Articles | Volume 20, issue 1
https://doi.org/10.5194/acp-20-597-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-597-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
17 Jan 2020
Research article |
| 17 Jan 2020
| 17 Jan 2020
Ice core records of levoglucosan and dehydroabietic and vanillic acids from Aurora Peak in Alaska since the 1660s: a proxy signal of biomass-burning activities in the North Pacific Rim
Ambarish Pokhrel
Institute of Low Temperature Science, Hokkaido University, Sapporo,
Japan
Chubu Institute for Advanced Studies, Chubu University, Kasugai,
Japan
Institute of Science and Technology, Tribhuvan University, Kathmandu,
Nepal
Asian Research Center, Kathmandu, Nepal
Kimitaka Kawamura
CORRESPONDING AUTHOR
Institute of Low Temperature Science, Hokkaido University, Sapporo,
Japan
Chubu Institute for Advanced Studies, Chubu University, Kasugai,
Japan
Bhagawati Kunwar
Chubu Institute for Advanced Studies, Chubu University, Kasugai,
Japan
Kaori Ono
Institute of Low Temperature Science, Hokkaido University, Sapporo,
Japan
Akane Tsushima
Institute of Low Temperature Science, Hokkaido University, Sapporo,
Japan
Osamu Seki
Institute of Low Temperature Science, Hokkaido University, Sapporo,
Japan
Sumio Matoba
Institute of Low Temperature Science, Hokkaido University, Sapporo,
Japan
Takayuki Shiraiwa
Institute of Low Temperature Science, Hokkaido University, Sapporo,
Japan
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Zhao Wei, Shohei Hattori, Asuka Tsuruta, Zhuang Jiang, Sakiko Ishino, Koji Fujita, Sumito Matoba, Lei Geng, Alexis Lamothe, Ryu Uemura, Naohiro Yoshida, Joel Savarino, and Yoshinori Iizuka
Atmos. Chem. Phys., 25, 5727–5742, https://doi.org/10.5194/acp-25-5727-2025, https://doi.org/10.5194/acp-25-5727-2025, 2025
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Nitrate isotope records in ice cores reveal changes in NOₓ emissions and atmospheric oxidation chemistry driven by human activity. However, UV-driven postdepositional processes can alter nitrate in snow, making snow accumulation rates critical for preserving these records. This study examines nitrate isotopes in a southeastern Greenland ice core, where high snow accumulation minimizes these effects, providing a reliable archive of atmospheric nitrogen cycling.
Yutaka Kurosaki, Sumito Matoba, Mai Matsumoto, Tetsuhide Yamasaki, Ilannguaq Hendriksen, and Yoshinori Iizuka
EGUsphere, https://doi.org/10.5194/egusphere-2025-1560, https://doi.org/10.5194/egusphere-2025-1560, 2025
This preprint is open for discussion and under review for The Cryosphere (TC).
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We conducted snow observations on the coastal region in the northwestern Greenland Ice Sheet close to the North Water. The snowpack on the coastal region in the northwestern Greenland Ice Sheet contained aerosols originated from ocean biological activity and frost flowers in the North Water. The chemical substances in an ice core from the coastal region in the northwestern Greenland Ice Sheet could help explain past changes in ocean biological and sea ice conditions in the North Water.
Wenxin Zhang, Wei Hu, Mutong Niu, Quanfei Zhu, Na An, Qiang Zhang, Rui Jin, Xiaoli Fu, Jian Hao, Jianbo Yang, Jingle Liu, Jing Shi, Suqin Han, Junjun Deng, Libin Wu, Yuqi Feng, Kimitaka Kawamura, and Pingqing Fu
EGUsphere, https://doi.org/10.5194/egusphere-2025-2269, https://doi.org/10.5194/egusphere-2025-2269, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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This study investigated airborne endotoxins varying with height and season in northern China. By analyzing specific hydroxy fatty acids in aerosols, we estimated endotoxins at ground level and higher altitudes. Higher concentrations were observed near the ground during winter, likely driven by microbial emissions and combustion sources. Our findings suggest that air pollution and meteorological factors can influence endotoxin concentrations, posing potential health risks in urban environments.
Kumiko Goto-Azuma, Yoshimi Ogawa-Tsukagawa, Kaori Fukuda, Koji Fujita, Motohiro Hirabayashi, Remi Dallmayr, Jun Ogata, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Sumito Matoba, Moe Kadota, Akane Tsushima, Naoko Nagatsuka, and Teruo Aoki
Atmos. Chem. Phys., 25, 657–683, https://doi.org/10.5194/acp-25-657-2025, https://doi.org/10.5194/acp-25-657-2025, 2025
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Monthly ice core records spanning 350 years from Greenland show trends in refractory black carbon (rBC) concentrations and sizes. rBC levels have increased since the 1870s due to the inflow of anthropogenic rBC, with larger diameters than those from biomass burning (BB) rBC. High summer BB rBC peaks may reduce the ice sheet albedo, but BB rBC showed no increase until the early 2000s. These results are vital for validating aerosol and climate models.
Petr Vodička, Kimitaka Kawamura, Bhagawati Kunwar, Lin Huang, Dhananjay K. Deshmukh, Md. Mozammel Haque, Sangeeta Sharma, and Leonard Barrie
EGUsphere, https://doi.org/10.5194/egusphere-2024-3656, https://doi.org/10.5194/egusphere-2024-3656, 2025
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Carbonate carbon (CC) is not negligible in Arctic total suspended particles (TSP). If not considered, CC biases the contribution of elemental and organic carbon. CC content in TSP was strongly reflected in the δ13C values of total carbon (TC). Carbon contribution from CaCO3 supports strong dependence of CC and δ13C on Ca. Finally, two hypothetical CC sources were identified based on the analysis of air mass back trajectories – dust resuspension and marine microorganisms.
Kumiko Goto-Azuma, Remi Dallmayr, Yoshimi Ogawa-Tsukagawa, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Motohiro Hirabayashi, Jun Ogata, Kyotaro Kitamura, Kenji Kawamura, Koji Fujita, Sumito Matoba, Naoko Nagatsuka, Akane Tsushima, Kaori Fukuda, and Teruo Aoki
Atmos. Chem. Phys., 24, 12985–13000, https://doi.org/10.5194/acp-24-12985-2024, https://doi.org/10.5194/acp-24-12985-2024, 2024
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We developed a continuous flow analysis system to analyze an ice core from northwestern Greenland and coupled it with an improved refractory black carbon (rBC) measurement technique. This allowed accurate high-resolution analyses of size distributions and concentrations of rBC particles with diameters of 70 nm–4 μm for the past 350 years. Our results provide crucial insights into rBC's climatic effects. We also found previous ice core studies substantially underestimated rBC mass concentrations.
Yuhao Cui, Eri Tachibana, Kimitaka Kawamura, and Yuzo Miyazaki
Biogeosciences, 20, 4969–4980, https://doi.org/10.5194/bg-20-4969-2023, https://doi.org/10.5194/bg-20-4969-2023, 2023
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Fatty alcohols (FAs) are major components of surface lipids in plant leaves and serve as surface-active aerosols. Our study on the aerosol size distributions in a forest suggests that secondary FAs (SFAs) originated from plant waxes and that leaf senescence status is likely an important factor controlling the size distribution of SFAs. This study provides new insights into the sources of primary biological aerosol particles (PBAPs) and their effects on the aerosol ice nucleation activity.
Motoshi Nishimura, Teruo Aoki, Masashi Niwano, Sumito Matoba, Tomonori Tanikawa, Tetsuhide Yamasaki, Satoru Yamaguchi, and Koji Fujita
Earth Syst. Sci. Data, 15, 5207–5226, https://doi.org/10.5194/essd-15-5207-2023, https://doi.org/10.5194/essd-15-5207-2023, 2023
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We presented the method of data quality checks and the dataset for two ground weather observations in northwest Greenland. We found that the warm and clear weather conditions in the 2015, 2019, and 2020 summers caused the snowmelt and the decline in surface reflectance of solar radiation at a low-elevated site (SIGMA-B; 944 m), but those were not seen at the high-elevated site (SIGMA-A; 1490 m). We hope that our data management method and findings will help climate scientists.
Jingjing Meng, Yachen Wang, Yuanyuan Li, Tonglin Huang, Zhifei Wang, Yiqiu Wang, Min Chen, Zhanfang Hou, Houhua Zhou, Keding Lu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 14481–14503, https://doi.org/10.5194/acp-23-14481-2023, https://doi.org/10.5194/acp-23-14481-2023, 2023
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This study investigated the effect of COVID-19 lockdown (LCD) measures on the formation and evolutionary process of diacids and related compounds from field observations. Results demonstrate that more aged organic aerosols are observed during the LCD due to the enhanced photochemical oxidation. Our study also found that the reactivity of 13C was higher than that of 12C in the gaseous photochemical oxidation, leading to higher δ13C values of C2 during the LCD than before the LCD.
Georgia R. Grant, Jonny H. T. Williams, Sebastian Naeher, Osamu Seki, Erin L. McClymont, Molly O. Patterson, Alan M. Haywood, Erik Behrens, Masanobu Yamamoto, and Katelyn Johnson
Clim. Past, 19, 1359–1381, https://doi.org/10.5194/cp-19-1359-2023, https://doi.org/10.5194/cp-19-1359-2023, 2023
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Regional warming will differ from global warming, and climate models perform poorly in the Southern Ocean. We reconstruct sea surface temperatures in the south-west Pacific during the mid-Pliocene, a time 3 million years ago that represents the long-term outcomes of 3 °C warming, which is expected for the future. Comparing these results to climate model simulations, we show that the south-west Pacific region will warm by 1 °C above the global average if atmospheric CO2 remains above 350 ppm.
Shujun Zhong, Shuang Chen, Junjun Deng, Yanbing Fan, Qiang Zhang, Qiaorong Xie, Yulin Qi, Wei Hu, Libin Wu, Xiaodong Li, Chandra Mouli Pavuluri, Jialei Zhu, Xin Wang, Di Liu, Xiaole Pan, Yele Sun, Zifa Wang, Yisheng Xu, Haijie Tong, Hang Su, Yafang Cheng, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 2061–2077, https://doi.org/10.5194/acp-23-2061-2023, https://doi.org/10.5194/acp-23-2061-2023, 2023
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This study investigated the role of the secondary organic aerosol (SOA) loading on the molecular composition of wintertime urban aerosols by ultrahigh-resolution mass spectrometry. Results demonstrate that the SOA loading is an important factor associated with the oxidation degree, nitrate group content, and chemodiversity of nitrooxy–organosulfates. Our study also found that the hydrolysis of nitrooxy–organosulfates is a possible pathway for the formation of organosulfates.
Junjun Deng, Hao Ma, Xinfeng Wang, Shujun Zhong, Zhimin Zhang, Jialei Zhu, Yanbing Fan, Wei Hu, Libin Wu, Xiaodong Li, Lujie Ren, Chandra Mouli Pavuluri, Xiaole Pan, Yele Sun, Zifa Wang, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 22, 6449–6470, https://doi.org/10.5194/acp-22-6449-2022, https://doi.org/10.5194/acp-22-6449-2022, 2022
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Light-absorbing brown carbon (BrC) plays an important role in climate change and atmospheric chemistry. Here we investigated the seasonal and diurnal variations in water-soluble BrC in PM2.5 in the megacity Tianjin in coastal China. Results of the source apportionments from the combination with organic molecular compositions and optical properties of water-soluble BrC reveal a large contribution from primary bioaerosol particles to BrC in the urban atmosphere.
Yange Deng, Hiroaki Fujinari, Hikari Yai, Kojiro Shimada, Yuzo Miyazaki, Eri Tachibana, Dhananjay K. Deshmukh, Kimitaka Kawamura, Tomoki Nakayama, Shiori Tatsuta, Mingfu Cai, Hanbing Xu, Fei Li, Haobo Tan, Sho Ohata, Yutaka Kondo, Akinori Takami, Shiro Hatakeyama, and Michihiro Mochida
Atmos. Chem. Phys., 22, 5515–5533, https://doi.org/10.5194/acp-22-5515-2022, https://doi.org/10.5194/acp-22-5515-2022, 2022
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Offline analyses of the hygroscopicity and composition of atmospheric aerosols are complementary to online analyses in view of the applicability to broader sizes, specific compound groups, and investigations at remote sites. This offline study characterized the composition of water-soluble matter in aerosols and their humidity-dependent hygroscopicity on Okinawa, a receptor site of East Asian outflow. Further, comparison with online analyses showed the appropriateness of the offline method.
Molly O. Patterson, Richard H. Levy, Denise K. Kulhanek, Tina van de Flierdt, Huw Horgan, Gavin B. Dunbar, Timothy R. Naish, Jeanine Ash, Alex Pyne, Darcy Mandeno, Paul Winberry, David M. Harwood, Fabio Florindo, Francisco J. Jimenez-Espejo, Andreas Läufer, Kyu-Cheul Yoo, Osamu Seki, Paolo Stocchi, Johann P. Klages, Jae Il Lee, Florence Colleoni, Yusuke Suganuma, Edward Gasson, Christian Ohneiser, José-Abel Flores, David Try, Rachel Kirkman, Daleen Koch, and the SWAIS 2C Science Team
Sci. Dril., 30, 101–112, https://doi.org/10.5194/sd-30-101-2022, https://doi.org/10.5194/sd-30-101-2022, 2022
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How much of the West Antarctic Ice Sheet will melt and how quickly it will happen when average global temperatures exceed 2 °C is currently unknown. Given the far-reaching and international consequences of Antarctica’s future contribution to global sea level rise, the SWAIS 2C Project was developed in order to better forecast the size and timing of future changes.
Md. Mozammel Haque, Yanlin Zhang, Srinivas Bikkina, Meehye Lee, and Kimitaka Kawamura
Atmos. Chem. Phys., 22, 1373–1393, https://doi.org/10.5194/acp-22-1373-2022, https://doi.org/10.5194/acp-22-1373-2022, 2022
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We attempt to understand the current state of East Asian organic aerosols with both the molecular marker approach and 14° C data of carbonaceous components. A significant positive correlation of nonfossil- and fossil-derived organic carbon with levoglucosan suggests the importance of biomass burning (BB) and coal combustion sources in the East Asian outflow. Thus, attribution of ambient levoglucosan levels over the western North Pacific to the impact of BB emission may cause large uncertainty.
Hong Ren, Wei Hu, Lianfang Wei, Siyao Yue, Jian Zhao, Linjie Li, Libin Wu, Wanyu Zhao, Lujie Ren, Mingjie Kang, Qiaorong Xie, Sihui Su, Xiaole Pan, Zifa Wang, Yele Sun, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 21, 12949–12963, https://doi.org/10.5194/acp-21-12949-2021, https://doi.org/10.5194/acp-21-12949-2021, 2021
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This study presents vertical profiles of biogenic and anthropogenic secondary organic aerosols (SOAs) in the urban boundary layer based on a 325 m tower in Beijing in late summer. The increases in the isoprene and toluene SOAs with height were found to be more related to regional transport, whereas the decrease in those from monoterpenes and sesquiterpene were more subject to local emissions. Such complicated vertical distributions of SOA should be considered in future modeling work.
Qiaorong Xie, Sihui Su, Jing Chen, Yuqing Dai, Siyao Yue, Hang Su, Haijie Tong, Wanyu Zhao, Lujie Ren, Yisheng Xu, Dong Cao, Ying Li, Yele Sun, Zifa Wang, Cong-Qiang Liu, Kimitaka Kawamura, Guibin Jiang, Yafang Cheng, and Pingqing Fu
Atmos. Chem. Phys., 21, 11453–11465, https://doi.org/10.5194/acp-21-11453-2021, https://doi.org/10.5194/acp-21-11453-2021, 2021
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This study investigated the role of nighttime chemistry during Chinese New Year's Eve that enhances the formation of nitrooxy organosulfates in the aerosol phase. Results show that anthropogenic precursors, together with biogenic ones, considerably contribute to the formation of low-volatility nitrooxy OSs. Our study provides detailed molecular composition of firework-related aerosols, which gives new insights into the physicochemical properties and potential health effects of urban aerosols.
Naoko Nagatsuka, Kumiko Goto-Azuma, Akane Tsushima, Koji Fujita, Sumito Matoba, Yukihiko Onuma, Remi Dallmayr, Moe Kadota, Motohiro Hirabayashi, Jun Ogata, Yoshimi Ogawa-Tsukagawa, Kyotaro Kitamura, Masahiro Minowa, Yuki Komuro, Hideaki Motoyama, and Teruo Aoki
Clim. Past, 17, 1341–1362, https://doi.org/10.5194/cp-17-1341-2021, https://doi.org/10.5194/cp-17-1341-2021, 2021
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Here we present a first high-temporal-resolution record of mineral composition in a Greenland ice core (SIGMA-D) over the past 100 years using SEM–EDS analysis. Our results show that the ice core dust composition varied on multi-decadal scales, which was likely affected by local temperature changes. We suggest that the ice core dust was constantly supplied from distant sources (mainly northern Canada) as well as local ice-free areas in warm periods (1915 to 1949 and 2005 to 2013).
Philippe Massicotte, Rainer M. W. Amon, David Antoine, Philippe Archambault, Sergio Balzano, Simon Bélanger, Ronald Benner, Dominique Boeuf, Annick Bricaud, Flavienne Bruyant, Gwenaëlle Chaillou, Malik Chami, Bruno Charrière, Jing Chen, Hervé Claustre, Pierre Coupel, Nicole Delsaut, David Doxaran, Jens Ehn, Cédric Fichot, Marie-Hélène Forget, Pingqing Fu, Jonathan Gagnon, Nicole Garcia, Beat Gasser, Jean-François Ghiglione, Gaby Gorsky, Michel Gosselin, Priscillia Gourvil, Yves Gratton, Pascal Guillot, Hermann J. Heipieper, Serge Heussner, Stanford B. Hooker, Yannick Huot, Christian Jeanthon, Wade Jeffrey, Fabien Joux, Kimitaka Kawamura, Bruno Lansard, Edouard Leymarie, Heike Link, Connie Lovejoy, Claudie Marec, Dominique Marie, Johannie Martin, Jacobo Martín, Guillaume Massé, Atsushi Matsuoka, Vanessa McKague, Alexandre Mignot, William L. Miller, Juan-Carlos Miquel, Alfonso Mucci, Kaori Ono, Eva Ortega-Retuerta, Christos Panagiotopoulos, Tim Papakyriakou, Marc Picheral, Louis Prieur, Patrick Raimbault, Joséphine Ras, Rick A. Reynolds, André Rochon, Jean-François Rontani, Catherine Schmechtig, Sabine Schmidt, Richard Sempéré, Yuan Shen, Guisheng Song, Dariusz Stramski, Eri Tachibana, Alexandre Thirouard, Imma Tolosa, Jean-Éric Tremblay, Mickael Vaïtilingom, Daniel Vaulot, Frédéric Vaultier, John K. Volkman, Huixiang Xie, Guangming Zheng, and Marcel Babin
Earth Syst. Sci. Data, 13, 1561–1592, https://doi.org/10.5194/essd-13-1561-2021, https://doi.org/10.5194/essd-13-1561-2021, 2021
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The MALINA oceanographic expedition was conducted in the Mackenzie River and the Beaufort Sea systems. The sampling was performed across seven shelf–basin transects to capture the meridional gradient between the estuary and the open ocean. The main goal of this research program was to better understand how processes such as primary production are influencing the fate of organic matter originating from the surrounding terrestrial landscape during its transition toward the Arctic Ocean.
Santosh Kumar Verma, Kimitaka Kawamura, Fei Yang, Pingqing Fu, Yugo Kanaya, and Zifa Wang
Atmos. Chem. Phys., 21, 4959–4978, https://doi.org/10.5194/acp-21-4959-2021, https://doi.org/10.5194/acp-21-4959-2021, 2021
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We studied aerosol samples collected in autumn 2007 with day and night intervals in a rural site of Mangshan, north of Beijing, for sugar compounds (SCs) that are abundant organic aerosol components and can influence the air quality and climate. We found higher concentrations of biomass burning (BB) products at nighttime than daytime, whereas pollen tracers and other SCs showed an opposite diurnal trend, because this site is meteorologically characterized by a mountain/valley breeze.
Kate E. Ashley, Robert McKay, Johan Etourneau, Francisco J. Jimenez-Espejo, Alan Condron, Anna Albot, Xavier Crosta, Christina Riesselman, Osamu Seki, Guillaume Massé, Nicholas R. Golledge, Edward Gasson, Daniel P. Lowry, Nicholas E. Barrand, Katelyn Johnson, Nancy Bertler, Carlota Escutia, Robert Dunbar, and James A. Bendle
Clim. Past, 17, 1–19, https://doi.org/10.5194/cp-17-1-2021, https://doi.org/10.5194/cp-17-1-2021, 2021
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We present a multi-proxy record of Holocene glacial meltwater input, sediment transport, and sea-ice variability off East Antarctica. Our record shows that a rapid Antarctic sea-ice increase during the mid-Holocene (~ 4.5 ka) occurred against a backdrop of increasing glacial meltwater input and gradual climate warming. We suggest that mid-Holocene ice shelf cavity expansion led to cooling of surface waters and sea-ice growth, which slowed basal ice shelf melting.
Takeshi Nakatsuka, Masaki Sano, Zhen Li, Chenxi Xu, Akane Tsushima, Yuki Shigeoka, Kenjiro Sho, Keiko Ohnishi, Minoru Sakamoto, Hiromasa Ozaki, Noboru Higami, Nanae Nakao, Misao Yokoyama, and Takumi Mitsutani
Clim. Past, 16, 2153–2172, https://doi.org/10.5194/cp-16-2153-2020, https://doi.org/10.5194/cp-16-2153-2020, 2020
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In general, it is not easy to reconstruct past climate variations over a wide band of frequencies using a single proxy. Here, we propose a new method to reconstruct past summer climate seamlessly from annual to millennial timescales by integrating tree-ring cellulose oxygen and hydrogen isotope ratios. The result can be utilized to investigate various scales of climatological phenomena in the past and climate–society relationships in long human history.
Wanyu Zhao, Hong Ren, Kimitaka Kawamura, Huiyun Du, Xueshun Chen, Siyao Yue, Qiaorong Xie, Lianfang Wei, Ping Li, Xin Zeng, Shaofei Kong, Yele Sun, Zifa Wang, and Pingqing Fu
Atmos. Chem. Phys., 20, 10331–10350, https://doi.org/10.5194/acp-20-10331-2020, https://doi.org/10.5194/acp-20-10331-2020, 2020
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Our observations provide detailed information on the abundance and vertical distribution of dicarboxylic acids, oxoacids and α-dicarbonyls in PM2.5 collected at three heights based on a 325 m meteorological tower in Beijing in summer. Our results demonstrate that organic acids at the ground surface are largely associated with local traffic emissions, while long-range atmospheric transport followed by photochemical ageing contributes more in the urban boundary layer than the ground surface.
Jing Yang, Wanyu Zhao, Lianfang Wei, Qiang Zhang, Yue Zhao, Wei Hu, Libin Wu, Xiaodong Li, Chandra Mouli Pavuluri, Xiaole Pan, Yele Sun, Zifa Wang, Cong-Qiang Liu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 20, 6841–6860, https://doi.org/10.5194/acp-20-6841-2020, https://doi.org/10.5194/acp-20-6841-2020, 2020
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Our observations provide novel detailed information on the atmospheric abundances and spatial distributions of dicarboxylic acids, oxoacids, and α-dicarbonyls in marine aerosols collected from the South China Sea to the East Indian Ocean. Our results demonstrate that the continental outflow of both biogenic and anthropogenic precursors followed by photochemical aging is one of the main sources and formation processes of marine organic aerosols over the tropical oceanic regions.
Qiaorong Xie, Sihui Su, Shuang Chen, Yisheng Xu, Dong Cao, Jing Chen, Lujie Ren, Siyao Yue, Wanyu Zhao, Yele Sun, Zifa Wang, Haijie Tong, Hang Su, Yafang Cheng, Kimitaka Kawamura, Guibin Jiang, Cong-Qiang Liu, and Pingqing Fu
Atmos. Chem. Phys., 20, 6803–6820, https://doi.org/10.5194/acp-20-6803-2020, https://doi.org/10.5194/acp-20-6803-2020, 2020
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Current knowledge on firework-related organic aerosols is very limited. Here the detailed molecular composition of organics in urban aerosols was characterized using ultrahigh-resolution FT-ICR mass spectrometry. Our findings highlight that firework emission leads to a sharp increase in CHO, CHNO, and CHOS containing high-molecular-weight species, particularly aromatic-like substances, which affect the physicochemical properties such as the light absorption and health effects of urban aerosols.
Yanhong Zhu, Andreas Tilgner, Erik Hans Hoffmann, Hartmut Herrmann, Kimitaka Kawamura, Lingxiao Yang, Likun Xue, and Wenxing Wang
Atmos. Chem. Phys., 20, 6725–6747, https://doi.org/10.5194/acp-20-6725-2020, https://doi.org/10.5194/acp-20-6725-2020, 2020
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The formation and processing of secondary inorganic and organic compounds at Mt. Tai, the highest mountain on the North China Plain, are modeled using a multiphase chemical model. The concentrations of key radical and non-radical oxidations in the formation processes are investigated. Sensitivity tests assess the impacts of emission data and glyoxal partitioning constants on modeled results. The key precursors of secondary organic compounds are also identified.
Yanbing Fan, Cong-Qiang Liu, Linjie Li, Lujie Ren, Hong Ren, Zhimin Zhang, Qinkai Li, Shuang Wang, Wei Hu, Junjun Deng, Libin Wu, Shujun Zhong, Yue Zhao, Chandra Mouli Pavuluri, Xiaodong Li, Xiaole Pan, Yele Sun, Zifa Wang, Kimitaka Kawamura, Zongbo Shi, and Pingqing Fu
Atmos. Chem. Phys., 20, 117–137, https://doi.org/10.5194/acp-20-117-2020, https://doi.org/10.5194/acp-20-117-2020, 2020
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This study provides useful knowledge on the abundance, sources, and formation processes of organic aerosols in the coastal megacity of Tianjin, North China, based on the investigation of the molecular composition, diurnal variation, and winter/summer differences under the influence of land/sea breezes and the Asian summer monsoon.
Dhananjay Kumar Deshmukh, M. Mozammel Haque, Yongwon Kim, and Kimitaka Kawamura
Atmos. Chem. Phys., 19, 14009–14029, https://doi.org/10.5194/acp-19-14009-2019, https://doi.org/10.5194/acp-19-14009-2019, 2019
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Organic tracers are useful to understand the sources and formation mechanisms of organic aerosols. We determined organic tracers in PM2.5 samples collected during the summer season of 2009 using a gas chromatograph–mass spectrometer. A notable feature in the Alaskan aerosol is the high levels of anhydrosugars and n-alkanoic acids. Our results demonstrate that forest fires and plant emissions are the crucial factors controlling the organic aerosol burden in the atmosphere of central Alaska.
Koji Fujita, Sumito Matoba, Yoshinori Iizuka, Nozomu Takeuchi, and Teruo Aoki
Clim. Past Discuss., https://doi.org/10.5194/cp-2019-97, https://doi.org/10.5194/cp-2019-97, 2019
Revised manuscript not accepted
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This study presents a novel method for reconstructing summer temperatures from ice-layer thickness and annual accumulation in an ice core using an energy balance model. The method calculates a lookup table by considering heat conduction and meltwater refreezing in firn. We applied the method to four ice cores in different climates. Sensitivity analyses reveal that the annual temperature range, amount of annual precipitation, and firn albedo significantly affect the estimated summer temperature.
Md. Mozammel Haque, Kimitaka Kawamura, Dhananjay K. Deshmukh, Cao Fang, Wenhuai Song, Bao Mengying, and Yan-Lin Zhang
Atmos. Chem. Phys., 19, 5147–5164, https://doi.org/10.5194/acp-19-5147-2019, https://doi.org/10.5194/acp-19-5147-2019, 2019
Petr Vodička, Kimitaka Kawamura, Jaroslav Schwarz, Bhagawati Kunwar, and Vladimír Ždímal
Atmos. Chem. Phys., 19, 3463–3479, https://doi.org/10.5194/acp-19-3463-2019, https://doi.org/10.5194/acp-19-3463-2019, 2019
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Measurements of stable carbon and nitrogen isotopic compositions in the PM1 atmospheric aerosol provide partial insight into the possible sources of aerosol at a Central European rural background station but mainly offers a deeper insight into the physical and chemical processes taking place between the gas phase and particulate matter. These processes are probably valid in general (not only at this site), especially for nitrogen compounds.
Xin Wan, Shichang Kang, Maheswar Rupakheti, Qianggong Zhang, Lekhendra Tripathee, Junming Guo, Pengfei Chen, Dipesh Rupakheti, Arnico K. Panday, Mark G. Lawrence, Kimitaka Kawamura, and Zhiyuan Cong
Atmos. Chem. Phys., 19, 2725–2747, https://doi.org/10.5194/acp-19-2725-2019, https://doi.org/10.5194/acp-19-2725-2019, 2019
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The sources of primary and secondary aerosols in the Hindu Kush–Himalayan–Tibetan Plateau region are not well known. Organic molecular tracers are useful for aerosol source apportionment. The characterization of molecular tracers were first systemically investigated and the contribution from primary and secondary sources to carbonaceous aerosols was estimated in the Kathmandu Valley. Our results demonstrate that biomass burning contributed a significant fraction to OC in the Kathmandu Valley.
Tomoki Mochizuki, Kimitaka Kawamura, Yuzo Miyazaki, Bhagawati Kunwar, and Suresh Kumar Reddy Boreddy
Atmos. Chem. Phys., 19, 2421–2432, https://doi.org/10.5194/acp-19-2421-2019, https://doi.org/10.5194/acp-19-2421-2019, 2019
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Monocarboxylic acids (MCAs) in gases and particles were measured in deciduous forest. Formic acid in the gas phase and isopentanoic acid in the particle phase were dominant MCAs. Gaseous normal monoacids showed positive correlations with isobutyric acid. Particulate isopentanoic acid showed a positive correlation with lactic acid. The florest floor with soil microbes contributes to emission of MCAs. Our results may be useful to improve understanding of organic aerosol formation in the forest.
Mingjie Kang, Pingqing Fu, Kimitaka Kawamura, Fan Yang, Hongliang Zhang, Zhengchen Zang, Hong Ren, Lujie Ren, Ye Zhao, Yele Sun, and Zifa Wang
Atmos. Chem. Phys., 18, 13947–13967, https://doi.org/10.5194/acp-18-13947-2018, https://doi.org/10.5194/acp-18-13947-2018, 2018
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Molecular characterization and spatial distribution of biogenic primary organic aerosol (POA) and secondary organic aerosol (SOA) in the marine atmosphere are not well known. Here, we analysed the organic molecular composition of marine aerosols collected during a marine cruise in the East China Sea during May–June 2014. Our results suggest that the Asian continent can be a natural emitter of biogenic POA and SOA, which can be transported to the downwind marine atmosphere.
Yanhong Zhu, Lingxiao Yang, Jianmin Chen, Kimitaka Kawamura, Mamiko Sato, Andreas Tilgner, Dominik van Pinxteren, Ying Chen, Likun Xue, Xinfeng Wang, Isobel J. Simpson, Hartmut Herrmann, Donald R. Blake, and Wenxing Wang
Atmos. Chem. Phys., 18, 10741–10758, https://doi.org/10.5194/acp-18-10741-2018, https://doi.org/10.5194/acp-18-10741-2018, 2018
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Molecular distributions of dicarboxylic acids, oxocarboxylic acids and α-dicarbonyls in the free troposphere are identified, and their concentration variations between 2014 and 2006 are presented. High nighttime concentrations were probably due to precursor emissions and aqueous-phase oxidation. Biomass burning was significant, but its tracer levoglucosan in 2014 was 5 times lower than 2006 concentrations. Finally, regional emission from anthropogenic activities was identified as a major source.
Wanyu Zhao, Kimitaka Kawamura, Siyao Yue, Lianfang Wei, Hong Ren, Yu Yan, Mingjie Kang, Linjie Li, Lujie Ren, Senchao Lai, Jie Li, Yele Sun, Zifa Wang, and Pingqing Fu
Atmos. Chem. Phys., 18, 2749–2767, https://doi.org/10.5194/acp-18-2749-2018, https://doi.org/10.5194/acp-18-2749-2018, 2018
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In this paper, we investigate the seasonal trends in concentrations and compound-specific stable carbon isotope ratios of low molecular weight dicarboxylic acids (C2–C12) and related compounds in fine aerosols (PM2.5) in Beijing. Our study demonstrates that, in addition to the production via photo-oxidation, high abundances of diacids and related compounds in Beijing are largely associated with anthropogenic primary emissions such as biomass burning, fossil fuel combustion and plastic burning.
Masashi Niwano, Teruo Aoki, Akihiro Hashimoto, Sumito Matoba, Satoru Yamaguchi, Tomonori Tanikawa, Koji Fujita, Akane Tsushima, Yoshinori Iizuka, Rigen Shimada, and Masahiro Hori
The Cryosphere, 12, 635–655, https://doi.org/10.5194/tc-12-635-2018, https://doi.org/10.5194/tc-12-635-2018, 2018
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We present a high-resolution regional climate model called NHM–SMAP applied to the Greenland Ice Sheet (GrIS). The model forced by JRA-55 reanalysis is evaluated using in situ data from automated weather stations, stake measurements,
and ice core obtained from 2011 to 2014. By utilizing the model, we highlight that the choice of calculation schemes for vertical water movement in snow and firn has an effect of up to 200 Gt/year in the yearly accumulated GrIS-wide surface mass balance estimates.
Suresh K. R. Boreddy, M. Mozammel Haque, and Kimitaka Kawamura
Atmos. Chem. Phys., 18, 1291–1306, https://doi.org/10.5194/acp-18-1291-2018, https://doi.org/10.5194/acp-18-1291-2018, 2018
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To better understand the impact of long-range atmospheric transport of East Asian pollutants over the western North Pacific, we conducted a long-term (2001–12) study on carbonaceous aerosols over the WNP, which demonstrates that the photochemical formation of WSOC and its contributions to SOA have increased over the western North Pacific via long-range atmospheric transport. Biomass-burning-derived carbonaceous aerosols have increased, while primary fossil-fuel-derived aerosols have decreased.
Santosh Kumar Verma, Kimitaka Kawamura, Jing Chen, and Pingqing Fu
Atmos. Chem. Phys., 18, 81–101, https://doi.org/10.5194/acp-18-81-2018, https://doi.org/10.5194/acp-18-81-2018, 2018
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East Asia has experienced rapid economic development in the last several decades, of which activities emit bioaerosols. The atmospheric particles are transported to downwind regions in the Pacific. To understand the atmospheric transport of bioaerosols, we conducted long-term observations of sugar components over Chichijima Island from 2001 to 2013. We found that atmospheric circulations significantly affect the seasonal variation of bioaerosol distributions over the western North Pacific.
Xin Wan, Shichang Kang, Quanlian Li, Dipesh Rupakheti, Qianggong Zhang, Junming Guo, Pengfei Chen, Lekhendra Tripathee, Maheswar Rupakheti, Arnico K. Panday, Wu Wang, Kimitaka Kawamura, Shaopeng Gao, Guangming Wu, and Zhiyuan Cong
Atmos. Chem. Phys., 17, 8867–8885, https://doi.org/10.5194/acp-17-8867-2017, https://doi.org/10.5194/acp-17-8867-2017, 2017
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Biomass burning (BB) tracers in the aerosols in Lumbini, northern IGP, were studied for the first time. The levoglucosan was the predominant tracer and BB significantly contributed to the air quality in Lumbini. Mixed crop residues and hardwood were main burning materials. BB emissions constituted large fraction of OC, especially during the post-monsoon season. The sources of BB aerosols in Lumbini varies seasonally due to the influence of local emissions and long-range transport.
Keiichiro Hara, Sumito Matoba, Motohiro Hirabayashi, and Tetsuhide Yamasaki
Atmos. Chem. Phys., 17, 8577–8598, https://doi.org/10.5194/acp-17-8577-2017, https://doi.org/10.5194/acp-17-8577-2017, 2017
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To obtain knowledge about sea-salt chemistry in polar regions, we made simultaneous measurements and sampling of aerosols, frost flowers, and brine around northwestern Greenland during winter–spring. Our results show sea-salt enrichment in frost flowers and snow. Also, the fractionated sea-salt particles were suspended in the atmosphere over sea-ice areas. From the field evidence and results from earlier studies, we propose and describe sea-salt cycles in seasonal sea-ice areas.
Tomoki Mochizuki, Kimitaka Kawamura, Kazuma Aoki, and Nobuo Sugimoto
Atmos. Chem. Phys., 16, 14621–14633, https://doi.org/10.5194/acp-16-14621-2016, https://doi.org/10.5194/acp-16-14621-2016, 2016
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High abundances of formic and acetic acids in the snow pit samples (6 m in depth) collected at a snowfield site near Mt. Tateyama, central Japan. Formic and acetic acids are highly abundant in the snow, with dust layers in which Ca was enriched. We propose that alkaline metals in Asian dusts largely titrate gaseous organic acids during long-range atmospheric transport.
Yuzo Miyazaki, Sean Coburn, Kaori Ono, David T. Ho, R. Bradley Pierce, Kimitaka Kawamura, and Rainer Volkamer
Atmos. Chem. Phys., 16, 7695–7707, https://doi.org/10.5194/acp-16-7695-2016, https://doi.org/10.5194/acp-16-7695-2016, 2016
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We conducted a WSOC-specific 13C analysis of submicron marine aerosols over the eastern equatorial Pacific for the first time. The analysis of 13C combined with monosaccharides provides evidence of a significant contribution of marine dissolved organic carbon (DOC) to submicron particles in the MBL regardless of the oceanic area. The study demonstrates that DOC is closely correlated with the submicron WSOC and implies that it may characterize background OA in the MBL over the study region.
Chunmao Zhu, Kimitaka Kawamura, Yasuro Fukuda, Michihiro Mochida, and Yoko Iwamoto
Atmos. Chem. Phys., 16, 7497–7506, https://doi.org/10.5194/acp-16-7497-2016, https://doi.org/10.5194/acp-16-7497-2016, 2016
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We collected aerosol samples in a midlatitude forest in Wakayama, Japan and analyzed the organic tracers of various sources. We found that compounds originating from fungal spores contributed significantly to total organic aerosol mass. On the other hand, those from oxidation of biogenic volatile organic compounds, although they could not be ignored, had relatively smaller mass fractions.
Yan-Lin Zhang, Kimitaka Kawamura, Ping Qing Fu, Suresh K. R. Boreddy, Tomomi Watanabe, Shiro Hatakeyama, Akinori Takami, and Wei Wang
Atmos. Chem. Phys., 16, 6407–6419, https://doi.org/10.5194/acp-16-6407-2016, https://doi.org/10.5194/acp-16-6407-2016, 2016
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Here, based on three aircraft measurements over East Asia, we demonstrate an aqueous-phase mechanism for enhanced SOA production in the troposphere following correlation analysis of oxalic acid in tropospheric aerosols with other measured chemical variables including its precursors and its intermediate as well as biogenic-derived SOA from isoprene, monoterpenes and β-caryophyllene.
Dhananjay K. Deshmukh, Kimitaka Kawamura, Manuel Lazaar, Bhagawati Kunwar, and Suresh K. R. Boreddy
Atmos. Chem. Phys., 16, 5263–5282, https://doi.org/10.5194/acp-16-5263-2016, https://doi.org/10.5194/acp-16-5263-2016, 2016
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Size-segregated aerosols in nine size bins were collected in spring 2008 at Cape Hedo, Okinawa, in the western North Pacific Rim, and measured for diacids and related polar compounds. Oxalic acid, glyoxylic acid, and glyoxal peaked at 0.65–1.1 µm in fine mode, suggesting their secondary formation possibly in aerosol aqueous phase. Their strong correlations with liquid water content in fine mode further suggest an importance of the aqueous-phase production in Okinawa aerosols.
S. Kundu, K. Kawamura, M. Kobayashi, E. Tachibana, M. Lee, P. Q. Fu, and J. Jung
Atmos. Chem. Phys., 16, 585–596, https://doi.org/10.5194/acp-16-585-2016, https://doi.org/10.5194/acp-16-585-2016, 2016
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Chemistry-transport models have predicted a change in secondary organic aerosols (SOA) in the future atmosphere with a large uncertainty. This study measures diacids, major water-soluble surrogates of SOA, on a sub-decadal scale in atmospheric aerosols in eastern Asia. Diacids are observed to increase by 3.9–47.4 % per year. The increases in the water-soluble organic acid fraction could modify the aerosol organic composition and its sensitivity to climate-relevant physical properties.
P. Tyagi, S. Yamamoto, and K. Kawamura
Biogeosciences, 12, 7071–7080, https://doi.org/10.5194/bg-12-7071-2015, https://doi.org/10.5194/bg-12-7071-2015, 2015
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Our manuscript represents the first field-based data set on the abundances of hydroxy fatty acids (FAs) in fresh snow and its filtering capacity to reduce hydroxy FA burden on the atmosphere.
•Hydroxy fatty acids (FAs) in snow indicate a contribution from soil microbes and higher plants.
•Air mass back trajectories reveal their transport from Russia, Siberia and China.
We conducted the present study to better understand the impact of aeolian transport on bacteria & their filtering by snow.
T. Mochizuki, Y. Miyazaki, K. Ono, R. Wada, Y. Takahashi, N. Saigusa, K. Kawamura, and A. Tani
Atmos. Chem. Phys., 15, 12029–12041, https://doi.org/10.5194/acp-15-12029-2015, https://doi.org/10.5194/acp-15-12029-2015, 2015
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Simultaneous measurements of concentrations and above-canopy fluxes of isoprene and α-pinene in a forest, along with their oxidation products in aerosols, suggest that the inflow of anthropogenic precursors/aerosols enhanced the formation of both isoprene- and α-pinene-derived secondary organic aerosol (SOA) within the forest canopy even when the flux was low. We also emphasize the role of vegetation/soils near the forest floor as important sources of isoprene and α-pinene in the forest.
C. M. Pavuluri, K. Kawamura, and P. Q. Fu
Atmos. Chem. Phys., 15, 9883–9896, https://doi.org/10.5194/acp-15-9883-2015, https://doi.org/10.5194/acp-15-9883-2015, 2015
C. M. Pavuluri, K. Kawamura, N. Mihalopoulos, and T. Swaminathan
Atmos. Chem. Phys., 15, 7999–8012, https://doi.org/10.5194/acp-15-7999-2015, https://doi.org/10.5194/acp-15-7999-2015, 2015
S. K. R. Boreddy and K. Kawamura
Atmos. Chem. Phys., 15, 6437–6453, https://doi.org/10.5194/acp-15-6437-2015, https://doi.org/10.5194/acp-15-6437-2015, 2015
M. Niwano, T. Aoki, S. Matoba, S. Yamaguchi, T. Tanikawa, K. Kuchiki, and H. Motoyama
The Cryosphere, 9, 971–988, https://doi.org/10.5194/tc-9-971-2015, https://doi.org/10.5194/tc-9-971-2015, 2015
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A physical snowpack model SMAP and in situ meteorological and snow data obtained at site SIGMA-A on the northwest Greenland ice sheet are used to assess surface energy balance during the extreme near-surface snowmelt event around 12 July 2012. We determined that the main factor for the melt event observed at the SIGMA-A site was low-level clouds accompanied by a significant temperature increase, which induced surface heating via cloud radiative forcing in the polar region.
K. F. Ho, R.-J. Huang, K. Kawamura, E. Tachibana, S. C. Lee, S. S. H. Ho, T. Zhu, and L. Tian
Atmos. Chem. Phys., 15, 3111–3123, https://doi.org/10.5194/acp-15-3111-2015, https://doi.org/10.5194/acp-15-3111-2015, 2015
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The objective of this study is to identify the influence of traffic emissions and regional transport to the atmosphere in Beijing during the CAREBeijing-2007 in summer. This study demonstrates that even when primary exhaust was controlled by traffic restrictions, the contribution of secondary organic species formed from photochemical processes was critical with long-range atmospheric transport of pollutants.
C. Zhu, K. Kawamura, and B. Kunwar
Atmos. Chem. Phys., 15, 1959–1973, https://doi.org/10.5194/acp-15-1959-2015, https://doi.org/10.5194/acp-15-1959-2015, 2015
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Using levoglucosan as a biomass burning tracer, influence of biomass burning on the air quality of Okinawa Island in the western North Pacific Rim was evaluated. High levels of levoglucosan were found in the atmospheric aerosols during winter probably due to the open burning and domestic heating and cooking in north/northeast China, Mongolia and Russia, together with enhanced continental outflow.
Z. Cong, S. Kang, K. Kawamura, B. Liu, X. Wan, Z. Wang, S. Gao, and P. Fu
Atmos. Chem. Phys., 15, 1573–1584, https://doi.org/10.5194/acp-15-1573-2015, https://doi.org/10.5194/acp-15-1573-2015, 2015
A. Tsushima, S. Matoba, T. Shiraiwa, S. Okamoto, H. Sasaki, D. J. Solie, and K. Yoshikawa
Clim. Past, 11, 217–226, https://doi.org/10.5194/cp-11-217-2015, https://doi.org/10.5194/cp-11-217-2015, 2015
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A 180.17-m ice core was drilled at Aurora Peak in the central part of the Alaska Range, Alaska, in 2008. The ice core age was determined by annual counts of δD and seasonal cycles of Na+. Here, we show that the chronology of the Aurora Peak ice core from 95.61 m to the top corresponds to the period from 1900 to the summer season of 2008, with a dating error of ±3 years. Our results suggest that temporal variations in δD and annual accumulation rates are strongly related to shifts in PDO Index.
Y. Miyazaki, M. Sawano, and K. Kawamura
Biogeosciences, 11, 4407–4414, https://doi.org/10.5194/bg-11-4407-2014, https://doi.org/10.5194/bg-11-4407-2014, 2014
J. Jung and K. Kawamura
Atmos. Chem. Phys., 14, 7519–7531, https://doi.org/10.5194/acp-14-7519-2014, https://doi.org/10.5194/acp-14-7519-2014, 2014
P. Q. Fu, K. Kawamura, Y. F. Cheng, S. Hatakeyama, A. Takami, H. Li, and W. Wang
Atmos. Chem. Phys., 14, 4185–4199, https://doi.org/10.5194/acp-14-4185-2014, https://doi.org/10.5194/acp-14-4185-2014, 2014
T. Sato, T. Shiraiwa, R. Greve, H. Seddik, E. Edelmann, and T. Zwinger
Clim. Past, 10, 393–404, https://doi.org/10.5194/cp-10-393-2014, https://doi.org/10.5194/cp-10-393-2014, 2014
B. Kunwar and K. Kawamura
Atmos. Chem. Phys., 14, 1819–1836, https://doi.org/10.5194/acp-14-1819-2014, https://doi.org/10.5194/acp-14-1819-2014, 2014
K. Osada, S. Ura, M. Kagawa, M. Mikami, T. Y. Tanaka, S. Matoba, K. Aoki, M. Shinoda, Y. Kurosaki, M. Hayashi, A. Shimizu, and M. Uematsu
Atmos. Chem. Phys., 14, 1107–1121, https://doi.org/10.5194/acp-14-1107-2014, https://doi.org/10.5194/acp-14-1107-2014, 2014
S. L. Mkoma, K. Kawamura, and P. Q. Fu
Atmos. Chem. Phys., 13, 10325–10338, https://doi.org/10.5194/acp-13-10325-2013, https://doi.org/10.5194/acp-13-10325-2013, 2013
Y. Kanaya, H. Akimoto, Z.-F. Wang, P. Pochanart, K. Kawamura, Y. Liu, J. Li, Y. Komazaki, H. Irie, X.-L. Pan, F. Taketani, K. Yamaji, H. Tanimoto, S. Inomata, S. Kato, J. Suthawaree, K. Okuzawa, G. Wang, S. G. Aggarwal, P. Q. Fu, T. Wang, J. Gao, Y. Wang, and G. Zhuang
Atmos. Chem. Phys., 13, 8265–8283, https://doi.org/10.5194/acp-13-8265-2013, https://doi.org/10.5194/acp-13-8265-2013, 2013
K. Kawamura, E. Tachibana, K. Okuzawa, S. G. Aggarwal, Y. Kanaya, and Z. F. Wang
Atmos. Chem. Phys., 13, 8285–8302, https://doi.org/10.5194/acp-13-8285-2013, https://doi.org/10.5194/acp-13-8285-2013, 2013
N. He, K. Kawamura, K. Okuzawa, Y. Kanaya, and Z. F. Wang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-16699-2013, https://doi.org/10.5194/acpd-13-16699-2013, 2013
Revised manuscript not accepted
K. Kawamura, K. Okuzawa, S. G. Aggarwal, H. Irie, Y. Kanaya, and Z. Wang
Atmos. Chem. Phys., 13, 5369–5380, https://doi.org/10.5194/acp-13-5369-2013, https://doi.org/10.5194/acp-13-5369-2013, 2013
C. M. Pavuluri, K. Kawamura, N. Mihalopoulos, and P. Fu
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-6589-2013, https://doi.org/10.5194/acpd-13-6589-2013, 2013
Revised manuscript not accepted
S. L. Mkoma and K. Kawamura
Atmos. Chem. Phys., 13, 2235–2251, https://doi.org/10.5194/acp-13-2235-2013, https://doi.org/10.5194/acp-13-2235-2013, 2013
P. Q. Fu, K. Kawamura, J. Chen, B. Charrière, and R. Sempéré
Biogeosciences, 10, 653–667, https://doi.org/10.5194/bg-10-653-2013, https://doi.org/10.5194/bg-10-653-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Measurement report: Per- and polyfluoroalkyl substances (PFAS) in particulate matter (PM10) from activated sludge aeration
African dust transported to Barbados in the wintertime lacks indicators of chemical aging
A 60-year atmospheric nitrate isotope record from a southeastern Greenland ice core with minimal postdepositional alteration
Measurement report: Characterization of aerosol hygroscopicity over Southeast Asia during the NASA CAMP2Ex campaign
Molecular characterization of organic aerosols in urban and forested areas of Paris using high-resolution mass spectrometry
Measurement report: Wintertime aerosol characterization at an urban traffic site in Helsinki, Finland
Source apportionment and ecotoxicity of PM2.5 pollution events in a major Southern Hemisphere megacity: influence of a biofuel-impacted fleet and biomass burning
Marine organic aerosol at Mace Head: effects from phytoplankton and source region variability
Measurement report: Sources and meteorology influencing highly time-resolved PM2.5 trace elements at three urban sites in the extremely polluted Indo-Gangetic Plain in India
Formation of highly absorptive secondary brown carbon through nighttime multiphase chemistry of biomass burning emissions
Measurement report: Vertically resolved atmospheric properties observed over the Southern Great Plains with the ArcticShark uncrewed aerial system
Technical note: Towards a stronger observational support for haze pollution control by interpreting carbonaceous aerosol results derived from different measurement approaches
Non-biogenic sources are an important but overlooked contributor to aerosol isoprene-derived organosulfates during winter in northern China
The critical role of aqueous-phase processes in aromatic-derived nitrogen-containing organic aerosol formation in cities with different energy consumption patterns
Characterization of atmospheric water-soluble brown carbon in the Athabasca oil sands region, Canada
Sensitivity of aerosol and cloud properties to coupling strength of marine boundary layer clouds over the northwest Atlantic
Measurement Report: Molecular composition, sources, and evolution of atmospheric organic aerosols in a basin city in China
Burning conditions and transportation pathways determine biomass-burning aerosol properties in the Ascension Island marine boundary layer
Observations of high-time-resolution and size-resolved aerosol chemical composition and microphysics in the central Arctic: implications for climate-relevant particle properties
Measurement report: Brown carbon aerosol in rural Germany – sources, chemistry, and diurnal variations
Particle flux-gradient relationships in the high Arctic: Emission and deposition patterns across three surface types
Climatology of aerosol pH and its controlling factors at the Melpitz continental background site in central Europe
Measurement Report: Polycyclic aromatic hydrocarbons (PAHs) and their alkylated (RPAHs), nitrated (NPAHs) and oxygenated (OPAHs) derivatives in the global marine atmosphere: occurrence, spatial variations, and source apportionment
Multiple eco-regions contribute to the seasonal cycle of Antarctic aerosol size distributions
Seasonal investigation of ultrafine-particle organic composition in an eastern Amazonian rainforest
Characterizing lead-rich particles in Beijing's atmosphere following coal-to-gas conversion: Insights from single particle aerosol mass spectrometry
Contrasting solubility and speciation of metal ions in total suspended particulate matter and fog from the coast of Namibia
Significant secondary formation of nitrogenous organic aerosols in an urban atmosphere revealed by bihourly measurements of bulk organic nitrogen and comprehensive molecular markers
High-resolution analyses of concentrations and sizes of refractory black carbon particles deposited in northwestern Greenland over the past 350 years – Part 2: Seasonal and temporal trends in refractory black carbon originated from fossil fuel combustion and biomass burning
Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations
Significant role of biomass burning in heavy haze formation in Nanjing, a megacity in China: molecular-level insights from intensive PM2.5 sampling on winter hazy days
Widespread trace bromine and iodine in remote tropospheric non-sea-salt aerosols
Significant contributions of biomass burning to PM2.5-bound aromatic compounds: insights from field observations and quantum chemical calculations
Iron isotopes reveal significant aerosol dissolution over the Pacific Ocean
Formation and chemical evolution of secondary organic aerosol in two different environments: a dual-chamber study
Complementary aerosol mass spectrometry elucidates sources of wintertime sub-micron particle pollution in Fairbanks, Alaska, during ALPACA 2022
Enrichment of organic nitrogen in fog residuals observed in the Italian Po Valley
Technical note: Quantified organic aerosol subsaturated hygroscopicity by a simple optical scatter monitor system through field measurements
Measurement report: Oxidation potential of water-soluble aerosol components in the south and north of Beijing
Enhanced daytime secondary aerosol formation driven by gas–particle partitioning in downwind urban plumes
Technical note: Reconstructing surface missing aerosol elemental carbon data in long-term series with ensemble learning
Understanding the mechanism and importance of brown carbon bleaching across the visible spectrum in biomass burning plumes from the WE-CAN campaign
Influence of terrestrial and marine air mass on the constituents and intermixing of bioaerosols over a coastal atmosphere
A multi-site passive approach to studying the emissions and evolution of smoke from prescribed fires
The annual cycle and sources of relevant aerosol precursor vapors in the central Arctic during the MOSAiC expedition
Enhanced emission of intermediate/semi-volatile organic matters in both gas and particle phases from ship exhausts with low-sulfur fuels
Advances in characterization of black carbon particles and their associated coatings using the soot particle aerosol mass spectrometer in Singapore, a complex city environment
Measurement report: Crustal materials play an increasing role in elevating particle pH: Insights from 12-year records in a typical inland city of China
Opinion: How will advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution?
Machine Learning Assisted Chemical Characterization and Optical Properties of Atmospheric Brown Carbon in Nanjing, China
Jishnu Pandamkulangara Kizhakkethil, Zongbo Shi, Anna Bogush, and Ivan Kourtchev
Atmos. Chem. Phys., 25, 5947–5958, https://doi.org/10.5194/acp-25-5947-2025, https://doi.org/10.5194/acp-25-5947-2025, 2025
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Pollution with per- and polyfluoroalkyl substances (PFAS) has received attention due to their environmental persistence and bioaccumulation, but their sources remain poorly understood. PM10 (particulate matter) collected above a scaled-down activated sludge tank treating domestic sewage in the UK was analysed for a range of short-, medium-, and long-chain PFAS. Eight PFAS were detected in the PM10. Our results suggest that wastewater treatment processes, i.e. activated sludge aeration, could aerosolise PFAS into airborne PM.
Haley M. Royer, Michael T. Sheridan, Hope E. Elliott, Edmund Blades, Nurun Nahar Lata, Zezhen Cheng, Swarup China, Zihua Zhu, Andrew P. Ault, and Cassandra J. Gaston
Atmos. Chem. Phys., 25, 5743–5759, https://doi.org/10.5194/acp-25-5743-2025, https://doi.org/10.5194/acp-25-5743-2025, 2025
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Saharan dust transported across the Atlantic to the Caribbean, South America, and North America is hypothesized to undergo chemical processing by acids that enhances cloud droplet formation and nutrient availability. In this study, chemical analysis performed on African dust deposited over Barbados shows that acid tracers are found mostly on sea salt and smoke particles, rather than dust, indicating that dust particles undergo minimal chemical processing.
Zhao Wei, Shohei Hattori, Asuka Tsuruta, Zhuang Jiang, Sakiko Ishino, Koji Fujita, Sumito Matoba, Lei Geng, Alexis Lamothe, Ryu Uemura, Naohiro Yoshida, Joel Savarino, and Yoshinori Iizuka
Atmos. Chem. Phys., 25, 5727–5742, https://doi.org/10.5194/acp-25-5727-2025, https://doi.org/10.5194/acp-25-5727-2025, 2025
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Nitrate isotope records in ice cores reveal changes in NOₓ emissions and atmospheric oxidation chemistry driven by human activity. However, UV-driven postdepositional processes can alter nitrate in snow, making snow accumulation rates critical for preserving these records. This study examines nitrate isotopes in a southeastern Greenland ice core, where high snow accumulation minimizes these effects, providing a reliable archive of atmospheric nitrogen cycling.
Genevieve Rose Lorenzo, Luke D. Ziemba, Avelino F. Arellano, Mary C. Barth, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Richard Ferrare, Miguel Ricardo A. Hilario, Michael A. Shook, Simone Tilmes, Jian Wang, Qian Xiao, Jun Zhang, and Armin Sorooshian
Atmos. Chem. Phys., 25, 5469–5495, https://doi.org/10.5194/acp-25-5469-2025, https://doi.org/10.5194/acp-25-5469-2025, 2025
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Novel aerosol hygroscopicity analyses of CAMP2Ex (Cloud, Aerosol, and Monsoon Processes Philippines Experiment) field campaign data show low aerosol hygroscopicity values in Southeast Asia. Organic carbon from smoke decreases hygroscopicity to levels more like those in continental than in polluted marine regions. Hygroscopicity changes at cloud level demonstrate how surface particles impact clouds in the region, affecting model representation of aerosol and cloud interactions in similar polluted marine regions with high organic carbon emissions.
Diana L. Pereira, Chiara Giorio, Aline Gratien, Alexander Zherebker, Gael Noyalet, Servanne Chevaillier, Stéphanie Alage, Elie Almarj, Antonin Bergé, Thomas Bertin, Mathieu Cazaunau, Patrice Coll, Ludovico Di Antonio, Sergio Harb, Johannes Heuser, Cécile Gaimoz, Oscar Guillemant, Brigitte Language, Olivier Lauret, Camilo Macias, Franck Maisonneuve, Bénédicte Picquet-Varrault, Raquel Torres, Sylvain Triquet, Pascal Zapf, Lelia Hawkins, Drew Pronovost, Sydney Riley, Pierre-Marie Flaud, Emilie Perraudin, Pauline Pouyes, Eric Villenave, Alexandre Albinet, Olivier Favez, Robin Aujay-Plouzeau, Vincent Michoud, Christopher Cantrell, Manuela Cirtog, Claudia Di Biagio, Jean-François Doussin, and Paola Formenti
Atmos. Chem. Phys., 25, 4885–4905, https://doi.org/10.5194/acp-25-4885-2025, https://doi.org/10.5194/acp-25-4885-2025, 2025
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In order to study aerosols in environments influenced by anthropogenic and biogenic emissions, we performed analyses of samples collected during the ACROSS (Atmospheric Chemistry Of the Suburban Forest) campaign in summer 2022 in the greater Paris area. After analysis of the chemical composition by means of total carbon determination and high-resolution mass spectrometry, this work highlights the influence of anthropogenic inputs on the chemical composition of both urban and forested areas.
Kimmo Teinilä, Sanna Saarikoski, Henna Lintusaari, Teemu Lepistö, Petteri Marjanen, Minna Aurela, Heidi Hellén, Toni Tykkä, Markus Lampimäki, Janne Lampilahti, Luis Barreira, Timo Mäkelä, Leena Kangas, Juha Hatakka, Sami Harni, Joel Kuula, Jarkko V. Niemi, Harri Portin, Jaakko Yli-Ojanperä, Ville Niemelä, Milja Jäppi, Katrianne Lehtipalo, Joonas Vanhanen, Liisa Pirjola, Hanna E. Manninen, Tuukka Petäjä, Topi Rönkkö, and Hilkka Timonen
Atmos. Chem. Phys., 25, 4907–4928, https://doi.org/10.5194/acp-25-4907-2025, https://doi.org/10.5194/acp-25-4907-2025, 2025
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Physical and chemical properties of particulate matter and concentrations of trace gases were measured in a street canyon in Helsinki, Finland, and an urban background site in January–February 2022 to investigate the effect of wintertime conditions on pollutants. State-of-the-art instruments and a mobile laboratory were used, and the measurement data were analysed further with modelling tools like positive matrix factorization and the Pollution Detection Algorithm.
Guilherme Martins Pereira, Leonardo Yoshiaki Kamigauti, Rubens Fabio Pereira, Djacinto Monteiro dos Santos, Thayná da Silva Santos, José Vinicius Martins, Célia Alves, Cátia Gonçalves, Ismael Casotti Rienda, Nora Kováts, Thiago Nogueira, Luciana Rizzo, Paulo Artaxo, Regina Maura de Miranda, Marcia Akemi Yamasoe, Edmilson Dias de Freitas, Pérola de Castro Vasconcellos, and Maria de Fatima Andrade
Atmos. Chem. Phys., 25, 4587–4616, https://doi.org/10.5194/acp-25-4587-2025, https://doi.org/10.5194/acp-25-4587-2025, 2025
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The chemical composition of fine particulate matter was studied in the megacity of São Paulo (Brazil) during a polluted period. Vehicular-related sources remain relevant; however, a high contribution of biomass burning was observed and correlated with sample ecotoxicity. Emerging biomass burning sources, such as forest fires and sugarcane-bagasse-based power plants, highlight the need for additional control measures alongside stricter rules concerning vehicular emissions.
Emmanuel Chevassus, Kirsten N. Fossum, Darius Ceburnis, Lu Lei, Chunshui Lin, Wei Xu, Colin O'Dowd, and Jurgita Ovadnevaite
Atmos. Chem. Phys., 25, 4107–4129, https://doi.org/10.5194/acp-25-4107-2025, https://doi.org/10.5194/acp-25-4107-2025, 2025
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This study presents the first source apportionment of organic aerosol at Mace Head via high-resolution mass spectrometry. Introducing transfer entropy as a novel method reveals that aged organic aerosol originates from both open-ocean ozonolysis and local peat-burning oxidation. Methanesulfonic acid and organic sea spray both mirror phytoplankton activity, with the former closely tied to coccolithophore blooms and the latter linked to diatoms, chlorophytes, and cyanobacteria.
Ashutosh K. Shukla, Sachchida N. Tripathi, Shamitaksha Talukdar, Vishnu Murari, Sreenivas Gaddamidi, Manousos-Ioannis Manousakas, Vipul Lalchandani, Kuldeep Dixit, Vinayak M. Ruge, Peeyush Khare, Mayank Kumar, Vikram Singh, Neeraj Rastogi, Suresh Tiwari, Atul K. Srivastava, Dilip Ganguly, Kaspar Rudolf Daellenbach, and André S. H. Prévôt
Atmos. Chem. Phys., 25, 3765–3784, https://doi.org/10.5194/acp-25-3765-2025, https://doi.org/10.5194/acp-25-3765-2025, 2025
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Our study delves into the elemental composition of aerosols at three sites across the Indo-Gangetic Plain (IGP), revealing distinct patterns during pollution episodes. We found significant increases in chlorine (Cl)-rich and solid fuel combustion (SFC) sources, indicating dynamic emission sources, agricultural burning impacts, and meteorological influences. Surges in Cl-rich particles during cold periods highlight their role in particle growth under high-relative-humidity conditions.
Ye Kuang, Biao Luo, Shan Huang, Junwen Liu, Weiwei Hu, Yuwen Peng, Duohong Chen, Dingli Yue, Wanyun Xu, Bin Yuan, and Min Shao
Atmos. Chem. Phys., 25, 3737–3752, https://doi.org/10.5194/acp-25-3737-2025, https://doi.org/10.5194/acp-25-3737-2025, 2025
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This research reveals the potential importance of nighttime NO3 radical chemistry and aerosol water in the rapid formation of secondary brown carbon from diluted biomass burning emissions. The findings enhance our understanding of nighttime biomass burning evolution and its implications for climate and regional air quality, especially regarding interactions with background aerosol water and water-rich fogs and clouds.
Fan Mei, Qi Zhang, Damao Zhang, Jerome D. Fast, Gourihar Kulkarni, Mikhail S. Pekour, Christopher R. Niedek, Susanne Glienke, Israel Silber, Beat Schmid, Jason M. Tomlinson, Hardeep S. Mehta, Xena Mansoura, Zezhen Cheng, Gregory W. Vandergrift, Nurun Nahar Lata, Swarup China, and Zihua Zhu
Atmos. Chem. Phys., 25, 3425–3444, https://doi.org/10.5194/acp-25-3425-2025, https://doi.org/10.5194/acp-25-3425-2025, 2025
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This study highlights the unique capability of the ArcticShark, an uncrewed aerial system, in measuring vertically resolved atmospheric properties. Data from 32 research flights in 2023 reveal seasonal patterns and correlations with conventional measurements. The consistency and complementarity of in situ and remote sensing methods are highlighted. The study demonstrates the ArcticShark’s versatility in bridging data gaps and improving the understanding of vertical atmospheric structures.
Yuan Cheng, Ying-jie Zhong, Zhi-qing Zhang, Xu-bing Cao, and Jiu-meng Liu
EGUsphere, https://doi.org/10.5194/egusphere-2025-537, https://doi.org/10.5194/egusphere-2025-537, 2025
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As an emerging hotspot of atmospheric sciences, Northeast China is distinct due to the frigid winter and the strong emissions from agricultural fires. Based on field campaigns conducted in Harbin, we successively identified the analytical method that could lead to proper results of organic and elemental carbon. Our results are believed to be a support for future efforts on exploration of the PM2.5 sources in Northeast China, which are essential for further improving the regional air quality.
Ting Yang, Yu Xu, Yu-Chen Wang, Yi-Jia Ma, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 25, 2967–2978, https://doi.org/10.5194/acp-25-2967-2025, https://doi.org/10.5194/acp-25-2967-2025, 2025
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Previous measurement–model comparisons of atmospheric isoprene levels showed a significant unidentified source of isoprene in some northern Chinese cities during winter. Here, the first combination of large-scale observations and field combustion experiments provides novel insights into biomass burning emissions as a significant source of isoprene-derived organosulfates during winter in northern cities of China.
Yi-Jia Ma, Yu Xu, Ting Yang, Lin Gui, Hong-Wei Xiao, Hao Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 25, 2763–2780, https://doi.org/10.5194/acp-25-2763-2025, https://doi.org/10.5194/acp-25-2763-2025, 2025
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The abundance, potential precursors, and main formation mechanisms of nitrogen-containing organic compounds (NOCs) in PM2.5 during winter were compared among cities with different energy consumption patterns. The aerosol NOC pollution during winter in China is closely associated with the intensity of precursor emissions and the aqueous-phase processes. Our results highlight the importance of emission reduction strategies in controlling aerosol NOCs pollution during winter in China.
Dane Blanchard, Mark Gordon, Duc Huy Dang, Paul Andrew Makar, and Julian Aherne
Atmos. Chem. Phys., 25, 2423–2442, https://doi.org/10.5194/acp-25-2423-2025, https://doi.org/10.5194/acp-25-2423-2025, 2025
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This study offers the first known evaluation of water-soluble brown carbon aerosols in the Athabasca oil sands region (AOSR), Canada. Fluorescence spectroscopy analysis of aerosol samples from five regional sites (collected during the summer of 2021) identified oil sands operations as a measurable brown carbon source. Industrial aerosol emissions were unlikely to impact regional radiative forcing. These findings show that fluorescence spectroscopy can be used to monitor brown carbon in the AOSR.
Kira Zeider, Kayla McCauley, Sanja Dmitrovic, Leong Wai Siu, Yonghoon Choi, Ewan C. Crosbie, Joshua P. DiGangi, Glenn S. Diskin, Simon Kirschler, John B. Nowak, Michael A. Shook, Kenneth L. Thornhill, Christiane Voigt, Edward L. Winstead, Luke D. Ziemba, Paquita Zuidema, and Armin Sorooshian
Atmos. Chem. Phys., 25, 2407–2422, https://doi.org/10.5194/acp-25-2407-2025, https://doi.org/10.5194/acp-25-2407-2025, 2025
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In situ aircraft data collected over the northwest Atlantic Ocean are utilized to compare aerosol conditions and turbulence between near-surface and below-cloud-base altitudes for different regimes of coupling strength between those two levels, along with how cloud microphysical properties vary across those regimes. Stronger coupling yields more homogenous aerosol structure vertically along with higher cloud drop concentrations and sea salt influence in clouds.
Junke Zhang, Xinyi Fu, Chunying Chen, Yunfei Su, Siyu Liu, Luyao Chen, Yubao Chen, Gehui Wang, and Andre S. H. Prevot
EGUsphere, https://doi.org/10.5194/egusphere-2025-92, https://doi.org/10.5194/egusphere-2025-92, 2025
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The 125 organic aerosol (OA) compounds in PM2.5 in winter in Chengdu were measured at the molecular level. OA was dominated by fatty acids, phthalate esters, and anhydrosugars, and were deeply influenced by anthropogenic sources. As pollution worsens: secondary inorganic species and secondary organic carbon (OC) dominated the increase in PM2.5; fatty acids and anhydrosugars dominated the increase in OA; and the contribution of secondary formation and biomass burning to OC increased markedly.
Amie Dobracki, Ernie R. Lewis, Arthur J. Sedlacek III, Tyler Tatro, Maria A. Zawadowicz, and Paquita Zuidema
Atmos. Chem. Phys., 25, 2333–2363, https://doi.org/10.5194/acp-25-2333-2025, https://doi.org/10.5194/acp-25-2333-2025, 2025
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Biomass-burning aerosol is commonly present in the marine boundary layer over the southeast Atlantic Ocean between June and October. Our research indicates that burning conditions, aerosol transport pathways, and prolonged oxidation processes (heterogeneous and aqueous phases) determine the chemical, microphysical, and optical properties of the boundary layer aerosol. Notably, we find that the aerosol optical properties can be estimated from the chemical properties alone.
Benjamin Heutte, Nora Bergner, Hélène Angot, Jakob B. Pernov, Lubna Dada, Jessica A. Mirrielees, Ivo Beck, Andrea Baccarini, Matthew Boyer, Jessie M. Creamean, Kaspar R. Daellenbach, Imad El Haddad, Markus M. Frey, Silvia Henning, Tiia Laurila, Vaios Moschos, Tuukka Petäjä, Kerri A. Pratt, Lauriane L. J. Quéléver, Matthew D. Shupe, Paul Zieger, Tuija Jokinen, and Julia Schmale
Atmos. Chem. Phys., 25, 2207–2241, https://doi.org/10.5194/acp-25-2207-2025, https://doi.org/10.5194/acp-25-2207-2025, 2025
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Limited aerosol measurements in the central Arctic hinder our understanding of aerosol–climate interactions in the region. Our year-long observations of aerosol physicochemical properties during the MOSAiC expedition reveal strong seasonal variations in aerosol chemical composition, where the short-term variability is heavily affected by storms in the Arctic. Local wind-generated particles are shown to be an important source of cloud seeds, especially in autumn.
Feng Jiang, Harald Saathoff, Uzoamaka Ezenobi, Junwei Song, Hengheng Zhang, Linyu Gao, and Thomas Leisner
Atmos. Chem. Phys., 25, 1917–1930, https://doi.org/10.5194/acp-25-1917-2025, https://doi.org/10.5194/acp-25-1917-2025, 2025
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The chemical composition of brown carbon in the particle and gas phase was determined by mass spectrometry. BrC in the gas phase was mainly controlled by secondary formation and particle-to-gas partitioning. BrC in the particle phase was mainly from secondary formation. This work helps to get a better understanding of diurnal variations and the sources of brown carbon aerosol at a rural location in central Europe.
Theresa Mathes, Heather Guy, John Prytherch, Julia Kojoj, Ian Brooks, Sonja Murto, Paul Zieger, Birgit Wehner, Michael Tjernström, and Andreas Held
EGUsphere, https://doi.org/10.5194/egusphere-2025-183, https://doi.org/10.5194/egusphere-2025-183, 2025
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The Arctic is warming faster than the global average and aerosol-cloud-sea-ice interactions are crucial for studying its climate system. During the ARTofMELT Expedition 2023, particle and sensible heat fluxes were measured over multiple surfaces. Wide lead surfaces acted as particle sources with the strongest sensible heat fluxes, while closed ice surfaces acted as a particle sink. This study improves methods to measure these interactions, enhancing our understanding of Arctic climate processes.
Vikram Pratap, Christopher J. Hennigan, Bastian Stieger, Andreas Tilgner, Laurent Poulain, Dominik van Pinxteren, Gerald Spindler, and Hartmut Herrmann
EGUsphere, https://doi.org/10.5194/egusphere-2025-457, https://doi.org/10.5194/egusphere-2025-457, 2025
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In this work, we characterize trends in aerosol pH and its controlling factors over the period of 2010 – 2019 at the Melpitz research station in eastern Germany. We find strong trends in aerosol pH and major inorganic species in response to changing emissions. We conduct a detailed thermodynamic analysis of the aerosol system and discuss implications for controlling PM2.5 in the region.
Rui Li, Yubing Shen, Yumeng Shao, Yining Gao, Ziwei Yao, Qian Liu, Xing Liu, and Guitao Shi
EGUsphere, https://doi.org/10.5194/egusphere-2024-3740, https://doi.org/10.5194/egusphere-2024-3740, 2025
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It is the first time to reveal the global variations of PAHs derivatives in the marine air. We found that marine aerosols in East China Sea (ECS) and Western Pacific (WP) were significantly affected by coal and engine combustion, while those in Bismarck Sea (BS) and East Australian Sea (EAS) were mainly influenced by wildfire and coal combustion. Antarctic Ocean (AO) was dominated by biomass burning and local shipping emissions. This finding help elucidate the mechanism of global PAH cycle.
James Brean, David C. S. Beddows, Eija Asmi, Aki Virkkula, Lauriane L. J. Quéléver, Mikko Sipilä, Floortje Van Den Heuvel, Thomas Lachlan-Cope, Anna Jones, Markus Frey, Angelo Lupi, Jiyeon Park, Young Jun Yoon, Rolf Weller, Giselle L. Marincovich, Gabriela C. Mulena, Roy M. Harrison, and Manuel Dall'Osto
Atmos. Chem. Phys., 25, 1145–1162, https://doi.org/10.5194/acp-25-1145-2025, https://doi.org/10.5194/acp-25-1145-2025, 2025
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Our results emphasise how understanding the geographical variation in surface types across the Antarctic is key to understanding secondary aerosol sources.
Adam E. Thomas, Hayley S. Glicker, Alex B. Guenther, Roger Seco, Oscar Vega Bustillos, Julio Tota, Rodrigo A. F. Souza, and James N. Smith
Atmos. Chem. Phys., 25, 959–977, https://doi.org/10.5194/acp-25-959-2025, https://doi.org/10.5194/acp-25-959-2025, 2025
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We present measurements of the organic composition of ultrafine particles collected from the eastern Amazon, an understudied region that is subjected to increasing human influence. We find that while isoprene chemistry is likely significant for ultrafine-particle growth throughout the year, compounds related to other sources, such as biological-spore emissions and biomass burning, exhibit striking seasonal differences, implying extensive variation in regional ultrafine-particle sources.
Xiufeng Lian, Yongjiang Xu, Fengxian Liu, Long Peng, Xiaodong Hu, Guigang Tang, Xu Dao, Hui Guo, Liwei Wang, Bo Huang, Chunlei Cheng, Lei Li, Guohua Zhang, Xinhui Bi, Xiaofei Wang, Zhen Zhou, and Mei Li
EGUsphere, https://doi.org/10.5194/egusphere-2024-3469, https://doi.org/10.5194/egusphere-2024-3469, 2025
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In this study, we analyzed the mixing state and atmospheric chemical processes of Pb-rich single particles in Beijing. Then, we focused on analyzing the differences in Pb-rich particles between the heating period and non-heating period, as well as the formation mechanism of lead nitrate after coal-to-gas conversion. Our results highlighted the improvement of coal-to-gas conversion on Pb in the particulate.
Chiara Giorio, Anne Monod, Valerio Di Marco, Pierre Herckes, Denise Napolitano, Amy Sullivan, Gautier Landrot, Daniel Warnes, Marika Nasti, Sara D'Aronco, Agathe Gérardin, Nicolas Brun, Karine Desboeufs, Sylvain Triquet, Servanne Chevaillier, Claudia Di Biagio, Francesco Battaglia, Frédéric Burnet, Stuart J. Piketh, Andreas Namwoonde, Jean-François Doussin, and Paola Formenti
EGUsphere, https://doi.org/10.5194/egusphere-2024-4140, https://doi.org/10.5194/egusphere-2024-4140, 2025
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A comparison between the solubility of trace metals in pairs of total suspended particulate (TSP) and fog water samples collected in Henties Bay, Namibia, during the AEROCLO-sA field campaign is presented. We found enhanced solubility of metals in fog samples which we attributed to metal-ligand complexes formation in the early stages of particle activation into droplets which can then remain in a kinetically stable form in fog or lead to the formation of colloidal nanoparticles.
Xu Yu, Min Zhou, Shuhui Zhu, Liping Qiao, Jinjian Li, Yingge Ma, Zijing Zhang, Kezheng Liao, Hongli Wang, and Jian Zhen Yu
EGUsphere, https://doi.org/10.5194/egusphere-2024-4103, https://doi.org/10.5194/egusphere-2024-4103, 2025
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Online measurements of bulk aerosol organic nitrogen (ON), in conjunction with a comprehensive array of source markers, have revealed five emission sources and five potentially significant formation processes of nitrogenous organic aerosols. This study provides first quantitative source analysis of ON aerosol and valuable observational evidence on secondary ON aerosol formation through NH3 and NOx chemistries.
Kumiko Goto-Azuma, Yoshimi Ogawa-Tsukagawa, Kaori Fukuda, Koji Fujita, Motohiro Hirabayashi, Remi Dallmayr, Jun Ogata, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Sumito Matoba, Moe Kadota, Akane Tsushima, Naoko Nagatsuka, and Teruo Aoki
Atmos. Chem. Phys., 25, 657–683, https://doi.org/10.5194/acp-25-657-2025, https://doi.org/10.5194/acp-25-657-2025, 2025
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Monthly ice core records spanning 350 years from Greenland show trends in refractory black carbon (rBC) concentrations and sizes. rBC levels have increased since the 1870s due to the inflow of anthropogenic rBC, with larger diameters than those from biomass burning (BB) rBC. High summer BB rBC peaks may reduce the ice sheet albedo, but BB rBC showed no increase until the early 2000s. These results are vital for validating aerosol and climate models.
Jiayin Li, Tianyu Zhai, Xiaorui Chen, Haichao Wang, Shuyang Xie, Shiyi Chen, Chunmeng Li, Huabin Dong, and Keding Lu
EGUsphere, https://doi.org/10.5194/egusphere-2024-3804, https://doi.org/10.5194/egusphere-2024-3804, 2025
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We directly measured the dinitrogen pentoxide (N2O5) uptake coefficient which critical impact the NOx fate and particulate nitrate formation in a typical highland city, Kunming, in China. We found the performance of current γ(N2O5) parameterizations showed deviations with the varying aerosol liquid water content (ALWC). Such differences would lead to biased estimation on particulate nitrate production potential. Our findings suggest the directions for future studies.
Mingjie Kang, Mengying Bao, Wenhuai Song, Aduburexiati Abulimiti, Changliu Wu, Fang Cao, Sönke Szidat, and Yanlin Zhang
Atmos. Chem. Phys., 25, 73–91, https://doi.org/10.5194/acp-25-73-2025, https://doi.org/10.5194/acp-25-73-2025, 2025
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Reports on molecular-level knowledge of high-temporal-resolution particulate matter ≤2.5 µm in diameter (PM2.5) on hazy days are limited. We investigated various PM2.5 species and their sources. The results show biomass burning (BB) was the main source of organic carbon. Moreover, BB enhanced fungal spore emissions and secondary aerosol formation. The contribution of non-fossil sources increased with increasing haze pollution, suggesting BB may be an important driver of haze events in winter.
Gregory P. Schill, Karl D. Froyd, Daniel M. Murphy, Christina J. Williamson, Charles A. Brock, Tomás Sherwen, Mat J. Evans, Eric A. Ray, Eric C. Apel, Rebecca S. Hornbrook, Alan J. Hills, Jeff Peischl, Thomas B. Ryerson, Chelsea R. Thompson, Ilann Bourgeois, Donald R. Blake, Joshua P. DiGangi, and Glenn S. Diskin
Atmos. Chem. Phys., 25, 45–71, https://doi.org/10.5194/acp-25-45-2025, https://doi.org/10.5194/acp-25-45-2025, 2025
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Using single-particle mass spectrometry, we show that trace concentrations of bromine and iodine are ubiquitous in remote tropospheric aerosol and suggest that aerosols are an important part of the global reactive iodine budget. Comparisons to a global climate model with detailed iodine chemistry are favorable in the background atmosphere; however, the model cannot replicate our measurements near the ocean surface, in biomass burning plumes, and in the stratosphere.
Yanqin Ren, Zhenhai Wu, Fang Bi, Hong Li, Haijie Zhang, Junling Li, Rui Gao, Fangyun Long, Zhengyang Liu, Yuanyuan Ji, and Gehui Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3678, https://doi.org/10.5194/egusphere-2024-3678, 2025
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The daily concentrations of Polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (OPAHs), and nitrated phenols (NPs) in PM2.5 were all increased during the heating season. Biomass burning was identified to be the primary source of these aromatic compounds, particularly for PAHs. Phenol and nitrobenzene are two main primary precursors for 4NP, with phenol showing lower reaction barriers. P-Cresol was identified as the primary precursor for the formation of 4-methyl-5-nitrocatechol.
Capucine Camin, François Lacan, Catherine Pradoux, Marie Labatut, Anne Johansen, and James W. Murray
EGUsphere, https://doi.org/10.5194/egusphere-2024-3777, https://doi.org/10.5194/egusphere-2024-3777, 2024
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This manuscript presents the chemical composition of aerosols (> 1µm) over the Equatorial and Tropical Pacific Ocean, presenting the first measurements of iron isotopes in aerosols from this region. Iron concentrations and isotopes were determined using a Neptune MC-ICPMS. Our data analysis reveals that a significant portion of the aerosols undergo dissolution and removal during atmospheric transport. These findings contribute to original conclusions about the chemistry and physics of aerosols.
Andreas Aktypis, Dontavious J. Sippial, Christina N. Vasilakopoulou, Angeliki Matrali, Christos Kaltsonoudis, Andrea Simonati, Marco Paglione, Matteo Rinaldi, Stefano Decesari, and Spyros N. Pandis
Atmos. Chem. Phys., 24, 13769–13791, https://doi.org/10.5194/acp-24-13769-2024, https://doi.org/10.5194/acp-24-13769-2024, 2024
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A dual-chamber system was deployed in two different environments (Po Valley, Italy, and Pertouli forest, Greece) to study the potential of ambient air directly injected into the chambers, to form secondary organic aerosol (SOA). In the Po Valley, the system reacts rapidly, forming large amounts of SOA, while in Pertouli the SOA formation chemistry appears to have been practically terminated before the beginning of most experiments, so there is little additional SOA formation potential left.
Amna Ijaz, Brice Temime-Roussel, Benjamin Chazeau, Sarah Albertin, Stephen R. Arnold, Brice Barrett, Slimane Bekki, Natalie Brett, Meeta Cesler-Maloney, Elsa Dieudonne, Kayane K. Dingilian, Javier G. Fochesatto, Jingqiu Mao, Allison Moon, Joel Savarino, William Simpson, Rodney J. Weber, Kathy S. Law, and Barbara D'Anna
EGUsphere, https://doi.org/10.5194/egusphere-2024-3789, https://doi.org/10.5194/egusphere-2024-3789, 2024
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Fairbanks is among the most polluted cities with the highest particulate matter (PM) levels in the US during winters. Highly time-resolved measurements of the sub-micron PM elucidated residential heating with wood and oil and hydrocarbon-like organics from traffic, as well as sulphur-containing organic aerosol, to be the key pollution sources. Remarkable differences existed between complementary instruments, warranting the deployment of multiple tools at sites with wide-ranging influences.
Fredrik Mattsson, Almuth Neuberger, Liine Heikkinen, Yvette Gramlich, Marco Paglione, Matteo Rinaldi, Stefano Decesari, Paul Zieger, Ilona Riipinen, and Claudia Mohr
EGUsphere, https://doi.org/10.5194/egusphere-2024-3629, https://doi.org/10.5194/egusphere-2024-3629, 2024
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This study investigated aerosol-cloud interactions, focusing on organic nitrogen (ON) formation in the aqueous phase. Measurements were conducted in wintertime Italian Po Valley, using aerosol mass spectrometry. The fog was enriched in more hygroscopic inorganic compounds and ON, containing e.g. imidazoles. The formation of imidazole by aerosol-fog interactions could be confirmed for the first time in atmospheric observations. Findings highlight the role of fog in nitrogen aerosol formation.
Jie Zhang, Tianyu Zhu, Alexandra Catena, Yaowei Li, Margaret J. Schwab, Pengfei Liu, Akua Asa-Awuku, and James Schwab
Atmos. Chem. Phys., 24, 13445–13456, https://doi.org/10.5194/acp-24-13445-2024, https://doi.org/10.5194/acp-24-13445-2024, 2024
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This study shows the derived organic aerosol hygroscopicity under high-humidity conditions based on a simple optical scatter monitor system, including two nephelometric monitors (pDR-1500), when the aerosol chemical composition is already known.
Wei Yuan, Ru-Jin Huang, Chao Luo, Lu Yang, Wenjuan Cao, Jie Guo, and Huinan Yang
Atmos. Chem. Phys., 24, 13219–13230, https://doi.org/10.5194/acp-24-13219-2024, https://doi.org/10.5194/acp-24-13219-2024, 2024
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We characterized water-soluble oxidative potential (OP) levels in wintertime PM2.5 in the south and north of Beijing. Our results show that the volume-normalized dithiothreitol (DTTv) in the north was comparable to that in the south, while the mass-normalized dithiothreitol (DTTm) in the north was almost twice that in the south. Traffic-related emissions and biomass burning were the main sources of DTTv in the south, and traffic-related emissions contributed the most to DTTv in the north.
Mingfu Cai, Chenshuo Ye, Bin Yuan, Shan Huang, E Zheng, Suxia Yang, Zelong Wang, Yi Lin, Tiange Li, Weiwei Hu, Wei Chen, Qicong Song, Wei Li, Yuwen Peng, Baoling Liang, Qibin Sun, Jun Zhao, Duohong Chen, Jiaren Sun, Zhiyong Yang, and Min Shao
Atmos. Chem. Phys., 24, 13065–13079, https://doi.org/10.5194/acp-24-13065-2024, https://doi.org/10.5194/acp-24-13065-2024, 2024
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This study investigated the daytime secondary organic aerosol (SOA) formation in urban plumes. We observed a significant daytime SOA formation through gas–particle partitioning when the site was affected by urban plumes. A box model simulation indicated that urban pollutants (nitrogen oxide and volatile organic compounds) could enhance the oxidizing capacity, while the elevated volatile organic compounds were mainly responsible for promoting daytime SOA formation.
Qingxiao Meng, Yunjiang Zhang, Sheng Zhong, Jie Fang, Lili Tang, Yongcai Rao, Minfeng Zhou, Jian Qiu, Xiaofeng Xu, Jean-Eudes Petit, Olivier Favez, and Xinlei Ge
EGUsphere, https://doi.org/10.5194/egusphere-2024-2776, https://doi.org/10.5194/egusphere-2024-2776, 2024
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We developed a new method to reconstruct missing elemental carbon (EC) data in four Chinese cities from 2013 to 2023. Using machine learning, we accurately filled data gaps and introduced a new approach to analyze EC trends. Our findings reveal a significant decline in EC due to stricter pollution controls, though this slowed after 2020. This study provides a versatile framework for addressing data gaps and supports strategies to reduce urban air pollution and its climate impacts.
Yingjie Shen, Rudra P. Pokhrel, Amy P. Sullivan, Ezra J. T. Levin, Lauren A. Garofalo, Delphine K. Farmer, Wade Permar, Lu Hu, Darin W. Toohey, Teresa Campos, Emily V. Fischer, and Shane M. Murphy
Atmos. Chem. Phys., 24, 12881–12901, https://doi.org/10.5194/acp-24-12881-2024, https://doi.org/10.5194/acp-24-12881-2024, 2024
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The magnitude and evolution of brown carbon (BrC) absorption remain unclear, with uncertainty in climate models. Data from the WE-CAN airborne experiment show that model parameterizations overestimate the mass absorption cross section (MAC) of BrC. Observed decreases in BrC absorption with chemical markers are due to decreasing organic aerosol (OA) mass rather than a decreasing BrC MAC, which is currently implemented in models. Water-soluble BrC contributes 23 % of total absorption at 660 nm.
Qun He, Zhaowen Wang, Houfeng Liu, Pengju Xu, Rongbao Duan, Caihong Xu, Jianmin Chen, and Min Wei
Atmos. Chem. Phys., 24, 12775–12792, https://doi.org/10.5194/acp-24-12775-2024, https://doi.org/10.5194/acp-24-12775-2024, 2024
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Coastal environments provide an ideal setting for investigating the intermixing of terrestrial and marine aerosols. Terrestrial air mass constituted a larger number of microbes from anthropogenic and soil emissions, whereas saprophytic and gut microbes were predominant in marine samples. Mixed air masses indicated a fusion of marine and terrestrial aerosols, characterized by alterations in the ratio of pathogenic and saprophytic microbes when compared to either terrestrial or marine samples.
Rime El Asmar, Zongrun Li, David J. Tanner, Yongtao Hu, Susan O'Neill, L. Gregory Huey, M. Talat Odman, and Rodney J. Weber
Atmos. Chem. Phys., 24, 12749–12773, https://doi.org/10.5194/acp-24-12749-2024, https://doi.org/10.5194/acp-24-12749-2024, 2024
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Prescribed burning is an important method for managing ecosystems and preventing wildfires. However, smoke from prescribed fires can have a significant impact on air quality. Here, using a network of fixed sites and sampling throughout an extended prescribed burning period in 2 different years, we characterize emissions and evolutions of up to 8 h of PM2.5 mass, black carbon (BC), and brown carbon (BrC) in smoke from burning of forested lands in the southeastern USA.
Matthew Boyer, Diego Aliaga, Lauriane L. J. Quéléver, Silvia Bucci, Hélène Angot, Lubna Dada, Benjamin Heutte, Lisa Beck, Marina Duetsch, Andreas Stohl, Ivo Beck, Tiia Laurila, Nina Sarnela, Roseline C. Thakur, Branka Miljevic, Markku Kulmala, Tuukka Petäjä, Mikko Sipilä, Julia Schmale, and Tuija Jokinen
Atmos. Chem. Phys., 24, 12595–12621, https://doi.org/10.5194/acp-24-12595-2024, https://doi.org/10.5194/acp-24-12595-2024, 2024
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We analyze the seasonal cycle and sources of gases that are relevant for the formation of aerosol particles in the central Arctic. Since theses gases can form new particles, they can influence Arctic climate. We show that the sources of these gases are associated with changes in the Arctic environment during the year, especially with respect to sea ice. Therefore, the concentration of these gases will likely change in the future as the Arctic continues to warm.
Binyu Xiao, Fan Zhang, Zeyu Liu, Yan Zhang, Rui Li, Can Wu, Xinyi Wan, Yi Wang, Yubao Chen, Yong Han, Min Cui, Libo Zhang, Yingjun Chen, and Gehui Wang
EGUsphere, https://doi.org/10.5194/egusphere-2024-3433, https://doi.org/10.5194/egusphere-2024-3433, 2024
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Intermediate/semi-volatile organic compounds in both gas and particle phases from ship exhausts are enhanced due to the switch of fuels from low-sulfur to ultra-low-sulfur. The findings indicate that optimization is necessary for the forthcoming global implementation of an ultra-low-sulfur oil policy. Besides, we find that organic diagnostic markers of hopanes, in conjunction with the ratio of octadecanoic to tetradecanoic could be considered as potential tracers for HFO exhausts.
Mutian Ma, Laura-Hélèna Rivellini, Yichen Zong, Markus Kraft, Liya E. Yu, and Alex King Yin Lee
EGUsphere, https://doi.org/10.5194/egusphere-2024-3240, https://doi.org/10.5194/egusphere-2024-3240, 2024
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This work advances our understanding of emission and atmospheric evolution of black carbon (BC) particles in Singapore, a complex urban environment impacted by multiple local and regional combustion sources, based on the improved source apportionment analysis of real-time aerosol mass spectrometry measurement.
Hongyu Zhang, Shenbo Wang, Zhangsen Dong, Xiao Li, and Ruiqin Zhang
EGUsphere, https://doi.org/10.5194/egusphere-2024-2869, https://doi.org/10.5194/egusphere-2024-2869, 2024
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To address this, 12-year observational data in Zhengzhou were investigated and revealed that the resuspension of surrounding soil dust determined the rebound of crustal material concentrations after 2019, further elevating the particle pH. Therefore, the future ammonia reduction policies in North China may not lead to a rapid increase in particle acidity buffering by the crustal materials, but it is necessary to consider synergistic control with dust sources.
Imad El Haddad, Danielle Vienneau, Kaspar R. Daellenbach, Robin Modini, Jay G. Slowik, Abhishek Upadhyay, Petros N. Vasilakos, David Bell, Kees de Hoogh, and Andre S. H. Prevot
Atmos. Chem. Phys., 24, 11981–12011, https://doi.org/10.5194/acp-24-11981-2024, https://doi.org/10.5194/acp-24-11981-2024, 2024
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This opinion paper explores how advances in aerosol science inform our understanding of the health impacts of outdoor particulate pollution. We advocate for a shift in the way we target PM pollution, focusing on the most harmful anthropogenic emissions. We highlight key observations, modelling developments, and emission measurements needed to achieve this shift.
Yu Huang, Xingru Li, Dan Dan Huang, Ruoyuan Lei, Binhuang Zhou, Yunjiang Zhang, and Xinlei Ge
EGUsphere, https://doi.org/10.5194/egusphere-2024-2757, https://doi.org/10.5194/egusphere-2024-2757, 2024
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This work performed a comprehensive investigation on the chemical and optical properties of the brown carbon in PM2.5 samples collected in Nanjing, China. In particular, we used the machine learning approach to identify a list of key BrC species, which can be a good reference for future studies. Our findings extend the understanding on BrC properties and are valuable to the assessment of its impact on air quality and radiative forcing.
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Short summary
A 180 m long (ca. 274 year) ice core was drilled in the saddle of the Aurora Peak in Alaska (63.52° N, 146.54° W; elevation: 2,825 m). The ice core samples were derived with O-bis-(trimethylsilyl)trifluoroacetamide with 1 % trimethylsilyl chloride and pyridine followed by gas-chromatography–mass-spectrometry analyses. Levoglucosan, dehydroabietic acid and vanillic acid are reported for the first time from the alpine glacier to better understand historical biomass burning.
A 180 m long (ca. 274 year) ice core was drilled in the saddle of the Aurora Peak in Alaska...
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