Articles | Volume 22, issue 20
https://doi.org/10.5194/acp-22-13407-2022
https://doi.org/10.5194/acp-22-13407-2022
Research article
 | 
18 Oct 2022
Research article |  | 18 Oct 2022

On the potential fingerprint of the Antarctic ozone hole in ice-core nitrate isotopes: a case study based on a South Pole ice core

Yanzhi Cao, Zhuang Jiang, Becky Alexander, Jihong Cole-Dai, Joel Savarino, Joseph Erbland, and Lei Geng

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Cited articles

Abbatt, J. P. D., Thomas, J. L., Abrahamsson, K., Boxe, C., Granfors, A., Jones, A. E., King, M. D., Saiz-Lopez, A., Shepson, P. B., Sodeau, J., Toohey, D. W., Toubin, C., von Glasow, R., Wren, S. N., and Yang, X.: Halogen activation via interactions with environmental ice and snow in the polar lower troposphere and other regions, Atmos. Chem. Phys., 12, 6237–6271, https://doi.org/10.5194/acp-12-6237-2012, 2012. 
Akers, P. D., Savarino, J., Caillon, N., Servettaz, A. P., Le Meur, E., Magand, O., Martins, J., Agosta, C., Crockford, P., and Kobayashi, K.: Sunlight-driven nitrate loss records Antarctic surface mass balance, Nat. Commun., 13, 4274, https://doi.org/10.1038/s41467-022-31855-7, 2022. 
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We investigate the potential of ice-core preserved nitrate isotopes as proxies of stratospheric ozone variability by measuring nitrate isotopes in a shallow ice core from the South Pole. The large variability in the snow accumulation rate and its slight increase after the 1970s masked any signals caused by the ozone hole. Moreover, the nitrate oxygen isotope decrease may reflect changes in the atmospheric oxidation environment in the Southern Ocean.
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