estimate the return dates of the stratospheric ozone layer from depletion by anthropogenic chlorine and bromine. The simulations from 20 models project that global column ozone will return to 1980 values in 2047 (uncertainty range 2042–2052). Return dates in other regions vary depending on factors related to climate change and importance of chlorine and bromine. Column ozone in the tropics may continue to decline.
Christos Zerefos, John Kapsomenakis, Kostas Eleftheratos, Kleareti Tourpali, Irina Petropavlovskikh, Daan Hubert, Sophie Godin-Beekmann, Wolfgang Steinbrecht, Stacey Frith, Viktoria Sofieva, and Birgit Hassler
Atmos. Chem. Phys., 18, 6427–6440, https://doi.org/10.5194/acp-18-6427-2018, https://doi.org/10.5194/acp-18-6427-2018, 2018
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We point out the representativeness of single lidar stations for zonally averaged ozone profile variations in the middle/upper stratosphere. We examine the contribution of chemistry and natural proxies to ozone profile trends. Above 10 hPa an “inflection point” between 1997–99 marks the end of significant negative ozone trends, followed by a recent period of positive ozone change in 1998–2015. Below 15 hPa the pre-1998 negative ozone trends tend to become insignificant as we move to 2015.
Martine De Mazière, Anne M. Thompson, Michael J. Kurylo, Jeannette D. Wild, Germar Bernhard, Thomas Blumenstock, Geir O. Braathen, James W. Hannigan, Jean-Christopher Lambert, Thierry Leblanc, Thomas J. McGee, Gerald Nedoluha, Irina Petropavlovskikh, Gunther Seckmeyer, Paul C. Simon, Wolfgang Steinbrecht, and Susan E. Strahan
Atmos. Chem. Phys., 18, 4935–4964, https://doi.org/10.5194/acp-18-4935-2018, https://doi.org/10.5194/acp-18-4935-2018, 2018
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This paper serves as an introduction to the special issue "Twenty-five years of operations of the Network for the Detection of Atmospheric Composition Change (NDACC)". It describes the origins of the network, its actual status, and some perspectives for its future evolution in the context of atmospheric sciences.
Ulf Köhler, Saulius Nevas, Glen McConville, Robert Evans, Marek Smid, Martin Stanek, Alberto Redondas, and Fritz Schönenborn
Atmos. Meas. Tech., 11, 1989–1999, https://doi.org/10.5194/amt-11-1989-2018, https://doi.org/10.5194/amt-11-1989-2018, 2018
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Laboratory investigations of optical characteristics of three standard Dobsons provide real wavelength settings and slit functions. These parameters were compared with the original values given in the manuals. The differences between real and nominal values are not too large, but their application will in any case improve the quality of the total ozone column measurements in the global
network. This improvement was the main objective of the ATMOZ project funding these activities.
David A. Westenbarger and Gary A. Morris
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2017-1234, https://doi.org/10.5194/acp-2017-1234, 2018
Revised manuscript not accepted
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As ambient air quality standards are strengthened, understanding transported pollution becomes more important. We identify transported biomass burning plumes using an ensemble of in situ ambient monitors, remote sensing instruments, and chemical transport models. An example for Houston TX USA over a multi-day period in 2011 is examined. Enhancements in O3, aerosols, and CO confirm presence of transported parcels likely originating from upwind regions with pervasive biomass burning.
Germar Bernhard, Irina Petropavlovskikh, and Bernhard Mayer
Atmos. Meas. Tech., 10, 4979–4994, https://doi.org/10.5194/amt-10-4979-2017, https://doi.org/10.5194/amt-10-4979-2017, 2017
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The vertical distribution of atmospheric ozone has historically been measured from the ground by analysing the wavelength dependence of zenith radiation. Our method retrieves the same information from global irradiance, which is defined as radiant flux received from the entire upper hemisphere, including the Sun. The new method makes existing long-term data sets of global irradiance available for studying ozone profiles. The accuracy of the new method is similar to that of the legacy method.
Lihua Wang, Michael J. Newchurch, Raul J. Alvarez II, Timothy A. Berkoff, Steven S. Brown, William Carrion, Russell J. De Young, Bryan J. Johnson, Rene Ganoe, Guillaume Gronoff, Guillaume Kirgis, Shi Kuang, Andrew O. Langford, Thierry Leblanc, Erin E. McDuffie, Thomas J. McGee, Denis Pliutau, Christoph J. Senff, John T. Sullivan, Grant Sumnicht, Laurence W. Twigg, and Andrew J. Weinheimer
Atmos. Meas. Tech., 10, 3865–3876, https://doi.org/10.5194/amt-10-3865-2017, https://doi.org/10.5194/amt-10-3865-2017, 2017
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Intercomparisons have been made between three TOLNet ozone lidars and between the lidars and other ozone instruments during the 2014 DISCOVER-AQ and FRAPPÉ campaigns in Colorado. Overall, the TOLNet lidars are capable of measuring 5 min tropospheric ozone variations with accuracy better than ±15 % in terms of their vertical resolving capability and better than ±5 % in terms of their column average measurement. These results indicate very good measurement accuracy for the three TOLNet lidars.
Robert D. Evans, Irina Petropavlovskikh, Audra McClure-Begley, Glen McConville, Dorothy Quincy, and Koji Miyagawa
Atmos. Chem. Phys., 17, 12051–12070, https://doi.org/10.5194/acp-17-12051-2017, https://doi.org/10.5194/acp-17-12051-2017, 2017
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The record of the total ozone column (TOC) from stations using the Dobson ozone spectrophotometer is one of the longest geophysical records in existence. Recent adoption of a new data processing scheme, with improved results prompted a complete reprocessing of the historical record from these NOAA/NDACC sites. As the original record of TOC from these stations are used for trend analysis and satellite verification, the scientific community should be aware of the changes in the new data set.
Jay Herman, Robert Evans, Alexander Cede, Nader Abuhassan, Irina Petropavlovskikh, Glenn McConville, Koji Miyagawa, and Brandon Noirot
Atmos. Meas. Tech., 10, 3539–3545, https://doi.org/10.5194/amt-10-3539-2017, https://doi.org/10.5194/amt-10-3539-2017, 2017
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A co-located Pandora Spectrometer Instrument (Pan #034) has been compared to a well-calibrated Dobson spectroradiometer (Dobson #061) in Boulder, Colorado, and with two satellite instruments over a 3-year period. The results show good agreement between Pa n#034 and Dobson #061 and with the satellite data within their statistical uncertainties.
Wolfgang Steinbrecht, Lucien Froidevaux, Ryan Fuller, Ray Wang, John Anderson, Chris Roth, Adam Bourassa, Doug Degenstein, Robert Damadeo, Joe Zawodny, Stacey Frith, Richard McPeters, Pawan Bhartia, Jeannette Wild, Craig Long, Sean Davis, Karen Rosenlof, Viktoria Sofieva, Kaley Walker, Nabiz Rahpoe, Alexei Rozanov, Mark Weber, Alexandra Laeng, Thomas von Clarmann, Gabriele Stiller, Natalya Kramarova, Sophie Godin-Beekmann, Thierry Leblanc, Richard Querel, Daan Swart, Ian Boyd, Klemens Hocke, Niklaus Kämpfer, Eliane Maillard Barras, Lorena Moreira, Gerald Nedoluha, Corinne Vigouroux, Thomas Blumenstock, Matthias Schneider, Omaira García, Nicholas Jones, Emmanuel Mahieu, Dan Smale, Michael Kotkamp, John Robinson, Irina Petropavlovskikh, Neil Harris, Birgit Hassler, Daan Hubert, and Fiona Tummon
Atmos. Chem. Phys., 17, 10675–10690, https://doi.org/10.5194/acp-17-10675-2017, https://doi.org/10.5194/acp-17-10675-2017, 2017
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Thanks to the 1987 Montreal Protocol and its amendments, ozone-depleting chlorine (and bromine) in the stratosphere has declined slowly since the late 1990s. Improved and extended long-term ozone profile observations from satellites and ground-based stations confirm that ozone is responding as expected and has increased by about 2 % per decade since 2000 in the upper stratosphere, around 40 km altitude. At lower altitudes, however, ozone has not changed significantly since 2000.
Guanyu Huang, Xiong Liu, Kelly Chance, Kai Yang, Pawan K. Bhartia, Zhaonan Cai, Marc Allaart, Gérard Ancellet, Bertrand Calpini, Gerrie J. R. Coetzee, Emilio Cuevas-Agulló, Manuel Cupeiro, Hugo De Backer, Manvendra K. Dubey, Henry E. Fuelberg, Masatomo Fujiwara, Sophie Godin-Beekmann, Tristan J. Hall, Bryan Johnson, Everette Joseph, Rigel Kivi, Bogumil Kois, Ninong Komala, Gert König-Langlo, Giovanni Laneve, Thierry Leblanc, Marion Marchand, Kenneth R. Minschwaner, Gary Morris, Michael J. Newchurch, Shin-Ya Ogino, Nozomu Ohkawara, Ankie J. M. Piters, Françoise Posny, Richard Querel, Rinus Scheele, Frank J. Schmidlin, Russell C. Schnell, Otto Schrems, Henry Selkirk, Masato Shiotani, Pavla Skrivánková, René Stübi, Ghassan Taha, David W. Tarasick, Anne M. Thompson, Valérie Thouret, Matthew B. Tully, Roeland Van Malderen, Holger Vömel, Peter von der Gathen, Jacquelyn C. Witte, and Margarita Yela
Atmos. Meas. Tech., 10, 2455–2475, https://doi.org/10.5194/amt-10-2455-2017, https://doi.org/10.5194/amt-10-2455-2017, 2017
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It is essential to understand the data quality of +10-year OMI ozone product and impacts of the “row anomaly” (RA). We validate the OMI Ozone Profile (PROFOZ) product from Oct 2004 to Dec 2014 against ozonesonde observations globally. Generally, OMI has good agreement with ozonesondes. The spatiotemporal variation of retrieval performance suggests the need to improve OMI’s radiometric calibration especially during the post-RA period to maintain the long-term stability.
Terry Deshler, Rene Stübi, Francis J. Schmidlin, Jennifer L. Mercer, Herman G. J. Smit, Bryan J. Johnson, Rigel Kivi, and Bruno Nardi
Atmos. Meas. Tech., 10, 2021–2043, https://doi.org/10.5194/amt-10-2021-2017, https://doi.org/10.5194/amt-10-2021-2017, 2017
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Ozonesondes, small balloon-borne instruments to measure ozone profiles, are used once and lost. Quality control is thus essential. From the mid-1990s to late 2000s differences in manufacturers' (Science Pump and ENSCI) recommended sensor solution concentrations, 1.0 % and 0.5 % potassium iodide, led to some confusion. This paper uses comparison measurements to derive transfer functions to homogenize the measurements made with non-standard combinations of instrument and sensor solution.
Vanessa Caicedo, Bernhard Rappenglück, Barry Lefer, Gary Morris, Daniel Toledo, and Ruben Delgado
Atmos. Meas. Tech., 10, 1609–1622, https://doi.org/10.5194/amt-10-1609-2017, https://doi.org/10.5194/amt-10-1609-2017, 2017
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Three methods for estimating the boundary layer height using aerosol backscatter measurements are evaluated here. Radiosonde profiles are used to evaluate aerosol-backscatter-derived boundary layer heights. Overall good agreement between radiosonde and all aerosol-derived boundary layer heights was found, and specific limitations to each method are discussed. A recommended method is given for future aerosol backscatter retrieval of the boundary layer height.
Christos S. Zerefos, Kostas Eleftheratos, John Kapsomenakis, Stavros Solomos, Antje Inness, Dimitris Balis, Alberto Redondas, Henk Eskes, Marc Allaart, Vassilis Amiridis, Arne Dahlback, Veerle De Bock, Henri Diémoz, Ronny Engelmann, Paul Eriksen, Vitali Fioletov, Julian Gröbner, Anu Heikkilä, Irina Petropavlovskikh, Janusz Jarosławski, Weine Josefsson, Tomi Karppinen, Ulf Köhler, Charoula Meleti, Christos Repapis, John Rimmer, Vladimir Savinykh, Vadim Shirotov, Anna Maria Siani, Andrew R. D. Smedley, Martin Stanek, and René Stübi
Atmos. Chem. Phys., 17, 551–574, https://doi.org/10.5194/acp-17-551-2017, https://doi.org/10.5194/acp-17-551-2017, 2017
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The paper makes a convincing case that the Brewer network is capable of detecting enhanced SO2 columns, as observed, e.g., after volcanic eruptions. For this reason, large volcanic eruptions of the past decade have been used to detect and forecast SO2 plumes of volcanic origin using the Brewer and other ground-based networks, aided by satellite, trajectory analysis calculations and modelling.
Gerard Ancellet, Nikos Daskalakis, Jean Christophe Raut, David Tarasick, Jonathan Hair, Boris Quennehen, François Ravetta, Hans Schlager, Andrew J. Weinheimer, Anne M. Thompson, Bryan Johnson, Jennie L. Thomas, and Katharine S. Law
Atmos. Chem. Phys., 16, 13341–13358, https://doi.org/10.5194/acp-16-13341-2016, https://doi.org/10.5194/acp-16-13341-2016, 2016
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An integrated analysis of all the ozone observations (lidar, sondes, and airborne in situ measurements) conducted during the 2008 IPY campaigns is performed and the processes that determine summer ozone concentrations over Greenland and Canada are discussed. Combined with a regional model simulation (WRFChem), the analysis of ozone, CO, and PV latitudinal and vertical variability allows the determination of the influence of stratospheric sources and biomass burning and anthropogenic emissions.
Sean M. Davis, Karen H. Rosenlof, Birgit Hassler, Dale F. Hurst, William G. Read, Holger Vömel, Henry Selkirk, Masatomo Fujiwara, and Robert Damadeo
Earth Syst. Sci. Data, 8, 461–490, https://doi.org/10.5194/essd-8-461-2016, https://doi.org/10.5194/essd-8-461-2016, 2016
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This paper describes the construction of the Stratospheric Water and Ozone Satellite Homogenized (SWOOSH) database, whose main feature is a combined data product created by homogenizing multiple satellite records. This motivation for SWOOSH is that in order to study multiyear to decadal variability in ozone and water vapor concentrations, it is necessary to have a continuous and smooth record without artificial jumps in the data.
Dale F. Hurst, William G. Read, Holger Vömel, Henry B. Selkirk, Karen H. Rosenlof, Sean M. Davis, Emrys G. Hall, Allen F. Jordan, and Samuel J. Oltmans
Atmos. Meas. Tech., 9, 4447–4457, https://doi.org/10.5194/amt-9-4447-2016, https://doi.org/10.5194/amt-9-4447-2016, 2016
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This study compares stratospheric water vapor measurements by the Aura Microwave Limb Sounder (MLS) and balloon-borne frost point hygrometers (FPs) at five sites that launch two different types of FPs. The results demonstrate that FP and MLS measurements have been diverging at statistically significant rates of 0.6 to 1.5 % per year since approximately 2010. Similarities in the divergences at different sites suggest a positive drift in MLS retrievals since approximately 2010.
Emrys G. Hall, Allen F. Jordan, Dale F. Hurst, Samuel J. Oltmans, Holger Vömel, Benjamin Kühnreich, and Volker Ebert
Atmos. Meas. Tech., 9, 4295–4310, https://doi.org/10.5194/amt-9-4295-2016, https://doi.org/10.5194/amt-9-4295-2016, 2016
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This work focuses on the balloon borne NOAA frost point hygrometer (FPH) instrument flown at three locations around the world: Boulder, Colorado, Lauder, New Zealand, and Hilo, Hawaii. The ongoing 36-year record is the longest continuous water vapor record with profiles reaching 28 km. Significant instrument updates in 2008 decreased the weight, cost, power consumption, and manufacturing time offering greater precision and ease of use.
Daan Hubert, Jean-Christopher Lambert, Tijl Verhoelst, José Granville, Arno Keppens, Jean-Luc Baray, Adam E. Bourassa, Ugo Cortesi, Doug A. Degenstein, Lucien Froidevaux, Sophie Godin-Beekmann, Karl W. Hoppel, Bryan J. Johnson, Erkki Kyrölä, Thierry Leblanc, Günter Lichtenberg, Marion Marchand, C. Thomas McElroy, Donal Murtagh, Hideaki Nakane, Thierry Portafaix, Richard Querel, James M. Russell III, Jacobo Salvador, Herman G. J. Smit, Kerstin Stebel, Wolfgang Steinbrecht, Kevin B. Strawbridge, René Stübi, Daan P. J. Swart, Ghassan Taha, David W. Tarasick, Anne M. Thompson, Joachim Urban, Joanna A. E. van Gijsel, Roeland Van Malderen, Peter von der Gathen, Kaley A. Walker, Elian Wolfram, and Joseph M. Zawodny
Atmos. Meas. Tech., 9, 2497–2534, https://doi.org/10.5194/amt-9-2497-2016, https://doi.org/10.5194/amt-9-2497-2016, 2016
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A more detailed understanding of satellite O3 profile data records is vital for further progress in O3 research. To this end, we made a comprehensive assessment of 14 limb/occultation profilers using ground-based reference data. The mutual consistency of satellite O3 in terms of bias, short-term variability and decadal stability is generally good over most of the stratosphere. However, we identified some exceptions that impact the quality of recently merged data sets and ozone trend assessments.
D. W. Tarasick, J. Davies, H. G. J. Smit, and S. J. Oltmans
Atmos. Meas. Tech., 9, 195–214, https://doi.org/10.5194/amt-9-195-2016, https://doi.org/10.5194/amt-9-195-2016, 2016
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Changes to measurement methods over Canada's 48-year ozonesonde record have been characterized and corrections applied. An estimate of the altitude-dependent uncertainty is added to each profile. The re-evaluated time series show negative trends in the lower stratosphere of up to 5 % per decade for the period 1966–2013. In the troposphere trends for the 48-year period are generally not significant. This suggests that free tropospheric ozone levels over Canada have not changed in nearly 50 years.
N. R. P. Harris, B. Hassler, F. Tummon, G. E. Bodeker, D. Hubert, I. Petropavlovskikh, W. Steinbrecht, J. Anderson, P. K. Bhartia, C. D. Boone, A. Bourassa, S. M. Davis, D. Degenstein, A. Delcloo, S. M. Frith, L. Froidevaux, S. Godin-Beekmann, N. Jones, M. J. Kurylo, E. Kyrölä, M. Laine, S. T. Leblanc, J.-C. Lambert, B. Liley, E. Mahieu, A. Maycock, M. de Mazière, A. Parrish, R. Querel, K. H. Rosenlof, C. Roth, C. Sioris, J. Staehelin, R. S. Stolarski, R. Stübi, J. Tamminen, C. Vigouroux, K. A. Walker, H. J. Wang, J. Wild, and J. M. Zawodny
Atmos. Chem. Phys., 15, 9965–9982, https://doi.org/10.5194/acp-15-9965-2015, https://doi.org/10.5194/acp-15-9965-2015, 2015
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Trends in the vertical distribution of ozone are reported for new and recently revised data sets. The amount of ozone-depleting compounds in the stratosphere peaked in the second half of the 1990s. We examine the trends before and after that peak to see if any change in trend is discernible. The previously reported decreases are confirmed. Furthermore, the downward trend in upper stratospheric ozone has not continued. The possible significance of any increase is discussed in detail.
J. Herman, R. Evans, A. Cede, N. Abuhassan, I. Petropavlovskikh, and G. McConville
Atmos. Meas. Tech., 8, 3407–3418, https://doi.org/10.5194/amt-8-3407-2015, https://doi.org/10.5194/amt-8-3407-2015, 2015
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Measurements of total column ozone have been obtained by the Dobson #061 spectrophotometer and the Pandora spectrometer system from the roof of the NOAA building in Boulder, Colorado. A comparison of 1 year (17 Dec 2013 to 18 Dec 2014) of ozone data shows that the two instruments are in close agreement after a separate correction was applied to the retrieved ozone data from each instrument. Good agreement was also obtained between Pandora and two satellite data sets, AURA OMI and SUOMI OMPS.
L. J. Kramer, D. Helmig, J. F. Burkhart, A. Stohl, S. Oltmans, and R. E. Honrath
Atmos. Chem. Phys., 15, 6827–6849, https://doi.org/10.5194/acp-15-6827-2015, https://doi.org/10.5194/acp-15-6827-2015, 2015
J. Huang, H. Liu, J. H. Crawford, C. Chan, D. B. Considine, Y. Zhang, X. Zheng, C. Zhao, V. Thouret, S. J. Oltmans, S. C. Liu, D. B. A. Jones, S. D. Steenrod, and M. R. Damon
Atmos. Chem. Phys., 15, 5161–5179, https://doi.org/10.5194/acp-15-5161-2015, https://doi.org/10.5194/acp-15-5161-2015, 2015
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High ozone concentrations (up to 94.7ppbv) were frequently observed at an altitude of ~1.5--2km over Beijing during April--May 2005. Ozone due to Asian anthropogenic pollution made major contributions to the observed ozone enhancements. These enhancements typically occurred under southerly wind and warmer conditions. An earlier onset of the Asian summer monsoon would cause more ozone enhancement events in the lower troposphere over the North China Plain in late spring and early summer.
F. Tummon, B. Hassler, N. R. P. Harris, J. Staehelin, W. Steinbrecht, J. Anderson, G. E. Bodeker, A. Bourassa, S. M. Davis, D. Degenstein, S. M. Frith, L. Froidevaux, E. Kyrölä, M. Laine, C. Long, A. A. Penckwitt, C. E. Sioris, K. H. Rosenlof, C. Roth, H.-J. Wang, and J. Wild
Atmos. Chem. Phys., 15, 3021–3043, https://doi.org/10.5194/acp-15-3021-2015, https://doi.org/10.5194/acp-15-3021-2015, 2015
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Understanding ozone trends in the vertical is vital in terms of assessing the success of the Montreal Protocol. This paper compares and analyses the long-term trends in stratospheric ozone from seven new merged satellite data sets. The data sets largely agree well with each other, particularly for the negative trends seen in the early period 1984-1997. For the 1998-2011 period there is less agreement, but a clear shift from negative to mostly positive trends.
I. Petropavlovskikh, R. Evans, G. McConville, G. L. Manney, and H. E. Rieder
Atmos. Chem. Phys., 15, 1585–1598, https://doi.org/10.5194/acp-15-1585-2015, https://doi.org/10.5194/acp-15-1585-2015, 2015
R. Ahmadov, S. McKeen, M. Trainer, R. Banta, A. Brewer, S. Brown, P. M. Edwards, J. A. de Gouw, G. J. Frost, J. Gilman, D. Helmig, B. Johnson, A. Karion, A. Koss, A. Langford, B. Lerner, J. Olson, S. Oltmans, J. Peischl, G. Pétron, Y. Pichugina, J. M. Roberts, T. Ryerson, R. Schnell, C. Senff, C. Sweeney, C. Thompson, P. R. Veres, C. Warneke, R. Wild, E. J. Williams, B. Yuan, and R. Zamora
Atmos. Chem. Phys., 15, 411–429, https://doi.org/10.5194/acp-15-411-2015, https://doi.org/10.5194/acp-15-411-2015, 2015
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High 2013 wintertime O3 pollution events associated with oil/gas production within the Uinta Basin are studied using a 3D model. It's able quantitatively to reproduce these events using emission estimates of O3 precursors based on ambient measurements (top-down approach), but unable to reproduce them using a recent bottom-up emission inventory for the oil/gas industry. The role of various physical and meteorological processes, chemical species and pathways contributing to high O3 are quantified.
A. Laeng, U. Grabowski, T. von Clarmann, G. Stiller, N. Glatthor, M. Höpfner, S. Kellmann, M. Kiefer, A. Linden, S. Lossow, V. Sofieva, I. Petropavlovskikh, D. Hubert, T. Bathgate, P. Bernath, C. D. Boone, C. Clerbaux, P. Coheur, R. Damadeo, D. Degenstein, S. Frith, L. Froidevaux, J. Gille, K. Hoppel, M. McHugh, Y. Kasai, J. Lumpe, N. Rahpoe, G. Toon, T. Sano, M. Suzuki, J. Tamminen, J. Urban, K. Walker, M. Weber, and J. Zawodny
Atmos. Meas. Tech., 7, 3971–3987, https://doi.org/10.5194/amt-7-3971-2014, https://doi.org/10.5194/amt-7-3971-2014, 2014
S. J. Oltmans, A. Karion, R. C. Schnell, G. Pétron, C. Sweeney, S. Wolter, D. Neff, S. A. Montzka, B. R. Miller, D. Helmig, B. J. Johnson, and J. Hueber
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-14-20117-2014, https://doi.org/10.5194/acpd-14-20117-2014, 2014
Revised manuscript not accepted
B. Hassler, I. Petropavlovskikh, J. Staehelin, T. August, P. K. Bhartia, C. Clerbaux, D. Degenstein, M. De Mazière, B. M. Dinelli, A. Dudhia, G. Dufour, S. M. Frith, L. Froidevaux, S. Godin-Beekmann, J. Granville, N. R. P. Harris, K. Hoppel, D. Hubert, Y. Kasai, M. J. Kurylo, E. Kyrölä, J.-C. Lambert, P. F. Levelt, C. T. McElroy, R. D. McPeters, R. Munro, H. Nakajima, A. Parrish, P. Raspollini, E. E. Remsberg, K. H. Rosenlof, A. Rozanov, T. Sano, Y. Sasano, M. Shiotani, H. G. J. Smit, G. Stiller, J. Tamminen, D. W. Tarasick, J. Urban, R. J. van der A, J. P. Veefkind, C. Vigouroux, T. von Clarmann, C. von Savigny, K. A. Walker, M. Weber, J. Wild, and J. M. Zawodny
Atmos. Meas. Tech., 7, 1395–1427, https://doi.org/10.5194/amt-7-1395-2014, https://doi.org/10.5194/amt-7-1395-2014, 2014
K. Miyagawa, I. Petropavlovskikh, R. D. Evans, C. Long, J. Wild, G. L. Manney, and W. H. Daffer
Atmos. Chem. Phys., 14, 3945–3968, https://doi.org/10.5194/acp-14-3945-2014, https://doi.org/10.5194/acp-14-3945-2014, 2014
M. C. Parrondo, M. Gil, M. Yela, B. J. Johnson, and H. A. Ochoa
Atmos. Chem. Phys., 14, 217–229, https://doi.org/10.5194/acp-14-217-2014, https://doi.org/10.5194/acp-14-217-2014, 2014
V. F. Sofieva, J. Tamminen, E. Kyrölä, T. Mielonen, P. Veefkind, B. Hassler, and G.E. Bodeker
Atmos. Chem. Phys., 14, 283–299, https://doi.org/10.5194/acp-14-283-2014, https://doi.org/10.5194/acp-14-283-2014, 2014
A. Park, S. Guillas, and I. Petropavlovskikh
Atmos. Chem. Phys., 13, 11473–11501, https://doi.org/10.5194/acp-13-11473-2013, https://doi.org/10.5194/acp-13-11473-2013, 2013
S. Brönnimann, J. Bhend, J. Franke, S. Flückiger, A. M. Fischer, R. Bleisch, G. Bodeker, B. Hassler, E. Rozanov, and M. Schraner
Atmos. Chem. Phys., 13, 9623–9639, https://doi.org/10.5194/acp-13-9623-2013, https://doi.org/10.5194/acp-13-9623-2013, 2013
B. Hassler, P. J. Young, R. W. Portmann, G. E. Bodeker, J. S. Daniel, K. H. Rosenlof, and S. Solomon
Atmos. Chem. Phys., 13, 5533–5550, https://doi.org/10.5194/acp-13-5533-2013, https://doi.org/10.5194/acp-13-5533-2013, 2013
F. Hasebe, Y. Inai, M. Shiotani, M. Fujiwara, H. Vömel, N. Nishi, S.-Y. Ogino, T. Shibata, S. Iwasaki, N. Komala, T. Peter, and S. J. Oltmans
Atmos. Chem. Phys., 13, 4393–4411, https://doi.org/10.5194/acp-13-4393-2013, https://doi.org/10.5194/acp-13-4393-2013, 2013
G. E. Bodeker, B. Hassler, P. J. Young, and R. W. Portmann
Earth Syst. Sci. Data, 5, 31–43, https://doi.org/10.5194/essd-5-31-2013, https://doi.org/10.5194/essd-5-31-2013, 2013
M. Huang, G. R. Carmichael, T. Chai, R. B. Pierce, S. J. Oltmans, D. A. Jaffe, K. W. Bowman, A. Kaduwela, C. Cai, S. N. Spak, A. J. Weinheimer, L. G. Huey, and G. S. Diskin
Atmos. Chem. Phys., 13, 359–391, https://doi.org/10.5194/acp-13-359-2013, https://doi.org/10.5194/acp-13-359-2013, 2013
Related subject area
Subject: Gases | Research Activity: Field Measurements | Altitude Range: Stratosphere | Science Focus: Chemistry (chemical composition and reactions)
Aircraft observations of biomass burning pollutants in the equatorial lower stratosphere over the tropical western Pacific during boreal winter
Measurement report: Greenhouse gas profiles and age of air from the 2021 HEMERA-TWIN balloon launch
Technical note: Water vapour climatologies in the extra-tropical upper troposphere and lower stratosphere derived from a synthesis of passenger and research aircraft measurements
Stratospheric δ13CO2 observed over Japan and its governing processes and potential as an air age tracer
Ozone and water vapor variability in the polar middle atmosphere observed with ground-based microwave radiometers
Global seasonal distribution of CH2Br2 and CHBr3 in the upper troposphere and lower stratosphere
Redistribution of total reactive nitrogen in the lowermost Arctic stratosphere during the cold winter 2015/2016
Comparison of inorganic chlorine in the Antarctic and Arctic lowermost stratosphere by separate late winter aircraft measurements
Organic and inorganic bromine measurements around the extratropical tropopause and lowermost stratosphere: insights into the transport pathways and total bromine
GUV long-term measurements of total ozone column and effective cloud transmittance at three Norwegian sites
Mixing at the extratropical tropopause as characterized by collocated airborne H2O and O3 lidar observations
Gravitational separation of Ar∕N2 and age of air in the lowermost stratosphere in airborne observations and a chemical transport model
Effect of deep convection on the tropical tropopause layer composition over the southwest Indian Ocean during austral summer
Investigating stratospheric changes between 2009 and 2018 with halogenated trace gas data from aircraft, AirCores, and a global model focusing on CFC-11
Bromine from short-lived source gases in the extratropical northern hemispheric upper troposphere and lower stratosphere (UTLS)
Chlorine partitioning in the lowermost Arctic vortex during the cold winter 2015/2016
Balloon-borne measurements of temperature, water vapor, ozone and aerosol backscatter on the southern slopes of the Himalayas during StratoClim 2016–2017
Mercury distribution in the upper troposphere and lowermost stratosphere according to measurements by the IAGOS-CARIBIC observatory: 2014–2016
EuBrewNet – A European Brewer network (COST Action ES1207), an overview
Stratospheric ozone measurements at Arosa (Switzerland): history and scientific relevance
Continued increase of CFC-113a (CCl3CF3) mixing ratios in the global atmosphere: emissions, occurrence and potential sources
Evaluation of stratospheric age of air from CF4, C2F6, C3F8, CHF3, HFC-125, HFC-227ea and SF6; implications for the calculations of halocarbon lifetimes, fractional release factors and ozone depletion potentials
Water vapor increase in the lower stratosphere of the Northern Hemisphere due to the Asian monsoon anticyclone observed during the TACTS/ESMVal campaigns
A refined method for calculating equivalent effective stratospheric chlorine
Hemispheric asymmetry in stratospheric NO2 trends
Mean age of stratospheric air derived from AirCore observations
Enhanced stratospheric water vapor over the summertime continental United States and the role of overshooting convection
An assessment of the climatological representativeness of IAGOS-CARIBIC trace gas measurements using EMAC model simulations
Impact of a moderate volcanic eruption on chemistry in the lower stratosphere: balloon-borne observations and model calculations
20 years of ClO measurements in the Antarctic lower stratosphere
Impact of the Asian monsoon on the extratropical lower stratosphere: trace gas observations during TACTS over Europe 2012
An objective determination of optimal site locations for detecting expected trends in upper-air temperature and total column ozone
First quasi-Lagrangian in situ measurements of Antarctic Polar springtime ozone: observed ozone loss rates from the Concordiasi long-duration balloon campaign
Constraining the N2O5 UV absorption cross section from spectroscopic trace gas measurements in the tropical mid-stratosphere
Diurnal variations of stratospheric ozone measured by ground-based microwave remote sensing at the Mauna Loa NDACC site: measurement validation and GEOSCCM model comparison
Trends in stratospheric ozone profiles using functional mixed models
Arctic stratospheric dehydration – Part 1: Unprecedented observation of vertical redistribution of water
Reconciliation of essential process parameters for an enhanced predictability of Arctic stratospheric ozone loss and its climate interactions (RECONCILE): activities and results
Re-analysis of ground-based microwave ClO measurements from Mauna Kea, 1992 to early 2012
Atmospheric test of the J(BrONO2)/kBrO+NO2 ratio: implications for total stratospheric Bry and bromine-mediated ozone loss
Stratospheric BrO abundance measured by a balloon-borne submillimeterwave radiometer
Observation-based assessment of stratospheric fractional release, lifetimes, and ozone depletion potentials of ten important source gases
Detection in the summer polar stratosphere of pollution plume from East Asia and North America by balloon-borne in situ CO measurements
Commentary on using equivalent latitude in the upper troposphere and lower stratosphere
Unusually low ozone, HCl, and HNO3 column measurements at Eureka, Canada during winter/spring 2011
ClOOCl photolysis at high solar zenith angles: analysis of the RECONCILE self-match flight
In-situ observation of Asian pollution transported into the Arctic lowermost stratosphere
Retrievals of chlorine chemistry kinetic parameters from Antarctic ClO microwave radiometer measurements
Evidence for heterogeneous chlorine activation in the tropical UTLS
A closer look at Arctic ozone loss and polar stratospheric clouds
Jasna V. Pittman, Bruce C. Daube, Steven C. Wofsy, Elliot L. Atlas, Maria A. Navarro, Eric J. Hintsa, Fred L. Moore, Geoff S. Dutton, James W. Elkins, Troy D. Thornberry, Andrew W. Rollins, Eric J. Jensen, Thaopaul Bui, Jonathan Dean-Day, and Leonhard Pfister
Atmos. Chem. Phys., 25, 7543–7562, https://doi.org/10.5194/acp-25-7543-2025, https://doi.org/10.5194/acp-25-7543-2025, 2025
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Biomass fires emit aerosols and precursors that can provide a novel environment for initiating stratospheric ozone loss. The Airborne Tropical TRopopause EXperiment campaign sampled the western Pacific, the dominant longitudes for surface air lofted by convection to enter the global stratosphere. Aircraft measurements over multiple flights revealed persistent layers of biomass burning pollutants entering the lower stratosphere and originating from fires as far away as Africa and Indonesia.
Tanja J. Schuck, Johannes Degen, Timo Keber, Katharina Meixner, Thomas Wagenhäuser, Mélanie Ghysels, Georges Durry, Nadir Amarouche, Alessandro Zanchetta, Steven van Heuven, Huilin Chen, Johannes C. Laube, Sophie L. Baartman, Carina van der Veen, Maria Elena Popa, and Andreas Engel
Atmos. Chem. Phys., 25, 4333–4348, https://doi.org/10.5194/acp-25-4333-2025, https://doi.org/10.5194/acp-25-4333-2025, 2025
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A balloon was launched in 2021 in the Arctic to carry instruments for trace gas measurements up to 32 km. One purpose was to compare measurement techniques. We focus on the major greenhouse gases. To measure these, air was sampled with the AirCore technique and with flask sampling, and samples were analysed after the flight. In flight, observations were done with an optical method. In a companion paper, we report on observations of chlorine and bromine containing trace gases.
Patrick Konjari, Christian Rolf, Michaela I. Hegglin, Susanne Rohs, Yun Li, Andreas Zahn, Harald Bönisch, Philippe Nedelec, Martina Krämer, and Andreas Petzold
Atmos. Chem. Phys., 25, 4269–4289, https://doi.org/10.5194/acp-25-4269-2025, https://doi.org/10.5194/acp-25-4269-2025, 2025
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This study introduces a new method to derive adjusted water vapor (H2O) climatologies for the upper tropopshere and lower statosphere (UT/LS) using data from 60 000 flights under the IAGOS program. Biases in the IAGOS water vapour dataset are adjusted, based on the more accurate IAGOS-CARIBIC data. The resulting highly resolved H2O climatologies will contribute to a better understanding of the H2O variability in the UT/LS and its connection to various transport and mixing processes.
Satoshi Sugawara, Shinji Morimoto, Shigeyuki Ishidoya, Taku Umezawa, Shuji Aoki, Takakiyo Nakazawa, Sakae Toyoda, Kentaro Ishijima, Daisuke Goto, and Hideyuki Honda
EGUsphere, https://doi.org/10.5194/egusphere-2025-1003, https://doi.org/10.5194/egusphere-2025-1003, 2025
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We have been collected stratospheric air samples since 1985 over Japan and analyzed them for δ13CO2. δ13CO2 has decreased through time in the mid-stratosphere with an average rate of change of −0.026 ± 0.001 ‰ yr−1. It has become clear that the oxidation of methane and gravitational separation are important for stratospheric δ13CO2 variations. We newly defined ‘stratospheric potential δ13C’ as a quasi-conservative parameter and demonstrated that it can be used as an air age tracer.
Guochun Shi, Witali Krochin, Eric Sauvageat, and Gunter Stober
Atmos. Chem. Phys., 23, 9137–9159, https://doi.org/10.5194/acp-23-9137-2023, https://doi.org/10.5194/acp-23-9137-2023, 2023
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We present the interannual and climatological behavior of ozone and water vapor from microwave radiometers in the Arctic.
By defining a virtual conjugate latitude station in the Southern Hemisphere, we investigate altitude-dependent interhemispheric differences and estimate the ascent and descent rates of water vapor in both hemispheres. Ozone and water vapor measurements will create a deeper understanding of the evolution of middle atmospheric ozone and water vapor.
Markus Jesswein, Rafael P. Fernandez, Lucas Berná, Alfonso Saiz-Lopez, Jens-Uwe Grooß, Ryan Hossaini, Eric C. Apel, Rebecca S. Hornbrook, Elliot L. Atlas, Donald R. Blake, Stephen Montzka, Timo Keber, Tanja Schuck, Thomas Wagenhäuser, and Andreas Engel
Atmos. Chem. Phys., 22, 15049–15070, https://doi.org/10.5194/acp-22-15049-2022, https://doi.org/10.5194/acp-22-15049-2022, 2022
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This study presents the global and seasonal distribution of the two major brominated short-lived substances CH2Br2 and CHBr3 in the upper troposphere and lower stratosphere based on observations from several aircraft campaigns. They show similar seasonality for both hemispheres, except in the respective hemispheric autumn lower stratosphere. A comparison with the TOMCAT and CAM-Chem models shows good agreement in the annual mean but larger differences in the seasonal consideration.
Helmut Ziereis, Peter Hoor, Jens-Uwe Grooß, Andreas Zahn, Greta Stratmann, Paul Stock, Michael Lichtenstern, Jens Krause, Vera Bense, Armin Afchine, Christian Rolf, Wolfgang Woiwode, Marleen Braun, Jörn Ungermann, Andreas Marsing, Christiane Voigt, Andreas Engel, Björn-Martin Sinnhuber, and Hermann Oelhaf
Atmos. Chem. Phys., 22, 3631–3654, https://doi.org/10.5194/acp-22-3631-2022, https://doi.org/10.5194/acp-22-3631-2022, 2022
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Airborne observations were conducted in the lowermost Arctic stratosphere during the winter of 2015/2016. The observed distribution of reactive nitrogen shows clear indications of nitrification in mid-winter and denitrification in late winter. This was caused by the formation of polar stratospheric cloud particles, which were observed during several flights. The sedimentation and evaporation of these particles and the descent of air masses cause a redistribution of reactive nitrogen.
Markus Jesswein, Heiko Bozem, Hans-Christoph Lachnitt, Peter Hoor, Thomas Wagenhäuser, Timo Keber, Tanja Schuck, and Andreas Engel
Atmos. Chem. Phys., 21, 17225–17241, https://doi.org/10.5194/acp-21-17225-2021, https://doi.org/10.5194/acp-21-17225-2021, 2021
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This study presents and compares inorganic chlorine (Cly) derived from observations with the HALO research aircraft in the Antarctic late winter–early fall 2019 and the Arctic winter 2015–2016. Trend-corrected correlations from the Northern Hemisphere show excellent agreement with those from the Southern Hemisphere. After observation allocation inside and outside the vortex based on N2O measurements, results of the two campaigns reveal substantial differences in Cly within the respective vortex.
Meike K. Rotermund, Vera Bense, Martyn P. Chipperfield, Andreas Engel, Jens-Uwe Grooß, Peter Hoor, Tilman Hüneke, Timo Keber, Flora Kluge, Benjamin Schreiner, Tanja Schuck, Bärbel Vogel, Andreas Zahn, and Klaus Pfeilsticker
Atmos. Chem. Phys., 21, 15375–15407, https://doi.org/10.5194/acp-21-15375-2021, https://doi.org/10.5194/acp-21-15375-2021, 2021
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Airborne total bromine (Brtot) and tracer measurements suggest Brtot-rich air masses persistently protruded into the lower stratosphere (LS), creating a high Brtot region over the North Atlantic in fall 2017. The main source is via isentropic transport by the Asian monsoon and to a lesser extent transport across the extratropical tropopause as quantified by a Lagrange model. The transport of Brtot via Central American hurricanes is also observed. Lastly, the impact of Brtot on LS O3 is assessed.
Tove M. Svendby, Bjørn Johnsen, Arve Kylling, Arne Dahlback, Germar H. Bernhard, Georg H. Hansen, Boyan Petkov, and Vito Vitale
Atmos. Chem. Phys., 21, 7881–7899, https://doi.org/10.5194/acp-21-7881-2021, https://doi.org/10.5194/acp-21-7881-2021, 2021
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Measurements of total ozone and effective cloud transmittance (eCLT) have been performed since 1995 at three Norwegian sites with GUV multi-filter instruments. The unique data sets of high-time-resolution measurements can be used for a broad range of studies. Data analyses reveal an increase in total ozone above Norway from 1995 to 2019. Measurements of GUV eCLT indicate changes in albedo in Ny-Ålesund (Svalbard) during the past 25 years, most likely resulting from increased Arctic ice melt.
Andreas Schäfler, Andreas Fix, and Martin Wirth
Atmos. Chem. Phys., 21, 5217–5234, https://doi.org/10.5194/acp-21-5217-2021, https://doi.org/10.5194/acp-21-5217-2021, 2021
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First-ever, collocated ozone and water vapor lidar observations across the tropopause are applied to investigate the extratropical transition layer (ExTL). The combined view of a quasi-instantaneous cross section and its tracer–tracer depiction allows us to analyze the ExTL shape and composition and the formation of mixing lines in relation to the dynamic situation. Such lidar data are relevant for future upper-tropospheric and lower-stratospheric investigations and model validations.
Benjamin Birner, Martyn P. Chipperfield, Eric J. Morgan, Britton B. Stephens, Marianna Linz, Wuhu Feng, Chris Wilson, Jonathan D. Bent, Steven C. Wofsy, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Chem. Phys., 20, 12391–12408, https://doi.org/10.5194/acp-20-12391-2020, https://doi.org/10.5194/acp-20-12391-2020, 2020
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With new high-precision observations from nine aircraft campaigns and 3-D chemical transport modeling, we show that the argon-to-nitrogen ratio (Ar / N2) in the lowermost stratosphere provides a useful constraint on the “age of air” (the time elapsed since entry of an air parcel into the stratosphere). Therefore, Ar / N2 in combination with traditional age-of-air indicators, such as CO2 and N2O, could provide new insights into atmospheric mixing and transport.
Stephanie Evan, Jerome Brioude, Karen Rosenlof, Sean M. Davis, Holger Vömel, Damien Héron, Françoise Posny, Jean-Marc Metzger, Valentin Duflot, Guillaume Payen, Hélène Vérèmes, Philippe Keckhut, and Jean-Pierre Cammas
Atmos. Chem. Phys., 20, 10565–10586, https://doi.org/10.5194/acp-20-10565-2020, https://doi.org/10.5194/acp-20-10565-2020, 2020
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The role of deep convection in the southwest Indian Ocean (the 3rd most active tropical cyclone basin) on the composition of the tropical tropopause layer (TTL) and the climate system is less understood due to scarce observations. Balloon-borne lidar and satellite measurements in the southwest Indian Ocean were used to study tropical cyclones' influence on TTL composition. This study compares the impact of a tropical storm and cyclone on the humidification of the TTL over the SW Indian Ocean.
Johannes C. Laube, Emma C. Leedham Elvidge, Karina E. Adcock, Bianca Baier, Carl A. M. Brenninkmeijer, Huilin Chen, Elise S. Droste, Jens-Uwe Grooß, Pauli Heikkinen, Andrew J. Hind, Rigel Kivi, Alexander Lojko, Stephen A. Montzka, David E. Oram, Steve Randall, Thomas Röckmann, William T. Sturges, Colm Sweeney, Max Thomas, Elinor Tuffnell, and Felix Ploeger
Atmos. Chem. Phys., 20, 9771–9782, https://doi.org/10.5194/acp-20-9771-2020, https://doi.org/10.5194/acp-20-9771-2020, 2020
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We demonstrate that AirCore technology, which is based on small low-cost balloons, can provide access to trace gas measurements such as CFCs at ultra-low abundances. This is a new way to quantify ozone-depleting, and related, substances in the stratosphere, which is largely inaccessible to aircraft. We show two potential uses: (a) tracking the stratospheric circulation, which is predicted to change, and (b) assessing three common meteorological reanalyses driving a global stratospheric model.
Timo Keber, Harald Bönisch, Carl Hartick, Marius Hauck, Fides Lefrancois, Florian Obersteiner, Akima Ringsdorf, Nils Schohl, Tanja Schuck, Ryan Hossaini, Phoebe Graf, Patrick Jöckel, and Andreas Engel
Atmos. Chem. Phys., 20, 4105–4132, https://doi.org/10.5194/acp-20-4105-2020, https://doi.org/10.5194/acp-20-4105-2020, 2020
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In this paper we summarize observations of short-lived halocarbons in the tropopause region. We show that, especially during winter, the levels of short-lived bromine gases at the extratropical tropopause are higher than at the tropical tropopause. We discuss the impact of the distributions on stratospheric bromine levels and compare our observations to two models with four different emission scenarios.
Andreas Marsing, Tina Jurkat-Witschas, Jens-Uwe Grooß, Stefan Kaufmann, Romy Heller, Andreas Engel, Peter Hoor, Jens Krause, and Christiane Voigt
Atmos. Chem. Phys., 19, 10757–10772, https://doi.org/10.5194/acp-19-10757-2019, https://doi.org/10.5194/acp-19-10757-2019, 2019
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We study the partitioning of inorganic chlorine into active (ozone-depleting) and reservoir species in the lowermost stratosphere of the Arctic polar vortex, using novel in situ aircraft measurements in winter 2015/2016. We observe a change in recovery pathways of the reservoirs HCl and ClONO2 with increasing potential temperature. A comparison with the CLaMS model relates the observations to the vortex-wide evolution and confirms unresolved discrepancies in the mid-winter HCl distribution.
Simone Brunamonti, Teresa Jorge, Peter Oelsner, Sreeharsha Hanumanthu, Bhupendra B. Singh, K. Ravi Kumar, Sunil Sonbawne, Susanne Meier, Deepak Singh, Frank G. Wienhold, Bei Ping Luo, Maxi Boettcher, Yann Poltera, Hannu Jauhiainen, Rijan Kayastha, Jagadishwor Karmacharya, Ruud Dirksen, Manish Naja, Markus Rex, Suvarna Fadnavis, and Thomas Peter
Atmos. Chem. Phys., 18, 15937–15957, https://doi.org/10.5194/acp-18-15937-2018, https://doi.org/10.5194/acp-18-15937-2018, 2018
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Based on balloon-borne measurements performed in India and Nepal in 2016–2017, we infer the vertical distributions of water vapor, ozone and aerosols in the atmosphere, from the surface to 30 km altitude. Our measurements show that the atmospheric dynamics of the Asian summer monsoon system over the polluted Indian subcontinent lead to increased concentrations of water vapor and aerosols in the high atmosphere (approximately 14–20 km altitude), which can have an important effect on climate.
Franz Slemr, Andreas Weigelt, Ralf Ebinghaus, Johannes Bieser, Carl A. M. Brenninkmeijer, Armin Rauthe-Schöch, Markus Hermann, Bengt G. Martinsson, Peter van Velthoven, Harald Bönisch, Marco Neumaier, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 18, 12329–12343, https://doi.org/10.5194/acp-18-12329-2018, https://doi.org/10.5194/acp-18-12329-2018, 2018
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Total and elemental mercury were measured in the upper troposphere and lower stratosphere onboard a passenger aircraft. Their concentrations in the upper troposphere were comparable implying low concentrations of oxidized mercury in this region. Large scale seasonally dependent influence of emissions from biomass burning was also observed. Their distributions in the lower stratosphere implies a long stratospheric lifetime, which precludes significant mercury oxidation by ozone.
John S. Rimmer, Alberto Redondas, and Tomi Karppinen
Atmos. Chem. Phys., 18, 10347–10353, https://doi.org/10.5194/acp-18-10347-2018, https://doi.org/10.5194/acp-18-10347-2018, 2018
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The Vienna Convention to Protect the Ozone Layer was signed in 1985 to promote research and information exchange on the science of ozone depletion including monitoring of total ozone column and spectrally resolved solar ultraviolet radiation. This is a global challenge and, as such, all efforts to gather data should be consistent. This work has resulted in a framework for all Brewer Ozone spectrophotometers to provide data in a consistent way in terms of calibration and quality assurance.
Johannes Staehelin, Pierre Viatte, Rene Stübi, Fiona Tummon, and Thomas Peter
Atmos. Chem. Phys., 18, 6567–6584, https://doi.org/10.5194/acp-18-6567-2018, https://doi.org/10.5194/acp-18-6567-2018, 2018
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In 1926, total ozone series started in Arosa (Switzerland). Since the mid-1970s ozone is measured to document the effects of anthropogenic ozone-depleting substances (ODSs). ODSs peaked around the mid-1990s, resulting from the Montreal Protocol (1987) and its enforcement. Chemical ozone depletion stopped worsening around the mid-1990s but the large variability complicates demonstrations of the success of the protocol and the effect of ongoing climate change still requires continuous measurement.
Karina E. Adcock, Claire E. Reeves, Lauren J. Gooch, Emma C. Leedham Elvidge, Matthew J. Ashfold, Carl A. M. Brenninkmeijer, Charles Chou, Paul J. Fraser, Ray L. Langenfelds, Norfazrin Mohd Hanif, Simon O'Doherty, David E. Oram, Chang-Feng Ou-Yang, Siew Moi Phang, Azizan Abu Samah, Thomas Röckmann, William T. Sturges, and Johannes C. Laube
Atmos. Chem. Phys., 18, 4737–4751, https://doi.org/10.5194/acp-18-4737-2018, https://doi.org/10.5194/acp-18-4737-2018, 2018
Emma C. Leedham Elvidge, Harald Bönisch, Carl A. M. Brenninkmeijer, Andreas Engel, Paul J. Fraser, Eileen Gallacher, Ray Langenfelds, Jens Mühle, David E. Oram, Eric A. Ray, Anna R. Ridley, Thomas Röckmann, William T. Sturges, Ray F. Weiss, and Johannes C. Laube
Atmos. Chem. Phys., 18, 3369–3385, https://doi.org/10.5194/acp-18-3369-2018, https://doi.org/10.5194/acp-18-3369-2018, 2018
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Chemical species measured in stratospheric air can be used as proxies for stratospheric circulation changes which cannot be measured directly. A range of tracers is important to understand changing stratospheric dynamics. We demonstrate the suitability of PFCs and HFCs as tracers and support recent work that reduces the current stratospheric lifetime of SF6. Updates to policy-relevant parameters (e.g. stratospheric lifetime) linked to this change are provided for O3-depleting substances.
Christian Rolf, Bärbel Vogel, Peter Hoor, Armin Afchine, Gebhard Günther, Martina Krämer, Rolf Müller, Stefan Müller, Nicole Spelten, and Martin Riese
Atmos. Chem. Phys., 18, 2973–2983, https://doi.org/10.5194/acp-18-2973-2018, https://doi.org/10.5194/acp-18-2973-2018, 2018
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The Asian monsoon is a pronounced circulation system linked to rapid vertical transport of surface air from India and east Asia in the summer months. We found, based on aircraft measurements, higher concentration of water vapor in the lowermost stratosphere caused by the Asian monsoon. Enrichment of water vapor concentrations in the lowermost stratosphere impacts the radiation budget and thus climate. Understanding those variations in water vapor is important for climate projections.
Andreas Engel, Harald Bönisch, Jennifer Ostermöller, Martyn P. Chipperfield, Sandip Dhomse, and Patrick Jöckel
Atmos. Chem. Phys., 18, 601–619, https://doi.org/10.5194/acp-18-601-2018, https://doi.org/10.5194/acp-18-601-2018, 2018
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We present a new method to derive equivalent effective stratospheric chlorine (EESC), which is based on an improved formulation of the propagation of trends of species with chemical loss from the troposphere to the stratosphere. EESC calculated with the new method shows much better agreement with model-derived ESC. Based on this new formulation, we expect the halogen impact on midlatitude stratospheric ozone to return to 1980 values about 10 years later, then using the current formulation.
Margarita Yela, Manuel Gil-Ojeda, Mónica Navarro-Comas, David Gonzalez-Bartolomé, Olga Puentedura, Bernd Funke, Javier Iglesias, Santiago Rodríguez, Omaira García, Héctor Ochoa, and Guillermo Deferrari
Atmos. Chem. Phys., 17, 13373–13389, https://doi.org/10.5194/acp-17-13373-2017, https://doi.org/10.5194/acp-17-13373-2017, 2017
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The paper focuses on stratospheric trends of NO2, a species involved in the ozone equilibrium, using data from four NDACC stations. The global stratospheric NO2 trend has not yet been established conclusively. We analyse DOAS data from stations in the Northern Hemisphere and Southern Hemisphere during 1993–2014. The most relevant finding is the hemispheric asymmetry found in the sign of the NO2 trend, providing further evidence of changes in the stratosphere dynamics on the global scale.
Andreas Engel, Harald Bönisch, Markus Ullrich, Robert Sitals, Olivier Membrive, Francois Danis, and Cyril Crevoisier
Atmos. Chem. Phys., 17, 6825–6838, https://doi.org/10.5194/acp-17-6825-2017, https://doi.org/10.5194/acp-17-6825-2017, 2017
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AirCore is new technique for sampling stratospheric air. We present new observations of CO2 and CH4 using AirCore and derive stratospheric transport time, called the mean age of air. The purpose of using AirCore is to provide a cost-effective tool for deriving mean age. Mean age may serve as a proxy to investigate changes in stratospheric circulation. We show that there is no statistically significant trend in our 40-year time series of mean age, which is now extended using AirCore.
Robert L. Herman, Eric A. Ray, Karen H. Rosenlof, Kristopher M. Bedka, Michael J. Schwartz, William G. Read, Robert F. Troy, Keith Chin, Lance E. Christensen, Dejian Fu, Robert A. Stachnik, T. Paul Bui, and Jonathan M. Dean-Day
Atmos. Chem. Phys., 17, 6113–6124, https://doi.org/10.5194/acp-17-6113-2017, https://doi.org/10.5194/acp-17-6113-2017, 2017
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This study reports new aircraft field observations of elevated water vapor greater than 10 ppmv in the overworld stratosphere over the summertime continental US. Back trajectories from the flight track intersect overshooting convective tops within the previous 1 to 7 days, suggesting that ice is convectively and irreversibly transported to the stratosphere in the most energetic overshooting convective events. Satellite measurements (Aura MLS) indicate that such events are uncommon (< 1 %).
Johannes Eckstein, Roland Ruhnke, Andreas Zahn, Marco Neumaier, Ole Kirner, and Peter Braesicke
Atmos. Chem. Phys., 17, 2775–2794, https://doi.org/10.5194/acp-17-2775-2017, https://doi.org/10.5194/acp-17-2775-2017, 2017
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Data on atmospheric trace gases have been collected with instruments on-board a commercial airliner for more than 10 years in the CARIBIC project. We investigate which species in the dataset can be used for a representative climatology, by comparing data from the chemistry–climate model EMAC along the flight paths to a larger set of model data. We find that long-lived species are captured quite well by the CARIBIC sample while this is not the case for more variable, shorter-lived species.
Gwenaël Berthet, Fabrice Jégou, Valéry Catoire, Gisèle Krysztofiak, Jean-Baptiste Renard, Adam E. Bourassa, Doug A. Degenstein, Colette Brogniez, Marcel Dorf, Sebastian Kreycy, Klaus Pfeilsticker, Bodo Werner, Franck Lefèvre, Tjarda J. Roberts, Thibaut Lurton, Damien Vignelles, Nelson Bègue, Quentin Bourgeois, Daniel Daugeron, Michel Chartier, Claude Robert, Bertrand Gaubicher, and Christophe Guimbaud
Atmos. Chem. Phys., 17, 2229–2253, https://doi.org/10.5194/acp-17-2229-2017, https://doi.org/10.5194/acp-17-2229-2017, 2017
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Since the last major volcanic event, i.e. the Pinatubo eruption in 1991, only
moderateeruptions have regularly injected sulfur into the stratosphere, typically enhancing the aerosol loading for several months. We investigate here for the first time the chemical perturbation associated with the Sarychev eruption in June 2009, using balloon-borne instruments and model calculations. Some chemical compounds are significantly affected by the aerosols, but the impact on stratospheric ozone is weak.
Gerald E. Nedoluha, Brian J. Connor, Thomas Mooney, James W. Barrett, Alan Parrish, R. Michael Gomez, Ian Boyd, Douglas R. Allen, Michael Kotkamp, Stefanie Kremser, Terry Deshler, Paul Newman, and Michelle L. Santee
Atmos. Chem. Phys., 16, 10725–10734, https://doi.org/10.5194/acp-16-10725-2016, https://doi.org/10.5194/acp-16-10725-2016, 2016
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Chlorine monoxide (ClO) is central to the formation of the springtime Antarctic ozone hole since it is the catalytic agent in the most important ozone-depleting chemical cycle. We present 20 years of measurements of ClO from the Chlorine monOxide Experiment at Scott Base, Antarctica, and 12 years of measurements from the Aura Microwave Limb Sounder to show that the trends in ClO during the ozone hole season are consistent with changes in stratospheric chlorine observed elsewhere.
Stefan Müller, Peter Hoor, Heiko Bozem, Ellen Gute, Bärbel Vogel, Andreas Zahn, Harald Bönisch, Timo Keber, Martina Krämer, Christian Rolf, Martin Riese, Hans Schlager, and Andreas Engel
Atmos. Chem. Phys., 16, 10573–10589, https://doi.org/10.5194/acp-16-10573-2016, https://doi.org/10.5194/acp-16-10573-2016, 2016
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In situ airborne measurements performed during TACTS/ESMVal 2012 were analysed to investigate the chemical compostion of the upper troposphere and lower stratosphere. N2O, CO and O3 data show an increase in tropospherically affected air masses within the extratropical stratosphere from August to September 2012, which originate from the Asian monsoon region. Thus, the Asian monsoon anticyclone significantly affected the chemical composition of the extratropical stratosphere during summer 2012.
K. Kreher, G. E. Bodeker, and M. Sigmond
Atmos. Chem. Phys., 15, 7653–7665, https://doi.org/10.5194/acp-15-7653-2015, https://doi.org/10.5194/acp-15-7653-2015, 2015
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This manuscript aims to answer the following question: which of the existing sites engaged in upper-air temperature measurements are best located to detect expected future trends within the shortest time possible? To do so, we explore one objective method for selecting the optimal locations for detecting projected 21st century trends and then demonstrate a similar technique for objectively selecting optimal locations for detecting expected future trends in total column ozone.
R. Schofield, L. M. Avallone, L. E. Kalnajs, A. Hertzog, I. Wohltmann, and M. Rex
Atmos. Chem. Phys., 15, 2463–2472, https://doi.org/10.5194/acp-15-2463-2015, https://doi.org/10.5194/acp-15-2463-2015, 2015
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Ozone measurements onboard three Concordiasi balloons flown in the stratosphere in
the Antarctic spring of 2010 are presented. These measurements are the first long-duration in situ measurements of Antarctic springtime stratospheric ozone. By matching air parcels, ozone loss rates where derived. Downwind of the Antarctic Peninsula, very large ozone losses of up to 230 ppb per day or 16 ppbv per sunlit hour were observed. These high rates are consistent with almost complete chlorine activation.
L. Kritten, A. Butz, M. P. Chipperfield, M. Dorf, S. Dhomse, R. Hossaini, H. Oelhaf, C. Prados-Roman, G. Wetzel, and K. Pfeilsticker
Atmos. Chem. Phys., 14, 9555–9566, https://doi.org/10.5194/acp-14-9555-2014, https://doi.org/10.5194/acp-14-9555-2014, 2014
A. Parrish, I. S. Boyd, G. E. Nedoluha, P. K. Bhartia, S. M. Frith, N. A. Kramarova, B. J. Connor, G. E. Bodeker, L. Froidevaux, M. Shiotani, and T. Sakazaki
Atmos. Chem. Phys., 14, 7255–7272, https://doi.org/10.5194/acp-14-7255-2014, https://doi.org/10.5194/acp-14-7255-2014, 2014
A. Park, S. Guillas, and I. Petropavlovskikh
Atmos. Chem. Phys., 13, 11473–11501, https://doi.org/10.5194/acp-13-11473-2013, https://doi.org/10.5194/acp-13-11473-2013, 2013
S. M. Khaykin, I. Engel, H. Vömel, I. M. Formanyuk, R. Kivi, L. I. Korshunov, M. Krämer, A. D. Lykov, S. Meier, T. Naebert, M. C. Pitts, M. L. Santee, N. Spelten, F. G. Wienhold, V. A. Yushkov, and T. Peter
Atmos. Chem. Phys., 13, 11503–11517, https://doi.org/10.5194/acp-13-11503-2013, https://doi.org/10.5194/acp-13-11503-2013, 2013
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Short summary
In 1986, soon after the discovery of the Antarctic ozone hole, NOAA began year-round ozonesonde observations at South Pole Station to measure vertical profiles of ozone and temperature from the surface to 35 km. Balloon-borne ozonesondes launched at this unique site allow for tracking all phases of the yearly springtime ozone hole beginning in late winter and after sunrise, when rapid ozone depletion begins over the South Pole throughout the month of September.
In 1986, soon after the discovery of the Antarctic ozone hole, NOAA began year-round ozonesonde...
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