Articles | Volume 22, issue 20
https://doi.org/10.5194/acp-22-13407-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-13407-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
18 Oct 2022
Research article |
| 18 Oct 2022
| 18 Oct 2022
On the potential fingerprint of the Antarctic ozone hole in ice-core nitrate isotopes: a case study based on a South Pole ice core
Yanzhi Cao
Deep Space Exploration Laboratory/School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, China
Zhuang Jiang
Deep Space Exploration Laboratory/School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, China
Becky Alexander
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Jihong Cole-Dai
Department of Chemistry and Biochemistry, South Dakota State
University, Brookings, SD, USA
Joel Savarino
Univ. Grenoble Alpes, CNRS, IRD, G-INP, Institut des Géosciences de l'Environnement, Grenoble, France
Joseph Erbland
Univ. Grenoble Alpes, CNRS, IRD, G-INP, Institut des Géosciences de l'Environnement, Grenoble, France
Deep Space Exploration Laboratory/School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, China
CAS Center for Excellence in Comparative Planetology, University of
Science and Technology of China, Hefei, Anhui, China
Laboratory for Ocean Dynamics and Climate, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao, Shandong, China
Related authors
No articles found.
Michael Oluwatoyin Sunday, Laura Marie Dahler Heinlein, Junwei He, Allison Moon, Sukriti Kapur, Ting Fang, Kasey C. Edwards, Fangzhou Guo, Jack Dibb, James H. Flynn III, Becky Alexander, Manabu Shiraiwa, and Cort Anastasio
EGUsphere, https://doi.org/10.5194/egusphere-2024-3272, https://doi.org/10.5194/egusphere-2024-3272, 2024
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
Hydrogen peroxide (HOOH) is an important oxidant that forms atmospheric sulfate. We demonstrate that illumination of brown carbon can rapidly form HOOH within particles, even under the low sunlight conditions of Fairbanks, Alaska during winter. This in-particle formation of HOOH is fast enough that it forms sulfate at significant rates. In contrast, the formation of HOOH in the gas phase during the campaign is expected to be negligible because of high NOx levels.
Ursula A. Jongebloed, Jacob I. Chalif, Linia Tashmim, William C. Porter, Kelvin H. Bates, Qianjie Chen, Erich C. Osterberg, Bess G. Koffman, Jihong Cole-Dai, Dominic A. Winksi, David G. Ferris, Karl J. Kreutz, Cameron P. Wake, and Becky Alexander
EGUsphere, https://doi.org/10.5194/egusphere-2024-3026, https://doi.org/10.5194/egusphere-2024-3026, 2024
Short summary
Short summary
Marine phytoplankton emit dimethyl sulfide (DMS), which forms methanesulfonic acid (MSA) and sulfate. MSA concentrations in ice cores decreased over the industrial era, which has been attributed to pollution-driven changes in DMS chemistry. We use a models to investigate DMS chemistry compared to observations of DMS, MSA, and sulfate. We find that modeled DMS, MSA, and sulfate are influenced by pollution-sensitive oxidant concentrations, characterization of DMS chemistry, and other variables.
Tianming Ma, Zhuang Jiang, Minghu Ding, Pengzhen He, Yuansheng Li, Wenqian Zhang, and Lei Geng
The Cryosphere, 18, 4547–4565, https://doi.org/10.5194/tc-18-4547-2024, https://doi.org/10.5194/tc-18-4547-2024, 2024
Short summary
Short summary
We constructed a box model to evaluate the isotope effects of atmosphere–snow water vapor exchange at Dome A, Antarctica. The results show clear and invisible diurnal changes in surface snow isotopes under summer and winter conditions, respectively. The model also predicts that the annual net effects of atmosphere–snow water vapor exchange would be overall enrichments in snow isotopes since the effects in summer appear to be greater than those in winter at the study site.
Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonne, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
EGUsphere, https://doi.org/10.5194/egusphere-2024-1450, https://doi.org/10.5194/egusphere-2024-1450, 2024
Short summary
Short summary
Processes influencing dispersion of local anthropogenic emissions in Arctic wintertime are investigated with dispersion model simulations. Modelled power plant plume rise that considers surface and elevated temperature inversions improves results compared to observations. Modelled near-surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching -35 °C are required to reproduce observed NOx.
V. Holly L. Winton, Robert Mulvaney, Joel Savarino, Kyle R. Clem, and Markus M. Frey
Clim. Past, 20, 1213–1232, https://doi.org/10.5194/cp-20-1213-2024, https://doi.org/10.5194/cp-20-1213-2024, 2024
Short summary
Short summary
In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We present the first results including a 1300-year record of snow accumulation and aerosol chemistry. We investigate the aerosol and moisture source regions and atmospheric processes related to the ice core record and discuss what this means for developing a record of past ultraviolet radiation and ozone depletion using the stable isotopic composition of nitrate measured in the same ice core.
Xia Wang, Tao Che, Xueyin Ruan, Shanna Yue, Jing Wang, Chun Zhao, and Lei Geng
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-37, https://doi.org/10.5194/gmd-2024-37, 2024
Revised manuscript under review for GMD
Short summary
Short summary
We employed the WRF-Chem model to parameterize atmospheric nitrate deposition in snow and evaluated its performance in simulating snow cover, snow depth, and concentrations of black carbon (BC), dust, and nitrate using new observations from Northern China. The results generally exhibit reasonable agreement with field observations in northern China, demonstrating the model's capability to simulate snow properties, including concentrations of reservoir species.
Zhuang Jiang, Becky Alexander, Joel Savarino, and Lei Geng
Atmos. Chem. Phys., 24, 4895–4914, https://doi.org/10.5194/acp-24-4895-2024, https://doi.org/10.5194/acp-24-4895-2024, 2024
Short summary
Short summary
Ice-core nitrate could track the past atmospheric NOx and oxidant level, but its interpretation is hampered by the post-depositional processing. In this work, an inverse model was developed and tested against two polar sites and was shown to well reproduce the observed nitrate signals in snow and atmosphere, suggesting that the model can properly correct for the effect of post-depositional processing. This model offers a very useful tool for future studies on ice-core nitrate records.
Linia Tashmim, William C. Porter, Qianjie Chen, Becky Alexander, Charles H. Fite, Christopher D. Holmes, Jeffrey R. Pierce, Betty Croft, and Sakiko Ishino
Atmos. Chem. Phys., 24, 3379–3403, https://doi.org/10.5194/acp-24-3379-2024, https://doi.org/10.5194/acp-24-3379-2024, 2024
Short summary
Short summary
Dimethyl sulfide (DMS) is mostly emitted from ocean surfaces and represents the largest natural source of sulfur for the atmosphere. Once in the atmosphere, DMS forms stable oxidation products such as SO2 and H2SO4, which can subsequently contribute to airborne particle formation and growth. In this study, we update the DMS oxidation mechanism in the chemical transport model GEOS-Chem and describe resulting changes in particle growth as well as the overall global sulfur budget.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, Roberto Grilli, Quentin Fournier, Irène Ventrillard, Nicolas Caillon, and Kathy Law
Atmos. Chem. Phys., 24, 1361–1388, https://doi.org/10.5194/acp-24-1361-2024, https://doi.org/10.5194/acp-24-1361-2024, 2024
Short summary
Short summary
This study reports the first simultaneous records of oxygen (Δ17O) and nitrogen (δ15N) isotopes in nitrogen dioxide (NO2) and nitrate (NO3−). These data are combined with atmospheric observations to explore sub-daily N reactive chemistry and quantify N fractionation effects in an Alpine winter city. The results highlight the necessity of using Δ17O and δ15N in both NO2 and NO3− to avoid biased estimations of NOx sources and fates from NO3− isotopic records in urban winter environments.
Alexis Lamothe, Joel Savarino, Patrick Ginot, Lison Soussaintjean, Elsa Gautier, Pete D. Akers, Nicolas Caillon, and Joseph Erbland
Atmos. Meas. Tech., 16, 4015–4030, https://doi.org/10.5194/amt-16-4015-2023, https://doi.org/10.5194/amt-16-4015-2023, 2023
Short summary
Short summary
Ammonia is a reactive gas in our atmosphere that is key in air quality issues. Assessing its emissions and how it reacts is a hot topic that can be addressed from the past. Stable isotopes (the mass of the molecule) measured in ice cores (glacial archives) can teach us a lot. However, the concentrations in ice cores are very small. We propose a protocol to limit the contamination and apply it to one ice core drilled in Mont Blanc, describing the opportunities our method brings.
Simone Ventisette, Samuele Baldini, Claudio Artoni, Silvia Becagli, Laura Caiazzo, Barbara Delmonte, Massimo Frezzotti, Raffaello Nardin, Joel Savarino, Mirko Severi, Andrea Spolaor, Barbara Stenni, and Rita Traversi
EGUsphere, https://doi.org/10.5194/egusphere-2023-393, https://doi.org/10.5194/egusphere-2023-393, 2023
Preprint archived
Short summary
Short summary
The paper reports the spatial variability of concentration and fluxes of chemical impurities in superficial snow over unexplored area of the East Antarctic ice sheet. Pinatubo and Puyehue-Cordón Caulle volcanic eruptions in non-sea salt sulfate and dust snow pits record were used to achieve the accumulation rates. Deposition (wet, dry and uptake from snow surface) and post deposition processes are constrained. These knowledges are fundamental in Antarctic ice cores stratigraphies interpretation.
Aaron Chesler, Dominic Winski, Karl Kreutz, Bess Koffman, Erich Osterberg, David Ferris, Zayta Thundercloud, Joseph Mohan, Jihong Cole-Dai, Mark Wells, Michael Handley, Aaron Putnam, Katherine Anderson, and Natalie Harmon
Clim. Past, 19, 477–492, https://doi.org/10.5194/cp-19-477-2023, https://doi.org/10.5194/cp-19-477-2023, 2023
Short summary
Short summary
Ice core microparticle data typically use geometry assumptions to calculate particle mass and flux. We use dynamic particle imaging, a novel technique for ice core dust analyses, combined with traditional laser particle counting and Coulter counter techniques to assess particle shape in the South Pole Ice Core (SPC14) spanning 50–16 ka. Our results suggest that particles are dominantly ellipsoidal in shape and that spherical assumptions overestimate particle mass and flux.
Pete D. Akers, Joël Savarino, Nicolas Caillon, Olivier Magand, and Emmanuel Le Meur
Atmos. Chem. Phys., 22, 15637–15657, https://doi.org/10.5194/acp-22-15637-2022, https://doi.org/10.5194/acp-22-15637-2022, 2022
Short summary
Short summary
Nitrate isotopes in Antarctic ice do not preserve the seasonal isotopic cycles of the atmosphere, which limits their use to study the past. We studied nitrate along an 850 km Antarctic transect to learn how these cycles are changed by sunlight-driven chemistry in the snow. Our findings suggest that the snow accumulation rate and other environmental signals can be extracted from nitrate with the right sampling and analytical approaches.
William F. Swanson, Chris D. Holmes, William R. Simpson, Kaitlyn Confer, Louis Marelle, Jennie L. Thomas, Lyatt Jaeglé, Becky Alexander, Shuting Zhai, Qianjie Chen, Xuan Wang, and Tomás Sherwen
Atmos. Chem. Phys., 22, 14467–14488, https://doi.org/10.5194/acp-22-14467-2022, https://doi.org/10.5194/acp-22-14467-2022, 2022
Short summary
Short summary
Radical bromine molecules are seen at higher concentrations during the Arctic spring. We use the global model GEOS-Chem to test whether snowpack and wind-blown snow sources can explain high bromine concentrations. We run this model for the entire year of 2015 and compare results to observations of bromine from floating platforms on the Arctic Ocean and at Utqiaġvik. We find that the model performs best when both sources are enabled but may overestimate bromine production in summer and fall.
Albane Barbero, Roberto Grilli, Markus M. Frey, Camille Blouzon, Detlev Helmig, Nicolas Caillon, and Joël Savarino
Atmos. Chem. Phys., 22, 12025–12054, https://doi.org/10.5194/acp-22-12025-2022, https://doi.org/10.5194/acp-22-12025-2022, 2022
Short summary
Short summary
The high reactivity of the summer Antarctic boundary layer results in part from the emissions of nitrogen oxides produced during photo-denitrification of the snowpack, but its underlying mechanisms are not yet fully understood. The results of this study suggest that more NO2 is produced from the snowpack early in the photolytic season, possibly due to stronger UV irradiance caused by a smaller solar zenith angle near the solstice.
Xueyin Ruan, Chun Zhao, Rahul A. Zaveri, Pengzhen He, Xinming Wang, Jingyuan Shao, and Lei Geng
Geosci. Model Dev., 15, 6143–6164, https://doi.org/10.5194/gmd-15-6143-2022, https://doi.org/10.5194/gmd-15-6143-2022, 2022
Short summary
Short summary
Accurate prediction of aerosol pH in chemical transport models is essential to aerosol modeling. This study examines the performance of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) on aerosol pH predictions and the sensitivities to emissions of nonvolatile cations and NH3, aerosol-phase state assumption, and heterogeneous sulfate production. Temporal evolution of aerosol pH during haze cycles in Beijing and the driving factors are also presented and discussed.
Zhuang Jiang, Joel Savarino, Becky Alexander, Joseph Erbland, Jean-Luc Jaffrezo, and Lei Geng
The Cryosphere, 16, 2709–2724, https://doi.org/10.5194/tc-16-2709-2022, https://doi.org/10.5194/tc-16-2709-2022, 2022
Short summary
Short summary
A record of year-round atmospheric nitrate isotopic composition along with snow nitrate isotopic data from Summit, Greenland, revealed apparent enrichments in nitrogen isotopes in snow nitrate compared to atmospheric nitrate, in addition to a relatively smaller degree of changes in oxygen isotopes. The results suggest that at this site post-depositional processing takes effect, which should be taken into account when interpreting ice-core nitrate isotope records.
Michael Sigl, Matthew Toohey, Joseph R. McConnell, Jihong Cole-Dai, and Mirko Severi
Earth Syst. Sci. Data, 14, 3167–3196, https://doi.org/10.5194/essd-14-3167-2022, https://doi.org/10.5194/essd-14-3167-2022, 2022
Short summary
Short summary
Volcanism is a key driver of climate. Based on ice cores from Greenland and Antarctica, we reconstruct its climate impact potential over the Holocene. By aligning records on a well-dated chronology from Antarctica, we resolve long-standing inconsistencies in the dating of past volcanic eruptions. We reconstruct 850 eruptions (which, in total, injected 7410 Tg of sulfur in the stratosphere) and estimate how they changed the opacity of the atmosphere, a prerequisite for climate model simulations.
Saehee Lim, Meehye Lee, Joel Savarino, and Paolo Laj
Atmos. Chem. Phys., 22, 5099–5115, https://doi.org/10.5194/acp-22-5099-2022, https://doi.org/10.5194/acp-22-5099-2022, 2022
Short summary
Short summary
We determined δ15N(NO3−) and Δ17O(NO3−) of PM2.5 in Seoul during 2018–2019 and estimated quantitatively the contribution of oxidation pathways to NO3− formation and NOx emission sources. The nighttime pathway played a significant role in NO3− formation during the winter, and its contribution further increased up to 70 % on haze days when PM2.5 was greater than 75 µg m−3. Vehicle emissions were confirmed as a main NO3− source with an increasing contribution from coal combustion in winter.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
Short summary
Short summary
The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Xuan Wang, Daniel J. Jacob, William Downs, Shuting Zhai, Lei Zhu, Viral Shah, Christopher D. Holmes, Tomás Sherwen, Becky Alexander, Mathew J. Evans, Sebastian D. Eastham, J. Andrew Neuman, Patrick R. Veres, Theodore K. Koenig, Rainer Volkamer, L. Gregory Huey, Thomas J. Bannan, Carl J. Percival, Ben H. Lee, and Joel A. Thornton
Atmos. Chem. Phys., 21, 13973–13996, https://doi.org/10.5194/acp-21-13973-2021, https://doi.org/10.5194/acp-21-13973-2021, 2021
Short summary
Short summary
Halogen radicals have a broad range of implications for tropospheric chemistry, air quality, and climate. We present a new mechanistic description and comprehensive simulation of tropospheric halogens in a global 3-D model and compare the model results with surface and aircraft measurements. We find that halogen chemistry decreases the global tropospheric burden of ozone by 11 %, NOx by 6 %, and OH by 4 %.
Andreas Tilgner, Thomas Schaefer, Becky Alexander, Mary Barth, Jeffrey L. Collett Jr., Kathleen M. Fahey, Athanasios Nenes, Havala O. T. Pye, Hartmut Herrmann, and V. Faye McNeill
Atmos. Chem. Phys., 21, 13483–13536, https://doi.org/10.5194/acp-21-13483-2021, https://doi.org/10.5194/acp-21-13483-2021, 2021
Short summary
Short summary
Feedbacks of acidity and atmospheric multiphase chemistry in deliquesced particles and clouds are crucial for the tropospheric composition, depositions, climate, and human health. This review synthesizes the current scientific knowledge on these feedbacks using both inorganic and organic aqueous-phase chemistry. Finally, this review outlines atmospheric implications and highlights the need for future investigations with respect to reducing emissions of key acid precursors in a changing world.
Zhuang Jiang, Becky Alexander, Joel Savarino, Joseph Erbland, and Lei Geng
The Cryosphere, 15, 4207–4220, https://doi.org/10.5194/tc-15-4207-2021, https://doi.org/10.5194/tc-15-4207-2021, 2021
Short summary
Short summary
We used a snow photochemistry model (TRANSITS) to simulate the seasonal nitrate snow profile at Summit, Greenland. Comparisons between model outputs and observations suggest that at Summit post-depositional processing is active and probably dominates the snowpack δ15N seasonality. We also used the model to assess the degree of snow nitrate loss and the consequences in its isotopes at present and in the past, which helps for quantitative interpretations of ice-core nitrate records.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, and Nicolas Caillon
Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, https://doi.org/10.5194/acp-21-10477-2021, 2021
Short summary
Short summary
We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
Kun Wang, Shohei Hattori, Mang Lin, Sakiko Ishino, Becky Alexander, Kazuki Kamezaki, Naohiro Yoshida, and Shichang Kang
Atmos. Chem. Phys., 21, 8357–8376, https://doi.org/10.5194/acp-21-8357-2021, https://doi.org/10.5194/acp-21-8357-2021, 2021
Short summary
Short summary
Sulfate aerosols play an important climatic role and exert adverse effects on the ecological environment and human health. In this study, we present the triple oxygen isotopic composition of sulfate from the Mt. Everest region, southern Tibetan Plateau, and decipher the formation mechanisms of atmospheric sulfate in this pristine environment. The results indicate the important role of the S(IV) + O3 pathway in atmospheric sulfate formation promoted by conditions of high cloud water pH.
Albane Barbero, Camille Blouzon, Joël Savarino, Nicolas Caillon, Aurélien Dommergue, and Roberto Grilli
Atmos. Meas. Tech., 13, 4317–4331, https://doi.org/10.5194/amt-13-4317-2020, https://doi.org/10.5194/amt-13-4317-2020, 2020
Short summary
Short summary
In this paper, we present a compact, affordable and robust instrument for in situ measurements of different trace gases: NOx, IO, CHOCHO and O3 with very low detection limits. The device weighs 15 kg and has a total electrical power consumption of < 300 W. Its very low detection limits and its design make it suitable for field applications to address different questions such as how to better constrain the oxidative capacity of the atmosphere and study the chemistry of highly reactive species.
Jiayue Huang, Lyatt Jaeglé, Qianjie Chen, Becky Alexander, Tomás Sherwen, Mat J. Evans, Nicolas Theys, and Sungyeon Choi
Atmos. Chem. Phys., 20, 7335–7358, https://doi.org/10.5194/acp-20-7335-2020, https://doi.org/10.5194/acp-20-7335-2020, 2020
Short summary
Short summary
Large-scale enhancements of tropospheric BrO and the depletion of surface ozone are often observed in the springtime Arctic. Here, we use a chemical transport model to examine the role of sea salt aerosol from blowing snow in explaining these phenomena. We find that our simulation can account for the spatiotemporal variability of satellite observations of BrO. However, the model has difficulty in producing the magnitude of observed ozone depletion events.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
Short summary
Short summary
The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Havala O. T. Pye, Athanasios Nenes, Becky Alexander, Andrew P. Ault, Mary C. Barth, Simon L. Clegg, Jeffrey L. Collett Jr., Kathleen M. Fahey, Christopher J. Hennigan, Hartmut Herrmann, Maria Kanakidou, James T. Kelly, I-Ting Ku, V. Faye McNeill, Nicole Riemer, Thomas Schaefer, Guoliang Shi, Andreas Tilgner, John T. Walker, Tao Wang, Rodney Weber, Jia Xing, Rahul A. Zaveri, and Andreas Zuend
Atmos. Chem. Phys., 20, 4809–4888, https://doi.org/10.5194/acp-20-4809-2020, https://doi.org/10.5194/acp-20-4809-2020, 2020
Short summary
Short summary
Acid rain is recognized for its impacts on human health and ecosystems, and programs to mitigate these effects have had implications for atmospheric acidity. Historical measurements indicate that cloud and fog droplet acidity has changed in recent decades in response to controls on emissions from human activity, while the limited trend data for suspended particles indicate acidity may be relatively constant. This review synthesizes knowledge on the acidity of atmospheric particles and clouds.
Becky Alexander, Tomás Sherwen, Christopher D. Holmes, Jenny A. Fisher, Qianjie Chen, Mat J. Evans, and Prasad Kasibhatla
Atmos. Chem. Phys., 20, 3859–3877, https://doi.org/10.5194/acp-20-3859-2020, https://doi.org/10.5194/acp-20-3859-2020, 2020
Short summary
Short summary
Nitrogen oxides are important for the formation of tropospheric oxidants and are removed from the atmosphere mainly through the formation of nitrate. We compare observations of the oxygen isotopes of nitrate with a global model to test our understanding of the chemistry nitrate formation. We use the model to quantify nitrate formation pathways in the atmosphere and identify key uncertainties and their relevance for the oxidation capacity of the atmosphere.
Detlev Helmig, Daniel Liptzin, Jacques Hueber, and Joel Savarino
The Cryosphere, 14, 199–209, https://doi.org/10.5194/tc-14-199-2020, https://doi.org/10.5194/tc-14-199-2020, 2020
Short summary
Short summary
We present 15 months of trace gas observations from air withdrawn within the snowpack and from above the snow at Concordia Station in Antarctica. The data show occasional positive spikes, indicative of pollution from the station generator. The pollution signal can be seen in snowpack air shortly after it is observed above the snow surface, and lasting for up to several days, much longer than above the surface.
Dominic A. Winski, Tyler J. Fudge, David G. Ferris, Erich C. Osterberg, John M. Fegyveresi, Jihong Cole-Dai, Zayta Thundercloud, Thomas S. Cox, Karl J. Kreutz, Nikolas Ortman, Christo Buizert, Jenna Epifanio, Edward J. Brook, Ross Beaudette, Jeffrey Severinghaus, Todd Sowers, Eric J. Steig, Emma C. Kahle, Tyler R. Jones, Valerie Morris, Murat Aydin, Melinda R. Nicewonger, Kimberly A. Casey, Richard B. Alley, Edwin D. Waddington, Nels A. Iverson, Nelia W. Dunbar, Ryan C. Bay, Joseph M. Souney, Michael Sigl, and Joseph R. McConnell
Clim. Past, 15, 1793–1808, https://doi.org/10.5194/cp-15-1793-2019, https://doi.org/10.5194/cp-15-1793-2019, 2019
Short summary
Short summary
A deep ice core was recently drilled at the South Pole to understand past variations in the Earth's climate. To understand the information contained within the ice, we present the relationship between the depth and age of the ice in the South Pole Ice Core. We found that the oldest ice in our record is from 54 302 ± 519 years ago. Our results show that, on average, 7.4 cm of snow falls at the South Pole each year.
Lei Zhu, Daniel J. Jacob, Sebastian D. Eastham, Melissa P. Sulprizio, Xuan Wang, Tomás Sherwen, Mat J. Evans, Qianjie Chen, Becky Alexander, Theodore K. Koenig, Rainer Volkamer, L. Gregory Huey, Michael Le Breton, Thomas J. Bannan, and Carl J. Percival
Atmos. Chem. Phys., 19, 6497–6507, https://doi.org/10.5194/acp-19-6497-2019, https://doi.org/10.5194/acp-19-6497-2019, 2019
Short summary
Short summary
We quantify the effect of sea salt aerosol on tropospheric bromine chemistry with a new mechanistic description of the halogen chemistry in a global atmospheric chemistry model. For the first time, we are able to reproduce the observed levels of bromide activation from the sea salt aerosol in a manner consistent with bromine oxide radical measured from various platforms. Sea salt aerosol plays a far more complex role in global tropospheric chemistry than previously recognized.
Jingyuan Shao, Qianjie Chen, Yuxuan Wang, Xiao Lu, Pengzhen He, Yele Sun, Viral Shah, Randall V. Martin, Sajeev Philip, Shaojie Song, Yue Zhao, Zhouqing Xie, Lin Zhang, and Becky Alexander
Atmos. Chem. Phys., 19, 6107–6123, https://doi.org/10.5194/acp-19-6107-2019, https://doi.org/10.5194/acp-19-6107-2019, 2019
Short summary
Short summary
Sulfate is a key species contributing to particle formation and growth during wintertime Chinese haze events. This study combines observations and modeling of oxygen isotope signatures in sulfate aerosol to investigate its formation mechanisms, with a focus on heterogeneous production on aerosol surface via H2O2, O3, and NO2 and trace metal catalyzed oxidation. Contributions from different formation pathways are presented.
Xuan Wang, Daniel J. Jacob, Sebastian D. Eastham, Melissa P. Sulprizio, Lei Zhu, Qianjie Chen, Becky Alexander, Tomás Sherwen, Mathew J. Evans, Ben H. Lee, Jessica D. Haskins, Felipe D. Lopez-Hilfiker, Joel A. Thornton, Gregory L. Huey, and Hong Liao
Atmos. Chem. Phys., 19, 3981–4003, https://doi.org/10.5194/acp-19-3981-2019, https://doi.org/10.5194/acp-19-3981-2019, 2019
Short summary
Short summary
Chlorine radicals have a broad range of implications for tropospheric chemistry, air quality, and climate. We present a comprehensive simulation of tropospheric chlorine in a global 3-D model, which includes explicit accounting of chloride mobilization from sea salt aerosol. We find the chlorine chemistry contributes 1.0 % of the global oxidation of methane and decreases global burdens of tropospheric ozone by 7 % and OH by 3 % through the associated bromine radical chemistry.
Tommaso Galeazzo, Slimane Bekki, Erwan Martin, Joël Savarino, and Stephen R. Arnold
Atmos. Chem. Phys., 18, 17909–17931, https://doi.org/10.5194/acp-18-17909-2018, https://doi.org/10.5194/acp-18-17909-2018, 2018
Short summary
Short summary
Volcanic sulfur can have climatic impacts for the planet via sulfate aerosol formation, leading also to pollution events. We provide model constraints on tropospheric volcanic sulfate formation, with implications for its lifetime and impacts on regional air quality. Oxygen isotope investigations from our model suggest that in the poor tropospheric plumes of halogens, the O2/TMI sulfur oxidation pathway might significantly control sulfate production. The produced sulfate has no isotopic anomaly.
Shaojie Song, Hélène Angot, Noelle E. Selin, Hubert Gallée, Francesca Sprovieri, Nicola Pirrone, Detlev Helmig, Joël Savarino, Olivier Magand, and Aurélien Dommergue
Atmos. Chem. Phys., 18, 15825–15840, https://doi.org/10.5194/acp-18-15825-2018, https://doi.org/10.5194/acp-18-15825-2018, 2018
Short summary
Short summary
Mercury is a trace metal with adverse health effects on human and wildlife. Its unique property makes it undergo long-range transport, and even remote Antarctica receives significant inputs. This paper presents the first model that aims to understand mercury behavior over the Antarctic Plateau. We find that mercury is quickly cycled between snow and air in the sunlit period, likely driven by bromine chemistry, and that several uncertain processes contribute to its behavior in the dark period.
Qianjie Chen, Tomás Sherwen, Mathew Evans, and Becky Alexander
Atmos. Chem. Phys., 18, 13617–13637, https://doi.org/10.5194/acp-18-13617-2018, https://doi.org/10.5194/acp-18-13617-2018, 2018
Short summary
Short summary
Uncertainty in the natural tropospheric sulfur cycle represents the largest source of uncertainty in radiative forcing estimates of sulfate aerosol. This study investigates the natural sulfur cycle in the marine troposphere using the GEOS-Chem model. We found that BrO is important for DMS oxidation and multiphase chemistry is important for MSA production and loss, which have implications for the yield of SO2 and MSA from DMS oxidation and the radiative effect of DMS-derived sulfate aerosol.
Prasad Kasibhatla, Tomás Sherwen, Mathew J. Evans, Lucy J. Carpenter, Chris Reed, Becky Alexander, Qianjie Chen, Melissa P. Sulprizio, James D. Lee, Katie A. Read, William Bloss, Leigh R. Crilley, William C. Keene, Alexander A. P. Pszenny, and Alma Hodzic
Atmos. Chem. Phys., 18, 11185–11203, https://doi.org/10.5194/acp-18-11185-2018, https://doi.org/10.5194/acp-18-11185-2018, 2018
Short summary
Short summary
Recent measurements of NOx and HONO suggest that photolysis of particulate nitrate in sea-salt aerosols is important in terms of marine boundary layer oxidant chemistry. We present the first global-scale assessment of the significance of this new chemical pathway for NOx, O3, and OH in the marine boundary layer. We also present a preliminary assessment of the potential impact of photolysis of particulate nitrate associated with other aerosol types on continental boundary layer chemistry.
Pengzhen He, Becky Alexander, Lei Geng, Xiyuan Chi, Shidong Fan, Haicong Zhan, Hui Kang, Guangjie Zheng, Yafang Cheng, Hang Su, Cheng Liu, and Zhouqing Xie
Atmos. Chem. Phys., 18, 5515–5528, https://doi.org/10.5194/acp-18-5515-2018, https://doi.org/10.5194/acp-18-5515-2018, 2018
Short summary
Short summary
We use observations of the oxygen isotopic composition of sulfate aerosol as a fingerprint to quantify various sulfate formation mechanisms during pollution events in Beijing, China. We found that heterogeneous reactions on aerosols dominated sulfate production in general; however, in-cloud reactions would dominate haze sulfate production when cloud liquid water content was high. The findings also suggest the heterogeneity of aerosol acidity should be parameterized in models.
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
Short summary
Short summary
We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
Maria Zatko, Joseph Erbland, Joel Savarino, Lei Geng, Lauren Easley, Andrew Schauer, Timothy Bates, Patricia K. Quinn, Bonnie Light, David Morison, Hans D. Osthoff, Seth Lyman, William Neff, Bin Yuan, and Becky Alexander
Atmos. Chem. Phys., 16, 13837–13851, https://doi.org/10.5194/acp-16-13837-2016, https://doi.org/10.5194/acp-16-13837-2016, 2016
Short summary
Short summary
This manuscript presents chemical and optical observations collected in the air and snow during UBWOS2014 in eastern Utah. These observations are used to calculate fluxes of reactive nitrogen associated with snow nitrate photolysis. Snow-sourced reactive nitrogen fluxes are compared to reactive nitrogen emission inventories to find that snow-sourced reactive nitrogen is a minor contributor to the reactive nitrogen budget, and thus wintertime ground-level ozone formation, in the Uintah Basin.
Josué Bock, Joël Savarino, and Ghislain Picard
Atmos. Chem. Phys., 16, 12531–12550, https://doi.org/10.5194/acp-16-12531-2016, https://doi.org/10.5194/acp-16-12531-2016, 2016
Short summary
Short summary
We develop a physically based parameterisation of the co-condensation process. Our model includes solid-state diffusion within a snow grain. It reproduces with good agreement the nitrate measurement in surface snow. Winter and summer concentrations are driven respectively by thermodynamic equilibrium and co-condensation. Adsorbed nitrate likely accounts for a minor part. This work shows that co-condensation is required to explain the chemical composition of snow undergoing temperature gradient.
Qianjie Chen, Lei Geng, Johan A. Schmidt, Zhouqing Xie, Hui Kang, Jordi Dachs, Jihong Cole-Dai, Andrew J. Schauer, Madeline G. Camp, and Becky Alexander
Atmos. Chem. Phys., 16, 11433–11450, https://doi.org/10.5194/acp-16-11433-2016, https://doi.org/10.5194/acp-16-11433-2016, 2016
Short summary
Short summary
The formation mechanisms of sulfate in the marine boundary layer are not well understood, which could result in large uncertainties in aerosol radiative forcing. We measure the oxygen isotopic composition (Δ17O) of sulfate collected in the MBL and analyze with a global transport model. Our results suggest that 33–50 % of MBL sulfate is formed via oxidation of S(IV) by hypohalous acids HOBr / HOCl in the aqueous phase, and the daily-mean HOBr/HOCl concentrations are on the order of 0.01–0.1 ppt.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
Short summary
Short summary
Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
Short summary
Short summary
The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
Michael Sigl, Tyler J. Fudge, Mai Winstrup, Jihong Cole-Dai, David Ferris, Joseph R. McConnell, Ken C. Taylor, Kees C. Welten, Thomas E. Woodruff, Florian Adolphi, Marion Bisiaux, Edward J. Brook, Christo Buizert, Marc W. Caffee, Nelia W. Dunbar, Ross Edwards, Lei Geng, Nels Iverson, Bess Koffman, Lawrence Layman, Olivia J. Maselli, Kenneth McGwire, Raimund Muscheler, Kunihiko Nishiizumi, Daniel R. Pasteris, Rachael H. Rhodes, and Todd A. Sowers
Clim. Past, 12, 769–786, https://doi.org/10.5194/cp-12-769-2016, https://doi.org/10.5194/cp-12-769-2016, 2016
Short summary
Short summary
Here we present a chronology (WD2014) for the upper part (0–2850 m; 31.2 ka BP) of the West Antarctic Ice Sheet (WAIS) Divide ice core, which is based on layer counting of distinctive annual cycles preserved in the elemental, chemical and electrical conductivity records. We validated the chronology by comparing it to independent high-accuracy, absolutely dated chronologies. Given its demonstrated high accuracy, WD2014 can become a reference chronology for the Southern Hemisphere.
Maria Zatko, Lei Geng, Becky Alexander, Eric Sofen, and Katarina Klein
Atmos. Chem. Phys., 16, 2819–2842, https://doi.org/10.5194/acp-16-2819-2016, https://doi.org/10.5194/acp-16-2819-2016, 2016
Short summary
Short summary
We have incorporated an idealized snowpack with a nitrate photolysis parameterization into a global chemical transport model (GEOS-Chem) to examine the implications of snow nitrate photolysis for boundary layer chemistry, the recycling and redistribution of reactive nitrogen, and the preservation of ice-core nitrate in ice cores across Antarctica and Greenland. We also examine the sensitivity of these processes to meteorological parameters and chemical, optical, and physical snow properties.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
Short summary
Short summary
Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
E. Gautier, J. Savarino, J. Erbland, A. Lanciki, and P. Possenti
Clim. Past, 12, 103–113, https://doi.org/10.5194/cp-12-103-2016, https://doi.org/10.5194/cp-12-103-2016, 2016
Short summary
Short summary
We evaluate the local-scale variability of a sulfate profile at a low-accumulation site (Dome C, Antarctica) to assess the representativeness of one ice core for volcanic reconstructions. Peak statistical occurrence, depth and flux variability are evaluated from five cores. Due to local-scale variability, 64 volcanic peaks can be identified by a five-cores analysis, while only half of them can be assessed from two cores. Using five cores, the uncertainty of the mean flux is reduced to 29 %.
J. Erbland, J. Savarino, S. Morin, J. L. France, M. M. Frey, and M. D. King
Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, https://doi.org/10.5194/acp-15-12079-2015, 2015
Short summary
Short summary
In this paper, we describe the development of a numerical model which aims at representing nitrate recycling at the air-snow interface on the East Antarctic Plateau. Stable isotopes are used as diagnostic and evaluation tools by comparing the model's results to recent field measurements of nitrate and key atmospheric species at Dome C, Antarctica. From sensitivity tests conducted with the model, we propose a framework for the interpretation of the nitrate isotope record in deep ice cores.
T. A. Berhanu, J. Savarino, J. Erbland, W. C. Vicars, S. Preunkert, J. F. Martins, and M. S. Johnson
Atmos. Chem. Phys., 15, 11243–11256, https://doi.org/10.5194/acp-15-11243-2015, https://doi.org/10.5194/acp-15-11243-2015, 2015
Short summary
Short summary
In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
P. Achakulwisut, L. J. Mickley, L. T. Murray, A. P. K. Tai, J. O. Kaplan, and B. Alexander
Atmos. Chem. Phys., 15, 7977–7998, https://doi.org/10.5194/acp-15-7977-2015, https://doi.org/10.5194/acp-15-7977-2015, 2015
Short summary
Short summary
The atmosphere’s oxidative capacity determines the lifetime of many trace gases important to climate, chemistry, and human health. Yet uncertainties remain about its past variations, its controlling factors, and the radiative forcing of short-lived species it influences. To reduce these uncertainties, we must better quantify the natural emissions and chemical reaction mechanisms of organic compounds in the atmosphere, which play a role in governing the oxidative capacity.
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
Short summary
Short summary
During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
L. Geng, J. Cole-Dai, B. Alexander, J. Erbland, J. Savarino, A. J. Schauer, E. J. Steig, P. Lin, Q. Fu, and M. C. Zatko
Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, https://doi.org/10.5194/acp-14-13361-2014, 2014
Short summary
Short summary
Examinations on snowpit and firn core results from Summit, Greenland suggest that there are two mechanisms leading to the observed double nitrate peaks in some years in the industrial era: 1) long-rang transport of nitrate and 2) enhanced local photochemical production of nitrate. Both of these mechanisms are related to pollution transport, as the additional nitrate from either direct transport or enhanced local photochemistry requires enhanced nitrogen sources from anthropogenic emissions.
J.-C. Gallet, F. Domine, J. Savarino, M. Dumont, and E. Brun
The Cryosphere, 8, 1205–1215, https://doi.org/10.5194/tc-8-1205-2014, https://doi.org/10.5194/tc-8-1205-2014, 2014
E. D. Sofen, B. Alexander, E. J. Steig, M. H. Thiemens, S. A. Kunasek, H. M. Amos, A. J. Schauer, M. G. Hastings, J. Bautista, T. L. Jackson, L. E. Vogel, J. R. McConnell, D. R. Pasteris, and E. S. Saltzman
Atmos. Chem. Phys., 14, 5749–5769, https://doi.org/10.5194/acp-14-5749-2014, https://doi.org/10.5194/acp-14-5749-2014, 2014
L. T. Murray, L. J. Mickley, J. O. Kaplan, E. D. Sofen, M. Pfeiffer, and B. Alexander
Atmos. Chem. Phys., 14, 3589–3622, https://doi.org/10.5194/acp-14-3589-2014, https://doi.org/10.5194/acp-14-3589-2014, 2014
Related subject area
Subject: Isotopes | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Quantifying the nitrogen isotope effects during photochemical equilibrium between NO and NO2: implications for δ15N in tropospheric reactive nitrogen
Temporal variation in 129I and 127I in aerosols from Xi'an, China: influence of East Asian monsoon and heavy haze events
High time-resolved measurement of stable carbon isotope composition in water-soluble organic aerosols: method optimization and a case study during winter haze in eastern China
Dependence between the photochemical age of light aromatic hydrocarbons and the carbon isotope ratios of atmospheric nitrophenols
Evidence for a major missing source in the global chloromethane budget from stable carbon isotopes
Atmospheric Δ17O(NO3−) reveals nocturnal chemistry dominates nitrate production in Beijing haze
Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl
Stable carbon isotope ratios of ambient aromatic volatile organic compounds
Kinetic isotope effects of 12CH3D + OH and 13CH3D + OH from 278 to 313 K
Investigation of post-depositional processing of nitrate in East Antarctic snow: isotopic constraints on photolytic loss, re-oxidation, and source inputs
Chlorine isotope composition in chlorofluorocarbons CFC-11, CFC-12 and CFC-113 in firn, stratospheric and tropospheric air
NOx cycle and the tropospheric ozone isotope anomaly: an experimental investigation
Fractionation of sulfur isotopes during heterogeneous oxidation of SO2 on sea salt aerosol: a new tool to investigate non-sea salt sulfate production in the marine boundary layer
Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H2O2, O3 and iron catalysis
Molecular hydrogen (H2) emissions and their isotopic signatures (H/D) from a motor vehicle: implications on atmospheric H2
Isotope effect in the formation of H2 from H2CO studied at the atmospheric simulation chamber SAPHIR
Pressure dependence of the deuterium isotope effect in the photolysis of formaldehyde by ultraviolet light
Jianghanyang Li, Xuan Zhang, John Orlando, Geoffrey Tyndall, and Greg Michalski
Atmos. Chem. Phys., 20, 9805–9819, https://doi.org/10.5194/acp-20-9805-2020, https://doi.org/10.5194/acp-20-9805-2020, 2020
Short summary
Short summary
Nitrogen isotopic compositions of atmospheric reactive nitrogen are widely used to infer their sources. However, the reactions between NO and NO2 strongly impact their isotopes, which was not well understood. We conducted a series of experiments in an atmospheric simulation chamber to determine the isotopic effects of (1) direct isotopic exchange between NO and NO2 and (2) the isotopic fractionations during NOx photochemistry, then developed an equation to quantify the overall isotopic effect.
Luyuan Zhang, Xiaolin Hou, Sheng Xu, Tian Feng, Peng Cheng, Yunchong Fu, and Ning Chen
Atmos. Chem. Phys., 20, 2623–2635, https://doi.org/10.5194/acp-20-2623-2020, https://doi.org/10.5194/acp-20-2623-2020, 2020
Short summary
Short summary
To trace the long-range transport of air pollutants and understand the atmospheric effect of iodine, the daily-resolution temporal variations of 129I and 127I in aerosols from a monsoonal city indicate the East Asian monsoon and fossil fuel combustion plays crucial roles on transport of 129I from Europe to East Asia and on elevated 127I concentrations. Through linking iodine isotopes with five major air pollutants, this study proposes the possible role of iodine in urban air pollution.
Wenqi Zhang, Yan-Lin Zhang, Fang Cao, Yankun Xiang, Yuanyuan Zhang, Mengying Bao, Xiaoyan Liu, and Yu-Chi Lin
Atmos. Chem. Phys., 19, 11071–11087, https://doi.org/10.5194/acp-19-11071-2019, https://doi.org/10.5194/acp-19-11071-2019, 2019
Short summary
Short summary
A novel method to determine the concentration and the isotopes of WSOC in aerosols is established and applied in the analysis of a severe haze in eastern China. The results show that the studied site is affected by the photochemical aging, biomass burning and dust aerosols in different episodes during the sampling period. The analysis of WSOC and its isotopes offers a great potential to better understand the source emission, the atmospheric aging and the secondary production of WSOC.
Marina Saccon, Anna Kornilova, Lin Huang, and Jochen Rudolph
Atmos. Chem. Phys., 19, 5495–5509, https://doi.org/10.5194/acp-19-5495-2019, https://doi.org/10.5194/acp-19-5495-2019, 2019
Short summary
Short summary
As compound are emitted into the atmosphere, they can undergo chemical reactions to produce secondary products. This paper investigates the relations of compounds' unique chemical characteristics to the processes that formed them from emissions in the atmosphere. A model is applied to help with this investigation. The complexity of the atmosphere, including mixing of air masses and variability in precursor reactivity, is taken into consideration, and results are presented.
Enno Bahlmann, Frank Keppler, Julian Wittmer, Markus Greule, Heinz Friedrich Schöler, Richard Seifert, and Cornelius Zetzsch
Atmos. Chem. Phys., 19, 1703–1719, https://doi.org/10.5194/acp-19-1703-2019, https://doi.org/10.5194/acp-19-1703-2019, 2019
Short summary
Short summary
Chloromethane is the most important natural carrier of chlorine to the stratosphere. From a newly determined carbon isotope effect of −11.2 ‰ for the tropospheric loss of CH3Cl we derive a tropical rainforest CH3Cl source of 670 ± 200 Gg a−1, 60 % smaller than previous estimates. A revision of previous bottom-up estimates using above-ground biomass instead of rainforest area strongly supports this lower estimate. Our results suggest a large unknown tropical value of 1530 ± 200 Gg a−1.
Pengzhen He, Zhouqing Xie, Xiyuan Chi, Xiawei Yu, Shidong Fan, Hui Kang, Cheng Liu, and Haicong Zhan
Atmos. Chem. Phys., 18, 14465–14476, https://doi.org/10.5194/acp-18-14465-2018, https://doi.org/10.5194/acp-18-14465-2018, 2018
Short summary
Short summary
We present the first observations of the oxygen-17 excess of atmospheric nitrate (Δ17O(NO−3)) collected in Beijing haze to reveal the relative importance of different nitrate formation pathways. We found that nocturnal pathways (N2O5 + H2O/Cl– and NO3 + HC) dominated nitrate production during polluted days (PM2.5 ≥ 75 μg m–3), with a mean possible fraction of 56–97 %.
Frank Keppler, Enno Bahlmann, Markus Greule, Heinz Friedrich Schöler, Julian Wittmer, and Cornelius Zetzsch
Atmos. Chem. Phys., 18, 6625–6635, https://doi.org/10.5194/acp-18-6625-2018, https://doi.org/10.5194/acp-18-6625-2018, 2018
Short summary
Short summary
Chloromethane is involved in stratospheric ozone depletion, but detailed knowledge of its global budget is missing. In this study stable hydrogen isotope analyses were performed to investigate the dominant loss process for atmospheric chloromethane with photochemically produced hydroxyl radicals. The findings might have significant implications for the use of stable isotope signatures in elucidation of global chloromethane cycling.
Anna Kornilova, Lin Huang, Marina Saccon, and Jochen Rudolph
Atmos. Chem. Phys., 16, 11755–11772, https://doi.org/10.5194/acp-16-11755-2016, https://doi.org/10.5194/acp-16-11755-2016, 2016
Short summary
Short summary
The photochemical oxidation of organic compounds in the atmosphere results in the formation of important secondary pollutants such as ozone and fine particles. The extent of oxidation the organic compounds have been subjected too since there emissions is essential is key for understanding the formation of secondary pollutants. This paper demonstrates that measurements of the carbon isotope ratios allow determining the extent of photochemical processing for individual compounds.
L. M. T. Joelsson, J. A. Schmidt, E. J. K. Nilsson, T. Blunier, D. W. T. Griffith, S. Ono, and M. S. Johnson
Atmos. Chem. Phys., 16, 4439–4449, https://doi.org/10.5194/acp-16-4439-2016, https://doi.org/10.5194/acp-16-4439-2016, 2016
Short summary
Short summary
We present experimental kinetic isotope effects (KIE) for the OH oxidation of CH3D and 13CH3D and their temperature dependence. Our determination of the 13CH3D + OH KIE is novel and we find no "clumped" isotope effect within the experimental uncertainty.
G. Shi, A. M. Buffen, M. G. Hastings, C. Li, H. Ma, Y. Li, B. Sun, C. An, and S. Jiang
Atmos. Chem. Phys., 15, 9435–9453, https://doi.org/10.5194/acp-15-9435-2015, https://doi.org/10.5194/acp-15-9435-2015, 2015
Short summary
Short summary
We evaluate isotopic composition of NO3- in different environments across East Antarctica. At high snow accumulation sites, isotopic ratios are suggestive of preservation of NO3- deposition. At low accumulation sites, isotopes are sensitive to both the loss of NO3- due to photolysis and secondary formation of NO3- within the snow. The imprint of post-depositional alteration is not uniform with depth, making it difficult to predict the isotopic composition at depth from near-surface data alone.
S. J. Allin, J. C. Laube, E. Witrant, J. Kaiser, E. McKenna, P. Dennis, R. Mulvaney, E. Capron, P. Martinerie, T. Röckmann, T. Blunier, J. Schwander, P. J. Fraser, R. L. Langenfelds, and W. T. Sturges
Atmos. Chem. Phys., 15, 6867–6877, https://doi.org/10.5194/acp-15-6867-2015, https://doi.org/10.5194/acp-15-6867-2015, 2015
Short summary
Short summary
Stratospheric ozone protects life on Earth from harmful UV-B radiation. Chlorofluorocarbons (CFCs) are man-made compounds which act to destroy this barrier.
This paper presents (1) the first measurements of the stratospheric δ(37Cl) of CFCs -11 and -113; (2) the first quantification of long-term trends in the tropospheric δ(37Cl) of CFCs -11, -12 and -113.
This study provides a better understanding of source and sink processes associated with these destructive compounds.
G. Michalski, S. K. Bhattacharya, and G. Girsch
Atmos. Chem. Phys., 14, 4935–4953, https://doi.org/10.5194/acp-14-4935-2014, https://doi.org/10.5194/acp-14-4935-2014, 2014
E. Harris, B. Sinha, P. Hoppe, S. Foley, and S. Borrmann
Atmos. Chem. Phys., 12, 4619–4631, https://doi.org/10.5194/acp-12-4619-2012, https://doi.org/10.5194/acp-12-4619-2012, 2012
E. Harris, B. Sinha, P. Hoppe, J. N. Crowley, S. Ono, and S. Foley
Atmos. Chem. Phys., 12, 407–423, https://doi.org/10.5194/acp-12-407-2012, https://doi.org/10.5194/acp-12-407-2012, 2012
M. K. Vollmer, S. Walter, S. W. Bond, P. Soltic, and T. Röckmann
Atmos. Chem. Phys., 10, 5707–5718, https://doi.org/10.5194/acp-10-5707-2010, https://doi.org/10.5194/acp-10-5707-2010, 2010
T. Röckmann, S. Walter, B. Bohn, R. Wegener, H. Spahn, T. Brauers, R. Tillmann, E. Schlosser, R. Koppmann, and F. Rohrer
Atmos. Chem. Phys., 10, 5343–5357, https://doi.org/10.5194/acp-10-5343-2010, https://doi.org/10.5194/acp-10-5343-2010, 2010
E. J. K. Nilsson, V. F. Andersen, H. Skov, and M. S. Johnson
Atmos. Chem. Phys., 10, 3455–3462, https://doi.org/10.5194/acp-10-3455-2010, https://doi.org/10.5194/acp-10-3455-2010, 2010
Cited articles
Abbatt, J. P. D., Thomas, J. L., Abrahamsson, K., Boxe, C., Granfors, A., Jones, A. E., King, M. D., Saiz-Lopez, A., Shepson, P. B., Sodeau, J., Toohey, D. W., Toubin, C., von Glasow, R., Wren, S. N., and Yang, X.: Halogen activation via interactions with environmental ice and snow in the polar lower troposphere and other regions, Atmos. Chem. Phys., 12, 6237–6271, https://doi.org/10.5194/acp-12-6237-2012, 2012.
Akers, P. D., Savarino, J., Caillon, N., Servettaz, A. P., Le Meur, E., Magand, O., Martins, J., Agosta, C., Crockford, P., and Kobayashi, K.: Sunlight-driven nitrate loss records Antarctic surface mass balance, Nat. Commun., 13, 4274, https://doi.org/10.1038/s41467-022-31855-7, 2022.
Alexander, B., Sherwen, T., Holmes, C. D., Fisher, J. A., Chen, Q., Evans, M. J., and Kasibhatla, P.: Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations, Atmos. Chem. Phys., 20, 3859–3877, https://doi.org/10.5194/acp-20-3859-2020, 2020.
Andrady, A., Aucamp, P. J., Austin, A. T., Bais, A. F., Ballare, C. L.,
Barnes, P. W., Bernhard, G. H., Bjoern, L. O., Bornman, J. F., and Congdon,
N.: Environmental effects of ozone depletion and its interactions with
climate change: Progress report, 2016, Photoch. Photobio.
Sci., 16, 107, https://doi.org/10.1039/c7pp90001e, 2017.
Archer, C. L. and Caldeira, K.: Historical trends in the jet streams,
Geophys. Res. Lett., 35, L08803, https://doi.org/10.1029/2008GL033614, 2008.
Berhanu, T. A., Meusinger, C., Erbland, J., Jost, R., Bhattacharya, S. K.,
Johnson, M. S., and Savarino, J.: Laboratory study of nitrate photolysis in
Antarctic snow. II. Isotopic effects and wavelength dependence, J.
Chem. Phys., 140, 244306, https://doi.org/10.1063/1.4882899, 2014.
Bitz, C. M. and Polvani, L. M.: Antarctic climate response to stratospheric
ozone depletion in a fine resolution ocean climate model, Geophys.
Res. Lett., 39, L20705, https://doi.org/10.1029/2012gl053393, 2012.
Butchart, N.: The Brewer-Dobson circulation, Rev. Geophys., 52, 157–184, https://doi.org/10.1002/2013RG000448, 2014.
Casey, K. A., Kaspari, S. D., Skiles, S., Kreutz, K., and Handley, M.: The
spectral and chemical measurement of pollutants on snow near South Pole,
Antarctica, J. Geophys. Res.-Atmos., 122, 6592–6610, https://doi.org/10.1002/2016JD026418, 2017.
Chu, L. and Anastasio, C.: Quantum Yields of Hydroxyl Radical and Nitrogen
Dioxide from the Photolysis of Nitrate on Ice, J. Phys.
Chem. A, 107, 9594–9602, https://doi.org/10.1021/jp0349132, 2003.
Cole-Dai, J., Budner, D. M., and Ferris, D. G.: High speed, high resolution,
and continuous chemical analysis of ice cores using a melter and ion
chromatography, Environ. Sci. Technol., 40, 6764–6769, https://doi.org/10.1021/es061188a, 2006.
Cole-Dai, J., Ferris, D. G., Kennedy, J. A., Sigl, M., McConnell, J. R.,
Fudge, T. J., Geng, L., Maselli, O. J., Taylor, K. C., and Souney, J. M.:
Comprehensive Record of Volcanic Eruptions in the Holocene (11,000 years)
From the WAIS Divide, Antarctica Ice Core, J. Geophys. Res.-Atmos., 126,
e2020JD032855, https://doi.org/10.1029/2020JD032855, 2021.
Davis, D., Chen, G., Buhr, M., Crawford, J., Lenschow, D., Lefer, B.,
Shetter, R., Eisele, F., Mauldin, L., and Hogan, A.: South Pole NOx
chemistry: an assessment of factors controlling variability and absolute
levels, Atmos. Environ., 38, 5375–5388, https://doi.org/10.1029/2003JD004300, 2004.
Dibb, J. E. and Fahnestock, M.: Snow accumulation, surface height change,
and firn densification at Summit, Greenland: Insights from 2 years of in
situ observation, J. Geophys. Res.-Atmos., 109, D24113, 2004.
Dominé, F. and Shepson, P. B.: Air-snow interactions and atmospheric
chemistry, Science, 297, 1506–1510, https://doi.org/10.1126/science.1074610, 2002.
Erbland, J., Vicars, W. C., Savarino, J., Morin, S., Frey, M. M., Frosini, D., Vince, E., and Martins, J. M. F.: Air–snow transfer of nitrate on the East Antarctic Plateau – Part 1: Isotopic evidence for a photolytically driven dynamic equilibrium in summer, Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, 2013.
Erbland, J., Savarino, J., Morin, S., France, J. L., Frey, M. M., and King, M. D.: Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records, Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, 2015.
Farman, J. C., Gardiner, B. G., and Shanklin, J. D.: Large losses of total
ozone in Antarctica reveal seasonal ClOx
Ferris, D. G., Cole-Dai, J., Reyes, A. R., and Budner, D. M.: South Pole ice
core record of explosive volcanic eruptions in the first and second
millennia A.D. and evidence of a large eruption in the tropics around 535
A.D, J. Geophys. Res., 116, D17308, https://doi.org/10.1029/2011jd015916, 2011.
Frey, M. M., Savarino, J., Morin, S., Erbland, J., and Martins, J. M. F.: Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling, Atmos. Chem. Phys., 9, 8681–8696, https://doi.org/10.5194/acp-9-8681-2009, 2009.
Frezzotti, M., Scarchilli, C., Becagli, S., Proposito, M., and Urbini, S.: A synthesis of the Antarctic surface mass balance during the last 800 yr, The Cryosphere, 7, 303–319, https://doi.org/10.5194/tc-7-303-2013, 2013.
Gallet, J.-C., Domine, F., Arnaud, L., Picard, G., and Savarino, J.: Vertical profile of the specific surface area and density of the snow at Dome C and on a transect to Dumont D'Urville, Antarctica – albedo calculations and comparison to remote sensing products, The Cryosphere, 5, 631–649, https://doi.org/10.5194/tc-5-631-2011, 2011.
Geng, L.: Isotopes as Tracers of Chemical Reactivity in Snow, in: Chemistry in
the Cryosphere, 503–569, https://doi.org/10.1142/9789811230134_0010, 2022.
Geng, L., Cole-Dai, J., Alexander, B., Erbland, J., Savarino, J., Schauer, A. J., Steig, E. J., Lin, P., Fu, Q., and Zatko, M. C.: On the origin of the occasional spring nitrate peak in Greenland snow, Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, 2014.
Geng, L., Zatko, M. C., Alexander, B., Fudge, T. J., Schauer, A. J., Murray,
L. T., and Mickley, L. J.: Effects of postdepositional processing on
nitrogen isotopes of nitrate in the Greenland Ice Sheet Project 2 ice core,
Geophys. Res. Lett., 42, 5346–5354, https://doi.org/10.1002/2015gl064218, 2015.
Grannas, A. M., Jones, A. E., Dibb, J., Ammann, M., Anastasio, C., Beine, H. J., Bergin, M., Bottenheim, J., Boxe, C. S., Carver, G., Chen, G., Crawford, J. H., Dominé, F., Frey, M. M., Guzmán, M. I., Heard, D. E., Helmig, D., Hoffmann, M. R., Honrath, R. E., Huey, L. G., Hutterli, M., Jacobi, H. W., Klán, P., Lefer, B., McConnell, J., Plane, J., Sander, R., Savarino, J., Shepson, P. B., Simpson, W. R., Sodeau, J. R., von Glasow, R., Weller, R., Wolff, E. W., and Zhu, T.: An overview of snow photochemistry: evidence, mechanisms and impacts, Atmos. Chem. Phys., 7, 4329–4373, https://doi.org/10.5194/acp-7-4329-2007, 2007.
Grooß, J.-U., Brautzsch, K., Pommrich, R., Solomon, S., and Müller, R.: Stratospheric ozone chemistry in the Antarctic: what determines the lowest ozone values reached and their recovery?, Atmos. Chem. Phys., 11, 12217–12226, https://doi.org/10.5194/acp-11-12217-2011, 2011.
Hu, Y. and Fu, Q.: Observed poleward expansion of the Hadley circulation since 1979, Atmos. Chem. Phys., 7, 5229–5236, https://doi.org/10.5194/acp-7-5229-2007, 2007.
Huang, J. and Jaeglé, L.: Wintertime enhancements of sea salt aerosol in polar regions consistent with a sea ice source from blowing snow, Atmos. Chem. Phys., 17, 3699–3712, https://doi.org/10.5194/acp-17-3699-2017, 2017.
Jacob, D. J.: Introduction to atmospheric chemistry, Princeton University
Press, Princeton, https://doi.org/10.1515/9781400841547, 1999.
Jarvis, J. C.: Isotopic studies of ice core nitrate and atmospheric nitrogen
oxides in polar regions, Dissertation, Uinversity of Washington, Seattle,
WA, ISBN 9780549816201, 2008.
Jiang, Z., Alexander, B., Savarino, J., Erbland, J., and Geng, L.: Impacts of the photo-driven post-depositional processing on snow nitrate and its isotopes at Summit, Greenland: a model-based study, The Cryosphere, 15, 4207–4220, https://doi.org/10.5194/tc-15-4207-2021, 2021.
Jiang, Z., Savarino, J., Alexander, B., Erbland, J., Jaffrezo, J.-L., and Geng, L.: Impacts of post-depositional processing on nitrate isotopes in the snow and the overlying atmosphere at Summit, Greenland, The Cryosphere, 16, 2709–2724, https://doi.org/10.5194/tc-16-2709-2022, 2022.
Jones, A. E. and Wolff, E. W.: An analysis of the oxidation potential of the
South Pole boundary layer and the influence of stratospheric ozone
depletion, J. Geophys. Res.-Atmos., 108, 4565, https://doi.org/10.1029/2003jd003379, 2003.
Keeble, J., Braesicke, P., Abraham, N. L., Roscoe, H. K., and Pyle, J. A.: The impact of polar stratospheric ozone loss on Southern Hemisphere stratospheric circulation and climate, Atmos. Chem. Phys., 14, 13705–13717, https://doi.org/10.5194/acp-14-13705-2014, 2014.
Kukui, A., Legrand, M., Preunkert, S., Frey, M. M., Loisil, R., Gil Roca, J., Jourdain, B., King, M. D., France, J. L., and Ancellet, G.: Measurements of OH and RO2 radicals at Dome C, East Antarctica, Atmos. Chem. Phys., 14, 12373–12392, https://doi.org/10.5194/acp-14-12373-2014, 2014.
Lazzara, M., Keller, L., Markle, T., and Gallagher, J.: Fifty-year AmundsenScott South Pole station surface climatology, Atmos. Res., 118, 240259, https://doi.org/10.1016/j.atmosres.2012.06.027, 2012 (data available at: http://amrc.ssec.wisc.edu/usap/southpole/, last access: 12 October 2022).
Libois, Q., Picard, G., France, J. L., Arnaud, L., Dumont, M., Carmagnola, C. M., and King, M. D.: Influence of grain shape on light penetration in snow, The Cryosphere, 7, 1803–1818, https://doi.org/10.5194/tc-7-1803-2013, 2013.
Madronich, S., McKenzie, R. L., Björn, L. O., and Caldwell, M. M.:
Changes in biologically active ultraviolet radiation reaching the Earth's
surface, J. Photoch. Photobio. B, 46, 5–19, https://doi.org/10.1016/s1011-1344(98)00182-1, 1998.
Marshall, G. J. and Bracegirdle, T. J.: An examination of the relationship
between the Southern Annular Mode and Antarctic surface air temperatures in
the CMIP5 historical runs, Clim. Dynam., 45, 1513–1535, https://doi.org/10.1007/s00382-014-2406-z, 2015.
Mauldin, R. L., Kosciuch, E., Henry, B., Eisele, F. L., Shetter, R., Lefer,
B., Chen, G., Davis, D., Huey, G., and Tanner, D.: Measurements of OH,
HO2 +RO2, H2SO4, and MSA at the South Pole during ISCAT 2000, Atmos.
Environ., 38, 5423–5437, https://doi.org/10.1016/j.atmosenv.2004.06.031, 2004.
McCabe, J. R., Boxe, C. S., Colussi, A. J., Hoffmann, M. R., and Thiemens,
M. H.: Oxygen isotopic fractionation in the photochemistry of nitrate in
water and ice, J. Geophys. Res., 110, D15310, https://doi.org/10.1029/2004jd005484,
2005.
McCabe, J. R., Thiemens, M. H., and Savarino, J.: A record of ozone
variability in South Pole Antarctic snow: Role of nitrate oxygen isotopes,
J. Geophys. Res., 112, D12303, https://doi.org/10.1029/2006jd007822, 2007.
McConnell, J. R., Burke, A., Dunbar, N. W., Kohler, P., Thomas, J. L.,
Arienzo, M. M., Chellman, N. J., Maselli, O. J., Sigl, M., Adkins, J. F.,
Baggenstos, D., Burkhart, J. F., Brook, E. J., Buizert, C., Cole-Dai, J.,
Fudge, T. J., Knorr, G., Graf, H. F., Grieman, M. M., Iverson, N., McGwire,
K. C., Mulvaney, R., Paris, G., Rhodes, R. H., Saltzman, E. S.,
Severinghaus, J. P., Steffensen, J. P., Taylor, K. C., and Winckler, G.:
Synchronous volcanic eruptions and abrupt climate change approximately 17.7
ka plausibly linked by stratospheric ozone depletion, P. Natl. Acad. Sci. USA, 114, 10035–10040, https://doi.org/10.1073/pnas.1705595114, 2017.
Meusinger, C., Berhanu, T. A., Erbland, J., Savarino, J., and Johnson, M.
S.: Laboratory study of nitrate photolysis in Antarctic snow. I. Observed
quantum yield, domain of photolysis, and secondary chemistry, J. Chem. Phys.,
140, 244305, https://doi.org/10.1063/1.4882898, 2014.
Van Den Broeke, M. R. and Lipzig, N. P. M. V.: Response of wintertime Antarctic temperatures to the Antarctic Oscillation: Results of a regional climate model, in: Antarctic Peninsula climate variability: historical and paleoenvironmental perspectives, edited by: Domack, E., Levente, A., Burnet, A., Bindschadler, R., Convey, P., and Kirby, M., Cambridge University Press, 43–58, https://doi.org/10.1029/AR079p0043, 2003.
McClure-Begley, A., Petropavlovskikh, I., Oltmans, S., and NOAA ESRL: Earth System Research Laboratory Ozone Water Vapor Group Surface Ozone Measurements, Version 1, NOAA National Centers for Environmental Information [data set], https://doi.org/10.7289/V57P8WBF, 2013.
Ming, A., Winton, V. H. L., Keeble, J., Abraham, N. L., Dalvi, M. C.,
Griffiths, P., Caillon, N., Jones, A. E., Mulvaney, R., Savarino, J., Frey,
M. M., and Yang, X.: Stratospheric Ozone Changes From Explosive Tropical
Volcanoes: Modeling and Ice Core Constraints, J. Geophys.
Res.-Atmos., 125, e2019JD032290, https://doi.org/10.1029/2019jd032290, 2020.
Morin, S., Savarino, J., Bekki, S., Gong, S., and Bottenheim, J. W.: Signature of Arctic surface ozone depletion events in the isotope anomaly (Δ17O) of atmospheric nitrate, Atmos. Chem. Phys., 7, 1451–1469, https://doi.org/10.5194/acp-7-1451-2007, 2007.
Morin, S., Savarino, J., Frey, M. M., Yan, N., Bekki, S., Bottenheim, J. W.,
and Martins, J. M. F.: Tracing the Origin and Fate of NOx in the Arctic
Atmosphere Using Stable Isotopes in Nitrate, Science, 322, 730–732, https://doi.org/10.1126/science.1161910, 2008.
Morin, S., Savarino, J., Frey, M. M., Domine, F., Jacobi, H. W., Kaleschke,
L., and Martins, J. M.: Comprehensive isotopic composition of atmospheric
nitrate in the Atlantic Ocean boundary layer from 65∘ S to 79∘ N, J.
Geophys. Res.-Atmos., 114, D05303, https://doi.org/10.1029/2008JD010696, 2009.
Mosley-Thompson, E., Thompson, L., Paskievitch, J., Pourchet, M., Gow, A.,
Davis, M., and Kleinman, J.: Recent increase in South Pole snow
accumulation, Ann. Glaciol., 21, 131–138, https://doi.org/10.3189/S0260305500015718,
1995.
Müller, R., Grooß, J.-U., Lemmen, C., Heinze, D., Dameris, M., and Bodeker, G.: Simple measures of ozone depletion in the polar stratosphere, Atmos. Chem. Phys., 8, 251–264, https://doi.org/10.5194/acp-8-251-2008, 2008.
Mulvaney, R. and Wolff, E. W.: Evidence for Winter Spring Denitrification of
the Stratosphere in the Nitrate Record of Antarctic Firn Cores, J. Geophys.
Res.-Atmos., 98, 5213–5220, https://doi.org/10.1029/92JD02966, 1993.
Neff, W., Crawford, J., Buhr, M., Nicovich, J., Chen, G., and Davis, D.: The meteorology and chemistry of high nitrogen oxide concentrations in the stable boundary layer at the South Pole, Atmos. Chem. Phys., 18, 3755–3778, https://doi.org/10.5194/acp-18-3755-2018, 2018.
Parish, T. R. and Bromwich, D. H.: Continental-Scale Simulation of the
Antarctic Katabatic Wind Regime, J. Climate, 4, 135–146, https://doi.org/10.1175/1520-0442(1991)004<0135:CSSOTA>2.0.CO;2, 1991.
Parkinson, C. L.: A 40-y record reveals gradual Antarctic sea ice increases
followed by decreases at rates far exceeding the rates seen in the Arctic, P.
Natl. Acad. Sci. USA, 116, 14414–14423, https://doi.org/10.1073/pnas.1906556116, 2019.
Polvani, L. M., Waugh, D. W., Correa, G. J. P., and Son, S.-W.:
Stratospheric Ozone Depletion: The Main Driver of Twentieth-Century
Atmospheric Circulation Changes in the Southern Hemisphere, J.
Climate, 24, 795–812, https://doi.org/10.1175/2010jcli3772.1, 2011.
Previdi, M., Smith, K. L., and Polvani, L. M.: The Antarctic Atmospheric
Energy Budget. Part I: Climatology and Intraseasonal-to-Interannual
Variability, J. Climate, 26, 6406–6418, https://doi.org/10.1175/jcli-d-12-00640.1,
2013.
Savarino, J., Kaiser, J., Morin, S., Sigman, D. M., and Thiemens, M. H.: Nitrogen and oxygen isotopic constraints on the origin of atmospheric nitrate in coastal Antarctica, Atmos. Chem. Phys., 7, 1925–1945, https://doi.org/10.5194/acp-7-1925-2007, 2007.
Shi, G., Hastings, M. G., Yu, J., Ma, T., Hu, Z., An, C., Li, C., Ma, H., Jiang, S., and Li, Y.: Nitrate deposition and preservation in the snowpack along a traverse from coast to the ice sheet summit (Dome A) in East Antarctica, The Cryosphere, 12, 1177–1194, https://doi.org/10.5194/tc-12-1177-2018, 2018.
Shi, G., Hu, Y., Ma, H., Jiang, S., Chen, Z., Hu, Z., An, C., Sun, B., and
Hastings, M. G.: Snow Nitrate Isotopes in Central Antarctica Record the
Prolonged Period of Stratospheric Ozone Depletion From ∼ 1960
to 2000, Geophys. Res. Lett., 49, e2022GL098986,
https://doi.org/10.1029/2022GL098986, 2022.
Sofen, E. D., Alexander, B., Steig, E. J., Thiemens, M. H., Kunasek, S. A., Amos, H. M., Schauer, A. J., Hastings, M. G., Bautista, J., Jackson, T. L., Vogel, L. E., McConnell, J. R., Pasteris, D. R., and Saltzman, E. S.: WAIS Divide ice core suggests sustained changes in the atmospheric formation pathways of sulfate and nitrate since the 19th century in the extratropical Southern Hemisphere, Atmos. Chem. Phys., 14, 5749–5769, https://doi.org/10.5194/acp-14-5749-2014, 2014.
Son, S.-W., Polvani, L. M., Waugh, D. W., Birner, T., Akiyoshi, H., Garcia,
R. R., Gettelman, A., Plummer, D. A., and Rozanov, E.: The impact of
stratospheric ozone recovery on tropopause height trends, J.
Climate, 22, 429–445, https://doi.org/10.1175/2008JCLI2215.1, 2009.
Spolaor, A., Burgay, F., Fernandez, R. P., Turetta, C., Cuevas, C. A., Kim,
K., Kinnison, D. E., Lamarque, J.-F., de Blasi, F., and Barbaro, E.:
Antarctic ozone hole modifies iodine geochemistry on the Antarctic Plateau,
Nat. Commun., 12, 1–9, https://doi.org/10.1038/s41467-021-26109-x, 2021.
Stolarski, R. S., Krueger, A. J., Schoeberl, M. R., McPeters, R. D., Newman,
P. A., and Alpert, J. C.: Nimbus 7 satellite measurements of the springtime
Antarctic ozone decrease, Nature, 322, 808–811, https://doi.org/10.1038/322808a0, 1986.
Thomas, E. R., van Wessem, J. M., Roberts, J., Isaksson, E., Schlosser, E., Fudge, T. J., Vallelonga, P., Medley, B., Lenaerts, J., Bertler, N., van den Broeke, M. R., Dixon, D. A., Frezzotti, M., Stenni, B., Curran, M., and Ekaykin, A. A.: Regional Antarctic snow accumulation over the past 1000 years, Clim. Past, 13, 1491–1513, https://doi.org/10.5194/cp-13-1491-2017, 2017.
Thomas, J. L., Dibb, J. E., Huey, L. G., Liao, J., Tanner, D., Lefer, B., von Glasow, R., and Stutz, J.: Modeling chemistry in and above snow at Summit, Greenland – Part 2: Impact of snowpack chemistry on the oxidation capacity of the boundary layer, Atmos. Chem. Phys., 12, 6537–6554, https://doi.org/10.5194/acp-12-6537-2012, 2012.
Thompson, D. W. J., Solomon, S., Kushner, P. J., England, M. H., Grise, K.
M., and Karoly, D. J.: Signatures of the Antarctic ozone hole in Southern
Hemisphere surface climate change, Nat. Geosci., 4, 741–749, https://doi.org/10.1038/ngeo1296, 2011.
Walters, W. W., Michalski, G., Böhlke, J. K., Alexander, B., Savarino,
J., and Thiemens, M. H.: Assessing the Seasonal Dynamics of Nitrate and
Sulfate Aerosols at the South Pole Utilizing Stable Isotopes, J.
Geophys. Res.-Atmos., 124, 8161–8177, https://doi.org/10.1029/2019jd030517,
2019.
Weller, R., Traufetter, F., Fischer, H., Oerter, H., Piel, C., and Miller,
H.: Postdepositional losses of methane sulfonate, nitrate, and chloride at
the European Project for Ice Coring in Antarctica deep-drilling site in
Dronning Maud Land, Antarctica, J. Geophys. Res.-Atmos., 109, D07301, https://doi.org/10.1029/2003JD004189, 2004.
Winski, D. A., Fudge, T. J., Ferris, D. G., Osterberg, E. C., Fegyveresi, J. M., Cole-Dai, J., Thundercloud, Z., Cox, T. S., Kreutz, K. J., Ortman, N., Buizert, C., Epifanio, J., Brook, E. J., Beaudette, R., Severinghaus, J., Sowers, T., Steig, E. J., Kahle, E. C., Jones, T. R., Morris, V., Aydin, M., Nicewonger, M. R., Casey, K. A., Alley, R. B., Waddington, E. D., Iverson, N. A., Dunbar, N. W., Bay, R. C., Souney, J. M., Sigl, M., and McConnell, J. R.: The SP19 chronology for the South Pole Ice Core – Part 1: volcanic matching and annual layer counting, Clim. Past, 15, 1793–1808, https://doi.org/10.5194/cp-15-1793-2019, 2019.
Winski, D. A., Osterberg, E. C., Kreutz, K. J., Ferris, D. G., Cole-Dai, J.,
Thundercloud, Z., Huang, J., Alexander, B., Jaeglé, L., Kennedy, J. A.,
Larrick, C., Kahle, E. C., Steig, E. J., and Jones, T. R.: Seasonally
Resolved Holocene Sea Ice Variability Inferred From South Pole Ice Core
Chemistry, Geophys. Res. Lett., 48, e2020GL091602,
https://doi.org/10.1029/2020GL091602, 2021.
Winton, V. H. L., Ming, A., Caillon, N., Hauge, L., Jones, A. E., Savarino, J., Yang, X., and Frey, M. M.: Deposition, recycling, and archival of nitrate stable isotopes between the air–snow interface: comparison between Dronning Maud Land and Dome C, Antarctica, Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, 2020.
WMO: WMO Statement on the State of the Global Climate in 2017, World Meteorological Organization (WMO), 1211 Geneva 2, Switzerland, https://library.wmo.int/doc_num.php?explnum_id=4453 (last access: 12 October 2022), 2018.
Wohltmann, I., Lehmann, R., and Rex, M.: A quantitative analysis of the reactions involved in stratospheric ozone depletion in the polar vortex core, Atmos. Chem. Phys., 17, 10535–10563, https://doi.org/10.5194/acp-17-10535-2017, 2017.
Wolff, E. W., Jones, A. E., Martin, T. J., and Grenfell, T. C.: Modelling
photochemical NOx production and nitrate loss in the upper snowpack of
Antarctica, Geophys. Res. Lett., 29, 5-1–5-4,
https://doi.org/10.1029/2002GL015823, 2002.
Yang, X., Pyle, J. A., and Cox, R. A.: Sea salt aerosol production and
bromine release: Role of snow on sea ice, Geophys. Res. Lett., 35, L16815, https://doi.org/10.1029/2008gl034536, 2008.
Zambri, B., Solomon, S., Thompson, D., and Fu, Q.: Emergence of Southern Hemisphere circulation changes in response to ozone recovery, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-22211, https://doi.org/10.5194/egusphere-egu2020-22211, 2020.
Zatko, M., Geng, L., Alexander, B., Sofen, E., and Klein, K.: The impact of snow nitrate photolysis on boundary layer chemistry and the recycling and redistribution of reactive nitrogen across Antarctica and Greenland in a global chemical transport model, Atmos. Chem. Phys., 16, 2819–2842, https://doi.org/10.5194/acp-16-2819-2016, 2016.
Zatko, M. C., Grenfell, T. C., Alexander, B., Doherty, S. J., Thomas, J. L., and Yang, X.: The influence of snow grain size and impurities on the vertical profiles of actinic flux and associated NOx emissions on the Antarctic and Greenland ice sheets, Atmos. Chem. Phys., 13, 3547–3567, https://doi.org/10.5194/acp-13-3547-2013, 2013.
Short summary
We investigate the potential of ice-core preserved nitrate isotopes as proxies of stratospheric ozone variability by measuring nitrate isotopes in a shallow ice core from the South Pole. The large variability in the snow accumulation rate and its slight increase after the 1970s masked any signals caused by the ozone hole. Moreover, the nitrate oxygen isotope decrease may reflect changes in the atmospheric oxidation environment in the Southern Ocean.
We investigate the potential of ice-core preserved nitrate isotopes as proxies of stratospheric...
Altmetrics
Final-revised paper
Preprint