Articles | Volume 22, issue 2
https://doi.org/10.5194/acp-22-973-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-973-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Extension of the AIOMFAC model by iodine and carbonate species: applications for aerosol acidity and cloud droplet activation
Department of Atmospheric and Oceanic Sciences, McGill University, Montréal, Quebec, Canada
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
Liviana Klein
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
Ulrich K. Krieger
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
Alison Bain
Department of Chemistry, McGill University, Montréal, Quebec, Canada
Brandon J. Wallace
Department of Chemistry, McGill University, Montréal, Quebec, Canada
Thomas C. Preston
Department of Atmospheric and Oceanic Sciences, McGill University, Montréal, Quebec, Canada
Department of Chemistry, McGill University, Montréal, Quebec, Canada
Department of Atmospheric and Oceanic Sciences, McGill University, Montréal, Quebec, Canada
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10 citations as recorded by crossref.
- Mixed Solvent Electrolyte Solutions: A Review and Calculations with the eSAFT-VR Mie Equation of State N. Novak et al. 10.1021/acs.iecr.3c00717
- Impact of pH on Gas-Particle Partitioning of Semi-Volatile Organics in Multicomponent Aerosol B. Wallace et al. 10.1021/acs.est.3c02894
- Role of WSOCs and pH on Ammonium Nitrate Aerosol Efflorescence: Insights into Secondary Aerosol Formation J. Sun et al. 10.1021/acs.est.3c07603
- A thermodynamic framework for bulk–surface partitioning in finite-volume mixed organic–inorganic aerosol particles and cloud droplets R. Schmedding & A. Zuend 10.5194/acp-23-7741-2023
- Depletion of iodide in ageing aerosols and the role of humidity: A case study of mixed sodium iodide-malonic acid aerosol S. Saha & M. Pandiyathuray 10.1016/j.chemosphere.2024.143411
- Experimental phase diagram and its temporal evolution for submicron 2-methylglutaric acid and ammonium sulfate aerosol particles Q. Huang et al. 10.1039/D3CP04411D
- A predictive viscosity model for aqueous electrolytes and mixed organic–inorganic aerosol phases J. Lilek & A. Zuend 10.5194/acp-22-3203-2022
- Phase Transitions in Organic and Organic/Inorganic Aerosol Particles M. Freedman et al. 10.1146/annurev-physchem-083122-115909
- Capturing the Relative‐Humidity‐Sensitive Gas–Particle Partitioning of Organic Aerosols in a 2D Volatility Basis Set C. Serrano Damha et al. 10.1029/2023GL106095
- Role of Carbon Dioxide, Ammonia, and Organic Acids in Buffering Atmospheric Acidity: The Distinct Contribution in Clouds and Aerosols G. Zheng et al. 10.1021/acs.est.2c09851
10 citations as recorded by crossref.
- Mixed Solvent Electrolyte Solutions: A Review and Calculations with the eSAFT-VR Mie Equation of State N. Novak et al. 10.1021/acs.iecr.3c00717
- Impact of pH on Gas-Particle Partitioning of Semi-Volatile Organics in Multicomponent Aerosol B. Wallace et al. 10.1021/acs.est.3c02894
- Role of WSOCs and pH on Ammonium Nitrate Aerosol Efflorescence: Insights into Secondary Aerosol Formation J. Sun et al. 10.1021/acs.est.3c07603
- A thermodynamic framework for bulk–surface partitioning in finite-volume mixed organic–inorganic aerosol particles and cloud droplets R. Schmedding & A. Zuend 10.5194/acp-23-7741-2023
- Depletion of iodide in ageing aerosols and the role of humidity: A case study of mixed sodium iodide-malonic acid aerosol S. Saha & M. Pandiyathuray 10.1016/j.chemosphere.2024.143411
- Experimental phase diagram and its temporal evolution for submicron 2-methylglutaric acid and ammonium sulfate aerosol particles Q. Huang et al. 10.1039/D3CP04411D
- A predictive viscosity model for aqueous electrolytes and mixed organic–inorganic aerosol phases J. Lilek & A. Zuend 10.5194/acp-22-3203-2022
- Phase Transitions in Organic and Organic/Inorganic Aerosol Particles M. Freedman et al. 10.1146/annurev-physchem-083122-115909
- Capturing the Relative‐Humidity‐Sensitive Gas–Particle Partitioning of Organic Aerosols in a 2D Volatility Basis Set C. Serrano Damha et al. 10.1029/2023GL106095
- Role of Carbon Dioxide, Ammonia, and Organic Acids in Buffering Atmospheric Acidity: The Distinct Contribution in Clouds and Aerosols G. Zheng et al. 10.1021/acs.est.2c09851
Latest update: 23 Nov 2024
Short summary
Iodine and carbonate species are important components in marine and dust aerosols, respectively. We introduce an extended version of the AIOMFAC thermodynamic mixing model, which includes the ions I−, IO3−, HCO3−, CO32−, OH−, and CO2(aq) as new species, and we discuss two methods for solving the carbonate dissociation equilibria numerically. We also present new experimental water activity data for aqueous iodide and iodate systems.
Iodine and carbonate species are important components in marine and dust aerosols, respectively....
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