Articles | Volume 21, issue 11
https://doi.org/10.5194/acp-21-8531-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-8531-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Measurement report
| 
07 Jun 2021
Measurement report |
| 07 Jun 2021
| 07 Jun 2021
Measurement report: Molecular composition, optical properties, and radiative effects of water-soluble organic carbon in snowpack samples from northern Xinjiang, China
Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou 730000, China
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA
Christopher P. West
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA
Anusha P. S. Hettiyadura
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA
Xiaoying Niu
Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou 730000, China
Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou 730000, China
Jiecan Cui
Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou 730000, China
Tenglong Shi
Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou 730000, China
Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou 730000, China
Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou 730000, China
Institute of Surface-Earth System Science, Tianjin University, Tianjin 300072, China
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA
Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, Indiana 47907, USA
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We make the first quantitative, remote-sensing-based, and hemisphere-scale assessment of radiative forcing (RF) due to light-absorbing particles (LAPs) in snow. We observed significant spatial variations in snow albedo reduction and RF due to LAPs throughout the Northern Hemisphere, with the lowest values occurring in the Arctic and the highest in northeastern China. We determined that the LAPs in snow play a critical role in spatial variability in Northern Hemisphere albedo reduction and RF.
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Jay M. Tomlin, Kevin A. Jankowski, Daniel P. Veghte, Swarup China, Peiwen Wang, Matthew Fraund, Johannes Weis, Guangjie Zheng, Yang Wang, Felipe Rivera-Adorno, Shira Raveh-Rubin, Daniel A. Knopf, Jian Wang, Mary K. Gilles, Ryan C. Moffet, and Alexander Laskin
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Analysis of individual atmospheric particles shows that aerosol transported from North America during meteorological dry intrusion episodes may have a substantial impact on the mixing state and particle-type population over the mid-Atlantic, as organic contribution and particle-type diversity are significantly enhanced during these periods. These observations need to be considered in current atmospheric models.
Yang Wang, Guangjie Zheng, Michael P. Jensen, Daniel A. Knopf, Alexander Laskin, Alyssa A. Matthews, David Mechem, Fan Mei, Ryan Moffet, Arthur J. Sedlacek, John E. Shilling, Stephen Springston, Amy Sullivan, Jason Tomlinson, Daniel Veghte, Rodney Weber, Robert Wood, Maria A. Zawadowicz, and Jian Wang
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This paper reports the vertical profiles of trace gas and aerosol properties over the eastern North Atlantic, a region of persistent but diverse subtropical marine boundary layer (MBL) clouds. We examined the key processes that drive the cloud condensation nuclei (CCN) population and how it varies with season and synoptic conditions. This study helps improve the model representation of the aerosol processes in the remote MBL, reducing the simulated aerosol indirect effects.
Wei Pu, Tenglong Shi, Jiecan Cui, Yang Chen, Yue Zhou, and Xin Wang
The Cryosphere, 15, 2255–2272, https://doi.org/10.5194/tc-15-2255-2021, https://doi.org/10.5194/tc-15-2255-2021, 2021
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We have explicitly resolved optical properties of coated BC in snow for explaining complex enhancement of snow albedo reduction due to coating effect in real environments. The parameterizations are developed for climate models to improve the understanding of BC in snow on global climate. We demonstrated that the contribution of BC coating effect to snow light absorption has exceeded dust over north China and will significantly contribute to the retreat of Arctic sea ice and Tibetan glaciers.
Tenglong Shi, Jiecan Cui, Yang Chen, Yue Zhou, Wei Pu, Xuanye Xu, Quanliang Chen, Xuelei Zhang, and Xin Wang
Atmos. Chem. Phys., 21, 6035–6051, https://doi.org/10.5194/acp-21-6035-2021, https://doi.org/10.5194/acp-21-6035-2021, 2021
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We assess the effect of dust external and internal mixing with snow grains on the absorption coefficient and albedo of snowpack. The results suggest that dust–snow internal mixing strongly enhances snow absorption coefficient and albedo reduction relative to external mixing. Meanwhile, the possible non-uniform distribution of dust in snow grains may lead to significantly different values of absorption coefficient and albedo of snowpack in the visible spectral range.
Demetrios Pagonis, Pedro Campuzano-Jost, Hongyu Guo, Douglas A. Day, Melinda K. Schueneman, Wyatt L. Brown, Benjamin A. Nault, Harald Stark, Kyla Siemens, Alex Laskin, Felix Piel, Laura Tomsche, Armin Wisthaler, Matthew M. Coggon, Georgios I. Gkatzelis, Hannah S. Halliday, Jordan E. Krechmer, Richard H. Moore, David S. Thomson, Carsten Warneke, Elizabeth B. Wiggins, and Jose L. Jimenez
Atmos. Meas. Tech., 14, 1545–1559, https://doi.org/10.5194/amt-14-1545-2021, https://doi.org/10.5194/amt-14-1545-2021, 2021
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We describe the airborne deployment of an extractive electrospray time-of-flight mass spectrometer (EESI-MS). The instrument provides a quantitative 1 Hz measurement of the chemical composition of organic aerosol up to altitudes of
7 km, with single-compound detection limits as low as 50 ng per standard cubic meter.
Jiecan Cui, Tenglong Shi, Yue Zhou, Dongyou Wu, Xin Wang, and Wei Pu
Atmos. Chem. Phys., 21, 269–288, https://doi.org/10.5194/acp-21-269-2021, https://doi.org/10.5194/acp-21-269-2021, 2021
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We make the first quantitative, remote-sensing-based, and hemisphere-scale assessment of radiative forcing (RF) due to light-absorbing particles (LAPs) in snow. We observed significant spatial variations in snow albedo reduction and RF due to LAPs throughout the Northern Hemisphere, with the lowest values occurring in the Arctic and the highest in northeastern China. We determined that the LAPs in snow play a critical role in spatial variability in Northern Hemisphere albedo reduction and RF.
Ana C. Morales, Thilina Jayarathne, Jonathan H. Slade, Alexander Laskin, and Paul B. Shepson
Atmos. Chem. Phys., 21, 129–145, https://doi.org/10.5194/acp-21-129-2021, https://doi.org/10.5194/acp-21-129-2021, 2021
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Organic nitrates formed from the oxidation of biogenic volatile organic compounds impact both ozone and particulate matter as they remove nitrogen oxides, but they represent important aerosol precursors. We conducted a series of reaction chamber experiments that quantified the total organic nitrate and secondary organic aerosol yield from the OH-radical-initiated oxidation of ocimene, and also measured their hydrolysis lifetimes in the aqueous phase, as a function of pH.
Matthew Fraund, Daniel J. Bonanno, Swarup China, Don Q. Pham, Daniel Veghte, Johannes Weis, Gourihar Kulkarni, Ken Teske, Mary K. Gilles, Alexander Laskin, and Ryan C. Moffet
Atmos. Chem. Phys., 20, 11593–11606, https://doi.org/10.5194/acp-20-11593-2020, https://doi.org/10.5194/acp-20-11593-2020, 2020
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High viscosity organic particles (HVOPs) in the Southern Great Plains have been analyzed, and two particle types were found. Previously studied tar balls and the recently discovered airborne soil organic particles (ASOPs) are both shown to be brown carbon (BrC). These particle types can be identified in bulk by an absorption Ångström exponent approaching 2.6. HVOP types can be differentiated by comparing carbon absorption spectrum peak ratios between the carboxylic acid, alcohol, and sp2 peaks.
Wei Pu, Zhouxing Zou, Weihao Wang, David Tanner, Zhe Wang, and Tao Wang
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2020-252, https://doi.org/10.5194/amt-2020-252, 2020
Revised manuscript not accepted
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The hydroxyl radical (OH) is responsible for the degradation of trace gases and plays key roles in major environmental issues such as photochemical pollution. However, the measurement of atmospheric OH radical is a huge challenge due to its high reactivity. Our study provides systematic optimization of a chemical ionization mass spectrometer (CIMS) for OH measurement as a reference for other CIMS users. The ambient result demonstrates the capability of the CIMS for ambient OH measurement.
Dandan Zhao, Guangjing Liu, Jinyuan Xin, Jiannong Quan, Yuesi Wang, Xin Wang, Lindong Dai, Wenkang Gao, Guiqian Tang, Bo Hu, Yongxiang Ma, Xiaoyan Wu, Lili Wang, Zirui Liu, and Fangkun Wu
Atmos. Chem. Phys., 20, 4575–4592, https://doi.org/10.5194/acp-20-4575-2020, https://doi.org/10.5194/acp-20-4575-2020, 2020
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Under strong atmospheric oxidization capacity, haze pollution in the summer in Beijing was the result of the synergistic effect of the physicochemical process in the atmospheric boundary layer (ABL). With the premise of an extremely stable ABL structure, the formation of secondary aerosols dominated by nitrate was quite intense, driving the outbreak of haze pollution.
Lauren T. Fleming, Peng Lin, James M. Roberts, Vanessa Selimovic, Robert Yokelson, Julia Laskin, Alexander Laskin, and Sergey A. Nizkorodov
Atmos. Chem. Phys., 20, 1105–1129, https://doi.org/10.5194/acp-20-1105-2020, https://doi.org/10.5194/acp-20-1105-2020, 2020
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We have explored the nature and stability of molecules that give biomass burning smoke its faint brown color. Different types of biomass fuels were burned and the resulting smoke was collected for a detailed chemical analysis. We found that brown molecules in smoke become less colored when they are irradiated by sunlight, but this photobleaching process is very slow. This means that biomass burning smoke will remain brown-colored for a long time and efficiently warm up the atmosphere.
Xin Wang, Xueying Zhang, and Wenjing Di
Atmos. Meas. Tech., 13, 39–52, https://doi.org/10.5194/amt-13-39-2020, https://doi.org/10.5194/amt-13-39-2020, 2020
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We developed an improved two-sphere integration (TSI) technique to quantify black carbon (BC) concentrations in the atmosphere and seasonal snow. The major advantage of this system is that it combines two distinct integrated spheres to reduce the scattering effect due to light-absorbing particles and thus provides accurate determinations of total light absorption from BC collected on Nuclepore filters.
Siqi Ma, Xuelei Zhang, Chao Gao, Daniel Q. Tong, Aijun Xiu, Guangjian Wu, Xinyuan Cao, Ling Huang, Hongmei Zhao, Shichun Zhang, Sergio Ibarra-Espinosa, Xin Wang, Xiaolan Li, and Mo Dan
Geosci. Model Dev., 12, 4603–4625, https://doi.org/10.5194/gmd-12-4603-2019, https://doi.org/10.5194/gmd-12-4603-2019, 2019
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Dust storms are thought to be a worldwide societal issue, and numerical modeling is an effective way to help us to predict dust events. Here we present the first comprehensive evaluation of dust emission modules in four commonly used air quality models for northeastern China. The results showed that most of these models were able to capture this dust event and indicated the dust source maps should be carefully selected or replaced with a new one that is constructed with local data.
Mijung Song, Adrian M. Maclean, Yuanzhou Huang, Natalie R. Smith, Sandra L. Blair, Julia Laskin, Alexander Laskin, Wing-Sy Wong DeRieux, Ying Li, Manabu Shiraiwa, Sergey A. Nizkorodov, and Allan K. Bertram
Atmos. Chem. Phys., 19, 12515–12529, https://doi.org/10.5194/acp-19-12515-2019, https://doi.org/10.5194/acp-19-12515-2019, 2019
Wei Pu, Jiecan Cui, Tenglong Shi, Xuelei Zhang, Cenlin He, and Xin Wang
Atmos. Chem. Phys., 19, 9949–9968, https://doi.org/10.5194/acp-19-9949-2019, https://doi.org/10.5194/acp-19-9949-2019, 2019
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LAPs (light-absorbing particles) deposited on snow can decrease snow albedo and increase the absorption of solar radiation. Radiative forcing by LAPs will affect the regional hydrological cycle and climate. We use MODIS observations to retrieve the radiative forcing by LAPs in snow across northeastern China (NEC). The results of radiative forcing present distinct spatial variability. We find that the biases are negatively correlated with LAP concentrations and range from
~ 5 % to ~ 350 %.
Xin Wang, Hailun Wei, Jun Liu, Baiqing Xu, Mo Wang, Mingxia Ji, and Hongchun Jin
The Cryosphere, 13, 309–324, https://doi.org/10.5194/tc-13-309-2019, https://doi.org/10.5194/tc-13-309-2019, 2019
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A large survey on measuring optical and chemical properties of insoluble light-absorbing impurities (ILAPs) from seven glaciers was conducted on the Tibetan Plateau (TP) during 2013–2015. The results indicated that the mixing ratios of black carbon (BC), organic carbon (OC), and iron (Fe) all showed a tendency to decrease from north to south, and the industrial pollution (33.1 %), biomass and biofuel burning (29.4 %), and soil dust (37.5 %) were the major sources of the ILAPs on the TP.
Victoria E. Irish, Sarah J. Hanna, Megan D. Willis, Swarup China, Jennie L. Thomas, Jeremy J. B. Wentzell, Ana Cirisan, Meng Si, W. Richard Leaitch, Jennifer G. Murphy, Jonathan P. D. Abbatt, Alexander Laskin, Eric Girard, and Allan K. Bertram
Atmos. Chem. Phys., 19, 1027–1039, https://doi.org/10.5194/acp-19-1027-2019, https://doi.org/10.5194/acp-19-1027-2019, 2019
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Ice nucleating particles (INPs) are atmospheric particles that catalyse the formation of ice crystals in clouds. INPs influence the Earth's radiative balance and hydrological cycle. In this study we measured the concentrations of INPs in the Canadian Arctic marine boundary layer. Average INP concentrations fell within the range measured in other marine boundary layer locations. We also found that mineral dust is a more important contributor to the INP population than sea spray aerosol.
Yue Zhou, Hui Wen, Jun Liu, Wei Pu, Qingcai Chen, and Xin Wang
The Cryosphere, 13, 157–175, https://doi.org/10.5194/tc-13-157-2019, https://doi.org/10.5194/tc-13-157-2019, 2019
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We first investigated the optical characteristics and potential sources of chromophoric dissolved organic matter (CDOM) in seasonal snow over northwestern China. The abundance of CDOM showed regional variation. At some sites strongly influenced by local soil, the absorption of CDOM cannot be neglected compared to black carbon. We found two humic-like and one protein-like fluorophores in snow. The major sources of snow CDOM were soil, biomass burning, and anthropogenic pollution.
Chunlin Li, Quanfu He, Julian Schade, Johannes Passig, Ralf Zimmermann, Daphne Meidan, Alexander Laskin, and Yinon Rudich
Atmos. Chem. Phys., 19, 139–163, https://doi.org/10.5194/acp-19-139-2019, https://doi.org/10.5194/acp-19-139-2019, 2019
Zhiyuan Cong, Shaopeng Gao, Wancang Zhao, Xin Wang, Guangming Wu, Yulan Zhang, Shichang Kang, Yongqin Liu, and Junfeng Ji
The Cryosphere, 12, 3177–3186, https://doi.org/10.5194/tc-12-3177-2018, https://doi.org/10.5194/tc-12-3177-2018, 2018
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Cryoconites from glaciers on the Tibetan Plateau and surrounding area were studied for iron oxides. We found that goethite is the predominant iron oxide form. Using the abundance, speciation and optical properties of iron oxides, the total light absorption was quantitatively attributed to goethite, hematite, black carbon and organic matter. Such findings are essential to understand the relative significance of anthropogenic and natural impacts.
Amy L. Bondy, Daniel Bonanno, Ryan C. Moffet, Bingbing Wang, Alexander Laskin, and Andrew P. Ault
Atmos. Chem. Phys., 18, 12595–12612, https://doi.org/10.5194/acp-18-12595-2018, https://doi.org/10.5194/acp-18-12595-2018, 2018
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To determine important sources of aerosols during the Southern Oxidant and Aerosol Study (SOAS), as well as their mixing with secondary species, individual particles were analyzed with electron and X-ray microscopy to determine size and chemical composition. Secondary organic aerosol, sea spray aerosol, and mineral dust each dominated during different periods. Particles were less similar chemically to each other than is commonly assumed, which is important for air quality and climate models.
Wing-Sy Wong DeRieux, Ying Li, Peng Lin, Julia Laskin, Alexander Laskin, Allan K. Bertram, Sergey A. Nizkorodov, and Manabu Shiraiwa
Atmos. Chem. Phys., 18, 6331–6351, https://doi.org/10.5194/acp-18-6331-2018, https://doi.org/10.5194/acp-18-6331-2018, 2018
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The phase transition of organic particles between glassy and semi-solid states occurs at the glass transition temperature. We developed a method to predict glass transition temperatures and the viscosity of secondary organic aerosols using molecular composition, with consistent results with viscosity measurements. The viscosity of biomass burning particles was also estimated using the chemical composition measured by high-resolution mass spectrometry with two different ionization techniques.
Rachel M. Kirpes, Amy L. Bondy, Daniel Bonanno, Ryan C. Moffet, Bingbing Wang, Alexander Laskin, Andrew P. Ault, and Kerri A. Pratt
Atmos. Chem. Phys., 18, 3937–3949, https://doi.org/10.5194/acp-18-3937-2018, https://doi.org/10.5194/acp-18-3937-2018, 2018
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Arctic atmospheric particles have important climate impacts via cloud formation and precipitation, particularly in the wintertime. We show that sulfate, formed during atmospheric transport, is within individual sea spray particles and organic particles measured in the Alaskan Arctic. Greater contributions of combustion emissions were observed when the wind direction came from the Prudhoe Bay oil fields, showing its regional influence.
Lauren T. Fleming, Peng Lin, Alexander Laskin, Julia Laskin, Robert Weltman, Rufus D. Edwards, Narendra K. Arora, Ankit Yadav, Simone Meinardi, Donald R. Blake, Ajay Pillarisetti, Kirk R. Smith, and Sergey A. Nizkorodov
Atmos. Chem. Phys., 18, 2461–2480, https://doi.org/10.5194/acp-18-2461-2018, https://doi.org/10.5194/acp-18-2461-2018, 2018
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Household cooking emissions in India, which rely on traditional meal preparation with dung- and brushwood-fueled cookstoves, produce copious amounts of particulate matter. Detailed chemical analysis of the compounds found in this particulate matter detected a large number of previously unidentified nitrogen-containing organic compounds, originating from dung-fueled cookstoves.
Xin Wang, Hui Wen, Jinsen Shi, Jianrong Bi, Zhongwei Huang, Beidou Zhang, Tian Zhou, Kaiqi Fu, Quanliang Chen, and Jinyuan Xin
Atmos. Chem. Phys., 18, 2119–2138, https://doi.org/10.5194/acp-18-2119-2018, https://doi.org/10.5194/acp-18-2119-2018, 2018
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A ground-based mobile laboratory was deployed near the dust source regions over northwestern China.
We not only captured natural dust but also characterized the properties of anthropogenic soil dust produced by agricultural cultivations.
The results indicate that large differences were found between the optical and microphysical properties of anthropogenic and natural dust.
Mallory L. Hinks, Julia Montoya-Aguilera, Lucas Ellison, Peng Lin, Alexander Laskin, Julia Laskin, Manabu Shiraiwa, Donald Dabdub, and Sergey A. Nizkorodov
Atmos. Chem. Phys., 18, 1643–1652, https://doi.org/10.5194/acp-18-1643-2018, https://doi.org/10.5194/acp-18-1643-2018, 2018
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We have observed a strong effect of relative humidity on the composition of particulate matter produced from the oxidation of toluene in clean air. At higher relative humidity, there was a significant reduction in the fraction of high-molecular-weight compounds present in the particles. The amount of particulate matter also decreased at higher relative humidity. The main implication of this study is that water vapor participates in the photooxidation of toluene in a complicated way.
Ryan D. Cook, Ying-Hsuan Lin, Zhuoyu Peng, Eric Boone, Rosalie K. Chu, James E. Dukett, Matthew J. Gunsch, Wuliang Zhang, Nikola Tolic, Alexander Laskin, and Kerri A. Pratt
Atmos. Chem. Phys., 17, 15167–15180, https://doi.org/10.5194/acp-17-15167-2017, https://doi.org/10.5194/acp-17-15167-2017, 2017
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Reactions occur within water in both atmospheric particles and cloud droplets, yet little is known about the organic compounds in cloud water. In this work, cloud water samples were collected at Whiteface Mountain, New York, and analyzed using ultra-high-resolution mass spectrometry to investigate the molecular composition of the dissolved organic compounds. The results focus on changes in cloud water composition with air mass origin – influences of forest, urban, and wildfire emissions.
Julia Montoya-Aguilera, Jeremy R. Horne, Mallory L. Hinks, Lauren T. Fleming, Véronique Perraud, Peng Lin, Alexander Laskin, Julia Laskin, Donald Dabdub, and Sergey A. Nizkorodov
Atmos. Chem. Phys., 17, 11605–11621, https://doi.org/10.5194/acp-17-11605-2017, https://doi.org/10.5194/acp-17-11605-2017, 2017
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Various plant species emit a chemical compound called indole under stressed conditions or during flowering events. Our experiments show that indole can be oxidized in the atmosphere to produce a brownish haze containing well-known indole-derived dyes, such as indigo dye. An airshed model that includes indole chemistry shows that indole aerosol makes a significant contribution to the total aerosol burden and to visibility.
Yevgeny Derimian, Marie Choël, Yinon Rudich, Karine Deboudt, Oleg Dubovik, Alexander Laskin, Michel Legrand, Bahaiddin Damiri, Ilan Koren, Florin Unga, Myriam Moreau, Meinrat O. Andreae, and Arnon Karnieli
Atmos. Chem. Phys., 17, 11331–11353, https://doi.org/10.5194/acp-17-11331-2017, https://doi.org/10.5194/acp-17-11331-2017, 2017
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We present influence of daily occurrence of the sea breeze flow from the Mediterranean Sea on physicochemical and optical properties of atmospheric aerosol deep inland in the Negev Desert of Israel. Sampled airborne dust was found be internally mixed with sea-salt particles and reacted with anthropogenic pollution, which makes the dust highly hygroscopic and a liquid coating of particles appears. These physicochemical transformations are associated with a change in aerosol radiative properties.
Matthew J. Gunsch, Rachel M. Kirpes, Katheryn R. Kolesar, Tate E. Barrett, Swarup China, Rebecca J. Sheesley, Alexander Laskin, Alfred Wiedensohler, Thomas Tuch, and Kerri A. Pratt
Atmos. Chem. Phys., 17, 10879–10892, https://doi.org/10.5194/acp-17-10879-2017, https://doi.org/10.5194/acp-17-10879-2017, 2017
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Arctic sea ice loss is leading to increasing petroleum extraction and shipping. It is necessary to identify emissions from these activities for improved Arctic air quality and climate assessment. Atmospheric particles were measured from August to September 2015 in Utqiaġvik, AK. For periods influenced by Prudhoe Bay, significant influence associated with combustion emissions was observed, compared to fresh sea spray influence during Arctic Ocean periods.
Jianrong Bi, Jianping Huang, Jinsen Shi, Zhiyuan Hu, Tian Zhou, Guolong Zhang, Zhongwei Huang, Xin Wang, and Hongchun Jin
Atmos. Chem. Phys., 17, 7775–7792, https://doi.org/10.5194/acp-17-7775-2017, https://doi.org/10.5194/acp-17-7775-2017, 2017
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We conducted a field campaign on exploring dust aerosol in Dunhuang farmland nearby Gobi deserts. The anthropogenic dust produced by agricultural cultivations exerted a significant superimposed effect on elevated dust loadings. Strong south wind in daytime scavenged the pollution and weak northeast wind at night favorably accumulated air pollutants near the surface. The local emissions remarkably modified the absorptive and optical characteristics of mineral dust in desert source region.
Ling Qi, Qinbin Li, Cenlin He, Xin Wang, and Jianping Huang
Atmos. Chem. Phys., 17, 7459–7479, https://doi.org/10.5194/acp-17-7459-2017, https://doi.org/10.5194/acp-17-7459-2017, 2017
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Black carbon (BC) is the second only to CO2 in heating the planet, but the simulation of BC is associated with large uncertainties. BC burden is largely underestimated over land and overestimated over ocean. Our study finds that a missing process in current Wegener–Bergeron–Findeisen models largely explains the discrepancy in BC simulation over land. We call for more observations of BC in mixed-phase clouds to understand this process and improve the simulation of global BC.
Wei Pu, Xin Wang, Hailun Wei, Yue Zhou, Jinsen Shi, Zhiyuan Hu, Hongchun Jin, and Quanliang Chen
The Cryosphere, 11, 1213–1233, https://doi.org/10.5194/tc-11-1213-2017, https://doi.org/10.5194/tc-11-1213-2017, 2017
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We conducted a large field campaign to collect snow samples in Xinjiang. We measured insoluble light-absorbing particles with estimated black carbon concentrations of 10–150 ngg-1. We found a probable shift in emission sources with the progression of winter and dominated contributions of BC and OC to light absorption. A PMF model indicated an optimal three-factor/source solution that included industrial pollution, biomass burning, and soil dust.
Xin Wang, Wei Pu, Yong Ren, Xuelei Zhang, Xueying Zhang, Jinsen Shi, Hongchun Jin, Mingkai Dai, and Quanliang Chen
Atmos. Chem. Phys., 17, 2279–2296, https://doi.org/10.5194/acp-17-2279-2017, https://doi.org/10.5194/acp-17-2279-2017, 2017
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A 2014 snow survey was performed across northeastern China to analyze light absorption of ILAPs in seasonal snow, and modeling studies were conducted to compare snow albedo reduction due to assumptions of internal–external mixing of BC in snow and different snow grain shapes. The results show that the simulated snow albedos from both SAMDS and SNICAR agree well with the observed values at low ILAP mixing ratios, but they tend to be higher than surface observations at high ILAP mixing ratios.
Adam P. Bateman, Zhaoheng Gong, Tristan H. Harder, Suzane S. de Sá, Bingbing Wang, Paulo Castillo, Swarup China, Yingjun Liu, Rachel E. O'Brien, Brett B. Palm, Hung-Wei Shiu, Glauber G. Cirino, Ryan Thalman, Kouji Adachi, M. Lizabeth Alexander, Paulo Artaxo, Allan K. Bertram, Peter R. Buseck, Mary K. Gilles, Jose L. Jimenez, Alexander Laskin, Antonio O. Manzi, Arthur Sedlacek, Rodrigo A. F. Souza, Jian Wang, Rahul Zaveri, and Scot T. Martin
Atmos. Chem. Phys., 17, 1759–1773, https://doi.org/10.5194/acp-17-1759-2017, https://doi.org/10.5194/acp-17-1759-2017, 2017
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The occurrence of nonliquid and liquid physical states of submicron atmospheric particulate matter (PM) downwind of an urban region in central Amazonia was investigated. Air masses representing background conditions, urban pollution, and regional- and continental-scale biomass were measured. Anthropogenic influences contributed to the presence of nonliquid PM in the atmospheric particle population, while liquid PM dominated during periods of biogenic influence.
Ryan C. Moffet, Rachel E. O'Brien, Peter A. Alpert, Stephen T. Kelly, Don Q. Pham, Mary K. Gilles, Daniel A. Knopf, and Alexander Laskin
Atmos. Chem. Phys., 16, 14515–14525, https://doi.org/10.5194/acp-16-14515-2016, https://doi.org/10.5194/acp-16-14515-2016, 2016
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Atmospheric black carbon (BC), commonly known as soot, is an important constituent of the earth that imparts a warming similar to that of carbon dioxide. However, BC is much shorter lived and has uncertain warming due to its mixture with other solid and liquid components. Here, advanced microscopic methods have provided a detailed look at thousands of BC particles sampled from central California; these measurements will lead towards a better understanding of the effects that BC has on climate.
Jiumeng Liu, Peng Lin, Alexander Laskin, Julia Laskin, Shawn M. Kathmann, Matthew Wise, Ryan Caylor, Felisha Imholt, Vanessa Selimovic, and John E. Shilling
Atmos. Chem. Phys., 16, 12815–12827, https://doi.org/10.5194/acp-16-12815-2016, https://doi.org/10.5194/acp-16-12815-2016, 2016
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Light absorbing organic aerosols (BrC) absorb sunlight thereby influencing climate; however, understanding of the link between their optical properties and environmental variables remains limited. Our chamber experiment results suggest that variables including NOx concentration, RH level, and photolysis time have considerable influence on secondary BrC optical properties. The results contribute to a more accurate characterization of the impacts of aerosols on climate, especially in urban areas.
Xuelei Zhang, Daniel Q. Tong, Guangjian Wu, Xin Wang, Aijun Xiu, Yongxiang Han, Tianli Xu, Shichun Zhang, and Hongmei Zhao
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2016-681, https://doi.org/10.5194/acp-2016-681, 2016
Revised manuscript has not been submitted
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More detailed knowledge regarding recent variations in the characteristics of East Asian dust events and dust sources can effectively improve regional dust modeling and forecasts. Here we reassess the accuracy of previous predictions of trends in dust variations in East Asia, and establish a relatively detailed inventory of dust events based on satellite observations from 2000 to 2015.
Xuezhe Xu, Weixiong Zhao, Qilei Zhang, Shuo Wang, Bo Fang, Weidong Chen, Dean S. Venables, Xinfeng Wang, Wei Pu, Xin Wang, Xiaoming Gao, and Weijun Zhang
Atmos. Chem. Phys., 16, 6421–6439, https://doi.org/10.5194/acp-16-6421-2016, https://doi.org/10.5194/acp-16-6421-2016, 2016
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We report on the field measurement of the optical properties and chemical composition of PM1.0 particles in a suburban environment in Beijing during the winter coal heating season. Organic mass was the largest contributor to the total extinction of PM1.0, while EC, owing to its high absorption efficiency, contributed appreciably to PM1.0 extinction and should be a key target to air quality controls. Non-BC absorption from secondary organic aerosol also contributes to particle absorption.
Lu Yu, Jeremy Smith, Alexander Laskin, Katheryn M. George, Cort Anastasio, Julia Laskin, Ann M. Dillner, and Qi Zhang
Atmos. Chem. Phys., 16, 4511–4527, https://doi.org/10.5194/acp-16-4511-2016, https://doi.org/10.5194/acp-16-4511-2016, 2016
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The chemical evolution of SOA formed during aqueous reactions of phenolic compounds is studied via combined bulk and molecular analysis. Phenolic SOA evolve dynamically during photochemical aging, with different reaction mechanisms (oligomerization, fragmentation, and functionalization) leading to different generations of products that span an enormous range in volatilities and a large range in oxidation state and composition. Aqueous reactions of phenols are likely an important source of ELVOC.
H. M. Allen, D. C. Draper, B. R. Ayres, A. Ault, A. Bondy, S. Takahama, R. L. Modini, K. Baumann, E. Edgerton, C. Knote, A. Laskin, B. Wang, and J. L. Fry
Atmos. Chem. Phys., 15, 10669–10685, https://doi.org/10.5194/acp-15-10669-2015, https://doi.org/10.5194/acp-15-10669-2015, 2015
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We report ion chromatographic measurements of gas- and aerosol-phase inorganic species at the SOAS 2013 field study. Our particular focus is on inorganic nitrate aerosol formation via HNO3 uptake onto coarse-mode dust and sea salt particles, which we find to be the dominant source of episodic inorganic nitrate at this site, due to the high acidity of the particles preventing formation of NH4NO3. We calculate a production rate of inorganic nitrate aerosol.
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Characterizing lead-rich particles in Beijing's atmosphere following coal-to-gas conversion: insights from single-particle aerosol mass spectrometry
Climatology of aerosol pH and its controlling factors at the Melpitz continental background site in Central Europe
Technical note: Towards a stronger observational support for haze pollution control by interpreting carbonaceous aerosol results derived from different measurement approaches
Particle flux–gradient relationships in the high Arctic: emission and deposition patterns across three surface types
Advances in characterization of black carbon particles and their associated coatings using the soot-particle aerosol mass spectrometer in Singapore, a complex city environment
Iron isotopes suggest significant aerosol dissolution over the Pacific Ocean
Enrichment of organic nitrogen in fog residuals observed in the Italian Po Valley
Asian dust transport of proteinaceous matter from the Gobi Desert to northern China
Machine-learning-assisted chemical characterization and optical properties of atmospheric brown carbon in Nanjing, China
Technical note: Reconstructing missing surface aerosol elemental carbon data in long-term series with ensemble learning
Enhanced emission of intermediate-volatility/semi-volatile organic matter in gas and particle phases from ship exhausts with low-sulfur fuels
Measurement report: Crustal materials play an increasing role in elevating particle pH – insights from 12-year records in a typical inland city of China
Significant contributions of biomass burning to PM2.5-bound aromatic compounds: insights from field observations and quantum chemical calculations
Measurement report: In-depth characterization of ship emissions during operations in a Mediterranean port
Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations
Measurement report: Per- and polyfluoroalkyl substances (PFAS) in particulate matter (PM10) from activated sludge aeration
African dust transported to Barbados in the wintertime lacks indicators of chemical aging
A 60-year atmospheric nitrate isotope record from a southeastern Greenland ice core with minimal postdepositional alteration
Measurement report: Characterization of aerosol hygroscopicity over Southeast Asia during the NASA CAMP2Ex campaign
Long–term Trends in PM2.5 Chemical Composition and Its Impact on Aerosol Properties: Field Observations from 2007 to 2020 in Pearl River Delta, South China
Atmospheric Organosulfate Formation Regulated by Continental Outflows and Marine Emissions over East Asian Marginal Seas
Individual particle compositions and aerosol mixing states at different altitudes over the ocean in East Asia
Molecular characterization of organic aerosols in urban and forested areas of Paris using high-resolution mass spectrometry
Measurement report: Wintertime aerosol characterization at an urban traffic site in Helsinki, Finland
Source apportionment and ecotoxicity of PM2.5 pollution events in a major Southern Hemisphere megacity: influence of a biofuel-impacted fleet and biomass burning
The impacts of pollution sources and temperature on the light absorption of HULIS were revealed by UHPLC-HRMS/MS at the molecular structure level
Effects of Anthropogenic Pollutants on Biogenic Secondary Organic Aerosol Formation in the Atmosphere of Mt. Hua, China
Marine organic aerosol at Mace Head: effects from phytoplankton and source region variability
Elemental composition, iron mineralogy and solubility of anthropogenic and natural mineral dust aerosols in Namibia: a case study analysis from the AEROCLO-sA campaign
Fossil-Dominated SOA Formation in Coastal China: Size-Divergent Pathways of Aqueous Fenton Reactions versus Gas-phase VOC Autoxidation
Measurement report: Sources and meteorology influencing highly time-resolved PM2.5 trace elements at three urban sites in the extremely polluted Indo-Gangetic Plain in India
Measurement report: Year-long chemical composition, optical properties, and sources of atmospheric aerosols in the northeastern Tibetan Plateau
Formation of highly absorptive secondary brown carbon through nighttime multiphase chemistry of biomass burning emissions
Hydroxymethanesulfonate (HMS) Formation under Urban and Marine Atmosphere: role of aerosol ionic strength
The sources and diurnal variations of submicron aerosols in a coastal-rural environment near Houston, US
Measurement report: Vertically resolved atmospheric properties observed over the Southern Great Plains with the ArcticShark uncrewed aerial system
Measurement report: Simultaneous measurement on atmospheric gas- and aerosol-phase water-soluble organics in Shanghai: Remarkable increase in light absorbing of Asian dust aerosols during long-range transport
Unraveling Arctic submicron organic aerosol sources: a year-long study by H-NMR and AMS in Ny-Ålesund, Svalbard
Non-biogenic sources are an important but overlooked contributor to aerosol isoprene-derived organosulfates during winter in northern China
Unveiling single-particle composition, size, shape, and mixing state of freshly emitted Icelandic dust via electron microscopy analysis
The Critical Role of Volatile Organic Compounds Emission in Nitrate Formation in Lhasa, Tibetan Plateau: Insights from Oxygen Isotope Anomaly Measurements
The critical role of aqueous-phase processes in aromatic-derived nitrogen-containing organic aerosol formation in cities with different energy consumption patterns
Characterization of atmospheric water-soluble brown carbon in the Athabasca oil sands region, Canada
Sensitivity of aerosol and cloud properties to coupling strength of marine boundary layer clouds over the northwest Atlantic
Measurement Report: Molecular composition, sources, and evolution of atmospheric organic aerosols in a basin city in China
Burning conditions and transportation pathways determine biomass-burning aerosol properties in the Ascension Island marine boundary layer
Observations of high-time-resolution and size-resolved aerosol chemical composition and microphysics in the central Arctic: implications for climate-relevant particle properties
A critical review of the use of iron isotopes in atmospheric aerosol research
Measurement report: Brown carbon aerosol in rural Germany – sources, chemistry, and diurnal variations
Atmospheric chemistry in East Asia determines the iron solubility of aerosol particles supplied to the North Pacific Ocean
Xiufeng Lian, Yongjiang Xu, Fengxian Liu, Long Peng, Xiaodong Hu, Guigang Tang, Xu Dao, Hui Guo, Liwei Wang, Bo Huang, Chunlei Cheng, Lei Li, Guohua Zhang, Xinhui Bi, Xiaofei Wang, Zhen Zhou, and Mei Li
Atmos. Chem. Phys., 25, 8891–8905, https://doi.org/10.5194/acp-25-8891-2025, https://doi.org/10.5194/acp-25-8891-2025, 2025
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In this study, we analyzed the mixing state and atmospheric chemical processes of Pb-rich single particles in Beijing. We focused on analyzing the differences in Pb-rich particles between the heating period and non-heating period, as well as the formation mechanism of lead nitrate after coal-to-gas conversion. Our results highlighted the improvement of Pb levels in the particulate as a result of coal-to-gas conversion.
Vikram Pratap, Christopher J. Hennigan, Bastian Stieger, Andreas Tilgner, Laurent Poulain, Dominik van Pinxteren, Gerald Spindler, and Hartmut Herrmann
Atmos. Chem. Phys., 25, 8871–8889, https://doi.org/10.5194/acp-25-8871-2025, https://doi.org/10.5194/acp-25-8871-2025, 2025
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In this work, we characterize trends in aerosol pH and its controlling factors during the period 2010–2019 at the Melpitz research station in eastern Germany. We find strong trends in aerosol pH and major inorganic species in response to changing emissions. We conduct a detailed thermodynamic analysis of the aerosol system and discuss implications for controlling particulate matter in the region.
Yuan Cheng, Ying-jie Zhong, Zhi-qing Zhang, Xu-bing Cao, and Jiu-meng Liu
Atmos. Chem. Phys., 25, 8493–8505, https://doi.org/10.5194/acp-25-8493-2025, https://doi.org/10.5194/acp-25-8493-2025, 2025
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As an emerging hotspot of atmospheric sciences, northeastern China is distinct due to the frigid winter and the strong emissions from agricultural fires. Based on field campaigns conducted in Harbin, we successively identified the analytical method that could lead to proper results of organic and elemental carbon. Our results are believed to be a support for future efforts in the exploration of PM2.5 sources in northeastern China, which are essential for further improving the regional air quality.
Theresa Mathes, Heather Guy, John Prytherch, Julia Kojoj, Ian Brooks, Sonja Murto, Paul Zieger, Birgit Wehner, Michael Tjernström, and Andreas Held
Atmos. Chem. Phys., 25, 8455–8474, https://doi.org/10.5194/acp-25-8455-2025, https://doi.org/10.5194/acp-25-8455-2025, 2025
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The Arctic is warming faster than the global average and an investigation of aerosol–cloud–sea ice interactions is crucial for studying its climate system. During the ARTofMELT Expedition 2023, particle and sensible heat fluxes were measured over different surfaces. Wide lead surfaces acted as particle sources, with the strongest sensible heat fluxes, while closed ice surfaces acted as particle sinks. In this study, methods to measure these interactions are improved, enhancing our understanding of Arctic climate processes.
Mutian Ma, Laura-Hélèna Rivellini, Yichen Zong, Markus Kraft, Liya E. Yu, and Alex King Yin Lee
Atmos. Chem. Phys., 25, 8185–8211, https://doi.org/10.5194/acp-25-8185-2025, https://doi.org/10.5194/acp-25-8185-2025, 2025
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This work advances our understanding of the emission and atmospheric evolution of black carbon (BC) particles in Singapore, a complex urban environment impacted by multiple local and regional combustion sources, based on the improved source apportionment analysis of real-time aerosol mass spectrometry measurement.
Capucine Camin, François Lacan, Catherine Pradoux, Marie Labatut, Anne Johansen, and James W. Murray
Atmos. Chem. Phys., 25, 8213–8228, https://doi.org/10.5194/acp-25-8213-2025, https://doi.org/10.5194/acp-25-8213-2025, 2025
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This paper presents the chemical and iron isotopic composition of aerosols (> 1 µm) over the equatorial and tropical Pacific Ocean in previously undocumented areas. Analysis of our data suggests that a significant proportion of aerosol iron (∼ 13 %) is not only dissolved but also removed during atmospheric transport. Such removal had not previously been evidenced to our knowledge. This highlights the unique and strong constraints brought by iron isotopes on atmospheric process studies.
Fredrik Mattsson, Almuth Neuberger, Liine Heikkinen, Yvette Gramlich, Marco Paglione, Matteo Rinaldi, Stefano Decesari, Paul Zieger, Ilona Riipinen, and Claudia Mohr
Atmos. Chem. Phys., 25, 7973–7989, https://doi.org/10.5194/acp-25-7973-2025, https://doi.org/10.5194/acp-25-7973-2025, 2025
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This study investigated aerosol–cloud interactions, focusing on organic nitrogen (ON) formation in the aqueous phase. Measurements were conducted in wintertime in the Po Valley, Italy, using aerosol mass spectrometry. The fog was enriched in more hygroscopic inorganic compounds and ON, containing, e.g., imidazoles. The formation of imidazole by aerosol–fog interactions could be confirmed for the first time in atmospheric observations. Findings highlight the role of fog in nitrogen aerosol formation.
Ren-Guo Zhu, Hua-Yun Xiao, Meiju Yin, Hao Xiao, Zhongkui Zhou, Yuanyuan Pan, Guo Wei, and Cheng Liu
Atmos. Chem. Phys., 25, 7699–7718, https://doi.org/10.5194/acp-25-7699-2025, https://doi.org/10.5194/acp-25-7699-2025, 2025
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The concentrations and δ15N isotopic values of CAAs (combined amino acids) in surface soil and plants from the Gobi Desert, as well as in PM2.5 samples from four cities in Northern China, were measured. CAAs transported by Gobi dust were rich in alanine, glycine and glutamic acid. Glycine and leucine in Gobi Desert sources exhibited δ15N depletion by more than 6 ‰ compared to their values in urban PM2.5. Substantial protein-N deposition can be transported by the Gobi Desert to northern China over brief periods.
Yu Huang, Xingru Li, Dan Dan Huang, Ruoyuan Lei, Binhuang Zhou, Yunjiang Zhang, and Xinlei Ge
Atmos. Chem. Phys., 25, 7619–7645, https://doi.org/10.5194/acp-25-7619-2025, https://doi.org/10.5194/acp-25-7619-2025, 2025
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This work comprises a comprehensive investigation into the chemical and optical properties of brown carbon (BrC) in PM2.5 samples collected in Nanjing, China. In particular, we used a machine learning approach to identify a list of key BrC species, which can be a good reference for future studies. Our findings extend understanding of BrC properties and are valuable to the assessment of BrC's impact on air quality and radiative forcing.
Qingxiao Meng, Yunjiang Zhang, Sheng Zhong, Jie Fang, Lili Tang, Yongcai Rao, Minfeng Zhou, Jian Qiu, Xiaofeng Xu, Jean-Eudes Petit, Olivier Favez, and Xinlei Ge
Atmos. Chem. Phys., 25, 7485–7498, https://doi.org/10.5194/acp-25-7485-2025, https://doi.org/10.5194/acp-25-7485-2025, 2025
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We developed a machine-learning-based method to reconstruct missing elemental carbon (EC) data in four Chinese cities from 2013 to 2023. Using machine learning, we filled data gaps and introduced a new approach to analyze EC trends. Our findings reveal a significant decline in EC due to stricter pollution controls, though this slowed after 2020. This study provides a versatile framework for addressing data gaps and supports strategies to reduce urban air pollution and its climate impacts.
Binyu Xiao, Fan Zhang, Zeyu Liu, Yan Zhang, Rui Li, Can Wu, Xinyi Wan, Yi Wang, Yubao Chen, Yong Han, Min Cui, Libo Zhang, Yingjun Chen, and Gehui Wang
Atmos. Chem. Phys., 25, 7053–7069, https://doi.org/10.5194/acp-25-7053-2025, https://doi.org/10.5194/acp-25-7053-2025, 2025
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Intermediate-volatility/semi-volatile organic compounds in gas and particle phases from ship exhausts are enhanced due to the switch of fuels from low sulfur to ultra-low sulfur. The findings indicate that optimization is necessary for the forthcoming global implementation of an ultra-low-sulfur oil policy. Besides, we find that organic diagnostic markers of hopanes in conjunction with the ratio of octadecanoic to tetradecanoic could be considered potential tracers for heavy fuel oil exhausts.
Hongyu Zhang, Shenbo Wang, Zhangsen Dong, Xiao Li, and Ruiqin Zhang
Atmos. Chem. Phys., 25, 6943–6955, https://doi.org/10.5194/acp-25-6943-2025, https://doi.org/10.5194/acp-25-6943-2025, 2025
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Analyzing 12-year Zhengzhou data revealed post-2019 crustal material rebound caused by soil dust resuspension, elevating particle pH. Similar coarse particle increases are observed across cities of the North China Plain. Long-term particle acidity evolution in this region requires an integrated assessment of interactions among acidic precursors, ammonia, and crustal components.
Yanqin Ren, Zhenhai Wu, Fang Bi, Hong Li, Haijie Zhang, Junling Li, Rui Gao, Fangyun Long, Zhengyang Liu, Yuanyuan Ji, and Gehui Wang
Atmos. Chem. Phys., 25, 6975–6990, https://doi.org/10.5194/acp-25-6975-2025, https://doi.org/10.5194/acp-25-6975-2025, 2025
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The daily concentrations of Polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (OPAHs), and nitrated phenols (NPs) in PM2.5 were all increased during the heating season. Biomass burning was identified to be the primary source of these aromatic compounds, particularly for PAHs. Phenol and nitrobenzene are two main primary precursors for 4NP, with phenol showing lower reaction barriers. P-Cresol was identified as the primary precursor for the formation of 4-methyl-5-nitrocatechol.
Lise Le Berre, Brice Temime-Roussel, Grazia Maria Lanzafame, Barbara D'Anna, Nicolas Marchand, Stéphane Sauvage, Marvin Dufresne, Liselotte Tinel, Thierry Leonardis, Joel Ferreira de Brito, Alexandre Armengaud, Grégory Gille, Ludovic Lanzi, Romain Bourjot, and Henri Wortham
Atmos. Chem. Phys., 25, 6575–6605, https://doi.org/10.5194/acp-25-6575-2025, https://doi.org/10.5194/acp-25-6575-2025, 2025
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A summer campaign in a Mediterranean port examined pollution caused by ships. Two stations in the port measured pollution levels and captured over 350 ship plumes to study their chemical composition. Results showed that pollution levels, such as ultra-fine particles, were higher in the port than in the city and offer strong support to improve emission inventories. These findings may also serve as reference to assess the benefits of a sulfur Emission Control Area in the Mediterranean in 2025.
Jiayin Li, Tianyu Zhai, Xiaorui Chen, Haichao Wang, Shuyang Xie, Shiyi Chen, Chunmeng Li, Yuanjun Gong, Huabin Dong, and Keding Lu
Atmos. Chem. Phys., 25, 6395–6406, https://doi.org/10.5194/acp-25-6395-2025, https://doi.org/10.5194/acp-25-6395-2025, 2025
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We directly measured the dinitrogen pentoxide (N2O5) uptake coefficient using an aerosol flow tube, which critically impacts the NOx fate and particulate nitrate formation in a typical highland city, Kunming, in China. We found that the performance of current γ (N2O5) parameterizations showed deviations with the varying aerosol liquid water content (ALWC). Such differences would lead to biased estimation of particulate nitrate production potential. We give suggestions for future research directions.
Jishnu Pandamkulangara Kizhakkethil, Zongbo Shi, Anna Bogush, and Ivan Kourtchev
Atmos. Chem. Phys., 25, 5947–5958, https://doi.org/10.5194/acp-25-5947-2025, https://doi.org/10.5194/acp-25-5947-2025, 2025
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Pollution with per- and polyfluoroalkyl substances (PFAS) has received attention due to their environmental persistence and bioaccumulation, but their sources remain poorly understood. PM10 (particulate matter) collected above a scaled-down activated sludge tank treating domestic sewage in the UK was analysed for a range of short-, medium-, and long-chain PFAS. Eight PFAS were detected in the PM10. Our results suggest that wastewater treatment processes, i.e. activated sludge aeration, could aerosolise PFAS into airborne PM.
Haley M. Royer, Michael T. Sheridan, Hope E. Elliott, Edmund Blades, Nurun Nahar Lata, Zezhen Cheng, Swarup China, Zihua Zhu, Andrew P. Ault, and Cassandra J. Gaston
Atmos. Chem. Phys., 25, 5743–5759, https://doi.org/10.5194/acp-25-5743-2025, https://doi.org/10.5194/acp-25-5743-2025, 2025
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Saharan dust transported across the Atlantic to the Caribbean, South America, and North America is hypothesized to undergo chemical processing by acids that enhances cloud droplet formation and nutrient availability. In this study, chemical analysis performed on African dust deposited over Barbados shows that acid tracers are found mostly on sea salt and smoke particles, rather than dust, indicating that dust particles undergo minimal chemical processing.
Zhao Wei, Shohei Hattori, Asuka Tsuruta, Zhuang Jiang, Sakiko Ishino, Koji Fujita, Sumito Matoba, Lei Geng, Alexis Lamothe, Ryu Uemura, Naohiro Yoshida, Joel Savarino, and Yoshinori Iizuka
Atmos. Chem. Phys., 25, 5727–5742, https://doi.org/10.5194/acp-25-5727-2025, https://doi.org/10.5194/acp-25-5727-2025, 2025
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Nitrate isotope records in ice cores reveal changes in NOₓ emissions and atmospheric oxidation chemistry driven by human activity. However, UV-driven postdepositional processes can alter nitrate in snow, making snow accumulation rates critical for preserving these records. This study examines nitrate isotopes in a southeastern Greenland ice core, where high snow accumulation minimizes these effects, providing a reliable archive of atmospheric nitrogen cycling.
Genevieve Rose Lorenzo, Luke D. Ziemba, Avelino F. Arellano, Mary C. Barth, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Richard Ferrare, Miguel Ricardo A. Hilario, Michael A. Shook, Simone Tilmes, Jian Wang, Qian Xiao, Jun Zhang, and Armin Sorooshian
Atmos. Chem. Phys., 25, 5469–5495, https://doi.org/10.5194/acp-25-5469-2025, https://doi.org/10.5194/acp-25-5469-2025, 2025
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Novel aerosol hygroscopicity analyses of CAMP2Ex (Cloud, Aerosol, and Monsoon Processes Philippines Experiment) field campaign data show low aerosol hygroscopicity values in Southeast Asia. Organic carbon from smoke decreases hygroscopicity to levels more like those in continental than in polluted marine regions. Hygroscopicity changes at cloud level demonstrate how surface particles impact clouds in the region, affecting model representation of aerosol and cloud interactions in similar polluted marine regions with high organic carbon emissions.
Yunfeng He, Xiang Ding, Quanfu He, Yuqing Zhang, Duohong Chen, Tao Zhang, Kong Yang, Junqi Wang, Qian Cheng, Hao Jiang, Zirui Wang, Ping Liu, Xinming Wang, and Michael Boy
EGUsphere, https://doi.org/10.5194/egusphere-2025-2204, https://doi.org/10.5194/egusphere-2025-2204, 2025
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The long-term field measurements in the Pearl River Delta revealed a significant decline in PM2.5 main components. As air quality improved, secondary species became more dominant. In addition, the proportion of nitrate had doubled. The changes in chemical composition led to the reductions in aerosol acidity, liquid water content and light extinction coefficient. Our results help to improve understanding of the secondary species formation under decreasing anthropogenic emissions.
Shubin Li, Yujue Wang, Yiwen Zhang, Yizhe Yi, Yuchen Wang, Yuqi Guo, Chao Yu, Yue Jiang, Jinhui Shi, Chao Zhang, Jialei Zhu, Wei Hu, Jianzhen Yu, Xiaohong Yao, Huiwang Gao, and Min Hu
EGUsphere, https://doi.org/10.5194/egusphere-2025-2154, https://doi.org/10.5194/egusphere-2025-2154, 2025
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Organosulfates (OSs) are an unrecognized and potentially important component in marine organic aerosols. In this study, we quantified and characterized the OSs over East Asian marginal seas. The chemical nature and spatiotemporal distribution of OSs were modified by the joint influence of marine emissions and transported terrestrial pollutants. The results highlight the vital roles of OSs in shaping organic aerosol formation and sulfur cycle during summer in marine boundary layer.
Kouji Adachi, Atsushi Yoshida, Tatsuhiro Mori, Nobuhiro Moteki, Sho Ohata, Kazuyuki Kita, Yoshimi Kawai, and Makoto Koike
EGUsphere, https://doi.org/10.5194/egusphere-2025-2230, https://doi.org/10.5194/egusphere-2025-2230, 2025
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This study measured the compositions and mixing states of individual aerosol particles collected at different altitudes over the western North Pacific by simultaneous sampling from an aircraft and a research vessel. The results showed that they were strongly influenced by Siberian Forest biomass burning and mixed with sea spray, and identified various aerosol compositions at different altitudes, sizes, and aerosol sources, highlighting a wide range of individual particle compositions.
Diana L. Pereira, Chiara Giorio, Aline Gratien, Alexander Zherebker, Gael Noyalet, Servanne Chevaillier, Stéphanie Alage, Elie Almarj, Antonin Bergé, Thomas Bertin, Mathieu Cazaunau, Patrice Coll, Ludovico Di Antonio, Sergio Harb, Johannes Heuser, Cécile Gaimoz, Oscar Guillemant, Brigitte Language, Olivier Lauret, Camilo Macias, Franck Maisonneuve, Bénédicte Picquet-Varrault, Raquel Torres, Sylvain Triquet, Pascal Zapf, Lelia Hawkins, Drew Pronovost, Sydney Riley, Pierre-Marie Flaud, Emilie Perraudin, Pauline Pouyes, Eric Villenave, Alexandre Albinet, Olivier Favez, Robin Aujay-Plouzeau, Vincent Michoud, Christopher Cantrell, Manuela Cirtog, Claudia Di Biagio, Jean-François Doussin, and Paola Formenti
Atmos. Chem. Phys., 25, 4885–4905, https://doi.org/10.5194/acp-25-4885-2025, https://doi.org/10.5194/acp-25-4885-2025, 2025
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In order to study aerosols in environments influenced by anthropogenic and biogenic emissions, we performed analyses of samples collected during the ACROSS (Atmospheric Chemistry Of the Suburban Forest) campaign in summer 2022 in the greater Paris area. After analysis of the chemical composition by means of total carbon determination and high-resolution mass spectrometry, this work highlights the influence of anthropogenic inputs on the chemical composition of both urban and forested areas.
Kimmo Teinilä, Sanna Saarikoski, Henna Lintusaari, Teemu Lepistö, Petteri Marjanen, Minna Aurela, Heidi Hellén, Toni Tykkä, Markus Lampimäki, Janne Lampilahti, Luis Barreira, Timo Mäkelä, Leena Kangas, Juha Hatakka, Sami Harni, Joel Kuula, Jarkko V. Niemi, Harri Portin, Jaakko Yli-Ojanperä, Ville Niemelä, Milja Jäppi, Katrianne Lehtipalo, Joonas Vanhanen, Liisa Pirjola, Hanna E. Manninen, Tuukka Petäjä, Topi Rönkkö, and Hilkka Timonen
Atmos. Chem. Phys., 25, 4907–4928, https://doi.org/10.5194/acp-25-4907-2025, https://doi.org/10.5194/acp-25-4907-2025, 2025
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Physical and chemical properties of particulate matter and concentrations of trace gases were measured in a street canyon in Helsinki, Finland, and an urban background site in January–February 2022 to investigate the effect of wintertime conditions on pollutants. State-of-the-art instruments and a mobile laboratory were used, and the measurement data were analysed further with modelling tools like positive matrix factorization and the Pollution Detection Algorithm.
Guilherme Martins Pereira, Leonardo Yoshiaki Kamigauti, Rubens Fabio Pereira, Djacinto Monteiro dos Santos, Thayná da Silva Santos, José Vinicius Martins, Célia Alves, Cátia Gonçalves, Ismael Casotti Rienda, Nora Kováts, Thiago Nogueira, Luciana Rizzo, Paulo Artaxo, Regina Maura de Miranda, Marcia Akemi Yamasoe, Edmilson Dias de Freitas, Pérola de Castro Vasconcellos, and Maria de Fatima Andrade
Atmos. Chem. Phys., 25, 4587–4616, https://doi.org/10.5194/acp-25-4587-2025, https://doi.org/10.5194/acp-25-4587-2025, 2025
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The chemical composition of fine particulate matter was studied in the megacity of São Paulo (Brazil) during a polluted period. Vehicular-related sources remain relevant; however, a high contribution of biomass burning was observed and correlated with sample ecotoxicity. Emerging biomass burning sources, such as forest fires and sugarcane-bagasse-based power plants, highlight the need for additional control measures alongside stricter rules concerning vehicular emissions.
Tao Qiu, Yanting Qiu, Yongyi Yuan, Rui Su, Xiangxinyue Meng, Jialiang Ma, Xiaofan Wang, Yu Gu, Zhijun Wu, Yang Ning, Xiuyi Hua, Dapeng Liang, and Deming Dong
EGUsphere, https://doi.org/10.5194/egusphere-2025-1808, https://doi.org/10.5194/egusphere-2025-1808, 2025
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Our research reveals that some species from biomass burning and coal combustion dominate the light absorption of organic aerosols during winter. Cold weather helps these species accumulate in aerosols by slowing their degradation and altering atmospheric chemical processes. This means colder regions might experience stronger and more persistent climate impacts. Our findings highlight the importance of local temperatures and pollution sources when tackling climate challenges.
Can Wu, Yubao Chen, Yuwei Sun, Huijun Zhang, Si Zhang, Cong Cao, Jianjun Li, and Gehui Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-1668, https://doi.org/10.5194/egusphere-2025-1668, 2025
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Biogenic secondary organic aerosol (BSOA), as an important atmospheric component, is prevalent within the boundary layer and can influence air quality and human health. Our observations demonstrate that anthropogenic NOx and the enhanced aerosol water driven by sulfate inhibit BSOA formation in lifting air masses, leading to a moderate reduction in the SOA burden in the upper boundary layer.
Emmanuel Chevassus, Kirsten N. Fossum, Darius Ceburnis, Lu Lei, Chunshui Lin, Wei Xu, Colin O'Dowd, and Jurgita Ovadnevaite
Atmos. Chem. Phys., 25, 4107–4129, https://doi.org/10.5194/acp-25-4107-2025, https://doi.org/10.5194/acp-25-4107-2025, 2025
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This study presents the first source apportionment of organic aerosol at Mace Head via high-resolution mass spectrometry. Introducing transfer entropy as a novel method reveals that aged organic aerosol originates from both open-ocean ozonolysis and local peat-burning oxidation. Methanesulfonic acid and organic sea spray both mirror phytoplankton activity, with the former closely tied to coccolithophore blooms and the latter linked to diatoms, chlorophytes, and cyanobacteria.
Paola Formenti, Chiara Giorio, Karine Desboeufs, Alexander Zherebker, Marco Gaetani, Clarissa Baldo, Gautier Landrot, Simona Montebello, Servanne Chevaillier, Sylvain Triquet, Guillaume Siour, Claudia Di Biagio, Francesco Battaglia, Jean-François Doussin, Anais Feron, Andreas Namwoonde, and Stuart John Piketh
EGUsphere, https://doi.org/10.5194/egusphere-2025-446, https://doi.org/10.5194/egusphere-2025-446, 2025
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The elemental composition and solubility of several metals, including iron, at a coastal site in Namibia in August–September 2017, indicate that natural and anthropogenic dust had different solubility depending on mineralogy but mostly to the processing by fluoride ions from marine emissions, pointing out to the complexity of atmospheric/oceanic interactions in this region of the world influenced by the Benguela current and significant aerosol load.
Jia-Yuan Wang, Meng-Xue Tang, Shan Lu, Ke-Jin Tang, Xing Peng, Ling-Yan He, and Xiao-Feng Huang
EGUsphere, https://doi.org/10.5194/egusphere-2025-1034, https://doi.org/10.5194/egusphere-2025-1034, 2025
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Our study explores how secondary organic aerosols (SOA), a major component of air pollution, form in different particle sizes in a coastal city in China. We found that SOA in fine particles is mainly produced through aqueous chemical reactions, especially those involving iron. In contrast, coarse particles form SOA through reactions with ozone and gases from both fossil fuels and natural sources. These findings highlight the need for size-specific air pollution models.
Ashutosh K. Shukla, Sachchida N. Tripathi, Shamitaksha Talukdar, Vishnu Murari, Sreenivas Gaddamidi, Manousos-Ioannis Manousakas, Vipul Lalchandani, Kuldeep Dixit, Vinayak M. Ruge, Peeyush Khare, Mayank Kumar, Vikram Singh, Neeraj Rastogi, Suresh Tiwari, Atul K. Srivastava, Dilip Ganguly, Kaspar Rudolf Daellenbach, and André S. H. Prévôt
Atmos. Chem. Phys., 25, 3765–3784, https://doi.org/10.5194/acp-25-3765-2025, https://doi.org/10.5194/acp-25-3765-2025, 2025
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Our study delves into the elemental composition of aerosols at three sites across the Indo-Gangetic Plain (IGP), revealing distinct patterns during pollution episodes. We found significant increases in chlorine (Cl)-rich and solid fuel combustion (SFC) sources, indicating dynamic emission sources, agricultural burning impacts, and meteorological influences. Surges in Cl-rich particles during cold periods highlight their role in particle growth under high-relative-humidity conditions.
Kemei Li, Yanqing An, Jianzhong Xu, Miao Zhong, Wenhui Zhao, and Xiang Qin
EGUsphere, https://doi.org/10.5194/egusphere-2025-41, https://doi.org/10.5194/egusphere-2025-41, 2025
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This study presents a year-long PM2.5 study at Waliguan Baseline Observatory in the northeast of the Tibet Plateau to investigate the optical properties of water-soluble brown carbon and its source. Our findings highlight that organic matter, sulfate, and nitrate are the dominant contributors to PM2.5 mass concentrations. Notable seasonal variations in the light absorption capacity of water-soluble brown carbon, accompanied by a high degree of photochemical oxidation are also observed.
Ye Kuang, Biao Luo, Shan Huang, Junwen Liu, Weiwei Hu, Yuwen Peng, Duohong Chen, Dingli Yue, Wanyun Xu, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 25, 3737–3752, https://doi.org/10.5194/acp-25-3737-2025, https://doi.org/10.5194/acp-25-3737-2025, 2025
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This research reveals the potential importance of nighttime NO3 radical chemistry and aerosol water in the rapid formation of secondary brown carbon from diluted biomass burning emissions. The findings enhance our understanding of nighttime biomass burning evolution and its implications for climate and regional air quality, especially regarding interactions with background aerosol water and water-rich fogs and clouds.
Rongshuang Xu, Yu-Chi Lin, Siyu Bian, Feng Xie, and Yan-Lin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2025-683, https://doi.org/10.5194/egusphere-2025-683, 2025
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This work reported the hydroxymethanesulfonate (HMS) level in a continental city and, for the first time, in marine atmosphere. The enhancement by aerosol ionic strength (IS) on HMS formation was quantified which first rise with increasing IS, peaking at 4 mol kg–1 before declining. Given the IS range of marine (2–6) and urban aerosol (6–20 mol kg–1) and the clearly negative correlation between humidity and IS, the moderate IS level under humid condition may notably boost ambient HMS formation.
Jing Li, Jiaoshi Zhang, Xianda Gong, Steven Spielman, Chongai Kuang, Ashish Singh, Maria A. Zawadowicz, Lu Xu, and Jian Wang
EGUsphere, https://doi.org/10.5194/egusphere-2025-726, https://doi.org/10.5194/egusphere-2025-726, 2025
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Using measurements at a rural coastal site, we quantified aerosols in representative air masses and identified major source of organics in Houston area. Our results show cooking aerosol is likely overestimated by earlier studies. Additionally, diurnal variation of highly oxidized organics is mostly driven by air mass changes instead of photochemistry. This study highlights the impacts of emissions, atmospheric chemistry, and meteorology on aerosol properties in the coastal-rural environment.
Fan Mei, Qi Zhang, Damao Zhang, Jerome D. Fast, Gourihar Kulkarni, Mikhail S. Pekour, Christopher R. Niedek, Susanne Glienke, Israel Silber, Beat Schmid, Jason M. Tomlinson, Hardeep S. Mehta, Xena Mansoura, Zezhen Cheng, Gregory W. Vandergrift, Nurun Nahar Lata, Swarup China, and Zihua Zhu
Atmos. Chem. Phys., 25, 3425–3444, https://doi.org/10.5194/acp-25-3425-2025, https://doi.org/10.5194/acp-25-3425-2025, 2025
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This study highlights the unique capability of the ArcticShark, an uncrewed aerial system, in measuring vertically resolved atmospheric properties. Data from 32 research flights in 2023 reveal seasonal patterns and correlations with conventional measurements. The consistency and complementarity of in situ and remote sensing methods are highlighted. The study demonstrates the ArcticShark’s versatility in bridging data gaps and improving the understanding of vertical atmospheric structures.
Zheng Li, Gehui Wang, Binyu Xiao, Rongjie Li, Can Wu, Shaojun Lv, Feng Wu, Qingyan Fu, and Yusen Duan
EGUsphere, https://doi.org/10.5194/egusphere-2025-654, https://doi.org/10.5194/egusphere-2025-654, 2025
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Gas-to-aerosol partitioning of organics were investigated in Shanghai during 2023 dust storm period. We found the partitioning coefficients (Fp) of WSOCs in DS were comparable to those during a haze episode (HE), and aerosol liquid water content primarily drove Fp variation in HE, while pH was the dominant factor in DS. Moreover, an enhanced light absorption of Asian dust by brown carbon, mainly in coarse mode, formation was revealed.
Marco Paglione, Yufang Hao, Stefano Decesari, Mara Russo, Karam Mansour, Mauro Mazzola, Diego Fellin, Andrea Mazzanti, Emilio Tagliavini, Manousos Ioannis Manousakas, Evangelia Diapouli, Elena Barbaro, Matteo Feltracco, Kaspar Rudolf Daellenbach, and Matteo Rinaldi
EGUsphere, https://doi.org/10.5194/egusphere-2025-760, https://doi.org/10.5194/egusphere-2025-760, 2025
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A year-long set of PM1 samples from Ny-Ålesund, Svalbard, was analyzed by H-NMR and HR-TOF-AMS for the chemical characterization of the organic fraction. Positive Matrix Factorization allowed to identify five organic aerosol sources with specific seasonality. Winter-spring aerosol is dominated by Eurasian pollution, while summer is characterized by biogenic aerosols from marine sources; occasional summertime high OA loadings are associated with wildfire aerosols.
Ting Yang, Yu Xu, Yu-Chen Wang, Yi-Jia Ma, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 25, 2967–2978, https://doi.org/10.5194/acp-25-2967-2025, https://doi.org/10.5194/acp-25-2967-2025, 2025
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Previous measurement–model comparisons of atmospheric isoprene levels showed a significant unidentified source of isoprene in some northern Chinese cities during winter. Here, the first combination of large-scale observations and field combustion experiments provides novel insights into biomass burning emissions as a significant source of isoprene-derived organosulfates during winter in northern cities of China.
Agnesh Panta, Konrad Kandler, Kerstin Schepanski, Andres Alastuey, Pavla Dagsson Waldhauserova, Sylvain Dupont, Melanie Eknayan, Cristina González-Flórez, Adolfo González-Romero, Martina Klose, Mara Montag, Xavier Querol, Jesús Yus-Díez, and Carlos Pérez García-Pando
EGUsphere, https://doi.org/10.5194/egusphere-2025-494, https://doi.org/10.5194/egusphere-2025-494, 2025
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Iceland is among the most active dust source areas in the world. Dust properties are influenced by particle size, mineralogy, shape, and mixing state. This work characterizes freshly emitted individual aerosol particles of Icelandic dust using electron microscopy. Our study provides insights into critical particle-specific information will contribute to better constraining climate models that consider mineralogical variations in their representation of the dust cycle.
Xueqin Zheng, Junwen Liu, Nima Chuduo, Bian Ba, Pengfei Yu, Phu Drolgar, Fang Cao, and Yanlin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2025-164, https://doi.org/10.5194/egusphere-2025-164, 2025
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In this study, we present the first report on the annual variation of stable oxygen isotope anomalies (∆17O = δ17O - 0.52 × δ18O) in NO3- collected from the urban area of Lhasa , on the Tibetan Plateau, China. Using a Bayesian isotope mixture model, we found that the relative contribution of the NO3+VOC pathway to NO3- formation in spring in Lhasa was several times higher than in urban cities, highlighting the significant influence of VOC transported from outside the Tibetan Plateau.
Yi-Jia Ma, Yu Xu, Ting Yang, Lin Gui, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 25, 2763–2780, https://doi.org/10.5194/acp-25-2763-2025, https://doi.org/10.5194/acp-25-2763-2025, 2025
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The abundance, potential precursors, and main formation mechanisms of nitrogen-containing organic compounds (NOCs) in PM2.5 during winter were compared among cities with different energy consumption patterns. The aerosol NOC pollution during winter in China is closely associated with the intensity of precursor emissions and the aqueous-phase processes. Our results highlight the importance of emission reduction strategies in controlling aerosol NOCs pollution during winter in China.
Dane Blanchard, Mark Gordon, Duc Huy Dang, Paul Andrew Makar, and Julian Aherne
Atmos. Chem. Phys., 25, 2423–2442, https://doi.org/10.5194/acp-25-2423-2025, https://doi.org/10.5194/acp-25-2423-2025, 2025
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This study offers the first known evaluation of water-soluble brown carbon aerosols in the Athabasca oil sands region (AOSR), Canada. Fluorescence spectroscopy analysis of aerosol samples from five regional sites (collected during the summer of 2021) identified oil sands operations as a measurable brown carbon source. Industrial aerosol emissions were unlikely to impact regional radiative forcing. These findings show that fluorescence spectroscopy can be used to monitor brown carbon in the AOSR.
Kira Zeider, Kayla McCauley, Sanja Dmitrovic, Leong Wai Siu, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Simon Kirschler, John B. Nowak, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, Paquita Zuidema, and Armin Sorooshian
Atmos. Chem. Phys., 25, 2407–2422, https://doi.org/10.5194/acp-25-2407-2025, https://doi.org/10.5194/acp-25-2407-2025, 2025
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In situ aircraft data collected over the northwest Atlantic Ocean are utilized to compare aerosol conditions and turbulence between near-surface and below-cloud-base altitudes for different regimes of coupling strength between those two levels, along with how cloud microphysical properties vary across those regimes. Stronger coupling yields more homogenous aerosol structure vertically along with higher cloud drop concentrations and sea salt influence in clouds.
Junke Zhang, Xinyi Fu, Chunying Chen, Yunfei Su, Siyu Liu, Luyao Chen, Yubao Chen, Gehui Wang, and Andre S. H. Prevot
EGUsphere, https://doi.org/10.5194/egusphere-2025-92, https://doi.org/10.5194/egusphere-2025-92, 2025
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The 125 organic aerosol (OA) compounds in PM2.5 in winter in Chengdu were measured at the molecular level. OA was dominated by fatty acids, phthalate esters, and anhydrosugars, and were deeply influenced by anthropogenic sources. As pollution worsens: secondary inorganic species and secondary organic carbon (OC) dominated the increase in PM2.5; fatty acids and anhydrosugars dominated the increase in OA; and the contribution of secondary formation and biomass burning to OC increased markedly.
Amie Dobracki, Ernie R. Lewis, Arthur J. Sedlacek III, Tyler Tatro, Maria A. Zawadowicz, and Paquita Zuidema
Atmos. Chem. Phys., 25, 2333–2363, https://doi.org/10.5194/acp-25-2333-2025, https://doi.org/10.5194/acp-25-2333-2025, 2025
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Biomass-burning aerosol is commonly present in the marine boundary layer over the southeast Atlantic Ocean between June and October. Our research indicates that burning conditions, aerosol transport pathways, and prolonged oxidation processes (heterogeneous and aqueous phases) determine the chemical, microphysical, and optical properties of the boundary layer aerosol. Notably, we find that the aerosol optical properties can be estimated from the chemical properties alone.
Benjamin Heutte, Nora Bergner, Hélène Angot, Jakob B. Pernov, Lubna Dada, Jessica A. Mirrielees, Ivo Beck, Andrea Baccarini, Matthew Boyer, Jessie M. Creamean, Kaspar R. Daellenbach, Imad El Haddad, Markus M. Frey, Silvia Henning, Tiia Laurila, Vaios Moschos, Tuukka Petäjä, Kerri A. Pratt, Lauriane L. J. Quéléver, Matthew D. Shupe, Paul Zieger, Tuija Jokinen, and Julia Schmale
Atmos. Chem. Phys., 25, 2207–2241, https://doi.org/10.5194/acp-25-2207-2025, https://doi.org/10.5194/acp-25-2207-2025, 2025
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Limited aerosol measurements in the central Arctic hinder our understanding of aerosol–climate interactions in the region. Our year-long observations of aerosol physicochemical properties during the MOSAiC expedition reveal strong seasonal variations in aerosol chemical composition, where the short-term variability is heavily affected by storms in the Arctic. Local wind-generated particles are shown to be an important source of cloud seeds, especially in autumn.
Yifan Zhang, Rui Li, Zachary B. Bunnell, Yizhu Chen, Guanhong Zhu, Jinlong Ma, Guohua Zhang, Tim M. Conway, and Mingjin Tang
EGUsphere, https://doi.org/10.5194/egusphere-2025-474, https://doi.org/10.5194/egusphere-2025-474, 2025
Short summary
Short summary
The sources of aerosol Fe, especially soluble aerosol Fe, remain to be constrained. The stable isotope ratio of Fe (δ56Fe) has emerged as a potential tracer for discriminating and quantifying sources of aerosol Fe. In this review, we examine the state of the field for using δ56Fe as an aerosol source tracer, and constraints on endmember signatures.
Feng Jiang, Harald Saathoff, Uzoamaka Ezenobi, Junwei Song, Hengheng Zhang, Linyu Gao, and Thomas Leisner
Atmos. Chem. Phys., 25, 1917–1930, https://doi.org/10.5194/acp-25-1917-2025, https://doi.org/10.5194/acp-25-1917-2025, 2025
Short summary
Short summary
The chemical composition of brown carbon in the particle and gas phase was determined by mass spectrometry. BrC in the gas phase was mainly controlled by secondary formation and particle-to-gas partitioning. BrC in the particle phase was mainly from secondary formation. This work helps to get a better understanding of diurnal variations and the sources of brown carbon aerosol at a rural location in central Europe.
Kohei Sakata, Shotaro Takano, Atsushi Matsuki, Yasuo Takeichi, Hiroshi Tanimoto, Aya Sakaguchi, Minako Kurisu, and Yoshio Takahashi
EGUsphere, https://doi.org/10.5194/egusphere-2025-161, https://doi.org/10.5194/egusphere-2025-161, 2025
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Short summary
Deposition of aerosol iron (Fe) into the ocean stimulates primary production and influences the global carbon cycle, although the factors governing the aerosol Fe solubility remain uncertain. Our observations in Japan revealed that both mineral dust and anthropogenic aerosols are significant sources of dissolved Fe, and that atmospheric chemical weathering enhances their solubility. This finding is expected to play a crucial role in estimating the supply of dissolved iron to the ocean.
Cited articles
Amoroso, A., Domine, F., Esposito, G., Morin, S., Savarino, J., Nardino, M., Montagnoli, M., Bonneville, J. M., Clement, J. C., Ianniello, A., and Beine, H. J.:
Microorganisms in Dry Polar Snow Are Involved in the Exchanges of Reactive Nitrogen Species with the Atmosphere,
Environ. Sci. Technol.,
44, 714–719, https://doi.org/10.1021/es9027309, 2010.
Anastasio, C. and Robles, T.:
Light absorption by soluble chemical species in Arctic and Antarctic snow,
J. Geophys. Res.-Atmos.,
112, D24304, https://doi.org/10.1029/2007JD008695, 2007.
Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006.
Antony, R., Grannas, A. M., Willoughby, A. S., Sleighter, R. L., Thamban, M., and Hatcher, P. G.:
Origin and Sources of Dissolved Organic Matter in Snow on the East Antarctic Ice Sheet,
Environ. Sci. Technol.,
48, 6151–6159, https://doi.org/10.1021/es405246a, 2014.
Antony, R., Willoughby, A. S., Grannas, A. M., Catanzano, V., Sleighter, R. L., Thamban, M., Hatcher, P. G., and Nair, S.:
Molecular Insights on Dissolved Organic Matter Transformation by Supraglacial Microbial Communities,
Environ. Sci. Technol.,
51, 4328–4337, https://doi.org/10.1021/acs.est.6b05780, 2017.
Bandowe, B. A., Meusel, H., Huang, R., Hoffmann, T., Cao, J., and Ho, K.:
Azaarenes in fine particulate matter from the atmosphere of a Chinese megacity,
Environ. Sci. Pollut. Res. Int.,
23, 16025–16036, https://doi.org/10.1007/s11356-016-6740-z, 2016.
Bandowe, B. A. M. and Meusel, H.:
Nitrated polycyclic aromatic hydrocarbons (nitro-PAHs) in the environment – A review,
Sci. Total Environ.,
581–582, 237–257, https://doi.org/10.1016/j.scitotenv.2016.12.115, 2017.
Beine, H., Anastasio, C., Esposito, G., Patten, K., Wilkening, E., Domine, F., Voisin, D., Barret, M., Houdier, S., and Hall, S.:
Soluble, light-absorbing species in snow at Barrow, Alaska,
J. Geophys. Res.-Atmos.,
116, D00R05, https://doi.org/10.1029/2011jd016181, 2011.
Beres, N. D., Sengupta, D., Samburova, V., Khlystov, A. Y., and Moosmüller, H.: Deposition of brown carbon onto snow: changes in snow optical and radiative properties, Atmos. Chem. Phys., 20, 6095–6114, https://doi.org/10.5194/acp-20-6095-2020, 2020.
Bhatia, M. P., Das, S. B., Longnecker, K., Charette, M. A., and Kujawinski, E. B.:
Molecular characterization of dissolved organic matter associated with the Greenland ice sheet,
Geochim. Cosmochim. Ac.,
74, 3768–3784, https://doi.org/10.1016/j.gca.2010.03.035, 2010.
Bianco, A., Deguillaume, L., Vaitilingom, M., Nicol, E., Baray, J. L., Chaumerliac, N., and Bridoux, M.:
Molecular Characterization of Cloud Water Samples Collected at the Puy de Dome (France) by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry,
Environ. Sci. Technol.,
52, 10275–10285, https://doi.org/10.1021/acs.est.8b01964, 2018.
Birdwell, J. E. and Valsaraj, K. T.:
Characterization of dissolved organic matter in fogwater by excitation–emission matrix fluorescence spectroscopy,
Atmos. Environ.,
44, 3246–3253, https://doi.org/10.1016/j.atmosenv.2010.05.055, 2010.
Bond, T. C. and Bergstrom, R. W.:
Light absorption by carbonaceous particles: An investigative review,
Aerosol Sci. Tech.,
40, 27–67, https://doi.org/10.1080/02786820500421521, 2006.
Bond, T. C., Doherty, S. J., Fahey, D. W., Forster, P. M., Berntsen, T., DeAngelo, B. J., Flanner, M. G., Ghan, S., Karcher, B., Koch, D., Kinne, S., Kondo, Y., Quinn, P. K., Sarofim, M. C., Schultz, M. G., Schulz, M., Venkataraman, C., Zhang, H., Zhang, S., Bellouin, N., Guttikunda, S. K., Hopke, P. K., Jacobson, M. Z., Kaiser, J. W., Klimont, Z., Lohmann, U., Schwarz, J. P., Shindell, D., Storelvmo, T., Warren, S. G., and Zender, C. S.:
Bounding the role of black carbon in the climate system: A scientific assessment,
J. Geophys. Res.-Atmos.,
118, 5380–5552, https://doi.org/10.1002/jgrd.50171, 2013.
Brutel-Vuilmet, C., Ménégoz, M., and Krinner, G.: An analysis of present and future seasonal Northern Hemisphere land snow cover simulated by CMIP5 coupled climate models, The Cryosphere, 7, 67–80, https://doi.org/10.5194/tc-7-67-2013, 2013.
Cain, J., Laskin, A., Kholghy, M. R., Thomson, M. J., and Wang, H.:
Molecular characterization of organic content of soot along the centerline of a coflow diffusion flame,
Phys. Chem. Chem. Phys.,
16, 25862–25875, https://doi.org/10.1039/c4cp03330b, 2014.
Cech, N. B. and Enke, C. G.:
Practical implications of some recent studies in electrospray ionization fundamentals,
Mass Spectrom. Rev.,
20, 362–387, https://doi.org/10.1002/mas.10008, 2001.
Chen, Q., Mu, Z., Song, W., Wang, Y., Yang, Z., Zhang, L., and Zhang, Y. L.:
Size-Resolved Characterization of the Chromophores in Atmospheric Particulate Matter From a Typical Coal-Burning City in China,
J. Geophys. Res.-Atmos.,
124, 10546–10563, https://doi.org/10.1029/2019jd031149, 2019.
Chen, Q., Li, J., Hua, X., Jiang, X., Mu, Z., Wang, M., Wang, J., Shan, M., Yang, X., Fan, X., Song, J., Wang, Y., Guan, D., and Du, L.:
Identification of species and sources of atmospheric chromophores by fluorescence excitation–emission matrix with parallel factor analysis,
Sci. Total Environ.,
718, 137322, https://doi.org/10.1016/j.scitotenv.2020.137322, 2020.
Chen, Q. C., Ikemori, F., and Mochida, M.:
Light Absorption and Excitation–Emission Fluorescence of Urban Organic Aerosol Components and Their Relationship to Chemical Structure,
Environ. Sci. Technol.,
50, 10859–10868, https://doi.org/10.1021/acs.est.6b02541, 2016a.
Chen, Q. C., Miyazaki, Y., Kawamura, K., Matsumoto, K., Coburn, S., Volkamer, R., Iwamoto, Y., Kagami, S., Deng, Y. G., Ogawa, S., Ramasamy, S., Kato, S., Ida, A., Kajii, Y., and Mochida, M.:
Characterization of Chromophoric Water-Soluble Organic Matter in Urban, Forest, and Marine Aerosols by HR-ToF-AMS Analysis and Excitation Emission Matrix Spectroscopy,
Environ. Sci. Technol.,
50, 10351–10360, https://doi.org/10.1021/acs.est.6b01643, 2016b.
Chen, Y. and Bond, T. C.: Light absorption by organic carbon from wood combustion, Atmos. Chem. Phys., 10, 1773–1787, https://doi.org/10.5194/acp-10-1773-2010, 2010.
Coble, P. G.:
Characterization of marine and terrestrial DOM in seawater using excitation emission matrix spectroscopy,
Mar. Chem.,
51, 325–346, https://doi.org/10.1016/0304-4203(95)00062-3, 1996.
Coble, P. G., Del Castillo, C. E., and Avril, B.:
Distribution and optical properties of CDOM in the Arabian Sea during the 1995 Southwest Monsoon,
Deep-Sea Res. Pt. II,
45, 2195–2223, https://doi.org/10.1016/S0967-0645(98)00068-X, 1998.
Cook, J. M., Hodson, A. J., Gardner, A. S., Flanner, M., Tedstone, A. J., Williamson, C., Irvine-Fynn, T. D. L., Nilsson, J., Bryant, R., and Tranter, M.: Quantifying bioalbedo: a new physically based model and discussion of empirical methods for characterising biological influence on ice and snow albedo, The Cryosphere, 11, 2611–2632, https://doi.org/10.5194/tc-11-2611-2017, 2017a.
Cook, J. M., Hodson, A. J., Taggart, A. J., Mernild, S. H., and Tranter, M.:
A predictive model for the spectral ”bioalbedo” of snow,
J. Geophys. Res.-Earth,
122, 434–454, https://doi.org/10.1002/2016JF003932, 2017b.
DiDonato, N., Chen, H., Waggoner, D., and Hatcher, P. G.:
Potential origin and formation for molecular components of humic acids in soils,
Geochim. Cosmochim. Ac.,
178, 210–222, https://doi.org/10.1016/j.gca.2016.01.013, 2016.
Doherty, S. J., Warren, S. G., Grenfell, T. C., Clarke, A. D., and Brandt, R. E.: Light-absorbing impurities in Arctic snow, Atmos. Chem. Phys., 10, 11647–11680, https://doi.org/10.5194/acp-10-11647-2010, 2010.
Duarte, R. M. B. O., Santos, E. B. H., Pio, C. A., and Duarte, A. C.:
Comparison of structural features of water-soluble organic matter from atmospheric aerosols with those of aquatic humic substances,
Atmos. Environ.,
41, 8100–8113, https://doi.org/10.1016/j.atmosenv.2007.06.034, 2007.
Duval, J., Pecher, V., Poujol, M., and Lesellier, E.:
Research advances for the extraction, analysis and uses of anthraquinones: A review,
Ind. Crop. Prod.,
94, 812–833, https://doi.org/10.1016/j.indcrop.2016.09.056, 2016.
Elliott, A., Mundy, C. J., Gosselin, M., Poulin, M., Campbell, K., and Wang, F.:
Spring production of mycosporine-like amino acids and other UV-absorbing compounds in sea ice-associated algae communities in the Canadian Arctic,
Mar. Ecol.-Prog. Ser.,
541, 91–104, https://doi.org/10.3354/meps11540, 2015.
Fede, A. and Grannas, A. M.:
Photochemical Production of Singlet Oxygen from Dissolved Organic Matter in Ice,
Environ. Sci. Technol.,
49, 12808–12815, https://doi.org/10.1021/acs.est.5b03600, 2015.
Fellman, J. B., Hood, E., Raymond, P. A., Stubbins, A., and Spencer, R. G. M.:
Spatial Variation in the Origin of Dissolved Organic Carbon in Snow on the Juneau Icefield, Southeast Alaska,
Environ. Sci. Technol.,
49, 11492–11499, https://doi.org/10.1021/acs.est.5b02685, 2015.
Feng, L., Xu, J. Z., Kang, S. C., Li, X. F., Li, Y., Jiang, B., and Shi, Q.:
Chemical Composition of Microbe-Derived Dissolved Organic Matter in Cryoconite in Tibetan Plateau Glaciers: Insights from Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Analysis,
Environ. Sci. Technol.,
50, 13215–13223, https://doi.org/10.1021/acs.est.6b03971, 2016.
Feng, L., An, Y., Xu, J., and Kang, S.:
Characteristics and sources of dissolved organic matter in a glacier in the northern Tibetan Plateau: differences between different snow categories,
Ann. Glaciol.,
59, 31–40, https://doi.org/10.1017/aog.2018.20, 2018.
Feng, L., An, Y., Xu, J., Li, X., Jiang, B., and Liao, Y.:
Biochemical evolution of dissolved organic matter during snow metamorphism across the ablation season for a glacier on the central Tibetan Plateau,
Sci. Rep.,
10, 6123, https://doi.org/10.1038/s41598-020-62851-w, 2020.
Flanner, M. G., Zender, C. S., Randerson, J. T., and Rasch, P. J.:
Present-day climate forcing and response from black carbon in snow,
J. Geophys. Res.-Atmos.,
112, D11202, https://doi.org/10.1029/2006jd008003, 2007.
Fu, P. Q., Kawamura, K., Chen, J., Qin, M. Y., Ren, L. J., Sun, Y. L., Wang, Z. F., Barrie, L. A., Tachibana, E., Ding, A. J., and Yamashita, Y.:
Fluorescent water-soluble organic aerosols in the High Arctic atmosphere,
Sci. Rep.,
5, 9845, https://doi.org/10.1038/Srep09845, 2015.
Ganey, G. Q., Loso, M. G., Burgess, A. B., and Dial, R. J.:
The role of microbes in snowmelt and radiative forcing on an Alaskan icefield,
Nat. Geosci.,
10, 754–759, https://doi.org/10.1038/ngeo3027, 2017.
Geisseler, D., Horwath, W. R., Joergensen, R. G., and Ludwig, B.:
Pathways of nitrogen utilization by soil microorganisms – A review,
Soil Biol. Biochem.,
42, 2058–2067, https://doi.org/10.1016/j.soilbio.2010.08.021, 2010.
Grannas, A. M., Jones, A. E., Dibb, J., Ammann, M., Anastasio, C., Beine, H. J., Bergin, M., Bottenheim, J., Boxe, C. S., Carver, G., Chen, G., Crawford, J. H., Dominé, F., Frey, M. M., Guzmán, M. I., Heard, D. E., Helmig, D., Hoffmann, M. R., Honrath, R. E., Huey, L. G., Hutterli, M., Jacobi, H. W., Klán, P., Lefer, B., McConnell, J., Plane, J., Sander, R., Savarino, J., Shepson, P. B., Simpson, W. R., Sodeau, J. R., von Glasow, R., Weller, R., Wolff, E. W., and Zhu, T.: An overview of snow photochemistry: evidence, mechanisms and impacts, Atmos. Chem. Phys., 7, 4329–4373, https://doi.org/10.5194/acp-7-4329-2007, 2007.
Grannas, A. M., Pagano, L. P., Pierce, B. C., Bobby, R., and Fede, A.:
Role of dissolved organic matter in ice photochemistry,
Environ. Sci. Technol.,
48, 10725–10733, https://doi.org/10.1021/es5023834, 2014.
Hadley, O. L. and Kirchstetter, T. W.:
Black-carbon reduction of snow albedo,
Nat. Clim. Change,
2, 437–440, https://doi.org/10.1038/Nclimate1433, 2012.
Hagler, G. S. W., Bergin, M. H., Smith, E. A., and Dibb, J. E.:
A summer time series of particulate carbon in the air and snow at Summit, Greenland,
J. Geophys. Res.-Atmos.,
112, D21309, https://doi.org/10.1029/2007jd008993, 2007a.
Hagler, G. S. W., Bergin, M. H., Smith, E. A., Dibb, J. E., Anderson, C., and Steig, E. J.: Particulate and water-soluble carbon measured in recent snow at Summit, Greenland, Geophys. Res. Lett., 34, L16505, https://doi.org/10.1029/2007GL030110, 2007b.
Hall, D. K., Riggs, G. A., and Salomonson, V. V.:
Development of Methods for Mapping Global Snow Cover Using Moderate Resolution Imaging Spectroradiometer Data,
Remote Sens. Environ.,
54, 127–140, https://doi.org/10.1016/0034-4257(95)00137-P, 1995.
Handley, S. R., Clifford, D., and Donaldson, D. J.:
Photochemical Loss of Nitric Acid on Organic Films: a Possible Recycling Mechanism for NOx,
Environ. Sci. Technol.,
41, 3898–3903, https://doi.org/10.1021/es062044z, 2007.
Hansen, J. and Nazarenko, L.:
Soot climate forcing via snow and ice albedos,
P. Natl. Acad. Sci. USA,
101, 423–428, https://doi.org/10.1073/pnas.2237157100, 2004.
He, C. L., Li, Q. B., Liou, K. N., Takano, Y., Gu, Y., Qi, L., Mao, Y. H., and Leung, L. R.:
Black carbon radiative forcing over the Tibetan Plateau,
Geophys. Res. Lett.,
41, 7806–7813, https://doi.org/10.1002/2014GL062191, 2014.
He, Z., Mao, J., Honeycutt, C. W., Ohno, T., Hunt, J. F., and Cade-Menun, B. J.:
Characterization of plant-derived water extractable organic matter by multiple spectroscopic techniques,
Biol. Fert. Soils,
45, 609–616, https://doi.org/10.1007/s00374-009-0369-8, 2009.
Hertkorn, N., Benner, R., Frommberger, M., Schmitt-Kopplin, P., Witt, M., Kaiser, K., Kettrup, A., and Hedges, J. I.:
Characterization of a major refractory component of marine dissolved organic matter,
Geochim. Cosmochim. Ac.,
70, 2990–3010, https://doi.org/10.1016/j.gca.2006.03.021, 2006.
Hood, E., Fellman, J., Spencer, R. G. M., Hernes, P. J., Edwards, R., D'Amore, D., and Scott, D.:
Glaciers as a source of ancient and labile organic matter to the marine environment,
Nature,
462, 1044–1047, https://doi.org/10.1038/nature08580, 2009.
Hood, E., Battin, T. J., Fellman, J., O'Neel, S., and Spencer, R. G. M.:
Storage and release of organic carbon from glaciers and ice sheets,
Nat. Geosci.,
8, 91–96, https://doi.org/10.1038/NGEO2331, 2015.
Huang, J. P., Fu, Q. A., Zhang, W., Wang, X., Zhang, R. D., Ye, H., and Warren, S. G.:
Dust And Black Carbon In Seasonal Snow across Northern China,
B. Am. Meteorol. Soc.,
92, 175–181, https://doi.org/10.1175/2010BAMS3064.1, 2011.
Hullar, T., Bononi, F. C., Chen, Z., Magadia, D., Palmer, O., Tran, T., Rocca, D., Andreussi, O., Donadio, D., and Anastasio, C.:
Photodecay of guaiacol is faster in ice, and even more rapid on ice, than in aqueous solution,
Environ. Sci.-Proc. Imp.,
22, 1666–1677, https://doi.org/10.1039/d0em00242a, 2020.
Hunt, J. F. and Ohno, T.:
Characterization of Fresh and Decomposed Dissolved Organic Matter Using Excitation–Emission Matrix Fluorescence Spectroscopy and Multiway Analysis,
J. Agr. Food. Chem.,
55, 2121–2128, https://doi.org/10.1021/jf063336m, 2007.
Ikeya, K., Sleighter, R. L., Hatcher, P. G., and Watanabe, A.:
Characterization of the chemical composition of soil humic acids using Fourier transform ion cyclotron resonance mass spectrometry,
Geochim. Cosmochim. Ac.,
153, 169–182, https://doi.org/10.1016/j.gca.2015.01.002, 2015.
Jacobson, M. Z.:
Climate response of fossil fuel and biofuel soot, accounting for soot's feedback to snow and sea ice albedo and emissivity,
J. Geophys. Res.-Atmos.,
109, D21201, https://doi.org/10.1029/2004jd004945, 2004.
Jaffé, R., Cawley, K. M., and Yamashita, Y.: Applications of Excitation Emission Matrix Fluorescence with Parallel Factor Analysis (EEM-PARAFAC) in Assessing Environmental Dynamics of Natural Dissolved Organic Matter (DOM) in Aquatic Environments: A Review, in: Advances in the Physicochemical Characterization of Dissolved Organic Matter: Impact on Natural and Engineered Systems, ACS Symposium Series, 1160, American Chemical Society, Washington, DC, 27–73, 2014.
Jin, Z. H., Charlock, T. P., Rutledge, K., Stamnes, K., and Wang, Y. J.:
Analytical solution of radiative transfer in the coupled atmosphere-ocean system with a rough surface,
Appl. Optics,
45, 7443–7455, https://doi.org/10.1364/AO.45.007443, 2006.
Jones, H. G.:
The ecology of snow-covered systems: a brief overview of nutrient cycling and life in the cold,
Hydrol. Process.,
13, 2135–2147, https://doi.org/10.1002/(SICI)1099-1085(199910)13:14/15<2135::AID-HYP862>3.0.CO;2-Y, 1999.
Kim, S., Kramer, R. W., and Hatcher, P. G.:
Graphical method for analysis of ultrahigh-resolution broadband mass spectra of natural organic matter, the van Krevelen diagram,
Anal. Chem.,
75, 5336–5344, https://doi.org/10.1021/ac034415p, 2003.
Kirchstetter, T. W., Novakov, T., and Hobbs, P. V.:
Evidence that the spectral dependence of light absorption by aerosols is affected by organic carbon,
J. Geophys. Res.-Atmos.,
109, D21208, https://doi.org/10.1029/2004jd004999, 2004.
Kirillova, E. N., Andersson, A., Han, J., Lee, M., and Gustafsson, Ö.: Sources and light absorption of water-soluble organic carbon aerosols in the outflow from northern China, Atmos. Chem. Phys., 14, 1413–1422, https://doi.org/10.5194/acp-14-1413-2014, 2014.
Koch, B. P. and Dittmar, T.:
From mass to structure: an aromaticity index for high-resolution mass data of natural organic matter,
Rapid Commun. Mass Sp.,
20, 926–932, https://doi.org/10.1002/rcm.2386, 2006.
Koch, B. P. and Dittmar, T.: From mass to structure: an aromaticity index for high-resolution mass data of natural organic matter, Erratum, Rapid Commun. Mass Sp., 30, 250–250, https://doi.org/10.1002/rcm.7433, 2016.
Kothawala, D. N., Murphy, K. R., Stedmon, C. A., Weyhenmeyer, G. A., and Tranvik, L. J.:
Inner filter correction of dissolved organic matter fluorescence,
Limnol. Oceanogr.-Meth.,
11, 616–630, https://doi.org/10.4319/Iom.2013.11.616, 2013.
Kroll, J. H., Donahue, N. M., Jimenez, J. L., Kessler, S. H., Canagaratna, M. R., Wilson, K. R., Altieri, K. E., Mazzoleni, L. R., Wozniak, A. S., Bluhm, H., Mysak, E. R., Smith, J. D., Kolb, C. E., and Worsnop, D. R.:
Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol,
Nat. Chem.,
3, 133–139, https://doi.org/10.1038/nchem.948, 2011.
Laskin, A., Smith, J. S., and Laskin, J.: Molecular Characterization of Nitrogen-Containing Organic Compounds in Biomass Burning Aerosols Using High-Resolution Mass Spectrometry, Environ. Sci. Technol., 43, 3764–3771, https://doi.org/10.1021/es803456n, 2009.
Laskin, A., Laskin, J., and Nizkorodov, S. A.:
Chemistry of Atmospheric Brown Carbon,
Chem. Rev.,
115, 4335–4382, https://doi.org/10.1021/cr5006167, 2015.
Lawaetz, A. J. and Stedmon, C. A.:
Fluorescence Intensity Calibration Using the Raman Scatter Peak of Water,
Appl. Spectrosc.,
63, 936–940, https://doi.org/10.1366/000370209788964548, 2009.
Legrand, M., Preunkert, S., Jourdain, B., Guilhermet, J., Faïn, X., Alekhina, I., and Petit, J. R.: Water-soluble organic carbon in snow and ice deposited at Alpine, Greenland, and Antarctic sites: a critical review of available data and their atmospheric relevance, Clim. Past, 9, 2195–2211, https://doi.org/10.5194/cp-9-2195-2013, 2013.
Lin, P., Engling, G., and Yu, J. Z.: Humic-like substances in fresh emissions of rice straw burning and in ambient aerosols in the Pearl River Delta Region, China, Atmos. Chem. Phys., 10, 6487–6500, https://doi.org/10.5194/acp-10-6487-2010, 2010.
Lin, P., Rincon, A. G., Kalberer, M., and Yu, J. Z.:
Elemental composition of HULIS in the Pearl River Delta Region, China: results inferred from positive and negative electrospray high resolution mass spectrometric data,
Environ. Sci. Technol.,
46, 7454–7462, https://doi.org/10.1021/es300285d, 2012.
Lin, P., Aiona, P. K., Li, Y., Shiraiwa, M., Laskin, J., Nizkorodov, S. A., and Laskin, A.:
Molecular Characterization of Brown Carbon in Biomass Burning Aerosol Particles,
Environ. Sci. Technol.,
50, 11815–11824, https://doi.org/10.1021/acs.est.6b03024, 2016.
Lin, P., Fleming, L. T., Nizkorodov, S. A., Laskin, J., and Laskin, A.:
Comprehensive Molecular Characterization of Atmospheric Brown Carbon by High Resolution Mass Spectrometry with Electrospray and Atmospheric Pressure Photoionization,
Anal. Chem.,
90, 12493–12502, https://doi.org/10.1021/acs.analchem.8b02177, 2018.
Liu, Y. Q., Yao, T. D., Jiao, N. Z., Kang, S. C., Xu, B. Q., Zeng, Y. H., Huang, S. J., and Liu, X. B.:
Bacterial diversity in the snow over Tibetan Plateau Glaciers,
Extremophiles,
13, 411–423, https://doi.org/10.1007/s00792-009-0227-5, 2009.
Lobodin, V. V., Marshall, A. G., and Hsu, C. S.:
Compositional Space Boundaries for Organic Compounds,
Anal. Chem.,
84, 3410–3416, https://doi.org/10.1021/ac300244f, 2012.
Lu, Y., Li, X., Mesfioui, R., Bauer, J. E., Chambers, R. M., Canuel, E. A., and Hatcher, P. G.:
Use of ESI-FTICR-MS to Characterize Dissolved Organic Matter in Headwater Streams Draining Forest-Dominated and Pasture-Dominated Watersheds,
Plos One,
10, e0145639, https://doi.org/10.1371/journal.pone.0145639, 2015.
Lu, Z., Streets, D. G., Winijkul, E., Yan, F., Chen, Y., Bond, T. C., Feng, Y., Dubey, M. K., Liu, S., Pinto, J. P., and Carmichael, G. R.:
Light absorption properties and radiative effects of primary organic aerosol emissions,
Environ. Sci. Technol.,
49, 4868–4877, https://doi.org/10.1021/acs.est.5b00211, 2015.
Lutz, S., Anesio, A. M., Villar, S. E. J., and Benning, L. G.:
Variations of algal communities cause darkening of a Greenland glacier,
FEMS Microbiol. Ecol.,
89, 402–414, https://doi.org/10.1111/1574-6941.12351, 2014.
McLafferty, F. W., Tureček, F., and Turecek, F.: Interpretation of mass spectra, University science books, Sausalito, California, 1993.
McNeill, V. F., Grannas, A. M., Abbatt, J. P. D., Ammann, M., Ariya, P., Bartels-Rausch, T., Domine, F., Donaldson, D. J., Guzman, M. I., Heger, D., Kahan, T. F., Klán, P., Masclin, S., Toubin, C., and Voisin, D.: Organics in environmental ices: sources, chemistry, and impacts, Atmos. Chem. Phys., 12, 9653–9678, https://doi.org/10.5194/acp-12-9653-2012, 2012.
Mead, R. N., Felix, J. D., Avery, G. B., Kieber, R. J., Willey, J. D., and Podgorski, D. C.:
Characterization of CHOS compounds in rainwater from continental and coastal storms by ultrahigh resolution mass spectrometry,
Atmos. Environ.,
105, 162–168, https://doi.org/10.1016/j.atmosenv.2015.01.057, 2015.
Mladenov, N., Alados-Arboledas, L., Olmo, F. J., Lyamani, H., Delgado, A., Molina, A., and Reche, I.:
Applications of optical spectroscopy and stable isotope analyses to organic aerosol source discrimination in an urban area,
Atmos. Environ.,
45, 1960–1969, https://doi.org/10.1016/j.atmosenv.2011.01.029, 2011.
Mladenov, N., Williams, M. W., Schmidt, S. K., and Cawley, K.: Atmospheric deposition as a source of carbon and nutrients to an alpine catchment of the Colorado Rocky Mountains, Biogeosciences, 9, 3337–3355, https://doi.org/10.5194/bg-9-3337-2012, 2012.
Murphy, K. R., Stedmon, C. A., Waite, T. D., and Ruiz, G. M.:
Distinguishing between terrestrial and autochthonous organic matter sources in marine environments using fluorescence spectroscopy,
Mar. Chem.,
108, 40–58, https://doi.org/10.1016/j.marchem.2007.10.003, 2008.
Murphy, K. R., Stedmon, C. A., Graeber, D., and Bro, R.:
Fluorescence spectroscopy and multi-way techniques. PARAFAC,
Anal. Methods-UK,
5, 6557–6566, https://doi.org/10.1039/c3ay41160e, 2013.
Myers, O. D., Sumner, S. J., Li, S., Barnes, S., and Du, X.:
One Step Forward for Reducing False Positive and False Negative Compound Identifications from Mass Spectrometry Metabolomics Data: New Algorithms for Constructing Extracted Ion Chromatograms and Detecting Chromatographic Peaks,
Anal. Chem.,
89, 8696–8703, https://doi.org/10.1021/acs.analchem.7b00947, 2017.
Ning, C., Gao, Y., Zhang, H., Yu, H., Wang, L., Geng, N., Cao, R., and Chen, J.:
Molecular characterization of dissolved organic matters in winter atmospheric fine particulate matters (PM2.5) from a coastal city of northeast China,
Sci. Total Environ.,
689, 312–321, https://doi.org/10.1016/j.scitotenv.2019.06.418, 2019.
Niu, H. W., Kang, S. C., Lu, X. X., and Shi, X. F.: Distributions and light absorption property of water soluble organic carbon in a typical temperate glacier, southeastern Tibetan Plateau, Tellus B, 70, 1–15, https://doi.org/10.1080/16000889.2018.1468705, 2018.
Nizkorodov, S. A., Laskin, J., and Laskin, A.:
Molecular chemistry of organic aerosols through the application of high resolution mass spectrometry,
Phys. Chem. Chem. Phys.,
13, 3612–3629, https://doi.org/10.1039/c0cp02032j, 2011.
Noziere, B., Kalberer, M., Claeys, M., Allan, J., D'Anna, B., Decesari, S., Finessi, E., Glasius, M., Grgic, I., Hamilton, J. F., Hoffmann, T., Iinuma, Y., Jaoui, M., Kahnt, A., Kampf, C. J., Kourtchev, I., Maenhaut, W., Marsden, N., Saarikoski, S., Schnelle-Kreis, J., Surratt, J. D., Szidat, S., Szmigielski, R., and Wisthaler, A.:
The molecular identification of organic compounds in the atmosphere: state of the art and challenges,
Chem. Rev.,
115, 3919–3983, https://doi.org/10.1021/cr5003485, 2015.
Ohno, T., He, Z., Sleighter, R. L., Honeycutt, C. W., and Hatcher, P. G.:
Ultrahigh resolution mass spectrometry and indicator species analysis to identify marker components of soil- and plant biomass-derived organic matter fractions,
Environ. Sci. Technol.,
44, 8594–8600, https://doi.org/10.1021/es101089t, 2010.
Painter, T. H., Deems, J. S., Belnap, J., Hamlet, A. F., Landry, C. C., and Udall, B.:
Response of Colorado River runoff to dust radiative forcing in snow,
P. Natl. Acad. Sci. USA,
107, 17125–17130, https://doi.org/10.1073/pnas.0913139107, 2010.
Painter, T. H., Seidel, F. C., Bryant, A. C., McKenzie Skiles, S., and Rittger, K.:
Imaging spectroscopy of albedo and radiative forcing by light-absorbing impurities in mountain snow,
J. Geophys. Res.-Atmos.,
118, 9511–9523, https://doi.org/10.1002/jgrd.50520, 2013.
Pluskal, T., Castillo, S., Villar-Briones, A., and Orešič, M.:
MZmine 2: modular framework for processing, visualizing, and analyzing mass spectrometry-based molecular profile data,
BMC Bioinformatics,
11, 395, https://doi.org/10.1186/1471-2105-11-395, 2010.
Pöhlker, C., Huffman, J. A., and Pöschl, U.: Autofluorescence of atmospheric bioaerosols – fluorescent biomolecules and potential interferences, Atmos. Meas. Tech., 5, 37–71, https://doi.org/10.5194/amt-5-37-2012, 2012.
Pu, W., Wang, X., Wei, H., Zhou, Y., Shi, J., Hu, Z., Jin, H., and Chen, Q.: Properties of black carbon and other insoluble light-absorbing particles in seasonal snow of northwestern China, The Cryosphere, 11, 1213–1233, https://doi.org/10.5194/tc-11-1213-2017, 2017.
Pu, W., Cui, J., Shi, T., Zhang, X., He, C., and Wang, X.: The remote sensing of radiative forcing by light-absorbing particles (LAPs) in seasonal snow over northeastern China, Atmos. Chem. Phys., 19, 9949–9968, https://doi.org/10.5194/acp-19-9949-2019, 2019.
Qi, Y., Fu, P., and Volmer, D. A.: Analysis of natural organic matter via fourier transform ion cyclotron resonance mass spectrometry: an overview of recent non-petroleum applications, Mass Spectrom. Rev., https://doi.org/10.1002/mas.21634, in press, 2020.
Qian, Y., Wang, H., Zhang, R., Flanner, M. G., and Rasch, P. J.: A sensitivity study on modeling black carbon in snow and its radiative forcing over the Arctic and Northern China, Environ. Res. Lett., 9, 064001, https://doi.org/10.1088/1748-9326/9/6/064001, 2014.
Roach, P. J., Laskin, J., and Laskin, A.:
Higher-order mass defect analysis for mass spectra of complex organic mixtures,
Anal. Chem.,
83, 4924–4929, https://doi.org/10.1021/ac200654j, 2011.
Saleh, R.:
From Measurements to Models: Toward Accurate Representation of Brown Carbon in Climate Calculations,
Current Pollution Reports,
6, 90–104, https://doi.org/10.1007/s40726-020-00139-3, 2020.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics: from air pollution to climate change, 3rd Edn., John Wiley & Sons, Hoboken, New Jersey, 2016.
Shi, T., Pu, W., Zhou, Y., Cui, J., Zhang, D., and Wang, X.: Albedo of Black Carbon-Contaminated Snow Across Northwestern China and the Validation With Model Simulation, J. Geophys. Res.-Atmos., 125, e2019JD032065, https://doi.org/10.1029/2019jd032065, 2020.
Shick, J. M. and Dunlap, W. C.:
Mycosporine-like amino acids and related Gadusols: biosynthesis, acumulation, and UV-protective functions in aquatic organisms,
Annu. Rev. Physiol.,
64, 223–262, https://doi.org/10.1146/annurev.physiol.64.081501.155802, 2002.
Siegmann, K. and Sattler, K.:
Formation mechanism for polycyclic aromatic hydrocarbons in methane flames,
J. Chem. Phys.,
112, 698–709, https://doi.org/10.1063/1.480648, 2000.
Singer, G. A., Fasching, C., Wilhelm, L., Niggemann, J., Steier, P., Dittmar, T., and Battin, T. J.:
Biogeochemically diverse organic matter in Alpine glaciers and its downstream fate,
Nat. Geosci.,
5, 710–714, https://doi.org/10.1038/NGEO1581, 2012.
Skiles, S. M., Flanner, M., Cook, J. M., Dumont, M., and Painter, T. H.:
Radiative forcing by light-absorbing particles in snow,
Nat. Clim. Change,
8, 964–971, https://doi.org/10.1038/s41558-018-0296-5, 2018.
Spencer, R. G. M., Guo, W. D., Raymond, P. A., Dittmar, T., Hood, E., Fellman, J., and Stubbins, A.:
Source and biolability of ancient dissolved organic matter in glacier and lake ecosystems on the Tibetan Plateau,
Geochim. Cosmochim. Ac.,
142, 64–74, https://doi.org/10.1016/j.gca.2014.08.006, 2014.
Stedmon, C. A. and Markager, S.:
Resolving the variability in dissolved organic matter fluorescence in a temperate estuary and its catchment using PARAFAC analysis,
Limnol. Oceanogr.,
50, 686–697, https://doi.org/10.4319/lo.2005.50.2.0686, 2005.
Stedmon, C. A. and Bro, R.:
Characterizing dissolved organic matter fluorescence with parallel factor analysis: a tutorial,
Limnol. Oceanogr.-Meth.,
6, 572–579, https://doi.org/10.4319/lom.2008.6.572, 2008.
Stedmon, C. A., Markager, S., and Bro, R.:
Tracing dissolved organic matter in aquatic environments using a new approach to fluorescence spectroscopy,
Mar. Chem.,
82, 239–254, https://doi.org/10.1016/S0304-4203(03)00072-0, 2003.
Sun, H. L., Biedermann, L., and Bond, T. C.:
Color of brown carbon: A model for ultraviolet and visible light absorption by organic carbon aerosol,
Geophys. Res. Lett.,
34, L17813, https://doi.org/10.1029/2007gl029797, 2007.
Toon, O. B., Mckay, C. P., Ackerman, T. P., and Santhanam, K.:
Rapid Calculation of Radiative Heating Rates and Photodissociation Rates in Inhomogeneous Multiple-Scattering Atmospheres,
J. Geophys. Res.-Atmos.,
94, 16287–16301, https://doi.org/10.1029/JD094iD13p16287, 1989.
Voisin, D., Jaffrezo, J. L., Houdier, S., Barret, M., Cozic, J., King, M. D., France, J. L., Reay, H. J., Grannas, A., Kos, G., Ariya, P. A., Beine, H. J., and Domine, F.:
Carbonaceous species and humic like substances (HULIS) in Arctic snowpack during OASIS field campaign in Barrow,
J. Geophys. Res.-Atmos.,
117, D00r19, https://doi.org/10.1029/2011jd016612, 2012.
Wang, K., Zhang, Y., Huang, R.-J., Cao, J., and Hoffmann, T.:
UHPLC-Orbitrap mass spectrometric characterization of organic aerosol from a central European city (Mainz, Germany) and a Chinese megacity (Beijing),
Atmos. Environ.,
189, 22–29, https://doi.org/10.1016/j.atmosenv.2018.06.036, 2018.
Wang, X., Doherty, S. J., and Huang, J.:
Black carbon and other light-absorbing impurities in snow across Northern China,
J. Geophys. Res.-Atmos.,
118, 1471–1492, https://doi.org/10.1029/2012JD018291, 2013.
Wang, X., Hayeck, N., Brüggemann, M., Yao, L., Chen, H., Zhang, C., Emmelin, C., Chen, J., George, C., and Wang, L.:
Chemical Characteristics of Organic Aerosols in Shanghai: A Study by Ultrahigh-Performance Liquid Chromatography Coupled With Orbitrap Mass Spectrometry,
J. Geophys. Res.-Atmos.,
122, 11703–11722, https://doi.org/10.1002/2017jd026930, 2017a.
Wang, X., Pu, W., Ren, Y., Zhang, X., Zhang, X., Shi, J., Jin, H., Dai, M., and Chen, Q.: Observations and model simulations of snow albedo reduction in seasonal snow due to insoluble light-absorbing particles during 2014 Chinese survey, Atmos. Chem. Phys., 17, 2279–2296, https://doi.org/10.5194/acp-17-2279-2017, 2017b.
Wang, X., Hayeck, N., Brüggemann, M., Abis, L., Riva, M., Lu, Y., Wang, B., Chen, J., George, C., and Wang, L.: Chemical characteristics and brown carbon chromophores of atmospheric organic aerosols over the Yangtze River channel: a cruise campaign, J. Geophys. Res.-Atmos., 125, e2020JD032497, https://doi.org/10.1029/2020jd032497, 2020a.
Wang, X., Zhang, X., and Di, W.: Development of an improved two-sphere integration technique for quantifying black carbon concentrations in the atmosphere and seasonal snow, Atmos. Meas. Tech., 13, 39–52, https://doi.org/10.5194/amt-13-39-2020, 2020b.
Wiscombe, W. J. and Warren, S. G.:
A Model for the Spectral Albedo of Snow. I: Pure Snow,
J. Atmos. Sci.,
37, 2712–2733, https://doi.org/10.1175/1520-0469(1980)037<2712:AMFTSA>2.0.CO;2, 1980.
Wu, C., Yang, J., Fu, Q., Zhu, B., Ruan, T., and Jiang, G.:
Molecular characterization of water-soluble organic compounds in PM2.5 using ultrahigh resolution mass spectrometry,
Sci. Total Environ.,
668, 917–924, https://doi.org/10.1016/j.scitotenv.2019.03.031, 2019.
Wu, G., Ram, K., Fu, P., Wang, W., Zhang, Y., Liu, X., Stone, E. A., Pradhan, B. B., Dangol, P. M., Panday, A. K., Wan, X., Bai, Z., Kang, S., Zhang, Q., and Cong, Z.:
Water-Soluble Brown Carbon in Atmospheric Aerosols from Godavari (Nepal), a Regional Representative of South Asia,
Environ. Sci. Technol.,
53, 3471–3479, https://doi.org/10.1021/acs.est.9b00596, 2019.
Wu, G., Wan, X., Ram, K., Li, P., Liu, B., Yin, Y., Fu, P., Loewen, M., Gao, S., Kang, S., Kawamura, K., Wang, Y., and Cong, Z.:
Light absorption, fluorescence properties and sources of brown carbon aerosols in the Southeast Tibetan Plateau,
Environ. Pollut.,
257, 113616, https://doi.org/10.1016/j.envpol.2019.113616, 2020.
Wu, G., Fu, P., Ram, K., Song, J., Chen, Q., Kawamura, K., Wan, X., Kang, S., Wang, X., Laskin, A., and Cong, Z.:
Fluorescence characteristics of water-soluble organic carbon in atmospheric aerosol,
Environ. Pollut.,
268, 115906, https://doi.org/10.1016/j.envpol.2020.115906, 2021.
Xie, Q., Su, S., Chen, S., Zhang, Q., Yue, S., Zhao, W., Du, H., Ren, H., Wei, L., Dong, C., Xu, Y., Sun, Y., Wang, Z., and Fu, P.: Molecular Characterization of Size-Segregated Organic Aerosols in the Urban Boundary Layer in Wintertime Beijing by FT-ICR MS, Faraday Discuss., 226, 457, https://doi.org/10.1039/d0fd00084a, 2021.
Xu, C., Chen, Y., Yang, Y., Hao, X., and Shen, Y.:
Hydrology and water resources variation and its response to regional climate change in Xinjiang,
J. Geogr. Sci.,
20, 599–612, https://doi.org/10.1007/s11442-010-0599-6, 2010.
Yan, F., Kang, S., Li, C., Zhang, Y., Qin, X., Li, Y., Zhang, X., Hu, Z., Chen, P., Li, X., Qu, B., and Sillanpää, M.: Concentration, sources and light absorption characteristics of dissolved organic carbon on a medium-sized valley glacier, northern Tibetan Plateau, The Cryosphere, 10, 2611–2621, https://doi.org/10.5194/tc-10-2611-2016, 2016.
Yang, W., Han, C., Yang, H., and Xue, X.:
Significant HONO formation by the photolysis of nitrates in the presence of humic acids,
Environ. Pollut.,
243, 679–686, https://doi.org/10.1016/j.envpol.2018.09.039, 2018.
Ye, H., Zhang, R. D., Shi, J. S., Huang, J. P., Warren, S. G., and Fu, Q.:
Black carbon in seasonal snow across northern Xinjiang in northwestern China,
Environ. Res. Lett.,
7, 044002, https://doi.org/10.1088/1748-9326/7/4/044002, 2012.
Zatko, M. C., Grenfell, T. C., Alexander, B., Doherty, S. J., Thomas, J. L., and Yang, X.: The influence of snow grain size and impurities on the vertical profiles of actinic flux and associated NOx emissions on the Antarctic and Greenland ice sheets, Atmos. Chem. Phys., 13, 3547–3567, https://doi.org/10.5194/acp-13-3547-2013, 2013.
Zhang, Y., Kang, S., Sprenger, M., Cong, Z., Gao, T., Li, C., Tao, S., Li, X., Zhong, X., Xu, M., Meng, W., Neupane, B., Qin, X., and Sillanpää, M.: Black carbon and mineral dust in snow cover on the Tibetan Plateau, The Cryosphere, 12, 413–431, https://doi.org/10.5194/tc-12-413-2018, 2018.
Zhang, Y., Kang, S., Gao, T., Schmale, J., Liu, Y., Zhang, W., Guo, J., Du, W., Hu, Z., Cui, X., and Sillanpaa, M.:
Dissolved organic carbon in snow cover of the Chinese Altai Mountains, Central Asia: Concentrations, sources and light-absorption properties,
Sci. Total Environ.,
647, 1385–1397, https://doi.org/10.1016/j.scitotenv.2018.07.417, 2019.
Zhang, Y., Kang, S., Gao, T., Sprenger, M., Dou, T., Han, W., Zhang, Q., Sun, S., Du, W., Chen, P., Guo, J., Cui, X., and Sillanpää, M.:
Dissolved organic carbon in Alaskan Arctic snow: concentrations, light-absorption properties, and bioavailability,
Tellus B,
72, 1–19, https://doi.org/10.1080/16000889.2020.1778968, 2020.
Zhang, Y. L., Zhang, E. L., Yin, Y., van Dijk, M. A., Feng, L. Q., Shi, Z. Q., Liu, M. L., and Qin, B. Q.:
Characteristics and sources of chromophoric dissolved organic matter in lakes of the Yungui Plateau, China, differing in trophic state and altitude,
Limnol. Oceanogr.,
55, 2645–2659, https://doi.org/10.4319/lo.2010.55.6.2645, 2010.
Zhang, Y.-L., El-Haddad, I., Huang, R.-J., Ho, K.-F., Cao, J.-J., Han, Y., Zotter, P., Bozzetti, C., Daellenbach, K. R., Slowik, J. G., Salazar, G., Prévôt, A. S. H., and Szidat, S.: Large contribution of fossil fuel derived secondary organic carbon to water soluble organic aerosols in winter haze in China, Atmos. Chem. Phys., 18, 4005–4017, https://doi.org/10.5194/acp-18-4005-2018, 2018.
Zhao, C., Hu, Z., Qian, Y., Ruby Leung, L., Huang, J., Huang, M., Jin, J., Flanner, M. G., Zhang, R., Wang, H., Yan, H., Lu, Z., and Streets, D. G.: Simulating black carbon and dust and their radiative forcing in seasonal snow: a case study over North China with field campaign measurements, Atmos. Chem. Phys., 14, 11475–11491, https://doi.org/10.5194/acp-14-11475-2014, 2014.
Zhao, Y., Song, K., Wen, Z., Li, L., Zang, S., Shao, T., Li, S., and Du, J.: Seasonal characterization of CDOM for lakes in semiarid regions of Northeast China using excitation–emission matrix fluorescence and parallel factor analysis (EEM–PARAFAC), Biogeosciences, 13, 1635–1645, https://doi.org/10.5194/bg-13-1635-2016, 2016.
Zhou, L., Zhou, Y., Hu, Y., Cai, J., Liu, X., Bai, C., Tang, X., Zhang, Y., Jang, K. S., Spencer, R. G. M., and Jeppesen, E.:
Microbial production and consumption of dissolved organic matter in glacial ecosystems on the Tibetan Plateau,
Water Res.,
160, 18–28, https://doi.org/10.1016/j.watres.2019.05.048, 2019.
Zhou, Y., Wen, H., Liu, J., Pu, W., Chen, Q., and Wang, X.: The optical characteristics and sources of chromophoric dissolved organic matter (CDOM) in seasonal snow of northwestern China, The Cryosphere, 13, 157–175, https://doi.org/10.5194/tc-13-157-2019, 2019a.
Zhou, Y., Zhou, L., He, X., Jang, K. S., Yao, X., Hu, Y., Zhang, Y., Li, X., Spencer, R. G. M., Brookes, J. D., and Jeppesen, E.:
Variability in Dissolved Organic Matter Composition and Biolability across Gradients of Glacial Coverage and Distance from Glacial Terminus on the Tibetan Plateau,
Environ. Sci. Technol.,
53, 12207–12217, https://doi.org/10.1021/acs.est.9b03348, 2019b.
Short summary
We present a comprehensive characterization of water-soluble organic carbon (WSOC) in seasonal snow of northwestern China. We applied complementary multimodal analytical techniques to investigate bulk and molecular-level composition, optical properties, and sources of WSOC. For the first time, we estimated the extent of radiative forcing due to WSOC in snow using a model simulation and showed the profound influences of WSOC on the energy budget of midlatitude seasonal snowpack.
We present a comprehensive characterization of water-soluble organic carbon (WSOC) in seasonal...
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