Articles | Volume 22, issue 2
https://doi.org/10.5194/acp-22-973-2022
https://doi.org/10.5194/acp-22-973-2022
Research article
 | 
21 Jan 2022
Research article |  | 21 Jan 2022

Extension of the AIOMFAC model by iodine and carbonate species: applications for aerosol acidity and cloud droplet activation

Hang Yin, Jing Dou, Liviana Klein, Ulrich K. Krieger, Alison Bain, Brandon J. Wallace, Thomas C. Preston, and Andreas Zuend

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Cited articles

Abel, E., Redlich, O., and Hersch, F.: Freezing-point measurements. III Activity coefficients and dissociation of iodic acid, Z. Phys. Chem. A, 170A, 112–122, https://doi.org/10.1515/zpch-1934-17010, 1934. a
Abrams, D. S. and Prausnitz, J. M.: Statistical thermodynamics of liquid mixtures: A new expression for the excess Gibbs energy of partly or completely miscible systems, AIChE J., 21, 116–128, https://doi.org/10.1002/aic.690210115, 1975. a
Al-Sahhaf, T. A. and Jabbar, N. J.: Vapor-liquid equilibrium of the acetone-water-salt system, J. Chem. Eng. Data, 38, 522–526, https://doi.org/10.1021/je00012a010, 1993. a, b, c
Al-Sahhaf, T. A. and Kapetanovic, E.: Salt Effects of Lithium Chloride, Sodium Bromide, or Potassium Iodide on Liquid-Liquid Equilibrium in the System Water + 1-Butanol, J. Chem. Eng. Data, 42, 74–77, https://doi.org/10.1021/je960234r, 1997. a, b
Al-Sahhaf, T. A., Kapetanovic, E., and Kadhem, Q.: Salt effects on liquid-liquid equilibria in the partially miscible systems water + 2-butanone and water + ethyl acetate, Fluid Phase Equilibr., 157, 271–283, https://doi.org/10.1016/S0378-3812(99)00040-0, 1999. a, b, c
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Short summary
Iodine and carbonate species are important components in marine and dust aerosols, respectively. We introduce an extended version of the AIOMFAC thermodynamic mixing model, which includes the ions I, IO3, HCO3, CO32−, OH, and CO2(aq) as new species, and we discuss two methods for solving the carbonate dissociation equilibria numerically. We also present new experimental water activity data for aqueous iodide and iodate systems.
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