Articles | Volume 21, issue 5
https://doi.org/10.5194/acp-21-3763-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-3763-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Mar 2021
Research article |
| 12 Mar 2021
| 12 Mar 2021
Identification and source attribution of organic compounds in ultrafine particles near Frankfurt International Airport
Florian Ungeheuer
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany
Dominik van Pinxteren
Atmospheric Chemistry Department (ACD), Leibniz Institute for
Tropospheric Research (TROPOS), 04318 Leipzig, Germany
Alexander L. Vogel
CORRESPONDING AUTHOR
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany
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Lady Mateus-Fontecha, Angela Vargas-Burbano, Rodrigo Jimenez, Nestor Y. Rojas, German Rueda-Saa, Dominik van Pinxteren, Manuela van Pinxteren, Khanneh Wadinga Fomba, and Hartmut Herrmann
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Kristina Glojek, Griša Močnik, Honey Dawn C. Alas, Andrea Cuesta-Mosquera, Luka Drinovec, Asta Gregorič, Matej Ogrin, Kay Weinhold, Irena Ježek, Thomas Müller, Martin Rigler, Maja Remškar, Dominik van Pinxteren, Hartmut Herrmann, Martina Ristorini, Maik Merkel, Miha Markelj, and Alfred Wiedensohler
Atmos. Chem. Phys., 22, 5577–5601, https://doi.org/10.5194/acp-22-5577-2022, https://doi.org/10.5194/acp-22-5577-2022, 2022
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A pilot study to determine the emissions of wood burning under
real-world laboratoryconditions was conducted. We found that measured black carbon (eBC) and particulate matter (PM) in rural shallow terrain depressions with residential wood burning could be much greater than predicted by models. The exceeding levels are a cause for concern since similar conditions can be expected in numerous hilly and mountainous regions across Europe, where approximately 20 % of the total population lives.
Laurent Poulain, Benjamin Fahlbusch, Gerald Spindler, Konrad Müller, Dominik van Pinxteren, Zhijun Wu, Yoshiteru Iinuma, Wolfram Birmili, Alfred Wiedensohler, and Hartmut Herrmann
Atmos. Chem. Phys., 21, 3667–3684, https://doi.org/10.5194/acp-21-3667-2021, https://doi.org/10.5194/acp-21-3667-2021, 2021
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We present results from source apportionment analysis on the carbonaceous aerosol particles, including organic aerosol (OA) and equivalent black carbon (eBC), allowing us to distinguish local emissions from long-range transport for OA and eBC sources. By merging online chemical measurements and considering particle number size distribution, the different air masses reaching the sampling place were described and discussed, based on their respective chemical composition and size distribution.
Martin Heinritzi, Lubna Dada, Mario Simon, Dominik Stolzenburg, Andrea C. Wagner, Lukas Fischer, Lauri R. Ahonen, Stavros Amanatidis, Rima Baalbaki, Andrea Baccarini, Paulus S. Bauer, Bernhard Baumgartner, Federico Bianchi, Sophia Brilke, Dexian Chen, Randall Chiu, Antonio Dias, Josef Dommen, Jonathan Duplissy, Henning Finkenzeller, Carla Frege, Claudia Fuchs, Olga Garmash, Hamish Gordon, Manuel Granzin, Imad El Haddad, Xucheng He, Johanna Helm, Victoria Hofbauer, Christopher R. Hoyle, Juha Kangasluoma, Timo Keber, Changhyuk Kim, Andreas Kürten, Houssni Lamkaddam, Tiia M. Laurila, Janne Lampilahti, Chuan Ping Lee, Katrianne Lehtipalo, Markus Leiminger, Huajun Mai, Vladimir Makhmutov, Hanna Elina Manninen, Ruby Marten, Serge Mathot, Roy Lee Mauldin, Bernhard Mentler, Ugo Molteni, Tatjana Müller, Wei Nie, Tuomo Nieminen, Antti Onnela, Eva Partoll, Monica Passananti, Tuukka Petäjä, Joschka Pfeifer, Veronika Pospisilova, Lauriane L. J. Quéléver, Matti P. Rissanen, Clémence Rose, Siegfried Schobesberger, Wiebke Scholz, Kay Scholze, Mikko Sipilä, Gerhard Steiner, Yuri Stozhkov, Christian Tauber, Yee Jun Tham, Miguel Vazquez-Pufleau, Annele Virtanen, Alexander L. Vogel, Rainer Volkamer, Robert Wagner, Mingyi Wang, Lena Weitz, Daniela Wimmer, Mao Xiao, Chao Yan, Penglin Ye, Qiaozhi Zha, Xueqin Zhou, Antonio Amorim, Urs Baltensperger, Armin Hansel, Markku Kulmala, António Tomé, Paul M. Winkler, Douglas R. Worsnop, Neil M. Donahue, Jasper Kirkby, and Joachim Curtius
Atmos. Chem. Phys., 20, 11809–11821, https://doi.org/10.5194/acp-20-11809-2020, https://doi.org/10.5194/acp-20-11809-2020, 2020
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With experiments performed at CLOUD, we show how isoprene interferes in monoterpene oxidation via RO2 termination at atmospherically relevant concentrations. This interference shifts the distribution of highly oxygenated organic molecules (HOMs) away from C20 class dimers towards C15 class dimers, which subsequently reduces both biogenic nucleation and early growth rates. Our results may help to understand the absence of new-particle formation in isoprene-rich environments.
Laurent Poulain, Gerald Spindler, Achim Grüner, Thomas Tuch, Bastian Stieger, Dominik van Pinxteren, Jean-Eudes Petit, Olivier Favez, Hartmut Herrmann, and Alfred Wiedensohler
Atmos. Meas. Tech., 13, 4973–4994, https://doi.org/10.5194/amt-13-4973-2020, https://doi.org/10.5194/amt-13-4973-2020, 2020
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The stability and the comparability between ACSM and collocated filter sampling and MPSS measurements was investigated in order to examine the instruments robustness for year-long measurements. Specific attention was paid to the influence of the upper size cutoff diameter to better understand how it might affect the data validation. Recommendations are provided for better on-site quality assurance and quality control of the ACSM, which would be useful for either long-term or intensive campaigns.
Cited articles
Allan, J. D., Williams, P. I., Morgan, W. T., Martin, C. L., Flynn, M. J.,
Lee, J., Nemitz, E., Phillips, G. J., Gallagher, M. W., and Coe, H.:
Contributions from transport, solid fuel burning and cooking to primary
organic aerosols in two UK cities, Atmos. Chem. Phys., 10, 647–668,
https://doi.org/10.5194/acp-10-647-2010, 2010.
Beyersdorf, A. J., Timko, M. T., Ziemba, L. D., Bulzan, D., Corporan, E.,
Herndon, S. C., Howard, R., Miake-Lye, R., Thornhill, K. L., Winstead, E.,
Wey, C., Yu, Z., and Anderson, B. E.: Reductions in aircraft particulate
emissions due to the use of Fischer–Tropsch fuels, Atmos. Chem. Phys., 14,
11–23, https://doi.org/10.5194/acp-14-11-2014, 2014.
Bowery, N. G., Collins, J. F., Hill, R. G., and Pearson, S.: GABA antagonism
as a possible basis for the convulsant action of a series of bicyclic phosphorus esters, Br. J. Pharmacol., 57, P435–P436, 1976.
Bowery, N. G., Collins, J. F., Hill, R. G., and Pearson, S.: t-Butyl bicyclo
phosphate: a convulsant and GABA antagonist more potent than bicuculline,
Br. J. Pharmacol., 60, 275–276, 1977.
Boyce, M. P.: Gas turbine engineering handbook, 4th Edn., Butterworth-Heinemann, Waltham, Mass., Elsevier, Amsterdam, 956 pp., 2012.
Callahan, A. B., Tappan, D. V., Mooney, L. W., and Heyder, E.: Analysis of
Hydraulic Fluids and Lubricating Oils for the Formation of Trimethylolpropane Phosphate (TMP-P), Naval Submarine Medical Research Lab, Groton, CT, 98 pp., 1989.
Campen, M. J., Nolan, J. P., Schladweiler, M. C., Kodavanti, U. P., Evansky,
P. A., Costa, D. L., and Watkinson, W. P.: Cardiovascular and thermoregulatory effects of inhaled PM-associated transition metals: a
potential interaction between nickel and vanadium sulfate, Toxicol. Sci.,
64, 243–252, https://doi.org/10.1093/toxsci/64.2.243, 2001.
Cena, L. G., Chisholm, W. P., Keane, M. J., Cumpston, A., and Chen, B. T.:
Size Distribution and Estimated Respiratory Deposition of Total Chromium,
Hexavalent Chromium, Manganese, and Nickel in Gas Metal Arc Welding Fume
Aerosols, Aerosol Sci. Tech., 48, 1254–1263, https://doi.org/10.1080/02786826.2014.980883, 2014.
Centers, P. W.: Potential neurotoxin formation in thermally degraded synthetic ester turbine lubricants, Arch. Toxicol., 66, 679–680, https://doi.org/10.1007/BF01981509, 1992.
Chang, Y., Cui, H., Jiang, X., and Li, M.: Comparative assessment of
neurotoxicity impacts induced by alkyl tri-n-butyl phosphate and aromatic
tricresyl phosphate in PC12 cells, Environ. Toxicol., 35, 1326–1333, https://doi.org/10.1002/tox.22997, 2020.
Chen, X., Balasubramanian, R., Zhu, Q., Behera, S. N., Bo, D., Huang, X.,
Xie, H., and Cheng, J.: Characteristics of atmospheric particulate mercury in size-fractionated particles during haze days in Shanghai, Atmos. Environ., 131, 400–408, https://doi.org/10.1016/j.atmosenv.2016.02.019, 2016.
Costa, D. L. and Dreher, K. L.: Bioavailable Transition Metals in Particulate Matter Mediate Cardiopulmonary Injury in Healthy and Compromised Animal Models, Environ. Health. Persp., 105, 1053, https://doi.org/10.2307/3433509, 1997.
de Boer, J., Antelo, A., van der Veen, I., Brandsma, S., and Lammertse, N.:
Tricresyl phosphate and the aerotoxic syndrome of flight crew members – current gaps in knowledge, Chemosphere, 119, 58–61,
https://doi.org/10.1016/j.chemosphere.2014.05.015, 2015.
de Nola, G., Kibby, J., and Mazurek, W.: Determination of ortho-cresyl phosphate isomers of tricresyl phosphate used in aircraft turbine engine oils by gas chromatography and mass spectrometry, J. Chromatogr. A, 1200,
211–216, https://doi.org/10.1016/j.chroma.2008.05.035, 2008.
Duangkaewmanee, S. and Petsom, A.: Synergistic and antagonistic effects on
oxidation stability of antioxidants in a synthetic ester based oil, Tribol.
Int., 44, 266–271, https://doi.org/10.1016/j.triboint.2010.10.028, 2011.
Du Han, H. and Masuko, M.: Elucidation of the Antiwear Performance of Several Organic Phosphates Used with Different Polyol Ester Base Oils from the Aspect of Interaction between Additive and Base Oil, Tribol. T., 41, 600–604, https://doi.org/10.1080/10402009808983788, 1998.
Ehrich, M., Jortner, B. S., and Padilla, S.: Relationship of neuropathy target esterase inhibition to neuropathology and ataxia in hens given
organophosphorus esters, Chem.-Biol. Interact., 87, 431–437, https://doi.org/10.1016/0009-2797(93)90071-6, 1993.
Eurocontrol: European Aviation in 2040: Challenges of Growth, Annex1 Flight
Forecast to 2040, European Organisation for the Safety of Air Navigation, 92 pp., available at: https://www.eurocontrol.int/sites/default/files/2019-07/challenges-of-growth-2018-annex1_0.pdf (last access: 5 March 2021), 2018.
Eurocontrol: Five-Year Forecast 2020–2024 European Flight Movements and
Service Units: Three Scenarios for Recovery from COVID-19, Brussels, 15 pp.,
2020.
Eurocontrol: What COVID-19 did to European Aviation in 2020, and Outlook 2021: Think Paper #8 – 1 January 2021, Brussels, 12 pp., 2021.
Eyer, P.: Neuropsychopathological changes by organophosphorus compounds – a
review, Hum. Exp. Toxicol., 14, 857–864, https://doi.org/10.1177/096032719501401101, 1995.
Fraport AG: Fraport-Verkehrszahlen 2019: Über 70,5 Millionen Passagiere
am Flughafen Frankfurt, available at: https://www.fraport.com/de/newsroom/pressemitteilungen/2020/q1-2020/fraport-verkehrszahlen-2019--ueber-70-5-millionen-passagiere-am-.html, last access: 14 July 2020.
Fraport AG: Fraport-Verkehrszahlen 2020: Passagieraufkommen infolge der
COVID-19-Pandemie auf historisch niedrigem Niveau, available at: https://www.fraport.com/de/newsroom/pressemitteilungen/2021/q1-2021/fraport-verkehrszahlen-2020--passagieraufkommen-infolge-der-covi.html, last access: 18 January 2021.
Freudenthal, R. I., Rausch, L., Gerhart, J. M., Barth, M. L., Mackerer, C. R., and Bisinger, E. C.: Subchronic Neurotoxicity of Oil Formulations
Containing Either Tricresyl Phosphate or Tri-Orthocresyl Phosphate, J. Am.
Coll. Toxicol., 12, 409–416, https://doi.org/10.1177/109158189301200410, 1993.
Fushimi, A., Saitoh, K., Fujitani, Y., and Takegawa, N.: Identification of
jet lubrication oil as a major component of aircraft exhaust nanoparticles,
Atmos. Chem. Phys., 19, 6389–6399, https://doi.org/10.5194/acp-19-6389-2019, 2019.
Hanhela, P. J., Kibby, J., DeNola, G., and Mazurek, W.: Organophosphate and
Amine Contamination of Cockpit Air in the Hawk, F-111 and Hercules
C-130 Aircraft, Maritime Platforms Division Platforms Sciences Laboratory, Victoria, Australia, 31 pp., 2005.
Hudda, N. and Fruin, S. A.: International Airport Impacts to Air Quality: Size and Related Properties of Large Increases in Ultrafine Particle Number
Concentrations, Environ. Sci. Technol., 50, 3362–3370, https://doi.org/10.1021/acs.est.5b05313, 2016.
Ji, X., Li, N., Ma, M., Rao, K., Yang, R., and Wang, Z.: Tricresyl phosphate
isomers exert estrogenic effects via G protein-coupled estrogen receptor-mediated pathways, Environ. Pollut., 264, 114747, https://doi.org/10.1016/j.envpol.2020.114747, 2020.
Jonsdottir, H. R., Delaval, M., Leni, Z., Keller, A., Brem, B. T., Siegerist, F., Schönenberger, D., Durdina, L., Elser, M., Burtscher, H., Liati, A., and Geiser, M.: Non-volatile particle emissions from aircraft turbine engines at ground-idle induce oxidative stress in bronchial cells, Commun. Biol., 2, 90, https://doi.org/10.1038/s42003-019-0332-7, 2019.
Kendrick, E.: A Mass Scale Based on CH2=14.0000 for High Resolution Mass Spectrometry of Organic Compounds, Anal. Chem., 35, 2146–2154, https://doi.org/10.1021/ac60206a048, 1963.
Keuken, M. P., Moerman, M., Zandveld, P., Henzing, J. S., and Hoek, G.: Total and size-resolved particle number and black carbon concentrations in urban areas near Schiphol airport (the Netherlands), Atmos. Environ., 104, 132–142, https://doi.org/10.1016/j.atmosenv.2015.01.015, 2015.
Kılıç, D., El Haddad, I., Brem, B. T., Bruns, E., Bozetti, C.,
Corbin, J., Durdina, L., Huang, R.-J., Jiang, J., Klein, F., Lavi, A., Pieber, S. M., Rindlisbacher, T., Rudich, Y., Slowik, J. G., Wang, J.,
Baltensperger, U., and Prévôt, A. S. H.: Identification of secondary
aerosol precursors emitted by an aircraft turbofan, Atmos. Chem. Phys., 18,
7379–7391, https://doi.org/10.5194/acp-18-7379-2018, 2018.
Kroll, J. H., Donahue, N. M., Jimenez, J. L., Kessler, S. H., Canagaratna,
M. R., Wilson, K. R., Altieri, K. E., Mazzoleni, L. R., Wozniak, A. S.,
Bluhm, H., Mysak, E. R., Smith, J. D., Kolb, C. E., and Worsnop, D. R.: Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol, Nat. Chem., 3, 133–139, https://doi.org/10.1038/nchem.948, 2011.
Lee, D. S., Fahey, D. W., Forster, P. M., Newton, P. J., Wit, R. C. N., Lim,
L. L., Owen, B., and Sausen, R.: Aviation and global climate change in the
21st century, Atmos. Environ., 43, 3520–3537, https://doi.org/10.1016/j.atmosenv.2009.04.024, 2009.
Lewis Sr., R, J., Larrañaga, M. D., and Lewis, R. A.: Hawley's Condensed Chemical Dictionary, John Wiley & Sons, Incorporated, Hoboken, USA, 2016.
Lobo, P., Durdina, L., Smallwood, G. J., Rindlisbacher, T., Siegerist, F.,
Black, E. A., Yu, Z., Mensah, A. A., Hagen, D. E., Miake-Lye, R. C., Thomson, K. A., Brem, B. T., Corbin, J. C., Abegglen, M., Sierau, B., Whitefield, P. D., and Wang, J.: Measurement of Aircraft Engine Non-Volatile PM Emissions: Results of the Aviation-Particle Regulatory Instrumentation Demonstration Experiment (A-PRIDE) 4 Campaign, Aerosol Sci. Tech., 49, 472–484, https://doi.org/10.1080/02786826.2015.1047012, 2015.
Masiol, M. and Harrison, R. M.: Aircraft engine exhaust emissions and other
airport-related contributions to ambient air pollution: A review, Atmos.
Environ., 95, 409–455, https://doi.org/10.1016/j.atmosenv.2014.05.070, 2014.
Mattsson, H.: Bicyclic phosphates increase the cyclic GMP level in rat
cerebellum, presumably due to reduced GABA inhibition, Brain Res., 181, 175–184, https://doi.org/10.1016/0006-8993(80)91267-6, 1980.
Morawska, L., Ristovski, Z., Jayaratne, E. R., Keogh, D. U., and Ling, X.:
Ambient nano and ultrafine particles from motor vehicle emissions: Characteristics, ambient processing and implications on human exposure, Atmos. Environ., 42, 8113–8138, https://doi.org/10.1016/j.atmosenv.2008.07.050, 2008.
O'Callaghan, J. P.: Neurotoxic esterase: not so toxic?, Nat. Genet., 33,
437–438, https://doi.org/10.1038/ng1135, 2003.
Paasonen, P., Kupiainen, K., Klimont, Z., Visschedijk, A., van der Denier Gon, H. A. C., and Amann, M.: Continental anthropogenic primary particle number emissions, Atmos. Chem. Phys., 16, 6823–6840, https://doi.org/10.5194/acp-16-6823-2016, 2016.
Riesz, P., Berdahl, D., and Christman, C. L.: Free radical generation by
ultrasound in aqueous and nonaqueous solutions, Environ. Health. Persp., 64,
233–252, https://doi.org/10.1289/ehp.8564233, 1985.
Rönkkö, T., Kuuluvainen, H., Karjalainen, P., Keskinen, J., Hillamo,
R., Niemi, J. V., Pirjola, L., Timonen, H. J., Saarikoski, S., Saukko, E.,
Järvinen, A., Silvennoinen, H., Rostedt, A., Olin, M., Yli-Ojanperä,
J., Nousiainen, P., Kousa, A., and Dal Maso, M.: Traffic is a major source
of atmospheric nanocluster aerosol, P. Natl. Acad. Sci. USA, 114, 7549–7554, https://doi.org/10.1073/pnas.1700830114, 2017.
Rose, D. and Jacobi, S.: 1. Zwischenbericht zur Untersuchung der regionalen
Luftqualität auf ultrafeine Partikel im Bereich des Flughafens Frankfurt, Hessisches Landesamt für Naturschutz, Umwelt und Geologie, Wiesbaden, 24 pp., 2018.
Schraufnagel, D. E.: The health effects of ultrafine particles, Exp. Mol. Med., 52, 311–317, https://doi.org/10.1038/s12276-020-0403-3, 2020.
Simmonds, M. A.: Classification of Some GABA Antagonists With Regard to Site
of Action and Potency in Slices of Rat Cuneate Nucleus, Eur. J. Pharmacol.,
80, 347–358, 1982.
Solbu, K., Daae, H. L., Thorud, S., Ellingsen, D. G., Lundanes, E., and Molander, P.: Exposure to airborne organophosphates originating from hydraulic and turbine oils among aviation technicians and loaders, J. Environ. Monit., 12, 2259–2268, https://doi.org/10.1039/c0em00273a, 2010.
Solbu, K., Daae, H. L., Olsen, R., Thorud, S., Ellingsen, D. G., Lindgren,
T., Bakke, B., Lundanes, E., and Molander, P.: Organophosphates in aircraft
cabin and cockpit air – method development and measurements of contaminants,
J. Environ. Monit., 13, 1393–1403, https://doi.org/10.1039/c0em00763c, 2011.
Ticku, M. K. and Ramanjaneyulu, R.: Differential interactions of GABA
agonists, depressant and convulsant drugs with [35S]-t-butylbicyclophosphorothionate binding sites in cortex and
cerebellum, Pharmacol. Biochem. Be., 21, 151–158, https://doi.org/10.1016/0091-3057(84)90145-X, 1984.
Timko, M. T., Yu, Z., Onasch, T. B., Wong, H.-W., Miake-Lye, R. C., Beyersdorf, A. J., Anderson, B. E., Thornhill, K. L., Winstead, E. L.,
Corporan, E., DeWitt, M. J., Klingshirn, C. D., Wey, C., Tacina, K., Liscinsky, D. S., Howard, R., and Bhargava, A.: Particulate Emissions of Gas
Turbine Engine Combustion of a Fischer–Tropsch Synthetic Fuel, Energ. Fuel., 24, 5883–5896, https://doi.org/10.1021/ef100727t, 2010.
Timko, M. T., Fortner, E., Franklin, J., Yu, Z., Wong, H.-W., Onasch, T. B.,
Miake-Lye, R. C., and Herndon, S. C.: Atmospheric measurements of the physical evolution of aircraft exhaust plumes, Environ. Sci. Technol., 47,
3513–3520, https://doi.org/10.1021/es304349c, 2013.
Timko, M. T., Albo, S. E., Onasch, T. B., Fortner, E. C., Yu, Z., Miake-Lye,
R. C., Canagaratna, M. R., Ng, N. L., and Worsnop, D. R.: Composition and
Sources of the Organic Particle Emissions from Aircraft Engines, Aerosol Sci. Tech., 48, 61–73, https://doi.org/10.1080/02786826.2013.857758, 2014.
van Netten, C. and Leung, V.: Comparison of the constituents of two jet engine lubricating oils and their volatile pyrolytic degradation products,
Appl. Occup. Environ. Hyg., 15, 277–283, https://doi.org/10.1080/104732200301593, 2000.
Vazquez-Duhalt, R.: Environmental impact of used motor oil, Sci. Total Environ., 79, 1–23, https://doi.org/10.1016/0048-9697(89)90049-1, 1989.
Vogel, A. L., Lauer, A., Fang, L., Arturi, K., Bachmeier, F., Daellenbach,
K. R., Käser, T., Vlachou, A., Pospisilova, V., Baltensperger, U., Haddad, I. E., Schwikowski, M., and Bjelić, S.: A Comprehensive Nontarget Analysis for the Molecular Reconstruction of Organic Aerosol Composition from Glacier Ice Cores, Environ. Sci. Technol., 53, 12565–12575, https://doi.org/10.1021/acs.est.9b03091, 2019.
Wey, C. C., Anderson, B. E., Wey, C., Miake-Lye, R. C., Whitefield, P., and
Howard, R.: Overview on the Aircraft Particle Emissions Experiment (APEX), J. Propul. Power, 23, 898–905, https://doi.org/10.2514/1.26406, 2007.
Winder, C. and Balouet, J.-C.: Aircrew Exposure to Chemicals in Aircraft:
Symptoms of Irritation and Toxicity, J. Occup. Health Safe., 17, 471–483, 2001.
Winder, C. and Balouet, J.-C.: The toxicity of commercial jet oils, Environ.
Res., 89, 146–164, https://doi.org/10.1006/enrs.2002.4346, 2002.
World Health Organization: Review of evidence on health aspects of air pollution – REVIHAAP, World Health Organization, Copenhagen Ø, Denmark, 33 pp., 2013.
Wright, R. L.: Formation of the Neurotoxin TMPP from TMPE-Phosphate Formulations, Tribol. T., 39, 827–834, https://doi.org/10.1080/10402009608983601, 1996.
Wu, Y., Li, W., Zhang, M., and Wang, X.: Improvement of oxidative stability of trimethylolpropane trioleate lubricant, Thermochim. Acta, 569, 112–118,
https://doi.org/10.1016/j.tca.2013.05.033, 2013.
Wyman, J. F., Porvaznik, M., Serve, P., Hobson, D., and Uddin, D. E.: High
Temperature Decomposition of Military Specification L-23699 Synthetic Aircraft Lubricants, J. Fire Sci., 5, 162–177, https://doi.org/10.1177/073490418700500303, 1987.
Yang, W. and Omaye, S. T.: Air pollutants, oxidative stress and human health, Mutat. Res., 674, 45–54, https://doi.org/10.1016/j.mrgentox.2008.10.005, 2009.
Yu, Z., Liscinsky, D. S., Winstead, E. L., True, B. S., Timko, M. T., Bhargava, A., Herndon, S. C., Miake-Lye, R. C., and Anderson, B. E.:
Characterization of lubrication oil emissions from aircraft engines, Environ. Sci. Technol., 44, 9530–9534, https://doi.org/10.1021/es102145z, 2010.
Yu, Z., Herndon, S. C., Ziemba, L. D., Timko, M. T., Liscinsky, D. S., Anderson, B. E., and Miake-Lye, R. C.: Identification of lubrication oil in
the particulate matter emissions from engine exhaust of in-service commercial aircraft, Environ. Sci. Technol., 46, 9630–9637, https://doi.org/10.1021/es301692t, 2012.
Yu, Z., Liscinsky, D. S., Fortner, E. C., Yacovitch, T. I., Croteau, P.,
Herndon, S. C., and Miake-Lye, R. C.: Evaluation of PM emissions from two
in-service gas turbine general aviation aircraft engines, Atmos. Environ.,
160, 9–18, https://doi.org/10.1016/j.atmosenv.2017.04.007, 2017.
Yu, Z., Timko, M. T., Herndon, S. C., Miake-Lye, R. C., Beyersdorf, A. J.,
Ziemba, L. D., Winstead, E. L., and Anderson, B. E.: Mode-specific, semi-volatile chemical composition of particulate matter emissions from a
commercial gas turbine aircraft engine, Atmos. Environ., 218, 116974,
https://doi.org/10.1016/j.atmosenv.2019.116974, 2019.
Zhu, Y., Hinds, W. C., Kim, S., Shen, S., and Sioutas, C.: Study of ultrafine particles near a major highway with heavy-duty diesel traffic, Atmos. Environ., 36, 4323–4335, https://doi.org/10.1016/S1352-2310(02)00354-0, 2002a.
Zhu, Y., Hinds, W. C., Kim, S., and Sioutas, C.: Concentration and size
distribution of ultrafine particles near a major highway, J. Air Waste Manage. Assoc., 52, 1032–1042, https://doi.org/10.1080/10473289.2002.10470842, 2002b.
Short summary
We analysed the chemical composition of ultrafine particles from 10–56 nm near Frankfurt Airport based on cascade impactor samples. We used an offline non-target screening to determine size-resolved molecular fingerprints. Unambiguous attribution of two homologous ester series to jet engine oils enables a new strategy of source attribution and explains the majority of the detected compounds. In addition, we identified additives of jet oils and a detrimental thermal transformation product.
We analysed the chemical composition of ultrafine particles from 10–56 nm near Frankfurt Airport...
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