Articles | Volume 23, issue 18
https://doi.org/10.5194/acp-23-10413-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-10413-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Sep 2023
Research article |
| 20 Sep 2023
| 20 Sep 2023
Inferring the photolysis rate of NO2 in the stratosphere based on satellite observations
Department of Earth, Atmospheric, and Planetary Sciences, MIT,
Cambridge, MA 02139, USA
Susan Solomon
Department of Earth, Atmospheric, and Planetary Sciences, MIT,
Cambridge, MA 02139, USA
Sasha Madronich
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
USDA UV-B Monitoring and Research Program, Natural Resource Ecology
Laboratory, Colorado State University, Fort Collins, CO 80523, USA
Douglas Kinnison
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
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Yuanhong Zhao, Marielle Saunois, Philippe Bousquet, Xin Lin, Antoine Berchet, Michaela I. Hegglin, Josep G. Canadell, Robert B. Jackson, Makoto Deushi, Patrick Jöckel, Douglas Kinnison, Ole Kirner, Sarah Strode, Simone Tilmes, Edward J. Dlugokencky, and Bo Zheng
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Daniele Minganti, Simon Chabrillat, Yves Christophe, Quentin Errera, Marta Abalos, Maxime Prignon, Douglas E. Kinnison, and Emmanuel Mahieu
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The climatology of the N2O transport budget in the stratosphere is studied in the transformed Eulerian mean framework across a variety of datasets: a chemistry climate model, a chemistry transport model driven by four reanalyses and a chemical reanalysis. The impact of vertical advection on N2O agrees well in the datasets, but horizontal mixing presents large differences above the Antarctic and in the whole Northern Hemisphere.
Cited articles
Anderson, G., Gille, J., Bailey, P., and Solomon, S.: LRIR observations of diurnal ozone variation in the mesosphere, in: Proceedings Quadrennial International Ozone Symposium, Boulder, CO, USA, 4–9 August 1980, 580–585, 1981.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reactions of OX, HOX, NOX and SOX species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Bösch, H., Camy-Peyret, C., Chipperfield, M., Fitzenberger, R., Harder,
H., Schiller, C., Schneider, M., Trautmann, T., and Pfeilsticker, K.:
Comparison of measured and modeled stratospheric UV/Visible actinic fluxes
at large solar zenith angles, Geophys. Res. Lett., 28, 1179–1182,
https://doi.org/10.1029/2000GL012134, 2001.
Brandt, R. E., Warren, S. G., Worby, A. P., and Grenfell, T. C.: Surface
Albedo of the Antarctic Sea Ice Zone, J. Climate, 18, 3606–3622,
https://doi.org/10.1175/JCLI3489.1, 2005.
Burkholder, J. B., Sander, S. P., Abbatt, J. P. D., Barker, J. R., Huie, R.
E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., and Wine, P.
H.: Chemical kinetics and photochemical data for use in atmospheric studies:
evaluation number 18, Jet Propulsion Laboratory, National Aeronautics and Space Administration, Pasadena, CA, https://jpldataeval.jpl.nasa.gov/pdf/JPL_Publication_15-10.pdf (last access: 12 September 2023), 2015.
Crutzen, P. J.: The influence of nitrogen oxides on the atmospheric ozone
content, Q. J. Roy. Meteor. Soc., 96, 320–325, https://doi.org/10.1002/qj.49709640815, 1970.
Crutzen, P. J.: The Role of NO and NO2 in the Chemistry of the Troposphere
and Stratosphere, Annu. Rev. Earth Pl. Sc., 7, 443–472,
https://doi.org/10.1146/annurev.ea.07.050179.002303, 1979.
Danabasoglu, G., Lamarque, J. -F., Bacmeister, J., Bailey, D. A., DuVivier,
A. K., Edwards, J., Emmons, L. K., Fasullo, J., Garcia, R., Gettelman, A.,
Hannay, C., Holland, M. M., Large, W. G., Lauritzen, P. H., Lawrence, D. M.,
Lenaerts, J. T. M., Lindsay, K., Lipscomb, W. H., Mills, M. J., Neale, R.,
Oleson, K. W., Otto-Bliesner, B., Phillips, A. S., Sacks, W., Tilmes, S.,
Kampenhout, L., Vertenstein, M., Bertini, A., Dennis, J., Deser, C.,
Fischer, C., Fox-Kemper, B., Kay, J. E., Kinnison, D., Kushner, P. J.,
Larson, V. E., Long, M. C., Mickelson, S., Moore, J. K., Nienhouse, E.,
Polvani, L., Rasch, P. J., and Strand, W. G.: The Community Earth System
Model Version 2 (CESM2), J. Adv. Model. Earth Sy., 12, e2019MS001916,
https://doi.org/10.1029/2019MS001916, 2020.
Del Negro, L. A., Fahey, D. W., Gao, R. S., Donnelly, S. G., Keim, E. R.,
Neuman, J. A., Cohen, R. C., Perkins, K. K., Koch, L. C., Salawitch, R. J.,
Lloyd, S. A., Proffitt, M. H., Margitan, J. J., Stimpfle, R. M., Bonne, G.
P., Voss, P. B., Wennberg, P. O., McElroy, C. T., Swartz, W. H., Kusterer,
T. L., Anderson, D. E., Lait, L. R., and Bui, T. P.: Comparison of modeled
and observed values of NO2 and JNO2 during the Photochemistry of Ozone Loss in the Arctic Region in Summer (POLARIS) mission, J. Geophys. Res., 104,
26687–26703, https://doi.org/10.1029/1999JD900246, 1999.
Fabian, P., Pyle, J. A., and Wells, R. J.: Diurnal variations of minor
constituents in the stratosphere modeled as a function of latitude and
season, J. Geophys. Res., 87, 4981, https://doi.org/10.1029/JC087iC07p04981, 1982.
Fischer, H., Birk, M., Blom, C., Carli, B., Carlotti, M., von Clarmann, T., Delbouille, L., Dudhia, A., Ehhalt, D., Endemann, M., Flaud, J. M., Gessner, R., Kleinert, A., Koopman, R., Langen, J., López-Puertas, M., Mosner, P., Nett, H., Oelhaf, H., Perron, G., Remedios, J., Ridolfi, M., Stiller, G., and Zander, R.: MIPAS: an instrument for atmospheric and climate research, Atmos. Chem. Phys., 8, 2151–2188, https://doi.org/10.5194/acp-8-2151-2008, 2008.
Funke, B., López-Puertas, M., von Clarmann, T., Stiller, G. P., Fischer,
H., Glatthor, N., Grabowski, U., Höpfner, M., Kellmann, S., Kiefer, M.,
Linden, A., Mengistu Tsidu, G., Milz, M., Steck, T., and Wang, D. Y.:
Retrieval of stratospheric NOx from 5.3 and 6.2 µm nonlocal thermodynamic equilibrium emissions measured by Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on Envisat, J. Geophys. Res.-Atmos., 110, D09302, https://doi.org/10.1029/2004JD005225, 2005.
Funke, B., García-Comas, M., Glatthor, N., Grabowski, U., Kellmann, S., Kiefer, M., Linden, A., López-Puertas, M., Stiller, G. P., and von Clarmann, T.: Michelson Interferometer for Passive Atmospheric Sounding Institute of Meteorology and Climate Research/Instituto de Astrofísica de Andalucía version 8 retrieval of nitric oxide and lower-thermospheric temperature, Atmos. Meas. Tech., 16, 2167–2196, https://doi.org/10.5194/amt-16-2167-2023, 2023.
Gelaro, R., McCarty, W., Suárez, M. J., Todling, R., Molod, A., Takacs,
L., Randles, C. A., Darmenov, A., Bosilovich, M. G., Reichle, R., Wargan,
K., Coy, L., Cullather, R., Draper, C., Akella, S., Buchard, V., Conaty, A.,
da Silva, A. M., Gu, W., Kim, G.-K., Koster, R., Lucchesi, R., Merkova, D.,
Nielsen, J. E., Partyka, G., Pawson, S., Putman, W., Rienecker, M.,
Schubert, S. D., Sienkiewicz, M., and Zhao, B.: The Modern-Era Retrospective
Analysis for Research and Applications, Version 2 (MERRA-2), J. Climate, 30,
5419–5454, https://doi.org/10.1175/JCLI-D-16-0758.1, 2017.
Gettelman, A., Mills, M. J., Kinnison, D. E., Garcia, R. R., Smith, A. K.,
Marsh, D. R., Tilmes, S., Vitt, F., Bardeen, C. G., McInerny, J., Liu, H.-L., Solomon, S. C., Polvani, L. M., Emmons, L. K., Lamarque, J.-F., Richter, J. H., Glanville, A. S., Bacmeister, J. T., Phillips, A. S., Neale, R. B., Simpson, I. R., DuVivier, A. K., Hodzic, A., and Randel, W. J.: The Whole Atmosphere Community Climate Model Version 6 (WACCM6), J. Geophys. Res.-Atmos., 124, 12380–12403, https://doi.org/10.1029/2019JD030943, 2019.
Guan, J., Solomon, S., Madronich, S., and Kinnison, D.: Inferring the Photolysis Rate of NO2 in the Stratosphere Based on Satellite Observations, Zenodo [code/data set], https://doi.org/10.5281/zenodo.7764756, 2023.
Johnston, H.: Reduction of Stratospheric Ozone by Nitrogen Oxide Catalysts
from Supersonic Transport Exhaust, Science, 173, 517–522,
https://doi.org/10.1126/science.173.3996.517, 1971.
Johnston, H. S. and Podolske, J.: Interpretations of stratospheric
photochemistry, Rev. Geophys., 16, 491–519, https://doi.org/10.1029/RG016i004p00491, 1978.
Junkermann, W., Platt, U., and Volz-Thomas, A.: A photoelectric detector for
the measurement of photolysis frequencies of ozone and other atmospheric
molecules, J. Atmos. Chem., 8, 203–227, https://doi.org/10.1007/BF00051494, 1989.
Kawa, S. R., Fahey, D. W., Solomon, S., Brune, W. H., Proffitt, M. H.,
Toohey, D. W., Anderson, D. E., Anderson, L. C., and Chan, K. R.:
Interpretation of aircraft measurements of NO, ClO, and O3 in the lower
stratosphere, J. Geophys. Res., 95, 18597, https://doi.org/10.1029/JD095iD11p18597, 1990.
Kiefer, M., von Clarmann, T., Funke, B., García-Comas, M., Glatthor, N., Grabowski, U., Kellmann, S., Kleinert, A., Laeng, A., Linden, A., López-Puertas, M., Marsh, D. R., and Stiller, G. P.: IMK/IAA MIPAS temperature retrieval version 8: nominal measurements, Atmos. Meas. Tech., 14, 4111–4138, https://doi.org/10.5194/amt-14-4111-2021, 2021.
Kiefer, M., von Clarmann, T., Funke, B., García-Comas, M., Glatthor, N., Grabowski, U., Höpfner, M., Kellmann, S., Laeng, A., Linden, A., López-Puertas, M., and Stiller, G. P.: Version 8 IMK–IAA MIPAS ozone profiles: nominal observation mode, Atmos. Meas. Tech., 16, 1443–1460, https://doi.org/10.5194/amt-16-1443-2023, 2023.
Kinnison, D. E., Brasseur, G. P., Walters, S., Garcia, R. R., Marsh, D. R.,
Sassi, F., Harvey, V. L., Randall, C. E., Emmons, L., Lamarque, J. F., Hess,
P., Orlando, J. J., Tie, X. X., Randel, W., Pan, L. L., Gettelman, A.,
Granier, C., Diehl, T., Niemeier, U., and Simmons, A. J.: Sensitivity of
chemical tracers to meteorological parameters in the MOZART-3 chemical
transport model, J. Geophys. Res., 112, D20302,
https://doi.org/10.1029/2006JD007879, 2007.
Laepple, T., Schultz, M. G., Lamarque, J. F., Madronich, S., Shetter, R. E.,
Lefer, B. L., and Atlas, E.: Improved albedo formulation for chemistry
transport models based on satellite observations and assimilated snow data
and its impact on tropospheric photochemistry, J. Geophys. Res., 110,
D11308, https://doi.org/10.1029/2004JD005463, 2005.
Madronich, S.: Photodissociation in the atmosphere: 1. Actinic flux and the
effects of ground reflections and clouds, J. Geophys. Res., 92, 9740,
https://doi.org/10.1029/JD092iD08p09740, 1987.
Madronich, S. and Weller, G.: Numerical integration errors in calculated
tropospheric photodissociation rate coefficients, J. Atmos. Chem., 10,
289–300, https://doi.org/10.1007/BF00053864, 1990.
Madronich, S., Hastie, D. R., Ridley, B. A., and Schiff, H. I.: Measurement
of the photodissociation coefficient of NO2 in the atmosphere: I. Method and surface measurements, J. Atmos. Chem., 1, 3–25,
https://doi.org/10.1007/BF00113977, 1983.
Madronich, S., Hastie, D. R., Schiff, H. I., and Ridley, B. A.: Measurement
of the photodissociation coefficient of NO2 in the atmosphere: II,
stratospheric measurements, J. Atmos. Chem., 3, 233–245,
https://doi.org/10.1007/BF00210498, 1985.
Pommereau, J. P.: Observation of NO2 diurnal variation in the stratosphere, Geophys. Res. Lett., 9, 850–853, https://doi.org/10.1029/GL009i008p00850, 1982.
Roscoe, H. K., Kerridge, B. J., Gray, L. J., Wells, R. J., and Pyle, J. A.:
Simultaneous measurements of stratospheric NO and NO2 and their comparison
with model predictions, J. Geophys. Res., 91, 5405, https://doi.org/10.1029/JD091iD05p05405, 1986.
Sagawa, H., Sato, T. O., Baron, P., Dupuy, E., Livesey, N., Urban, J., von Clarmann, T., de Lange, A., Wetzel, G., Connor, B. J., Kagawa, A., Murtagh, D., and Kasai, Y.: Comparison of SMILES ClO profiles with satellite, balloon-borne and ground-based measurements, Atmos. Meas. Tech., 6, 3325–3347, https://doi.org/10.5194/amt-6-3325-2013, 2013.
Shao, Z.-D. and Ke, C.-Q.: Spring–summer albedo variations of Antarctic sea
ice from 1982 to 2009, Environ. Res. Lett., 10, 064001,
https://doi.org/10.1088/1748-9326/10/6/064001, 2015.
Shetter, R. E., McDaniel, A. H., Cantrell, C. A., Madronich, S., and
Calvert, J. G.: Actinometer and Eppley radiometer measurements of the NO2
photolysis rate coefficient during the Mauna Loa Observatory photochemistry
experiment, J. Geophys. Res., 97, 10349, https://doi.org/10.1029/91JD02289, 1992.
Shetter, R. E, Junkermann, W., Swartz, W., Frost, G., Crawford, J., Lefer, B., Barrick, J., Hall, S., Hofzumahaus, A., Bais, A., Calvert, J. G., Cantrell, C. A., Madronich, S., muller, M., Kraus, A., Monks, P. S., Edwards, G. D., McKenzie, R., Johnston, P., Schmitt, R., Griffioen, E., Krol, M., Kylling, A., Dickerson, R. R., Lloyd, S. A., Martin, T., Gardiner, B., Mayer, B., Pfister, E., Roth, E. P., keopke, P., Ruggaber, A., Schwander, H., and van Weele, M.: Photolysis frequency of NO2: measurement and modeling during the International Photolysis Frequency Measurement and Modeling Intercomparison (IPMMI), J. Geophys. Res.-Atmos., 108, 8544, https://doi.org/10.1029/2002JD002932, 2003.
Solomon, S., Russell, J. M., and Gordley, L. L.: Observations of the diurnal
variation of nitrogen dioxide in the stratosphere, J. Geophys. Res., 91,
5455, https://doi.org/10.1029/JD091iD05p05455, 1986.
von Clarmann, T., Höpfner, M., Kellmann, S., Linden, A., Chauhan, S., Funke, B., Grabowski, U., Glatthor, N., Kiefer, M., Schieferdecker, T., Stiller, G. P., and Versick, S.: Retrieval of temperature, H2O, O3, HNO3, CH4, N2O, ClONO2 and ClO from MIPAS reduced resolution nominal mode limb emission measurements, Atmos. Meas. Tech., 2, 159–175, https://doi.org/10.5194/amt-2-159-2009,
2009.
Walker, H. L., Heal, M. R., Braban, C. F., Leeson, S. R., Simmons, I., Jones, M. R., Kift, R., Marsden, N., and Twigg, M. M.: The Importance of Capturing Local Measurement-Driven Adjustment of Modelled j(NO2), Atmosphere, 13, 1065, https://doi.org/10.3390/atmos13071065, 2022.
Webster, C. R. and May, R. D.: Simultaneous in situ measurements and diurnal
variations of NO, NO2, O3, jNO2, CH4, H2O, and CO2 in the 40- to 26-km region using an open path tunable diode laser spectrometer, J. Geophys. Res., 92, 11931, https://doi.org/10.1029/JD092iD10p11931, 1987.
Short summary
This paper provides a novel method to obtain a global and accurate photodissociation coefficient for NO2 (J(NO2)) based on satellite data, and the results are shown to be consistent with model results. The J(NO2) value decreases as the solar zenith angle increases and has a weak altitude dependence. A key finding is that the satellite-derived J(NO2) increases in the polar regions, in good agreement with model predictions, due to the effects of ice and snow on surface albedo.
This paper provides a novel method to obtain a global and accurate photodissociation coefficient...
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