Articles | Volume 16, issue 19
https://doi.org/10.5194/acp-16-12531-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-12531-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
07 Oct 2016
Research article |
| 07 Oct 2016
Air–snow exchange of nitrate: a modelling approach to investigate physicochemical processes in surface snow at Dome C, Antarctica
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norfolk, NR4 7TJ, Norwich, UK
now at: Météo France, CNRM, Centre National de Recherches Météorologiques, UMR3589, 42 avenue G. Coriolis, 31057 Toulouse CEDEX 1, France
Joël Savarino
Université Grenoble Alpes, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38041 Grenoble, France
CNRS, LGGE UMR5183, 38041 Grenoble, France
Ghislain Picard
Université Grenoble Alpes, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38041 Grenoble, France
CNRS, LGGE UMR5183, 38041 Grenoble, France
Related authors
Feras Abdulsamad, Josué Bock, Florence Magnin, Emmanuel Malet, André Revil, Matan Ben-Asher, Jessy Richard, Pierre-Allain Duvillard, Marios Karaoulis, Thomas Condom, Ludovic Ravanel, and Philip Deline
EGUsphere, https://doi.org/10.5194/egusphere-2025-637, https://doi.org/10.5194/egusphere-2025-637, 2025
Short summary
Short summary
Permafrost dynamics at Aiguille du Midi in the French Alps was investigated using Automated Electrical Resistivity Tomography (A-ERT) during four years. A-ERT reveals seasonal and multi-year permafrost changes. Temperatures estimated using resistivity measurements provide a good agreement with measured temperature in borehole in frozen zone. Variations in active layer thickness across different faces were observed, along with a slight decrease in permafrost resistivity suggesting warming.
Matan Ben-Asher, Florence Magnin, Sebastian Westermann, Josué Bock, Emmanuel Malet, Johan Berthet, Ludovic Ravanel, and Philip Deline
Earth Surf. Dynam., 11, 899–915, https://doi.org/10.5194/esurf-11-899-2023, https://doi.org/10.5194/esurf-11-899-2023, 2023
Short summary
Short summary
Quantitative knowledge of water availability on high mountain rock slopes is very limited. We use a numerical model and field measurements to estimate the water balance at a steep rock wall site. We show that snowmelt is the main source of water at elevations >3600 m and that snowpack hydrology and sublimation are key factors. The new information presented here can be used to improve the understanding of thermal, hydrogeological, and mechanical processes on steep mountain rock slopes.
Josué Bock, Jan Kaiser, Max Thomas, Andreas Bott, and Roland von Glasow
Geosci. Model Dev., 15, 5807–5828, https://doi.org/10.5194/gmd-15-5807-2022, https://doi.org/10.5194/gmd-15-5807-2022, 2022
Short summary
Short summary
MISTRA-v9.0 is an atmospheric boundary layer chemistry model. The model includes a detailed particle description with regards to the microphysics, gas–particle interactions, and liquid phase chemistry within particles. Version 9.0 is the first release of MISTRA as an open-source community model. This paper presents a thorough description of the model characteristics and components. We show some examples of simulations reproducing previous studies with MISTRA with good consistency.
Josué Bock, Martine Michou, Pierre Nabat, Manabu Abe, Jane P. Mulcahy, Dirk J. L. Olivié, Jörg Schwinger, Parvadha Suntharalingam, Jerry Tjiputra, Marco van Hulten, Michio Watanabe, Andrew Yool, and Roland Séférian
Biogeosciences, 18, 3823–3860, https://doi.org/10.5194/bg-18-3823-2021, https://doi.org/10.5194/bg-18-3823-2021, 2021
Short summary
Short summary
In this study we analyse surface ocean dimethylsulfide (DMS) concentration and flux to the atmosphere from four CMIP6 Earth system models over the historical and ssp585 simulations.
Our analysis of contemporary (1980–2009) climatologies shows that models better reproduce observations in mid to high latitudes. The models disagree on the sign of the trend of the global DMS flux from 1980 onwards. The models agree on a positive trend of DMS over polar latitudes following sea-ice retreat dynamics.
Lison Soussaintjean, Jochen Schmitt, Joël Savarino, J. Andy Menking, Edward J. Brook, Barbara Seth, Vladimir Lipenkov, Thomas Röckmann, and Hubertus Fischer
EGUsphere, https://doi.org/10.5194/egusphere-2025-3108, https://doi.org/10.5194/egusphere-2025-3108, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Short summary
Nitrous oxide (N2O) produced in dust-rich Antarctic ice complicates the reconstruction of past atmospheric levels from ice core records. Using isotope analysis, we show that N2O forms from two nitrogen precursors, one being nitrate. For the first time, we demonstrate that the site preference (SP) of N2O reflects the isotopic difference between these precursors, not the production pathway, which challenges the common interpretation of SP.
Titouan Tcheng, Elise Fourré, Christophe Leroy-Dos-Santos, Frédéric Parrenin, Emmanuel Le Meur, Frédéric Prié, Olivier Jossoud, Roxanne Jacob, Bénédicte Minster, Olivier Magand, Cécile Agosta, Niels Dutrievoz, Vincent Favier, Léa Baubant, Coralie Lassalle-Bernard, Mathieu Casado, Martin Werner, Alexandre Cauquoin, Laurent Arnaud, Bruno Jourdain, Ghislain Picard, Marie Bouchet, and Amaëlle Landais
EGUsphere, https://doi.org/10.5194/egusphere-2025-2863, https://doi.org/10.5194/egusphere-2025-2863, 2025
This preprint is open for discussion and under review for The Cryosphere (TC).
Short summary
Short summary
Studying Antarctic ice cores is crucial to assess past climate changes, as they hold historical climate data. This study examines multiple ice cores from three sites in coastal Adélie Land to see if combining cores improves data interpretability. It does at two sites, but at a third, wind-driven snow layer mixing limited benefits. We show that using multiple ice cores from one location can better uncover climate history, especially in areas with less wind disturbance.
Filip Pastierovic, Roberto Grilli, Nicolas Caillon, and Joel Savarino
EGUsphere, https://doi.org/10.5194/egusphere-2025-3115, https://doi.org/10.5194/egusphere-2025-3115, 2025
This preprint is open for discussion and under review for Atmospheric Measurement Techniques (AMT).
Short summary
Short summary
The development of an open detector based on absorption spectroscopy, enhanced by high-reflectivity mirrors, for the simultaneous measurement of NO2, IO, and CHOCHO is reported. The instrument shows good correlation with a closed system during both indoor and outdoor measurements. An open system is able to measure NO2, IO, and CHOCHO with high precision.
Zhao Wei, Shohei Hattori, Asuka Tsuruta, Zhuang Jiang, Sakiko Ishino, Koji Fujita, Sumito Matoba, Lei Geng, Alexis Lamothe, Ryu Uemura, Naohiro Yoshida, Joel Savarino, and Yoshinori Iizuka
Atmos. Chem. Phys., 25, 5727–5742, https://doi.org/10.5194/acp-25-5727-2025, https://doi.org/10.5194/acp-25-5727-2025, 2025
Short summary
Short summary
Nitrate isotope records in ice cores reveal changes in NOₓ emissions and atmospheric oxidation chemistry driven by human activity. However, UV-driven postdepositional processes can alter nitrate in snow, making snow accumulation rates critical for preserving these records. This study examines nitrate isotopes in a southeastern Greenland ice core, where high snow accumulation minimizes these effects, providing a reliable archive of atmospheric nitrogen cycling.
Florent Domine, Mireille Quémener, Ludovick Bégin, Benjamin Bouchard, Valérie Dionne, Sébastien Jerczynski, Raphaël Larouche, Félix Lévesque-Desrosiers, Simon-Olivier Philibert, Marc-André Vigneault, Ghislain Picard, and Daniel C. Côté
The Cryosphere, 19, 1757–1774, https://doi.org/10.5194/tc-19-1757-2025, https://doi.org/10.5194/tc-19-1757-2025, 2025
Short summary
Short summary
Shrubs buried in snow absorb solar radiation and reduce irradiance in the snowpack. This decreases photochemical reaction rates and emissions to the atmosphere. By monitoring irradiance in snowpacks with and without shrubs, we conclude that shrubs absorb solar radiation as much as 140 ppb of soot and reduce irradiance by a factor of 2. Shrub expansion in the Arctic may therefore affect tropospheric composition during the snow season with climatic effects.
Léa Elise Bonnefoy, Catherine Prigent, Ghislain Picard, Clément Soriot, Alice Le Gall, Lise Kilic, and Carlos Jimenez
EGUsphere, https://doi.org/10.5194/egusphere-2024-3972, https://doi.org/10.5194/egusphere-2024-3972, 2025
Short summary
Short summary
Microwave radiometry senses the thermal emission from a target, whereas its active counterpart, radar, sends a signal to the target and measures the signal reflected back. We simultaneously model radar and radiometry over the East Antarctic ice sheet, which we propose as an analog for icy moons: we can reproduce most data with a unique model. Saturn's moons' radar brightness cannot be reproduced and must be caused by processes unaccounted for in the model and less active in the Antarctic.
Marion Leduc-Leballeur, Ghislain Picard, Pierre Zeiger, and Giovanni Macelloni
EGUsphere, https://doi.org/10.5194/egusphere-2025-732, https://doi.org/10.5194/egusphere-2025-732, 2025
Short summary
Short summary
This study presents a quantitative and synthetic classification of the snowpack in 10 dry-wet status by aggregating separate binary indicators derived from satellite observations. The classification follows the expected evolution of the melt season: night refreezing is frequent at the onset, sustained melting is observed during the summer peak, and remnant liquid water at depth occurs at the end. This dataset improves the knowledge of melt processes using passive microwave remote sensing.
Brice Barret, Patrice Medina, Natalie Brett, Roman Pohorsky, Kathy S. Law, Slimane Bekki, Gilberto J. Fochesatto, Julia Schmale, Steve R. Arnold, Andrea Baccarini, Maurizio Busetto, Meeta Cesler-Maloney, Barbara D'Anna, Stefano Decesari, Jingqiu Mao, Gianluca Pappaccogli, Joel Savarino, Federico Scoto, and William R. Simpson
Atmos. Meas. Tech., 18, 1163–1184, https://doi.org/10.5194/amt-18-1163-2025, https://doi.org/10.5194/amt-18-1163-2025, 2025
Short summary
Short summary
The Fairbanks area experiences severe pollution episodes in winter because of enhanced emissions of pollutants trapped near the surface by strong temperature inversions. Low-cost sensors were deployed on board a car and a tethered balloon to measure the concentrations of gaseous pollutants (CO, O3, and NOx) in Fairbanks during winter 2022. Data calibration with reference measurements and machine learning methods enabled us to document pollution at the surface and power plant plumes aloft.
Feras Abdulsamad, Josué Bock, Florence Magnin, Emmanuel Malet, André Revil, Matan Ben-Asher, Jessy Richard, Pierre-Allain Duvillard, Marios Karaoulis, Thomas Condom, Ludovic Ravanel, and Philip Deline
EGUsphere, https://doi.org/10.5194/egusphere-2025-637, https://doi.org/10.5194/egusphere-2025-637, 2025
Short summary
Short summary
Permafrost dynamics at Aiguille du Midi in the French Alps was investigated using Automated Electrical Resistivity Tomography (A-ERT) during four years. A-ERT reveals seasonal and multi-year permafrost changes. Temperatures estimated using resistivity measurements provide a good agreement with measured temperature in borehole in frozen zone. Variations in active layer thickness across different faces were observed, along with a slight decrease in permafrost resistivity suggesting warming.
Natalie Brett, Kathy S. Law, Steve R. Arnold, Javier G. Fochesatto, Jean-Christophe Raut, Tatsuo Onishi, Robert Gilliam, Kathleen Fahey, Deanna Huff, George Pouliot, Brice Barret, Elsa Dieudonné, Roman Pohorsky, Julia Schmale, Andrea Baccarini, Slimane Bekki, Gianluca Pappaccogli, Federico Scoto, Stefano Decesari, Antonio Donateo, Meeta Cesler-Maloney, William Simpson, Patrice Medina, Barbara D'Anna, Brice Temime-Roussel, Joel Savarino, Sarah Albertin, Jingqiu Mao, Becky Alexander, Allison Moon, Peter F. DeCarlo, Vanessa Selimovic, Robert Yokelson, and Ellis S. Robinson
Atmos. Chem. Phys., 25, 1063–1104, https://doi.org/10.5194/acp-25-1063-2025, https://doi.org/10.5194/acp-25-1063-2025, 2025
Short summary
Short summary
Processes influencing dispersion of local anthropogenic pollution in Arctic wintertime are investigated with Lagrangian dispersion modelling. Simulated power plant plume rise that considers temperature inversion layers improves results compared to observations (interior Alaska). Modelled surface concentrations are improved by representation of vertical mixing and emission estimates. Large increases in diesel vehicle emissions at temperatures reaching −35°C are required to reproduce observed NOx.
Agnese Petteni, Elise Fourré, Elsa Gautier, Azzurra Spagnesi, Roxanne Jacob, Pete D. Akers, Daniele Zannoni, Jacopo Gabrieli, Olivier Jossoud, Frédéric Prié, Amaëlle Landais, Titouan Tcheng, Barbara Stenni, Joel Savarino, Patrick Ginot, and Mathieu Casado
EGUsphere, https://doi.org/10.5194/egusphere-2024-3335, https://doi.org/10.5194/egusphere-2024-3335, 2025
Short summary
Short summary
Our research compares three CFA-CRDS systems from Venice, Paris, and Grenoble for measuring water isotopes in ice cores, crucial for reconstructing past climate. We quantify each system’s mixing and measurement noise effects, which impact the achievable resolution of isotope continuous records. Our findings reveal specific configurations and procedures to enhance measurement accuracy, providing a framework to optimise water isotope analysis.
Inès Ollivier, Hans Christian Steen-Larsen, Barbara Stenni, Laurent Arnaud, Mathieu Casado, Alexandre Cauquoin, Giuliano Dreossi, Christophe Genthon, Bénédicte Minster, Ghislain Picard, Martin Werner, and Amaëlle Landais
The Cryosphere, 19, 173–200, https://doi.org/10.5194/tc-19-173-2025, https://doi.org/10.5194/tc-19-173-2025, 2025
Short summary
Short summary
The role of post-depositional processes taking place at the ice sheet's surface on the water stable isotope signal measured in polar ice cores is not fully understood. Using field observations and modelling results, we show that the original precipitation isotopic signal at Dome C, East Antarctica, is modified by post-depositional processes and provide the first quantitative estimation of their mean impact on the isotopic signal observed in the snow.
Ghislain Picard and Quentin Libois
Geosci. Model Dev., 17, 8927–8953, https://doi.org/10.5194/gmd-17-8927-2024, https://doi.org/10.5194/gmd-17-8927-2024, 2024
Short summary
Short summary
The Two-streAm Radiative TransfEr in Snow (TARTES) is a radiative transfer model to compute snow albedo in the solar domain and the profiles of light and energy absorption in a multi-layered snowpack whose physical properties are user defined. It uniquely considers snow grain shape flexibly, based on recent insights showing that snow does not behave as a collection of ice spheres but instead as a random medium. TARTES is user-friendly yet performs comparably to more complex models.
Amna Ijaz, Brice Temime-Roussel, Benjamin Chazeau, Sarah Albertin, Stephen R. Arnold, Brice Barrett, Slimane Bekki, Natalie Brett, Meeta Cesler-Maloney, Elsa Dieudonne, Kayane K. Dingilian, Javier G. Fochesatto, Jingqiu Mao, Allison Moon, Joel Savarino, William Simpson, Rodney J. Weber, Kathy S. Law, and Barbara D'Anna
EGUsphere, https://doi.org/10.5194/egusphere-2024-3789, https://doi.org/10.5194/egusphere-2024-3789, 2024
Short summary
Short summary
Fairbanks is among the most polluted cities with the highest particulate matter (PM) levels in the US during winters. Highly time-resolved measurements of the sub-micron PM elucidated residential heating with wood and oil and hydrocarbon-like organics from traffic, as well as sulphur-containing organic aerosol, to be the key pollution sources. Remarkable differences existed between complementary instruments, warranting the deployment of multiple tools at sites with wide-ranging influences.
Melody Sandells, Nick Rutter, Kirsty Wivell, Richard Essery, Stuart Fox, Chawn Harlow, Ghislain Picard, Alexandre Roy, Alain Royer, and Peter Toose
The Cryosphere, 18, 3971–3990, https://doi.org/10.5194/tc-18-3971-2024, https://doi.org/10.5194/tc-18-3971-2024, 2024
Short summary
Short summary
Satellite microwave observations are used for weather forecasting. In Arctic regions this is complicated by natural emission from snow. By simulating airborne observations from in situ measurements of snow, this study shows how snow properties affect the signal within the atmosphere. Fresh snowfall between flights changed airborne measurements. Good knowledge of snow layering and structure can be used to account for the effects of snow and could unlock these data to improve forecasts.
Sara Arioli, Ghislain Picard, Laurent Arnaud, Simon Gascoin, Esteban Alonso-González, Marine Poizat, and Mark Irvine
Earth Syst. Sci. Data, 16, 3913–3934, https://doi.org/10.5194/essd-16-3913-2024, https://doi.org/10.5194/essd-16-3913-2024, 2024
Short summary
Short summary
High-accuracy precision maps of the surface temperature of snow were acquired with an uncooled thermal-infrared camera during winter 2021–2022 and spring 2023. The accuracy – i.e., mean absolute error – improved from 1.28 K to 0.67 K between the seasons thanks to an improved camera setup and temperature stabilization. The dataset represents a major advance in the validation of satellite measurements and physical snow models over a complex topography.
Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffrey Severinghaus, Barbara Stenni, and Patricia Martinerie
The Cryosphere, 18, 3741–3763, https://doi.org/10.5194/tc-18-3741-2024, https://doi.org/10.5194/tc-18-3741-2024, 2024
Short summary
Short summary
Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
Julien Meloche, Melody Sandells, Henning Löwe, Nick Rutter, Richard Essery, Ghislain Picard, Randall K. Scharien, Alexandre Langlois, Matthias Jaggi, Josh King, Peter Toose, Jérôme Bouffard, Alessandro Di Bella, and Michele Scagliola
EGUsphere, https://doi.org/10.5194/egusphere-2024-1583, https://doi.org/10.5194/egusphere-2024-1583, 2024
Preprint archived
Short summary
Short summary
Sea ice thickness is essential for climate studies. Radar altimetry has provided sea ice thickness measurement, but uncertainty arises from interaction of the signal with the snow cover. Therefore, modelling the signal interaction with the snow is necessary to improve retrieval. A radar model was used to simulate the radar signal from the snow-covered sea ice. This work paved the way to improved physical algorithm to retrieve snow depth and sea ice thickness for radar altimeter missions.
V. Holly L. Winton, Robert Mulvaney, Joel Savarino, Kyle R. Clem, and Markus M. Frey
Clim. Past, 20, 1213–1232, https://doi.org/10.5194/cp-20-1213-2024, https://doi.org/10.5194/cp-20-1213-2024, 2024
Short summary
Short summary
In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We present the first results including a 1300-year record of snow accumulation and aerosol chemistry. We investigate the aerosol and moisture source regions and atmospheric processes related to the ice core record and discuss what this means for developing a record of past ultraviolet radiation and ozone depletion using the stable isotopic composition of nitrate measured in the same ice core.
Zhuang Jiang, Becky Alexander, Joel Savarino, and Lei Geng
Atmos. Chem. Phys., 24, 4895–4914, https://doi.org/10.5194/acp-24-4895-2024, https://doi.org/10.5194/acp-24-4895-2024, 2024
Short summary
Short summary
Ice-core nitrate could track the past atmospheric NOx and oxidant level, but its interpretation is hampered by the post-depositional processing. In this work, an inverse model was developed and tested against two polar sites and was shown to well reproduce the observed nitrate signals in snow and atmosphere, suggesting that the model can properly correct for the effect of post-depositional processing. This model offers a very useful tool for future studies on ice-core nitrate records.
Naomi E. Ochwat, Ted A. Scambos, Alison F. Banwell, Robert S. Anderson, Michelle L. Maclennan, Ghislain Picard, Julia A. Shates, Sebastian Marinsek, Liliana Margonari, Martin Truffer, and Erin C. Pettit
The Cryosphere, 18, 1709–1731, https://doi.org/10.5194/tc-18-1709-2024, https://doi.org/10.5194/tc-18-1709-2024, 2024
Short summary
Short summary
On the Antarctic Peninsula, there is a small bay that had sea ice fastened to the shoreline (
fast ice) for over a decade. The fast ice stabilized the glaciers that fed into the ocean. In January 2022, the fast ice broke away. Using satellite data we found that this was because of low sea ice concentrations and a high long-period ocean wave swell. We find that the glaciers have responded to this event by thinning, speeding up, and retreating by breaking off lots of icebergs at remarkable rates.
Justin Murfitt, Claude Duguay, Ghislain Picard, and Juha Lemmetyinen
The Cryosphere, 18, 869–888, https://doi.org/10.5194/tc-18-869-2024, https://doi.org/10.5194/tc-18-869-2024, 2024
Short summary
Short summary
This research focuses on the interaction between microwave signals and lake ice under wet conditions. Field data collected for Lake Oulujärvi in Finland were used to model backscatter under different conditions. The results of the modelling likely indicate that a combination of increased water content and roughness of different interfaces caused backscatter to increase. These results could help to identify areas where lake ice is unsafe for winter transportation.
Claudio Stefanini, Giovanni Macelloni, Marion Leduc-Leballeur, Vincent Favier, Benjamin Pohl, and Ghislain Picard
The Cryosphere, 18, 593–608, https://doi.org/10.5194/tc-18-593-2024, https://doi.org/10.5194/tc-18-593-2024, 2024
Short summary
Short summary
Local and large-scale meteorological conditions have been considered in order to explain some peculiar changes of snow grains on the East Antarctic Plateau from 2000 to 2022, by using remote sensing observations and reanalysis. We identified some extreme grain size events on the highest ice divide, resulting from a combination of conditions of low wind speed and low temperature. Moreover, the beginning of seasonal grain growth has been linked to the occurrence of atmospheric rivers.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, Roberto Grilli, Quentin Fournier, Irène Ventrillard, Nicolas Caillon, and Kathy Law
Atmos. Chem. Phys., 24, 1361–1388, https://doi.org/10.5194/acp-24-1361-2024, https://doi.org/10.5194/acp-24-1361-2024, 2024
Short summary
Short summary
This study reports the first simultaneous records of oxygen (Δ17O) and nitrogen (δ15N) isotopes in nitrogen dioxide (NO2) and nitrate (NO3−). These data are combined with atmospheric observations to explore sub-daily N reactive chemistry and quantify N fractionation effects in an Alpine winter city. The results highlight the necessity of using Δ17O and δ15N in both NO2 and NO3− to avoid biased estimations of NOx sources and fates from NO3− isotopic records in urban winter environments.
Jean Emmanuel Sicart, Victor Ramseyer, Ghislain Picard, Laurent Arnaud, Catherine Coulaud, Guilhem Freche, Damien Soubeyrand, Yves Lejeune, Marie Dumont, Isabelle Gouttevin, Erwan Le Gac, Frédéric Berger, Jean-Matthieu Monnet, Laurent Borgniet, Éric Mermin, Nick Rutter, Clare Webster, and Richard Essery
Earth Syst. Sci. Data, 15, 5121–5133, https://doi.org/10.5194/essd-15-5121-2023, https://doi.org/10.5194/essd-15-5121-2023, 2023
Short summary
Short summary
Forests strongly modify the accumulation, metamorphism and melting of snow in midlatitude and high-latitude regions. Two field campaigns during the winters 2016–17 and 2017–18 were conducted in a coniferous forest in the French Alps to study interactions between snow and vegetation. This paper presents the field site, instrumentation and collection methods. The observations include forest characteristics, meteorology, snow cover and snow interception by the canopy during precipitation events.
Thomas Dethinne, Quentin Glaude, Ghislain Picard, Christoph Kittel, Patrick Alexander, Anne Orban, and Xavier Fettweis
The Cryosphere, 17, 4267–4288, https://doi.org/10.5194/tc-17-4267-2023, https://doi.org/10.5194/tc-17-4267-2023, 2023
Short summary
Short summary
We investigate the sensitivity of the regional climate model
Modèle Atmosphérique Régional(MAR) to the assimilation of wet-snow occurrence estimated by remote sensing datasets. The assimilation is performed by nudging the MAR snowpack temperature. The data assimilation is performed over the Antarctic Peninsula for the 2019–2021 period. The results show an increase in the melt production (+66.7 %) and a decrease in surface mass balance (−4.5 %) of the model for the 2019–2020 melt season.
Matan Ben-Asher, Florence Magnin, Sebastian Westermann, Josué Bock, Emmanuel Malet, Johan Berthet, Ludovic Ravanel, and Philip Deline
Earth Surf. Dynam., 11, 899–915, https://doi.org/10.5194/esurf-11-899-2023, https://doi.org/10.5194/esurf-11-899-2023, 2023
Short summary
Short summary
Quantitative knowledge of water availability on high mountain rock slopes is very limited. We use a numerical model and field measurements to estimate the water balance at a steep rock wall site. We show that snowmelt is the main source of water at elevations >3600 m and that snowpack hydrology and sublimation are key factors. The new information presented here can be used to improve the understanding of thermal, hydrogeological, and mechanical processes on steep mountain rock slopes.
Alexis Lamothe, Joel Savarino, Patrick Ginot, Lison Soussaintjean, Elsa Gautier, Pete D. Akers, Nicolas Caillon, and Joseph Erbland
Atmos. Meas. Tech., 16, 4015–4030, https://doi.org/10.5194/amt-16-4015-2023, https://doi.org/10.5194/amt-16-4015-2023, 2023
Short summary
Short summary
Ammonia is a reactive gas in our atmosphere that is key in air quality issues. Assessing its emissions and how it reacts is a hot topic that can be addressed from the past. Stable isotopes (the mass of the molecule) measured in ice cores (glacial archives) can teach us a lot. However, the concentrations in ice cores are very small. We propose a protocol to limit the contamination and apply it to one ice core drilled in Mont Blanc, describing the opportunities our method brings.
Yaowen Zheng, Nicholas R. Golledge, Alexandra Gossart, Ghislain Picard, and Marion Leduc-Leballeur
The Cryosphere, 17, 3667–3694, https://doi.org/10.5194/tc-17-3667-2023, https://doi.org/10.5194/tc-17-3667-2023, 2023
Short summary
Short summary
Positive degree-day (PDD) schemes are widely used in many Antarctic numerical ice sheet models. However, the PDD approach has not been systematically explored for its application in Antarctica. We have constructed a novel grid-cell-level spatially distributed PDD (dist-PDD) model and assessed its accuracy. We suggest that an appropriately parameterized dist-PDD model can be a valuable tool for exploring Antarctic surface melt beyond the satellite era.
Esteban Alonso-González, Simon Gascoin, Sara Arioli, and Ghislain Picard
The Cryosphere, 17, 3329–3342, https://doi.org/10.5194/tc-17-3329-2023, https://doi.org/10.5194/tc-17-3329-2023, 2023
Short summary
Short summary
Data assimilation techniques are a promising approach to improve snowpack simulations in remote areas that are difficult to monitor. This paper studies the ability of satellite-observed land surface temperature to improve snowpack simulations through data assimilation. We show that it is possible to improve snowpack simulations, but the temporal resolution of the observations and the algorithm used are critical to obtain satisfactory results.
Sara Arioli, Ghislain Picard, Laurent Arnaud, and Vincent Favier
The Cryosphere, 17, 2323–2342, https://doi.org/10.5194/tc-17-2323-2023, https://doi.org/10.5194/tc-17-2323-2023, 2023
Short summary
Short summary
To assess the drivers of the snow grain size evolution during snow drift, we exploit a 5-year time series of the snow grain size retrieved from spectral-albedo observations made with a new, autonomous, multi-band radiometer and compare it to observations of snow drift, snowfall and snowmelt at a windy location of coastal Antarctica. Our results highlight the complexity of the grain size evolution in the presence of snow drift and show an overall tendency of snow drift to limit its variations.
Simone Ventisette, Samuele Baldini, Claudio Artoni, Silvia Becagli, Laura Caiazzo, Barbara Delmonte, Massimo Frezzotti, Raffaello Nardin, Joel Savarino, Mirko Severi, Andrea Spolaor, Barbara Stenni, and Rita Traversi
EGUsphere, https://doi.org/10.5194/egusphere-2023-393, https://doi.org/10.5194/egusphere-2023-393, 2023
Preprint archived
Short summary
Short summary
The paper reports the spatial variability of concentration and fluxes of chemical impurities in superficial snow over unexplored area of the East Antarctic ice sheet. Pinatubo and Puyehue-Cordón Caulle volcanic eruptions in non-sea salt sulfate and dust snow pits record were used to achieve the accumulation rates. Deposition (wet, dry and uptake from snow surface) and post deposition processes are constrained. These knowledges are fundamental in Antarctic ice cores stratigraphies interpretation.
Ghislain Picard, Marion Leduc-Leballeur, Alison F. Banwell, Ludovic Brucker, and Giovanni Macelloni
The Cryosphere, 16, 5061–5083, https://doi.org/10.5194/tc-16-5061-2022, https://doi.org/10.5194/tc-16-5061-2022, 2022
Short summary
Short summary
Using a snowpack radiative transfer model, we investigate in which conditions meltwater can be detected from passive microwave satellite observations from 1.4 to 37 GHz. In particular, we determine the minimum detectable liquid water content, the maximum depth of detection of a buried wet snow layer and the risk of false alarm due to supraglacial lakes. These results provide information for the developers of new, more advanced satellite melt products and for the users of the existing products.
Pete D. Akers, Joël Savarino, Nicolas Caillon, Olivier Magand, and Emmanuel Le Meur
Atmos. Chem. Phys., 22, 15637–15657, https://doi.org/10.5194/acp-22-15637-2022, https://doi.org/10.5194/acp-22-15637-2022, 2022
Short summary
Short summary
Nitrate isotopes in Antarctic ice do not preserve the seasonal isotopic cycles of the atmosphere, which limits their use to study the past. We studied nitrate along an 850 km Antarctic transect to learn how these cycles are changed by sunlight-driven chemistry in the snow. Our findings suggest that the snow accumulation rate and other environmental signals can be extracted from nitrate with the right sampling and analytical approaches.
Dominic Saunderson, Andrew Mackintosh, Felicity McCormack, Richard Selwyn Jones, and Ghislain Picard
The Cryosphere, 16, 4553–4569, https://doi.org/10.5194/tc-16-4553-2022, https://doi.org/10.5194/tc-16-4553-2022, 2022
Short summary
Short summary
We investigate the variability in surface melt on the Shackleton Ice Shelf in East Antarctica over the last 2 decades (2003–2021). Using daily satellite observations and the machine learning approach of a self-organising map, we identify nine distinct spatial patterns of melt. These patterns allow comparisons of melt within and across melt seasons and highlight the importance of both air temperatures and local controls such as topography, katabatic winds, and albedo in driving surface melt.
Yanzhi Cao, Zhuang Jiang, Becky Alexander, Jihong Cole-Dai, Joel Savarino, Joseph Erbland, and Lei Geng
Atmos. Chem. Phys., 22, 13407–13422, https://doi.org/10.5194/acp-22-13407-2022, https://doi.org/10.5194/acp-22-13407-2022, 2022
Short summary
Short summary
We investigate the potential of ice-core preserved nitrate isotopes as proxies of stratospheric ozone variability by measuring nitrate isotopes in a shallow ice core from the South Pole. The large variability in the snow accumulation rate and its slight increase after the 1970s masked any signals caused by the ozone hole. Moreover, the nitrate oxygen isotope decrease may reflect changes in the atmospheric oxidation environment in the Southern Ocean.
Ghislain Picard, Henning Löwe, and Christian Mätzler
The Cryosphere, 16, 3861–3866, https://doi.org/10.5194/tc-16-3861-2022, https://doi.org/10.5194/tc-16-3861-2022, 2022
Short summary
Short summary
Microwave satellite observations used to monitor the cryosphere require radiative transfer models for their interpretation. These models represent how microwaves are scattered by snow and ice. However no existing theory is suitable for all types of snow and ice found on Earth. We adapted a recently published generic scattering theory to snow and show how it may improve the representation of snows with intermediate densities (~500 kg/m3) and/or with coarse grains at high microwave frequencies.
Albane Barbero, Roberto Grilli, Markus M. Frey, Camille Blouzon, Detlev Helmig, Nicolas Caillon, and Joël Savarino
Atmos. Chem. Phys., 22, 12025–12054, https://doi.org/10.5194/acp-22-12025-2022, https://doi.org/10.5194/acp-22-12025-2022, 2022
Short summary
Short summary
The high reactivity of the summer Antarctic boundary layer results in part from the emissions of nitrogen oxides produced during photo-denitrification of the snowpack, but its underlying mechanisms are not yet fully understood. The results of this study suggest that more NO2 is produced from the snowpack early in the photolytic season, possibly due to stronger UV irradiance caused by a smaller solar zenith angle near the solstice.
Gauthier Vérin, Florent Domine, Marcel Babin, Ghislain Picard, and Laurent Arnaud
The Cryosphere, 16, 3431–3449, https://doi.org/10.5194/tc-16-3431-2022, https://doi.org/10.5194/tc-16-3431-2022, 2022
Short summary
Short summary
Snow physical properties on Arctic sea ice are monitored during the melt season. As snow grains grow, and the snowpack thickness is reduced, the surface albedo decreases. The extra absorbed energy accelerates melting. Radiative transfer modeling shows that more radiation is then transmitted to the snow–sea-ice interface. A sharp increase in transmitted radiation takes place when the snowpack thins significantly, and this coincides with the initiation of the phytoplankton bloom in the seawater.
Josué Bock, Jan Kaiser, Max Thomas, Andreas Bott, and Roland von Glasow
Geosci. Model Dev., 15, 5807–5828, https://doi.org/10.5194/gmd-15-5807-2022, https://doi.org/10.5194/gmd-15-5807-2022, 2022
Short summary
Short summary
MISTRA-v9.0 is an atmospheric boundary layer chemistry model. The model includes a detailed particle description with regards to the microphysics, gas–particle interactions, and liquid phase chemistry within particles. Version 9.0 is the first release of MISTRA as an open-source community model. This paper presents a thorough description of the model characteristics and components. We show some examples of simulations reproducing previous studies with MISTRA with good consistency.
Zhuang Jiang, Joel Savarino, Becky Alexander, Joseph Erbland, Jean-Luc Jaffrezo, and Lei Geng
The Cryosphere, 16, 2709–2724, https://doi.org/10.5194/tc-16-2709-2022, https://doi.org/10.5194/tc-16-2709-2022, 2022
Short summary
Short summary
A record of year-round atmospheric nitrate isotopic composition along with snow nitrate isotopic data from Summit, Greenland, revealed apparent enrichments in nitrogen isotopes in snow nitrate compared to atmospheric nitrate, in addition to a relatively smaller degree of changes in oxygen isotopes. The results suggest that at this site post-depositional processing takes effect, which should be taken into account when interpreting ice-core nitrate isotope records.
Saehee Lim, Meehye Lee, Joel Savarino, and Paolo Laj
Atmos. Chem. Phys., 22, 5099–5115, https://doi.org/10.5194/acp-22-5099-2022, https://doi.org/10.5194/acp-22-5099-2022, 2022
Short summary
Short summary
We determined δ15N(NO3−) and Δ17O(NO3−) of PM2.5 in Seoul during 2018–2019 and estimated quantitatively the contribution of oxidation pathways to NO3− formation and NOx emission sources. The nighttime pathway played a significant role in NO3− formation during the winter, and its contribution further increased up to 70 % on haze days when PM2.5 was greater than 75 µg m−3. Vehicle emissions were confirmed as a main NO3− source with an increasing contribution from coal combustion in winter.
Alvaro Robledano, Ghislain Picard, Laurent Arnaud, Fanny Larue, and Inès Ollivier
The Cryosphere, 16, 559–579, https://doi.org/10.5194/tc-16-559-2022, https://doi.org/10.5194/tc-16-559-2022, 2022
Short summary
Short summary
Topography controls the surface temperature of snow-covered, mountainous areas. We developed a modelling chain that uses ray-tracing methods to quantify the impact of a few topographic effects on snow surface temperature at high spatial resolution. Its large spatial and temporal variations are correctly simulated over a 50 km2 area in the French Alps, and our results show that excluding a single topographic effect results in cooling (or warming) effects on the order of 1 °C.
Maria Belke-Brea, Florent Domine, Ghislain Picard, Mathieu Barrere, and Laurent Arnaud
Biogeosciences, 18, 5851–5869, https://doi.org/10.5194/bg-18-5851-2021, https://doi.org/10.5194/bg-18-5851-2021, 2021
Short summary
Short summary
Expanding shrubs in the Arctic change snowpacks into a mix of snow, impurities and buried branches. Snow is a translucent medium into which light penetrates and gets partly absorbed by branches or impurities. Measurements of light attenuation in snow in Northern Quebec, Canada, showed (1) black-carbon-dominated light attenuation in snowpacks without shrubs and (2) buried branches influence radiation attenuation in snow locally, leading to melting and pockets of large crystals close to branches.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
Short summary
Short summary
The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Zhuang Jiang, Becky Alexander, Joel Savarino, Joseph Erbland, and Lei Geng
The Cryosphere, 15, 4207–4220, https://doi.org/10.5194/tc-15-4207-2021, https://doi.org/10.5194/tc-15-4207-2021, 2021
Short summary
Short summary
We used a snow photochemistry model (TRANSITS) to simulate the seasonal nitrate snow profile at Summit, Greenland. Comparisons between model outputs and observations suggest that at Summit post-depositional processing is active and probably dominates the snowpack δ15N seasonality. We also used the model to assess the degree of snow nitrate loss and the consequences in its isotopes at present and in the past, which helps for quantitative interpretations of ice-core nitrate records.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, and Nicolas Caillon
Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, https://doi.org/10.5194/acp-21-10477-2021, 2021
Short summary
Short summary
We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
Josué Bock, Martine Michou, Pierre Nabat, Manabu Abe, Jane P. Mulcahy, Dirk J. L. Olivié, Jörg Schwinger, Parvadha Suntharalingam, Jerry Tjiputra, Marco van Hulten, Michio Watanabe, Andrew Yool, and Roland Séférian
Biogeosciences, 18, 3823–3860, https://doi.org/10.5194/bg-18-3823-2021, https://doi.org/10.5194/bg-18-3823-2021, 2021
Short summary
Short summary
In this study we analyse surface ocean dimethylsulfide (DMS) concentration and flux to the atmosphere from four CMIP6 Earth system models over the historical and ssp585 simulations.
Our analysis of contemporary (1980–2009) climatologies shows that models better reproduce observations in mid to high latitudes. The models disagree on the sign of the trend of the global DMS flux from 1980 onwards. The models agree on a positive trend of DMS over polar latitudes following sea-ice retreat dynamics.
Alison F. Banwell, Rajashree Tri Datta, Rebecca L. Dell, Mahsa Moussavi, Ludovic Brucker, Ghislain Picard, Christopher A. Shuman, and Laura A. Stevens
The Cryosphere, 15, 909–925, https://doi.org/10.5194/tc-15-909-2021, https://doi.org/10.5194/tc-15-909-2021, 2021
Short summary
Short summary
Ice shelves are thick floating layers of glacier ice extending from the glaciers on land that buttress much of the Antarctic Ice Sheet and help to protect it from losing ice to the ocean. However, the stability of ice shelves is vulnerable to meltwater lakes that form on their surfaces during the summer. This study focuses on the northern George VI Ice Shelf on the western side of the AP, which had an exceptionally long and extensive melt season in 2019/2020 compared to the previous 31 seasons.
François Tuzet, Marie Dumont, Ghislain Picard, Maxim Lamare, Didier Voisin, Pierre Nabat, Mathieu Lafaysse, Fanny Larue, Jesus Revuelto, and Laurent Arnaud
The Cryosphere, 14, 4553–4579, https://doi.org/10.5194/tc-14-4553-2020, https://doi.org/10.5194/tc-14-4553-2020, 2020
Short summary
Short summary
This study presents a field dataset collected over 30 d from two snow seasons at a Col du Lautaret site (French Alps). The dataset compares different measurements or estimates of light-absorbing particle (LAP) concentrations in snow, highlighting a gap in the current understanding of the measurement of these quantities. An ensemble snowpack model is then evaluated for this dataset estimating that LAPs shorten each snow season by around 10 d despite contrasting meteorological conditions.
Maxim Lamare, Marie Dumont, Ghislain Picard, Fanny Larue, François Tuzet, Clément Delcourt, and Laurent Arnaud
The Cryosphere, 14, 3995–4020, https://doi.org/10.5194/tc-14-3995-2020, https://doi.org/10.5194/tc-14-3995-2020, 2020
Short summary
Short summary
Terrain features found in mountainous regions introduce large errors into the calculation of the physical properties of snow using optical satellite images. We present a new model performing rapid calculations of solar radiation over snow-covered rugged terrain that we tested over a site in the French Alps. The results of the study show that all the interactions between sunlight and the terrain should be accounted for over snow-covered surfaces to correctly estimate snow properties from space.
Albane Barbero, Camille Blouzon, Joël Savarino, Nicolas Caillon, Aurélien Dommergue, and Roberto Grilli
Atmos. Meas. Tech., 13, 4317–4331, https://doi.org/10.5194/amt-13-4317-2020, https://doi.org/10.5194/amt-13-4317-2020, 2020
Short summary
Short summary
In this paper, we present a compact, affordable and robust instrument for in situ measurements of different trace gases: NOx, IO, CHOCHO and O3 with very low detection limits. The device weighs 15 kg and has a total electrical power consumption of < 300 W. Its very low detection limits and its design make it suitable for field applications to address different questions such as how to better constrain the oxidative capacity of the atmosphere and study the chemistry of highly reactive species.
Fanny Larue, Ghislain Picard, Laurent Arnaud, Inès Ollivier, Clément Delcourt, Maxim Lamare, François Tuzet, Jesus Revuelto, and Marie Dumont
The Cryosphere, 14, 1651–1672, https://doi.org/10.5194/tc-14-1651-2020, https://doi.org/10.5194/tc-14-1651-2020, 2020
Short summary
Short summary
The effect of surface roughness on snow albedo is often overlooked,
although a small change in albedo may strongly affect the surface energy
budget. By carving artificial roughness in an initially smooth snowpack,
we highlight albedo reductions of 0.03–0.04 at 700 nm and 0.06–0.10 at 1000 nm. A model using photon transport is developed to compute albedo considering roughness and applied to understand the impact of roughness as a function of snow properties and illumination conditions.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
Short summary
Short summary
The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Ghislain Picard, Marie Dumont, Maxim Lamare, François Tuzet, Fanny Larue, Roberta Pirazzini, and Laurent Arnaud
The Cryosphere, 14, 1497–1517, https://doi.org/10.5194/tc-14-1497-2020, https://doi.org/10.5194/tc-14-1497-2020, 2020
Short summary
Short summary
Surface albedo is an essential variable of snow-covered areas. The measurement of this variable over a tilted terrain with levelled sensors is affected by artefacts that need to be corrected. Here we develop a theory of spectral albedo measurement over slopes from which we derive four correction algorithms. The comparison to in situ measurements taken in the Alps shows the adequacy of the theory, and the application of the algorithms shows systematic improvements.
Marion Leduc-Leballeur, Ghislain Picard, Giovanni Macelloni, Arnaud Mialon, and Yann H. Kerr
The Cryosphere, 14, 539–548, https://doi.org/10.5194/tc-14-539-2020, https://doi.org/10.5194/tc-14-539-2020, 2020
Short summary
Short summary
To study the coast and ice shelves affected by melt in Antarctica during the austral summer, we exploited the 1.4 GHz radiometric satellite observations. We showed that this frequency provides additional information on melt occurrence and on the location of the water in the snowpack compared to the 19 GHz observations. This opens an avenue for improving the melting season monitoring with a combination of both frequencies and exploring the possibility of deep-water detection in the snowpack.
Philippe Massicotte, Rémi Amiraux, Marie-Pier Amyot, Philippe Archambault, Mathieu Ardyna, Laurent Arnaud, Lise Artigue, Cyril Aubry, Pierre Ayotte, Guislain Bécu, Simon Bélanger, Ronald Benner, Henry C. Bittig, Annick Bricaud, Éric Brossier, Flavienne Bruyant, Laurent Chauvaud, Debra Christiansen-Stowe, Hervé Claustre, Véronique Cornet-Barthaux, Pierre Coupel, Christine Cox, Aurelie Delaforge, Thibaud Dezutter, Céline Dimier, Florent Domine, Francis Dufour, Christiane Dufresne, Dany Dumont, Jens Ehn, Brent Else, Joannie Ferland, Marie-Hélène Forget, Louis Fortier, Martí Galí, Virginie Galindo, Morgane Gallinari, Nicole Garcia, Catherine Gérikas Ribeiro, Margaux Gourdal, Priscilla Gourvil, Clemence Goyens, Pierre-Luc Grondin, Pascal Guillot, Caroline Guilmette, Marie-Noëlle Houssais, Fabien Joux, Léo Lacour, Thomas Lacour, Augustin Lafond, José Lagunas, Catherine Lalande, Julien Laliberté, Simon Lambert-Girard, Jade Larivière, Johann Lavaud, Anita LeBaron, Karine Leblanc, Florence Le Gall, Justine Legras, Mélanie Lemire, Maurice Levasseur, Edouard Leymarie, Aude Leynaert, Adriana Lopes dos Santos, Antonio Lourenço, David Mah, Claudie Marec, Dominique Marie, Nicolas Martin, Constance Marty, Sabine Marty, Guillaume Massé, Atsushi Matsuoka, Lisa Matthes, Brivaela Moriceau, Pierre-Emmanuel Muller, Christopher-John Mundy, Griet Neukermans, Laurent Oziel, Christos Panagiotopoulos, Jean-Jacques Pangrazi, Ghislain Picard, Marc Picheral, France Pinczon du Sel, Nicole Pogorzelec, Ian Probert, Bernard Quéguiner, Patrick Raimbault, Joséphine Ras, Eric Rehm, Erin Reimer, Jean-François Rontani, Søren Rysgaard, Blanche Saint-Béat, Makoto Sampei, Julie Sansoulet, Catherine Schmechtig, Sabine Schmidt, Richard Sempéré, Caroline Sévigny, Yuan Shen, Margot Tragin, Jean-Éric Tremblay, Daniel Vaulot, Gauthier Verin, Frédéric Vivier, Anda Vladoiu, Jeremy Whitehead, and Marcel Babin
Earth Syst. Sci. Data, 12, 151–176, https://doi.org/10.5194/essd-12-151-2020, https://doi.org/10.5194/essd-12-151-2020, 2020
Short summary
Short summary
The Green Edge initiative was developed to understand the processes controlling the primary productivity and the fate of organic matter produced during the Arctic spring bloom (PSB). In this article, we present an overview of an extensive and comprehensive dataset acquired during two expeditions conducted in 2015 and 2016 on landfast ice southeast of Qikiqtarjuaq Island in Baffin Bay.
Detlev Helmig, Daniel Liptzin, Jacques Hueber, and Joel Savarino
The Cryosphere, 14, 199–209, https://doi.org/10.5194/tc-14-199-2020, https://doi.org/10.5194/tc-14-199-2020, 2020
Short summary
Short summary
We present 15 months of trace gas observations from air withdrawn within the snowpack and from above the snow at Concordia Station in Antarctica. The data show occasional positive spikes, indicative of pollution from the station generator. The pollution signal can be seen in snowpack air shortly after it is observed above the snow surface, and lasting for up to several days, much longer than above the surface.
Christiaan T. van Dalum, Willem Jan van de Berg, Quentin Libois, Ghislain Picard, and Michiel R. van den Broeke
Geosci. Model Dev., 12, 5157–5175, https://doi.org/10.5194/gmd-12-5157-2019, https://doi.org/10.5194/gmd-12-5157-2019, 2019
Short summary
Short summary
Climate models are often limited to relatively simple snow albedo schemes. Therefore, we have developed the SNOWBAL module to couple a climate model with a physically based wavelength dependent snow albedo model. Using SNOWBAL v1.2 to couple the snow albedo model TARTES with the regional climate model RACMO2 indicates a potential performance gain for the Greenland ice sheet.
Francois Tuzet, Marie Dumont, Laurent Arnaud, Didier Voisin, Maxim Lamare, Fanny Larue, Jesus Revuelto, and Ghislain Picard
The Cryosphere, 13, 2169–2187, https://doi.org/10.5194/tc-13-2169-2019, https://doi.org/10.5194/tc-13-2169-2019, 2019
Short summary
Short summary
Here we present a novel method to estimate the impurity content (e.g. black carbon or mineral dust) in Alpine snow based on measurements of light extinction profiles. This method is proposed as an alternative to chemical measurements, allowing rapid retrievals of vertical concentrations of impurities in the snowpack. In addition, the results provide a better understanding of the impact of impurities on visible light extinction in snow.
Gauthier Verin, Florent Dominé, Marcel Babin, Ghislain Picard, and Laurent Arnaud
The Cryosphere Discuss., https://doi.org/10.5194/tc-2019-113, https://doi.org/10.5194/tc-2019-113, 2019
Publication in TC not foreseen
Short summary
Short summary
The results of two sampling campaigns conducted on landfast sea ice in Baffin Bay show that the melt season can be divided into four main phases during which surface albedo and snow properties show distinct signatures. A radiative transfer model was used to successfully reconstruct the albedo from snow properties. This modeling work highlights that only little changes on the very surface of the snowpack are able to dramatically change the albedo, a key element for the energy budget of sea ice.
Ghislain Picard, Laurent Arnaud, Romain Caneill, Eric Lefebvre, and Maxim Lamare
The Cryosphere, 13, 1983–1999, https://doi.org/10.5194/tc-13-1983-2019, https://doi.org/10.5194/tc-13-1983-2019, 2019
Short summary
Short summary
To study how snow accumulates in Antarctica, we analyze daily surface elevation recorded by an automatic laser scanner. We show that new snow often accumulates in thick patches covering a small fraction of the surface. Most patches are removed by erosion within weeks, implying that only a few contribute to the snowpack. This explains the heterogeneity on the surface and in the snowpack. These findings are important for surface mass and energy balance, photochemistry, and ice core interpretation.
Nicolas Champollion, Ghislain Picard, Laurent Arnaud, Éric Lefebvre, Giovanni Macelloni, Frédérique Rémy, and Michel Fily
The Cryosphere, 13, 1215–1232, https://doi.org/10.5194/tc-13-1215-2019, https://doi.org/10.5194/tc-13-1215-2019, 2019
Short summary
Short summary
The snow density close to the surface has been retrieved from satellite observations at Dome C on the Antarctic Ice Sheet. It shows a marked decrease between 2002 and 2011 of about 10 kg m-3 yr-1. This trend has been confirmed by in situ measurements and other satellite observations though no long-term meteorological evolution has been found. These results have implications for surface mass balance and energy budget.
Tommaso Galeazzo, Slimane Bekki, Erwan Martin, Joël Savarino, and Stephen R. Arnold
Atmos. Chem. Phys., 18, 17909–17931, https://doi.org/10.5194/acp-18-17909-2018, https://doi.org/10.5194/acp-18-17909-2018, 2018
Short summary
Short summary
Volcanic sulfur can have climatic impacts for the planet via sulfate aerosol formation, leading also to pollution events. We provide model constraints on tropospheric volcanic sulfate formation, with implications for its lifetime and impacts on regional air quality. Oxygen isotope investigations from our model suggest that in the poor tropospheric plumes of halogens, the O2/TMI sulfur oxidation pathway might significantly control sulfate production. The produced sulfate has no isotopic anomaly.
Shaojie Song, Hélène Angot, Noelle E. Selin, Hubert Gallée, Francesca Sprovieri, Nicola Pirrone, Detlev Helmig, Joël Savarino, Olivier Magand, and Aurélien Dommergue
Atmos. Chem. Phys., 18, 15825–15840, https://doi.org/10.5194/acp-18-15825-2018, https://doi.org/10.5194/acp-18-15825-2018, 2018
Short summary
Short summary
Mercury is a trace metal with adverse health effects on human and wildlife. Its unique property makes it undergo long-range transport, and even remote Antarctica receives significant inputs. This paper presents the first model that aims to understand mercury behavior over the Antarctic Plateau. We find that mercury is quickly cycled between snow and air in the sunlit period, likely driven by bromine chemistry, and that several uncertain processes contribute to its behavior in the dark period.
Alexander Kokhanovsky, Maxim Lamare, Biagio Di Mauro, Ghislain Picard, Laurent Arnaud, Marie Dumont, François Tuzet, Carsten Brockmann, and Jason E. Box
The Cryosphere, 12, 2371–2382, https://doi.org/10.5194/tc-12-2371-2018, https://doi.org/10.5194/tc-12-2371-2018, 2018
Short summary
Short summary
This work presents a new technique with which to derive the snow microphysical and optical properties from snow spectral reflectance measurements. The technique is robust and easy to use, and it does not require the extraction of snow samples from a given snowpack. It can be used in processing satellite imagery over extended fresh dry, wet and polluted snowfields.
Ghislain Picard, Melody Sandells, and Henning Löwe
Geosci. Model Dev., 11, 2763–2788, https://doi.org/10.5194/gmd-11-2763-2018, https://doi.org/10.5194/gmd-11-2763-2018, 2018
Short summary
Short summary
The Snow Microwave Radiative Transfer (SMRT) is a novel model developed to calculate how microwaves are scattered and emitted by snow. The model is built from separate, interconnecting modules to make it easy to compare different aspects of the theory. SMRT is the first model to allow a choice of how to represent the microstructure of the snow, which is extremely important, and has been used to unite multiple previous studies. This model will ultimately be used to observe snow from space.
Alexandra Touzeau, Amaëlle Landais, Samuel Morin, Laurent Arnaud, and Ghislain Picard
Geosci. Model Dev., 11, 2393–2418, https://doi.org/10.5194/gmd-11-2393-2018, https://doi.org/10.5194/gmd-11-2393-2018, 2018
Short summary
Short summary
We introduced a new module of water vapor diffusion into the snowpack model Crocus. Vapor transport locally modifies the density of snow layers, possibly influencing compaction. It also affects the original isotopic signature of snow layers. We also introduced water isotopes (𝛿18O) in the model. Over 10 years, the modeled attenuation of isotopic variations due to vapor diffusion is 7–18 % lower than the observations. Thus, other processes are required to explain the total attenuation.
Fifi Ibrahime Adodo, Frédérique Remy, and Ghislain Picard
The Cryosphere, 12, 1767–1778, https://doi.org/10.5194/tc-12-1767-2018, https://doi.org/10.5194/tc-12-1767-2018, 2018
Short summary
Short summary
In Antarctica, the seasonal cycle of the backscatter behaves differently at high and low frequencies, peaking in winter and in summer, respectively. At the intermediate frequency, some areas behave analogously to low frequency in terms of the seasonal cycle, but other areas behave analogously to high frequency. This calls into question the empirical relationships often used to correct elevation changes from radar penetration into the snowpack using backscatter.
Mathieu Casado, Amaelle Landais, Ghislain Picard, Thomas Münch, Thomas Laepple, Barbara Stenni, Giuliano Dreossi, Alexey Ekaykin, Laurent Arnaud, Christophe Genthon, Alexandra Touzeau, Valerie Masson-Delmotte, and Jean Jouzel
The Cryosphere, 12, 1745–1766, https://doi.org/10.5194/tc-12-1745-2018, https://doi.org/10.5194/tc-12-1745-2018, 2018
Short summary
Short summary
Ice core isotopic records rely on the knowledge of the processes involved in the archival processes of the snow. In the East Antarctic Plateau, post-deposition processes strongly affect the signal found in the surface and buried snow compared to the initial climatic signal. We evaluate the different contributions to the surface snow isotopic composition between the precipitation and the exchanges with the atmosphere and the variability of the isotopic signal found in profiles from snow pits.
Francois Tuzet, Marie Dumont, Matthieu Lafaysse, Ghislain Picard, Laurent Arnaud, Didier Voisin, Yves Lejeune, Luc Charrois, Pierre Nabat, and Samuel Morin
The Cryosphere, 11, 2633–2653, https://doi.org/10.5194/tc-11-2633-2017, https://doi.org/10.5194/tc-11-2633-2017, 2017
Short summary
Short summary
Light-absorbing impurities deposited on snow, such as soot or dust, strongly modify its evolution. We implemented impurity deposition and evolution in a detailed snowpack model, thereby expanding the reach of such models into addressing the subtle interplays between snow physics and impurities' optical properties. Model results were evaluated based on innovative field observations at an Alpine site. This allows future investigations in the fields of climate, hydrology and avalanche prediction.
Marie Dumont, Laurent Arnaud, Ghislain Picard, Quentin Libois, Yves Lejeune, Pierre Nabat, Didier Voisin, and Samuel Morin
The Cryosphere, 11, 1091–1110, https://doi.org/10.5194/tc-11-1091-2017, https://doi.org/10.5194/tc-11-1091-2017, 2017
Short summary
Short summary
Snow spectral albedo in the visible/near-infrared range has been continuously measured during a winter season at Col de Porte alpine site (French Alps; 45.30° N, 5.77°E; 1325 m a.s.l.). This study highlights that the variations of spectral albedo can be successfully explained by variations of the following snow surface variables: snow-specific surface area, effective light-absorbing impurities content, presence of liquid water and slope.
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
Short summary
Short summary
We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
Mathieu Casado, Amaelle Landais, Ghislain Picard, Thomas Münch, Thomas Laepple, Barbara Stenni, Giuliano Dreossi, Alexey Ekaykin, Laurent Arnaud, Christophe Genthon, Alexandra Touzeau, Valérie Masson-Delmotte, and Jean Jouzel
The Cryosphere Discuss., https://doi.org/10.5194/tc-2016-263, https://doi.org/10.5194/tc-2016-263, 2016
Revised manuscript not accepted
Short summary
Short summary
Ice core isotopic records rely on the knowledge of the processes involved in the archival of the snow. In the East Antarctic Plateau, post-deposition processes strongly affect the signal found in the surface and buried snow compared to the initial climatic signal. We evaluate the different contributions to the surface snow isotopic composition between the precipitation and the exchanges with the atmosphere and the variability of the isotopic signal found in profiles from snow pits.
Ghislain Picard, Quentin Libois, and Laurent Arnaud
The Cryosphere, 10, 2655–2672, https://doi.org/10.5194/tc-10-2655-2016, https://doi.org/10.5194/tc-10-2655-2016, 2016
Short summary
Short summary
The absorption of visible light in ice is very weak but its precise value is unknown. By measuring the profile of light intensity in snow, Warren and Brand (2006) deduced that light is attenuated by a factor 2 per kilometer in pure ice at a wavelength of 400 nm. We replicated their experiment on a large number of samples and found that ice absorption is at least 10 times stronger. The paper explores various potential physical and statistical biases that could impact the experiment.
Ghislain Picard, Laurent Arnaud, Jean-Michel Panel, and Samuel Morin
The Cryosphere, 10, 1495–1511, https://doi.org/10.5194/tc-10-1495-2016, https://doi.org/10.5194/tc-10-1495-2016, 2016
Short summary
Short summary
A cost-effective automatic laser scan has been built to measure snow depth spatio-temporal variations. Deployed in the Alps and in Dome C (Antarctica), two devices acquired daily scans covering a surface area of 100–150 m2. The precision and long-term stability of the measurements are about 1 cm and the accuracy is better than 5 cm. These high performances are particularly suited at Dome C, where it was possible to reveal that most of the accumulation in the year 2015 stems from a single event.
Mathieu Casado, Amaelle Landais, Valérie Masson-Delmotte, Christophe Genthon, Erik Kerstel, Samir Kassi, Laurent Arnaud, Ghislain Picard, Frederic Prie, Olivier Cattani, Hans-Christian Steen-Larsen, Etienne Vignon, and Peter Cermak
Atmos. Chem. Phys., 16, 8521–8538, https://doi.org/10.5194/acp-16-8521-2016, https://doi.org/10.5194/acp-16-8521-2016, 2016
Short summary
Short summary
Climatic conditions in Concordia are very cold (−55 °C in average) and very dry, imposing difficult conditions to measure the water vapour isotopic composition. New developments in infrared spectroscopy enable now the measurement of isotopic composition in water vapour traces (down to 20 ppmv). Here we present the results results of a first campaign of measurement of isotopic composition of water vapour in Concordia, the site where the 800 000 years long ice core was drilled.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
Short summary
Short summary
Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Ghislain Picard, Quentin Libois, Laurent Arnaud, Gauthier Verin, and Marie Dumont
The Cryosphere, 10, 1297–1316, https://doi.org/10.5194/tc-10-1297-2016, https://doi.org/10.5194/tc-10-1297-2016, 2016
Short summary
Short summary
Albedo of snow surfaces depends on snow grain size. By measuring albedo during 3 years at Dome C in Antarctica with an automatic spectroradiometer, we were able to monitor the snow specific surface area and show an overall growth of the grains in spring and summer followed by an accumulation of small-grained snow from mid-summer. This study focuses on the uncertainties due to the spectroradiometer and concludes that the observed variations are significant with respect to the precision.
Luc Charrois, Emmanuel Cosme, Marie Dumont, Matthieu Lafaysse, Samuel Morin, Quentin Libois, and Ghislain Picard
The Cryosphere, 10, 1021–1038, https://doi.org/10.5194/tc-10-1021-2016, https://doi.org/10.5194/tc-10-1021-2016, 2016
Short summary
Short summary
This study investigates the assimilation of optical reflectances, snowdepth data and both combined into a multilayer snowpack model. Data assimilation is performed with an ensemble-based method, the Sequential Importance Resampling Particle filter. Experiments assimilating only synthetic data are conducted at one point in the French Alps, the Col du Lautaret, over five hydrological years. Results of the assimilation experiments show improvements of the snowpack bulk variables estimates.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
Short summary
Short summary
The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
Lucie Bazin, Amaelle Landais, Emilie Capron, Valérie Masson-Delmotte, Catherine Ritz, Ghislain Picard, Jean Jouzel, Marie Dumont, Markus Leuenberger, and Frédéric Prié
Clim. Past, 12, 729–748, https://doi.org/10.5194/cp-12-729-2016, https://doi.org/10.5194/cp-12-729-2016, 2016
Short summary
Short summary
We present new measurements of δO2⁄N2 and δ18Oatm performed on well-conserved ice from EDC covering MIS5 and between 380 and 800 ka. The combination of the observation of a 100 ka periodicity in the new δO2⁄N2 record with a MIS5 multi-site multi-proxy study has revealed a potential influence of local climatic parameters on δO2⁄N2. Moreover, we propose that the varying delay between d18Oatm and precession for the last 800 ka is affected by the occurrence of ice sheet discharge events.
Alexandre Roy, Alain Royer, Olivier St-Jean-Rondeau, Benoit Montpetit, Ghislain Picard, Alex Mavrovic, Nicolas Marchand, and Alexandre Langlois
The Cryosphere, 10, 623–638, https://doi.org/10.5194/tc-10-623-2016, https://doi.org/10.5194/tc-10-623-2016, 2016
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
Short summary
Short summary
Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
E. Gautier, J. Savarino, J. Erbland, A. Lanciki, and P. Possenti
Clim. Past, 12, 103–113, https://doi.org/10.5194/cp-12-103-2016, https://doi.org/10.5194/cp-12-103-2016, 2016
Short summary
Short summary
We evaluate the local-scale variability of a sulfate profile at a low-accumulation site (Dome C, Antarctica) to assess the representativeness of one ice core for volcanic reconstructions. Peak statistical occurrence, depth and flux variability are evaluated from five cores. Due to local-scale variability, 64 volcanic peaks can be identified by a five-cores analysis, while only half of them can be assessed from two cores. Using five cores, the uncertainty of the mean flux is reduced to 29 %.
Q. Libois, G. Picard, L. Arnaud, M. Dumont, M. Lafaysse, S. Morin, and E. Lefebvre
The Cryosphere, 9, 2383–2398, https://doi.org/10.5194/tc-9-2383-2015, https://doi.org/10.5194/tc-9-2383-2015, 2015
Short summary
Short summary
The albedo and surface energy budget of the Antarctic Plateau are largely determined by snow specific surface area. The latter experiences substantial daily-to-seasonal variations in response to meteorological conditions. In particular, it decreases by a factor three in summer, causing a drop in albedo. These variations are monitored from in situ and remote sensing observations at Dome C. For the first time, they are also simulated with a snowpack evolution model adapted to Antarctic conditions.
H. Löwe and G. Picard
The Cryosphere, 9, 2101–2117, https://doi.org/10.5194/tc-9-2101-2015, https://doi.org/10.5194/tc-9-2101-2015, 2015
Short summary
Short summary
The paper establishes a theoretical link between two widely used microwave models for snow. The scattering formulations from both models are unified by reformulating their microstructure models in a common framework. The results show that the scattering formulations can be considered equivalent, if exactly the same microstructure model is used. The paper also provides a method to measure a hitherto unknown input parameter for the microwave models from tomography images of snow.
J. Erbland, J. Savarino, S. Morin, J. L. France, M. M. Frey, and M. D. King
Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, https://doi.org/10.5194/acp-15-12079-2015, 2015
Short summary
Short summary
In this paper, we describe the development of a numerical model which aims at representing nitrate recycling at the air-snow interface on the East Antarctic Plateau. Stable isotopes are used as diagnostic and evaluation tools by comparing the model's results to recent field measurements of nitrate and key atmospheric species at Dome C, Antarctica. From sensitivity tests conducted with the model, we propose a framework for the interpretation of the nitrate isotope record in deep ice cores.
T. A. Berhanu, J. Savarino, J. Erbland, W. C. Vicars, S. Preunkert, J. F. Martins, and M. S. Johnson
Atmos. Chem. Phys., 15, 11243–11256, https://doi.org/10.5194/acp-15-11243-2015, https://doi.org/10.5194/acp-15-11243-2015, 2015
Short summary
Short summary
In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
Short summary
Short summary
During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
L. Geng, J. Cole-Dai, B. Alexander, J. Erbland, J. Savarino, A. J. Schauer, E. J. Steig, P. Lin, Q. Fu, and M. C. Zatko
Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, https://doi.org/10.5194/acp-14-13361-2014, 2014
Short summary
Short summary
Examinations on snowpit and firn core results from Summit, Greenland suggest that there are two mechanisms leading to the observed double nitrate peaks in some years in the industrial era: 1) long-rang transport of nitrate and 2) enhanced local photochemical production of nitrate. Both of these mechanisms are related to pollution transport, as the additional nitrate from either direct transport or enhanced local photochemistry requires enhanced nitrogen sources from anthropogenic emissions.
J.-C. Gallet, F. Domine, J. Savarino, M. Dumont, and E. Brun
The Cryosphere, 8, 1205–1215, https://doi.org/10.5194/tc-8-1205-2014, https://doi.org/10.5194/tc-8-1205-2014, 2014
G. Picard, A. Royer, L. Arnaud, and M. Fily
The Cryosphere, 8, 1105–1119, https://doi.org/10.5194/tc-8-1105-2014, https://doi.org/10.5194/tc-8-1105-2014, 2014
Q. Libois, G. Picard, J. L. France, L. Arnaud, M. Dumont, C. M. Carmagnola, and M. D. King
The Cryosphere, 7, 1803–1818, https://doi.org/10.5194/tc-7-1803-2013, https://doi.org/10.5194/tc-7-1803-2013, 2013
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Tropospheric ozone trends and attributions over East and Southeast Asia in 1995–2019: an integrated assessment using statistical methods, machine learning models, and multiple chemical transport models
Characterization of reactive oxidized nitrogen in the global upper troposphere using recent and historic commercial and research aircraft campaigns and GEOS-Chem
Soil deposition of atmospheric hydrogen constrained using planetary-scale observations
Comparative ozone production sensitivity to NOx and VOCs in Quito, Ecuador, and Santiago, Chile
South Asia anthropogenic ammonia emission inversion through assimilating IASI observations
A new parameterization of photolysis rates for oxygenated volatile organic compounds (OVOCs)
Constraining the budget of NOx and volatile organic compounds at a remote tropical island using multi-platform observations and WRF-Chem model simulations
Multi-observational estimation of regional and sectoral emission contributions to the persistent high growth rate of atmospheric CH4 for 2020–2022
Representing improved tropospheric ozone distribution over the Northern Hemisphere by including lightning NOx emissions in CHIMERE
Assessing the ability to quantify the decrease in NOx anthropogenic emissions in 2019 compared to 2005 using OMI and TROPOMI satellite observations
Tracking daily NOx emissions from an urban agglomeration based on TROPOMI NO2 and a local ensemble transform Kalman filter
Evaluation of O3, H2O, CO, and NOy climatologies simulated by four global models in the upper troposphere–lower stratosphere with IAGOS measurements
Source contribution to ozone pollution during June 2021 fire events in Arizona: insights from WRF-Chem-tagged O3 and CO
High-resolution mapping of on-road vehicle emissions with real-time traffic datasets based on big data
Sensitivity of climate–chemistry model simulated atmospheric composition to the application of an inverse relationship between NOx emission and lightning flash frequency
Regional and sectoral contributions of NOx and reactive carbon emission sources to global trends in tropospheric ozone during the 2000–2018 period
Underappreciated contributions of biogenic volatile organic compounds from urban green spaces to ozone pollution
Chemistry–climate feedback of atmospheric methane in a methane-emission-flux-driven chemistry–climate model
Surface ozone trend variability across the United States and the impact of heat waves (1990–2023)
Influence of Various Criteria on Identifying the Springtime Tropospheric Ozone Depletion Events (ODEs) at Utqiagvik, Arctic
Sensitivity of climate effects of hydrogen to leakage size, location, and chemical background
Evaluating tropospheric nitrogen dioxide in UKCA using OMI satellite retrievals over south and east Asia
Shifts in global atmospheric oxidant chemistry from land cover change
Technical note: A comparative study of chemistry schemes for volcanic sulfur dioxide in Lagrangian transport simulations – a case study of the 2019 Raikoke eruption
Revisiting the high tropospheric ozone over southern Africa: role of biomass burning and anthropogenic emissions
Monoterpene oxidation pathways initiated by acyl peroxy radical addition
Local and transboundary contributions to NOy loadings across East Asia using CMAQ-ISAM and a GEMS-informed emission inventory during the winter–spring transition
Estimating the variability in NOx emissions from Wuhan with TROPOMI NO2 data during 2018 to 2023
Effects of enhancing nitrogen use efficiency in cropland and livestock systems on agricultural ammonia emissions and particulate matter air quality in China
Enhanced understanding of atmospheric blocking modulation on ozone dynamics within a high-resolution Earth system model
Tropospheric ozone responses to the El Niño-Southern Oscillation (ENSO): quantification of individual processes and future projections from multiple chemical models
Natural emissions of VOC and NOx over Africa constrained by TROPOMI HCHO and NO2 data using the MAGRITTEv1.1 model
Contributions of lightning to long-term trends and inter-annual variability in global atmospheric chemistry constrained by Schumann Resonance observations
Simulated photochemical response to observational constraints on aerosol vertical distribution over North China
Impacts of wildfire smoke aerosols on near-surface ozone photochemistry
Anthropogenic emission controls reduce summertime ozone–temperature sensitivity in the United States
Effectiveness of Emission Controls on Atmospheric Oxidation and Air Pollutant Concentrations: Uncertainties due to Chemical Mechanisms and Inventories
Investigating the response of China's surface ozone concentration to the future changes of multiple factors
The 21st-century wetting inhibits growing surface ozone in Northwestern China
Assessing the relative impacts of satellite ozone and its precursor observations to improve global tropospheric ozone analysis using multiple chemical reanalysis systems
Evaluating present-day and future impacts of agricultural ammonia emissions on atmospheric chemistry and climate
Global atmospheric inversion of the NH3 emissions over 2019–2022 using the LMDZ-INCA chemistry-transport model and the IASI NH3 observations
Air-pollution-satellite-based CO2 emission inversion: system evaluation, sensitivity analysis, and future research direction
The impact of sea spray aerosol on photochemical ozone formation over eastern China: heterogeneous reaction of chlorine particles and radiative effect
Insights into ozone pollution control in urban areas by decoupling meteorological factors based on machine learning
Improving the computation efficiency of a source-oriented chemical mechanism for the simultaneous source apportionment of ozone and secondary particulate pollutants
Quantification of regional net CO2 flux errors in the Orbiting Carbon Observatory-2 (OCO-2) v10 model intercomparison project (MIP) ensemble using airborne measurements
Fertilization-driven Pulses of Atmospheric Nitrogen Dioxide Complicate Air Pollution in Early Spring over North China
Reactive nitrogen in and around the northeastern and mid-Atlantic US: sources, sinks, and connections with ozone
Preindustrial-to-present-day changes in atmospheric carbon monoxide: agreement and gaps between ice archives and global model reconstructions
Xiao Lu, Yiming Liu, Jiayin Su, Xiang Weng, Tabish Ansari, Yuqiang Zhang, Guowen He, Yuqi Zhu, Haolin Wang, Ganquan Zeng, Jingyu Li, Cheng He, Shuai Li, Teerachai Amnuaylojaroen, Tim Butler, Qi Fan, Shaojia Fan, Grant L. Forster, Meng Gao, Jianlin Hu, Yugo Kanaya, Mohd Talib Latif, Keding Lu, Philippe Nédélec, Peer Nowack, Bastien Sauvage, Xiaobin Xu, Lin Zhang, Ke Li, Ja-Ho Koo, and Tatsuya Nagashima
Atmos. Chem. Phys., 25, 7991–8028, https://doi.org/10.5194/acp-25-7991-2025, https://doi.org/10.5194/acp-25-7991-2025, 2025
Short summary
Short summary
This study analyzes summertime ozone trends in East and Southeast Asia derived from a comprehensive observational database spanning from 1995 to 2019, incorporating aircraft observations, ozonesonde data, and measurements from 2500 surface sites. Multiple models are applied to attribute to changes in anthropogenic emissions and climate. The results highlight that increases in anthropogenic emissions are the primary driver of ozone increases both in the free troposphere and at the surface.
Nana Wei, Eloise A. Marais, Gongda Lu, Robert G. Ryan, and Bastien Sauvage
Atmos. Chem. Phys., 25, 7925–7940, https://doi.org/10.5194/acp-25-7925-2025, https://doi.org/10.5194/acp-25-7925-2025, 2025
Short summary
Short summary
This study uses reactive nitrogen observations from NASA DC-8 research aircraft and the In-service Aircraft for a Global Observing System (IAGOS) campaigns to characterize reactive nitrogen seasonality and composition in the global upper troposphere and to diagnose the greatest knowledge gaps from comparison to a state-of-the-science model, GEOS-Chem, that need to be resolved for climate, nitrogen cycle, and air pollution assessments.
Alexander K. Tardito Chaudhri and David S. Stevenson
Atmos. Chem. Phys., 25, 7369–7385, https://doi.org/10.5194/acp-25-7369-2025, https://doi.org/10.5194/acp-25-7369-2025, 2025
Short summary
Short summary
There remains a large uncertainty in the global warming potential of atmospheric hydrogen due to poor constraints on its soil deposition and, therefore, its lifetime. A new analysis of the latitudinal variation in the observed seasonality of hydrogen is used to constrain its surface fluxes. This is complemented with a simple latitude–height model where surface fluxes are adjusted from a prototype deposition scheme.
María Cazorla, Melissa Trujillo, Rodrigo Seguel, and Laura Gallardo
Atmos. Chem. Phys., 25, 7087–7109, https://doi.org/10.5194/acp-25-7087-2025, https://doi.org/10.5194/acp-25-7087-2025, 2025
Short summary
Short summary
The current climate and environmental crises impose the need to take actions in cities to curb ozone as a pollutant and a climate forcer. This endeavor is challenging in understudied regions. In this work we analyze how reducing levels of precursor chemicals would affect ozone formation in Quito, Ecuador, and Santiago, Chile.
Ji Xia, Yi Zhou, Li Fang, Yingfei Qi, Dehao Li, Hong Liao, and Jianbing Jin
Atmos. Chem. Phys., 25, 7071–7086, https://doi.org/10.5194/acp-25-7071-2025, https://doi.org/10.5194/acp-25-7071-2025, 2025
Short summary
Short summary
This study established an ammonia emission inventory for South Asia via an assimilation-based inversion system. The posterior emissions, calculated by integrating the anthropogenic inventory and satellite observations, showed significant improvement over the prior. Validation against various measurements supports our results. The study offers a deep understanding of ammonia emissions for policymakers and researchers aiming to develop air quality management and mitigation strategies for South Asia.
Yuwen Peng, Bin Yuan, Sihang Wang, Xin Song, Zhe Peng, Wenjie Wang, Suxia Yang, Jipeng Qi, Xianjun He, Yibo Huangfu, Xiao-Bing Li, and Min Shao
Atmos. Chem. Phys., 25, 7037–7052, https://doi.org/10.5194/acp-25-7037-2025, https://doi.org/10.5194/acp-25-7037-2025, 2025
Short summary
Short summary
A structural-based parameterization for the photolysis rates of oxygenated volatile organic compounds (OVOCs) was integrated into an updated chemical mechanism. This method links photolysis rates to species' structure, bypassing limitations of insufficient quantum yield data. Box model results show that non-HCHO OVOCs, particularly multifunctional carbonyl compounds, significantly contribute to radical production, with alkene and aromatic oxidation products playing key roles.
Catalina Poraicu, Jean-François Müller, Trissevgeni Stavrakou, Crist Amelynck, Bert W. D. Verreyken, Niels Schoon, Corinne Vigouroux, Nicolas Kumps, Jérôme Brioude, Pierre Tulet, and Camille Mouchel-Vallon
Atmos. Chem. Phys., 25, 6903–6941, https://doi.org/10.5194/acp-25-6903-2025, https://doi.org/10.5194/acp-25-6903-2025, 2025
Short summary
Short summary
We investigated the sources and impacts of nitrogen oxides and organic compounds over a remote tropical island. Simulations of the high-resolution Weather Research and Forecasting model coupled with chemistry (WRF-Chem) were evaluated using in situ Fourier transform infrared spectroscopy (FTIR) and satellite measurements. This work highlights gaps in current models, like missing sources of key organic compounds and inaccuracies in emission inventories, emphasizing the importance of improving chemical and dynamical processes in atmospheric modelling for budget estimates in tropical regions.
Yosuke Niwa, Yasunori Tohjima, Yukio Terao, Tazu Saeki, Akihiko Ito, Taku Umezawa, Kyohei Yamada, Motoki Sasakawa, Toshinobu Machida, Shin-Ichiro Nakaoka, Hideki Nara, Hiroshi Tanimoto, Hitoshi Mukai, Yukio Yoshida, Shinji Morimoto, Shinya Takatsuji, Kazuhiro Tsuboi, Yousuke Sawa, Hidekazu Matsueda, Kentaro Ishijima, Ryo Fujita, Daisuke Goto, Xin Lan, Kenneth Schuldt, Michal Heliasz, Tobias Biermann, Lukasz Chmura, Jarsolaw Necki, Irène Xueref-Remy, and Damiano Sferlazzo
Atmos. Chem. Phys., 25, 6757–6785, https://doi.org/10.5194/acp-25-6757-2025, https://doi.org/10.5194/acp-25-6757-2025, 2025
Short summary
Short summary
This study estimated regional and sectoral emission contributions to the unprecedented surge of atmospheric methane for 2020–2022. The methane is the second most important greenhouse gas, and its emissions reduction is urgently required to mitigate global warming. Numerical modeling-based estimates with three different sets of atmospheric observations consistently suggested large contributions of biogenic emissions from South Asia and Southeast Asia to the surge of atmospheric methane.
Sanhita Ghosh, Arineh Cholakian, Sylvain Mailler, and Laurent Menut
Atmos. Chem. Phys., 25, 6273–6297, https://doi.org/10.5194/acp-25-6273-2025, https://doi.org/10.5194/acp-25-6273-2025, 2025
Short summary
Short summary
In this study, we evaluate the present state of modelling lightning flashes over the Northern Hemisphere, using the classical CTH (cloud-top height) scheme and the ICEFLUX scheme with the CHIMERE model. Our study provides a comprehensive 3D comparison of model outputs to assess the robustness and applicability of these schemes. An improvement in O3 distribution in the tropical free troposphere is observed due to inclusion of LNOx (nitrogen oxide emissions from lightning) in the model. Inclusion of LNOx also reduces the lifetime of trace gas CH4.
Audrey Fortems-Cheiney, Grégoire Broquet, Elise Potier, Antoine Berchet, Isabelle Pison, Adrien Martinez, Robin Plauchu, Rimal Abeed, Aurélien Sicsik-Paré, Gaelle Dufour, Adriana Coman, Dilek Savas, Guillaume Siour, Henk Eskes, Hugo A. C. Denier van der Gon, and Stijn N. C. Dellaert
Atmos. Chem. Phys., 25, 6047–6068, https://doi.org/10.5194/acp-25-6047-2025, https://doi.org/10.5194/acp-25-6047-2025, 2025
Short summary
Short summary
This study assesses the potential of the Ozone Monitoring Instrument (OMI) and the TROPOspheric Monitoring Instrument (TROPOMI) satellite observations to inform about the decrease in anthropogenic emissions of nitrogen oxides (NOx) in 2019 compared with 2005 at regional to national scales in Europe. Both the OMI and TROPOMI inversions show decreases in European NOx anthropogenic emission budgets in 2019 compared to 2005 but with different magnitudes.
Yawen Kong, Bo Zheng, and Yuxi Liu
Atmos. Chem. Phys., 25, 5959–5976, https://doi.org/10.5194/acp-25-5959-2025, https://doi.org/10.5194/acp-25-5959-2025, 2025
Short summary
Short summary
Current high-resolution satellite remote sensing technologies provide a unique opportunity to derive timely high-resolution emission data. We developed an emission inversion system to assimilate satellite NO2 data to obtain daily kilometer-scale NOx emission inventories. Our results enhance inventory accuracy, allowing us to capture the effects of pollution control policies on daily emissions (e.g., during COVID-19 lockdowns) and improve fine-scale air quality modeling.
Yann Cohen, Didier Hauglustaine, Nicolas Bellouin, Marianne Tronstad Lund, Sigrun Matthes, Agnieszka Skowron, Robin Thor, Ulrich Bundke, Andreas Petzold, Susanne Rohs, Valérie Thouret, Andreas Zahn, and Helmut Ziereis
Atmos. Chem. Phys., 25, 5793–5836, https://doi.org/10.5194/acp-25-5793-2025, https://doi.org/10.5194/acp-25-5793-2025, 2025
Short summary
Short summary
The chemical composition of the atmosphere near the tropopause is a key parameter for evaluating the climate impact of subsonic aviation pollutants. This study uses in situ data collected aboard passenger aircraft to assess the ability of four chemistry–climate models to reproduce (bi-)decadal climatologies of ozone, carbon monoxide, water vapour, and reactive nitrogen in this region. The models reproduce the very distinct ozone seasonality in the upper troposphere and in the lower stratosphere well.
Yafang Guo, Mohammad Amin Mirrezaei, Armin Sorooshian, and Avelino F. Arellano
Atmos. Chem. Phys., 25, 5591–5616, https://doi.org/10.5194/acp-25-5591-2025, https://doi.org/10.5194/acp-25-5591-2025, 2025
Short summary
Short summary
We assess the contributions of fire and anthropogenic emissions to O3 levels in Phoenix, Arizona, during a period of intense heat and drought conditions. We find that fire exacerbates O3 pollution and that interactions between weather, climate, and air chemistry are important to consider. This has implications for activities related to formulating emission reduction strategies in areas that are currently understudied yet becoming relevant due to reports of increasing global aridity.
Yujia Wang, Hongbin Wang, Bo Zhang, Peng Liu, Xinfeng Wang, Shuchun Si, Likun Xue, Qingzhu Zhang, and Qiao Wang
Atmos. Chem. Phys., 25, 5537–5555, https://doi.org/10.5194/acp-25-5537-2025, https://doi.org/10.5194/acp-25-5537-2025, 2025
Short summary
Short summary
This study established a bottom-up approach that employs real-time traffic flows and interpolation to obtain a spatially continuous on-road vehicle emission mapping for the main urban area of Jinan. The diurnal variation, spatial distribution, and emission hotspots were analyzed with clustering and hotspot analysis, showing unique fine-scale variation characteristics of on-road vehicle emissions. Future scenario analysis demonstrates remarkable benefits of electrification on emission reduction.
Francisco J. Pérez-Invernón, Francisco J. Gordillo-Vázquez, Heidi Huntrieser, Patrick Jöckel, and Eric J. Bucsela
Atmos. Chem. Phys., 25, 5557–5575, https://doi.org/10.5194/acp-25-5557-2025, https://doi.org/10.5194/acp-25-5557-2025, 2025
Short summary
Short summary
Lightning plays a significant role in tropospheric chemistry by producing substantial amounts of nitrogen oxides. According to recent estimates, thunderstorms that produce a higher lightning frequency rate also produce less nitrogen oxide per flash. We implemented the dependency of nitrogen oxide production per flash on lightning flash frequency in a chemical atmospheric model.
Aditya Nalam, Aura Lupaşcu, Tabish Ansari, and Tim Butler
Atmos. Chem. Phys., 25, 5287–5311, https://doi.org/10.5194/acp-25-5287-2025, https://doi.org/10.5194/acp-25-5287-2025, 2025
Short summary
Short summary
Tropospheric O3 molecules are labeled with the identity of their precursor source to simulate contributions from various emission sources to the global tropospheric O3 burden (TOB) and its trends. With an equatorward shift, anthropogenic NOx emissions become significantly more efficient at producing O3 and play a major role in driving TOB trends, mainly due to larger convection at the tropics effectively lifting O3 and its precursors to the free troposphere, where O3 lifetime is longer.
Haofan Wang, Yuejin Li, Yiming Liu, Xiao Lu, Yang Zhang, Qi Fan, Chong Shen, Senchao Lai, Yan Zhou, Tao Zhang, and Dingli Yue
Atmos. Chem. Phys., 25, 5233–5250, https://doi.org/10.5194/acp-25-5233-2025, https://doi.org/10.5194/acp-25-5233-2025, 2025
Short summary
Short summary
This study explores how urban green spaces (UGSs) in Guangzhou influence ozone levels. By using advanced models, we found that natural emissions from these areas can significantly affect air quality. Our results suggest that the design and planning of UGSs should not only consider aesthetics and social factors but also their environmental impacts on air quality.
Laura Stecher, Franziska Winterstein, Patrick Jöckel, Michael Ponater, Mariano Mertens, and Martin Dameris
Atmos. Chem. Phys., 25, 5133–5158, https://doi.org/10.5194/acp-25-5133-2025, https://doi.org/10.5194/acp-25-5133-2025, 2025
Short summary
Short summary
Methane, the second most important anthropogenic greenhouse gas, is chemically decomposed in the atmosphere. The chemical sink of atmospheric methane is not constant but depends on the temperature and on the abundance of its reaction partners. In this study, we use a global chemistry–climate model to assess the feedback of atmospheric methane induced by changes in the chemical sink in a warming climate and its implications for the chemical composition and the surface air temperature change.
Kai-Lan Chang, Brian C. McDonald, Colin Harkins, and Owen R. Cooper
Atmos. Chem. Phys., 25, 5101–5132, https://doi.org/10.5194/acp-25-5101-2025, https://doi.org/10.5194/acp-25-5101-2025, 2025
Short summary
Short summary
Exposure to high levels of ozone can be harmful to human health. This study shows consistent and robust evidence of decreasing ozone extremes across much of the United States over the period from 1990 to 2023, previously attributed to ozone precursor emission controls. Nevertheless, we also show that the increasing heat wave frequencies are likely to contribute to additional ozone exceedances, slowing the progress of decreasing the frequency of ozone exceedances.
Xiaochun Zhu, Le Cao, Xin Yang, Simeng Li, Jiandong Wang, and Tianliang Zhao
EGUsphere, https://doi.org/10.5194/egusphere-2024-3873, https://doi.org/10.5194/egusphere-2024-3873, 2025
Short summary
Short summary
We applied various criteria to identify springtime ODEs at Utqiagvik, Arctic, and investigated the influences of using different criteria on conclusions regarding the characteristics of ODEs. We found criteria using a constant threshold and using thresholds based on the monthly averaged ozone more suitable for identifying ODEs than the others. Applying a threshold varying with the monthly average or stricter thresholds also signifies a more significant reduction in the ODE occurrences.
Ragnhild Bieltvedt Skeie, Marit Sandstad, Srinath Krishnan, Gunnar Myhre, and Maria Sand
Atmos. Chem. Phys., 25, 4929–4942, https://doi.org/10.5194/acp-25-4929-2025, https://doi.org/10.5194/acp-25-4929-2025, 2025
Short summary
Short summary
Hydrogen leakages can alter the amount of climate gases in the atmosphere and hence have a climate impact. In this study we investigate, using an atmospheric chemistry model, how this indirect climate effect differs with different amounts of leakages and with where the hydrogen leaks and if this effect changes in the future. The effect is largest for emissions far from areas where hydrogen is removed from the atmosphere by the soil, but these are not relevant locations for a future hydrogen economy.
Alok K. Pandey, David S. Stevenson, Alcide Zhao, Richard J. Pope, Ryan Hossaini, Krishan Kumar, and Martyn P. Chipperfield
Atmos. Chem. Phys., 25, 4785–4802, https://doi.org/10.5194/acp-25-4785-2025, https://doi.org/10.5194/acp-25-4785-2025, 2025
Short summary
Short summary
Nitrogen dioxide is an air pollutant largely controlled by human activity that affects ozone, methane, and aerosols. Satellite instruments can quantify column NO2 and, by carefully matching the time and location of measurements, enable evaluation of model simulations. NO2 over south and east Asia is assessed, showing that the model captures not only many features of the measurements, but also important differences that suggest model deficiencies in representing several aspects of the atmospheric chemistry of NO2.
Ryan Vella, Sergey Gromov, Clara M. Nussbaumer, Laura Stecher, Matthias Kohl, Samuel Ruhl, Holger Tost, Jos Lelieveld, and Andrea Pozzer
EGUsphere, https://doi.org/10.5194/egusphere-2025-1800, https://doi.org/10.5194/egusphere-2025-1800, 2025
Short summary
Short summary
We evaluated how replacing forests with farmland and grazing areas affects atmospheric composition. Using a global climate-chemistry model, we found that deforestation reduces BVOCs, increases farming pollutants, and shifts ozone chemistry. These changes lead to a small cooling effect on the climate. Restoring natural vegetation could reverse some of these effects.
Mingzhao Liu, Lars Hoffmann, Jens-Uwe Grooß, Zhongyin Cai, Sabine Grießbach, and Yi Heng
Atmos. Chem. Phys., 25, 4403–4418, https://doi.org/10.5194/acp-25-4403-2025, https://doi.org/10.5194/acp-25-4403-2025, 2025
Short summary
Short summary
We studied the transport and chemical decomposition of volcanic SO2, focusing on the 2019 Raikoke event. By comparing two different chemistry modeling schemes, we found that including complex chemical reactions leads to a more accurate prediction of how long SO2 stays in the atmosphere. This research helps improve our understanding of volcanic pollution and its impact on air quality and climate, providing better tools for scientists to track and predict the movement of these pollutants.
Yufen Wang, Ke Li, Xi Chen, Zhenjiang Yang, Minglong Tang, Pascoal M. D. Campos, Yang Yang, Xu Yue, and Hong Liao
Atmos. Chem. Phys., 25, 4455–4475, https://doi.org/10.5194/acp-25-4455-2025, https://doi.org/10.5194/acp-25-4455-2025, 2025
Short summary
Short summary
The impacts of biomass burning and anthropogenic emissions on high tropospheric ozone levels are not well studied in southern Africa. We combined model simulations with recent observations at the surface and from space to quantify tropospheric ozone and its drivers in southern Africa. Our work focuses on the impact of emissions from different sources at different spatial scales, contributing to a comprehensive understanding of air pollution drivers and their uncertainties in southern Africa.
Dominika Pasik, Thomas Golin Almeida, Emelda Ahongshangbam, Siddharth Iyer, and Nanna Myllys
Atmos. Chem. Phys., 25, 4313–4331, https://doi.org/10.5194/acp-25-4313-2025, https://doi.org/10.5194/acp-25-4313-2025, 2025
Short summary
Short summary
We used quantum chemistry methods to investigate the oxidation mechanisms of acyl peroxy radicals (APRs) with various monoterpenes. Our findings reveal unique oxidation pathways for different monoterpenes, leading to either chain-terminating products or highly reactive intermediates that can contribute to particle formation in the atmosphere. This research highlights APRs as potentially significant but underexplored atmospheric oxidants that may influence future approaches to modelling climate.
Jincheol Park, Yunsoo Choi, and Sagun Kayastha
Atmos. Chem. Phys., 25, 4291–4311, https://doi.org/10.5194/acp-25-4291-2025, https://doi.org/10.5194/acp-25-4291-2025, 2025
Short summary
Short summary
We investigated NOx emission contributions to NOy loadings across five regions of East Asia during the 2022 winter–spring transition through chemical transport modeling informed by satellite data. As seasons progress, local contributions within each region to its NOy budget decreased from 32 %–43 % to 23 %–30 %, while transboundary contributions increased from 16 %–33 % to 27 %–37 %, driven by a shift in synoptic settings that allowed pollutants to spread more broadly across the regions.
Qianqian Zhang, K. Folkert Boersma, Chiel van der Laan, Alba Mols, Bin Zhao, Shengyue Li, and Yuepeng Pan
Atmos. Chem. Phys., 25, 3313–3326, https://doi.org/10.5194/acp-25-3313-2025, https://doi.org/10.5194/acp-25-3313-2025, 2025
Short summary
Short summary
Accurate NOx emission estimates are required to better understand air pollution. This study investigates and demonstrates the ability of the superposition column model in combination with TROPOMI tropospheric NO2 column data to estimate city-scale NOx emissions and lifetimes and their variabilities. The results of this work nevertheless confirm the strength of the superposition column model in estimating urban NOx emissions with reasonable accuracy.
Biao Luo, Lei Liu, David H. Y. Yung, Tiangang Yuan, Jingwei Zhang, Leo T. H. Ng, and Amos P. K. Tai
EGUsphere, https://doi.org/10.5194/egusphere-2025-72, https://doi.org/10.5194/egusphere-2025-72, 2025
Short summary
Short summary
Through a combination of emission models and air quality model, we aimed to address the pressing issue of poor nitrogen management while promoting sustainable food systems and public health in China. We discovered that improving nitrogen management of crop and livestock can substantially reduce air pollutant emissions, particularly in North China Plain. Our findings further provide the benefits of such interventions on PM2.5 reductions, offering valuable insights for policymakers.
Wenbin Kou, Yang Gao, Dan Tong, Xiaojie Guo, Xiadong An, Wenyu Liu, Mengshi Cui, Xiuwen Guo, Shaoqing Zhang, Huiwang Gao, and Lixin Wu
Atmos. Chem. Phys., 25, 3029–3048, https://doi.org/10.5194/acp-25-3029-2025, https://doi.org/10.5194/acp-25-3029-2025, 2025
Short summary
Short summary
Unlike traditional numerical studies, we apply a high-resolution Earth system model, improving simulations of surface ozone and large-scale circulations such as atmospheric blocking. Besides local heat waves, we quantify the impact of atmospheric blocking on downstream ozone concentrations, which is closely associated with the blocking position. We identify three major pathways of Rossby wave propagation, stressing the critical role of large-scale circulation in regional air quality.
Jingyu Li, Haolin Wang, Qi Fan, and Xiao Lu
EGUsphere, https://doi.org/10.5194/egusphere-2025-782, https://doi.org/10.5194/egusphere-2025-782, 2025
Short summary
Short summary
We use multiple global chemical models to quantify processes contributing the ozone response to ENSO. We find that changes in transport patterns are the dominant factor in the overall ozone-ENSO responses, with the opposing effects of chemical depletion and increased biomass burning on ozone largely offsetting each other. Models consistently project an increase in tropical ozone-ENSO response associated with strengthening anomalous circulation and more abundant water vapor with global warming.
Beata Opacka, Trissevgeni Stavrakou, Jean-François Müller, Isabelle De Smedt, Jos van Geffen, Eloise A. Marais, Rebekah P. Horner, Dylan B. Millet, Kelly C. Wells, and Alex B. Guenther
Atmos. Chem. Phys., 25, 2863–2894, https://doi.org/10.5194/acp-25-2863-2025, https://doi.org/10.5194/acp-25-2863-2025, 2025
Short summary
Short summary
Vegetation releases biogenic volatile organic compounds, while soils and lightning contribute to the natural emissions of nitrogen oxides into the atmosphere. These gases interact in complex ways. Using satellite data and models, we developed a new method to simultaneously optimize these natural emissions over Africa in 2019. Our approach resulted in an increase in natural emissions, supported by independent data indicating that current estimates are underestimated.
Xiaobo Wang, Yuzhong Zhang, Tamás Bozóki, Ruosi Liang, Xinchun Xie, Shutao Zhao, Rui Wang, Yujia Zhao, and Shuai Sun
EGUsphere, https://doi.org/10.5194/egusphere-2025-370, https://doi.org/10.5194/egusphere-2025-370, 2025
Short summary
Short summary
Schumann Resonance observations are used to parameterize lightning NOx emissions for better capturing global lightning trend and variability. Updated simulations reveal insignificant trend but greater variability in lightning NOx emissions, impacting tropospheric NOx, O3 and OH. Lightning generally counteracts non-lightning factors, reducing the inter-annua variability of tropospheric O3 and OH. Variations of global lightning play important role in understanding the atmospheric methane budget.
Xi Chen, Ke Li, Ting Yang, Xipeng Jin, Lei Chen, Yang Yang, Shuman Zhao, Bo Hu, Bin Zhu, Zifa Wang, and Hong Liao
EGUsphere, https://doi.org/10.5194/egusphere-2025-430, https://doi.org/10.5194/egusphere-2025-430, 2025
Short summary
Short summary
Aerosol vertical distribution that plays a crucial role in aerosol-photolysis interaction (API) remains underrepresented in chemical models. We integrated lidar and radiosonde observations to constrain the simulated aerosol profiles over North China and quantified the photochemical responses. The increased photolysis rates in the lower layers led to increased ozone and accounted for a 36 %–56 % reduction in API effects, resulting in enhanced atmospheric oxidizing capacity and aerosol formation.
Jiaqi Shen, Ronald C. Cohen, Glenn M. Wolfe, and Xiaomeng Jin
EGUsphere, https://doi.org/10.5194/egusphere-2025-706, https://doi.org/10.5194/egusphere-2025-706, 2025
Short summary
Short summary
This study shows large chemical and radiative effects of smoke aerosols from fires on near-surface ozone production. Aerosol loading and NOx levels are identified as the primary factors influencing these effects. Furthermore, we show that the surface PM2.5 to NO2 column ratio can be used as an indicator for identifying aerosol-dominated regimes, facilitating the assessments of aerosol impacts on ozone formation through satellite observations.
Shuai Li, Haolin Wang, and Xiao Lu
Atmos. Chem. Phys., 25, 2725–2743, https://doi.org/10.5194/acp-25-2725-2025, https://doi.org/10.5194/acp-25-2725-2025, 2025
Short summary
Short summary
Summertime ozone–temperature sensitivity has decreased by 50 % from 3.0 ppbv per K in 1990 to 1.5 ppb per K in 2021 in the US. GEOS-Chem simulations show that anthropogenic nitrogen oxide emission reduction is the dominant driver of ozone–temperature sensitivity decline by influencing both temperature direct and temperature indirect processes. Reduced ozone–temperature sensitivity has decreased ozone enhancement from low to high temperatures by an average of 6.8 ppbv across the US.
Mingjie Kang, Hongliang Zhang, and Qi Ying
EGUsphere, https://doi.org/10.5194/egusphere-2025-255, https://doi.org/10.5194/egusphere-2025-255, 2025
Short summary
Short summary
This study examines the impacts of reducing nitrogen oxides and volatile organic compounds on ozone (O3), secondary inorganic aerosols (SIA), and OH and NO3 radicals. The results show similar predictions for 8-h O3 but significant variability for SIA and radicals, with differences up to 30 % for SIA and 200 % for radicals across chemical mechanisms and inventories. The findings highlight that evaluating control strategies for SIA and atmospheric oxidation capacity requires an ensemble approach.
Jinya Yang, Yutong Wang, Lei Zhang, and Yu Zhao
Atmos. Chem. Phys., 25, 2649–2666, https://doi.org/10.5194/acp-25-2649-2025, https://doi.org/10.5194/acp-25-2649-2025, 2025
Short summary
Short summary
We develop a modeling framework to predict future ozone concentrations (till the 2060s) in China following an IPCC scenario. We evaluate the contributions of climatic, anthropogenic, and biogenic factors by season and region. We find persistent emission controls will alter the nonlinear response of ozone to its precursors and dominate the declining ozone level. The outcomes highlight the importance of human actions, even with a climate penalty on air quality.
Xiaodong Zhang, Yu Yan, Ning Zhang, Wenpeng Wang, Huabing Suo, Xiaohu Jian, Chao Wang, Haibo Ma, Hong Gao, Zhaoli Yang, Tao Huang, and Jianmin Ma
EGUsphere, https://doi.org/10.5194/egusphere-2025-258, https://doi.org/10.5194/egusphere-2025-258, 2025
Short summary
Short summary
This study performed comprehensive sensitivity model simulations to explore the surface O3 responses to historical and projected climate change in Northwestern China (NW). Our results reveal that substantial wetting trends since the 21st century have mitigated O3 growth in this region, with the influence of wetting on O3 evolution outweighing the warming effect. These findings should be taken into account in future policymaking aimed at scientifically reducing O3 pollution in NW.
Takashi Sekiya, Emanuele Emili, Kazuyuki Miyazaki, Antje Inness, Zhen Qu, R. Bradley Pierce, Dylan Jones, Helen Worden, William Y. Y. Cheng, Vincent Huijnen, and Gerbrand Koren
Atmos. Chem. Phys., 25, 2243–2268, https://doi.org/10.5194/acp-25-2243-2025, https://doi.org/10.5194/acp-25-2243-2025, 2025
Short summary
Short summary
Five global chemical reanalysis datasets were used to assess the relative impacts of assimilating satellite ozone and its precursor measurements on tropospheric ozone analyses for 2010. The multiple reanalysis system comparison allows an evaluation of the dependency of the impacts on different reanalysis systems. The results suggested the importance of satellite ozone and its precursor measurements for improving ozone analysis in the whole troposphere, with varying magnitudes among the systems.
Maureen Beaudor, Didier Hauglustaine, Juliette Lathière, Martin Van Damme, Lieven Clarisse, and Nicolas Vuichard
Atmos. Chem. Phys., 25, 2017–2046, https://doi.org/10.5194/acp-25-2017-2025, https://doi.org/10.5194/acp-25-2017-2025, 2025
Short summary
Short summary
Agriculture is the biggest ammonia (NH3) source, impacting air quality, climate, and ecosystems. Because of food demand, NH3 emissions are projected to rise by 2100. Using a global model, we analyzed the impact of present and future NH3 emissions generated from a land model. Our results show improved ammonia patterns compared to a reference inventory. Future scenarios predict up to 70 % increase in global NH3 burden, with significant changes in radiative forcing that can greatly elevate N2O.
Pramod Kumar, Grégoire Broquet, Didier Hauglustaine, Maureen Beaudor, Lieven Clarisse, Martin Van Damme, Pierre Coheur, Anne Cozic, Bo Zheng, Beatriz Revilla Romero, Antony Delavois, and Philippe Ciais
EGUsphere, https://doi.org/10.5194/egusphere-2025-162, https://doi.org/10.5194/egusphere-2025-162, 2025
Short summary
Short summary
Global maps of the NH3 emissions over 2019–2022 are derived using IASI NH3 spaceborne observations, the LMDZ-INCA chemistry-transport model at 1.27°×2.5° resolution and mass balance approach. The average global NH3 emissions over the period are ~98 Tg NH3 yr-1, which is significantly higher than three reference inventories. The analysis provides confidence in the seasonal variability and regional budgets, and provides new insights into NH3 emissions at global and regional scales.
Hui Li, Jiaxin Qiu, and Bo Zheng
Atmos. Chem. Phys., 25, 1949–1963, https://doi.org/10.5194/acp-25-1949-2025, https://doi.org/10.5194/acp-25-1949-2025, 2025
Short summary
Short summary
We conduct a sensitivity analysis with 31 tests on various factors including prior emissions, model resolution, satellite constraint, and other system configurations to assess the vulnerability of emission estimates across temporal, sectoral, and regional dimensions. This reveals the robustness of emissions estimated by this air-pollution-satellite-based CO2 emission inversion system, with relative change between tests and base inversion below 4.0 % for national annual NOx and CO2 emissions.
Yingying Hong, Yuqi Zhu, Yuxuan Huang, Yiming Liu, Chuqi Xiong, and Qi Fan
EGUsphere, https://doi.org/10.5194/egusphere-2024-4132, https://doi.org/10.5194/egusphere-2024-4132, 2025
Short summary
Short summary
This study investigates the impact of sea spray aerosol on ozone formation across Eastern China, highlighting its complex influence through both chemical reactions and radiative effects, which vary seasonally and geographically.
Yuqing Qiu, Xin Li, Wenxuan Chai, Yi Liu, Mengdi Song, Xudong Tian, Qiaoli Zou, Wenjun Lou, Wangyao Zhang, Juan Li, and Yuanhang Zhang
Atmos. Chem. Phys., 25, 1749–1763, https://doi.org/10.5194/acp-25-1749-2025, https://doi.org/10.5194/acp-25-1749-2025, 2025
Short summary
Short summary
The chemical reactions of ozone (O3) formation are related to meteorology and local emissions. Here, a random forest approach was used to eliminate the effects of meteorological factors (dispersion or transport) on O3 and its precursors. Variations in the sensitivity of O3 formation and the apportionment of emission sources were revealed after meteorological normalization. Our results suggest that meteorological variations should be considered when diagnosing O3 formation.
Qixiang Xu, Fangcheng Su, Ke Wang, Ruiqin Zhang, Qi Ying, and Michael J. Kleeman
EGUsphere, https://doi.org/10.5194/egusphere-2025-44, https://doi.org/10.5194/egusphere-2025-44, 2025
Short summary
Short summary
This manuscript introduces a novel approach for improving the computational efficiency and scalability of source-oriented chemical mechanisms by simplifying the representation of reactions involving source-tagged species and implementing a source-oriented Euler Backward Iterative (EBI) solver. These advancements reduce simulation times by up to 74 % while maintaining accuracy, offering significant practical benefits for long-term source apportionment studies.
Jeongmin Yun, Junjie Liu, Brendan Byrne, Brad Weir, Lesley E. Ott, Kathryn McKain, Bianca C. Baier, Luciana V. Gatti, and Sebastien C. Biraud
Atmos. Chem. Phys., 25, 1725–1748, https://doi.org/10.5194/acp-25-1725-2025, https://doi.org/10.5194/acp-25-1725-2025, 2025
Short summary
Short summary
This study quantifies errors in regional net surface–atmosphere CO2 flux estimates from an inverse model ensemble using airborne CO2 measurements. Our results show that flux error estimates based on observations significantly exceed those computed from the ensemble spread of flux estimates in regions with high fossil fuel emissions. This finding suggests the presence of systematic biases in the inversion estimates, associated with errors in the fossil fuel emissions common to all models.
Tian Feng, Guohui Li, Shuyu Zhao, Naifang Bei, Xin Long, Yuepeng Pan, Yu Song, Ruonan Wang, Xuexi Tie, and Luisa Molina
EGUsphere, https://doi.org/10.5194/egusphere-2025-243, https://doi.org/10.5194/egusphere-2025-243, 2025
Short summary
Short summary
Impacts of agricultural fertilization on nitrogen oxide and air quality are becoming more pronounced with continuous reductions in fossil fuel sources in China. We report that atmospheric nitrogen dioxide pulses driven by agricultural fertilizations largely complicate air pollution in North China, highlighting the necessity of agricultural emission control.
Min Huang, Gregory R. Carmichael, Kevin W. Bowman, Isabelle De Smedt, Andreas Colliander, Michael H. Cosh, Sujay V. Kumar, Alex B. Guenther, Scott J. Janz, Ryan M. Stauffer, Anne M. Thompson, Niko M. Fedkin, Robert J. Swap, John D. Bolten, and Alicia T. Joseph
Atmos. Chem. Phys., 25, 1449–1476, https://doi.org/10.5194/acp-25-1449-2025, https://doi.org/10.5194/acp-25-1449-2025, 2025
Short summary
Short summary
We use model simulations along with multiplatform, multidisciplinary observations and a range of analysis methods to estimate and understand the distributions, temporal changes, and impacts of reactive nitrogen and ozone over the most populous US region that has undergone significant environmental changes. Deposition, biogenic emissions, and extra-regional sources have been playing increasingly important roles in controlling pollutant budgets in this area as local anthropogenic emissions drop.
Xavier Faïn, Sophie Szopa, Vaishali Naïk, Patricia Martinerie, David M. Etheridge, Rachael H. Rhodes, Cathy M. Trudinger, Vasilii V. Petrenko, Kévin Fourteau, and Philip Place
Atmos. Chem. Phys., 25, 1105–1119, https://doi.org/10.5194/acp-25-1105-2025, https://doi.org/10.5194/acp-25-1105-2025, 2025
Short summary
Short summary
Carbon monoxide (CO) plays a crucial role in the atmosphere's oxidizing capacity. In this study, we analyse how historical (1850–2014) [CO] outputs from state-of-the-art global chemistry–climate models over Greenland and Antarctica are able to capture both absolute values and trends recorded in multi-site ice archives. A disparity in [CO] growth rates emerges in the Northern Hemisphere between models and observations from 1920–1975 CE, possibly linked to uncertainties in CO emission factors.
Cited articles
Abbatt, J. P. D.: Interaction of HNO3 with water–ice surfaces at temperatures of the free troposphere, Geophys. Res. Lett., 24, 1479–1482, https://doi.org/10.1029/97GL01403, 1997.
Abbatt, J. P. D.: Interactions of atmospheric trace gases with ice surfaces: adsorption and reaction, Chem. Rev., 103, 4783–4800, https://doi.org/10.1021/cr0206418, 2003.
Abbatt, J. P. D., Bartels-Rausch, T., Ullerstam, M., and Ye, T. J.: Uptake of acetone, ethanol and benzene to snow and ice: effects of surface area and temperature, Environ. Res. Lett., 3, 045008, https://doi.org/10.1088/1748-9326/3/4/045008, 2008.
Arimoto, R., Zeng, T., Davis, D., Wang, Y., Khaing, H., Nesbit, C., and Huey, G.: Concentrations and sources of aerosol ions and trace elements during ANTCI-2003, Atmos. Environ., 42, 2864–2876, https://doi.org/10.1016/j.atmosenv.2007.05.054, 2008.
Arora, O. P., Cziczo, D. J., Morgan, A. M., Abbatt, J. P. D., and Niedziela, R. F.: Uptake of nitric acid by sub-micron-sized ice particles, Geophys. Res. Lett., 26, 3621–3624, https://doi.org/10.1029/1999GL010881, 1999.
Bales, R. C., Losleben, M. V., McConnell, J. R., Fuhrer, K., and Neftel, A.: H2O2 in snow, air and open pore space in firn at Summit, Greenland, Geophys. Res. Lett., 22, 1261–1264, https://doi.org/10.1029/95GL01110, 1995.
Barret, M., Dominé, F., Houdier, S., Gallet, J.-C., Weibring, P., Walega, J., Fried, A., and Richter, D.: Formaldehyde in the Alaskan Arctic snowpack: partitioning and physical processes involved in air-snow exchanges, J. Geophys. Res., 116, D00R03, https://doi.org/10.1029/2011JD016038, 2011a.
Barret, M., Houdier, S., and Dominé, F.: Thermodynamics of the formaldehyde–water and formaldehyde–ice systems for atmospheric applications, J. Phys. Chem. A, 115, 307–317, https://doi.org/10.1021/jp108907u, 2011b.
Beine, H., Dominé, F., Simpson, W., Honrath, R., Sparapani, R., Zhou, X., and King, M.: Snow-pile and chamber experiments during the Polar Sunrise Experiment “Alert 2000”: exploration of nitrogen chemistry, Atmos. Environ., 36, 2707–2719, https://doi.org/10.1016/S1352-2310(02)00120-6, 2002.
Beine, H. J., Dominé, F., Ianniello, A., Nardino, M., Allegrini, I., Teinilä, K., and Hillamo, R.: Fluxes of nitrates between snow surfaces and the atmosphere in the European high Arctic, Atmos. Chem. Phys., 3, 335–346, https://doi.org/10.5194/acp-3-335-2003, 2003.
Berhanu, T. A., Meusinger, C., Erbland, J., Jost, R., Bhattacharya, S. K., Johnson, M. S., and Savarino, J.: Laboratory study of nitrate photolysis in Antarctic snow. II. Isotopic effects and wavelength dependence, J. Chem. Phys., 140, 244306, https://doi.org/10.1063/1.4882899, 2014.
Bianco, R., Wang, S., and Hynes, J. T.: Theoretical study of the dissociation of nitric acid at a model aqueous surface, J. Phys. Chem. A, 111, 11033–11042, https://doi.org/10.1021/jp075054a, 2007.
Bianco, R., Wang, S., and Hynes, J. T.: Infrared signatures of HNO3 and NO3− at a model aqueous surface. A theoretical study, J. Phys. Chem. A, 112, 9467–9476, https://doi.org/10.1021/jp802563g, 2008.
Bock, J. and Jacobi, H.-W.: Development of a mechanism for nitrate photochemistry in snow, J. Phys. Chem. A, 114, 1790–1796, https://doi.org/10.1021/jp909205e, 2010.
Bolton, K. and Pettersson, J. B. C.: A molecular dynamics study of the long-time ice Ih surface dynamics, J. Phys. Chem. B, 104, 1590–1595, https://doi.org/10.1021/jp9934883, 2000.
Boxe, C. S. and Saiz-Lopez, A.: Multiphase modeling of nitrate photochemistry in the quasi-liquid layer (QLL): implications for NOx release from the Arctic and coastal Antarctic snowpack, Atmos. Chem. Phys., 8, 4855–4864, https://doi.org/10.5194/acp-8-4855-2008, 2008.
Brandt, R. E. and Warren, S. G.: Solar-heating rates and temperature profiles in Antarctic snow and ice, J. Glaciol., 39, 99–110, https://doi.org/10.3198/1993JoG39-131-99-110, 1993.
Brun, E., Six, D., Picard, G., Vionnet, V., Arnaud, L., Bazile, E., Boone, A., Bouchard, A., Genthon, C., Guidard, V., Le Moigne, P., Rabier, F., and Seity, Y.: Snow/atmosphere coupled simulation at Dome C, Antarctica, J. Glaciol., 57, 721–736, https://doi.org/10.3189/002214311797409794, 2011.
Buch, V., Sadlej, J., Aytemiz-Uras, N., and Devlin, J. P.: Solvation and ionization stages of HCl on ice nanocrystals, J. Phys. Chem. A, 106, 9374–9389, https://doi.org/10.1021/jp021539h, 2002.
Calonne, N., Geindreau, C., and Flin, F.: Macroscopic modeling for heat and water vapor transfer in dry snow by homogenization, J. Phys. Chem. B, 118, 13393–13403, https://doi.org/10.1021/jp5052535, 2014.
Champollion, N., Picard, G., Arnaud, L., Lefebvre, E., and Fily, M.: Hoar crystal development and disappearance at Dome C, Antarctica: observation by near-infrared photography and passive microwave satellite, The Cryosphere, 7, 1247–1262, https://doi.org/10.5194/tc-7-1247-2013, 2013.
Chu, L. and Anastasio, C.: Quantum yields of hydroxyl radical and nitrogen dioxide from the photolysis of nitrate on ice, J. Phys. Chem. A, 107, 9594–9602, https://doi.org/10.1021/jp0349132, 2003.
Chu, L. and Anastasio, C.: Temperature and wavelength dependence of nitrite photolysis in frozen and aqueous solutions, Environ. Sci. Technol., 41, 3626–3632, https://doi.org/10.1021/es062731q, 2007.
Colbeck, S.: Snow-crystal growth with varying surface temperatures and radiation penetration, J. Glaciol., 35, 23–29, https://doi.org/10.3189/002214389793701536, 1989.
Conklin, M. H., Sigg, A., Neftel, A., and Bales, R. C.: Atmosphere-snow transfer function for H2O2: microphysical considerations, J. Geophys. Res., 98, 18367–18376, https://doi.org/10.1029/93JD01194, 1993.
Cotter, E. S. N., Jones, A. E., Wolff, E. W., and Bauguitte, S. J.-B.: What controls photochemical NO and NO2 production from Antarctic snow? Laboratory investigation assessing the wavelength and temperature dependence, J. Geophys. Res., 108, 4147, https://doi.org/10.1029/2002JD002602, 2003.
Cox, R. A., Fernandez, M. A., Symington, A., Ullerstam, M., and Abbatt, J. P. D.: A kinetic model for uptake of HNO3 and HCl on ice in a coated wall flow system, Phys. Chem. Chem. Phys., 7, 3434–3442, https://doi.org/10.1039/b506683b, 2005.
Crowley, J. N., Ammann, M., Cox, R. A., Hynes, R. G., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V – heterogeneous reactions on solid substrates, Atmos. Chem. Phys., 10, 9059–9223, https://doi.org/10.5194/acp-10-9059-2010, 2010.
Davis, D., Eisele, F., Chen, G., Crawford, J., Huey, G., Tanner, D., Slusher, D., Mauldin, L., Oncley, S., Lenschow, D., Semmer, S., Shetter, R., Lefer, B., Arimoto, R., Hogan, A., Grube, P., Lazzara, M., Bandy, A., Thornton, D., Berresheim, H., Bingemer, H., Hutterli, M., McConnell, J., Bales, R., Dibb, J., Buhr, M., Park, J., McMurry, P., Swanson, A., Meinardi, S., and Blake, D.: An overview of ISCAT 2000, Atmos. Environ., 38, 5363–5373, https://doi.org/10.1016/j.atmosenv.2004.05.037, 2004.
Davis, D., Seelig, J., Huey, G., Crawford, J., Chen, G., Wang, Y., Buhr, M., Helmig, D., Neff, W., and Blake, D.: A reassessment of Antarctic plateau reactive nitrogen based on ANTCI 2003 airborne and ground based measurements, Atmos. Environ., 42, 2831–2848, https://doi.org/10.1016/j.atmosenv.2007.07.039, 2008.
Dibb, J. E., Talbot, R. W., Munger, J. W., Jacob, D. J., and Fan, S.-M.: Air-snow exchange of HNO3 and NOy at Summit, Greenland, J. Geophys. Res., 103, 3475–3486, https://doi.org/10.1029/97JD03132, 1998.
Dibb, J. E., Arsenault, M., Peterson, M. C., and Honrath, R. E.: Fast nitrogen oxide photochemistry in Summit, Greenland snow, Atmos. Environ., 36, 2501–2511, https://doi.org/10.1016/S1352-2310(02)00130-9, 2002.
Dibb, J. E., Gregory Huey, L., Slusher, D. L., and Tanner, D. J.: Soluble reactive nitrogen oxides at South Pole during ISCAT 2000, Atmos. Environ., 38, 5399–5409, https://doi.org/10.1016/j.atmosenv.2003.01.001, 2004.
Dominé, F. and Rauzy, C.: Influence of the ice growth rate on the incorporation of gaseous HCl, Atmos. Chem. Phys., 4, 2513–2519, https://doi.org/10.5194/acp-4-2513-2004, 2004.
Dominé, F. and Thibert, E.: Relationship between atmospheric composition and snow composition for HCl and HNO3, in: Proceedings of a Boulder Symposium, IAHS Publ. no. 228, pp. 3–10, edited by: Tonnessen, K. A., Williams, M. W., and Tranter, M., 12–13 July 1995, Boulder, Colorado, USA, 1995.
Dominé, F. and Thibert, E.: Mechanism of incorporation of trace gases in ice grown from the gas phase, Geophys. Res. Lett., 23, 3627–3630, https://doi.org/10.1029/96GL03290, 1996.
Dominé, F., Thibert, E., Van Landeghem, F., Silvente, E., and Wagnon, P.: Diffusion and solubility of HCl in ice: preliminary results, Geophys. Res. Lett., 21, 601–604, https://doi.org/10.1029/94GL00512, 1994.
Dominé, F., Thibert, E., Silvente, E., Legrand, M., and Jaffrezo, J.-L.: Determining past atmospheric HCl mixing ratios from ice core analyses, J. Atmos. Chem., 21, 165–186, https://doi.org/10.1007/BF00696579, 1995.
Dominé, F., Albert, M., Huthwelker, T., Jacobi, H.-W., Kokhanovsky, A. A., Lehning, M., Picard, G., and Simpson, W. R.: Snow physics as relevant to snow photochemistry, Atmos. Chem. Phys., 8, 171–208, https://doi.org/10.5194/acp-8-171-2008, 2008.
Dominé, F., Bock, J., Voisin, D., and Donaldson, D. J.: Can we model snow photochemistry? Problems with the current approaches, J. Phys. Chem. A, 117, 4733–4749, https://doi.org/10.1021/jp3123314, 2013.
Dubowski, Y., Colussi, A. J., and Hoffmann, M. R.: Nitrogen dioxide release in the 302 nm band photolysis of spray-frozen aqueous nitrate solutions. Atmospheric implications, J. Phys. Chem. A, 105, 4928–4932, https://doi.org/10.1021/jp0042009, 2001.
Dubowski, Y., Colussi, A. J., Boxe, C., and Hoffmann, M. R.: Monotonic increase of nitrite yields in the photolysis of nitrate in ice and water between 238 and 294 K, J. Phys. Chem. A, 106, 6967–6971, https://doi.org/10.1021/jp0142942, 2002.
Ebner, P. P., Andreoli, C., Schneebeli, M., and Steinfeld, A.: Tomography-based characterization of ice-air interface dynamics of temperature gradient snow metamorphism under advective conditions, J. Geophys. Res.-Earth, 120, 2437–2451, https://doi.org/10.1002/2015JF003648, 2015.
Eisele, F., Davis, D., Helmig, D., Oltmans, S., Neff, W., Huey, G., Tanner, D., Chen, G., Crawford, J., and Arimoto, R.: Antarctic Tropospheric Chemistry Investigation (ANTCI) 2003 overview, Atmos. Environ., 42, 2749–2761, https://doi.org/10.1016/j.atmosenv.2007.04.013, 2008.
Erbland, J., Vicars, W. C., Savarino, J., Morin, S., Frey, M. M., Frosini, D., Vince, E., and Martins, J. M. F.: Air–snow transfer of nitrate on the East Antarctic Plateau – Part 1: Isotopic evidence for a photolytically driven dynamic equilibrium in summer, Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, 2013.
Erbland, J., Savarino, J., Morin, S., France, J. L., Frey, M. M., and King, M. D.: Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records, Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, 2015.
Finlayson-Pitts, B. J. and Pitts, J. N.: Chemistry of the upper and lower atmosphere: theory, experiments, and applications, Academic Press, San Diego, USA, 2000.
Flanner, M. G. and Zender, C. S.: Linking snowpack microphysics and albedo evolution, J. Geophys. Res., 111, D12208, https://doi.org/10.1029/2005JD006834, 2006.
Flin, F. and Brzoska, J.-B.: The temperature-gradient metamorphism of snow: vapour diffusion model and application to tomographic images, Ann. Glaciol., 49, 17–21, https://doi.org/10.3189/172756408787814834, 2008.
Flin, F., Brzoska, J.-B., Lesaffre, B., Coléou, C., and Pieritz, R. A.: Full three-dimensional modelling of curvature-dependent snow metamorphism: first results and comparison with experimental tomographic data, J. Phys. D Appl. Phys., 36, A49–A54, https://doi.org/10.1088/0022-3727/36/10A/310, 2003.
France, J. L., King, M. D., Frey, M. M., Erbland, J., Picard, G., Preunkert, S., MacArthur, A., and Savarino, J.: Snow optical properties at Dome C (Concordia), Antarctica; implications for snow emissions and snow chemistry of reactive nitrogen, Atmos. Chem. Phys., 11, 9787–9801, https://doi.org/10.5194/acp-11-9787-2011, 2011.
Fréville, H., Brun, E., Picard, G., Tatarinova, N., Arnaud, L., Lanconelli, C., Reijmer, C., and van den Broeke, M.: Using MODIS land surface temperatures and the Crocus snow model to understand the warm bias of ERA-Interim reanalyses at the surface in Antarctica, The Cryosphere, 8, 1361–1373, https://doi.org/10.5194/tc-8-1361-2014, 2014.
Frey, M. M., Savarino, J., Morin, S., Erbland, J., and Martins, J. M. F.: Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling, Atmos. Chem. Phys., 9, 8681–8696, https://doi.org/10.5194/acp-9-8681-2009, 2009.
Gallet, J.-C., Dominé, F., Arnaud, L., Picard, G., and Savarino, J.: Vertical profile of the specific surface area and density of the snow at Dome C and on a transect to Dumont D'Urville, Antarctica – albedo calculations and comparison to remote sensing products, The Cryosphere, 5, 631–649, https://doi.org/10.5194/tc-5-631-2011, 2011.
Gallet, J.-C., Dominé, F., Savarino, J., Dumont, M., and Brun, E.: The growth of sublimation crystals and surface hoar on the Antarctic plateau, The Cryosphere, 8, 1205–1215, https://doi.org/10.5194/tc-8-1205-2014, 2014.
Hansen, A. C. and Foslien, W. E.: A macroscale mixture theory analysis of deposition and sublimation rates during heat and mass transfer in dry snow, The Cryosphere, 9, 1857–1878, https://doi.org/10.5194/tc-9-1857-2015, 2015.
Hanson, D. R.: The uptake of HNO3 onto ice, NAT, and frozen sulfuric acid, Geophys. Res. Lett., 19, 2063–2066, https://doi.org/10.1029/92GL02182, 1992.
Hobbs, P. V.: Ice physics, Clarendon Press, Oxford, UK, 1974.
Honrath, R., Lu, Y., Peterson, M., Dibb, J., Arsenault, M., Cullen, N., and Steffen, K.: Vertical fluxes of NOx, HONO, and HNO3 above the snowpack at Summit, Greenland, Atmos. Environ., 36, 2629–2640, https://doi.org/10.1016/S1352-2310(02)00132-2, 2002.
Honrath, R. E., Peterson, M. C., Guo, S., Dibb, J. E., Shepson, P. B., and Campbell, B.: Evidence of NOx production within or upon ice particles in the Greenland snowpack, Geophys. Res. Lett., 26, 695–698, https://doi.org/10.1029/1999GL900077, 1999.
Honrath, R. E., Guo, S., Peterson, M. C., Dziobak, M. P., Dibb, J. E., and Arsenault, M. A.: Photochemical production of gas phase NOx from ice crystal NO3−, J. Geophys. Res., 105, 24183–24190, https://doi.org/10.1029/2000JD900361, 2000a.
Honrath, R. E., Peterson, M. C., Dziobak, M. P., Dibb, J. E., Arsenault, M. A., and Green, S. A.: Release of NOx from sunlight-irradiated midlatitude snow, Geophys. Res. Lett., 27, 2237–2240, https://doi.org/10.1029/1999GL011286, 2000b.
Hudson, P. K., Shilling, J. E., Tolbert, M. A., and Toon, O. B.: Uptake of nitric acid on ice at tropospheric temperatures: implications for cirrus clouds, J. Phys. Chem. A, 106, 9874–9882, https://doi.org/10.1021/jp020508j, 2002.
Huthwelker, T., Ammann, M., and Peter, T.: The uptake of acidic gases on ice, Chem. Rev., 106, 1375–1444, https://doi.org/10.1021/cr020506v, 2006.
Hutterli, M. A., Röthlisberger, R., and Bales, R. C.: Atmosphere-to-snow-to-firn transfer studies of HCHO at Summit, Greenland, Geophys. Res. Lett., 26, 1691–1694, https://doi.org/10.1029/1999GL900327, 1999.
Hutterli, M. A., Bales, R. C., McConnell, J. R., and Stewart, R. W.: HCHO in Antarctic snow: preservation in ice cores and air-snow exchange, Geophys. Res. Lett., 29, 1235, https://doi.org/10.1029/2001GL014256, 2002.
Hutterli, M. A., McConnell, J. R., Bales, R. C., and Stewart, R. W.: Sensitivity of hydrogen peroxide (H2O2) and formaldehyde (HCHO) preservation in snow to changing environmental conditions: implications for ice core records, J. Geophys. Res., 108, 4023, https://doi.org/10.1029/2002JD002528, 2003.
Hynes, R. G., Fernandez, M. A., and Cox, R. A.: Uptake of HNO3 on water-ice and coadsorption of HNO3 and HCl in the temperature range 210–235 K, J. Geophys. Res., 107, 4797, https://doi.org/10.1029/2001JD001557, 2002.
Jacob, P. and Klockow, D.: Measurements of hydrogen peroxide in Antarctic ambient air, snow and firn cores, Fresen. J. Anal. Chem., 346, 429–434, https://doi.org/10.1007/BF00325856, 1993.
Jacobi, H.-W. and Hilker, B.: A mechanism for the photochemical transformation of nitrate in snow, J. Photoch. Photobio. A, 185, 371–382, https://doi.org/10.1016/j.jphotochem.2006.06.039, 2007.
Jones, A. E., Weller, R., Wolff, E. W., and Jacobi, H. W.: Speciation and rate of photochemical NO and NO2 production in Antarctic snow, Geophys. Res. Lett., 27, 345–348, https://doi.org/10.1029/1999GL010885, 2000.
Jones, A. E., Wolff, E. W., Salmon, R. A., Bauguitte, S. J.-B., Roscoe, H. K., Anderson, P. S., Ames, D., Clemitshaw, K. C., Fleming, Z. L., Bloss, W. J., Heard, D. E., Lee, J. D., Read, K. A., Hamer, P., Shallcross, D. E., Jackson, A. V., Walker, S. L., Lewis, A. C., Mills, G. P., Plane, J. M. C., Saiz-Lopez, A., Sturges, W. T., and Worton, D. R.: Chemistry of the Antarctic Boundary Layer and the Interface with Snow: an overview of the CHABLIS campaign, Atmos. Chem. Phys., 8, 3789–3803, https://doi.org/10.5194/acp-8-3789-2008, 2008.
Jones, A. E., Wolff, E. W., Ames, D., Bauguitte, S. J.-B., Clemitshaw, K. C., Fleming, Z., Mills, G. P., Saiz-Lopez, A., Salmon, R. A., Sturges, W. T., and Worton, D. R.: The multi-seasonal NOy budget in coastal Antarctica and its link with surface snow and ice core nitrate: results from the CHABLIS campaign, Atmos. Chem. Phys., 11, 9271–9285, https://doi.org/10.5194/acp-11-9271-2011, 2011.
Jones, A. E., Brough, N., Anderson, P. S., and Wolff, E. W.: HO2NO2 and HNO3 in the coastal Antarctic winter night: a “lab-in-the-field” experiment, Atmos. Chem. Phys., 14, 11843–11851, https://doi.org/10.5194/acp-14-11843-2014, 2014.
Kaempfer, T. and Plapp, M.: Phase-field modeling of dry snow metamorphism, Phys. Rev. E, 79, 031502, https://doi.org/10.1103/PhysRevE.79.031502, 2009.
Kärcher, B. and Basko, M. M.: Trapping of trace gases in growing ice crystals, J. Geophys. Res.-Atmos., 109, D22204, https://doi.org/10.1029/2004JD005254, 2004.
Kärcher, B., Abbatt, J. P. D., Cox, R. A., Popp, P. J., and Voigt, C.: Trapping of trace gases by growing ice surfaces including surface-saturated adsorption, J. Geophys. Res., 114, D13306, https://doi.org/10.1029/2009JD011857, 2009.
Křepelová, A., Newberg, J., Huthwelker, T., Bluhm, H., and Ammann, M.: The nature of nitrate at the ice surface studied by XPS and NEXAFS, Phys. Chem. Chem. Phys., 12, 8870–8880, https://doi.org/10.1039/c0cp00359j, 2010.
Kuipers Munneke, P., van den Broeke, M. R., Reijmer, C. H., Helsen, M. M., Boot, W., Schneebeli, M., and Steffen, K.: The role of radiation penetration in the energy budget of the snowpack at Summit, Greenland, The Cryosphere, 3, 155–165, https://doi.org/10.5194/tc-3-155-2009, 2009.
Laird, S. K. and Sommerfeld, R. A.: Nitric acid adsorption on ice: a preliminary study, Geophys. Res. Lett., 22, 921–923, https://doi.org/10.1029/95GL00817, 1995.
Legrand, M. and Mayewski, P.: Glaciochemistry of polar ice cores: a review, Rev. Geophys., 35, 219–243, https://doi.org/10.1029/96RG03527, 1997.
Leu, M.-T.: Laboratory studies of sticking coefficients and heterogeneous reactions important in the Antarctic stratosphere, Geophys. Res. Let., 15, 17–20, https://doi.org/10.1029/GL015i001p00017, 1988.
Leu, M.-T., Keyser, L. F., and Timonen, R. S.: Morphology and surface areas of thin ice films, J. Phys. Chem. B, 101, 6259–6262, https://doi.org/10.1021/jp963251w, 1997.
Liao, W. and Tan, D.: 1-D Air-snowpack modeling of atmospheric nitrous acid at South Pole during ANTCI 2003, Atmos. Chem. Phys., 8, 7087–7099, https://doi.org/10.5194/acp-8-7087-2008, 2008.
Libois, Q., Picard, G., Dumont, M., Arnaud, L., Sergent, C., Pougatch, E., Sudul, M., and Vial, D.: Experimental determination of the absorption enhancement parameter of snow, J. Glaciol., 60, 714–724, https://doi.org/10.3189/2014JoG14J015, 2014.
Libois, Q., Picard, G., Arnaud, L., Dumont, M., Lafaysse, M., Morin, S., and Lefebvre, E.: Summertime evolution of snow specific surface area close to the surface on the Antarctic Plateau, The Cryosphere, 9, 2383–2398, https://doi.org/10.5194/tc-9-2383-2015, 2015.
Marbouty, D.: An experimental study of temperature-gradient metamorphism, J. Glaciol., 26, 303–312, 1980.
Marchand, P., Marcotte, G., and Ayotte, P.: Spectroscopic study of HNO3 dissociation on ice, J. Phys. Chem. A, 116, 12112–12122, https://doi.org/10.1021/jp309533f, 2012.
Marcotte, G., Ayotte, P., Bendounan, A., Sirotti, F., Laffon, C., and Parent, P.: Dissociative adsorption of nitric acid at the surface of amorphous solid water revealed by X-ray absorption spectroscopy, J. Phys. Chem. Lett., 4, 2643–2648, https://doi.org/10.1021/jz401310j, 2013.
Marcotte, G., Marchand, P., Pronovost, S., Ayotte, P., Laffon, C., and Parent, P.: Surface-enhanced nitrate photolysis on ice, J. Phys. Chem. A, 119, 1996–2005, https://doi.org/10.1021/jp511173w, 2015.
McConnell, J. R., Bales, R. C., Winterle, J. R., Kuhns, H., and Stearns, C. R.: A lumped parameter model for the atmosphere-to-snow transfer function for hydrogen peroxide, J. Geophys. Res., 102, 26809–26818, https://doi.org/10.1029/96JC02194, 1997a.
McConnell, J. R., Winterle, J. R., Bales, R. C., Thompson, A. M., and Stewart, R. W.: Physically based inversion of surface snow concentrations of H2O2 to atmospheric concentrations at South Pole, Geophys. Res. Lett., 24, 441–444, https://doi.org/10.1029/97GL00183, 1997b.
McConnell, J. R., Bales, R. C., Stewart, R. W., Thompson, A. M., Albert, M. R., and Ramos, R.: Physically based modeling of atmosphere-to-snow-to-firn transfer of H2O2 at South Pole, J. Geophys. Res., 103, 10561–10570, https://doi.org/10.1029/98JD00460, 1998.
Meusinger, C., Berhanu, T. A., Erbland, J., Savarino, J., and Johnson, M. S.: Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry, J. Chem. Phys., 140, 244305, https://doi.org/10.1063/1.4882898, 2014.
Miller, D. and Adams, E.: A microstructural dry-snow metamorphism model for kinetic crystal growth, J. Glaciol., 55, 1003–1011, https://doi.org/10.3189/002214309790794832, 2009.
Murray, K. A., Kramer, L. J., Doskey, P. V., Ganzeveld, L., Seok, B., Van Dam, B., and Helmig, D.: Dynamics of ozone and nitrogen oxides at Summit, Greenland. II. Simulating snowpack chemistry during a spring high ozone event with a 1-D process-scale model, Atmos. Environ., 117, 110–123, https://doi.org/10.1016/j.atmosenv.2015.07.004, 2015.
Perrier, S., Sassin, P., and Dominé, F.: Diffusion and solubility of HCHO in ice: preliminary results, Can. J. Phys., 81, 319–324, https://doi.org/10.1139/p03-033, 2003.
Picard, G., Brucker, L., Fily, M., Gallée, H., and Krinner, G.: Modeling time series of microwave brightness temperature in Antarctica, J. Glaciol., 55, 537–551, https://doi.org/10.3189/002214309788816678, 2009.
Picard, G., Dominé, F., Krinner, G., Arnaud, L., and Lefebvre, E.: Inhibition of the positive snow-albedo feedback by precipitation in interior Antarctica, Nature Climate Change, 2, 795–798, https://doi.org/10.1038/nclimate1590, 2012.
Picard, G., Libois, Q., Arnaud, L., Verin, G., and Dumont, M.: Development and calibration of an automatic spectral albedometer to estimate near-surface snow SSA time series, The Cryosphere, 10, 1297–1316, https://doi.org/10.5194/tc-10-1297-2016, 2016.
Pinzer, B. R. and Schneebeli, M.: Snow metamorphism under alternating temperature gradients: morphology and recrystallization in surface snow, Geophys. Res. Lett., 36, L23503, https://doi.org/10.1029/2009GL039618, 2009.
Pinzer, B. R., Schneebeli, M., and Kaempfer, T. U.: Vapor flux and recrystallization during dry snow metamorphism under a steady temperature gradient as observed by time-lapse micro-tomography, The Cryosphere, 6, 1141–1155, https://doi.org/10.5194/tc-6-1141-2012, 2012.
Preunkert, S., Ancellet, G., Legrand, M., Kukui, A., Kerbrat, M., Sarda-Estève, R., Gros, V., and Jourdain, B.: Oxidant Production over Antarctic Land and its Export (OPALE) project: an overview of the 2010–2011 summer campaign, J. Geophys. Res., 117, D15307, https://doi.org/10.1029/2011JD017145, 2012.
Pruppacher, H. R. and Klett, J. D.: Microphysics of clouds and precipitation, 2nd revised and enlarged edn., Kluwer Academic Publishers, Dordrecht/Boston/London, 1997.
Riikonen, S., Parkkinen, P., Halonen, L., and Gerber, R. B.: Ionization of nitric acid on crystalline ice: the role of defects and collective proton movement, J. Phys. Chem. Lett., 4, 1850–1855, https://doi.org/10.1021/jz400531q, 2013.
Riikonen, S., Parkkinen, P., Halonen, L., and Gerber, R. B.: Ionization of acids on the quasi-liquid layer of ice, J. Phys. Chem. A, 118, 5029–5037, https://doi.org/10.1021/jp505627n, 2014.
Röthlisberger, R., Hutterli, M. A., Wolff, E. W., Mulvaney, R., Fischer, H., Bigler, M., Goto-Azuma, K., Hansson, M. E., Ruth, U., Siggaard-Andersen, M.-L., and Steffensen, J. P.: Nitrate in Greenland and Antarctic ice cores: a detailed description of post-depositional processes, Ann. Glaciol., 35, 209–216, https://doi.org/10.3189/172756402781817220, 2002.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics : from air pollution to climate change, Wiley, New York, USA, 1998.
Sigg, A. and Neftel, A.: Seasonal variations in hydrogen peroxide in polar ice cores, Ann. Glaciol., 10, 157–162, 1988.
Sigg, A., Staffelbach, T., and Neftel, A.: Gas phase measurements of hydrogen peroxide in Greenland and their meaning for the interpretation of H2O2 records in ice cores, J. Atmos. Chem., 14, 223–232, https://doi.org/10.1007/BF00115235, 1992.
Sokolov, O. and Abbatt, J. P. D.: Competitive adsorption of atmospheric trace gases onto ice at 228 K: HNO3/HCl, 1-Butanol/Acetic acid and 1-Butanol/HCl, Geophys. Res. Lett., 29, 1851, https://doi.org/10.1029/2002GL014843, 2002.
Sommerfeld, R. A.: A branch grain theory of temperature gradient metamorphism in snow, J. Geophys. Res., 88, 1484–1494, https://doi.org/10.1029/JC088iC02p01484, 1983.
Thibert, E. and Dominé, F.: Thermodynamics and kinetics of the solid solution of HCl in ice, J. Phys. Chem. B, 101, 3554–3565, https://doi.org/10.1021/jp962115o, 1997.
Thibert, E. and Dominé, F.: Thermodynamics and kinetics of the solid solution of HNO3 in ice, J. Phys. Chem. B, 102, 4432–4439, https://doi.org/10.1021/jp980569a, 1998.
Thomas, J. L., Stutz, J., Lefer, B., Huey, L. G., Toyota, K., Dibb, J. E., and von Glasow, R.: Modeling chemistry in and above snow at Summit, Greenland – Part 1: Model description and results, Atmos. Chem. Phys., 11, 4899–4914, https://doi.org/10.5194/acp-11-4899-2011, 2011.
Town, M. S., Waddington, E. D., Walden, V. P., and Warren, S. G.: Temperatures, heating rates and vapour pressures in near-surface snow at the South Pole, J. Glaciol., 54, 487–498, https://doi.org/10.3189/002214308785837075, 2008.
Toyota, K., McConnell, J. C., Staebler, R. M., and Dastoor, A. P.: Air–snowpack exchange of bromine, ozone and mercury in the springtime Arctic simulated by the 1-D model PHANTAS – Part 1: In-snow bromine activation and its impact on ozone, Atmos. Chem. Phys., 14, 4101–4133, https://doi.org/10.5194/acp-14-4101-2014, 2014.
Traversi, R., Usoskin, I. G., Solanki, S. K., Becagli, S., Frezzotti, M., Severi, M., Stenni, B., and Udisti, R.: Nitrate in polar ice: a new tracer of solar variability, Sol. Phys., 280, 237–254, https://doi.org/10.1007/s11207-012-0060-3, 2012.
Traversi, R., Udisti, R., Frosini, D., Becagli, S., Ciardini, V., Funke, B., Lanconelli, C., Petkov, B., Scarchilli, C., Severi, M., and Vitale, V.: Insights on nitrate sources at Dome C (East Antarctic Plateau) from multi-year aerosol and snow records, Tellus B, 66, 22550, https://doi.org/10.3402/tellusb.v66.22550, 2014.
Ullerstam, M. and Abbatt, J. P. D.: Burial of gas-phase HNO3 by growing ice surfaces under tropospheric conditions, Phys. Chem. Chem. Phys., 7, 3596–3600, https://doi.org/10.1039/b507797d, 2005.
Ullerstam, M., Thornberry, T., and Abbatt, J. P. D.: Uptake of gas-phase nitric acid to ice at low partial pressures: evidence for unsaturated surface coverage, Faraday Discuss., 130, 211–226, https://doi.org/10.1039/b417418f, 2005.
Valdez, M. P., Dawson, G. A., and Bales, R. C.: Sulfur dioxide incorporation into ice depositing from the vapor, J. Geophys. Res., 94, 1095–1103, https://doi.org/10.1029/JD094iD01p01095, 1989.
Wolff, E. W., Jones, A. E., Bauguitte, S. J.-B., and Salmon, R. A.: The interpretation of spikes and trends in concentration of nitrate in polar ice cores, based on evidence from snow and atmospheric measurements, Atmos. Chem. Phys., 8, 5627–5634, https://doi.org/10.5194/acp-8-5627-2008, 2008.
Xueref, I. and Dominé, F.: FTIR spectroscopic studies of the simultaneous condensation of HCl and H2O at 190 K – Atmospheric applications, Atmos. Chem. Phys., 3, 1779–1789, https://doi.org/10.5194/acp-3-1779-2003, 2003.
Zhu, C., Xiang, B., Chu, L. T., and Zhu, L.: 308 nm photolysis of nitric acid in the gas phase, on aluminum surfaces, and on ice films, J. Phys. Chem. A, 114, 2561–2568, https://doi.org/10.1021/jp909867a, 2010.
Zondlo, M. A., Barone, S. B., and Tolbert, M. A.: Uptake of HNO3 on ice under upper tropospheric conditions, Geophys. Res. Lett., 24, 1391–1394, https://doi.org/10.1029/97GL01287, 1997.
Short summary
We develop a physically based parameterisation of the co-condensation process. Our model includes solid-state diffusion within a snow grain. It reproduces with good agreement the nitrate measurement in surface snow. Winter and summer concentrations are driven respectively by thermodynamic equilibrium and co-condensation. Adsorbed nitrate likely accounts for a minor part. This work shows that co-condensation is required to explain the chemical composition of snow undergoing temperature gradient.
We develop a physically based parameterisation of the co-condensation process. Our model...
Altmetrics
Final-revised paper
Preprint