Articles | Volume 23, issue 5
https://doi.org/10.5194/acp-23-3015-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-3015-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Characteristics of particulate-bound n-alkanes indicating sources of PM2.5 in Beijing, China
Jiyuan Yang
College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
Guoyang Lei
College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
Chang Liu
College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
Yutong Wu
College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
Kai Hu
College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
Jinfeng Zhu
College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
Junsong Bao
State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875, China
Weili Lin
College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
Jun Jin
CORRESPONDING AUTHOR
College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China
Beijing Engineering Research Center of Food Environment and Public Health, Minzu University of China, Beijing 100081, China
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Cited articles
Alves, C., Pio, C., and Duarte, A.: Composition of extractable organic
matter of air particles from rural and urban Portuguese areas, Atmos.
Environ., 35, 5485–5496, https://doi.org/10.1016/S1352-2310(01)00243-6, 2001.
Anh, H. Q., Tran, T. M., Thuy, N. T. T., Minh, T. B., and Takahashi, S.: Screening analysis of organic micro-pollutants in road dusts from some areas in northern Vietnam: A preliminary investigation on contamination status, potential sources, human exposure, and ecological risk, Chemoshpere, 224, 428–436, https://doi.org/10.1016/j.chemosphere.2019.02.177, 2019.
Aumont, B., Valorso, R., Mouchel-Vallon, C., Camredon, M., Lee-Taylor, J., and Madronich, S.: Modeling SOA formation from the oxidation of intermediate volatility n-alkanes, Atmos. Chem. Phys., 12, 7577–7589, https://doi.org/10.5194/acp-12-7577-2012, 2012.
Aumont, B., Camredon, M., Mouchel-Vallon, C., La, S., Ouzebidour, F.,
Valorso, R., Lee-Taylor, J., and Madronich, S.: Modeling the influence of
alkane molecular structure on secondary organic aerosol formation, Faraday
Discuss., 165, 105–122, https://doi.org/10.1039/C3FD00029J, 2013.
Beijing Municipal Ecology and Environmental Bureau: Beijing Ecology and Environment Statement, 2016–2021, http://sthjj.beijing.gov.cn/, last access: 5 July 2022.
Bi, X. H., Sheng, G. Y., Peng, P. A., Chen, Y. J., Zhang, Z. Q., and Fu, J. M.: Distribution of particulate- and vapor-phase n-alkanes and polycyclic
aromatic hydrocarbons in urban atmosphere of Guangzhou, China, Atmos. Environ., 37, 289–298, https://doi.org/10.1016/S1352-2310(02)00832-4, 2003.
Bray, E. E. and Evans, E. D.: Distribution of n-paraffins as a clue to
recognition of source beds, Geochim. Cosmochim. Ac., 22, 2–15, https://doi.org/10.1016/0016-7037(61)90069-2, 1961.
Cass, G. R.: Organic molecular tracers for particulate air pollution sources,
TrAC - Trend. Anal. Chem., 17, 356–366, https://doi.org/10.1016/S0165-9936(98)00040-5, 1998.
Caumo, S., Bruns, R. E., and Vasconcellos, P. C.: Variation of the
Distribution of Atmospheric n-Alkanes Emitted by Different Fuels' Combustion, Atmosphere, 11, 643, https://doi.org/10.3390/atmos11060643, 2020.
Chen, Q., Chen, Y., Luo, X. S., Hong, Y. W., Hong, Z. Y., Zhao, Z., and
Chen, J. S.: Seasonal characteristics and health risks of PM2.5-bound
organic pollutants in industrial and urban areas of a China megacity, J.
Environ. Manage., 245, 273–281, https://doi.org/10.1016/j.jenvman.2019.05.061, 2019.
Chen, Y., Cao, J. J., Zhao, J., Xu, H. M., Arimoto, R., Wang, G. H., Han, Y.
M., Shen, Z. X., and Li, G. H.: n-Alkanes and polycyclic aromatic
hydrocarbons in total suspended particulates from the southeastern Tibetan
Plateau: concentrations, seasonal variations, and sources, Sci. Total
Environ., 470–471, 9–18, https://doi.org/10.1016/j.scitotenv.2013.09.033, 2014.
Chrysikou, L. P. and Samara, C. A.: Seasonal variation of the size distribution of urban particulate matter and associated organic pollutants
in the ambient air, Atmos. Environ., 43, 4557–4569, https://doi.org/10.1016/j.atmosenv.2009.06.033, 2009.
Daher, N., Saliba, N. A., Shihadeh, A. L., Jaafar, M., Baalbake, R., and Sioutas, C.: Chemical composition of size-resolved particulate matter at near-freeway and urban background sites in the greater Beirut area, Atmos. Environ., 80, 96–106, https://doi.org/10.1016/j.atmosenv.2013.08.004, 2013.
Duan, F. K., He, K. B., and Liu, X. D.: Characteristics and source
identification of fine particulate n-alkanes in Beijing, China, J. Environ.
Sci., 22, 998–1005, https://doi.org/10.1016/S1001-0742(09)60210-2, 2010.
Ficken, K. J., Li, B., Swain, D. L., and Eglinton, G.: An n-alkane proxy for
the sedimentary input of submerged/floating freshwater aquatic macrophytes,
Org. Geochem., 31, 745–749, https://doi.org/10.1016/S0146-6380(00)00081-4, 2000.
Fu, P. Q., Kawamura, K., Pavuluri, C. M., Swaminathan, T., and Chen, J.: Molecular characterization of urban organic aerosol in tropical India: contributions of primary emissions and secondary photooxidation, Atmos. Chem. Phys., 10, 2663–2689, https://doi.org/10.5194/acp-10-2663-2010, 2010.
Fujitani, Y., Saitoh, K., Fushimi, A., Takahashi, K., Hasegawa, S., Tanabe,
K., Kobayashi, S., Furuyama, A., Hirano, S., and Takami, A.: Effect of
isothermal dilution on emission factors of organic carbon and n-alkanes in
the particle and gas phases of diesel exhaust, Atmos. Environ., 59, 389–397,
https://doi.org/10.1016/j.atmosenv.2012.06.010, 2012.
Han, D., Fu, Q., Gao, S., Li, L., Ma, Y., Qiao, L., Xu, H., Liang, S., Cheng, P., Chen, X., Zhou, Y., Yu, J. Z., and Cheng, J.: Non-polar organic compounds in autumn and winter aerosols in a typical city of eastern China: size distribution and impact of gas–particle partitioning on PM2.5 source apportionment, Atmos. Chem. Phys., 18, 9375–9391, https://doi.org/10.5194/acp-18-9375-2018, 2018.
Huang, R. J., Zhang, Y. L., Bozzetti, C., Ho, K. F., Cao, J. J., Han, Y. M.,
Daellenbach, R. K., Slowik, J. G., Platt, S. M., Canonaco, F., Zotter, P.,
Wolf, R., Pieber, S. M., Bruns, E. A., Crippa, M., Ciarelli, G., Piazzalunga, A., Schwikowski, M., Abbaszade, G., Schnelle-Kreis, J., Zimmermann, R., An, Z. S., Szidat, S., Baltensperger, U., Haddad, I. E., and Prévôt, A. S. H.: High secondary aerosol contribution to particulate pollution during haze events in China, Nature, 514, 218–222, https://doi.org/10.1038/nature13774, 2014.
Kang, M. J., Fu, P. Q., Aggarwal, S. G., Kumar, S., Zhao, Y., Sun, Y. L., and
Wang, Z. F.: Size distributions of n-alkanes, fatty acids and fatty alcohols in springtime aerosols from New Delhi, India, Environ. Pollut., 219,
957–966, https://doi.org/10.1016/j.envpol.2016.09.077, 2016a.
Kang, M. J., Ren, L. J., Ren, H., Zhao, Y., Kawamura, K., Zhang, H. L., Wei,
L. F., Sun, Y. L., Wang, Z. F., and Fu, P. Q.: Primary biogenic and
anthropogenic sources of organic aerosols in Beijing, China: Insights from
saccharides and n-alkanes, Environ. Pollut., 243, 1579–1587, https://doi.org/10.1016/j.envpol.2018.09.118, 2016b.
Kang, M., Kim, K., Choi, N., Kim, Y. P., and Lee, J. Y.: Recent Occurrence
of PAHs and n-Alkanes in PM2.5 in Seoul, Korea and Characteristics of Their Sources and Toxicity, Int. J. Environ. Res. Pub. He., 17, 1397, https://doi.org/10.3390/ijerph17041397, 2020.
Kavouras, I. G, Koutrakis, P., Tsapakis, M., Lagoudaki, E., Stephanou, E. G.,
Baer, D. V., and Oyola, P.: Source apportionment of urban particulate
aliphatic and polynuclear aromatic hydrocarbons (PAHs) using multivariate
methods, Environ. Sci. Technol., 35, 2288–2294, https://doi.org/10.1021/es001540z,
2001.
Kawamura, K., Ishimura, Y., and Yamazaki, K.: Four years' observations of
terrestrial lipid class compounds in marine aerosols from the western North
Pacific, Global Biogeochem. Cy., 17, 1–19, https://doi.org/10.1029/2001GB001810,
2003.
Li, F. X., Gu, J. W., Xin, J. Y., Schnelle-Kreis, J., Wang, Y. S., Liu, Z.
R., Shen, R. R., Michalke, B., Abbaszade, G., and Zimmermann, R.: Characteristics of chemical profile, sources and PAH toxicity of PM2.5 in Beijing in autumn-winter transit season with regard to domestic heating,
pollution control measures and meteorology, Chemosphere, 276, 130143, https://doi.org/10.1016/j.chemosphere.2021.130143, 2021.
Li, W. F., Peng, Y., and Bai, Z. P.: Distributions and sources of n-alkanes
in PM2.5 at urban, industrial and coastal sites in Tianjin, China, J.
Environ. Sci., 22, 1551–1557, https://doi.org/10.1016/S1001-0742(09)60288-6, 2010.
Li, X. R., Wang, Y. S., Guo, X. Q., and Wang, Y. F.: Seasonal variation and
source apportionment of organic and inorganic compounds in PM2.5 and PM10 particulates in Beijing, China, J. Environ. Sci., 25, 741–750, https://doi.org/10.1016/S1001-0742(12)60121-1, 2013.
Li, Y. S., Cao, J. J., Li, J. J., Zhou, J. M., Xu, H. M., Zhang, R. J., and
Ouyang, Z. Y.: Molecular distribution and seasonal variation of hydrocarbons
in PM2.5 from Beijing during 2006, Particuology, 11, 78–85, https://doi.org/10.1016/j.partic.2012.09.002, 2013.
Liao, H. T., Lee, C. L., Tsai, W. C., Yu, J. Z., Tsai, S. W., Chou, C. C. K.,
and Wu, C. F.: Source apportionment of urban PM2.5 using positive matrix
factorization with vertically distributed measurements of trace elements and
nonpolar organic compounds, Atmos. Pollut. Res., 12, 200–207, https://doi.org/10.1016/j.apr.2021.03.007, 2021.
Liebezeit, G. and Wöstmann, R.: n-Alkanes as indicators of natural and anthropogenic organic matter sources in the Siak River and its Estuary, E Sumatra, Indonesia, B. Environ. Contam. Tox., 83, 403–409, https://doi.org/10.1007/s00128-009-9734-4, 2009.
Liu, L. Y., Wei, G. L., Wang, J. Z., Guan, Y. F., Wong, C. S., Wu, F. C., and
Zeng, E. Y.: Anthropogenic activities have contributed moderately to
increased inputs of organic materials in marginal seas off China, Environ.
Sci. Technol., 47, 11414–11422, https://doi.org/10.1021/es401751k, 2013.
Liu, X. D., Meng, J. J., Hou, Z. F., Yi, Y. N., Wei, B. J., and Fu, M. X.:
Pollution Characteristics and Source Analysis of n-alkanes and Saccharides
in PM2.5 During the Winter in Liaocheng City, Environ. Sci., 40, 548–557, https://doi.org/10.13227/j.hjkx.201807132, 2019 (in Chinese).
Lv, L. L., Chen, Y. J., Han, Y., Cui, M., Wei, P., Zheng, M., and Hu, J. N.:
High-time-resolution PM2.5 source apportionment based on multi-model with organic tracers in Beijing during haze episodes, Sci. Total Environ., 772, 144766, https://doi.org/10.1016/j.scitotenv.2020.144766, 2020.
Lyu, R. H., Shi, Z. B., Alam, M. S., Wu, X. F., Liu, D., Vu, T. V, Stark,
C., Xu, R. X., Fu, P. Q., Feng, Y. C., and Harrison, R. M: Alkanes and
aliphatic carbonyl compounds in wintertime PM2.5 in Beijing, China, Atmos. Environ., 202, 244–255, https://doi.org/10.1016/j.atmosenv.2019.01.023, 2019.
Lyu, Y., Xu, T. T., Yang, X., Chen, J. M., Cheng, T. T., and Li, X.:
Seasonal contributions to size-resolved n-alkanes (C8–C40) in the Shanghai atmosphere from regional anthropogenic activities and terrestrial plant waxes, Sci. Total Environ., 579, 1918–1928, https://doi.org/10.1016/j.scitotenv.2016.11.201, 2016.
Ma, J. Z., Xu, X. B., Zhao, C. S., and Yan, P.: A review of atmospheric
chemistry research in China: Photochemical smog, haze pollution, and
gas-aerosol interactions, Adv. Atmos. Sci., 29, 1006–1026, https://doi.org/10.1007/s00376-012-1188-7, 2012.
Marzi, R., Torkelson, B. E., and Olson, R. K.: A revised carbon preference
index, Org. Geochem., 20, 1303–1306, https://doi.org/10.1016/0146-6380(93)90016-5,
1993.
Michoud, V., Kukui, A., Camredon, M., Colomb, A., Borbon, A., Miet, K., Aumont, B., Beekmann, M., Durand-Jolibois, R., Perrier, S., Zapf, P., Siour, G., Ait-Helal, W., Locoge, N., Sauvage, S., Afif, C., Gros, V., Furger, M., Ancellet, G., and Doussin, J. F.: Radical budget analysis in a suburban European site during the MEGAPOLI summer field campaign, Atmos. Chem. Phys., 12, 11951–11974, https://doi.org/10.5194/acp-12-11951-2012, 2012.
Moeinaddini, M., Sari, A. E., Bakhtiari, A. R., Chan, A. Y. C., Taghavi, S.
M., Hawker, D., and Connell, D.: Source apportionment of PAHs and n-alkanes
in respirable particles in Tehran, Iran by wind sector and vertical profile,
Environ. Sci. Pollut. R., 21, 7757–7772, https://doi.org/10.1007/s11356-014-2694-1,
2014.
Niu, H. Y., Zhao, X., Dai, Z. X., Wang, G. H., and Wang, L. S.: Characterization, source apportionment of particulate matter and n-alkanes
in atmospheric aerosols in Nanjing City, Environ. Pollut. Control, 27, 363–366, https://doi.org/10.3969/j.issn.1001-3865.2005.05.014, 2005 (in Chinese).
Oros, D. R. and Simoneit, B. R. T.: Identification and emission rates of
molecular tracers in coal smoke particulate matter, Fuel, 79, 515–536, https://doi.org/10.1016/S0016-2361(99)00153-2, 2000.
Presto, A. A., Miracolo, M. A., Kroll, J. H., Worsnop, D. R., Robinson, A. L.,
and Donahue, N. M.: Intermediate-volatility organic compounds: a potential
source of ambient oxidized organic aerosol, Environ. Sci. Technol., 43,
4744–4749, https://doi.org/10.1021/es803219q, 2009.
Qi, M. X., Jiang, L., Liu, Y. X., Xiong, Q. L., Sun, C. Y., Li, X., Zhao, W.
J., and Yang, X. C.: Analysis of the Characteristics and Sources of
Carbonaceous Aerosols in PM2.5 in the Beijing, Tianjin, and Langfang Region, China, Int. J. Environ. Res. Pub. He., 15, 1438, https://doi.org/10.3390/ijerph15071483, 2018.
Ren, L. J., Fu, P. Q., He, Y., Hou, J. Z., Chen, J., Pavuluri, C. M., Sun,
Y. L., and Wang, Z. F.: Molecular distributions and compound-specific stable
carbon isotopic compositions of lipids in wintertime aerosols from Beijing,
Sci. Rep.-UK, 6, 27481, https://doi.org/10.1038/srep27481, 2016.
Ren, L. J., Hu, W., Hou, J. Z., Li, L. J., Yue, S. Y., Sun, Y. L., Wang, Z.
F., Li, X. F., Pavuluri, C. M., Hou, S. J., Liu, C. Q., Kawamura, K., Ellam,
R. M., and Fu, P. Q.: Compound-Specific Stable Carbon Isotope Ratios of
Terrestrial Biomarkers in Urban Aerosols from Beijing, China, ACS Earth
Space Chem., 3, 1896–1904, https://doi.org/10.1021/acsearthspacechem.9b00113, 2019.
Ren, Y. Q., Wang, G. H., Wu, C., Wang, J. Y., Li, J. J., Zhang, L., Han, Y.
N., Liu, L., Cao, C., Cao, J. J., He, Q., and Liu, X. C.: Changes in
concentration, composition and source contribution of atmospheric organic
aerosols by shifting coal to natural gas in Urumqi, Atmos. Environ., 148,
306–315, https://doi.org/10.1016/j.atmosenv.2016.10.053, 2017.
Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R., and Simoneit, B. R. T.: Sources of fine organic aerosol. 4. Particulate abrasion products from
leaf surfaces of urban plants, Environ. Sci. Technol., 27, 2700–2711, https://doi.org/10.1021/es00049a008, 1993.
Schauer, J. J., Kleeman, M. J., Cass, G. R., and Simoneit, B. R. T.: Measurement of Emissions from Air Pollution Sources. 2. C1 through C30 Organic Compounds from Medium Duty Diesel Trucks, Environ. Sci. Technol., 33, 1578–1587, https://doi.org/10.1021/es980081n, 1999.
Schauer, J. J., Kleeman, M. J., Cass, G. R., and Simoneit, B. R. T.: Measurement of Emissions from Air Pollution Sources. 5. C1–C32 Organic Compounds from gasoline-Powered Motor Vehicles, Environ. Sci. Technol., 36, 1169–1180, https://doi.org/10.1021/es0108077, 2002.
Simoneit, B. R. T.: Application of Molecular Marker Analysis to Vehicular
Exhaust for Source Reconciliations, Int. J. Environ. An. Ch., 22, 203–232, https://doi.org/10.1080/03067318508076422, 1985.
Simoneit, B. R. T.: Organic matter of the troposphere – V: Application of
molecular marker analysis to biogenic emissions into the troposphere for
source reconciliations, J. Atmos. Chem., 8, 251–275, https://doi.org/10.1007/BF00051497, 1989.
Simoneit, B. R. T., Kobayashi, M., Mochida, M., Kawamura, K., and Huebert, B.
J.: Aerosol particles collected on aircraft flights over the northwestern
Pacific region during the ACE-Asia campaign: composition and major sources
of the organic compounds, J. Geophys. Res., 109, D19S09, https://doi.org/10.1029/2004JD004565, 2004.
Sun, N., Li, X. D., Ji, Y., Huang, H. Y., Ye, Z. L., and Zhao, Z. Z.:
Sources of PM2.5-Associated PAHs and n-alkanes in Changzhou China,
Atmosphere, 12, 1127, https://doi.org/10.3390/atmos12091127, 2021.
Tang, G., Zhang, J., Zhu, X., Song, T., Münkel, C., Hu, B., Schäfer, K., Liu, Z., Zhang, J., Wang, L., Xin, J., Suppan, P., and Wang, Y.: Mixing layer height and its implications for air pollution over Beijing, China, Atmos. Chem. Phys., 16, 2459–2475, https://doi.org/10.5194/acp-16-2459-2016, 2016.
United States Environmental Protection Agency: EPA Positive Matrix Factorization (PMF) 5.0 Fundamentals and User Guide, EPA/600/R-14/108, https://www.epa.gov/, last access: 25/7/2022, 2014.
Wagner, P. and Schäfer, K.: Influence of mixing layer height on air
pollutant concentrations in an urban street canyon, Urban Climate, 22, 64–79, https://doi.org/10.1016/j.uclim.2015.11.001, 2017.
Wang, F. W., Guo, Z. G., Lin, T., and Rose, N. L.: Seasonal variation of
carbonaceous pollutants in PM2.5 at an urban 'supersite' in Shanghai, China, Chemosphere, 146, 238–244, https://doi.org/10.1016/j.chemosphere.2015.12.036, 2016.
Wang, G. H. and Kawamura, K.: Molecular characteristics of urban organic
aerosols from Nanjing: a case study of a mega-city in China, Environ. Sci.
Technol., 39, 7430–7438, https://doi.org/10.1021/es051055+, 2005.
Wang, G. H., Huang, L. M., Zhao, X., Niu, H. Y., and Dai, Z. X.: Aliphatic
and polycyclic aromatic hydrocarbons of atmospheric aerosols in five
locations of Nanjing urban area, China, Atmos. Res., 81, 54–66, https://doi.org/10.1016/j.atmosres.2005.11.004, 2006a.
Wang, G. H., Kawamura, K., Lee, S. C., Ho, K. F., and Cao, J. J.: Molecular,
Seasonal, and Spatial Distributions of Organic Aerosols from Fourteen
Chinese Cities, Environ. Sci. Technol., 40, 4619–4625, https://doi.org/10.1021/es060291x, 2006b.
Wang, G. H., Zhang, R. Y., Gomez, M. E., Yang, L. X., Zamora, M. L., Hu, M.,
Lin, Y., Peng, J. F., Guo, S., Meng, J. J., Li, J. J., Chen, C. L., Hu, T.
F., Ren, Y. Q., Wang, Y. S., Gao, J., Cao, J. J., An, Z. S., Zhou, W. J.,
Li, G. H., Wang, J. Y., Tian, P. F., Marrero-Ortiz, W., Secrest, J., Du, Z.
F., Zheng, J., Shang, D. J., Zheng, L. M., Shao, M., Wang, W. G., Huang, Y.,
Wang, Y., Zhu, Y. J., Li, Y. X., Hu, J. X., Pan, B. W., Cai, L., Cheng, Y. T., Ji, Y. M., Zhang, F., Rosenfeld, D., Liss, P. S., Duce, R. A., Kolb, C. E., and Molina, M. J.: Persistent sulfate formation from London Fog to China
haze, P. Natl. Acad. Sci. USA, 113, 13630–13635, https://doi.org/10.1073/pnas.1616540113, 2016.
Wang, H., Li, Z., Lv, Y., Zhang, Y., Xu, H., Guo, J., and Goloub, P.: Determination and climatology of the diurnal cycle of the atmospheric mixing layer height over Beijing 2013–2018: lidar measurements and implications for air pollution, Atmos. Chem. Phys., 20, 8839–8854, https://doi.org/10.5194/acp-20-8839-2020, 2020.
Wang, J. Z., Ho, S. S. H., Ma, S. X., Cao, J. J., Dai, W. T., Liu, S. X.,
Shen, Z. X., Huang, R. J., Wang, G. H., and Han, Y. M.: Characterization of PM2.5 in Guangzhou, China: uses of organic markers for supporting source apportionment, Sci. Total Environ., 550, 961–971, https://doi.org/10.1016/j.scitotenv.2016.01.138, 2016.
Wang, Q., Jiang, N., Yin, S. S., Li, X., Yu, F., Guo, Y., and Zhang, R. Q.:
Carbonaceous species in PM2.5 and PM10 in urban area of Zhengzhou in China: Seasonal variations and source apportionment, Atmos. Res., 191, 1–11, https://doi.org/10.1016/j.atmosres.2017.02.003, 2017.
Wei, M., Li, M. Y., Xu, C. H., Xu, P. J., and Liu, H. F.: Pollution
characteristics of bioaerosols in PM2.5 during the winter heating season in a coastal city of northern China, Environ. Sci. Pollut. R., 27,
27750–27761, https://doi.org/10.1007/s11356-020-09070-y, 2020.
Wick, C. D., Siepmann, J., Klotz, W. L., and Schure, M. R.: Temperature
effects on the retention of n-alkanes and arenes in helium–squalane
gas–liquid chromatography: experiment and molecular simulation, J.
Chromatogr. A, 957, 181–190, https://doi.org/10.1016/S0021-9673(02)00171-1, 2002.
Xu, H. M., Tao, J., Ho, S. S. H., Ho, K. F., Cao, J. J., Li, N., Chow, J.
C., Wang, G. H., Han, Y. M., and Zhang, R. J.: Characteristics of fine
particulate non-polar organic compounds in Guangzhou during the 16th Asian
Games: Effectiveness of air pollution controls, Atmos. Environ., 76, 94–101,
https://doi.org/10.1016/j.atmosenv.2012.12.037, 2013.
Xu, T. T., Lv, Y., Cheng, T. T., and Li, X.: Using comprehensive
GC×GC to study PAHs and n-alkanes associated with PM2.5 in urban atmosphere, Environ. Sci. Pollut. R., 22, 5253–5262, https://doi.org/10.1007/s11356-014-3695-9, 2015.
Yadav, S., Tandon, A., and Attri, A.: Monthly and seasonal variation in
aerosol associated n-alkane profiles in relation to meteorological
parameters in New Delhi, India, Aerosol Air Qual. Res., 13, 287–300, https://doi.org/10.4209/aaqr.2012.01.0004, 2013.
Yang, X. H., Luo, F. X., Li, J. Q., Chen. D. Y., Ye, E., Lin, W. L., and Jin,
J.: Alkyl and aromatic nitrates in atmospheric particles determined by gas
chromatography tandem mass spectrometry, J. Am. Soc. Mass Spectr., 30, 2762–2770, https://doi.org/10.1007/s13361-019-02347-8, 2019.
Yao, L., Li, X. R., Guo, X. Q., Liu, X. R., and Wang, Y. S.: Pollution
Characteristics of n-alkanes in Atmospheric Fine Particles During Spring
Festival of 2007 in Beijing, Environ. Sci., 30, 589–593, https://doi.org/10.13227/j.hjkx.2009.02.042, 2009 (in Chinese).
Yuan, J. W., Liu, G., Li, J. H., and Xu, H.: Chemical Composition of Alkanes
and Organic Acids in Vehicle Exhaust, Environ. Sci., 37, 2052–2058, https://doi.org/10.13227/j.hjkx.2016.06.007, 2016 (in Chinese).
Zhao, Y., Zhang, Y., Fu, P., Ho, S. S., Ho, K. F., Liu, F., Zou, S., Wang,
S., and Lai, S.: Non-polar organic compounds in marine aerosols over the
northern South China Sea: Influence of continental outflow, Chemosphere, 153, 332–339, https://doi.org/10.1016/j.chemosphere.2016.03.069, 2016.
Zhang, R. Y., Wang, G. H., Guo, S., Zamora, M. L., Ying, Q., Lin, Y., Wang,
W. G., Hu, M., and Wang, Y.: Formation of urban fine particulate matter,
Chem. Rev., 115, 3803–3855, https://doi.org/10.1021/acs.chemrev.5b00067, 2015.
Zhu, X. L., Zhang, Y. H., Zeng, L. M., and Wang, W.: Source Identification
of Ambient PM2.5 in Beijing, Res. Environ. Sci., 18, 1–5, https://doi.org/10.3321/j.issn:1001-6929.2005.05.001, 2005 (in Chinese).
Short summary
The characteristics of n-alkanes and the contributions of various sources of PM2.5 in the atmosphere in Beijing were studied. There were marked seasonal and diurnal differences in the n-alkane concentrations (p<0.01). Particulate-bound n-alkanes were supplied by anthropogenic and biogenic sources; fossil fuel combustion was the dominant contributor. Vehicle exhausts strongly affect PM2.5 pollution. Controlling vehicle exhaust emissions is key to control n-alkane and PM2.5 pollution in Beijing.
The characteristics of n-alkanes and the contributions of various sources of PM2.5 in the...
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