Articles | Volume 22, issue 20
https://doi.org/10.5194/acp-22-13845-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-13845-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Measurement report: Investigation of pH- and particle-size-dependent chemical and optical properties of water-soluble organic carbon: implications for its sources and aging processes
Yuanyuan Qin
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
Juanjuan Qin
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences,
Guangzhou, 510640, China
Xiaobo Wang
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
Kang Xiao
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
Ting Qi
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
School of Chemical Sciences, University of Chinese Academy of
Sciences, Beijing, 100049, China
Yuwei Gao
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
Xueming Zhou
Faculty of Earth Resources, China University of Geosciences, Wuhan,
430074, China
Shaoxuan Shi
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
Jingnan Li
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
Jingsi Gao
School of Materials and Environmental Engineering, Shenzhen
Polytechnic, Shenzhen, 518055, China
Ziyin Zhang
Institute of Urban Meteorology, China Meteorological
Administration, Beijing, 100089, China
Jihua Tan
CORRESPONDING AUTHOR
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
Rongzhi Chen
College of Resources and Environment, University of Chinese Academy
of Sciences, Beijing, 100049, China
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Cited articles
Aiona, P. K., Luek, J. L., Timko, S. A., Powers, L. C., Gonsior, M., and
Nizkorodov, S. A.: Effect of photolysis on absorption and fluorescence
spectra of light-absorbing secondary organic aerosols, ACS Earth. Space.
Chem., 2, 235–245, https://doi.org/10.1021/acsearthspacechem.7b00153, 2018.
Ault, A. P.: Aerosol acidity: Novel measurements and implications for
atmospheric chemistry, Acc. Chem. Res., 53, 1703–1714,
https://doi.org/10.1021/acs.accounts.0c00303, 2020.
Baduel, C., Monge, M. E., Voisin, D., Jaffrezo, J. L., George, C., Haddad,
I. E., Marchand, N., and D'Anna, B.: Oxidation of atmospheric humic like
substances by ozone: A kinetic and structural analysis approach, Environ.
Sci. Technol., 45, 5238–5244, https://doi.org/10.1021/es200587z, 2011.
Battaglia, M. A., Douglas, S., and Hennigan, C. J.: Effect of the urban heat
island on aerosol pH, Environ. Sci. Technol., 51, 13095–13103,
https://doi.org/10.1021/acs.est.7b02786, 2017.
Boreddy, S. K. R., Hegde, P., and Aswini, A. R.: Chemical characteristics,
size distributions, and aerosol liquid water in size-resolved coastal urban
aerosols allied with distinct air masses over tropical peninsular India,
ACS Earth. Space. Chem., 5, 457–473,
https://doi.org/10.1021/acsearthspacechem.0c00282, 2021.
Bousiotis, D., Brean, J., Pope, F. D., Dall'Osto, M., Querol, X., Alastuey, A., Perez, N., Petäjä, T., Massling, A., Nøjgaard, J. K., Nordstrøm, C., Kouvarakis, G., Vratolis, S., Eleftheriadis, K., Niemi, J. V., Portin, H., Wiedensohler, A., Weinhold, K., Merkel, M., Tuch, T., and Harrison, R. M.: The effect of meteorological conditions and atmospheric composition in the occurrence and development of new particle formation (NPF) events in Europe, Atmos. Chem. Phys., 21, 3345–3370, https://doi.org/10.5194/acp-21-3345-2021, 2021.
Cawley, K. M., McKnight, D. M., Miller, P., Cory, R., Fimmen, R. L.,
Guerard, J., Dieser, M., Jaros, C., Chin, Y. P., and Foreman, C.:
Characterization of fulvic acid fractions of dissolved organic matter during
ice-out in a hyper-eutrophic, coastal pond in Antarctica, Environ. Res.
Lett., 8, 045–015, https://doi.org/10.1088/1748-9326/8/4/045015, 2013.
Chen, Q., Ikemori, F., Higo, H., Asakawa, D., and Mochida, M.: Chemical
structural characteristics of HULIS and other fractionated organic matter in
urban aerosols: Results from mass spectral and FT-IR analysis, Environ. Sci.
Technol., 50, 1721–1730, https://doi.org/10.1021/acs.est.5b05277, 2016a.
Chen, Q., Miyazaki, Y., Kawamura, K., Matsumoto, K., Coburn, S., Volkamer,
R., Iwamoto, Y., Kagami, S., Deng, Y., Ogawa, S., Ramasamy, S., Kato, S.,
Ida, A., Kajii, Y., and Mochida, M.: Characterization of chromophoric
water-soluble organic matter in urban, forest, and marine aerosols by
HR-ToF-AMS analysis and excitation–emission matrix spectroscopy, Environ.
Sci. Technol., 50, 10351–10360, https://doi.org/10.1021/acs.est.6b01643,
2016b.
Chen, Q., Ikemori, F., Nakamura, Y., Vodicka, P., Kawamura, K., and Mochida,
M.: Structural and light-absorption characteristics of complex
water-insoluble organic mixtures in urban submicrometer aerosols, Environ.
Sci. Technol., 51, 8293–8303, https://doi.org/10.1021/acs.est.7b01630,
2017.
Chen, Q., Mu, Z., Song, W., Wang, Y., Yang, Z., Zhang, L., and Zhang, Y. L.:
Size-resolved characterization of the chromophores in atmospheric
particulate matter from a typical coal-burning city in China, J. Geophys.
Res.-Atmos., 124, 10546–10563, https://doi.org/10.1029/2019JD031149, 2019.
Chen, Q., Li, J., Hua, X., Jiang, X., Mu, Z., Wang, M., Wang, J., Shan, M.,
Yang, X., and Fan, X.: Identification of species and sources of atmospheric
chromophores by fluorescence excitation-emission matrix with parallel factor
analysis, Sci. Total. Environ., 718, 137322,
https://doi.org/10.1016/j.scitotenv.2020.137322, 2020.
Coble, P., Lead, J., Baker, A., Reynolds, D. M., and Spencer, R. (Eds.): Aquatic Organic Matter Fluorescence, Cambridge University Press, New York, USA, https://doi.org/10.1017/CBO9781139045452, 2014.
Colthup, N. B., Daly, L. H., and Wiberley, S. E. (Eds.): Introduction to Infrared and Raman Spectroscopy, Academic press, New York and London, https://doi.org/10.1016/B978-0-08-091740-5.50003-X, 1990.
Craig, R. L., Peterson, P. K., Nandy, L., Lei, Z., Hossain, M. A., Camarena,
S., Dodson, R. A., Cook, R. D., Dutcher, C. S., and Ault, A. P.: Direct
determination of aerosol pH: Size-resolved measurements of submicrometer and
supermicrometer aqueous particles, Anal. Chem., 90, 11232–11239,
https://doi.org/10.1021/acs.analchem.8b00586, 2018.
Deshmukh, D. K., Kawamura, K., Lazaar, M., Kunwar, B., and Boreddy, S. K. R.: Dicarboxylic acids, oxoacids, benzoic acid, α-dicarbonyls, WSOC, OC, and ions in spring aerosols from Okinawa Island in the western North Pacific Rim: size distributions and formation processes, Atmos. Chem. Phys., 16, 5263–5282, https://doi.org/10.5194/acp-16-5263-2016, 2016.
Dryer, D. J., Korshin, G. V., and Fabbricino, M.: In situ examination of the
protonation behavior of fulvic acids using differential absorbance
spectroscopy, Environ. Sci. Technol., 42, 6644–6649,
https://doi.org/10.1021/es800741u, 2008.
Duarte, R. M. B. O., Pio, C. A., and Duarte, A. C.: Spectroscopic study of
the water-soluble organic matter isolated from atmospheric aerosols
collected under different atmospheric conditions, Anal. Chim. Acta, 530,
7–14, https://doi.org/10.1016/j.aca.2004.08.049, 2005.
Duarte, R. M. B. O., Santos, E. B. H., Pio, C. A., and Duarte, A. C.:
Comparison of structural features of water-soluble organic matter from
atmospheric aerosols with those of aquatic humic substances, Atmos.
Environ., 41, 8100–8113, https://doi.org/10.1016/j.atmosenv.2007.06.034,
2007.
Fan, X., Cao, T., Yu, X., Wang, Y., Xiao, X., Li, F., Xie, Y., Ji, W., Song, J., and Peng, P.: The evolutionary behavior of chromophoric brown carbon during ozone aging of fine particles from biomass burning, Atmos. Chem. Phys., 20, 4593–4605, https://doi.org/10.5194/acp-20-4593-2020, 2020.
Frka, S., Grgiæ, I., Turiè, J., Gini, M. I., and Eleftheriadis, K.:
Seasonal variability of carbon in humic-like matter of ambient
size-segregated water soluble organic aerosols from urban background
environment, Atmos. Environ., 173, 239–247,
https://doi.org/10.1016/j.atmosenv.2017.11.013, 2018.
Frka, S., Šala, M., Brodnik, H., Štefane, B., Krofliè, A., and
Grgiæ, I.: Seasonal variability of nitroaromatic compounds in ambient
aerosols: Mass size distribution, possible sources and contribution to
water-soluble brown carbon light absorption, Chemosphere, 299, 134381,
https://doi.org/10.1016/j.chemosphere.2022.134381, 2022.
Fu, P., Kawamura, K., Chen, J., Qin, M., Ren, L., Sun, Y., Wang, Z., Barrie,
L. A., Tachibana, E., and Ding, A.: Fluorescent water-soluble organic
aerosols in the High Arctic atmosphere, Sci. Rep.-UK, 5, 9845,
https://doi.org/10.1038/srep09845, 2015.
Ge, M., Tong, S., Wang, W., Zhang, W., Chen, M., Peng, C., Li, J., Zhou, L.,
Chen, Y., and Liu, M.: Important oxidants and their impact on the
environmental effects of aerosols, J. Phys. Chem. A., 125, 3813–3825,
https://doi.org/10.1021/acs.jpca.0c10236, 2021.
Geng, X., Mo, Y., Li, J., Zhong, G., Tang, J., Jiang, H., Ding, X., Malik,
R. N., and Zhang, G.: Source apportionment of water-soluble brown carbon in
aerosols over the northern South China Sea: Influence from land outflow, SOA
formation and marine emission, Atmos. Environ., 229, 117484,
https://doi.org/10.1016/j.atmosenv.2020.117484, 2020.
Horník, Š., Sýkora, J., Pokorná, P., Vodièka, P.,
Schwarz, J., and Dímal, V.: Detailed NMR analysis of water-soluble
organic compounds in size-resolved particulate matter seasonally collected
at a suburban site in Prague, Atmos. Environ., 267, 118757,
https://doi.org/10.1016/j.atmosenv.2021.118757, 2021.
Hu, B., Wang, P., Wang, C., Qian, J., Bao, T., and Shi, Y.: Investigating
spectroscopic and copper-binding characteristics of organic matter derived
from sediments and suspended particles using EEM-PARAFAC combined with
two-dimensional fluorescence/FTIR correlation analyses, Chemosphere, 219,
45–53, https://doi.org/10.1016/S1352-2310(02)00654-4, 2019.
Huang, S., Luo, Y., Wang, X., Zhang, T., Lei, Y., Zeng, Y., Sun, J., Che,
H., Xu, H., Cao, J., and Shen, Z.: Optical properties, chemical functional
group, and oxidative activity of different polarity levels of water-soluble
organic matter in PM2.5 from biomass and coal combustion in rural areas
in Northwest China, Atmos. Environ., 283, 119179,
https://doi.org/10.1016/j.atmosenv.2022.119179, 2022.
Huo, S., Xi, B., Yu, H., He, L., and Fan, S.: Characteristics of dissolved
organic matter (DOM) in leachate with different landfill ages, J. Environ.
Sci., 20, 492–498, https://doi.org/10.1016/S1001-0742(08)62085-9, 2008.
Jane, S. F., Winslow, L. A., Remucal, C. K., and Rose, K. C.: Long-term
trends and synchrony in dissolved organic matter characteristics in
Wisconsin, USA, lakes: quality, not quantity, is highly sensitive to
climate, J. Geophys. Res.-Biogeo., 122, 546–561,
https://doi.org/10.1002/2016JG003630, 2017.
Jang, K. S., Choi, A. Y., Choi, M., Kang, H., Kim, T. W., and Park, K. T.:
Size-segregated chemical compositions of HULISs in ambient aerosols
collected during the winter season in Songdo, South Korea, Atmosphere, 10,
226, https://doi.org/10.3390/atmos10040226, 2019.
Korshin, G. V., Li, C. W., and Benjamin, M. M.: The decrease of UV
absorbance as an indicator of TOX formation, Water Res., 31, 946–949,
https://doi.org/10.1016/S0043-1354(96)00393-4, 1997.
Kuang, Y., Shang, J., and Chen, Q.: Effect of ozone aging on light
absorption and fluorescence of brown carbon in soot particles: The important
role of polycyclic aromatic hydrocarbons, J. Hazard. Mater., 413, 125406,
https://doi.org/10.1016/j.jhazmat.2021.125406, 2021.
Laskin, A., Laskin, J., and Nizkorodov, S. A.: Chemistry of atmospheric
brown carbon, Chem. Rev., 115, 4335–4382,
https://doi.org/10.1021/cr5006167, 2015.
Lin, P., Aiona, P. K., Li, Y., Shiraiwa, M., Laskin, J., Nizkorodov, S. A.,
and Laskin, A.: Molecular characterization of brown carbon in biomass
burning aerosol particles, Environ. Sci. Technol., 50, 11815–11824,
https://doi.org/10.1021/acs.est.6b03024, 2016.
Liu, S., Benedetti, M. F., Han, W., and Korshin, G. V.: Comparison of the
properties of standard soil and aquatic fulvic and humic acids based on the
data of differential absorbance and fluorescence spectroscopy, Chemosphere.,
261, 128189, https://doi.org/10.1016/j.chemosphere.2020.128189, 2020.
Ma, L., Li, Z., Li, B., Fu, D., Sun, X., Sun, S., Lu, L., Jiang, J., Meng,
F., Qi, H., and Zhang, R.: Light-absorption and fluorescence fingerprinting
characteristics of water and methanol soluble organic compounds in
PM2.5 in cold regions of Northeast China, Sci. Total. Environ., 832,
155081, https://doi.org/10.1016/j.scitotenv.2022.155081, 2022.
Mo, Y., Li, J., Liu, J., Zhong, G., Cheng, Z., Tian, C., Chen, Y., and
Zhang, G.: The influence of solvent and pH on determination of the light
absorption properties of water-soluble brown carbon, Atmos. Environ., 161,
90–98, https://doi.org/10.1016/j.atmosenv.2017.04.037, 2017.
Mu, S., Wang, S., Liang, S., Xiao, K., Fan, H., Han, B., Liu, C., Wang, X.,
and Huang, X.: Effect of the relative degree of foulant “hydrophobicity”
on membrane fouling, J. Membr. Sci., 570, 1–8,
https://doi.org/10.1016/j.memsci.2018.10.023, 2019.
Pandey, A., Hsu, A., Tiwari, S., Pervez, S., and Chakrabarty, R. K.: Light
absorption by organic aerosol emissions rivals that of black carbon from
residential biomass fuels in South Asia, Environ. Sci. Technol. Lett., 7,
266–272, https://doi.org/10.1021/acs.estlett.0c00058, 2020.
Park, S., Cho, S. Y., and Bae, M. S.: Source identification of water-soluble
organic aerosols at a roadway site using a positive matrix factorization
analysis, Sci. Total. Environ., 533, 410–421,
https://doi.org/10.1016/j.scitotenv.2015.07.004, 2015.
Phillips, S. M., Bellcross, A. D., and Smith, G. D.: Light absorption by
brown carbon in the Southeastern United States is pH-dependent, Environ.
Sci. Technol., 51, 6782–6790, https://doi.org/10.1021/acs.est.7b01116,
2017.
Qin, J., Zhang, L., Zhou, X., Duan, J., Mu, S., Xiao, K., Hu, J., and Tan,
J.: Fluorescence fingerprinting properties for exploring water-soluble
organic compounds in PM2.5 in an industrial city of northwest China,
Atmos. Environ., 184, 203–211,
https://doi.org/10.1016/j.atmosenv.2018.04.049, 2018.
Qin, J., Tan, J., Zhou, X., Yang, Y., Qin, Y., Wang, X., Shi, S., Xiao, K., and Wang, X.: Measurement report: Particle-size-dependent fluorescence properties of water-soluble organic compounds (WSOCs) and their atmospheric implications for the aging of WSOCs, Atmos. Chem. Phys., 22, 465–479, https://doi.org/10.5194/acp-22-465-2022, 2022.
Qin, Y., Yang, Y., Qin, J., Zhang, L., Guo, S., Zhou, X., Chen, R., Tan, J.,
Xiao, K., and Wang, X.: pH-responsive fluorescence EEM to titrate the
interaction between fluorophores and acid/base groups in water-soluble
organic compounds of PM2.5, Environ. Sci. Technol. Lett., 8, 108–113,
https://doi.org/10.1021/acs.estlett.0c00645, 2021.
Qin, Y., Qin, J., Wang, X., Xiao, K., Qi, T., Gao, Y., Zhou, X., Shi, S.,
Li, J., Gao, J., Zhang, Z., Tan, J., Zhang, Y., and Chen, R.: Measurement
Report: Investigation of pH- and particle-size-dependent chemical and
optical properties of water-soluble organic carbon: implications for its
sources and aging processes, Zenodo [data set],
https://doi.org/10.5281/zenodo.7067423, 2022a.
Qin, Y., Qin, J., Zhou, X., Yang, Y., Chen, R., Tan, J., Xiao, K., and Wang,
X.: Effects of pH on light absorption properties of water-soluble organic
compounds in particulate matter emitted from typical emission sources, J.
Hazard. Mater., 424, 127688, https://doi.org/10.1016/j.jhazmat.2021.127688,
2022b.
Sannigrahi, P., Sullivan, A. P., Weber, R. J., and Ingall, E. D.:
Characterization of water-soluble organic carbon in urban atmospheric
aerosols using solid-state 13C NMR spectroscopy, Environ. Sci. Technol., 40,
666–672, https://doi.org/10.1021/es051150i, 2006.
Schendorf, T. M., Del Vecchio, R., Bianca, M., and Blough, N. V.: Combined
effects of pH and borohydride reduction on the optical properties of humic
substances (HS): A comparison of optical models, Environ. Sci. Technol., 53,
6310–6319, https://doi.org/10.1021/acs.est.9b01516, 2019.
Schulman, S. G., Winefordner, J. D., and Kolthoff, I. M. (Eds.): Molecular Luminescence Spectroscopy: Methods and Applications, Wiley, New York, 1985.
Snyder, D. C., Rutter, A. P., Collins, R., Worley, C., and Schauer, J. J.:
Insights into the origin of water soluble organic carbon in atmospheric fine
particulate matter, Aerosol Sci. Technol., 43, 1099–1107,
https://doi.org/10.1080/02786820903188701, 2009.
Sun, Y., Zhang, Q., Zheng, M., Ding, X., Edgerton, E. S., and Wang, X.:
Characterization and source apportionment of water-soluble organic matter in
atmospheric fine particles (PM2.5) with high-resolution aerosol mass
spectrometry and GC–MS, Environ. Sci. Technol., 45, 4854–4861,
https://doi.org/10.1021/es200162h, 2011.
Timonen, H., Saarikoski, S., Tolonen-Kivimäki, O., Aurela, M., Saarnio, K., Petäjä, T., Aalto, P. P., Kulmala, M., Pakkanen, T., and Hillamo, R.: Size distributions, sources and source areas of water-soluble organic carbon in urban background air, Atmos. Chem. Phys., 8, 5635–5647, https://doi.org/10.5194/acp-8-5635-2008, 2008.
Wang, L., Wang, Y., Li, Y., Zhang, W., Zhang, H., Niu, L., and Habibul, N.:
Benthic biofilm bacterial communities and their linkage with water-soluble
organic matter in effluent receivers, Int. J. Environ., 19, 1994,
https://doi.org/10.3390/ijerph19041994, 2022.
Wang, X. M. and Waite, T. D.: Role of gelling soluble and colloidal
microbial products in membrane fouling, Environ. Sci. Technol., 43,
9341–9347, https://doi.org/10.1021/es9013129, 2009.
Wang, Y., Hu, M., Wang, Y., Zheng, J., Shang, D., Yang, Y., Liu, Y., Li, X., Tang, R., Zhu, W., Du, Z., Wu, Y., Guo, S., Wu, Z., Lou, S., Hallquist, M., and Yu, J. Z.: The formation of nitro-aromatic compounds under high NOx and anthropogenic VOC conditions in urban Beijing, China, Atmos. Chem. Phys., 19, 7649–7665, https://doi.org/10.5194/acp-19-7649-2019, 2019.
Wu, C., Zhu, B., Liang, W., Ruan, T., and Jiang, G.: Molecular
characterization of nitrogen-containing organic compounds in fractionated
atmospheric humic-like substances (HULIS) and its relationship with optical
properties, Sci. Total. Environ., 832, 155043,
https://doi.org/10.1016/j.scitotenv.2022.155043, 2022.
Wu, G., Wan, X., Gao, S., Fu, P., Yin, Y., Li, G., Zhang, G., Kang, S., Ram,
K., and Cong, Z.: Humic-like substances (HULIS) in aerosols of central
Tibetan Plateau (Nam Co, 4730 m asl): Abundance, light absorption
properties, and sources, Environ. Sci. Technol., 52, 7203–7211,
https://doi.org/10.1021/acs.est.8b01251, 2018.
Wu, G., Fu, P., Ram, K., Song, J., Chen, Q., Kawamura, K., Wan, X., Kang,
S., Wang, X., Laskin, A., and Cong, Z.: Fluorescence characteristics of
water-soluble organic carbon in atmospheric aerosol, Environ. Pollut., 268,
115906, https://doi.org/10.1016/j.envpol.2020.115906, 2021.
Wu, J., Zhang, H., He, P. J., and Shao, L. M.: Insight into the heavy metal
binding potential of dissolved organic matter in MSW leachate using EEM
quenching combined with PARAFAC analysis, Water Res., 45, 1711–1719,
https://doi.org/10.1016/j.watres.2010.11.022, 2011.
Xiang, P., Zhou, X., Duan, J., Tan, J., and He, K.: Chemical characteristics
of water-soluble organic compounds (WSOC) in PM2.5 in Beijing, China:
2011–2012, Atmos. Res., 183, 104–112,
https://doi.org/10.1016/j.atmosres.2016.08.020, 2017.
Xiao, K., Shen, Y. X., Liang, S., Liang, P., Wang, X. M., and Huang, X.: A
systematic analysis of fouling evolution and irreversibility behaviors of
MBR supernatant hydrophilic/hydrophobic fractions during microfiltration, J.
Membr. Sci., 467, 206–216, https://doi.org/10.1016/j.memsci.2014.05.030,
2014.
Xiao, K., Liang, S., Xiao, A., Lei, T., Tan, J., Wang, X., and Huang, X.:
Fluorescence quotient of excitation–emission matrices as a potential
indicator of organic matter behavior in membrane bioreactors, Environ. Sci.
Water Res. Technol., 4, 281–290, https://doi.org/10.1039/C7EW00270J, 2018a.
Xiao, K., Shen, Y., Sun, J., Liang, S., Fan, H., Tan, J., Wang, X., Huang,
X., and Waite, T. D.: Correlating fluorescence spectral properties with DOM
molecular weight and size distribution in wastewater treatment systems,
Environ. Sci. Water Res. Technol., 4, 1933–1943,
https://doi.org/10.1039/C8EW00504D, 2018b.
Xiao, K., Han, B., Sun, J., Tan, J., Yu, J., Liang, S., Shen, Y., and Huang,
X.: Stokes shift and specific fluorescence as potential indicators of
organic matter hydrophobicity and molecular weight in membrane bioreactors,
Environ. Sci. Technol., 53, 8985–8993,
https://doi.org/10.1021/acs.est.9b02114, 2019.
Xiao, K., Yu, J., Wang, S., Du, J., Tan, J., Xue, K., Wang, Y., and Huang,
X.: Relationship between fluorescence excitation-emission matrix properties
and the relative degree of DOM hydrophobicity in wastewater treatment
effluents, Chemosphere., 254, 126830,
https://doi.org/10.1016/j.chemosphere.2020.126830, 2020.
Yang, Y., Qin, J., Qi, T., Zhou, X., Chen, R., Tan, J., Xiao, K., Ji, D.,
He, K., and Chen, X.: Fluorescence characteristics of particulate
water-soluble organic compounds emitted from coal-fired boilers, Atmos.
Environ., 223, 117297, https://doi.org/10.1016/j.atmosenv.2020.117297, 2020.
Young, T. R., Li, W., Guo, A., Korshin, G. V., and Dodd, M. C.:
Characterization of disinfection byproduct formation and associated changes
to dissolved organic matter during solar photolysis of free available
chlorine, Water Res., 146, 318–327,
https://doi.org/10.1016/j.watres.2018.09.022, 2018.
Yu, J., Yu, G. H., Park, S., and Bae, M. S.: Chemical and absorption
characteristics of water-soluble organic carbon and humic-like substances in
size-segregated particles from biomass burning emissions, Asian J.
Atmos. Environ., 11, 96–106,
https://doi.org/10.5572/ajae.2017.11.2.096, 2017.
Zhang, T., Shen, Z., Zeng, Y., Cheng, C., Wang, D., Zhang, Q., Lei, Y.,
Zhang, Y., Sun, J., Xu, H., Ho, S. S. H., and Cao, J.: Light absorption
properties and molecular profiles of HULIS in PM2.5 emitted from
biomass burning in traditional “Heated Kang” in Northwest China, Sci.
Total. Environ., 776, 146014–146022,
https://doi.org/10.1016/j.scitotenv.2021.146014, 2021.
Zhang, T., Huang, S., Wang, D., Sun, J., Zhang, Q., Xu, H., Hang Ho, S. S.,
Cao, J., and Shen, Z.: Seasonal and diurnal variation of PM2.5 HULIS
over Xi'an in Northwest China: Optical properties, chemical functional
group, and relationship with reactive oxygen species (ROS), Atmos. Environ.,
268, 118782, https://doi.org/10.1016/j.atmosenv.2021.118782, 2022.
Zhang, Y., Wei, D., Huang, R., Yang, M., Zhang, S., Dou, X., Wang, D., and
Vimonses, V.: Binding mechanisms and QSAR modeling of aromatic pollutant
biosorption on Penicillium oxalicum biomass, Chem. Eng. J., 166, 624–630,
https://doi.org/10.1016/j.cej.2010.11.034, 2011.
Short summary
Deep interrogation of water-soluble organic carbon (WSOC) in aerosols is critical and challenging considering its involvement in many key aerosol-associated chemical reactions. This work examined how the chemical structures (functional groups) and optical properties (UV/fluorescence properties) of WSOC were affected by pH and particle size. We found that the pH- and particle-size-dependent behaviors could be used to reveal the structures, sources, and aging of aerosol WSOC.
Deep interrogation of water-soluble organic carbon (WSOC) in aerosols is critical and...
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