Articles | Volume 21, issue 10
https://doi.org/10.5194/acp-21-7791-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-7791-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 May 2021
Research article |
| 21 May 2021
| 21 May 2021
Soot PCF: pore condensation and freezing framework for soot aggregates
Claudia Marcolli
CORRESPONDING AUTHOR
Institute for Atmospheric
and Climate Science, Department of Environmental Systems Science, ETH Zurich, 8092 Zurich, Switzerland
Fabian Mahrt
Department of Chemistry, University of British Columbia, 2036 Main
Mall, Vancouver, BC, V6T 1Z1, Canada
Laboratory of Environmental Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Bernd Kärcher
Institut für Physik der Atmosphäre, Deutsches Zentrum für
Luft- und Raumfahrt (DLR Oberpfaffenhofen), 82234 Weßling, Germany
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Nadia Shardt, Florin N. Isenrich, Julia Nette, Christopher Dreimol, Ning Ma, Zamin A. Kanji, Andrew J. deMello, and Claudia Marcolli
EGUsphere, https://doi.org/10.5194/egusphere-2025-2958, https://doi.org/10.5194/egusphere-2025-2958, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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In the atmosphere, minerals suspended in cloud droplets promote the formation of ice. We investigated ice formation in the presence of pure and binary mixtures of common minerals using a microfluidic device. The mineral with the best ability to initiate ice formation alone (that is, at the highest temperature) typically determined when ice formed in the binary mixture.
Anna J. Miller, Christopher Fuchs, Fabiola Ramelli, Huiying Zhang, Nadja Omanovic, Robert Spirig, Claudia Marcolli, Zamin A. Kanji, Ulrike Lohmann, and Jan Henneberger
Atmos. Chem. Phys., 25, 5387–5407, https://doi.org/10.5194/acp-25-5387-2025, https://doi.org/10.5194/acp-25-5387-2025, 2025
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We analyzed the ability of silver iodide particles (a commonly used cloud-seeding agent) to form ice crystals in naturally occurring liquid clouds at −5 to −8 °C and found that only ≈ 0.1 %−1 % of particles nucleate ice, with a negative dependence on temperature. By contextualizing our results with previous laboratory studies, we help to bridge the gap between laboratory and field experiments, which also helps to inform future cloud-seeding projects.
Judith Kleinheins, Nadia Shardt, Ulrike Lohmann, and Claudia Marcolli
Atmos. Chem. Phys., 25, 881–903, https://doi.org/10.5194/acp-25-881-2025, https://doi.org/10.5194/acp-25-881-2025, 2025
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We model the cloud condensation nuclei (CCN) activation of sea spray aerosol particles with classical Köhler theory and with a new model approach that takes surface tension lowering into account. We categorize organic compounds into weak, intermediate, and strong surfactants, and we outline for which composition surface tension lowering is important. The results suggest that surface tension lowering allows sea spray aerosol particles in the Aitken mode to be a source of CCN in marine updraughts.
Anand Kumar, Kristian Klumpp, Chen Barak, Giora Rytwo, Michael Plötze, Thomas Peter, and Claudia Marcolli
Atmos. Chem. Phys., 23, 4881–4902, https://doi.org/10.5194/acp-23-4881-2023, https://doi.org/10.5194/acp-23-4881-2023, 2023
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Smectites are a major class of clay minerals that are ice nucleation (IN) active. They form platelets that swell or even delaminate in water by intercalation of water between their layers. We hypothesize that at least three smectite layers need to be stacked together to host a critical ice embryo on clay mineral edges and that the larger the surface edge area is, the higher the freezing temperature. Edge sites on such clay particles play a crucial role in imparting IN ability to such particles.
Kristian Klumpp, Claudia Marcolli, Ana Alonso-Hellweg, Christopher H. Dreimol, and Thomas Peter
Atmos. Chem. Phys., 23, 1579–1598, https://doi.org/10.5194/acp-23-1579-2023, https://doi.org/10.5194/acp-23-1579-2023, 2023
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The prerequisites of a particle surface for efficient ice nucleation are still poorly understood. This study compares the ice nucleation activity of two chemically identical but morphologically different minerals (kaolinite and halloysite). We observe, on average, not only higher ice nucleation activities for halloysite than kaolinite but also higher diversity between individual samples. We identify the particle edges as being the most likely site for ice nucleation.
Nikou Hamzehpour, Claudia Marcolli, Sara Pashai, Kristian Klumpp, and Thomas Peter
Atmos. Chem. Phys., 22, 14905–14930, https://doi.org/10.5194/acp-22-14905-2022, https://doi.org/10.5194/acp-22-14905-2022, 2022
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Playa surfaces in Iran that emerged through Lake Urmia (LU) desiccation have become a relevant dust source of regional relevance. Here, we identify highly erodible LU playa surfaces and determine their physicochemical properties and mineralogical composition and perform emulsion-freezing experiments with them. We find high ice nucleation activities (up to 250 K) that correlate positively with organic matter and clay content and negatively with pH, salinity, K-feldspars, and quartz.
Nikou Hamzehpour, Claudia Marcolli, Kristian Klumpp, Debora Thöny, and Thomas Peter
Atmos. Chem. Phys., 22, 14931–14956, https://doi.org/10.5194/acp-22-14931-2022, https://doi.org/10.5194/acp-22-14931-2022, 2022
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Dust aerosols from dried lakebeds contain mineral particles, as well as soluble salts and (bio-)organic compounds. Here, we investigate ice nucleation (IN) activity of dust samples from Lake Urmia playa, Iran. We find high IN activity of the untreated samples that decreases after organic matter removal but increases after removing soluble salts and carbonates, evidencing inhibiting effects of soluble salts and carbonates on the IN activity of organic matter and minerals, especially microcline.
Florin N. Isenrich, Nadia Shardt, Michael Rösch, Julia Nette, Stavros Stavrakis, Claudia Marcolli, Zamin A. Kanji, Andrew J. deMello, and Ulrike Lohmann
Atmos. Meas. Tech., 15, 5367–5381, https://doi.org/10.5194/amt-15-5367-2022, https://doi.org/10.5194/amt-15-5367-2022, 2022
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Ice nucleation in the atmosphere influences cloud properties and lifetimes. Microfluidic instruments have recently been used to investigate ice nucleation, but these instruments are typically made out of a polymer that contributes to droplet instability over extended timescales and relatively high temperature uncertainty. To address these drawbacks, we develop and validate a new microfluidic instrument that uses fluoropolymer tubing to extend droplet stability and improve temperature accuracy.
Yu Wang, Aristeidis Voliotis, Dawei Hu, Yunqi Shao, Mao Du, Ying Chen, Judith Kleinheins, Claudia Marcolli, M. Rami Alfarra, and Gordon McFiggans
Atmos. Chem. Phys., 22, 4149–4166, https://doi.org/10.5194/acp-22-4149-2022, https://doi.org/10.5194/acp-22-4149-2022, 2022
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Aerosol water uptake plays a key role in atmospheric physicochemical processes. We designed chamber experiments on aerosol water uptake of secondary organic aerosol (SOA) from mixed biogenic and anthropogenic precursors with inorganic seed. Our results highlight this chemical composition influences the reconciliation of the sub- and super-saturated water uptake, providing laboratory evidence for understanding the chemical controls of water uptake of the multi-component aerosol.
Kristian Klumpp, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 22, 3655–3673, https://doi.org/10.5194/acp-22-3655-2022, https://doi.org/10.5194/acp-22-3655-2022, 2022
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Surface interactions with solutes can significantly alter the ice nucleation activity of mineral dust. Past studies revealed the sensitivity of microcline, one of the most ice-active types of dust in the atmosphere, to inorganic solutes. This study focuses on the interaction of microcline with bio-organic substances and the resulting effects on its ice nucleation activity. We observe strongly hampered ice nucleation activity due to the presence of carboxylic and amino acids but not for polyols.
Bernd Kärcher and Claudia Marcolli
Atmos. Chem. Phys., 21, 15213–15220, https://doi.org/10.5194/acp-21-15213-2021, https://doi.org/10.5194/acp-21-15213-2021, 2021
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Aerosol–cloud interactions play an important role in climate change. Simulations of the competition between homogeneous solution droplet freezing and heterogeneous ice nucleation can be compromised by the misapplication of ice-active particle fractions frequently derived from laboratory measurements or parametrizations. Our study frames the problem and establishes a solution that is easy to implement in cloud models.
Robert O. David, Jonas Fahrni, Claudia Marcolli, Fabian Mahrt, Dominik Brühwiler, and Zamin A. Kanji
Atmos. Chem. Phys., 20, 9419–9440, https://doi.org/10.5194/acp-20-9419-2020, https://doi.org/10.5194/acp-20-9419-2020, 2020
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Ice crystal formation plays an important role in controlling the Earth's climate. However, the mechanisms responsible for ice formation in the atmosphere are still uncertain. Here we use surrogates for atmospherically relevant porous particles to determine the role of pore diameter and wettability on the ability of porous particles to nucleate ice in the atmosphere. Our results are consistent with the pore condensation and freeing mechanism.
María Cascajo-Castresana, Robert O. David, Maiara A. Iriarte-Alonso, Alexander M. Bittner, and Claudia Marcolli
Atmos. Chem. Phys., 20, 3291–3315, https://doi.org/10.5194/acp-20-3291-2020, https://doi.org/10.5194/acp-20-3291-2020, 2020
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Atmospheric ice-nucleating particles are rare but relevant for cloud glaciation. A source of particles that nucleate ice above −15 °C is biological material including some proteins. Here we show that proteins of very diverse functions and structures can nucleate ice. Among these, the iron storage protein apoferritin stands out, with activity up to −4 °C. We show that its activity does not stem from correctly assembled proteins but from misfolded protein monomers or oligomers and aggregates.
Claudia Marcolli
Atmos. Chem. Phys., 20, 3209–3230, https://doi.org/10.5194/acp-20-3209-2020, https://doi.org/10.5194/acp-20-3209-2020, 2020
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Pore condensation and freezing (PCF) is an ice nucleation mechanism explaining ice formation at low ice supersaturation. It is assumed that liquid water condenses in pores of solid aerosol particles below water saturation followed by ice nucleation within the pores. This study discusses conditions of pore filling, homogeneous ice nucleation within the volume of porewater, and growth of ice out of the pores, taking the effect of negative pressure within pores below water saturation into account.
Robert O. David, Maria Cascajo-Castresana, Killian P. Brennan, Michael Rösch, Nora Els, Julia Werz, Vera Weichlinger, Lin S. Boynton, Sophie Bogler, Nadine Borduas-Dedekind, Claudia Marcolli, and Zamin A. Kanji
Atmos. Meas. Tech., 12, 6865–6888, https://doi.org/10.5194/amt-12-6865-2019, https://doi.org/10.5194/amt-12-6865-2019, 2019
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Here we present the development and applicability of the DRoplet Ice Nuclei Counter Zurich (DRINCZ). DRINCZ allows for ice nuclei in the immersion mode to be quantified between 0 and -25 °C with an uncertainty of ±0.9 °C. Furthermore, we present a new method for assessing biases in drop-freezing apparatuses and cumulative ice-nucleating-particle concentrations from snow samples collected in the Austrian Alps at the Sonnblick Observatory.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6035–6058, https://doi.org/10.5194/acp-19-6035-2019, https://doi.org/10.5194/acp-19-6035-2019, 2019
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This paper not only interests the atmospheric science community but has a potential to cater to a broader audience. We discuss both long- and
short-term effects of various
atmospherically relevantchemical species on a fairly abundant mineral surface
Quartz. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6059–6084, https://doi.org/10.5194/acp-19-6059-2019, https://doi.org/10.5194/acp-19-6059-2019, 2019
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This paper not only interests the Atmospheric Science community but has a potential to cater to a broader audience. We discuss both long- and short-term effects of various
atmospherically relevantchemical species on fairly abundant mineral surfaces like feldspars and clays. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Fabian Mahrt, Claudia Marcolli, Robert O. David, Philippe Grönquist, Eszter J. Barthazy Meier, Ulrike Lohmann, and Zamin A. Kanji
Atmos. Chem. Phys., 18, 13363–13392, https://doi.org/10.5194/acp-18-13363-2018, https://doi.org/10.5194/acp-18-13363-2018, 2018
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The ice nucleation ability of different soot particles in the cirrus and mixed-phase cloud temperature regime is presented. The impact of aerosol particle size, particle morphology, organic matter and hydrophilicity on ice nucleation is examined. We propose ice nucleation proceeds via a pore condensation freezing mechanism for soot particles with the necessary physicochemical properties that nucleated ice well below water saturation.
Anand Kumar, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 18, 7057–7079, https://doi.org/10.5194/acp-18-7057-2018, https://doi.org/10.5194/acp-18-7057-2018, 2018
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We have performed immersion freezing experiments with microcline (most active ice nucleation, IN, K-feldspar polymorph) and investigated the effect of ammonium and non-ammonium solutes on its IN efficiency. We report increased IN efficiency of microcline in dilute ammonia- or ammonium-containing solutions, which opens up a pathway for condensation freezing occurring at a warmer temperature than immersion freezing.
Ulrich K. Krieger, Franziska Siegrist, Claudia Marcolli, Eva U. Emanuelsson, Freya M. Gøbel, Merete Bilde, Aleksandra Marsh, Jonathan P. Reid, Andrew J. Huisman, Ilona Riipinen, Noora Hyttinen, Nanna Myllys, Theo Kurtén, Thomas Bannan, Carl J. Percival, and David Topping
Atmos. Meas. Tech., 11, 49–63, https://doi.org/10.5194/amt-11-49-2018, https://doi.org/10.5194/amt-11-49-2018, 2018
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Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the literature often differ by several orders of magnitude between measurement techniques. These discrepancies exceed the stated uncertainty of each technique, which is generally reported to be smaller than a factor of 2. We determined saturation vapor pressures for the homologous series of polyethylene glycols ranging in vapor pressure at 298 K from 1E−7 Pa to 5E−2 Pa as a reference set.
Lisa Stirnweis, Claudia Marcolli, Josef Dommen, Peter Barmet, Carla Frege, Stephen M. Platt, Emily A. Bruns, Manuel Krapf, Jay G. Slowik, Robert Wolf, Andre S. H. Prévôt, Urs Baltensperger, and Imad El-Haddad
Atmos. Chem. Phys., 17, 5035–5061, https://doi.org/10.5194/acp-17-5035-2017, https://doi.org/10.5194/acp-17-5035-2017, 2017
Lukas Kaufmann, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 17, 3525–3552, https://doi.org/10.5194/acp-17-3525-2017, https://doi.org/10.5194/acp-17-3525-2017, 2017
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To improve the understanding of heterogeneous ice nucleation, we have subjected different ice nuclei to repeated freezing cycles and evaluated the freezing temperatures with different parameterizations of classical nucleation theory. It was found that two fit parameters were necessary to describe the temperature dependence of the nucleation rate.
Claudia Marcolli
Atmos. Chem. Phys., 17, 1595–1622, https://doi.org/10.5194/acp-17-1595-2017, https://doi.org/10.5194/acp-17-1595-2017, 2017
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Laboratory studies from the last century have shown that some types of particles are susceptible to pre-activation, i.e. they are able to develop macroscopic ice at warmer temperatures or lower relative humidities after they had been involved in an ice nucleation event before. This review analyses these works under the presumption that pre-activation occurs by ice preserved in pores, and it discusses atmospheric scenarios for which pre-activation might be important.
Lukas Kaufmann, Claudia Marcolli, Julian Hofer, Valeria Pinti, Christopher R. Hoyle, and Thomas Peter
Atmos. Chem. Phys., 16, 11177–11206, https://doi.org/10.5194/acp-16-11177-2016, https://doi.org/10.5194/acp-16-11177-2016, 2016
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We investigated dust samples from dust source regions all over the globe with respect to their ice nucleation activity and their mineralogical composition. Stones of reference minerals were milled and investigated the same way as the natural dust samples. We found that the mineralogical composition is a major determinant of ice nucleation ability. Natural samples consist of mixtures of minerals with remarkably similar ice nucleation ability.
Baban Nagare, Claudia Marcolli, André Welti, Olaf Stetzer, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8899–8914, https://doi.org/10.5194/acp-16-8899-2016, https://doi.org/10.5194/acp-16-8899-2016, 2016
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The relative importance of contact freezing and immersion freezing at mixed-phase cloud temperatures is the subject of debate. We performed experiments using continuous-flow diffusion chambers to compare the freezing efficiency of ice-nucleating particles for both these nucleation modes. Silver iodide, kaolinite and Arizona Test Dust were used as ice-nucleating particles. We could not confirm the dominance of contact freezing over immersion freezing for our experimental conditions.
Claudia Marcolli, Baban Nagare, André Welti, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8915–8937, https://doi.org/10.5194/acp-16-8915-2016, https://doi.org/10.5194/acp-16-8915-2016, 2016
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Silver iodide is one of the best-investigated ice nuclei. It has relevance for the atmosphere since it is used for glaciogenic cloud seeding. Nevertheless, many open questions remain. This paper gives an overview of silver iodide as an ice nucleus and tries to identify the factors that influence the ice nucleation ability of silver iodide.
Lindsay Renbaum-Wolff, Mijung Song, Claudia Marcolli, Yue Zhang, Pengfei F. Liu, James W. Grayson, Franz M. Geiger, Scot T. Martin, and Allan K. Bertram
Atmos. Chem. Phys., 16, 7969–7979, https://doi.org/10.5194/acp-16-7969-2016, https://doi.org/10.5194/acp-16-7969-2016, 2016
B. Nagare, C. Marcolli, O. Stetzer, and U. Lohmann
Atmos. Chem. Phys., 15, 13759–13776, https://doi.org/10.5194/acp-15-13759-2015, https://doi.org/10.5194/acp-15-13759-2015, 2015
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We determined collision efficiencies of cloud droplets with aerosol particles experimentally and found that they were around 1 order of magnitude higher than theoretical formulations that include Brownian diffusion, impaction, interception, thermophoretic, diffusiophoretic and electric forces. This is most probably due to uncertainties and inaccuracies in the theoretical formulations of thermophoretic and diffusiophoretic processes.
D. M. Lienhard, A. J. Huisman, U. K. Krieger, Y. Rudich, C. Marcolli, B. P. Luo, D. L. Bones, J. P. Reid, A. T. Lambe, M. R. Canagaratna, P. Davidovits, T. B. Onasch, D. R. Worsnop, S. S. Steimer, T. Koop, and T. Peter
Atmos. Chem. Phys., 15, 13599–13613, https://doi.org/10.5194/acp-15-13599-2015, https://doi.org/10.5194/acp-15-13599-2015, 2015
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New data of water diffusivity in secondary organic aerosol (SOA) material and organic/inorganic model mixtures is presented over an extensive temperature range. Our data suggest that water diffusion in SOA is sufficiently fast so that it is unlikely to have significant consequences on the direct climatic effect under tropospheric conditions. Glass formation in SOA is unlikely to restrict homogeneous ice nucleation.
E. Hammer, N. Bukowiecki, B. P. Luo, U. Lohmann, C. Marcolli, E. Weingartner, U. Baltensperger, and C. R. Hoyle
Atmos. Chem. Phys., 15, 10309–10323, https://doi.org/10.5194/acp-15-10309-2015, https://doi.org/10.5194/acp-15-10309-2015, 2015
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An important quantity which determines aerosol activation and cloud formation is the effective peak supersaturation. The box model ZOMM was used to simulate the effective peak supersaturation experienced by an air parcel approaching a high-alpine research station in Switzerland. With the box model the sensitivity of the effective peak supersaturation to key aerosol and dynamical parameters was investigated.
G. Ganbavale, A. Zuend, C. Marcolli, and T. Peter
Atmos. Chem. Phys., 15, 447–493, https://doi.org/10.5194/acp-15-447-2015, https://doi.org/10.5194/acp-15-447-2015, 2015
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This study presents a new, improved parameterisation of the temperature dependence of activity coefficients implemented in the AIOMFAC group-contribution model. The AIOMFAC model with the improved parameterisation is applicable for a large variety of aqueous organic as well as water-free organic solutions of relevance for atmospheric aerosols. The new model parameters were determined based on published and new thermodynamic equilibrium data covering a temperature range from ~190 to 440 K.
G. Ganbavale, C. Marcolli, U. K. Krieger, A. Zuend, G. Stratmann, and T. Peter
Atmos. Chem. Phys., 14, 9993–10012, https://doi.org/10.5194/acp-14-9993-2014, https://doi.org/10.5194/acp-14-9993-2014, 2014
C. Marcolli
Atmos. Chem. Phys., 14, 2071–2104, https://doi.org/10.5194/acp-14-2071-2014, https://doi.org/10.5194/acp-14-2071-2014, 2014
A. J. Huisman, U. K. Krieger, A. Zuend, C. Marcolli, and T. Peter
Atmos. Chem. Phys., 13, 6647–6662, https://doi.org/10.5194/acp-13-6647-2013, https://doi.org/10.5194/acp-13-6647-2013, 2013
Nadia Shardt, Florin N. Isenrich, Julia Nette, Christopher Dreimol, Ning Ma, Zamin A. Kanji, Andrew J. deMello, and Claudia Marcolli
EGUsphere, https://doi.org/10.5194/egusphere-2025-2958, https://doi.org/10.5194/egusphere-2025-2958, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
In the atmosphere, minerals suspended in cloud droplets promote the formation of ice. We investigated ice formation in the presence of pure and binary mixtures of common minerals using a microfluidic device. The mineral with the best ability to initiate ice formation alone (that is, at the highest temperature) typically determined when ice formed in the binary mixture.
Anna J. Miller, Christopher Fuchs, Fabiola Ramelli, Huiying Zhang, Nadja Omanovic, Robert Spirig, Claudia Marcolli, Zamin A. Kanji, Ulrike Lohmann, and Jan Henneberger
Atmos. Chem. Phys., 25, 5387–5407, https://doi.org/10.5194/acp-25-5387-2025, https://doi.org/10.5194/acp-25-5387-2025, 2025
Short summary
Short summary
We analyzed the ability of silver iodide particles (a commonly used cloud-seeding agent) to form ice crystals in naturally occurring liquid clouds at −5 to −8 °C and found that only ≈ 0.1 %−1 % of particles nucleate ice, with a negative dependence on temperature. By contextualizing our results with previous laboratory studies, we help to bridge the gap between laboratory and field experiments, which also helps to inform future cloud-seeding projects.
Joel Ponsonby, Roger Teoh, Bernd Kärcher, and Marc Stettler
EGUsphere, https://doi.org/10.5194/egusphere-2025-1717, https://doi.org/10.5194/egusphere-2025-1717, 2025
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Aerosol emissions from aircraft engines contribute to the formation of contrails, which have a climate impact comparable to that of aviation’s CO2 emissions. We show that emissions of volatile particulate matter – from fuel sulphur, unburned fuel, and lubrication oil – can increase the number of ice particles formed within a contrail, and therefore have an important role in the climate impacts of aviation. This has implications for emissions regulation and climate mitigation strategies.
Kai Lyu, Xiaohong Liu, and Bernd Kärcher
EGUsphere, https://doi.org/10.5194/egusphere-2024-4144, https://doi.org/10.5194/egusphere-2024-4144, 2025
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Two nucleation schemes are used to study ice nucleation, focusing on three ice sources: mountains, turbulence and anvils. Ice from mountains is concentrated in mid- and high-latitudes, while ice from turbulence and anvils is more common in low and mid-latitudes. Both schemes simulate orographic cirrus clouds, with mountain ice as the dominant source. The schemes differ in how they handle ice source competition, causing turbulence and anvils to influence clouds differently.
Judith Kleinheins, Nadia Shardt, Ulrike Lohmann, and Claudia Marcolli
Atmos. Chem. Phys., 25, 881–903, https://doi.org/10.5194/acp-25-881-2025, https://doi.org/10.5194/acp-25-881-2025, 2025
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We model the cloud condensation nuclei (CCN) activation of sea spray aerosol particles with classical Köhler theory and with a new model approach that takes surface tension lowering into account. We categorize organic compounds into weak, intermediate, and strong surfactants, and we outline for which composition surface tension lowering is important. The results suggest that surface tension lowering allows sea spray aerosol particles in the Aitken mode to be a source of CCN in marine updraughts.
Xiaoli Shen, David M. Bell, Hugh Coe, Naruki Hiranuma, Fabian Mahrt, Nicholas A. Marsden, Claudia Mohr, Daniel M. Murphy, Harald Saathoff, Johannes Schneider, Jacqueline Wilson, Maria A. Zawadowicz, Alla Zelenyuk, Paul J. DeMott, Ottmar Möhler, and Daniel J. Cziczo
Atmos. Chem. Phys., 24, 10869–10891, https://doi.org/10.5194/acp-24-10869-2024, https://doi.org/10.5194/acp-24-10869-2024, 2024
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Single-particle mass spectrometry (SPMS) is commonly used to measure the chemical composition and mixing state of aerosol particles. Intercomparison of SPMS instruments was conducted. All instruments reported similar size ranges and common spectral features. The instrument-specific detection efficiency was found to be more dependent on particle size than type. All differentiated secondary organic aerosol, soot, and soil dust but had difficulties differentiating among minerals and dusts.
Baptiste Testa, Lukas Durdina, Peter A. Alpert, Fabian Mahrt, Christopher H. Dreimol, Jacinta Edebeli, Curdin Spirig, Zachary C. J. Decker, Julien Anet, and Zamin A. Kanji
Atmos. Chem. Phys., 24, 4537–4567, https://doi.org/10.5194/acp-24-4537-2024, https://doi.org/10.5194/acp-24-4537-2024, 2024
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Laboratory experiments on the ice nucleation of real commercial aviation soot particles are investigated for their cirrus cloud formation potential. Our results show that aircraft-emitted soot in the upper troposphere will be poor ice-nucleating particles. Measuring the soot particle morphology and modifying their mixing state allow us to elucidate why these particles are ineffective at forming ice, in contrast to previously used soot surrogates.
Blaž Gasparini, Sylvia C. Sullivan, Adam B. Sokol, Bernd Kärcher, Eric Jensen, and Dennis L. Hartmann
Atmos. Chem. Phys., 23, 15413–15444, https://doi.org/10.5194/acp-23-15413-2023, https://doi.org/10.5194/acp-23-15413-2023, 2023
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Tropical cirrus clouds are essential for climate, but our understanding of these clouds is limited due to their dependence on a wide range of small- and large-scale climate processes. In this opinion paper, we review recent advances in the study of tropical cirrus clouds, point out remaining open questions, and suggest ways to resolve them.
Anand Kumar, Kristian Klumpp, Chen Barak, Giora Rytwo, Michael Plötze, Thomas Peter, and Claudia Marcolli
Atmos. Chem. Phys., 23, 4881–4902, https://doi.org/10.5194/acp-23-4881-2023, https://doi.org/10.5194/acp-23-4881-2023, 2023
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Smectites are a major class of clay minerals that are ice nucleation (IN) active. They form platelets that swell or even delaminate in water by intercalation of water between their layers. We hypothesize that at least three smectite layers need to be stacked together to host a critical ice embryo on clay mineral edges and that the larger the surface edge area is, the higher the freezing temperature. Edge sites on such clay particles play a crucial role in imparting IN ability to such particles.
Kristian Klumpp, Claudia Marcolli, Ana Alonso-Hellweg, Christopher H. Dreimol, and Thomas Peter
Atmos. Chem. Phys., 23, 1579–1598, https://doi.org/10.5194/acp-23-1579-2023, https://doi.org/10.5194/acp-23-1579-2023, 2023
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The prerequisites of a particle surface for efficient ice nucleation are still poorly understood. This study compares the ice nucleation activity of two chemically identical but morphologically different minerals (kaolinite and halloysite). We observe, on average, not only higher ice nucleation activities for halloysite than kaolinite but also higher diversity between individual samples. We identify the particle edges as being the most likely site for ice nucleation.
Fabian Mahrt, Carolin Rösch, Kunfeng Gao, Christopher H. Dreimol, Maria A. Zawadowicz, and Zamin A. Kanji
Atmos. Chem. Phys., 23, 1285–1308, https://doi.org/10.5194/acp-23-1285-2023, https://doi.org/10.5194/acp-23-1285-2023, 2023
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Major aerosol types emitted by biomass burning include soot, ash, and charcoal particles. Here, we investigated the ice nucleation activity of 400 nm size-selected particles of two different pyrolyis-derived charcoal types in the mixed phase and cirrus cloud regime. We find that ice nucleation is constrained to cirrus cloud conditions, takes place via pore condensation and freezing, and is largely governed by the particle porosity and mineral content.
Nikou Hamzehpour, Claudia Marcolli, Sara Pashai, Kristian Klumpp, and Thomas Peter
Atmos. Chem. Phys., 22, 14905–14930, https://doi.org/10.5194/acp-22-14905-2022, https://doi.org/10.5194/acp-22-14905-2022, 2022
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Playa surfaces in Iran that emerged through Lake Urmia (LU) desiccation have become a relevant dust source of regional relevance. Here, we identify highly erodible LU playa surfaces and determine their physicochemical properties and mineralogical composition and perform emulsion-freezing experiments with them. We find high ice nucleation activities (up to 250 K) that correlate positively with organic matter and clay content and negatively with pH, salinity, K-feldspars, and quartz.
Nikou Hamzehpour, Claudia Marcolli, Kristian Klumpp, Debora Thöny, and Thomas Peter
Atmos. Chem. Phys., 22, 14931–14956, https://doi.org/10.5194/acp-22-14931-2022, https://doi.org/10.5194/acp-22-14931-2022, 2022
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Dust aerosols from dried lakebeds contain mineral particles, as well as soluble salts and (bio-)organic compounds. Here, we investigate ice nucleation (IN) activity of dust samples from Lake Urmia playa, Iran. We find high IN activity of the untreated samples that decreases after organic matter removal but increases after removing soluble salts and carbonates, evidencing inhibiting effects of soluble salts and carbonates on the IN activity of organic matter and minerals, especially microcline.
Fabian Mahrt, Long Peng, Julia Zaks, Yuanzhou Huang, Paul E. Ohno, Natalie R. Smith, Florence K. A. Gregson, Yiming Qin, Celia L. Faiola, Scot T. Martin, Sergey A. Nizkorodov, Markus Ammann, and Allan K. Bertram
Atmos. Chem. Phys., 22, 13783–13796, https://doi.org/10.5194/acp-22-13783-2022, https://doi.org/10.5194/acp-22-13783-2022, 2022
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The number of condensed phases in mixtures of different secondary organic aerosol (SOA) types determines their impact on air quality and climate. Here we observe the number of phases in individual particles that contain mixtures of two different types of SOA. We find that SOA mixtures can form one- or two-phase particles, depending on the difference in the average oxygen-to-carbon (O / C) ratios of the two SOA types that are internally mixed within individual particles.
Florin N. Isenrich, Nadia Shardt, Michael Rösch, Julia Nette, Stavros Stavrakis, Claudia Marcolli, Zamin A. Kanji, Andrew J. deMello, and Ulrike Lohmann
Atmos. Meas. Tech., 15, 5367–5381, https://doi.org/10.5194/amt-15-5367-2022, https://doi.org/10.5194/amt-15-5367-2022, 2022
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Ice nucleation in the atmosphere influences cloud properties and lifetimes. Microfluidic instruments have recently been used to investigate ice nucleation, but these instruments are typically made out of a polymer that contributes to droplet instability over extended timescales and relatively high temperature uncertainty. To address these drawbacks, we develop and validate a new microfluidic instrument that uses fluoropolymer tubing to extend droplet stability and improve temperature accuracy.
Yu Wang, Aristeidis Voliotis, Dawei Hu, Yunqi Shao, Mao Du, Ying Chen, Judith Kleinheins, Claudia Marcolli, M. Rami Alfarra, and Gordon McFiggans
Atmos. Chem. Phys., 22, 4149–4166, https://doi.org/10.5194/acp-22-4149-2022, https://doi.org/10.5194/acp-22-4149-2022, 2022
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Aerosol water uptake plays a key role in atmospheric physicochemical processes. We designed chamber experiments on aerosol water uptake of secondary organic aerosol (SOA) from mixed biogenic and anthropogenic precursors with inorganic seed. Our results highlight this chemical composition influences the reconciliation of the sub- and super-saturated water uptake, providing laboratory evidence for understanding the chemical controls of water uptake of the multi-component aerosol.
Kristian Klumpp, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 22, 3655–3673, https://doi.org/10.5194/acp-22-3655-2022, https://doi.org/10.5194/acp-22-3655-2022, 2022
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Surface interactions with solutes can significantly alter the ice nucleation activity of mineral dust. Past studies revealed the sensitivity of microcline, one of the most ice-active types of dust in the atmosphere, to inorganic solutes. This study focuses on the interaction of microcline with bio-organic substances and the resulting effects on its ice nucleation activity. We observe strongly hampered ice nucleation activity due to the presence of carboxylic and amino acids but not for polyols.
Bernd Kärcher and Claudia Marcolli
Atmos. Chem. Phys., 21, 15213–15220, https://doi.org/10.5194/acp-21-15213-2021, https://doi.org/10.5194/acp-21-15213-2021, 2021
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Aerosol–cloud interactions play an important role in climate change. Simulations of the competition between homogeneous solution droplet freezing and heterogeneous ice nucleation can be compromised by the misapplication of ice-active particle fractions frequently derived from laboratory measurements or parametrizations. Our study frames the problem and establishes a solution that is easy to implement in cloud models.
Robert O. David, Jonas Fahrni, Claudia Marcolli, Fabian Mahrt, Dominik Brühwiler, and Zamin A. Kanji
Atmos. Chem. Phys., 20, 9419–9440, https://doi.org/10.5194/acp-20-9419-2020, https://doi.org/10.5194/acp-20-9419-2020, 2020
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Ice crystal formation plays an important role in controlling the Earth's climate. However, the mechanisms responsible for ice formation in the atmosphere are still uncertain. Here we use surrogates for atmospherically relevant porous particles to determine the role of pore diameter and wettability on the ability of porous particles to nucleate ice in the atmosphere. Our results are consistent with the pore condensation and freeing mechanism.
María Cascajo-Castresana, Robert O. David, Maiara A. Iriarte-Alonso, Alexander M. Bittner, and Claudia Marcolli
Atmos. Chem. Phys., 20, 3291–3315, https://doi.org/10.5194/acp-20-3291-2020, https://doi.org/10.5194/acp-20-3291-2020, 2020
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Atmospheric ice-nucleating particles are rare but relevant for cloud glaciation. A source of particles that nucleate ice above −15 °C is biological material including some proteins. Here we show that proteins of very diverse functions and structures can nucleate ice. Among these, the iron storage protein apoferritin stands out, with activity up to −4 °C. We show that its activity does not stem from correctly assembled proteins but from misfolded protein monomers or oligomers and aggregates.
Claudia Marcolli
Atmos. Chem. Phys., 20, 3209–3230, https://doi.org/10.5194/acp-20-3209-2020, https://doi.org/10.5194/acp-20-3209-2020, 2020
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Pore condensation and freezing (PCF) is an ice nucleation mechanism explaining ice formation at low ice supersaturation. It is assumed that liquid water condenses in pores of solid aerosol particles below water saturation followed by ice nucleation within the pores. This study discusses conditions of pore filling, homogeneous ice nucleation within the volume of porewater, and growth of ice out of the pores, taking the effect of negative pressure within pores below water saturation into account.
Robert O. David, Maria Cascajo-Castresana, Killian P. Brennan, Michael Rösch, Nora Els, Julia Werz, Vera Weichlinger, Lin S. Boynton, Sophie Bogler, Nadine Borduas-Dedekind, Claudia Marcolli, and Zamin A. Kanji
Atmos. Meas. Tech., 12, 6865–6888, https://doi.org/10.5194/amt-12-6865-2019, https://doi.org/10.5194/amt-12-6865-2019, 2019
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Here we present the development and applicability of the DRoplet Ice Nuclei Counter Zurich (DRINCZ). DRINCZ allows for ice nuclei in the immersion mode to be quantified between 0 and -25 °C with an uncertainty of ±0.9 °C. Furthermore, we present a new method for assessing biases in drop-freezing apparatuses and cumulative ice-nucleating-particle concentrations from snow samples collected in the Austrian Alps at the Sonnblick Observatory.
Fabian Mahrt, Jörg Wieder, Remo Dietlicher, Helen R. Smith, Chris Stopford, and Zamin A. Kanji
Atmos. Meas. Tech., 12, 3183–3208, https://doi.org/10.5194/amt-12-3183-2019, https://doi.org/10.5194/amt-12-3183-2019, 2019
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A new instrument, the High Speed Particle Phase Discriminator (PPD-HS), is presented, with the goal of quantifying liquid and ice fraction in conditions relevant for mixed-phase clouds. PPD-HS captures the near-forward spatial intensity distribution of scattered light on a single particle basis. Symmetry analysis of the scattering pattern is used to determine the shape of the particles, with cloud droplets and ice crystals producing symmetrical and asymmetrical scattering patterns, respectively.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6035–6058, https://doi.org/10.5194/acp-19-6035-2019, https://doi.org/10.5194/acp-19-6035-2019, 2019
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This paper not only interests the atmospheric science community but has a potential to cater to a broader audience. We discuss both long- and
short-term effects of various
atmospherically relevantchemical species on a fairly abundant mineral surface
Quartz. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Anand Kumar, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 19, 6059–6084, https://doi.org/10.5194/acp-19-6059-2019, https://doi.org/10.5194/acp-19-6059-2019, 2019
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This paper not only interests the Atmospheric Science community but has a potential to cater to a broader audience. We discuss both long- and short-term effects of various
atmospherically relevantchemical species on fairly abundant mineral surfaces like feldspars and clays. We of course discuss these chemical interactions from the perspective of fate of airborne mineral dust but the same interactions could be interesting for studies on minerals at the ground level.
Fabian Mahrt, Claudia Marcolli, Robert O. David, Philippe Grönquist, Eszter J. Barthazy Meier, Ulrike Lohmann, and Zamin A. Kanji
Atmos. Chem. Phys., 18, 13363–13392, https://doi.org/10.5194/acp-18-13363-2018, https://doi.org/10.5194/acp-18-13363-2018, 2018
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The ice nucleation ability of different soot particles in the cirrus and mixed-phase cloud temperature regime is presented. The impact of aerosol particle size, particle morphology, organic matter and hydrophilicity on ice nucleation is examined. We propose ice nucleation proceeds via a pore condensation freezing mechanism for soot particles with the necessary physicochemical properties that nucleated ice well below water saturation.
Anand Kumar, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 18, 7057–7079, https://doi.org/10.5194/acp-18-7057-2018, https://doi.org/10.5194/acp-18-7057-2018, 2018
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We have performed immersion freezing experiments with microcline (most active ice nucleation, IN, K-feldspar polymorph) and investigated the effect of ammonium and non-ammonium solutes on its IN efficiency. We report increased IN efficiency of microcline in dilute ammonia- or ammonium-containing solutions, which opens up a pathway for condensation freezing occurring at a warmer temperature than immersion freezing.
Ulrich K. Krieger, Franziska Siegrist, Claudia Marcolli, Eva U. Emanuelsson, Freya M. Gøbel, Merete Bilde, Aleksandra Marsh, Jonathan P. Reid, Andrew J. Huisman, Ilona Riipinen, Noora Hyttinen, Nanna Myllys, Theo Kurtén, Thomas Bannan, Carl J. Percival, and David Topping
Atmos. Meas. Tech., 11, 49–63, https://doi.org/10.5194/amt-11-49-2018, https://doi.org/10.5194/amt-11-49-2018, 2018
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Vapor pressures of low-volatility organic molecules at atmospheric temperatures reported in the literature often differ by several orders of magnitude between measurement techniques. These discrepancies exceed the stated uncertainty of each technique, which is generally reported to be smaller than a factor of 2. We determined saturation vapor pressures for the homologous series of polyethylene glycols ranging in vapor pressure at 298 K from 1E−7 Pa to 5E−2 Pa as a reference set.
Lisa Stirnweis, Claudia Marcolli, Josef Dommen, Peter Barmet, Carla Frege, Stephen M. Platt, Emily A. Bruns, Manuel Krapf, Jay G. Slowik, Robert Wolf, Andre S. H. Prévôt, Urs Baltensperger, and Imad El-Haddad
Atmos. Chem. Phys., 17, 5035–5061, https://doi.org/10.5194/acp-17-5035-2017, https://doi.org/10.5194/acp-17-5035-2017, 2017
Lukas Kaufmann, Claudia Marcolli, Beiping Luo, and Thomas Peter
Atmos. Chem. Phys., 17, 3525–3552, https://doi.org/10.5194/acp-17-3525-2017, https://doi.org/10.5194/acp-17-3525-2017, 2017
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To improve the understanding of heterogeneous ice nucleation, we have subjected different ice nuclei to repeated freezing cycles and evaluated the freezing temperatures with different parameterizations of classical nucleation theory. It was found that two fit parameters were necessary to describe the temperature dependence of the nucleation rate.
Claudia Marcolli
Atmos. Chem. Phys., 17, 1595–1622, https://doi.org/10.5194/acp-17-1595-2017, https://doi.org/10.5194/acp-17-1595-2017, 2017
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Laboratory studies from the last century have shown that some types of particles are susceptible to pre-activation, i.e. they are able to develop macroscopic ice at warmer temperatures or lower relative humidities after they had been involved in an ice nucleation event before. This review analyses these works under the presumption that pre-activation occurs by ice preserved in pores, and it discusses atmospheric scenarios for which pre-activation might be important.
Lukas Kaufmann, Claudia Marcolli, Julian Hofer, Valeria Pinti, Christopher R. Hoyle, and Thomas Peter
Atmos. Chem. Phys., 16, 11177–11206, https://doi.org/10.5194/acp-16-11177-2016, https://doi.org/10.5194/acp-16-11177-2016, 2016
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We investigated dust samples from dust source regions all over the globe with respect to their ice nucleation activity and their mineralogical composition. Stones of reference minerals were milled and investigated the same way as the natural dust samples. We found that the mineralogical composition is a major determinant of ice nucleation ability. Natural samples consist of mixtures of minerals with remarkably similar ice nucleation ability.
Baban Nagare, Claudia Marcolli, André Welti, Olaf Stetzer, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8899–8914, https://doi.org/10.5194/acp-16-8899-2016, https://doi.org/10.5194/acp-16-8899-2016, 2016
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The relative importance of contact freezing and immersion freezing at mixed-phase cloud temperatures is the subject of debate. We performed experiments using continuous-flow diffusion chambers to compare the freezing efficiency of ice-nucleating particles for both these nucleation modes. Silver iodide, kaolinite and Arizona Test Dust were used as ice-nucleating particles. We could not confirm the dominance of contact freezing over immersion freezing for our experimental conditions.
Claudia Marcolli, Baban Nagare, André Welti, and Ulrike Lohmann
Atmos. Chem. Phys., 16, 8915–8937, https://doi.org/10.5194/acp-16-8915-2016, https://doi.org/10.5194/acp-16-8915-2016, 2016
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Silver iodide is one of the best-investigated ice nuclei. It has relevance for the atmosphere since it is used for glaciogenic cloud seeding. Nevertheless, many open questions remain. This paper gives an overview of silver iodide as an ice nucleus and tries to identify the factors that influence the ice nucleation ability of silver iodide.
Lindsay Renbaum-Wolff, Mijung Song, Claudia Marcolli, Yue Zhang, Pengfei F. Liu, James W. Grayson, Franz M. Geiger, Scot T. Martin, and Allan K. Bertram
Atmos. Chem. Phys., 16, 7969–7979, https://doi.org/10.5194/acp-16-7969-2016, https://doi.org/10.5194/acp-16-7969-2016, 2016
B. Nagare, C. Marcolli, O. Stetzer, and U. Lohmann
Atmos. Chem. Phys., 15, 13759–13776, https://doi.org/10.5194/acp-15-13759-2015, https://doi.org/10.5194/acp-15-13759-2015, 2015
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We determined collision efficiencies of cloud droplets with aerosol particles experimentally and found that they were around 1 order of magnitude higher than theoretical formulations that include Brownian diffusion, impaction, interception, thermophoretic, diffusiophoretic and electric forces. This is most probably due to uncertainties and inaccuracies in the theoretical formulations of thermophoretic and diffusiophoretic processes.
D. M. Lienhard, A. J. Huisman, U. K. Krieger, Y. Rudich, C. Marcolli, B. P. Luo, D. L. Bones, J. P. Reid, A. T. Lambe, M. R. Canagaratna, P. Davidovits, T. B. Onasch, D. R. Worsnop, S. S. Steimer, T. Koop, and T. Peter
Atmos. Chem. Phys., 15, 13599–13613, https://doi.org/10.5194/acp-15-13599-2015, https://doi.org/10.5194/acp-15-13599-2015, 2015
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New data of water diffusivity in secondary organic aerosol (SOA) material and organic/inorganic model mixtures is presented over an extensive temperature range. Our data suggest that water diffusion in SOA is sufficiently fast so that it is unlikely to have significant consequences on the direct climatic effect under tropospheric conditions. Glass formation in SOA is unlikely to restrict homogeneous ice nucleation.
E. Hammer, N. Bukowiecki, B. P. Luo, U. Lohmann, C. Marcolli, E. Weingartner, U. Baltensperger, and C. R. Hoyle
Atmos. Chem. Phys., 15, 10309–10323, https://doi.org/10.5194/acp-15-10309-2015, https://doi.org/10.5194/acp-15-10309-2015, 2015
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An important quantity which determines aerosol activation and cloud formation is the effective peak supersaturation. The box model ZOMM was used to simulate the effective peak supersaturation experienced by an air parcel approaching a high-alpine research station in Switzerland. With the box model the sensitivity of the effective peak supersaturation to key aerosol and dynamical parameters was investigated.
G. Ganbavale, A. Zuend, C. Marcolli, and T. Peter
Atmos. Chem. Phys., 15, 447–493, https://doi.org/10.5194/acp-15-447-2015, https://doi.org/10.5194/acp-15-447-2015, 2015
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This study presents a new, improved parameterisation of the temperature dependence of activity coefficients implemented in the AIOMFAC group-contribution model. The AIOMFAC model with the improved parameterisation is applicable for a large variety of aqueous organic as well as water-free organic solutions of relevance for atmospheric aerosols. The new model parameters were determined based on published and new thermodynamic equilibrium data covering a temperature range from ~190 to 440 K.
G. Ganbavale, C. Marcolli, U. K. Krieger, A. Zuend, G. Stratmann, and T. Peter
Atmos. Chem. Phys., 14, 9993–10012, https://doi.org/10.5194/acp-14-9993-2014, https://doi.org/10.5194/acp-14-9993-2014, 2014
M. Kuebbeler, U. Lohmann, J. Hendricks, and B. Kärcher
Atmos. Chem. Phys., 14, 3027–3046, https://doi.org/10.5194/acp-14-3027-2014, https://doi.org/10.5194/acp-14-3027-2014, 2014
C. Marcolli
Atmos. Chem. Phys., 14, 2071–2104, https://doi.org/10.5194/acp-14-2071-2014, https://doi.org/10.5194/acp-14-2071-2014, 2014
A. J. Huisman, U. K. Krieger, A. Zuend, C. Marcolli, and T. Peter
Atmos. Chem. Phys., 13, 6647–6662, https://doi.org/10.5194/acp-13-6647-2013, https://doi.org/10.5194/acp-13-6647-2013, 2013
Related subject area
Subject: Clouds and Precipitation | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Sensitivities of simulated mixed-phase Arctic multilayer clouds to primary and secondary ice processes
Assessing glaciogenic seeding impacts in Australia's Snowy Mountains: an ensemble modeling approach
How the representation of microphysical processes affects tropical condensate in the global storm-resolving model ICON
Magnitude and timescale of liquid water path adjustments to cloud droplet number concentration perturbations for nocturnal non-precipitating marine stratocumulus
Cold pools mediate mesoscale adjustments of trade-cumulus fields to changes in cloud droplet number concentration
Numerical case study of the aerosol–cloud interactions in warm boundary layer clouds over the eastern North Atlantic with an interactive chemistry module
Influence of temperature and humidity on contrail formation regions in the general circulation model EMAC: a spring case study
On the impact of thunder on cloud ice crystals and droplets
Counteracting influences of gravitational settling modulate aerosol impacts on cloud-base-lowering fog characteristics
The critical number and size of precipitation embryos to accelerate warm rain initiation
Impact on the stratocumulus-to-cumulus transition of the interaction of cloud microphysics and macrophysics with large-scale circulation
Technical note: Phase space depiction of cloud condensation nuclei activation and cloud droplet diffusional growth
Impact of wildfire smoke on Arctic cirrus formation – Part 2: Simulation of MOSAiC 2019–2020 cases
Constraining aerosol–cloud adjustments by uniting surface observations with a perturbed parameter ensemble
Investigating ice formation pathways using a novel two-moment multi-class cloud microphysics scheme
Exploiting airborne far-infrared measurements to optimise an ice cloud retrieval
Microphysics regimes due to haze–cloud interactions: cloud oscillation and cloud collapse
Microphysical fingerprints in anvil cloud albedo
Influence of Secondary Ice Production on cloud and rain properties: Analysis of the HYMEX IOP7a Heavy Precipitation Event
Factors Causing Stratocumulus to Deviate from Subtropical High Variability on Seasonal to Interannual Timescales
The influence of Amazonian anthropogenic emissions on new particle formation, aerosol, cloud and surface rain
Impact of secondary ice production on thunderstorm electrification under different aerosol conditions
Accelerated impact of airborne glaciogenic seeding of stratiform clouds by turbulence
Tropical cirrus evolution in a km-scale model with improved ice microphysics
Model analysis of biases in the satellite-diagnosed aerosol effect on the cloud liquid water path
Impacts of aerosol-radiation and aerosol-cloud interactions on a short-term heavy rainfall event – A case study in the Guanzhong Basin, China
Evaluation of biases in mid-to-high-latitude surface snowfall and cloud phase in ERA5 and CMIP6 using satellite observations
Failed cyclogenesis of a mesoscale convective system near Cape Verde: The role of the Saharan trade wind layer among other inhibiting factors observed during the CADDIWA field campaign
Dynamical imprints on precipitation cluster statistics across a hierarchy of high-resolution simulations
Ice formation processes key in determining WCB outflow cirrus properties
Role of a key microphysical factor in mixed-phase stratocumulus clouds and their interactions with aerosols
High-resolution modelling of early contrail evolution from hydrogen-powered aircraft
Investigating the impact of subgrid-scale aerosol-cloud interaction on mesoscale meteorology prediction
Correction of ERA5 temperature and relative humidity biases by bivariate quantile mapping for contrail formation analysis
Can pollen affect precipitation?
Potential impacts of marine fuel regulations on an Arctic stratocumulus case and its radiative response
The impact of the mesh size and microphysics scheme on the representation of mid-level clouds in the ICON model in hilly and complex terrain
The role of ascent timescales for warm conveyor belt (WCB) moisture transport into the upper troposphere and lower stratosphere (UTLS)
On the Processes Determining the Slope of Cloud-Water Adjustments in Non-Precipitating Stratocumulus
High sensitivity of simulated fog properties to parameterized aerosol activation in case studies from ParisFog
Adiabatic and radiative cooling are both important causes of aerosol activation in simulated fog events in Europe
Estimating the concentration of silver iodide needed to detect unambiguous signatures of glaciogenic cloud seeding
Ice-nucleating particle concentration impacts cloud properties over Dronning Maud Land, East Antarctica, in COSMO-CLM2
Numerical simulation of aerosol concentration effects on cloud droplet size spectrum evolutions of warm stratiform clouds in Jiangxi, China
The impact of aerosol on cloud water: a heuristic perspective
The presence of clouds lowers climate sensitivity in the MPI-ESM1.2 climate model
Diurnal variation in an amplified canopy urban heat island during heat wave periods in the megacity of Beijing: roles of mountain–valley breeze and urban morphology
Diurnal evolution of non-precipitating marine stratocumuli in a large-eddy simulation ensemble
Ambient and Intrinsic Dependencies of Evolving Ice-Phase Particles within a Decaying Winter Storm During IMPACTS
Adjustments to an abrupt solar forcing in the CMIP6 abrupt-solm4p experiment
Gabriella Wallentin, Annika Oertel, Luisa Ickes, Peggy Achtert, Matthias Tesche, and Corinna Hoose
Atmos. Chem. Phys., 25, 6607–6631, https://doi.org/10.5194/acp-25-6607-2025, https://doi.org/10.5194/acp-25-6607-2025, 2025
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Multilayer clouds are common in the Arctic but remain underrepresented. We use an atmospheric model to simulate multilayer cloud cases from the Arctic expedition MOSAiC 2019/2020. We find that it is complex to accurately model these cloud layers due to the lack of correct temperature profiles. The model also struggles to capture the observed cloud phase and the relative concentration of cloud droplets and cloud ice. We constrain our model to measured aerosols to mitigate this issue.
Sisi Chen, Lulin Xue, Sarah A. Tessendorf, Thomas Chubb, Andrew Peace, Suzanne Kenyon, Johanna Speirs, Jamie Wolff, and Bill Petzke
Atmos. Chem. Phys., 25, 6703–6724, https://doi.org/10.5194/acp-25-6703-2025, https://doi.org/10.5194/acp-25-6703-2025, 2025
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This study aims to investigate how cloud seeding affects snowfall in Australia's Snowy Mountains. By running simulations with different setups, we found that seeding impact varies greatly with weather conditions. Seeding increased snow in stable weather but sometimes reduced it in stormy weather. This helps us to better understand when seeding works best to boost water supplies.
Ann Kristin Naumann, Monika Esch, and Bjorn Stevens
Atmos. Chem. Phys., 25, 6429–6444, https://doi.org/10.5194/acp-25-6429-2025, https://doi.org/10.5194/acp-25-6429-2025, 2025
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This study explores how uncertainties in the representation of microphysical processes affect the tropical condensate distribution in the global storm-resolving model ICON. The results point to the importance of the fall speed of hydrometeor particles and to a simple relationship: the faster a condensate falls, the less there is of it. Implications for the energy balance and precipitation properties are discussed.
Yao-Sheng Chen, Prasanth Prabhakaran, Fabian Hoffmann, Jan Kazil, Takanobu Yamaguchi, and Graham Feingold
Atmos. Chem. Phys., 25, 6141–6159, https://doi.org/10.5194/acp-25-6141-2025, https://doi.org/10.5194/acp-25-6141-2025, 2025
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Injecting sea salt aerosols into marine stratiform clouds can distribute the cloud water over more droplets in smaller sizes. This process is expected to make the clouds brighter, allowing them to reflect more sunlight back to space. However, it may also cause the clouds to lose water over time, reducing their ability to reflect sunlight. We use a computer model to show that the loss of cloud water occurs relatively quickly and does not completely offset the initial brightening.
Pouriya Alinaghi, Fredrik Jansson, Daniel A. Blázquez, and Franziska Glassmeier
Atmos. Chem. Phys., 25, 6121–6139, https://doi.org/10.5194/acp-25-6121-2025, https://doi.org/10.5194/acp-25-6121-2025, 2025
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Shallow clouds in the trades are a major source of uncertainty in climate projections. These clouds organize into striking mesoscale patterns that are exactly what climate models lack. This study explores the origin of such patterns and investigates how variations in microscale properties control them. The importance of microscale effects is compared to that of large-scale forcing on the mesoscale organization of trade-cumulus fields.
Hsiang-He Lee, Xue Zheng, Shaoyue Qiu, and Yuan Wang
Atmos. Chem. Phys., 25, 6069–6091, https://doi.org/10.5194/acp-25-6069-2025, https://doi.org/10.5194/acp-25-6069-2025, 2025
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The study investigates how aerosol–cloud interactions affect warm boundary layer stratiform clouds over the eastern North Atlantic. High-resolution weather model simulations reveal that non-rain clouds at the edge of cloud systems are prone to evaporation, leading to an aerosol drying effect and a transition of aerosols back to the accumulation mode for future activation. The study shows that this dynamic behavior is often not adequately represented in most previous prescribed-aerosol simulations.
Patrick Peter, Sigrun Matthes, Christine Frömming, Patrick Jöckel, Luca Bugliaro, Andreas Giez, Martina Krämer, and Volker Grewe
Atmos. Chem. Phys., 25, 5911–5934, https://doi.org/10.5194/acp-25-5911-2025, https://doi.org/10.5194/acp-25-5911-2025, 2025
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Our study examines how well the global climate model EMAC (ECHAM/MESSy Atmospheric Chemistry) predicts contrail formation by analysing temperature and humidity – two key factors for contrail development and persistence. The model underestimates temperature, leading to an overprediction of contrail formation and larger ice-supersaturated regions. Adjusting the model improves temperature accuracy but adds uncertainties. Better predictions of contrail formation areas can help optimise flight tracks to reduce aviation's climate effect.
Konstantinos Kourtidis, Stavros Stathopoulos, and Vassilis Amiridis
Atmos. Chem. Phys., 25, 5935–5946, https://doi.org/10.5194/acp-25-5935-2025, https://doi.org/10.5194/acp-25-5935-2025, 2025
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The sound of thunder induces mechanical effects on cloud droplets and ice particles, causing changes in their size distribution. A shock wave near the lightning channel causes extensive shattering of cloud particles. At a distance, the audio wave will cause agglomeration of particles. So, thunder may influence the rain generation process and the radiative properties of clouds. As global warming may influence the occurrence rate of lightning, a climate feedback may be induced by these mechanisms.
Nathan H. Pope and Adele L. Igel
Atmos. Chem. Phys., 25, 5433–5444, https://doi.org/10.5194/acp-25-5433-2025, https://doi.org/10.5194/acp-25-5433-2025, 2025
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We used an atmospheric model that simulates a single column to study the sensitivity of marine fog formed through the lowering of the base of a stratus cloud to meteorology and aerosols. We found that higher aerosol concentration reduces the likelihood and duration of fog but leads to denser fog. This overall trend was caused by multiple physical mechanisms depending on conditions.
Jung-Sub Lim, Yign Noh, Hyunho Lee, and Fabian Hoffmann
Atmos. Chem. Phys., 25, 5313–5329, https://doi.org/10.5194/acp-25-5313-2025, https://doi.org/10.5194/acp-25-5313-2025, 2025
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Rain formation in warm clouds begins when small droplets collide, but this process can be slow without larger droplets. We used simulations to explore the role of bigger droplets, known as precipitation embryos, in triggering rain. We found that they speed up rain only when their size and number exceed a critical threshold. This threshold becomes larger when collisions are naturally efficient, such as in clouds with broad droplet size distributions or strong turbulence.
Je-Yun Chun, Robert Wood, Peter N. Blossey, and Sarah J. Doherty
Atmos. Chem. Phys., 25, 5251–5271, https://doi.org/10.5194/acp-25-5251-2025, https://doi.org/10.5194/acp-25-5251-2025, 2025
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This study explores how aerosols affect clouds transitioning from stratocumulus to cumulus along trade winds under varying atmospheric conditions. We found that aerosols typically reduce precipitation and raise cloud height, but their impact changes when subsidence changes by aerosol enhancement are considered. Our findings indicate that the cooling effect of aerosols might be overestimated if these atmospheric changes are not accounted for.
Wojciech W. Grabowski and Hanna Pawlowska
Atmos. Chem. Phys., 25, 5273–5285, https://doi.org/10.5194/acp-25-5273-2025, https://doi.org/10.5194/acp-25-5273-2025, 2025
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A simple diagram to depict cloud droplets' formation via the activation of cloud condensation nuclei (CCN) as well as their subsequent growth and evaporation is presented.
Albert Ansmann, Cristofer Jimenez, Daniel A. Knopf, Johanna Roschke, Johannes Bühl, Kevin Ohneiser, and Ronny Engelmann
Atmos. Chem. Phys., 25, 4867–4884, https://doi.org/10.5194/acp-25-4867-2025, https://doi.org/10.5194/acp-25-4867-2025, 2025
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In this study, we focus on the potential impact of wildfire smoke on cirrus formation. Aerosol and cirrus observations with lidar and radar during the MOSAiC (Multidisciplinary drifting Observatory for the Study of Arctic Climate) expedition, presented in the companion paper (Ansmann et al., 2025), are closely linked to comprehensive modeling of ice nucleation in cirrus evolution processes, presented in this article. A clear impact of wildfire smoke on cirrus formation was found.
August Mikkelsen, Daniel T. McCoy, Trude Eidhammer, Andrew Gettelman, Ci Song, Hamish Gordon, and Isabel L. McCoy
Atmos. Chem. Phys., 25, 4547–4570, https://doi.org/10.5194/acp-25-4547-2025, https://doi.org/10.5194/acp-25-4547-2025, 2025
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Whether increased aerosol increases or decreases liquid cloud mass has been a longstanding question. Observed correlations suggest that aerosols thin liquid cloud, but we are able to show that observations were consistent with an increase in liquid cloud in response to aerosols by leveraging a model where causality could be traced.
Tim Lüttmer, Peter Spichtinger, and Axel Seifert
Atmos. Chem. Phys., 25, 4505–4529, https://doi.org/10.5194/acp-25-4505-2025, https://doi.org/10.5194/acp-25-4505-2025, 2025
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We investigate ice formation pathways in idealized convective clouds using a novel microphysics scheme that distinguishes between five ice classes each with their own unique formation mechanism. Ice crystals from rime splintering form the lowermost layer of ice crystals around the updraft core. The majority of ice crystals in the anvil of the convective cloud stems from frozen droplets. Ice stemming from homogeneous and deposition nucleation was only relevant in the overshoot.
Sanjeevani Panditharatne, Helen Brindley, Caroline Cox, Rui Song, Richard Siddans, Richard Bantges, Jonathan Murray, Stuart Fox, and Cathryn Fox
EGUsphere, https://doi.org/10.5194/egusphere-2025-647, https://doi.org/10.5194/egusphere-2025-647, 2025
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Upwelling radiation with wavelengths between 15 and 100 microns is theorised to be highly sensitive to the properties of ice clouds, particularly the shape of the ice crystals. We exploit this sensitivity and perform the first retrieval of ice cloud properties using these wavelengths from an observation taken on an aircraft and evaluate it against measurements of the cloud’s properties.
Fan Yang, Hamed Fahandezh Sadi, Raymond A. Shaw, Fabian Hoffmann, Pei Hou, Aaron Wang, and Mikhail Ovchinnikov
Atmos. Chem. Phys., 25, 3785–3806, https://doi.org/10.5194/acp-25-3785-2025, https://doi.org/10.5194/acp-25-3785-2025, 2025
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Large-eddy simulations of a convection cloud chamber show two new microphysics regimes, cloud oscillation and cloud collapse, due to haze–cloud interactions. Our results suggest that haze particles and their interactions with cloud droplets should be considered especially in polluted conditions. To properly simulate haze–cloud interactions, we need to resolve droplet activation and deactivation processes, instead of using Twomey-type activation parameterization.
Declan L. Finney, Alan M. Blyth, Paul R. Field, Martin I. Daily, Benjamin J. Murray, Mengyu Sun, Paul J. Connolly, Zhiqiang Cui, and Steven Böing
EGUsphere, https://doi.org/10.5194/egusphere-2025-1227, https://doi.org/10.5194/egusphere-2025-1227, 2025
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We present observation-informed modelling from the Deep Convective Microphysics Experiment to study how environmental conditions and cloud processes affect anvil cloud albedo and radiation. Aerosols influencing cloud droplets or influencing ice formation yield varying radiative effects. We introduce fingerprint metrics to discern these effects. Using detailed observations and modelling, we offer insights into high cloud radiative effects and feedbacks.
Pierre Grzegorczyk, Wolfram Wobrock, Aymeric Dziduch, and Céline Planche
EGUsphere, https://doi.org/10.5194/egusphere-2025-819, https://doi.org/10.5194/egusphere-2025-819, 2025
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The impact of secondary ice production (SIP) on a HYMEX intense precipitation event is investigated using 3D bin microphysics. Including SIP improves agreement with in situ aircraft observations (ice crystal number concentration and supercooled drop number fraction), generates small ice crystals and redistributes condensed water mass toward smaller particle sizes. As these crystals melt, the liquid precipitation flux decreases, reducing total precipitation by 8 % and heavy rainfall by 20 %.
Hairu Ding, Bjorn Stevens, and Hauke Schmidt
EGUsphere, https://doi.org/10.5194/egusphere-2025-876, https://doi.org/10.5194/egusphere-2025-876, 2025
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This study examines the physical link between subtropical highs and stratocumulus variability. Using reanalysis data, we test two proposed pathways—one at the surface and one in the free troposphere—but find that neither is a dominant mechanism for stratocumulus variability on seasonal and interannual timescales. These results challenge the assumed influence of subtropical highs on stratocumulus and highlight the need for further research into lower tropospheric stability dynamics.
Xuemei Wang, Kenneth S. Carslaw, Daniel P. Grosvenor, and Hamish Gordon
EGUsphere, https://doi.org/10.5194/egusphere-2025-132, https://doi.org/10.5194/egusphere-2025-132, 2025
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Anthropogenic emissions can influence aerosol particle number concentrations via new particle formation. Our model simulations predict around 10 % increase of the particle and cloud droplet number concentrations when doubling the emissions in the Manaus region in the Amazonian wet season. However, the corresponding changes in cloud water and rain mass are around 4 %. Such weak response implied that this convective environment is not sensitive to the localised anthropogenic emission changes here.
Shiye Huang, Jing Yang, Jiaojiao Li, Qian Chen, Qilin Zhang, and Fengxia Guo
Atmos. Chem. Phys., 25, 1831–1850, https://doi.org/10.5194/acp-25-1831-2025, https://doi.org/10.5194/acp-25-1831-2025, 2025
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Aerosol and secondary ice production are both vital to charge separation in thunderstorms, but the relative importance of different SIP processes to cloud electrification under different aerosol conditions is not well understood. In this study, we show in a clean environment, the shattering of freezing drops has the greatest effect on the charging rate, while in a polluted environment, both rime splintering and the shattering of freezing drops have a significant effect on cloud electrification.
Meilian Chen, Xiaoqin Jing, Jiaojiao Li, Jing Yang, Xiaobo Dong, Bart Geerts, Yan Yin, Baojun Chen, Lulin Xue, Mengyu Huang, Ping Tian, and Shaofeng Hua
EGUsphere, https://doi.org/10.5194/egusphere-2025-47, https://doi.org/10.5194/egusphere-2025-47, 2025
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Several recent studies have reported complete cloud glaciation induced by airborne-based glaciogenic cloud seeding over plains. Since turbulence is an important factor to maintain clouds in mixed-phase, it is hypothesized that turbulence may have an impact on the seeding effect. This hypothesis is evident in the present study, which shows turbulence can accelerate the impact of airborne glaciogenic seeding of stratiform clouds.
Blaž Gasparini, Rachel Atlas, Aiko Voigt, Martina Krämer, and Peter N. Blossey
EGUsphere, https://doi.org/10.5194/egusphere-2025-203, https://doi.org/10.5194/egusphere-2025-203, 2025
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Tropical cirrus clouds, especially their evolution, are poorly understood, contributing to uncertainty in climate projections. We address this by using novel tracers in a cloud-resolving model to track the life cycle of cirrus clouds, providing insights into cloud formation, ice crystal evolution, and radiative effects. We also improve the model's cloud microphysics with a simple, computationally efficient approach that can be applied to other models.
Harri Kokkola, Juha Tonttila, Silvia M. Calderón, Sami Romakkaniemi, Antti Lipponen, Aapo Peräkorpi, Tero Mielonen, Edward Gryspeerdt, Timo Henrik Virtanen, Pekka Kolmonen, and Antti Arola
Atmos. Chem. Phys., 25, 1533–1543, https://doi.org/10.5194/acp-25-1533-2025, https://doi.org/10.5194/acp-25-1533-2025, 2025
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Understanding how atmospheric aerosols affect clouds is a scientific challenge. One question is how aerosols affects the amount of cloud water. We used a cloud-scale model to study these effects on marine clouds. The study showed that variations in cloud properties and instrument noise can cause bias in satellite-derived cloud water content. However, our results suggest that for similar weather conditions with well-defined aerosol concentrations, satellite data can reliably track these effects.
Naifang Bei, Bo Xiao, Ruonan Wang, Yuning Yang, Lang Liu, Yongming Han, and Guohui Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-3558, https://doi.org/10.5194/egusphere-2024-3558, 2025
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This study uses a cloud-resolving model to examine how aerosols influence a mesoscale convective system (MCS) in central China via aerosol-radiation (ARIs) and aerosol-cloud interactions (ACIs). Without ARIs, added aerosols don’t significantly affect precipitation due to cloud competition for moisture. ARIs can stabilize or enhance convection. High aerosol levels lead to a combined ARI and ACI effect that greatly reduces precipitation.
Franziska Hellmuth, Tim Carlsen, Anne Sophie Daloz, Robert Oscar David, Haochi Che, and Trude Storelvmo
Atmos. Chem. Phys., 25, 1353–1383, https://doi.org/10.5194/acp-25-1353-2025, https://doi.org/10.5194/acp-25-1353-2025, 2025
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This article compares the occurrence of supercooled liquid-containing clouds (sLCCs) and their link to surface snowfall in CloudSat–CALIPSO, ERA5, and the CMIP6 models. Significant discrepancies were found, with ERA5 and CMIP6 consistently overestimating sLCC and snowfall frequency. This bias is likely due to cloud microphysics parameterization. This conclusion has implications for accurately representing cloud phase and snowfall in future climate projections.
Guillaume Feger, Jean-Pierre Chaboureau, Thibaut Dauhut, Julien Delanoë, and Pierre Coutris
EGUsphere, https://doi.org/10.5194/egusphere-2025-105, https://doi.org/10.5194/egusphere-2025-105, 2025
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The Saharan air at trade wind layer, cold pools, and upper tropospheric dry air are identified as the three main factors inhibiting the cyclogenesis of the Pierre Henri mesoscale convective system. The findings were obtained trough observations made during two flights of the CADDIWA campaign and a convection-permitting simulation run with the Meso-NH model. They provide new insights into the complex dynamics of cyclogenesis in the Cape Verde region and challenge the existing model of the SAL.
Claudia Christine Stephan and Bjorn Stevens
Atmos. Chem. Phys., 25, 1209–1226, https://doi.org/10.5194/acp-25-1209-2025, https://doi.org/10.5194/acp-25-1209-2025, 2025
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Tropical precipitation cluster area and intensity distributions follow power laws, but the physical processes responsible for this behavior remain unknown. We analyze global simulations that realistically represent precipitation processes. We consider Earth-like planets as well as virtual planets to realize different types of large-scale dynamics. Our finding is that power laws in Earth’s precipitation cluster statistics stem from the robust power laws in Earth’s atmospheric wind field.
Tim Lüttmer, Annette Miltenberger, and Peter Spichtinger
EGUsphere, https://doi.org/10.5194/egusphere-2025-185, https://doi.org/10.5194/egusphere-2025-185, 2025
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We investigate ice formation pathways in a warm conveyor belt case study. We employ a multi-phase microphysics scheme that distinguishes between ice from different nucleation processes. Ice crystals in the cirrus outflow mostly stem from in-situ formation. Hence they were formed directly from the vapor phase. Sedimentational redistribution modulates cirrus properties and leads to a disagreement between cirrus origin classifications based on thermodynamic history and nucleation processes.
Seoung Soo Lee, Chang Hoon Jung, Jinho Choi, Young Jun Yoon, Junshik Um, Youtong Zheng, Jianping Guo, Manguttathil G. Manoj, Sang-Keun Song, and Kyung-Ja Ha
Atmos. Chem. Phys., 25, 705–726, https://doi.org/10.5194/acp-25-705-2025, https://doi.org/10.5194/acp-25-705-2025, 2025
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This study attempts to test a general factor that explains differences in the properties of different mixed-phase clouds using a modeling tool. Although this attempt is not to identify a factor that can perfectly explain and represent the properties of different mixed-phase clouds, we believe that this attempt acts as a valuable stepping stone towards a more complete, general way of using climate models to better predict climate change.
Annemarie Lottermoser and Simon Unterstraßer
EGUsphere, https://doi.org/10.5194/egusphere-2024-3859, https://doi.org/10.5194/egusphere-2024-3859, 2025
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Contrail-cirrus significantly contributes to aviation's overall climate impact. As hydrogen combustion and fuel cell use are emerging technologies for aircraft propulsion, we simulated individual contrails from hydrogen propulsion during the first six minutes after exhaust emission, termed the vortex phase. The ice crystal loss during that stage is crucial as the number of ice crystals has a large impact on the further evolution of contrails into contrail-cirrus and their radiative forcing.
Wenjie Zhang, Hong Wang, Xiaoye Zhang, Yue Peng, Zhaodong Liu, Deying Wang, Da Zhang, Chen Han, Yang Zhao, Junting Zhong, Wenxing Jia, Huiqiong Ning, and Huizheng Che
EGUsphere, https://doi.org/10.5194/egusphere-2024-3677, https://doi.org/10.5194/egusphere-2024-3677, 2025
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We implement a real-time subgrid-scale aerosol-cloud interaction (ACI) mechanism in a mesoscale atmospheric chemistry system and find that subgrid-scale ACI can improve meteorological factors predictions. This study demonstrates the importance of real-time subgrid-scale ACI to weather forecast and the necessity of multiscale ACI studies.
Kevin Wolf, Nicolas Bellouin, Olivier Boucher, Susanne Rohs, and Yun Li
Atmos. Chem. Phys., 25, 157–181, https://doi.org/10.5194/acp-25-157-2025, https://doi.org/10.5194/acp-25-157-2025, 2025
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ERA5 atmospheric reanalysis and airborne in situ observations from IAGOS are compared in terms of the representation of the contrail formation potential and the presence of supersaturation. Differences are traced back to biases in ERA5 relative humidity fields. Those biases are addressed by applying a quantile mapping technique that significantly improved contrail estimation based on post-processed ERA5 data.
Marje Prank, Juha Tonttila, Xiaoxia Shang, Sami Romakkaniemi, and Tomi Raatikainen
Atmos. Chem. Phys., 25, 183–197, https://doi.org/10.5194/acp-25-183-2025, https://doi.org/10.5194/acp-25-183-2025, 2025
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Large primary bioparticles such as pollen can be abundant in the atmosphere. In humid conditions pollen can rupture and release a large number of fine sub-pollen particles (SPPs). The paper investigates what kind of birch pollen concentrations are needed for the pollen and SPPs to start playing a noticeable role in cloud processes and alter precipitation formation. In the studied cases only the largest observed pollen concentrations were able to noticeably alter the precipitation formation.
Luís Filipe Escusa dos Santos, Hannah C. Frostenberg, Alejandro Baró Pérez, Annica M. L. Ekman, Luisa Ickes, and Erik S. Thomson
Atmos. Chem. Phys., 25, 119–142, https://doi.org/10.5194/acp-25-119-2025, https://doi.org/10.5194/acp-25-119-2025, 2025
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The Arctic is experiencing enhanced surface warming. The observed decline in Arctic sea-ice extent is projected to lead to an increase in Arctic shipping activity, which may lead to further climatic feedbacks. Using an atmospheric model and results from marine engine experiments that focused on fuel sulfur content reduction and exhaust wet scrubbing, we investigate how ship exhaust particles influence the properties of Arctic clouds. Implications for radiative surface processes are discussed.
Nadja Omanovic, Brigitta Goger, and Ulrike Lohmann
Atmos. Chem. Phys., 24, 14145–14175, https://doi.org/10.5194/acp-24-14145-2024, https://doi.org/10.5194/acp-24-14145-2024, 2024
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We evaluated the numerical weather model ICON in two horizontal resolutions with two bulk microphysics schemes over hilly and complex terrain in Switzerland and Austria, respectively. We focused on the model's ability to simulate mid-level clouds in summer and winter. By combining observational data from two different field campaigns, we show that an increase in the horizontal resolution and a more advanced cloud microphysics scheme is strongly beneficial for cloud representation.
Cornelis Schwenk and Annette Miltenberger
Atmos. Chem. Phys., 24, 14073–14099, https://doi.org/10.5194/acp-24-14073-2024, https://doi.org/10.5194/acp-24-14073-2024, 2024
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Warm conveyor belts (WCBs) transport moisture into the upper atmosphere, where it acts as a greenhouse gas. This transport is not well understood, and the role of rapidly rising air is unclear. We simulate a WCB and look at fast- and slow-rising air to see how moisture is (differently) transported. We find that for fast-ascending air more ice particles reach higher into the atmosphere and that frozen cloud particles are removed differently than during slow ascent, which has more water vapour.
Fabian Hoffmann, Yao-Sheng Chen, and Graham Feingold
EGUsphere, https://doi.org/10.5194/egusphere-2024-3893, https://doi.org/10.5194/egusphere-2024-3893, 2024
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Clouds reflect a substantial portion of the incoming solar radiation back into space. This capacity is determined by the number of cloud droplets, which in turn is influenced by the number of aerosol particles, forming the basis for aerosol-cloud-climate interactions. In this study, we use a simple mixed-layer approach to understand the effect of aerosol on cloud water in non-precipitating stratocumulus.
Pratapaditya Ghosh, Ian Boutle, Paul Field, Adrian Hill, Anthony Jones, Marie Mazoyer, Katherine J. Evans, Salil Mahajan, Hyun-Gyu Kang, Min Xu, Wei Zhang, Noah Asch, and Hamish Gordon
EGUsphere, https://doi.org/10.5194/egusphere-2024-3376, https://doi.org/10.5194/egusphere-2024-3376, 2024
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We study aerosol-fog interactions near Paris using a weather and climate model with high spatial resolution. We show that our model can simulate fog lifecycle effectively. We find that the fog droplet number concentrations, the amount of liquid water in the fog, and the vertical structure of the fog are highly sensitive to the parameterization that simulates droplet formation and growth. The changes we propose could improve fog forecasts significantly without increasing computational costs.
Pratapaditya Ghosh, Ian Boutle, Paul Field, Adrian Hill, Marie Mazoyer, Katherine J. Evans, Salil Mahajan, Hyun-Gyu Kang, Min Xu, Wei Zhang, and Hamish Gordon
EGUsphere, https://doi.org/10.5194/egusphere-2024-3397, https://doi.org/10.5194/egusphere-2024-3397, 2024
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We study the lifecycle of fog events in Europe using a weather and climate model. By incorporating droplet formation and growth driven by radiative cooling, our model better simulates the total liquid water in foggy atmospheric columns. We show that both adiabatic and radiative cooling play significant, often equally important roles in driving droplet formation and growth. We discuss strategies to address droplet number overpredictions, by improving model physics and addressing model artifacts.
Jing Yang, Jiaojiao Li, Meilian Chen, Xiaoqin Jing, Yan Yin, Bart Geerts, Zhien Wang, Yubao Liu, Baojun Chen, Shaofeng Hua, Hao Hu, Xiaobo Dong, Ping Tian, Qian Chen, and Yang Gao
Atmos. Chem. Phys., 24, 13833–13848, https://doi.org/10.5194/acp-24-13833-2024, https://doi.org/10.5194/acp-24-13833-2024, 2024
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Detecting unambiguous signatures is vital for examining cloud-seeding impacts, but often, seeding signatures are immersed in natural variability. In this study, reflectivity changes induced by glaciogenic seeding using different AgI concentrations are investigated under various conditions, and a method is developed to estimate the AgI concentration needed to detect unambiguous seeding signatures. The results aid in operational seeding-based decision-making regarding the amount of AgI dispersed.
Florian Sauerland, Niels Souverijns, Anna Possner, Heike Wex, Preben Van Overmeiren, Alexander Mangold, Kwinten Van Weverberg, and Nicole van Lipzig
Atmos. Chem. Phys., 24, 13751–13768, https://doi.org/10.5194/acp-24-13751-2024, https://doi.org/10.5194/acp-24-13751-2024, 2024
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We use a regional climate model, COSMO-CLM², enhanced with a module resolving aerosol processes, to study Antarctic clouds. We prescribe different concentrations of ice-nucleating particles to our model to assess how these clouds respond to concentration changes, validating results with cloud and aerosol observations from the Princess Elisabeth Antarctica station. Our results show that aerosol–cloud interactions vary with temperature, providing valuable insights into Antarctic cloud dynamics.
Yi Li, Xiaoli Liu, and Hengjia Cai
Atmos. Chem. Phys., 24, 13525–13540, https://doi.org/10.5194/acp-24-13525-2024, https://doi.org/10.5194/acp-24-13525-2024, 2024
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The influence of different aerosol modes on cloud processes remains controversial. We modified the aerosol spectra and concentrations to simulate a warm stratiform cloud process in Jiangxi, China, using the WRF-SBM scheme. Research shows that different aerosol spectra have diverse effects on cloud droplet spectra, cloud development, and the correlation between dispersion (ε) and cloud physics quantities. Compared to cloud droplet concentration, ε is more sensitive to the volume radius.
Fabian Hoffmann, Franziska Glassmeier, and Graham Feingold
Atmos. Chem. Phys., 24, 13403–13412, https://doi.org/10.5194/acp-24-13403-2024, https://doi.org/10.5194/acp-24-13403-2024, 2024
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Clouds constitute a major cooling influence on Earth's climate system by reflecting a large fraction of the incident solar radiation back to space. This ability is controlled by the number of cloud droplets, which is governed by the number of aerosol particles in the atmosphere, laying the foundation for so-called aerosol–cloud–climate interactions. In this study, a simple model to understand the effect of aerosol on cloud water is developed and applied.
Andrea Mosso, Thomas Hocking, and Thorsten Mauritsen
Atmos. Chem. Phys., 24, 12793–12806, https://doi.org/10.5194/acp-24-12793-2024, https://doi.org/10.5194/acp-24-12793-2024, 2024
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Clouds play a crucial role in the Earth's energy balance, as they can either warm up or cool down the area they cover depending on their height and depth. They are expected to alter their behaviour under climate change, affecting the warming generated by greenhouse gases. This paper proposes a new method to estimate their overall effect on this warming by simulating a climate where clouds are transparent. Results show that with the model used, clouds have a stabilising effect on climate.
Tao Shi, Yuanjian Yang, Ping Qi, and Simone Lolli
Atmos. Chem. Phys., 24, 12807–12822, https://doi.org/10.5194/acp-24-12807-2024, https://doi.org/10.5194/acp-24-12807-2024, 2024
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This paper explored the formation mechanisms of the amplified canopy urban heat island intensity (ΔCUHII) during heat wave (HW) periods in the megacity of Beijing from the perspectives of mountain–valley breeze and urban morphology. During the mountain breeze phase, high-rise buildings with lower sky view factors (SVFs) had a pronounced effect on the ΔCUHII. During the valley breeze phase, high-rise buildings exerted a dual influence on the ΔCUHII.
Yao-Sheng Chen, Jianhao Zhang, Fabian Hoffmann, Takanobu Yamaguchi, Franziska Glassmeier, Xiaoli Zhou, and Graham Feingold
Atmos. Chem. Phys., 24, 12661–12685, https://doi.org/10.5194/acp-24-12661-2024, https://doi.org/10.5194/acp-24-12661-2024, 2024
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Marine stratocumulus cloud is a type of shallow cloud that covers the vast areas of Earth's surface. It plays an important role in Earth's energy balance by reflecting solar radiation back to space. We used numerical models to simulate a large number of marine stratocumuli with different characteristics. We found that how the clouds develop throughout the day is affected by the level of humidity in the air above the clouds and how closely the clouds connect to the ocean surface.
Andrew DeLaFrance, Lynn McMurdie, Angela Rowe, and Andrew Heymsfield
EGUsphere, https://doi.org/10.5194/egusphere-2024-3423, https://doi.org/10.5194/egusphere-2024-3423, 2024
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Short summary
Numerical modeling simulations are used to investigate ice crystal growth and decay processes within a banded region of enhanced precipitation rates during a prominent winter storm. We identify robust primary ice growth in the upper portion of the cloud but decay exceeding 70 % during fallout through a subsaturated layer. The ice fall characteristics and decay rate are sensitive to the ambient cloud properties which has implications for radar-based measurements and precipitation accumulations.
Charlotte Lange and Johannes Quaas
EGUsphere, https://doi.org/10.5194/egusphere-2024-3229, https://doi.org/10.5194/egusphere-2024-3229, 2024
Short summary
Short summary
We studied how the Earth’s climate system adjusts to sudden changes in the energy budget, by analyzing data of four climate models, which simulated a 4 % reduction of incoming solar energy. We found rapid cooling of the atmosphere and shifts in cloud cover and atmospheric circulation patterns like land-sea-circulation. Our research helps to better understand cloud adjustments, which are a main source of uncertainty in climate models. This can improve future climate predictions.
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Short summary
Pores are aerosol particle features that trigger ice nucleation, as they take up water by capillary condensation below water saturation that freezes at low temperatures. The pore ice can then grow into macroscopic ice crystals making up cirrus clouds. Here, we investigate the pores in soot aggregates responsible for pore condensation and freezing (PCF). Moreover, we present a framework to parameterize soot PCF that is able to predict the ice nucleation activity based on soot properties.
Pores are aerosol particle features that trigger ice nucleation, as they take up water by...
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